Wet air oxidation of epoxy acrylate monomer industrial wastewater.
Epoxy acrylate monomer industrial wastewater contained highly concentrated and toxic organic compounds. The wet air oxidation (WAO) and catalytic wet air oxidation (CWAO) were used to eliminate pollutants in order to examine the feasibility of the WAO/CWAO as a pre-treatment method for the industrial wastewater. The results showed that in the WAO 63% chemical oxygen demand (COD) and 41% total organic carbon (TOC) removals were achieved and biological oxygen demand (BOD(5))/COD ratio increased from 0.13 to 0.72 after 3h reaction at 250 degrees C, 3.5MPa and the initial concentration of 100g(COD)/L. Among homogenous catalysts (Cu(2+), Fe(2+), Fe(3+) and Mn(2+) salts), Cu(2+) salt exhibited better performance. CuO catalyst was used in the CWAO of the wastewater, COD and TOC conversion were 77 and 54%, and good biodegradability was achieved. The results proved that the CWAO was an effective pre-treatment method for the epoxy acrylate monomer industrial wastewater.
Yang
Shaoxia
S
National Engineering Laboratory for Biomass Power Generation Equipment, School of Renewable Energy, North China Electric Power University, Beijing 102206, China. sx-yang@mail.tsinghua.edu.cn
Liu
Zhengqian
Z
Huang
Xiaohui
X
Zhang
Beiping
B
D001559:Benzhydryl Compounds; D002384:Catalysis; D052918:Environmental Restoration and Remediation; D004853:Epoxy Resins / Q000737:chemistry*; D006813:Humidity; D006863:Hydrogen-Ion Concentration; D008506:Medical Waste / Q000032:analysis*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000032:analysis / Q000737:chemistry; D013696:Temperature; D014865:Waste Disposal, Fluid / Q000379:methods*; D018508:Water Purification; D000098826:Bisphenol A Compounds
D001559:Benzhydryl Compounds; D004853:Epoxy Resins; D008506:Medical Waste; D010100:Oxygen; C029420:bisphenol A epoxy resin diacrylate ester; D000098826:Bisphenol A Compounds