Spin capturing with nitrones: radical coupling reactions with concurrent introduction of mid-chain functionality.
Nitrones are demonstrated to efficiently mediate radical coupling reactions on the example of the conjugation of ATRP-made polymers, yielding macromolecules with distinct functional alkoxyamine centres in mid-chain locations of the chains.
Wong
Edgar H H
EHH
Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, Geb. 11.23, 76128 Karlsruhe, Germany. christopher.barner-kowollik@kit.edu tanja.junkers@monash.edu and Centre for Advanced Macromolecular Design (CAMD), School of Chemical Sciences and Engineering, The University of New South Wales, Sydney, NSW 2052, Australia.
Boyer
Cyrille
C
Centre for Advanced Macromolecular Design (CAMD), School of Chemical Sciences and Engineering, The University of New South Wales, Sydney, NSW 2052, Australia.
Stenzel
Martina H
MH
Centre for Advanced Macromolecular Design (CAMD), School of Chemical Sciences and Engineering, The University of New South Wales, Sydney, NSW 2052, Australia.
Barner-Kowollik
Christopher
C
Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, Geb. 11.23, 76128 Karlsruhe, Germany. christopher.barner-kowollik@kit.edu tanja.junkers@monash.edu.
Junkers
Tanja
T
Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstr. 18, Geb. 11.23, 76128 Karlsruhe, Germany. christopher.barner-kowollik@kit.edu tanja.junkers@monash.edu.