Eicosanuclear cluster [Cu(13)W(7)] of copper-octacyanotungstate bimetallic assembly: synthesis, structure, and magnetic properties.
Octacyanotungstate(V) reacts with Cu(NO(3))(2).2H(2)O and 1,4,7-trimethyl-1,4,7-triazacyclononane in methanol, resulting in an eicosanuclear cluster [Cu(13)W(7)], which shows a diamondoid shape with a Tolkowsky cut and bears intracluster ferromagnetic coupling.
Wang
Jun
J
State Key Lab of Coordination Chemistry and School of Chemistry and Chemical Engineering, Nanjing University, Hankou Road 22, Nanjing 210093, People's Republic of China.
Zhang
Zai-Chao
ZC
Wang
Hui-Sheng
HS
Kang
Ling-Chen
LC
Zhou
Hong-Bo
HB
Song
You
Y
You
Xiao-Zeng
XZ