A discrete quadruple-decker phthalocyanine.
The reaction of a double-decker phthalocyanine (Pc) complex, bis(phthalocyaninato)lutetium ([LuPc(2)](-)), with cadmium acetate at 400 degrees C for 30 min under argon provided the first example of a discrete quadruple-decker Pc complex, 1. The structure of 1 was unambiguously determined through the use of high-resolution mass spectrometry, elemental analysis, and NMR techniques such as (1)H-(1)H COSY, (13)C-(1)H COSY, and NOE experiments. The absorption and magnetic circular dichroism spectra of 1 resembled those of [LuPc(2)](-) and [Lu(2)Pc(3)] rather than those of the neutral double-decker species [LuPc(2)](0), since the formal charge on each Pc moiety is 2-. Electrochemical measurements exhibited a stacking effect based on the delocalization of the holes or electrons introduced by oxidation or reduction, respectively, over the entire complex.
Fukuda
Takamitsu
T
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan. tfukuda@chem.sci.osaka-u.ac.jp
Biyajima
Tsuneaki
T
Kobayashi
Nagao
N