Spinel to CaFe2O4 transformation: mechanism and properties of beta-CdCr2O4.
The CdCr(2)O(4) spinel transforms to a 10.6% denser new polymorph of the CaFe(2)O(4)-type structure at 10 GPa and 1100 degrees C. This new polymorph has a honeycomb-like structure because of double rutile-type chains formed by [Cr-O(6)] edge-shared octehedra. This crystal structure is prone to be magnetically frustrated and presents low-dimensional antiferromagnetism at 25 K < T < 150 K, accompanied by more complex interactions as the temperature decreases. These transitions are evidenced by magnetic susceptibility and heat capacity measurements. We also discuss a possible structural mechanism for the transformation.
Arévalo-López
Angel M
AM
Departamento de Química Inorgánica, Facultad de Químicas, Universidad Complutense de Madrid, 28040 Madrid, Spain. gozdriov@gmail.com
Dos santos-García
Antonio J
AJ
Castillo-Martínez
Elizabeth
E
Durán
Alejandro
A
Alario-Franco
Miguel A
MA