title: The intramolecular amination of allenes.
abstract: Rhodium-bound nitrenoids are trapped by tethered allenes generating acyloxy-enamines, aminocyclopropanes, and methylene aziridines. The aminocyclopropanes undergo substitution of the acetoxy group by a variety of nucleophiles.
authors.affiliation: Department of Chemistry, Chemistry Research Laboratory, University of Oxford, Mansfield Road, Oxford, UKOX1 3TA.
authors.forename: George C
authors.initials: GC
authors.lastname: Feast
authors.forename: Lee W
authors.initials: LW
authors.lastname: Page
authors.forename: Jeremy
authors.initials: J
authors.lastname: Robertson
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D000586:Amination; D001388:Aziridines / Q000737:chemistry*; D003500:Cyclization; D008958:Models, Molecular; D015394:Molecular Structure; D011407:Propane / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D001388:Aziridines; D012238:Rhodium; D011407:Propane