An effective C-C double bond formation via Cu(I)-catalyzed dehydrogenation.
A dehydrogenation method using Cu(I) and either N,N-di-tert-butylthiadiaziridine 1,1-dioxide or N,N-di-tert-butyldiaziridinone is reported. The dehydrogenation allows a facile introduction of C-C double bond(s) into various carbo- and heterocycles such as oxazolines and thiazolines.
Ramirez
Thomas A
TA
Department of Chemistry, Colorado State University, Fort Collins, CO 80523.
Zhao
Baoguo
B
Shi
Yian
Y