Molecular metallocycles, acyclic metallodimers and 2D coordination polymers containing the twisted ligand bis(pyrimidin-2-ylthio)methane.
The versatile coordination chemistry of bis(pyrimidin-2-ylthio)methane (bptm) allows the synthesis of a series of different metal complexes with diverse structures. We describe here the synthesis and structural characterization of three kinds of compounds: four cyclic dimers, [Co(2)Cl(4)(bptm)(2)] (1), [Zn(2)I(4)(bptm)(2)] (2), [Cd(2)I(4)(bptm)(2)] (3), [Cu(2)(NO(3))(4)(bptm)(2)] (4); two acyclic dimers, [Cu(2)Br(4)(bptm)(3)] (5), [Cu(2)(AcO)(4)(bptm)(2)] (6); and two 2D coordination polymers, [CuBr(bptm)] (7) and [CuI(bptm)] (8). Different structural models are obtained on making small changes in the building units under different synthetic conditions. The effects of the weak interactions in the crystal packing were also analyzed.
Amoedo
Almudena
A
Departamento de Química Inorgánica, Facultade de Química, Universidade de Vigo, E-36310 Vigo, Galicia, Spain.
Carballo
Rosa
R
García-Martínez
Emilia
E
Lago
Ana Belén
AB
Vázquez-López
Ezequiel M
EM