Low-temperature and one-step synthesis of rutile TiO2 aqueous sol by heterogeneous nucleation method.
A phase-pure rutile TiO(2) aqueous sol has been prepared by heterogeneous nucleation method with an aqueous peroxotitanate solution as a precursor and SnCl(2) as rutile-phase crystalline growth promoter at a temperature as low as 100 °C in one-step process. TEM, XRD and UV-Vis spectra were used to characterize the rutile TiO(2) sol. The results reveal that a pure rutile phase TiO(2) aqueous sol with average particle sizes of around 20 nm has been synthesized, and a transparent film of rutile TiO(2) was also easily prepared by dip-coating method. Formation conditions and a possible mechanism of phase-controlling were investigated. The results show that the presence of the Sn content is essential for the formation of a pure rutile TiO(2) phase at low temperature, which involves a heterogeneous nucleation mechanism.
Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry & Graduate University of Chinese Academy of Sciences, No. 2, Beiyitiao, Zhong-guan-cun, Haidian District, Beijing 100190, PR China.
Bin
B
Qi
Liangzhuan
L
Wu
Yang
Y
Zhang
Qinghui
Q
Zeng
Jinfang
J
Zhi