Cs(9)[(gamma-PW(10)O(36))(2)Ru(4)O(5)(OH)(H(2)O)(4)], a new all-inorganic, soluble catalyst for the efficient visible-light-driven oxidation of water.
The tetraruthenium-substituted polyoxometalate Cs(9)[(gamma-PW(10)O(36))(2)Ru(4)O(5)(OH)(H(2)O)(4)] was synthesized and structurally, spectroscopically and electrochemically characterized; it was shown to be a catalyst for visible-light-induced water oxidation.
Besson
Claire
C
Institut Parisien de Chimie Moléculaire, UMR CNRS 7201, UPMC Univ. Paris 06, Case 42, 4 place Jussieu, 75005 Paris, France.
Huang
Zhuangqun
Z
Geletii
Yurii V
YV
Lense
Sheri
S
Hardcastle
Kenneth I
KI
Musaev
Djamaladdin G
DG
Lian
Tianquan
T
Proust
Anna
A
Hill
Craig L
CL