Brilliant reversible luminescent mechanochromism of silver(I) complexes containing o-bis(diphenylphosphino)benzene and phosphinesulfide.
The Ag(I) complex with o-bis(diphenylphosphino)benzene shows reversible interconversion between blue-emitting (1b) and green-emitting (1g) materials on grinding and heating; comparison of the structure of 1b with another green-emitting crystals (2) having the same formula suggests the chromism results from intermolecular interactions between adjacent phenylene rings.
Tsukuda
Toshiaki
T
Seikei University, Department of Materials and Life Science, 3-3-1 Kichijoji-Kitamachi, Musashino, 1808633, Tokyo, Japan. tsukuda@st.seikei.ac.jp
Kawase
Marina
M
Dairiki
Ayumi
A
Matsumoto
Kenji
K
Tsubomura
Taro
T