A facile catalyst-free synthesis of gem-dihydroperoxides with aqueous hydrogen peroxide.
gem-Dihydroperoxides were easily obtained from the corresponding carbonyl compounds in high yields through a catalyst-free method with aqueous H(2)O(2) (35%) in 1,2-dimethoxyethane at room temperature.
Tada
Norihiro
N
Gifu Pharmaceutical University, 5-6-1 Mitahora-higashi, Gifu 502-8585, Japan.
Cui
Lei
L
Okubo
Hiroaki
H
Miura
Tsuyoshi
T
Itoh
Akichika
A
D002384:Catalysis; D006861:Hydrogen Peroxide / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D013696:Temperature; D014867:Water / Q000737:chemistry*
D014867:Water; D006861:Hydrogen Peroxide