title: Total synthesis of (+)-chloriolide.
abstract: The first total synthesis of (+)-chloriolide, a 12-membered macrolide from Chloridium virescens (var. chlamydosporum), was accomplished in a longest linear sequence of 20 steps from commercial materials in 7% overall yield.
authors.affiliation: Department Chemie, Technische Universität München, Lichtenbergstr. 4, 85747 Garching, Germany.
authors.forename: Timm T
authors.initials: TT
authors.lastname: Haug
authors.forename: Stefan F
authors.initials: SF
authors.lastname: Kirsch
mesh_terms: D001203:Ascomycota / Q000737:chemistry*; D018942:Macrolides / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D018942:Macrolides; C510706:chloriolide