title: Enantioselective construction of allylic phosphine oxides through substitution of Morita-Baylis-Hillman carbonates with phosphine oxides.
abstract: The asymmetric organocatalytic allylic substitution reaction of MBH carbonates with phosphine oxides has been developed. This organocatalytic approach constitutes an easy and efficient method for the direct preparation of allylic phosphine oxides in high enantioselectivities.
authors.affiliation: State Key Laboratory of Applied Organic Chemistry and Institute of Biochemistry and Molecular Biology, Lanzhou University, Lanzhou, 730000, China.
authors.forename: Liang
authors.initials: L
authors.lastname: Hong
authors.forename: Wangsheng
authors.initials: W
authors.lastname: Sun
authors.forename: Chunxia
authors.initials: C
authors.lastname: Liu
authors.forename: Depeng
authors.initials: D
authors.lastname: Zhao
authors.forename: Rui
authors.initials: R
authors.lastname: Wang
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D002254:Carbonates / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D009930:Organic Chemicals / Q000737:chemistry; D010087:Oxides / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000498:Allyl Compounds; D002254:Carbonates; D009930:Organic Chemicals; D010087:Oxides; D010720:Phosphines; C044646:phosphine