title: Strain-rate frequency superposition in large-amplitude oscillatory shear.
abstract: In a recent work, Wyss [Phys. Rev. Lett. 98, 238303 (2007)] have noted a property of "soft solids" under oscillatory shear, the so-called strain-rate frequency superposition. We extend this study to the case of soft solids under large-amplitude oscillatory shear (LAOS). We show results from LAOS studies in a monodisperse hydrogel suspension, an aqueous gel, and a biopolymer suspension and show that constant strain-rate frequency sweep measurements with soft solids can be superimposed onto master curves for higher harmonic moduli with the same shift factors as for the linear viscoelastic moduli. We show that the behavior of higher harmonic moduli at low frequencies in constant strain-rate frequency sweep measurements is similar to that at large strain amplitude in strain-amplitude sweep tests. We show surface plots of the harmonic moduli and the energy dissipation rate per unit volume in LAOS for soft solids and show experimentally that the energy dissipated per unit volume depends on the first harmonic loss modulus alone, in both the linear and the nonlinear viscoelastic regime.
authors.affiliation: Complex Fluids and Polymer Engineering Group, Polymer Science and Engineering Division, National Chemical Laboratory, Pune 411008, India. kalelkar@gmail.com
authors.forename: Chirag
authors.initials: C
authors.lastname: Kalelkar
authors.forename: Ashish
authors.initials: A
authors.lastname: Lele
authors.forename: Samruddhi
authors.initials: S
authors.lastname: Kamble
mesh_terms: D003102:Colloids / Q000737:chemistry*; D003198:Computer Simulation; D055119:Elastic Modulus; D008956:Models, Chemical; D009991:Oscillometry / Q000379:methods*; D033081:Shear Strength; D013314:Stress, Mechanical; D014783:Viscosity
chemical_list: D003102:Colloids