Dithiodiolate ligands: group 4 complexes and application in lactide polymerization.
Dithiodiolate ligands were synthesized by reacting 1,2-ethanedithiol or 1,2-benzenedithiol with 2,2-bis(trifluoromethyl)oxirane, led selectively to mononuclear octahedral group 4 complexes of the type [{OSSO}M(OR)(2)], which features C(2) symmetry and fluxional behavior, and were highly active in the ring-opening polymerization of rac- and L-lactide.
Sergeeva
Ekaterina
E
School of Chemistry, Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Ramat Aviv, Tel Aviv 69978, Israel.
Kopilov
Jacob
J
Goldberg
Israel
I
Kol
Moshe
M
D018360:Crystallography, X-Ray; D004146:Dioxanes / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013237:Stereoisomerism; D013438:Sulfhydryl Compounds / Q000737:chemistry*
D004146:Dioxanes; D008024:Ligands; D009942:Organometallic Compounds; D013438:Sulfhydryl Compounds; C091880:dilactide