Cationic silane sigma-complexes of ruthenium with relevance to catalysis.
Hydrosilylation of carbonyls catalyzed by 2 goes via intermediate formation of cationic silane sigma-complexes 4 which undergo nucleophilic abstraction of the silylium cation studied by DFT calculations.
Gutsulyak
Dmitry V
DV
Chemistry Department, Brock University, 500 Glenridge Avenue, St. Catharines, Ontario L2S 3A1, Canada.
Vyboishchikov
Sergei F
SF
Nikonov
Georgii I
GI