Selective deprotection of methanesulfonamides to amines.
Methanesulfonamides were deprotected to their parent amines via deprotonation and oxygenation with O(2) (g), even in the presence of other traditional sulfonamides.
Naito
Hiroyuki
H
Department of Biomolecular Engineering, Graduate School of Bioscience and Biotechnology, Tokyo Institute of Technology, 4259-B-59 Nagatsuta-cho, Midori-ku, Yokohama, Kanagawa 226-8501, Japan.
Hata
Takeshi
T
Urabe
Hirokazu
H
D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010100:Oxygen / Q000737:chemistry; D013237:Stereoisomerism; D013449:Sulfonamides / Q000737:chemistry*
D000588:Amines; D013449:Sulfonamides; D010100:Oxygen