Suppressed blinking dynamics of single QDs on ITO.
The exciton quenching dynamics of single CdSe/CdS(3ML)ZnCdS(2ML)ZnS(2ML) core/multishell QDs adsorbed on glass, In2O3, and ITO have been compared. Single QDs on In2O3 show shorter fluorescence lifetimes and higher blinking frequencies than those on glass because of interfacial electron transfer from QDs to In2O3. Compared to glass and In2O3, single QDs on ITO show suppressed blinking activity as well as reduced fluorescence lifetimes. For QDs in contact with the n-doped ITO, the equilibration of their Fermi levels leads to the formation of negatively charged QDs. In these negatively charged QDs, the off states are suppressed because of the effective removal of the valence band holes, and their fluorescence lifetimes are shortened because of exciton Auger recombination and hole transfer processes involving the additional electrons. This study shows that the blinking of single QDs can be effectively suppressed on the surface of ITO. This phenomenon may also be observable for other QDs and on different n-doped semiconductors.
Jin
Shengye
S
Department of Chemistry, Emory University, Atlanta, Georgia 30322, USA.
Song
Nianhui
N
Lian
Tianquan
T