title: Platinum(II)-catalyzed intermolecular hydroamination of monosubstituted allenes with secondary alkylamines.
abstract: A 1:1 mixture of (dppf)PtCl(2) and AgOTf (5 mol%) catalyzed the intermolecular hydroamination of monosubstituted allenes with secondary alkylamines at 80 degrees C to form allylic amines in good yield with selective formation of the E-diastereomer.
authors.affiliation: French Family Science Center, Duke University, Durham, NC, USA.
authors.forename: Kristina L
authors.initials: KL
authors.lastname: Toups
authors.forename: Ross A
authors.initials: RA
authors.lastname: Widenhoefer
mesh_terms: D000466:Alkadienes / Q000737:chemistry*; D000586:Amination; D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D010984:Platinum / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000466:Alkadienes; D000588:Amines; D010984:Platinum; C025947:propadiene