Characterization of the degradation performance of the sulfamethazine antibiotic by photo-Fenton process.
The present study provides results describing the degradation performance of the Sulfamethazine (SMT) antibiotic via photo-Fenton treatment. Experiments were carried out using 1 L solution samples of SMT (50 mg L(-1)) under different conditions. HPLC results reveal that both Fenton and photo-Fenton reactions were able to completely remove SMT antibiotic from the studied samples in less than 2 min treatment. Half-life times and kinetic parameters (assuming a pseudo-first-order kinetics at reaction initial stage, far from the equilibrium) for SMT degradation were determined and discussed. Hence, appropriate Fenton reagent loads are given to attain different targets proposed. TOC and HPLC data also revealed the presence of reaction intermediates; thus toxicity assays were performed regarding bacterial growth rate. The toxicity of an SMT solution was shown to increase during its degradation by means of photo-Fenton reactions.
Pérez-Moya
Montserrat
M
Departament d'Enginyeria Química, EUETIB, Universitat Politècnica de Catalunya, c/Comte d'Urgell 187, 08036 Barcelona, Spain. montserrat.perez-moya@upc.edu
Graells
Moisès
M
Castells
Gloria
G
Amigó
Jordi
J
Ortega
Esther
E
Buhigas
Guillem
G
Pérez
Leonardo M
LM
Mansilla
Héctor D
HD
D001419:Bacteria; D002851:Chromatography, High Pressure Liquid; D006207:Half-Life; D006861:Hydrogen Peroxide; D007501:Iron; D007700:Kinetics; D010777:Photochemistry; D013418:Sulfamethazine / Q000737:chemistry* / Q000633:toxicity*; D014874:Water Pollutants, Chemical / Q000737:chemistry* / Q000633:toxicity*
C045076:Fenton's reagent; D014874:Water Pollutants, Chemical; D013418:Sulfamethazine; D006861:Hydrogen Peroxide; D007501:Iron