title: Tailoring magnetic nanoparticle for transformers application.
abstract: In this study photoacoustic spectroscopy was used to investigate the effect of dilution of an oil-based magnetic fluid sample on the magnetic nanoparticle surface-coating. Changes of the photoacoustic signal intensity on the band-L region (640 to 830 nm) upon dilution of the stock magnetic fluid sample were discussed in terms of molecular surface desorption. The model proposed here assumes that the driving force taking the molecules out from the nanoparticle surface into the bulk solvent is the gradient of osmotic pressure. This gradient of osmotic pressure is established between the nanoparticle surface and the bulk suspension. It is further assumed that the photoacoustic signal intensity (area under the photoacoustic spectra) scales linearly with the number of coating molecules (surface grafting) at the nanoparticle surface. This model picture provides a non-linear analytical description for the reduction of the surface grafting coefficient upon dilution, which was successfully-used to curve-fit the photoacoustic experimental data.
authors.affiliation: Universidade de Brasília, Instituto de Física, Núcleo de Física Aplicada, Brasília DF 70910-900, Brazil.
authors.forename: P C
authors.initials: PC
authors.lastname: Morais
authors.forename: A S
authors.initials: AS
authors.lastname: Silva
authors.forename: E S
authors.initials: ES
authors.lastname: Leite
authors.forename: V K
authors.initials: VK
authors.lastname: Garg
authors.forename: A C
authors.initials: AC
authors.lastname: Oliveira
authors.forename: W R
authors.initials: WR
authors.lastname: Viali
authors.forename: P P C
authors.initials: PP
authors.lastname: Sartoratto