A simple explanation of the enhancement or depletion of the enantiomeric excess in the partial sublimation of enantiomerically enriched amino acids.
In the partial sublimation of three enantiomerically enriched amino acids, the ee of the sublimates can be explained by the ratio between the saturated vapor pressures of the racemate and the pure enantiomers.
Bellec
Aurélien
A
Ecole Nationale Supérieure de Chimie de Rennes, and Université européenne de Bretagne, CNRS, UMR 6226, Avenue du Général Leclerc, CS 50837, 35708 Rennes Cedex 7, France.
Guillemin
Jean-Claude
JC
D000596:Amino Acids / Q000737:chemistry*; D013237:Stereoisomerism; D000074706:Sublimation, Chemical
D000596:Amino Acids