Magnetostructural D correlation in nickel(II) complexes: reinvestigation of the zero-field splitting.
The magnetostructural D correlation interrelates the zero-field-splitting parameter D withdrawn from the magnetic data with the structural tetragonality parameter D(str). This correlation allows the quantitative prediction that D < 0 occurs for the tetragonally compressed nickel(II) complexes.
Titis
Ján
J
Department of Chemistry, University of SS. Cyril and Methodius, SK-917 01 Trnava, Slovakia. jan.titis@ucm.sk
Boca
Roman
R
D008280:Magnetics; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*
D009942:Organometallic Compounds; D009532:Nickel