Annulation of tetrathiafulvalene to the bay region of perylenediimide.
A tetrathiafulvalene donor has been annulated to the bay region of perylenediimide affording a new pi-conjugated molecular dyad. Various electronic excited charge-transfer states are generated in different oxidation states, leading to almost full absorption in the visible to near-IR region with a high extinction coefficient.
Jaggi
Michael
M
Departement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, CH-3012 Bern, Switzerland.
Blum
Carmen
C
Marti
Basil S
BS
Liu
Shi-Xia
SX
Leutwyler
Samuel
S
Decurtins
Silvio
S
D003198:Computer Simulation; D005456:Fluorescent Dyes / Q000138:chemical synthesis* / Q000737:chemistry; D006571:Heterocyclic Compounds / Q000737:chemistry*; D007094:Imides / Q000737:chemistry*; D008956:Models, Chemical; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010569:Perylene / Q000031:analogs & derivatives* / Q000737:chemistry
D005456:Fluorescent Dyes; D006571:Heterocyclic Compounds; D007094:Imides; C521332:perylenediimide; D010569:Perylene; C063887:tetrathiafulvalene