[Photo-assisted degradation of dye malachite green solution over Fe3+ C2O4-loaded resin in the presence of H2O2].
In order to increase the reaction rate of the heterogeneous Fenton-like oxidation, the catalyst of Fe3+ C2O4/R was used to catalytically decompose H2O2 for the removal of malachite green (MG) in aqueous solution under the visible light irradiation condition. The results show that the catalyst of Fe3+ C2O4/R has a better catalytic reactivity to enhance the formation of *OH compared with that of Fe3+ /R. The higher the concentration of H2O2, the faster the reaction rate is. This reaction follows pseudo-first-order kinetics, the reaction rate constant has a good relativity with the concentration of H2O. The catalyst of Fe3+ C2O4/R could decompose H2O2 to degrade MG effectively at pH 3-9, the optimum pH is 6. The removal rate of MG increased with the increase of the dosage of catalyst. With the increase of the concentration of MG, the removal of MG by the adsorption turned to be by the oxidation. Repeated uses of catalyst did not decrease the removal rate of MG. The ferryl and hydroxyl radicals are both the reactive species in the oxidation of MG.
Zhang
Ying-jie
YJ
School of Chemical Engineering, Northeast Dianli University, Jilin 132012, China. zhangyingjiejls@yahoo.com.cn
Ma
Jun
J
Chen
Lei
L
Zhao
Ji
J
Wu
Pei-ying
PY
D001673:Biodegradation, Environmental; D002384:Catalysis; D005296:Ferrous Compounds / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D007475:Ion Exchange Resins; D010070:Oxalates / Q000737:chemistry*; D055668:Photochemical Processes; D012394:Rosaniline Dyes / Q000737:chemistry / Q000302:isolation & purification*; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000302:isolation & purification*
D005296:Ferrous Compounds; D007475:Ion Exchange Resins; D010070:Oxalates; D012394:Rosaniline Dyes; D014874:Water Pollutants, Chemical; C005095:malachite green; D006861:Hydrogen Peroxide