meso-Pyrimidinyl-substituted A2B- and A3-corroles.
A variety of meso-pyrimidinyl-substituted A(2)B- and A(3)-corroles (A = 4,6-dichloropyrimidin-5-yl) have been synthesized by careful optimization of the macrocyclization conditions. meso-Pyrimidinylcorroles offer the distinct advantage of an unprecedented broad scope of functionalization options. Highly sterically encumbered triarylcorroles were readily prepared via efficient nucleophilic aromatic substitution and Suzuki cross-coupling procedures.
Ngo
Thien H
TH
Molecular Design and Synthesis, Department of Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200F, B-3001 Leuven, Belgium.
Nastasi
Francesco
F
Puntoriero
Fausto
F
Campagna
Sebastiano
S
Dehaen
Wim
W
Maes
Wouter
W