Mobility and fate of carbetamide in an agricultural soil.
The objective of this work is to gain a better understanding of the fate of carbetamide, as a representative herbicide, after its soil application. To reach this goal, batch and column laboratory experiments were performed and a transport model was proposed consistent with these results. Then field-scale experiments were carried out for two years and the results compared with those that would be obtained from the transport model, once the degradation terms were introduced. All this is done for four different scenarios: first, considering that the soil is under its natural condition; second, the soil is amended with organic carbon by the addition of stabilized sewage sludge; third, considering that the percolating aqueous phase contains a significant quantity of surfactant [Linear Alkyl Benzene Sulfonate, (LAS)]; and fourth, the scenario in which the sewage sludge and the surfactant are present simultaneously. The Freundlich model yields a good fit to the data of the sorption isotherms obtained from batch equilibrium experiments, but the isotherms are close to linear. The batch sorption/desorption kinetic data together with the column and field results indicate that the retention kinetics are quite fast and local equilibrium can be assumed for the description of the sorption phenomenon. Results also prove that carbetamide is moderately retained in the original soil with a mean value of the partition coefficient of carbetamide about 0.46 (L kg(-1)). When the soil is amended with sewage sludge, this coefficient is somewhat lower, about 0.40 (L kg(-1)). A further decrease is observed 0.32 L kg(-1)) when the surfactant (LAS) at critical micelle concentration (CMC) is used. The two-region model yields a good reproduction of the results of carbetamide mobility in the soil, both at the laboratory scale and at the field scale.
Crovetto
Guillermo
G
Research Group of Analytical Chemistry and Life Sciences, University of Granada, Granada, Spain.
Navalón
Alberto
A
Ballesteros
Oscar
O
Vílchez
Jose Luis
JL
García-Herruzo
Francisco
F
Rodríguez-Maroto
Jose Miguel
JM
D000327:Adsorption; D000383:Agriculture; D001673:Biodegradation, Environmental; D002219:Carbamates / Q000032:analysis* / Q000737:chemistry; D006540:Herbicides / Q000032:analysis* / Q000737:chemistry / Q000378:metabolism; D007700:Kinetics; D008823:Micelles; D008954:Models, Biological; D016062:Porosity; D012722:Sewage / Q000032:analysis / Q000737:chemistry; D012987:Soil / Q000032:analysis*; D012989:Soil Pollutants / Q000032:analysis* / Q000737:chemistry / Q000378:metabolism; D012995:Solubility; D012997:Solvents / Q000737:chemistry; D013501:Surface-Active Agents / Q000032:analysis / Q000737:chemistry / Q000378:metabolism; D014872:Water Movements
D002219:Carbamates; D006540:Herbicides; D008823:Micelles; D012722:Sewage; D012987:Soil; D012989:Soil Pollutants; D012997:Solvents; D013501:Surface-Active Agents