Alkynylcopper(I) polymers and their use in a mechanistic study of alkyne-azide click reactions.
Polymeric dinuclear alkynylcopper(I) complexes, for example phenylethynylcopper(I), can be prepared by a robust method involving the interaction of terminal alkynes with copper(II) salts in acetonitrile. The use of the ladder polymers provides heterogeneous catalysts for copper-catalyzed azide-alkyne cycloaddition (CuAAC) reactions and provides important mechanistic information.
Buckley
Benjamin R
BR
Department of Chemistry, Loughborough University, Loughborough, Leicestershire, UK LE11 3TU.
Dann
Sandra E
SE
Harris
Daniel P
DP
Heaney
Harry
H
Stubbs
Emma C
EC