title: Characterization of roadway stormwater system residuals for reuse and disposal options.
abstract: The chemical characterization of sediments accumulated in catch basins and stormwater ponds provides important information for assessing risks associated with management of these residuals upon removal of accumulated deposits in stormwater systems. In this study, over a period of 15 months, more than 150 residual samples were collected from 77 catch basin units and 22 stormwater ponds from 16 municipalities throughout the state of Florida. Concentrations (mg/kg) of metals and metalloids (arsenic, barium, cadmium, chromium, copper, lead, mercury, nickel, selenium, silver, and zinc) and trace organics (volatile organics, semi-volatile organics, herbicides, and pesticides) in the sediments were measured. In addition, the synthetic precipitation leaching procedure (SPLP) was utilized to evaluate pollutant leachability risk for a subset of the samples collected. Measured pollutant concentrations were compared to corresponding risk-based guidelines in Florida (i.e., Florida soil cleanup target levels) to assess potential human health risks of beneficial use of these residuals through land application. Leached concentrations were compared to risk-based water quality guidelines (i.e., Florida groundwater cleanup target levels) to examine the potential for groundwater contamination. Although several metals (arsenic, barium, chromium, copper, nickel, lead, and zinc) were routinely detected in the catch basin and stormwater pond sediments, their concentrations were generally lower than the Florida's risk-based cleanup target levels for soils. A small number of organochlorine compounds (e.g., 4,4'-DDE, 4,4'-DDT) were detected, but only in a limited number of the samples (less than 10%); leaching of trace organic pollutants above the Florida risk-based groundwater thresholds was rare. The results suggest that when land-applied or beneficially used, these residuals are not expected to pose a significant threat to human health or the environment and the results of this research will provide stormwater managers and environmental management authorities with a useful resource to examine proper disposal and beneficial use of catch basin and stormwater pond sediments.
authors.affiliation: Department of Environmental Engineering and Sciences, University of Florida, Gainesville, FL 32611-6450, USA.
authors.forename: Yong-Chul
authors.initials: YC
authors.lastname: Jang
authors.forename: Pradeep
authors.initials: P
authors.lastname: Jain
authors.forename: Thabet
authors.initials: T
authors.lastname: Tolaymat
authors.forename: Brajesh
authors.initials: B
authors.lastname: Dubey
authors.forename: Shrawan
authors.initials: S
authors.lastname: Singh
authors.forename: Timothy
authors.initials: T
authors.lastname: Townsend
mesh_terms: D002947:Cities; D004784:Environmental Monitoring; D005431:Florida; D019015:Geologic Sediments / Q000032:analysis / Q000737:chemistry; D006843:Hydrocarbons, Chlorinated / Q000032:analysis* / Q000633:toxicity; D008670:Metals / Q000032:analysis* / Q000633:toxicity; D011891:Rain; D012037:Refuse Disposal / Q000379:methods*; D018570:Risk Assessment; D013997:Time Factors; D014872:Water Movements; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000633:toxicity; D014881:Water Supply / Q000032:analysis*
chemical_list: D006843:Hydrocarbons, Chlorinated; D008670:Metals; D014874:Water Pollutants, Chemical