title: Radical-mediated thiodesulfonylation of the vinyl sulfones: Access to (α-fluoro)vinyl sulfides.
abstract: Radical-mediated thiodesulfonylation of the vinyl and (α-fluoro)vinyl sulfones, derived from aldehydes and ketones, with aryl thiols in organic or aqueous medium provided access to vinyl and (α-fluoro)vinyl sulfides. The vinyl sulfides were formed predominantly with E stereochemistry independent of the stereochemistry of the starting vinyl sulfones.
authors.affiliation: Department of Chemistry and Biochemistry, Florida International University, Miami, Florida 33199, USA.
authors.forename: Pablo R
authors.initials: PR
authors.lastname: Sacasa
authors.forename: Jessica
authors.initials: J
authors.lastname: Zayas
authors.forename: Stanislaw F
authors.initials: SF
authors.lastname: Wnuk