Intrinsic electrical and thermal properties from single crystals of Na24Si136.
The observation of intrinsic structural, electrical, and thermal properties from measurements on single-crystal specimens of clathrate-II Na24Si136 is reported, revealing metallic conduction in agreement with electronic structure calculations. Low-temperature heat capacity measurements corroborate a substantial electronic density of states at the Fermi level, and reveal an Einstein-like mode that can be attributed to Na guest "rattling". The large thermal conductivity of Na24Si136, compared to literature data for other intermetallic clathrates, can be understood in terms of the predominant electronic contribution for the fully filled Na24Si136 composition.
Beekman
M
M
Department of Physics, University of South Florida, Tampa, Florida, USA.
Schnelle
W
W
Borrmann
H
H
Baitinger
M
M
Grin
Yu
Y
Nolas
G S
GS