title: Cyclic sulfamidates as vehicles for the synthesis of poly- and diversely substituted benzosultams via unusual S(O)2-O bond cleavage.
abstract: 1,2-Cyclic sulfamidates undergo novel, efficient, and regiospecific intramolecular nucleophilic cleavage with aryllithiated species to provide an entry to poly-, diversely, and enantiopure N-substituted benzosultams.
authors.affiliation: Univ Lille Nord de France, F-59000 Lille, France.
authors.forename: Magali
authors.initials: M
authors.lastname: Lorion
authors.forename: Vangelis
authors.initials: V
authors.lastname: Agouridas
authors.forename: Axel
authors.initials: A
authors.lastname: Couture
authors.forename: Eric
authors.initials: E
authors.lastname: Deniau
authors.forename: Pierre
authors.initials: P
authors.lastname: Grandclaudon
mesh_terms: D003500:Cyclization; D015394:Molecular Structure; D010100:Oxygen / Q000737:chemistry*; D013237:Stereoisomerism; D013449:Sulfonamides / Q000138:chemical synthesis* / Q000737:chemistry*; D013458:Sulfur Dioxide / Q000737:chemistry*
chemical_list: D013449:Sulfonamides; D013458:Sulfur Dioxide; D010100:Oxygen