title: Reversible gating controlled by enzymes at nanostructured interface.
abstract: A nanostructured biocatalytic interface reversibly gating electrochemical reactions upon chemical signals processed by immobilized enzymes was architectured. The chemical signals were converted to local interfacial pH changes causing restructuring of the stimuli-responsive polymer and switching ON-OFF the electrochemical reaction.
authors.affiliation: Department of Chemistry and Biomolecular Science, and NanoBio Laboratory (NABLAB), Clarkson University, Potsdam, NY 13699-5810, USA.
authors.forename: Vera
authors.initials: V
authors.lastname: Bocharova
authors.forename: Tsz Kin
authors.initials: TK
authors.lastname: Tam
authors.forename: Jan
authors.initials: J
authors.lastname: Halámek
authors.forename: Marcos
authors.initials: M
authors.lastname: Pita
authors.forename: Evgeny
authors.initials: E
authors.lastname: Katz
mesh_terms: D055162:Biocatalysis; D004563:Electrochemistry; D004798:Enzymes / Q000378:metabolism*; D006863:Hydrogen-Ion Concentration; D049329:Nanostructures
chemical_list: D004798:Enzymes