An EPR study of Cu(2+) doped [Na(Hmal)(H(2)O)(5)] single crystals.
The magnetic environments of Cu(2+) doped Na(+) complex have been identified by electron paramagnetic resonance (EPR) technique. The angular variation of the EPR spectra has shown that two different Cu(2+) complexes are located in different chemical environments, and each environment contains one magnetic Cu(2+) site occupying substantial positions in the lattice and showing very high angular dependence. The principal g, and the hyperfine structure parameter (A) values of two sets of Cu(2+) complex groups are determined. The covalency parameter, mixing coefficients and Fermi-contact term of the complex are obtained, and the ground state wave function of the Cu(2+) ion in the lattice has been constructed.
Karabulut
Bünyamin
B
Ondokuz Mayis University, Faculty of Art and Sciences, Department of Physics, 55139 Samsun, Turkey. bbulut@omu.edu.tr
Düzgün
Filiz
F
D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004578:Electron Spin Resonance Spectroscopy; D009942:Organometallic Compounds / Q000737:chemistry*; D011208:Powders; D012964:Sodium / Q000737:chemistry*; D013696:Temperature
D009942:Organometallic Compounds; D011208:Powders; D003300:Copper; D012964:Sodium