Complementary halogen and hydrogen bonding: sulfur...iodine interactions and thioamide ribbons.
Complementary halogen bonding and hydrogen bonding coexist in co-crystals of organoiodines with molecules containing the thioamide functionality. Thiourea.organoiodine co-crystals are shown to exhibit a remarkably reliable synthon with complementary N-H...S ribbons and S...I interactions.
Arman
Hadi D
HD
Department of Chemistry, Clemson University, Clemson, SC, USA.
Gieseking
Rebecca L
RL
Hanks
Timothy W
TW
Pennington
William T
WT
D018360:Crystallography, X-Ray; D006219:Halogens / Q000737:chemistry*; D006860:Hydrogen Bonding; D007455:Iodine / Q000737:chemistry*; D008968:Molecular Conformation; D013455:Sulfur / Q000737:chemistry*; D013854:Thioamides / Q000737:chemistry*
D006219:Halogens; D013854:Thioamides; D013455:Sulfur; D007455:Iodine