Three-dimensional supramolecular architecture in imidazolium hydrogen 2,3,5,6-tetrafluoroterephthalate.
The asymmetric unit of the title salt formed between 2,3,5,6-tetrafluoroterephthalic acid (H(2)tfbdc) and imidazolium (ImH), C(3)H(5)N(2)(+).C(8)HF(4)O(4)(-), contains one Htfbdc(-) anion and one ImH(2)(+) cation, joined by a classical N-H...O hydrogen bond. The acid and base subunits are further linked by N-H...O and O-H...O hydrogen bonds into infinite two-dimensional layers with R(6)(5)(32) hydrogen-bond motifs. The resulting (4,4) network layers interpenetrate to produce an interlocked three-dimensional structure. The final three-dimensional supramolecular architecture is further stabilized by the linkages of two C-H...O interactions.
Yu
Li-Li
LL
Key Laboratory of Fine Petrochemical Technology, School of Chemistry and Chemical Engineering, Jiangsu Polytechnic University, Changzhou 213164, Jiangsu, People's Republic of China.
Cheng
Mei-Ling
ML
Liu
Qi
Q
Zhang
Zhi-Hui
ZH
Chen
Qun
Q
D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D007093:Imidazoles / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D010795:Phthalic Acids / Q000737:chemistry*; D012492:Salts / Q000737:chemistry*
D007093:Imidazoles; D010795:Phthalic Acids; D012492:Salts