title: Alpha-functionalization of non-activated aliphatic amines: ruthenium-catalyzed alkynylations and alkylations.
abstract: Novel catalytic alpha-functionalizations of non-activated aliphatic amines with silylated alkynes are reported. In the presence of the Shvo catalyst alkylations and alkynylations proceed highly selectively to the branched amines.
authors.affiliation: Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany.
authors.forename: Irina
authors.initials: I
authors.lastname: Jovel
authors.forename: Saisuree
authors.initials: S
authors.lastname: Prateeptongkum
authors.forename: Ralf
authors.initials: R
authors.lastname: Jackstell
authors.forename: Nadine
authors.initials: N
authors.lastname: Vogl
authors.forename: Christoph
authors.initials: C
authors.lastname: Weckbecker
authors.forename: Matthias
authors.initials: M
authors.lastname: Beller
mesh_terms: D000478:Alkylation; D000480:Alkynes / Q000737:chemistry; D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D012428:Ruthenium / Q000737:chemistry*
chemical_list: D000480:Alkynes; D000588:Amines; D012428:Ruthenium