title: Radical amination with trimethylstannylated benzophenone imine.
abstract: Intermolecular radical amination reactions of various primary, secondary, and tertiary alkyl radicals by using trimethylstannylated benzophenone imine A as a novel radical acceptor to provide imines of type B are described. These imines are readily reduced with NaBH(4) to the corresponding secondary amines C. The novel radical amination can be combined with typical radical cyclization reactions.
authors.affiliation: Organisch-Chemisches Institut, Westfälische Wilhelms-Universität, Corrensstrasse 40, 48149 Münster, Germany.
authors.forename: Marie-Céline
authors.initials: MC
authors.lastname: Lamas
authors.forename: Santiago E
authors.initials: SE
authors.lastname: Vaillard
authors.forename: Birgit
authors.initials: B
authors.lastname: Wibbeling
authors.forename: Armido
authors.initials: A
authors.lastname: Studer
mesh_terms: D000586:Amination; D001577:Benzophenones / Q000737:chemistry*; D003500:Cyclization; D007097:Imines / Q000737:chemistry*; D008958:Models, Molecular; D017971:Tin Compounds / Q000737:chemistry*
chemical_list: D001577:Benzophenones; D007097:Imines; D017971:Tin Compounds