title: Efficient near-infrared polymer and organic light-emitting diodes based on electrophosphorescence from (tetraphenyltetranaphtho[2,3]porphyrin)platinum(II).
abstract: The new metalloporphyrin Pt(tptnp), where tptnp = tetraphenyltetranaphtho[2,3]porphyrin, has been prepared and subjected to photophysical and electrooptical device studies. In degassed toluene solution at room temperature Pt(tptnp) features efficient phosphorescence emission with lambda(max) 883 nm with a quantum efficiency of 0.22. The complex has been used as the active phosphor in polymer and organic light-emitting diodes. Polymer light-emitting diodes based on a spin-coated emissive layer consisting of a blend of Pt(tptnp) doped in poly(9-vinylcarbazole) and 2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole exhibit near-IR emission with lambda(max) 896 nm, with a maximum external quantum efficiency (EQE) of 0.4% and a maximum radiant emittance of 100 muW/cm(2). Organic light-emitting diodes prepared via vapor deposition of all layers and that feature an optimized multilayer hole injection and electron blocking layer heterostructure with an emissive layer consisting of 4,4'-bis(carbazol-9-yl)biphenyl (CBP) doped with Pt(tptnp) exhibit a maximum EQE of 3.8% and a maximum radiant emittance of 1.8 mW/cm(2). The polymer and organic light-emitting diodes characterized in this study exhibit record high efficiency for devices that emit in the near-IR at lambda >800 nm.
authors.forename: Jonathan R
authors.initials: JR
authors.lastname: Sommer
authors.forename: Richard T
authors.initials: RT
authors.lastname: Farley
authors.forename: Kenneth R
authors.initials: KR
authors.lastname: Graham
authors.forename: Yixing
authors.initials: Y
authors.lastname: Yang
authors.forename: John R
authors.initials: JR
authors.lastname: Reynolds
authors.forename: Jiangeng
authors.initials: J
authors.lastname: Xue
authors.forename: Kirk S
authors.initials: KS
authors.lastname: Schanze
mesh_terms: D055664:Electrochemical Techniques; D007259:Infrared Rays; D049408:Luminescent Agents / Q000138:chemical synthesis / Q000737:chemistry*; D008163:Luminescent Measurements / Q000379:methods; D008665:Metalloporphyrins / Q000138:chemical synthesis / Q000737:chemistry*; D009944:Organoplatinum Compounds / Q000737:chemistry*
chemical_list: C549253:(tetraphenyltetranaphtho(2,3)porphyrin)platinum(II); D049408:Luminescent Agents; D008665:Metalloporphyrins; D009944:Organoplatinum Compounds