Successive catalytic reactions specific to Pd-based rotaxane complexes as a result of wheel translation along the axle.
Rotaxane-structure-specific Pd-catalyzed rearrangement of propargyl or allyl urethane groups to oxazolidinone moieties proceeded efficiently. The conversion took place successively by the translation of the wheel along the axle, thus providing a novel macrocyclic catalytic system.
Miyagawa
Norihito
N
Department of Organic and Polymeric Materials, Tokyo Institute of Technology, 2-12-1, O-okayama, Meguro-ku, Tokyo 152-8552, Japan.
Watanabe
Masahiro
M
Matsuyama
Takanori
T
Koyama
Yasuhito
Y
Moriuchi
Toshiyuki
T
Hirao
Toshikazu
T
Furusho
Yoshio
Y
Takata
Toshikazu
T