Dielectric and Piezoelectric Properties of PZT Composite Thick Films with Variable Solution to Powder Ratios.
The use of PZT films in sliver-mode high-frequency ultrasonic transducers applications requires thick, dense, and crack-free films with excellent piezoelectric and dielectric properties. In this work, PZT composite solutions were used to deposit PZT films >10 μm in thickness. It was found that the functional properties depend strongly on the mass ratio of PZT sol-gel solution to PZT powder in the composite solution. Both the remanent polarization, P(r), and transverse piezoelectric coefficient, e(31,) (f), increase with increasing proportion of the sol-gel solution in the precursor. Films prepared using a solution-to-powder mass ratio of 0.5 have a remanent polarization of 8 μC/cm(2), a dielectric constant of 450 (at 1 kHz), and e(31,) (f) = -2.8 C/m(2). Increasing the solution-to-powder mass ratio to 6, the films were found to have remanent polarizations as large as 37 μC/cm(2), a dielectric constant of 1250 (at 1 kHz) and e(31,) (f) = -5.8 C/m(2).
Wu
Dawei
D
Department of Biomedical Engineering, NIH Transducer Resource Center University of Southern California, Los Angeles, California 90089.
Zhou
Qifa
Q
Shung
Koping Kirk
KK
Bharadwaja
Srowthi N
SN
Zhang
Dongshe
D
Zheng
Haixing
H