Analytical properties of p-[N,N-bis(2-chloroethyl)amino]benzaldehyde thiosemicarbazone: spectrophotometric determination of palladium(II) in alloys, catalysts, and complexes.
p-[N,N-bis(2-chloroethyl)amino]benzaldehyde thiosemicarbazone (CEABT) is proposed as a new, sensitive, and selective analytical reagent for the spectrophotometric determination of palladium(II). The reagent reacts with palladium(II) in the pH range 1-2 to form a yellow-colored complex. Beer's law is obeyed in the concentration range up to 2.64 μg cm(-3). The optimum concentration range for minimum photometric error as determined by Ringbom's plot method is 0.48-2.40 μg cm(-3). The yellowish Pd(II)-reagent complex shows a maximum absorbance at 395 nm, with molar absorptivity of 4.05×10(4) dm3 mol(-1) cm(-1) and Sandell's sensitivity of the complex from Beer's data, for D=0.001, is 0.0026 μg cm(-2). The composition of the Pd(II)-CEABT reagent complex is found to be 1:2 (M-L). The interference of various cations and anions in the method were studied. The proposed method was successfully used for the determination of Pd(II) in alloys, catalysts, complexes, water samples, and synthetic alloy mixtures with a fair degree of accuracy.
Department of Chemistry, Sathyabama University, Chennai, 600 119, India. jkarthik_chem@rediffmail.com
J
J
Karthikeyan
P
P
Parameshwara
A Nityananda
AN
Shetty
D000497:Alloys / Q000032:analysis*; D002384:Catalysis; D010165:Palladium / Q000032:analysis*; D013053:Spectrophotometry; D013882:Thiosemicarbazones / Q000032:analysis*
D000497:Alloys; D013882:Thiosemicarbazones; D010165:Palladium