Nanoscale homochiral C(3)-symmetric mixed-valence manganese cluster complexes with both ferromagnetic and ferroelectric properties.
Both ferromagnetic and ferroelectric properties were observed in two enantiomerically pure nanoscale manganese cluster complexes supported by chiral Schiff base ligands, each of which comprises a 22-nucleus mixed-valence manganese(II/III) supratetrahedral cluster cation and an equilateral-triangle trinuclear manganese(III) cluster anion with C(3) symmetry.
Liu
Cai-Ming
CM
Beijing National Laboratory for Molecular Sciences, Center for Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, PR China. cmliu@iccas.ac.cn
Xiong
Ren-Gen
RG
Zhang
De-Qing
DQ
Zhu
Dao-Ben
DB
D056831:Coordination Complexes / Q000737:chemistry*; D004563:Electrochemistry; D005290:Ferric Compounds / Q000737:chemistry*; D008280:Magnetics; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D036103:Nanotechnology; D013237:Stereoisomerism
D056831:Coordination Complexes; D005290:Ferric Compounds; C001215:ferrite; D008345:Manganese