title: Room-temperature ionic liquids as electrolytes in electroanalytical determination of traces of 2-furaldehyde from oil and related wastewaters from refining processes.
abstract: Three different ionic liquids, 1-ethyl-3-methylimidazolium tetrafluoroborate, [EMIM][BF(4)]; 1-butyl-3-methylimidazolium trifluoromethanesulfonate, [BMIM][OTf]; and 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl)imide [bmpyrr][NTf(2)] were studied as electrolytes in the electroanalytical quantification of 2-furaldehyde using square wave and differential pulse voltammetries. On applying a cathodic scan, a well-defined 2-electron wave was observed corresponding to the reduction of 2-furaldehyde to furfuryl alcohol. The electrochemical stability of the ionic liquids as electrolytes for analytical aspects and electrokinetic studies was investigated using a glassy carbon electrode (GCE). The measurements were carried out in a designed double-wall three-electrode cell, using two platinum wires as the quasi-reference and counter electrodes. Differential pulse voltammetry was found to be the most sensitive method at GCE. The detection limits of 1.4, 19.0 and 2.5 microg g(-1) were obtained for the determination of 2-furaldehyde in [EMIM][BF(4)], [BMIM][OTf] and [BMPyrr][NTf(2)], respectively. At a concentration of 50 microg g(-1), the maximum relative standard deviation (n=3) was 4.9%. The effect of water content of the ionic liquids on their potential windows and waveforms was also investigated. The proposed method was successfully applied to the determination of 2-furaldehyde in real samples, especially in oil matrices.
authors.affiliation: Department of Chemistry, Razi University, Kermanshah, Iran. mshamsipur@yahoo.com
authors.forename: Mojtaba
authors.initials: M
authors.lastname: Shamsipur
authors.forename: Ali Akbar Miran
authors.initials: AA
authors.lastname: Beigi
authors.forename: Mohammad
authors.initials: M
authors.lastname: Teymouri
authors.forename: Yousefali
authors.initials: Y
authors.lastname: Ghorbani
authors.forename: Mohsen
authors.initials: M
authors.lastname: Irandoust
authors.forename: Ali
authors.initials: A
authors.lastname: Mehdizadeh
mesh_terms: D004563:Electrochemistry; D004573:Electrolytes / Q000737:chemistry*; D005662:Furaldehyde / Q000032:analysis* / Q000737:chemistry*; D007220:Industrial Waste / Q000032:analysis*; D052578:Ionic Liquids / Q000737:chemistry*; D009821:Oils / Q000737:chemistry*; D013696:Temperature
chemical_list: D004573:Electrolytes; D007220:Industrial Waste; D052578:Ionic Liquids; D009821:Oils; D005662:Furaldehyde