Probing selected morphological models of hydrated Nafion using large-scale molecular dynamics simulations.
Atomistic molecular dynamics simulations were performed to study hydrated Nafion systems large enough (approximately 2 million atoms, approximately 30 nm box length) to directly observe several hydrophilic domains at the molecular level. These systems consisted of six of the most significant and relevant morphological models of Nafion to-date: (1) the cluster-channel model, (2) the parallel cylinder model, (3) the local order model, (4) the lamellar model, (5) the rod network model, and (6) a "random" model that does not directly assume any particular geometry, distribution, or morphology. Each system was initially built to closely approximate the proposed hydrophilic cluster structure in a given model. Molecular dynamics simulations were then used to observe resulting changes from and behavior of the assumed initial configurations. These simulations revealed fast intercluster "bridge" formation and network percolation in all models. Sulfonate groups were found inside these bridges and played a significant role in percolation. Sulfonates also strongly aggregated around and inside clusters. Cluster surfaces were analyzed to study the hydrophilic-hydrophobic interface. Interfacial area and cluster volume significantly increased during the simulations, and radial distribution functions and structure factors were also calculated. All nonrandom models clearly exhibited the characteristic experimental scattering peak, underscoring the insensitivity of this measurement to hydrophilic domain structure and highlighting the need for future work to clearly distinguish morphological models of Nafion.
Knox
Craig K
CK
Department of Chemistry and Center for Biophysical Modeling and Simulation, Room 2020, 315 South 1400 East, University of Utah, Salt Lake City, Utah 84112-0850, USA.
Voth
Gregory A
GA
D005465:Fluorocarbon Polymers / Q000737:chemistry*; D057927:Hydrophobic and Hydrophilic Interactions; D008956:Models, Chemical; D056004:Molecular Dynamics Simulation
D005465:Fluorocarbon Polymers; C040402:perfluorosulfonic acid