Ferromagnetic coupling of [Ni(dmit)2]- anions in (m-fluoroanilinium)(dicyclohexano[18]crown-6)[Ni(dmit)2].
Ferromagnetic coupling of the [Ni(dmit)(2)](-) anion layer through lateral sulfur-sulfur interactions along the short-axis of the anion was achieved using the flexible supramolecular cation of (m-fluoroanilinium(+))(meso-dicyclohexano[18]crown-6).
Akutagawa
Tomoyuki
T
Research Institute for Electronic Science, Hokkaido University, Sapporo, 001-0020, Japan. takuta@es.hokudai.ac.jp
Sato
Daisuke
D
Ye
Qiong
Q
Noro
Shin-ichiro
S
Nakamura
Takayoshi
T
D000838:Anions / Q000737:chemistry; D018360:Crystallography, X-Ray; D008024:Ligands; D046911:Macromolecular Substances / Q000737:chemistry; D008280:Magnetics; D008958:Models, Molecular; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*
D000838:Anions; D008024:Ligands; D046911:Macromolecular Substances; D009942:Organometallic Compounds; D009532:Nickel