Preparation of highly functionalized alkylzinc halides from alkyl bromides using Mg, ZnCl2 and LiCl.
Alkyl bromides bearing various functional groups are smoothly converted to functionalized alkylzinc reagents by the direct insertion of magnesium in the presence of LiCl and ZnCl(2).
Blümke
Tobias D
TD
Department Chemie, Ludwig-Maximilians-Universität, München, Butenandtstr. 5-13, Haus F, 81377 München, Germany.
Piller
Fabian M
FM
Knochel
Paul
P