Spin canting and slow relaxation in a 3D pillared nickel-organic framework.
A 3D nickel-organic framework formulated as {[Ni(2)(fum)(2)(bpt)(2)(H(2)O)] x 3 H(2)O}(n) (1), built from a mixed fumaric ion (fum), 1H-3,5-bis(4-pyridyl)-1,2,4-triazole (bpt), and nickel salt, has been hydrothermally synthesized and characterized. Compound 1, having a Ni-fum chain structure in which the chains are pillared by the bpt spacers in a 3D "brick-wall"-like architecture, exhibits canted antiferromagnetism at 5.0 K. Below this temperature, slow relaxation is observed from the alternating-current susceptibility measurements corresponding to the spin-glass-like behavior.
Huang
Fu-Ping
FP
Department of Chemistry, Nankai University. Tianjin 300071, People's Republic of China.
Tian
Jin-Lei
JL
Li
Dong-Dong
DD
Chen
Gong-Jun
GJ
Gu
Wen
W
Yan
Shi-Ping
SP
Liu
Xin
X
Liao
Dai-Zheng
DZ
Cheng
Peng
P