Pd-catalyzed oxidative cross-coupling of N-tosylhydrazones with arylboronic acids.
The Pd-catalyzed reaction of N-tosylhydrazones and arylboronic acids provides olefin derivatives. This oxidative cross-coupling is suggested to proceed through a migratory insertion process of a Pd carbene intermediate.
Zhao
Xia
X
Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.
Jing
Jing
J
Lu
Kui
K
Zhang
Yan
Y
Wang
Jianbo
J
D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D006835:Hydrazones / Q000737:chemistry*; D007700:Kinetics; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*
D001897:Boronic Acids; D006835:Hydrazones; D010165:Palladium