Preparation of a chitosan-coated C(18)-functionalized magnetite nanoparticle sorbent for extraction of phthalate ester compounds from environmental water samples.
Novel superparamagnetic chitosan-coated C(18)-functionalized magnetite nanoparticles (MNPs) were successfully synthesized and applied as an effective sorbent for the preconcentration of several typical phthalate ester compounds from environmental water samples. The MNPs were 20 nm in diameter and had a high magnetic saturation value (52 emu g(-1)), which endowed the sorbent with a large surface area and the convenience of isolation from water samples. Phthalate esters could be extracted by the interior octadecyl groups through hydrophobic interaction. The hydrophilic porous chitosan polymer coating promoted the dispersion of MNPs in water samples, and improved the anti-interference ability of the sorbent without influencing the adsorption of analytes. The main factors affecting the adsorption of phthalate esters, including the pH of the solution, humic acid, sample loading volume, adsorption time, and desorption conditions, were investigated and optimized. Under the conditions selected (pH 11, adsorption time 20 min, elution with 10 mL of acetonitrile, and concentration to 0.5 mL), concentration factors of 1,000 were achieved by extracting 500 mL of several environmental water samples with 0.1 g of MNP sorbent. The method detection limits obtained for di-n-propyl phthalate, di-n-butyl phthalate, dicyclohexyl phthalate, and di-n-octyl phthalate were 12.3, 18.7, 36.4, and 15.6 ng L(-1), respectively. The recoveries of spiked samples ranged from 60 to 100%, with a low relative standard deviation (1-8%), which indicated good method precision.
State Key Laboratory of Environmental Chemistry and Ecotoxicology of Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, P. O. Box 2871, Beijing, 100085, China.
Xiao Le
XL
Zhang
Hong Yun
HY
Niu
Sheng Xiao
SX
Zhang
Ya Qi
YQ
Cai
D000327:Adsorption; D002244:Carbon / Q000737:chemistry*; D048271:Chitosan / Q000737:chemistry*; D004952:Esters / Q000302:isolation & purification; D052203:Ferrosoferric Oxide / Q000737:chemistry*; D005618:Fresh Water / Q000032:analysis; D057230:Limit of Detection; D053768:Metal Nanoparticles / Q000737:chemistry / Q000648:ultrastructure; D010795:Phthalic Acids / Q000302:isolation & purification*; D052616:Solid Phase Extraction / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
D004952:Esters; D010795:Phthalic Acids; D014874:Water Pollutants, Chemical; C032279:phthalic acid; D002244:Carbon; D048271:Chitosan; D052203:Ferrosoferric Oxide