title: Black-light-induced radical/ionic hydroxymethylation of alkyl iodides with atmospheric CO in the presence of tetrabutylammonium borohydride.
abstract: Tin-free radical/ionic hydroxymethylation of secondary and tertiary alkyl iodides proceeded efficiently in the presence of tetrabutylammonium borohydride as the hydrogen source under atmospheric pressure of CO in conjunction with photoirradiation using black light. Two possible mechanisms were proposed, both of which involve hybrid radical/ionic processes.
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai 599-8531, Japan.
authors.forename: Shoji
authors.initials: S
authors.lastname: Kobayashi
authors.forename: Takuji
authors.initials: T
authors.lastname: Kawamoto
authors.forename: Shohei
authors.initials: S
authors.lastname: Uehara
authors.forename: Takahide
authors.initials: T
authors.lastname: Fukuyama
authors.forename: Ilhyong
authors.initials: I
authors.lastname: Ryu
mesh_terms: D000438:Alcohols / Q000138:chemical synthesis* / Q000737:chemistry; D001894:Borohydrides / Q000737:chemistry*; D002248:Carbon Monoxide / Q000737:chemistry*; D005609:Free Radicals / Q000737:chemistry; D006847:Hydrocarbons, Iodinated / Q000737:chemistry*; D008027:Light; D008745:Methylation; D015394:Molecular Structure; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D014001:Tin / Q000737:chemistry*
chemical_list: D000438:Alcohols; D001894:Borohydrides; D005609:Free Radicals; D006847:Hydrocarbons, Iodinated; D000644:Quaternary Ammonium Compounds; C550222:tetrabutylammonium borohydride; D014001:Tin; D002248:Carbon Monoxide