title: Desulfitative cross-coupling of protecting group-free 2-thiouracil derivatives with organostannanes.
abstract: We here report a unique and efficient copper bromide mediated pallado-catalyzed coupling of protecting group-free 2-thiouracil derivatives with organostannanes. The nature of the copper appears to be crucial for successful cross coupling.
authors.affiliation: School of Pharmaceutical Science, Peking University, 38, Xueyuan Road, Haidian District, Beijing, China, 100191.
authors.forename: Qi
authors.initials: Q
authors.lastname: Sun
authors.forename: Franck
authors.initials: F
authors.lastname: Suzenet
authors.forename: Gérald
authors.initials: G
authors.lastname: Guillaumet
mesh_terms: D002384:Catalysis; D003300:Copper / Q000737:chemistry; D015394:Molecular Structure; D009947:Organotin Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry; D013237:Stereoisomerism; D013889:Thiouracil / Q000737:chemistry*
chemical_list: D009947:Organotin Compounds; D013889:Thiouracil; D010165:Palladium; D003300:Copper