Exfoliation of alpha-hydroxides of nickel and cobalt in water.
p-Aminobenzoate ion intercalated alpha-hydroxides of nickel/cobalt were synthesized by precipitation using ammonia (pH= approximately 12). Aqueous colloidal suspension of alpha-hydroxide of nickel/cobalt was obtained on washing the precipitate as the pH was reduced to approximately 7. The development of partial positive charge on the amine end of the intercalated anion causes repulsion between the layers leading to exfoliation and colloidal suspension of monolayers in water. While the layers could be restacked from the colloidal suspension in the presence of other anions in the case of alpha-cobalt hydroxide, the exfoliation could not be reversed easily in the case of the nickel analog.
Nethravathi
C
C
Materials Research Group, Department of Chemistry, St. Joseph's College, 36 Lalbagh Road, Bangalore 560 027, India.
Viswanath
B
B
Sebastian
Mency
M
Rajamathi
Michael
M