Switching slow relaxation in a Mn(III)(3)Mn(IV) cluster: an example of grafting single-molecule magnets onto polyoxometalates.
Binding an established single-molecule magnet cluster of distorted cubane type [Mn(III)(3)Mn(IV)O(4)] to the lacunary site of an {alpha-P(2)W(15)} polyoxotungstate scaffold results in a surprising zero-field splitting inversion and the subsequent loss of magnetization bistability.
Fang
Xikui
X
Ames Laboratory, Iowa State University, Ames, IA 50011, USA. xfang@ameslab.gov
Speldrich
Manfred
M
Schilder
Helmut
H
Cao
Rui
R
O'Halloran
Kevin P
KP
Hill
Craig L
CL
Kögerler
Paul
P