Metal-dependent alternative activation of O-H and C-H bonds of methanol: on the formation and structure of "bare" [M,C,H3,O]+ complexes (M = Fe, Co, Ni) in the gas phase.
Structural aspects of the 'bare' [M(C,H(3),O)](+) complexes (M = Fe, Co, Ni), generated by electrospray ionization of aqueous methanolic solutions of MX(2) (X = Br, I), have been probed in the gas phase by a combination of labeling studies and collision-induced dissociation (CID) experiments.
Schlangen
Maria
M
Institut für Chemie, Technische Universität Berlin, Strasse des 17. Juni 115, 10623 Berlin, Germany. Maria.Schlangen@mail.chem.tu-berlin.de
Schwarz
Helmut
H