Ionic-liquid-supported (ILS) catalysts for asymmetric organic synthesis.
The asymmetric synthesis of compounds that contain new C-C and C-O bonds remains one of the most important types of synthesis in organic chemistry. Over the years, many different types of catalysts have been designed and used effectively to carry out such transformations. Ionic-liquid-supported (ILS) catalysts represent a new and very effective class of catalysts that are used to facilitate the asymmetric synthesis of such compounds. There are many advantages to using ILS catalysts; they are nontoxic, environmentally benign, and, most important, recyclable. An overview of the design, synthesis, mode of action, and effectiveness of this class of catalysts is reported.
Ni
Bukuo
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Department of Chemistry, Texas A&M University-Commerce, Commerce, TX 75429-3011 (USA), Fax: (+1) 903-886-5165.
Headley
Allan D
AD
asymmetric synthesis; homogeneous catalysis; ionic liquids; organocatalysis; transition metals