Structural, microstructural, and residual stress investigations of plasma-sprayed hydroxyapatite on Ti-6Al-4 V.
Plasma-spray (PS) is a classical technique usually employed to cover orthopaedic titanium implant surfaces with hydroxyapatite (HA - Ca(10)(PO(4))(6)(OH)(2)). The objective of the current study is to investigate the structure and microstructure of HA plasma-spray 50 mum thick coating on titanium alloy (Ti-6Al-4 V) and residual stress due to processing in the substrate and in HA coating. The structure of the coatings was determined by high-energy synchrotron X-ray diffraction in energy dispersive (HESXRD), selected area electron diffraction (saed), Scanning Electron Microscopy (SEM), and Fourier transform infrared spectroscopy (FTIR). No impurity phases in the HA were identified by HESXRD to keep away from the decomposition of HA at high temperature. hcp phase of HA substrate was detected with slight amorphous background. FTIR spectrum of a HA powder shows a typical spectrum for HA material with the characteristic phosphate peaks for HA at wavenumbers of 1090, 1052, 963, 602, and 573 cm(-1) are present. The morphology of HA powder observed by SEM exhibits grains of ca. 0.1 mum well-adapted for cell proliferation. HA/Ti-6Al-4 V interface observed by cross-section scanning and transmission electron microscopy (TEM) presents microcracks. Residual stresses were analyzed by sin(2) Psi X-ray diffraction method on titanium substrates and HA coating. Although the Ti substrates are in a slightly tensile residual state, the coated ones show a compressive state.
Carradó
Adele
A
Institut de Physique et Chimie des Materiaux de Strasbourg, UMR 7504 UDS-CNRS, BP 43, 67034 Strasbourg Cedex 2, France. adele.carrado@ipcms.u-strasbg.fr
D000497:Alloys; D018786:Bone Substitutes / Q000737:chemistry*; D020099:Coated Materials, Biocompatible / Q000737:chemistry*; D017886:Durapatite / Q000737:chemistry*; D055119:Elastic Modulus; D006358:Hot Temperature; D008422:Materials Testing; D013314:Stress, Mechanical; D013499:Surface Properties; D014025:Titanium / Q000737:chemistry*
D000497:Alloys; D018786:Bone Substitutes; D020099:Coated Materials, Biocompatible; C031462:titanium alloy (TiAl6V4); D017886:Durapatite; D014025:Titanium