Using of sonochemically prepared components for vapor phase growing of SbI3.3S8.
The using of sonochemically prepared components for growth of SbI(3).3S(8) single crystals from the vapor phase is presented for the first time. The good optical quality of the obtained crystals is important because this material is valuable for optoelectronics due to its non-linear optical properties. The products were characterized by using techniques such as X-ray crystallography, powder X-ray diffraction, scanning electron microscopy, energy dispersive X-ray analysis, high-resolution transmission electron microscopy, selected area electron diffraction, optical diffuse reflection spectroscopy and optical transmittance spectroscopy. The direct and indirect forbidden energy gaps of SbI(3).3S(8) illuminated with plane polarized light with electric field parallel and perpendicular to the c-axis of the crystal have been determined. The second harmonic generation of light in the grown crystals was observed.
Nowak
M
M
Solid State Physics Section, Institute of Physics, Silesian University of Technology, Krasińskiego 8, 40-019 Katowice, Poland. Marian.Nowak@polsl.pl
Kotyczka-Morańska
M
M
Szperlich
P
P
Bober
Ł
Ł
Jesionek
M
M
Kepińska
M
M
Stróz
D
D
Kusz
J
J
Szala
J
J
Moskal
G
G
Rzychoń
T
T
Młyńczak
J
J
Kopczyński
K
K
D003460:Crystallization / Q000379:methods*; D005740:Gases / Q000737:chemistry* / Q000528:radiation effects*; D044367:Phase Transition / Q000528:radiation effects; D013010:Sonication; D013457:Sulfur Compounds / Q000737:chemistry* / Q000528:radiation effects*
D005740:Gases; D013457:Sulfur Compounds