Intermolecular aerobic oxidative allylic amination of simple alkenes with diarylamines catalyzed by the Pd(OCOCF3)2/NPMoV/O2 system.
Intermolecular aerobic oxidative allylic amination of simple alkyl alkenes with simple amines such as diphenylamine was induced by a Pd(OCOCF(3))(2)/NPMoV catalytic system, leading to the corresponding (E)-allylamines in good yield and selectivity through the formation of (eta(3)-allyl)palladium(II) trifluoroacetate species as a possible key intermediate.
Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, High Technology Research Center, and ORDIST, Kansai University, Suita, Osaka 564-8680, Japan.
Yosuke
Y
Shimizu
Yasushi
Y
Obora
Yasutaka
Y
Ishii
D000475:Alkenes / Q000737:chemistry*; D000586:Amination; D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry*; D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry*; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D013237:Stereoisomerism; D014638:Vanadates / Q000737:chemistry*
D000475:Alkenes; D000588:Amines; D056831:Coordination Complexes; D014638:Vanadates; D008982:Molybdenum; D010100:Oxygen