exo-Selective asymmetric 1,3-dipolar cycloaddition of azomethine ylides with alkylidene malonates catalyzed by AgOAc/TF-BiphamPhos.
The first exo-selective asymmetric 1,3-dipolar cycloaddition of alkylidene malonates with azomethine ylides catalyzed by AgOAc/TF-BiphamPhos has been reported in good yields and good to excellent enantio-/diastereoselectivities.
Xue
Zhi-Yong
ZY
College of Chemistry and Molecular Sciences, Wuhan University, 430072, China.
Liu
Tang-Lin
TL
Lu
Zhou
Z
Huang
He
H
Tao
Hai-Yan
HY
Wang
Chun-Jiang
CJ
D000085:Acetates / Q000737:chemistry*; D001391:Azo Compounds / Q000737:chemistry*; D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry*; D008314:Malonates / Q000737:chemistry*; D018030:Silver Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D013379:Substrate Specificity; D013882:Thiosemicarbazones / Q000737:chemistry*
D000085:Acetates; D001391:Azo Compounds; D056831:Coordination Complexes; D008314:Malonates; D018030:Silver Compounds; C549499:TF-BiphamPhos; D013882:Thiosemicarbazones; C512188:azomethine; C103100:silver acetate; C030290:malonic acid