Facile fabrication of homogeneous 3D silver nanostructures on gold-supported polyaniline membranes as promising SERS substrates.
We report a facile synthesis of large-area homogeneous three-dimensional (3D) Ag nanostructures on Au-supported polyaniline (PANI) membranes through a direct chemical reduction of metal ions by PANI. The citric acid absorbed on the Au nuclei that are prefabricated on PANI membranes directs Ag nanoaprticles (AgNPs) to self-assemble into 3D Ag nanosheet structures. The fabricated hybrid metal nanostructures display uniform surface-enhanced Raman scattering (SERS) responses throughout the whole surface area, with an average enhancement factor of 10(6)-10(7). The nanocavities formed by the stereotypical stacking of these Ag nanosheets and the junctions and gaps between two neighboring AgNPs are believed to be responsible for the strong SERS response upon plasmon absorption. These homogeneous metal nanostructure decorated PANI membranes can be used as highly efficient SERS substrates for sensitive detection of chemical and biological analytes.
Xu
Ping
P
Physical Chemistry and Spectroscopy, Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA.
Mack
Nathan H
NH
Jeon
Sea-Ho
SH
Doorn
Stephen K
SK
Han
Xijiang
X
Wang
Hsing-Lin
HL
D000814:Aniline Compounds / Q000737:chemistry*; D006046:Gold / Q000737:chemistry*; D008567:Membranes, Artificial; D008855:Microscopy, Electron, Scanning; D049329:Nanostructures; D012834:Silver / Q000737:chemistry*
D000814:Aniline Compounds; D008567:Membranes, Artificial; C416807:polyaniline; D012834:Silver; D006046:Gold