title: Rare oxidation-state combinations and unusual structural motifs in hexanuclear Mn complexes using 2-pyridyloximate ligands.
abstract: The use of phenyl-2-pyridyl ketone oxime and di-2-pyridyl ketone oxime in Mn chemistry has led to hexanuclear clusters with unprecedented (Mn(II)(4)Mn(III)Mn(IV)) or extremely rare (Mn(II)Mn(III)(5) and Mn(II)(3)Mn(III)(3)) metal oxidation-state combinations and uncommon structural motifs.
authors.affiliation: Department of Chemistry, University of Patras, 265 04 Patras, Greece.
authors.forename: Constantinos C
authors.initials: CC
authors.lastname: Stoumpos
authors.forename: Ross
authors.initials: R
authors.lastname: Inglis
authors.forename: Olivier
authors.initials: O
authors.lastname: Roubeau
authors.forename: Harikleia
authors.initials: H
authors.lastname: Sartzi
authors.forename: Alexandros A
authors.initials: AA
authors.lastname: Kitos
authors.forename: Constantinos J
authors.initials: CJ
authors.lastname: Milios
authors.forename: Guillem
authors.initials: G
authors.lastname: Aromí
authors.forename: Anastasios J
authors.initials: AJ
authors.lastname: Tasiopoulos
authors.forename: Vasilios
authors.initials: V
authors.lastname: Nastopoulos
authors.forename: Euan K
authors.initials: EK
authors.lastname: Brechin
authors.forename: Spyros P
authors.initials: SP
authors.lastname: Perlepes