Trapping of atomic hydrogens in cage-shaped silsesquioxanes by electric discharge.
A simple and safe technique which is based on glow discharge is demonstrated for stable encapsulation of H atoms in cage-shaped silsesquioxanes at room temperature, leading to the encapsulation yield of ca. 10(-4) H atoms per molecule for 10-minute discharging, much faster than the conventional gamma-ray irradiation technique.
Harima
Yutaka
Y
Department of Applied Chemistry, Graduate School of Engineering, Hiroshima University, Higashi-Hiroshima 739-8527, Japan. harima@mls.ias.hiroshima-u.ac.jp
Komaguchi
Kenji
K
Oka
Kazuyuki
K
Maruoka
Takanori
T
Imae
Ichiro
I
Ooyama
Yousuke
Y