Characterization of the electrical and optical properties of viologen devices using chlorophyll a as an electron excimer.
This paper uses self-assembled monolayers (SAMs) on an Au(111) substrate to detect the unique characteristics of viologen molecules using scanning tunneling microscopy (STM), and reports the orientation and surface changes of molecules at the nano level in real-time. In particular, the rectification characteristics of the viologen molecule were observed at the molecular level using scanning tunneling spectroscopy (STS). After verifying the rectification characteristics of viologen molecules, an experiment was carried out to demonstrate the possibility of applying viologen to photodiodes and switching devices by forming a thin film of chlorophyll a on the viologen SAMs using the Langmuir-Blodgett (LB) method. This material mimics the photoinduced electron transport phenomenon in the early stage of photosynthesis in living plants. This study demonstrates the applicability of viologen to bioelectronic photodiodes and switching devices based on photo effects by observing the topography, current sensing, and current-voltage (I-V) characteristics using current-sensing atomic force microscopy (CS-AFM) by introducing light to the AFM-tip/chlorophyll a/viologen/Au(111) substrate structure.
Lee
Nam-Suk
NS
Department of Chemistry, Hanyang University, Seoul, Republic of Korea. hspirit7@gmail.com
Shin
Hoon-Kyu
HK
Kwon
Young-Soo
YS
Lee
Burm-Jong
BJ
D002734:Chlorophyll / Q000502:physiology*; D000077194:Chlorophyll A; D004563:Electrochemistry; D004579:Electron Transport; D006046:Gold / Q000737:chemistry; D018625:Microscopy, Atomic Force / Q000295:instrumentation / Q000379:methods*; D016252:Microscopy, Scanning Tunneling / Q000295:instrumentation / Q000379:methods*; D036103:Nanotechnology; D010788:Photosynthesis; D010860:Pigments, Biological / Q000502:physiology*; D013499:Surface Properties; D014755:Viologens / Q000737:chemistry / Q000378:metabolism*
D010860:Pigments, Biological; D014755:Viologens; D002734:Chlorophyll; D006046:Gold; D000077194:Chlorophyll A