Concise access to a model of the marine alkaloid halicyclamine A through macrocycle-forming addition of a 5-aminopenta-2,4-dienal onto a 2,3-dihydropyridinium salt.
Sinigaglia
Isabelle
I
Centre de Recherche de Gif, Institut de Chimie des Substances Naturelles, CNRS, Avenue de la Terrasse, 91198 Gif-sur-Yvette Cedex, France.
Nguyen
Tuan Minh
TM
Wypych
Jean-Charles
JC
Delpech
Bernard
B
Marazano
Christian
C
D000447:Aldehydes / Q000737:chemistry*; D000818:Animals; D001643:Bridged Bicyclo Compounds / Q000737:chemistry*; D003500:Cyclization; D004095:Dihydropyridines / Q000737:chemistry*; D047028:Macrocyclic Compounds / Q000737:chemistry*; D008956:Models, Chemical; D010880:Piperidines / Q000737:chemistry*; D011161:Porifera / Q000737:chemistry; D011726:Pyridinium Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D000447:Aldehydes; D001643:Bridged Bicyclo Compounds; D004095:Dihydropyridines; D047028:Macrocyclic Compounds; D010880:Piperidines; D011726:Pyridinium Compounds; C482962:halicyclamine A