title: Metal-organic polyhedral frameworks: high h(2) adsorption capacities and neutron powder diffraction studies.
abstract: Neutron powder diffraction experiments on D(2)-loaded NOTT-112 reveal that the axial sites of exposed Cu(II) ions in the smallest cuboctahedral cages are the first, strongest binding sites for D(2) leading to an overall discrimination between the two types of exposed Cu(II) sites at the paddlewheel nodes. Thus, the Cu(II) centers within the cuboctahedral cage are the first sites of D(2) binding with a Cu-D(2) distance of 2.23(1) A.
authors.affiliation: School of Chemistry, University of Nottingham, University Park, NG7 2RD, UK.
authors.forename: Yong
authors.initials: Y
authors.lastname: Yan
authors.forename: Irvin
authors.initials: I
authors.lastname: Telepeni
authors.forename: Sihai
authors.initials: S
authors.lastname: Yang
authors.forename: Xiang
authors.initials: X
authors.lastname: Lin
authors.forename: Winfried
authors.initials: W
authors.lastname: Kockelmann
authors.forename: Anne
authors.initials: A
authors.lastname: Dailly
authors.forename: Alexander J
authors.initials: AJ
authors.lastname: Blake
authors.forename: William
authors.initials: W
authors.lastname: Lewis
authors.forename: Gavin S
authors.initials: GS
authors.lastname: Walker
authors.forename: David R
authors.initials: DR
authors.lastname: Allan
authors.forename: Sarah A
authors.initials: SA
authors.lastname: Barnett
authors.forename: Neil R
authors.initials: NR
authors.lastname: Champness
authors.forename: Martin
authors.initials: M
authors.lastname: Schröder