Synthesis and reactions of hydroxobis(eta5-pentamethylcyclopenta-dienyl)(trifluoroethenyl)titanium(IV).
Hydrolysis of the trifluoroethenyl titanium complexes 1a and b yields the hydroxo complexes 2 which can be deprotonated forming the sodium salt of the anionic oxo complex 4. 4a is one of the rare examples of monomeric organometallic anionic oxo complexes.
Kickbusch
Rainer
R
Institut für Chemie und Biochemie-Anorganische Chemie, Freie Universität Berlin, Fabeckstr. 34-36, D-14195 Berlin, Germany.
Lentz
Dieter
D