Self-assembly of enantiopure domains: the case of indigo on Cu(111).
The adsorption of indigo molecules on Cu(111) was investigated by low temperature (5 K) scanning tunneling microscopy from the isolated single molecule regime to one monolayer. Structural optimization and image calculations demonstrate that the molecules are in a physisorbed state. Because of the reduced symmetry at the surface, single molecules acquire a chiral character upon adsorption leading to a two-dimensional (2D) chirality. They adopt two adsorption configurations, related by a mirror symmetry of the substrate, each with a distinct molecular orientation. Consequently, the 2D chirality is expressed by the orientation of the molecule. For higher coverage, molecules self-assemble by hydrogen bonding in nearly homochiral molecular chains, whose orientation is determined by the orientation taken by the isolated molecules. When the coverage approaches one monolayer, these chains pack into domains. Finally, the completion of the monolayer induces the expulsion of the molecules of the wrong chirality that are still in these domains, leading to perfect resolution in enantiopure domains.
Villagomez
C J
CJ
The NanoSciences Group, Centre d'élaboration de matériaux et d'études structurales (CEMES) CNRS and University of Toulouse III Paul Sabatier, 29 rue Jeanne-Marvig, BP 94347, F-31005 Toulouse Cedex 4, France.
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Goudeau
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Coudret
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Zambelli
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Gauthier
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