title: Electrochemical degradation of sulfonated amines on SI/BDD electrodes.
abstract: The electrochemical oxidation of aniline (AN) and ortanilic (OA), metanilic (MA) and sulfanilic (SA) acids was performed using as anode a boron-doped diamond (BDD) electrode. Tests were performed with model solutions of the different amines, with concentrations of 200mg L(-1), using as electrolyte 0.035 M Na2SO4, in a batch cell, with re-circulation, at different current densities (200 and 300 A m(-2)). Samples were collected at pre-selected intervals and absorbance measurements, Chemical Oxygen Demand (COD), Total Organic Carbon (TOC), Total Kjeldahl Nitrogen, Ammonia Nitrogen, Nitrates and Nitrites and HPLC analysis were performed. Results have shown a good elimination of the persistent pollutant, with COD and TOC removals always higher than, respectively: AN--91% and 90%; OA--75% and 82%; MA--88% and 87%; and SA--85% and 79%. The combustion efficiencies, calculated for the first hour of the runs, for the 300 A m(-2) assays, were the following: AN--0.93; OA--0.28; MA--0.82; and SA--0.83. For all the amines studied, after 6h degradation only oxalic and maleic acids were identified by HPLC.
authors.affiliation: Department of Chemistry, UMTP, University of Beira Interior, 6201001 Covilhã, Portugal.
authors.forename: V
authors.initials: V
authors.lastname: Santos
authors.forename: J
authors.initials: J
authors.lastname: Diogo
authors.forename: M J A
authors.initials: MJ
authors.lastname: Pacheco
authors.forename: L
authors.initials: L
authors.lastname: Ciríaco
authors.forename: A
authors.initials: A
authors.lastname: Morão
authors.forename: A
authors.initials: A
authors.lastname: Lopes
mesh_terms: D000588:Amines / Q000737:chemistry*; D000814:Aniline Compounds / Q000737:chemistry*; D002244:Carbon / Q000302:isolation & purification; D002274:Carcinogens, Environmental / Q000737:chemistry*; D002851:Chromatography, High Pressure Liquid; D004566:Electrodes; D004572:Electrolysis / Q000379:methods*; D009584:Nitrogen / Q000302:isolation & purification; D010100:Oxygen / Q000302:isolation & purification; D013053:Spectrophotometry; D013450:Sulfones / Q000737:chemistry*; D014865:Waste Disposal, Fluid / Q000379:methods
chemical_list: D000588:Amines; D000814:Aniline Compounds; D002274:Carcinogens, Environmental; D013450:Sulfones; D002244:Carbon; D009584:Nitrogen; D010100:Oxygen; C023650:aniline