Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines.
A 1:1 mixture of (dppf)PtCl(2) and AgOTf (5 mol%) catalyzed the intermolecular hydroamination of monosubstituted allenes with secondary alkylamines at 80 degrees C to form allylic amines in good yield with selective formation of the E-diastereomer.
Toups
Kristina L
KL
French Family Science Center, Duke University, Durham, NC, USA.
Widenhoefer
Ross A
RA
D000466:Alkadienes / Q000737:chemistry*; D000586:Amination; D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D010984:Platinum / Q000737:chemistry*; D013237:Stereoisomerism
D000466:Alkadienes; D000588:Amines; D010984:Platinum; C025947:propadiene