The stress tensor in thermodynamics and statistical mechanics.
We prove that the stress tensor, tau(ab), of a molecular system with arbitrary, short-range interactions can be point-wisely expressed as the functional derivative of the partition function with respect to the local deformation tensor. In this approach, the set of components of tau(ab) has a simple interpretation as the set of Lagrangian multipliers which one needs to introduce to enforce the conditions relating point particle displacements to the body local deformation tensor. The question of the possible nonuniqueness of the formula for tau(ab) is discussed.
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Dipartimento di Fisica, Università di Roma Tor Vergata INFN, Sezione di Roma Tor Vergata, Via della Ricerca Scientifica, I-00133 Roma, Italy. rossig@roma2.infn.it
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