title: Functionally relevant interplay between the Fe(4)S(4) cluster and CN(-) ligands in the active site of [FeFe]-hydrogenases.
authors.affiliation: Department of Environmental Science, University of Milano-Bicocca, Piazza della Scienza 1, 20126 Milan, Italy. maurizio.bruschi@unimib.it
authors.forename: Maurizio
authors.initials: M
authors.lastname: Bruschi
authors.forename: Claudio
authors.initials: C
authors.lastname: Greco
authors.forename: Luca
authors.initials: L
authors.lastname: Bertini
authors.forename: Piercarlo
authors.initials: P
authors.lastname: Fantucci
authors.forename: Ulf
authors.initials: U
authors.lastname: Ryde
authors.forename: Luca
authors.initials: L
authors.lastname: De Gioia
mesh_terms: D020134:Catalytic Domain; D005296:Ferrous Compounds / Q000737:chemistry*; D006864:Hydrogenase / Q000737:chemistry* / Q000378:metabolism; D007506:Iron-Sulfur Proteins / Q000737:chemistry* / Q000378:metabolism; D008024:Ligands; D009570:Nitriles / Q000737:chemistry*; D011789:Quantum Theory; D013438:Sulfhydryl Compounds / Q000737:chemistry*
chemical_list: D005296:Ferrous Compounds; D007506:Iron-Sulfur Proteins; D008024:Ligands; D009570:Nitriles; D013438:Sulfhydryl Compounds; C118830:iron hydrogenase; D006864:Hydrogenase