Tuning functional sites and thermal stability of mixed-linker MOFs based on MIL-53(Al).
The MIXMOF concept has been applied to the metal-organic framework compound MIL-53(Al). The random incorporation of two different linker molecules (benzene-1,4-dicarboxylate and 2-aminobenzene-1,4-dicarboxylate) in the framework structure and its influence on thermal stability were proven using several complementary techniques (XRD, ATR-IR, MAS-NMR and TG).
Marx
Stefan
S
Department of Chemistry and Applied Biosciences, ETH Zurich, CH-8093 Zurich, Switzerland.
Kleist
Wolfgang
W
Huang
Jun
J
Maciejewski
Marek
M
Baiker
Alfons
A