Metal nanoparticles via the atom-economy green approach.
Metal nanoparticles (NPs) of Cu (air-stable), Ag, and Au have been prepared using an atom-economy green approach. Simple mechanical stirring of solid mixtures (no solvent) of a metal salt and ammonia borane at 60 degrees C resulted in the formation of metal NPs. In this reaction, ammonia borane is transformed into a BNH(x) polymer, which protects the NPs formed and halts their growth. This results in the formation of the BNH(x) polymer protected monodisperse NPs. Thus, ammonia borane used in these reactions plays a dual role (reducing agent and precursor for the stabilizing agent).
Kalidindi
Suresh Babu
SB
Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bangalore 560 012, India.
Sanyal
Udishnu
U
Jagirdar
Balaji R
BR
D003300:Copper / Q000737:chemistry*; D006046:Gold / Q000737:chemistry*; D055772:Green Chemistry Technology; D053768:Metal Nanoparticles / Q000737:chemistry*; D010316:Particle Size; D012834:Silver / Q000737:chemistry*; D013499:Surface Properties
D012834:Silver; D006046:Gold; D003300:Copper