Drift tube soft-landing for the production and characterization of materials: applied to Cu clusters.
We have recently developed a soft-landing (SL) instrument that is capable of depositing ions onto substrates for preparative and developmental research of new materials using a laser ablation source. This instrument was designed with a custom drift tube and a split-ring ion optic for the isolation of selected ions. The drift tube allows for the separation and thermalization of ions formed after laser ablation through collisions with an inert bath gas. These collisions allow the ions to be landed at energies below 1 eV onto substrates. The split-ring ion optic is capable of directing ions toward the detector or a landing substrate for selected components. Experiments will be shown ablating Cu using an Nd:YAG (1064 and 532 nm) for cluster formation and landing onto a muscovite (mica) surface. The laser ablation of Cu in 8 Torr of He gas gives a spectrum that contains multiple peaks corresponding to Cu(n), Cu(n)O(m) clusters, and their corresponding isomers. Atomic force microscopy and drift tube measurements were performed to characterize the performance characteristics of the instrument.
Davila
Stephen J
SJ
Department of Chemistry, University of North Texas, Denton, Texas 76201, USA.
Birdwell
David O
DO
Verbeck
Guido F
GF
D000465:Algorithms; D000538:Aluminum Silicates; D003300:Copper; D006371:Helium; D007477:Ions; D007834:Lasers; D008422:Materials Testing / Q000295:instrumentation* / Q000379:methods; D018625:Microscopy, Atomic Force; D055095:Optics and Photonics / Q000295:instrumentation* / Q000379:methods; D010100:Oxygen
D000538:Aluminum Silicates; D007477:Ions; C517971:muscovite; D006371:Helium; D003300:Copper; D010100:Oxygen