title: Atmospheric distribution of polychlorinated dibenzo-p-dioxins, dibenzofurans and dioxin-like polychlorinated biphenyls around a steel plant area, northeast China.
abstract: Air monitoring of polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), and dioxin-like polychlorinated biphenyls (PCBs) was carried out in June 2008 and January 2009 to investigate the concentrations, profiles and estimating potential inhalation risks to the local residents around a steel plant area in northeast China. The air concentrations and WHO-TEQs of PCDD/Fs ranged 94-4944fgm(-3) (average 1352fgm(-3)) and 3-247fgm(-3) (average 81fgm(-3)), respectively. The WHO-TEQ concentrations of dioxin-like PCBs ranged 1-18fgm(-3) (average 5fgm(-3)), contributing to 3.6-26% of the total TEQ. Higher PCDD/F concentrations were observed in the winter, whereas higher dioxin-like PCB concentrations were found in the summer. The seasonal trend can be related to the significant correlation between the concentrations of dioxins and the reciprocal of temperature (positive for PCDD/Fs, P<0.01; negative for dioxin-like PCBs, P=0.05). A significant positive correlation (P<0.0001) was found between the concentration of total suspended particulate (TSP) and PCDD/F concentrations, but not for PCB congeners. Although the steel plant sites showed higher dioxin levels than the residential and background areas, the PCDD/F levels in the atmosphere of the steel plant area was at a relatively low level. The results from this study provides further aid in evaluating the impact of steel plants as PCDD/Fs emission sources to the ambient air in China.
authors.affiliation: Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, China.
authors.forename: Yingming
authors.initials: Y
authors.lastname: Li
authors.forename: Pu
authors.initials: P
authors.lastname: Wang
authors.forename: Lei
authors.initials: L
authors.lastname: Ding
authors.forename: Xiaomin
authors.initials: X
authors.lastname: Li
authors.forename: Thanh
authors.initials: T
authors.lastname: Wang
authors.forename: Qinghua
authors.initials: Q
authors.lastname: Zhang
authors.forename: Hongbiao
authors.initials: H
authors.lastname: Yang
authors.forename: Guibin
authors.initials: G
authors.lastname: Jiang
authors.forename: Fusheng
authors.initials: F
authors.lastname: Wei
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D001272:Atmosphere / Q000737:chemistry; D001572:Benzofurans / Q000032:analysis*; D002681:China; D004784:Environmental Monitoring; D007220:Industrial Waste / Q000032:analysis*; D019570:Inhalation Exposure / Q000032:analysis; D011078:Polychlorinated Biphenyls / Q000032:analysis*; D000072317:Polychlorinated Dibenzodioxins / Q000031:analogs & derivatives* / Q000032:analysis; D018570:Risk Assessment; D012621:Seasons; D013232:Steel
chemical_list: D000393:Air Pollutants; D001572:Benzofurans; D007220:Industrial Waste; D000072317:Polychlorinated Dibenzodioxins; D013232:Steel; C023614:dibenzofuran; D011078:Polychlorinated Biphenyls