New heterometallic [Mn(III)(4)Ln(III)(4)] wheels incorporating formate ligands.
Two heteroctanuclear wheel complexes with an eight-membered saddle-like ring of [Mn(III)(4)Ln(III)(4)] (Ln = Dy, Gd), prepared by employing formates as key carboxylate bridges, exhibit antiferromagnetic interactions between Mn(III) and Ln(III) centers, and the wheel containing anisotropic Dy(III) ions shows SMM behaviour.
Li
Mengyuan
M
Institut für Anorganische Chemie der Universität Karlsruhe, Engessserstr. 15, Karlsruhe Institute for Technologie, D-76131 Karlsruhe, Germany.
Ako
Ayuk M
AM
Lan
Yanhua
Y
Wernsdorfer
Wolfgang
W
Buth
Gernot
G
Anson
Christopher E
CE
Powell
Annie K
AK
Wang
Zheming
Z
Gao
Song
S