title: A square-planar Ni(II) complex with an N2S2 donor set similar to the active centre of nickel-containing superoxide dismutase and its reaction with superoxide.
abstract: The structure around the metal centre of a Ni(II) complex with an N(2)S(2) square-planar geometry, 1, prepared as a model compound of the NiSOD active site was drastically changed upon addition of potassium superoxide (KO(2)).
authors.affiliation: Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan.
authors.forename: Daisuke
authors.initials: D
authors.lastname: Nakane
authors.forename: Shin-ich
authors.initials: SI
authors.lastname: Kuwasako
authors.forename: Michiharu
authors.initials: M
authors.lastname: Tsuge
authors.forename: Minoru
authors.initials: M
authors.lastname: Kubo
authors.forename: Yasuhiro
authors.initials: Y
authors.lastname: Funahashi
authors.forename: Tomohiro
authors.initials: T
authors.lastname: Ozawa
authors.forename: Takashi
authors.initials: T
authors.lastname: Ogura
authors.forename: Hideki
authors.initials: H
authors.lastname: Masuda
mesh_terms: D020134:Catalytic Domain; D004578:Electron Spin Resonance Spectroscopy; D008958:Models, Molecular; D009532:Nickel / Q000378:metabolism*; D013482:Superoxide Dismutase / Q000378:metabolism*; D013481:Superoxides / Q000378:metabolism*
chemical_list: D013481:Superoxides; D009532:Nickel; D013482:Superoxide Dismutase