High photocatalytic degradation activity of the polyvinyl chloride (PVC)-vitamin C (VC)-TiO2 nano-composite film.
A novel photodegradable polyvinyl chloride (PVC)-vitamin C (VC)-TiO(2) nano-composite film was prepared by embedding VC modified nano-TiO(2) photocatalyst into the commercial PVC plastic. The solid-phase photocatalytic degradation behavior of PVC-VC-TiO(2) nano-composite film under UV light irradiation was investigated and compared with those of the PVC-TiO(2) film and the pure PVC film, with the aid of UV-Vis spectroscopy, scanning electron microscopy (SEM), weight loss monitoring, and X-ray diffraction spectra (XRD). The results show that PVC-VC-TiO(2) nano-composite film has a high photocatalytic activity; the photocatalytic degradation rate of it is two times higher than that of PVC-TiO(2) film and fifteen times higher than that of pure PVC film. The optimal mass ratio of VC to TiO(2) is found to be 0.5. The mechanism of enhancing photocatalytic activity is attributed to the formation of a Ti(IV)-VC charge-transfer complex with five-member chelate ring structure and a rapid photogenerated charge separation is thus achieved.
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, China.
Changjun
C
Yang
Chuqing
C
Gong
Tianyou
T
Peng
Kejian
K
Deng
Ling
L
Zan
D001205:Ascorbic Acid / Q000737:chemistry* / Q000528:radiation effects; D002384:Catalysis; D008855:Microscopy, Electron, Scanning; D036103:Nanotechnology; D010777:Photochemistry; D011143:Polyvinyl Chloride / Q000737:chemistry* / Q000528:radiation effects; D013056:Spectrophotometry, Ultraviolet; D014025:Titanium / Q000737:chemistry* / Q000528:radiation effects; D014466:Ultraviolet Rays; D014961:X-Ray Diffraction
C009495:titanium dioxide; D011143:Polyvinyl Chloride; D014025:Titanium; D001205:Ascorbic Acid