Vibrational relaxation of NO-(v=1) in icosahedral (Ar)12NO- clusters.
Relaxation dynamics of NO(-)(v=1) in icosahedral (Ar)(12)NO(-) clusters are studied using classical dynamics and semiclassical procedures over the temperature range of 100-300 K. The minimum energy of the equilibrium configuration (-9875 cm(-1)) needed in the study is determined by varying the cluster size z in (Ar)(z)NO(-). NO(-)(v=1) is embedded in the cluster, which is filled with low frequency motions: 39 cm(-1) for the argon modes, 77 cm(-1) for the Arc...NO(-) substructure vibration, 109 cm(-1) for the librational frequency of restricted rotation, and 128 cm(-1) for oscillatory local translation. Dynamics calculations show that in the early time period (<20 ps), part of the vibrational energy rapidly transfers to rotation, but most energy transfers to Ar atoms on a long time scale (approximately 1 ns). The long time scale leads to the relaxation rates of 0.403 ns(-1) at 100 K and 0.453 ns(-1) at 300 K. The rates calculated using analytical formulations vary nearly linearly from 0.288 ns(-1) at 100 K to 0.832 ns(-1) at 300 K. Although the temperature dependence is stronger in the latter, both approaches give the rates on a nanosecond time scale. The principal energy transfer pathway is from NO(-) vibration to Ar vibrations via oscillatory local translation, while the NO(-) rotation is in a librational state. The energy transfer probabilities are two orders of magnitude larger than the vibration-to-translation probabilities in the gas phase collision Ar-NO(-)(v=1).
Department of Chemistry, University of Nevada, Reno, Nevada 89557, USA. shin@unr.edu
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Shin