title: exo-Selective asymmetric 1,3-dipolar cycloaddition of azomethine ylides with alkylidene malonates catalyzed by AgOAc/TF-BiphamPhos.
abstract: The first exo-selective asymmetric 1,3-dipolar cycloaddition of alkylidene malonates with azomethine ylides catalyzed by AgOAc/TF-BiphamPhos has been reported in good yields and good to excellent enantio-/diastereoselectivities.
authors.affiliation: College of Chemistry and Molecular Sciences, Wuhan University, 430072, China.
authors.forename: Zhi-Yong
authors.initials: ZY
authors.lastname: Xue
authors.forename: Tang-Lin
authors.initials: TL
authors.lastname: Liu
authors.forename: Zhou
authors.initials: Z
authors.lastname: Lu
authors.forename: He
authors.initials: H
authors.lastname: Huang
authors.forename: Hai-Yan
authors.initials: HY
authors.lastname: Tao
authors.forename: Chun-Jiang
authors.initials: CJ
authors.lastname: Wang
mesh_terms: D000085:Acetates / Q000737:chemistry*; D001391:Azo Compounds / Q000737:chemistry*; D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry*; D008314:Malonates / Q000737:chemistry*; D018030:Silver Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D013379:Substrate Specificity; D013882:Thiosemicarbazones / Q000737:chemistry*
chemical_list: D000085:Acetates; D001391:Azo Compounds; D056831:Coordination Complexes; D008314:Malonates; D018030:Silver Compounds; C549499:TF-BiphamPhos; D013882:Thiosemicarbazones; C512188:azomethine; C103100:silver acetate; C030290:malonic acid