Multilevel supramolecular architectures self-assembled on metal surfaces.
We report the controllability of the complexity of surface-supported supramolecular assembly on metal surfaces. By introducing mismatch between the molecular packing and the surface atomic periodicity in the systems with comparable strength of intermolecular and molecule-substrate interactions, a homomolecular assembly exhibiting two-dimensional multilevel structures up to quaternary level was observed. In such a multiperiodicity modulated system, neither the intermolecular nor molecule-substrate interactions solely dominate the assembly, resulting in complicated multilevel structures. We further demonstrated that the multilevel assemblies can serve as templates for site-selective adsorption of guest molecules.
Zhong
Dingyong
D
Physikalisches Institut and Center for Nanotechnology (CeNTech), Universität Münster, Wilhelm-Klemm-Strasse 10, 48149 Münster, Germany.
Wedeking
Katrin
K
Blömker
Tobias
T
Erker
Gerhard
G
Fuchs
Harald
H
Chi
Lifeng
L
D000327:Adsorption; D008670:Metals / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D008958:Models, Molecular; D008968:Molecular Conformation; D013269:Stochastic Processes; D013499:Surface Properties
D008670:Metals