title: Characterization of particle number concentrations and PM2.5 in a school: influence of outdoor air pollution on indoor air.
abstract: OBJECTIVE
  The impact of air pollution on school children's health is currently one of the key foci of international and national agencies. Of particular concern are ultrafine particles which are emitted in large quantities, contain large concentrations of toxins and are deposited deeply in the respiratory tract.
  
  
  METHODS
  In this study, an intensive sampling campaign of indoor and outdoor airborne particulate matter was carried out in a primary school in February 2006 to investigate indoor and outdoor particle number (PN) and mass concentrations (PM(2.5)), and particle size distribution, and to evaluate the influence of outdoor air pollution on the indoor air.
  
  
  RESULTS
  For outdoor PN and PM(2.5), early morning and late afternoon peaks were observed on weekdays, which are consistent with traffic rush hours, indicating the predominant effect of vehicular emissions. However, the temporal variations of outdoor PM(2.5) and PN concentrations occasionally showed extremely high peaks, mainly due to human activities such as cigarette smoking and the operation of mower near the sampling site. The indoor PM(2.5) level was mainly affected by the outdoor PM(2.5) (r = 0.68, p < 0.01), whereas the indoor PN concentration had some association with outdoor PN values (r = 0.66, p < 0.01) even though the indoor PN concentration was occasionally influenced by indoor sources, such as cooking, cleaning and floor polishing activities. Correlation analysis indicated that the outdoor PM(2.5) was inversely correlated with the indoor to outdoor PM(2.5) ratio (I/O ratio; r = -0.49, p < 0.01), while the indoor PN had a weak correlation with the I/O ratio for PN (r = 0.34, p < 0.01).
  
  
  CONCLUSIONS
  The results showed that occupancy did not cause any major changes to the modal structure of particle number and size distribution, even though the I/O ratio was different for different size classes. The I/O curves had a maximum value for particles with diameters of 100-400 nm under both occupied and unoccupied scenarios, whereas no significant difference in I/O ratio for PM(2.5) was observed between occupied and unoccupied conditions. Inspection of the size-resolved I/O ratios in the preschool centre and the classroom suggested that the I/O ratio in the preschool centre was the highest for accumulation mode particles at 600 nm after school hours, whereas the average I/O ratios of both nucleation mode and accumulation mode particles in the classroom were much lower than those of Aitken mode particles.
  
  
  CONCLUSIONS
  The findings obtained in this study are useful for epidemiological studies to estimate the total personal exposure of children, and to develop appropriate control strategies for minimising the adverse health effects on school children.
authors.affiliation: International Laboratory for Air Quality and Health, Queensland University of Technology, 2 George Street, Brisbane, Q 4001, Australia.
authors.forename: Hai
authors.initials: H
authors.lastname: Guo
authors.forename: Lidia
authors.initials: L
authors.lastname: Morawska
authors.forename: Congrong
authors.initials: C
authors.lastname: He
authors.forename: Yanli L
authors.initials: YL
authors.lastname: Zhang
authors.forename: Godwin
authors.initials: G
authors.lastname: Ayoko
authors.forename: Min
authors.initials: M
authors.lastname: Cao
mesh_terms: D000392:Air Movements; D000393:Air Pollutants / Q000032:analysis*; D016902:Air Pollution, Indoor / Q000032:analysis*; D004784:Environmental Monitoring; D007700:Kinetics; D010316:Particle Size; D052638:Particulate Matter / Q000032:analysis*; D012574:Schools; D013995:Time
chemical_list: D000393:Air Pollutants; D052638:Particulate Matter