Zwitterionic dicopper helicates: anion encapsulation and binding studies.
The synthesis and spectroscopic studies of a dicopper(II) double helicate capable of binding anions is described. X-Ray crystallographic analysis of three anion variations of the complex have shown that the helicate is capable of accommodating anions with an approximate volume of 0.09 nm(3) and smaller. ESI-MS revealed that the supramolecular complexes retain the 2 : 2 ligand : metal cluster in solution. Spectrometric analysis has shown the complex is capable of binding anions in a 1 : 1 ratio of helicate to anion, in the order SO(4)(2-) > HPO(4)(2-) > ClO(4)(-) approximately BF(4)(-) approximately NO(3)(-). We demonstrate that coordination to the metal centre, H-bonding and electrostatic interactions all play a role in encapsulating the anions.
Wenzel
Marco
M
Institute of Fundamental Sciences, Massey University, Private Bag 11 222, Palmerston North, New Zealand.
Bruere
Sam R
SR
Knapp
Quintin W
QW
Tasker
Peter A
PA
Plieger
Paul G
PG