Biotreatment of acidic zinc- and copper-containing wastewater using ethanol-fed sulfidogenic anaerobic baffled reactor.
The treatment of acidic (pH 6.5-3), sulfate- (2-3 g/L), Zn- and Cu- (total metal 0-500 mg/L) containing wastewater was studied in a four-stage anaerobic baffled reactor (ABR) at 35 °C for 250 days. Ethanol was supplemented (COD/SO4(2-) = 0.67) as carbon and electron source for sulfate reducing bacteria. Sulfate reduction, COD oxidation and metal precipitation efficiencies were 70-92, 80-94 and >99%, respectively. The alkalinity produced from sulfidogenic ethanol oxidation increased the wastewater pH from 3.0 to 7.0-8.0. The electron flow from organic oxidation to sulfate averaged 87%. Decreasing feed pH to 3 and increasing total metal concentrations to 500 mg/L did not adversely affect the performance of ABR and sufficient alkalinity was produced to increase the effluent pH to neutral values. More than 99% of metals were precipitated in the form of metal-sulfides. Accumulation of precipitated metals in the first compartment allowed metal recovery without disturbing reactor performance seriously.
Sahinkaya
Erkan
E
Environmental Engineering Department, Harran University, Osmanbey Campus, 63000, Sanliurfa, Turkey. erkansahinkaya@yahoo.com
Yucesoy
Zeynep
Z
D000693:Anaerobiosis; D019149:Bioreactors; D003300:Copper / Q000737:chemistry*; D000431:Ethanol / Q000737:chemistry*; D013440:Sulfides / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000378:metabolism*; D015032:Zinc / Q000737:chemistry*
D013440:Sulfides; D014874:Water Pollutants, Chemical; D000431:Ethanol; D003300:Copper; D015032:Zinc