Rodlike fluorescent pi-conjugated 3,3'-bipyridazine ligand: optical, electronic, and complexation properties.
We report on the design and synthesis of a new quadrupolar pi-conjugated 3,3'-bipyridazine D-A-D ligand. Its electronic and optical properties were investigated. Besides high fluorescence and pronounced solvatochromism, it exhibits an inherent electroactivity exploited to build an organic green light emitting device. Moreover, the ability of this ligand to complex metallic centers (Cu(I), Ni(II), Pt(II), and Ir(III)) was also investigated to access different geometries and to tune their electronic and optical properties. These preliminary results open up the synthesis of heavy-metal complexes to obtain phosphorescent emitters.
Lincker
Frédéric
F
Université Pierre et Marie Curie, UMR CNRS 7610, Laboratoire de Chimie des Polymères 4, place Jussieu, Case Courrier 185 F, 75252 Paris CEDEX 05, France.
Kreher
David
D
Attias
André-Jean
AJ
Do
Jaekwon
J
Kim
Eunkyoung
E
Hapiot
Philippe
P
Lemaître
Noëlla
N
Geffroy
Bernard
B
Ulrich
Gilles
G
Ziessel
Raymond
R
D003198:Computer Simulation; D004583:Electrons; D005453:Fluorescence; D008024:Ligands; D008956:Models, Chemical; D015394:Molecular Structure; D055095:Optics and Photonics; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011724:Pyridazines / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; D011724:Pyridazines