Gold(I) derived thiosemicarbazone complexes with rare halogen-halogen interaction-reduction of [Au(damp-C1,N)Cl2].
An attempt to prepare gold(III) complexes of thiosemicarbazones with the starting material gold(III) [Au(damp-C(1),N)Cl(2)] led instead to gold(I) complexes with a rare Cl...Cl interaction.
Khanye
Setshaba D
SD
Department of Chemistry, University of Cape Town, Rondebosch 7701, Cape Town, South Africa.
Báthori
Nikoletta B
NB
Smith
Gregory S
GS
Chibale
Kelly
K
D018360:Crystallography, X-Ray; D006046:Gold / Q000737:chemistry*; D017612:Gold Compounds / Q000737:chemistry*; D006219:Halogens / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D013882:Thiosemicarbazones / Q000737:chemistry*
D017612:Gold Compounds; D006219:Halogens; D009942:Organometallic Compounds; D013882:Thiosemicarbazones; D006046:Gold