title: Iminonitroso ene reactions: experimental studies on reactivity, regioselectivity and enantioselectivity.
abstract: Ene reactions of iminonitroso agents with olefins were investigated in both solution and solid phase. Reactions afforded allyl hydroxylamine products in up to 99% yield and with high regioselectivity. A Cu(I)-mediated enantioselective nitroso ene reaction gave an ene product with up to 40% ee.
authors.affiliation: Department of Chemistry and Biochemistry, 251 Nieuwland Science Hall, University of Notre Dame, Notre Dame, IN 46556, United States.
authors.forename: Baiyuan
authors.initials: B
authors.lastname: Yang
authors.forename: Marvin J
authors.initials: MJ
authors.lastname: Miller