Pd(OAc)(2) catalyzed olefination of highly electron-deficient perfluoroarenes.
An efficient, Pd(OAc)(2) catalyzed method for direct olefination of highly electron-deficient perfluoroarenes was developed. The reaction scope includes a series of activated and nonactivated alkenes in moderate to high yields with moderate to high regio- and stereoselectivities.
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China. xgzhang@mail.sioc.ac.cn
Xingang
X
Zhang
Shilu
S
Fan
Chun-Yang
CY
He
Xiaolong
X
Wan
Qiao-Qiao
QQ
Min
Jie
J
Yang
Zhong-Xing
ZX
Jiang
D000085:Acetates / Q000737:chemistry*; D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D004583:Electrons; D005464:Fluorobenzenes / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D013237:Stereoisomerism
D000085:Acetates; D000475:Alkenes; D005464:Fluorobenzenes; D009942:Organometallic Compounds; C516071:palladium(II) acetate