A square-planar Ni(II) complex with an N2S2 donor set similar to the active centre of nickel-containing superoxide dismutase and its reaction with superoxide.
The structure around the metal centre of a Ni(II) complex with an N(2)S(2) square-planar geometry, 1, prepared as a model compound of the NiSOD active site was drastically changed upon addition of potassium superoxide (KO(2)).
Nakane
Daisuke
D
Department of Frontier Materials, Graduate School of Engineering, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya 466-8555, Japan.
Kuwasako
Shin-ich
SI
Tsuge
Michiharu
M
Kubo
Minoru
M
Funahashi
Yasuhiro
Y
Ozawa
Tomohiro
T
Ogura
Takashi
T
Masuda
Hideki
H
D020134:Catalytic Domain; D004578:Electron Spin Resonance Spectroscopy; D008958:Models, Molecular; D009532:Nickel / Q000378:metabolism*; D013482:Superoxide Dismutase / Q000378:metabolism*; D013481:Superoxides / Q000378:metabolism*
D013481:Superoxides; D009532:Nickel; D013482:Superoxide Dismutase