Concise synthesis of an antifeedant sesquiterpene against Locusta migratoria.
A concise synthesis of (1S*,3R*,6R*)-1-hydroxy-7(14),10-bisaboladien-4-one, an antifeedant against the locust Locusta migratoria isolated from the Japanese cedar Cryptomeria japonica, was achieved by starting from 4-hydroxy-2-cyclohexenone.
Matsui
Miki
M
Department of Agrobioscience, Graduate School of Agricultural Science, Kobe University, Nada-ku, Kobe, Japan.
Tashiro
Takuya
T
Sasaki
Mitsuru
M
Takikawa
Hirosato
H
D000818:Animals; D032485:Cryptomeria / Q000737:chemistry*; D003511:Cyclohexanols / Q000737:chemistry; D003512:Cyclohexanones / Q000737:chemistry; D048188:Locusta migratoria / Q000187:drug effects*; D000081222:Monocyclic Sesquiterpenes; D012717:Sesquiterpenes / Q000138:chemical synthesis* / Q000737:chemistry / Q000494:pharmacology; D013237:Stereoisomerism
C550424:1-hydroxy-7(14),10-bisaboladien-4-one; C529503:4-hydroxy-2-cyclohexenone; D003511:Cyclohexanols; D003512:Cyclohexanones; D000081222:Monocyclic Sesquiterpenes; D012717:Sesquiterpenes; C004497:bisabolol