Alpha-functionalization of non-activated aliphatic amines: ruthenium-catalyzed alkynylations and alkylations.
Novel catalytic alpha-functionalizations of non-activated aliphatic amines with silylated alkynes are reported. In the presence of the Shvo catalyst alkylations and alkynylations proceed highly selectively to the branched amines.
Jovel
Irina
I
Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany.
Prateeptongkum
Saisuree
S
Jackstell
Ralf
R
Vogl
Nadine
N
Weckbecker
Christoph
C
Beller
Matthias
M
D000478:Alkylation; D000480:Alkynes / Q000737:chemistry; D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D012428:Ruthenium / Q000737:chemistry*
D000480:Alkynes; D000588:Amines; D012428:Ruthenium