Photochemical formation of electrically conductive silver nanowires on polymer scaffolds.
A photochemical method has been exploited for the synthesis of electrically conductive silver (Ag) nanowires in a polymer solution in the presence of negatively charged Au seed particles. The synthesis was completed within 8 min of UV-photoirradiation in ambient conditions. The nanowires were fabricated on a PVA template having an average diameter of 135+/-20 nm and a length of 10-20 microm. The current-voltage (I-V) characterization showed that the PVA-Ag nanowires were continuous, having Ohmic behavior with low contact resistance. Results indicate that the PVA acted as a reducing agent, stabilizing agent, and a template for the nucleation and growth of Ag nanowires. The Ag deposition was highly selective and on the PVA only. Our research indicated that the PVA-Ag nanowires might be useful as interconnects in nanoscale integrated circuitry, functional nanodevices, and in optoelectronics.
Kundu
Subrata
S
Materials Science & Mechanical Engineering, Texas A&M University, College Station, TX 77843-3123, USA. v
Huitink
David
D
Wang
Ke
K
Liang
Hong
H
D004553:Electric Conductivity; D053768:Metal Nanoparticles / Q000737:chemistry*; D010316:Particle Size; D010777:Photochemistry; D011142:Polyvinyl Alcohol / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D013052:Spectrometry, X-Ray Emission; D013056:Spectrophotometry, Ultraviolet; D013499:Surface Properties; D014961:X-Ray Diffraction
D012834:Silver; D011142:Polyvinyl Alcohol