Towards peptide formation inside the channels of a new divinylaniline-bridged periodic mesoporous organosilica.
The first synthesis of a new highly ordered divinylaniline-bridged periodic mesoporous organosilica (PMO) with crystal-like pore walls and further chemical modification of the amino groups on the inner surface of the product by a peptide formation reaction with a chiral amino acid are reported.
Beretta
Mario
M
Department of Materials Science, University of Milano-Bicocca, Via R. Cozzi 53, 20125 Milan, Italy.
Morell
Jürgen
J
Sozzani
Piero
P
Fröba
Michael
M
D000409:Alanine / Q000031:analogs & derivatives / Q000737:chemistry*; D000596:Amino Acids / Q000737:chemistry; D000814:Aniline Compounds / Q000737:chemistry*; D010455:Peptides / Q000737:chemistry*; D016062:Porosity; D012822:Silicon Dioxide / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013237:Stereoisomerism; D014961:X-Ray Diffraction
D000596:Amino Acids; D000814:Aniline Compounds; D010455:Peptides; D012822:Silicon Dioxide; D000409:Alanine; C023650:aniline