A heterogeneous, selective oxidation catalyst based on Mn triazacyclononane grafted under reaction conditions.
A unique method has been developed to synthesize an active heterogeneous oxidation catalyst by the in situ grafting of a 1,4,7-trimethyl-1,4,7-triazacyclononane manganese complex on carboxylic acid-functionalized supports serving dual roles as surface tether and necessary co-catalyst, massively increasing total turnovers as compared to the homogeneous analog.
Schoenfeldt
Nicholas J
NJ
Northwestern University, Department of Chemical and Biological Engineering, 2145 Sheridan Rd., Tech. E136, Evanston, IL, USA.
Korinda
Andrew W
AW
Notestein
Justin M
JM