Synthesis and characterization of a tin(II) bis(phosphinoyl)methanediide complex: a stannavinylidene derivative.
The reaction of [CH(2)(PPh(2)=NSiMe(3))(PPh(2)=S)] (1) with two equivalents of [Sn{N(SiMe(3))(2)}(2)] in refluxing toluene afforded novel tin(II) bis(phosphinoyl)methanediide complex 3. The structure of compound 3 has been determined by X-ray crystallography and DFT calculations. The topological analysis of the electron densities of compound 3 was performed.
Guo
Jiayi
J
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371 Singapore.
Lau
Kai-Chung
KC
Xi
Hong-Wei
HW
Lim
Kok Hwa
KH
So
Cheuk-Wai
CW
D056831:Coordination Complexes / Q000138:chemical synthesis* / Q000737:chemistry; D018360:Crystallography, X-Ray; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008968:Molecular Conformation; D009947:Organotin Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013450:Sulfones / Q000737:chemistry*; D014001:Tin / Q000737:chemistry*
D056831:Coordination Complexes; D009947:Organotin Compounds; D013450:Sulfones; C517722:bis(phenylsulfonyl)methane; C550037:tin(II) bis(phosphinoyl)methanediide; D014001:Tin; D008697:Methane