Geometry of slow structural fluctuations in a supercooled binary alloy.
The liquid structure of a glass-forming binary alloy is studied using molecular dynamics simulations. The analysis employs the geometrical approach of Frank and Kasper to establish that the supercooled liquid contains extended clusters characterized by the same short range order as the crystal. The steep increase in the heat capacity on cooling is directly coupled to the growing fluctuations of the Frank-Kasper clusters. The relaxation of particles in the clusters dominates the slow tail of the self-intermediate scattering function.
Pedersen
Ulf R
UR
DNRF Centre Glass and Time, IMFUFA, Department of Sciences, Roskilde University, Postbox 260, DK-4000 Roskilde, Denmark.
Schrøder
Thomas B
TB
Dyre
Jeppe C
JC
Harrowell
Peter
P