Optimization, equilibrium and kinetics studies on sorption of Acid Blue 9 using brown marine algae Turbinaria conoides.
In the present study, the parameters, temperature, adsorbent dose, contact time, adsorbent size and agitation speed were optimized for Acid Blue 9 removal from aqueous medium by using response surface methodology (RSM). The optimum conditions for maximum removal of Acid Blue 9 from an aqueous solution of 100 mg/l were found as follows: temperature (33 degrees C), adsorbent dose (3 g/l), contact time (225 min), adsorbent size (85 mesh (0.177 mm)) and agitation speed (226 rpm). At these optimized conditions, batch adsorption experiments were conducted to study the effect of pH and initial dye concentration for the removal Acid Blue 9 dye. Kinetic and equilibrium studies were carried out for the experimental results. From the kinetic studies it was found that pseudo second order model suits the system well. From the equilibrium studies, the Freundlich and Redlich-Peterson isotherm fit the data well.
Department of Chemical Engineering, Annamalai University, Annamalai Nagar, Tamil Nadu, India. kannan_vrr007@yahoo.com
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R
Rajeshkannan
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M
Rajasimman
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N
Rajamohan
D000327:Adsorption; D000704:Analysis of Variance; D001557:Benzenesulfonates / Q000737:chemistry / Q000302:isolation & purification*; D001673:Biodegradation, Environmental; D004058:Diffusion; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D008956:Models, Chemical; D000459:Phaeophyceae / Q000378:metabolism*; D012623:Seawater; D013696:Temperature; D013997:Time Factors
D001557:Benzenesulfonates; C006796:brilliant blue