Nickel, manganese, cobalt, and iron-catalyzed deprotonative arene dimerization.
A number of first-row transition metal salts catalyze deprotonative dimerization of acidic arenes. Under the atmosphere of oxygen, nickel, manganese, cobalt, and iron chlorides have been shown to dimerize five- and six-membered ring heterocycles as well as electron-poor arenes. Both tetramethylpiperidide and dicyclohexylamide bases can be employed; however, the former afford slightly higher yields.
Truong
Thanh
T
Department of Chemistry, University of Houston, Houston, Texas 77204-5003, USA.
Alvarado
Joseph
J
Tran
Ly Dieu
LD
Daugulis
Olafs
O
D002384:Catalysis; D002712:Chlorides / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D019281:Dimerization; D005290:Ferric Compounds / Q000737:chemistry*; D017895:Manganese Compounds / Q000737:chemistry*; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D011522:Protons; D013237:Stereoisomerism; D014230:Triazoles / Q000138:chemical synthesis* / Q000737:chemistry
D002712:Chlorides; D005290:Ferric Compounds; D017895:Manganese Compounds; D011522:Protons; D014230:Triazoles; D003035:Cobalt; C022838:nickel chloride; D009532:Nickel; C018021:cobaltous chloride; C025340:manganese chloride; C024555:ferric chloride