Polymeric microspheres with N-methyl-D-glucamine ligands for boron removal from water solution by adsorption-membrane filtration process.
Polymeric microspheres with N-methyl-D-glucamine (NMDG) ligands have been tested in the adsorption-membrane filtration process for boron removal from aqueous solutions. The chelating resins were synthesized by reacting NMDG with the vinylbenzyl chloride-styrene-1,4-divinylbenzene (VBC/S/DVB) copolymer at the reflux temperature and in the microwave reactor. VBC/S/DVB spheres with a gel structure that contained 6 wt% DVB were obtained by membrane emulsification followed by suspension polymerization. By selecting the optimal emulsification and polymerization parameters, it was possible to obtain 25-microm-diameter particles with a narrow size distribution. Resins obtained by microwave modification showed the higher boron adsorption capacity.
Wolska
Joanna
J
Division of Polymer and Carbonaceous Materials, Wroclaw University of Technology, Wrocław, Poland. joanna.wolska@pwr.wroc.pl
Bryjak
Marek
M
Kabay
Nalan
N
D000327:Adsorption; D001895:Boron / Q000032:analysis / Q000737:chemistry*; D005374:Filtration; D008024:Ligands; D008536:Meglumine / Q000737:chemistry*; D008863:Microspheres; D011108:Polymers / Q000737:chemistry; D014867:Water / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000737:chemistry*; D018508:Water Purification / Q000379:methods*
D008024:Ligands; D011108:Polymers; D014874:Water Pollutants, Chemical; D014867:Water; D008536:Meglumine; D001895:Boron
J Am Diet Assoc. 1999 Mar;99(3):335-40
10076586
Sci Total Environ. 2003 Oct 1;314-316:255-69
14499536