title: Cationic silane sigma-complexes of ruthenium with relevance to catalysis.
abstract: Hydrosilylation of carbonyls catalyzed by 2 goes via intermediate formation of cationic silane sigma-complexes 4 which undergo nucleophilic abstraction of the silylium cation studied by DFT calculations.
authors.affiliation: Chemistry Department, Brock University, 500 Glenridge Avenue, St. Catharines, Ontario L2S 3A1, Canada.
authors.forename: Dmitry V
authors.initials: DV
authors.lastname: Gutsulyak
authors.forename: Sergei F
authors.initials: SF
authors.lastname: Vyboishchikov
authors.forename: Georgii I
authors.initials: GI
authors.lastname: Nikonov