Spin crossover in a heptanuclear mixed-valence iron complex.
The complex [Fe(II){(CN)Fe(III)L(5)}(6)]Cl(2) consists of a mixed-valence heptanuclear cyanide-bridged unit formed of a Schiff-base pentadentate ligand L(5) and it shows a spin crossover of the peripheral Fe(III) centres.
Boca
Roman
R
Institute of Inorganic Chemistry, Slovak Technical University (FCHPT), SK-812 37, Bratislava, Slovakia. roman.boca@stuba.sk
Salitros
Ivan
I
Kozísek
Jozef
J
Linares
Jorge
J
Moncol
Ján
J
Renz
Franz
F