title: Selective gas adsorption in the flexible metal-organic frameworks Cu(BDTri)L (L=DMF, DEF).
abstract: Use of the ditopic ligand 1,4-benzenedi(1H-1,2,3-triazole) (H(2)BDTri) enabled isolation of two new three-dimensional metal-organic frameworks of formulae Cu(BDTri)L in which L=DMF (1) and diethylformamide (DEF; 2). These compounds have the same primary structure, featuring one-dimensional channels with the bridging DMF or DEF molecules pointing into the cavity. Upon exposure to solvent vapors, both display a reversible flexibility, as characterized by single-crystal to single-crystal phase transitions in 1. The O(2) adsorption isotherms for the compounds show a two-step adsorption behavior associated with a permanent microporosity and a pore-opening process. In the case of N(2) adsorption, only 1 exhibits a two-step adsorption isotherm, whereas 2 does not present any pore opening, demonstrating that design of a flexible framework cavity can control the pore opening and thereby possibly enhance O(2)/N(2) separation.
authors.affiliation: Department of Chemistry, University of California, Berkeley, Berkeley, CA 94720-1460, USA.
authors.forename: Aude
authors.initials: A
authors.lastname: Demessence
authors.forename: Jeffrey R
authors.initials: JR
authors.lastname: Long