title: Switching slow relaxation in a Mn(III)(3)Mn(IV) cluster: an example of grafting single-molecule magnets onto polyoxometalates.
abstract: Binding an established single-molecule magnet cluster of distorted cubane type [Mn(III)(3)Mn(IV)O(4)] to the lacunary site of an {alpha-P(2)W(15)} polyoxotungstate scaffold results in a surprising zero-field splitting inversion and the subsequent loss of magnetization bistability.
authors.affiliation: Ames Laboratory, Iowa State University, Ames, IA 50011, USA. xfang@ameslab.gov
authors.forename: Xikui
authors.initials: X
authors.lastname: Fang
authors.forename: Manfred
authors.initials: M
authors.lastname: Speldrich
authors.forename: Helmut
authors.initials: H
authors.lastname: Schilder
authors.forename: Rui
authors.initials: R
authors.lastname: Cao
authors.forename: Kevin P
authors.initials: KP
authors.lastname: O'Halloran
authors.forename: Craig L
authors.initials: CL
authors.lastname: Hill
authors.forename: Paul
authors.initials: P
authors.lastname: Kögerler