Solvent-free sonochemical preparation of alpha-aminophosphonates catalyzed by 1-hexanesulphonic acid sodium salt.
1-Hexanesulphonic acid sodium salt was found to be an efficient catalyst for the green synthesis of alpha-aminophosphonates by the coupling of aldehydes/ketone, an amine and triethyl phosphite under ultrasound irradiation at ambient temperature for appropriate time to furnish the desired product in good to excellent yield under solvent-free condition. This catalyst provides clean conversion; greater selectivity and easy workup make this protocol practical and economically attractive.
Department of Chemistry, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad 431 004, India.
Kirti S
KS
Niralwad
Bapurao B
BB
Shingate
Murlidhar S
MS
Shingare
D017738:Alkanesulfonic Acids / Q000737:chemistry* / Q000528:radiation effects*; D002384:Catalysis / Q000528:radiation effects; D063065:Organophosphonates / Q000138:chemical synthesis* / Q000528:radiation effects*; D012492:Salts / Q000737:chemistry / Q000528:radiation effects; D012964:Sodium / Q000737:chemistry / Q000528:radiation effects; D012997:Solvents / Q000737:chemistry / Q000528:radiation effects; D013010:Sonication
D017738:Alkanesulfonic Acids; D063065:Organophosphonates; D012492:Salts; D012997:Solvents; C476608:1-hexanesulfonic acid; D012964:Sodium