title: Tailoring elastic properties of silica aerogels cross-linked with polystyrene.
abstract: The effect of incorporating an organic linking group, 1,6-bis(trimethoxysilyl)hexane (BTMSH), into the underlying silica structure of a styrene cross-linked silica aerogel is examined. Vinyltrimethoxysilane (VTMS) is used to provide a reactive site on the silica backbone for styrene polymerization. Replacement of up to 88 mol % of the silicon from tetramethoxyorthosilicate with silicon derived from BTMSH and VTMS during the making of silica gels improves the elastic behavior in some formulations of the cross-linked aerogels, as evidenced by measurement of the recovered length after compression of samples to 25% strain. This is especially true for some higher density formulations, which recover nearly 100% of their length after compression to 25% strain twice. The compressive modulus of the more elastic monoliths ranged from 0.2 to 3 MPa. Although some of these monoliths had greatly reduced surface areas, changing the solvent used to produce the gels from methanol to ethanol increased the surface area in one instance from 6 to 220 m(2)/g with little affect on the modulus, elastic recovery, porosity, or density.
authors.affiliation: Ohio Aerospace Institute, 22800 Cedar Point Road, Brookpark, OH 44142, USA. Baochau.n.nguyen@nasa.gov
authors.forename: Baochau N
authors.initials: BN
authors.lastname: Nguyen
authors.forename: Mary Ann B
authors.initials: MA
authors.lastname: Meador
authors.forename: Marissa E
authors.initials: ME
authors.lastname: Tousley
authors.forename: Brian
authors.initials: B
authors.lastname: Shonkwiler
authors.forename: Linda
authors.initials: L
authors.lastname: McCorkle
authors.forename: Daniel A
authors.initials: DA
authors.lastname: Scheiman
authors.forename: Anna
authors.initials: A
authors.lastname: Palczer