Studies of single aerosol particles containing malonic acid, glutaric acid, and their mixtures with sodium chloride. I. Hygroscopic growth.
We describe a newly constructed electrodynamic balance with which to measure the relative mass of single aerosol particles at varying relative humidity. Measurements of changing mass with respect to the relative humidity allow mass (m) growth factors (m(aqueous)/m(dry)) and diameter (d) growth factors (d(aqueous)/d(dry)) of the aerosol to be determined. Four aerosol types were investigated: malonic acid, glutaric acid, mixtures of malonic acid and sodium chloride, and mixtures of glutaric acid and sodium chloride. The mass growth factors of the malonic acid and glutaric acid aqueous phase aerosols, at 85% relative humidity, were 2.11 +/- 0.08 and 1.73 +/- 0.19, respectively. The mass growth factors of the mixed organic/inorganic aerosols are dependent upon the molar fraction of the individual components. Results are compared with previous laboratory determinations and theoretical predictions.
Pope
Francis D
FD
Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, CB2 1EW, UK. fdp21@cam.ac.uk
Dennis-Smither
Ben J
BJ
Griffiths
Paul T
PT
Clegg
Simon L
SL
Cox
R Anthony
RA
D000336:Aerosols / Q000737:chemistry*; D005977:Glutarates / Q000737:chemistry*; D008314:Malonates / Q000737:chemistry*; D010316:Particle Size; D012965:Sodium Chloride / Q000737:chemistry*; D017155:Wettability
D000336:Aerosols; D005977:Glutarates; D008314:Malonates; D012965:Sodium Chloride; C030290:malonic acid; C035736:glutaric acid