Nucleophilic phosphinidene complexes: access and applicability.
Syntheses, properties, and reactivities of nucleophilic phosphinidene complexes [L(n)M=P-R] are reviewed. Emphasis is placed on the electronic tuning of this emerging class of phosphorus reagents, using different ancillary ligands and coordinatively unsaturated transition-metal moieties. The difference in applicability of the established stable 18-electron and transient 16-electron phosphinidenes is addressed.
Department of Chemistry and Pharmaceutical Sciences, VU University Amsterdam, De Boelelaan 1083, 1081 HV Amsterdam, The Netherlands.
Halil
H
Aktaş
J Chris
JC
Slootweg
Koop
K
Lammertsma
D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010720:Phosphines / Q000138:chemical synthesis / Q000737:chemistry*
D009942:Organometallic Compounds; D010720:Phosphines