Resorcin[4]arene cavitand with 1,3,2-benzodiazaborolyl walls as a fluorescence receptor for ammonium cations.
Resorcin[4]arene cavitand 1 with 1,3,2-benzodiazaborolyl walls was newly synthesized. It showed a large blue shift in the fluorescence spectra upon selective complexation with alkyltrimethylammonium salts in CH(2)Cl(2)-DMSO (9 : 1 v/v); this shift was detectable with the naked eye.
Kubo
Yuji
Y
Department of Applied Chemistry, Graduate School of Urban Environmental Sciences, Tokyo Metropolitan University, 1-1 Minami-ohsawa, Hachioji, Tokyo 192-0397, Japan. yujik@tmu.ac.jp
Tsuruzoe
Kazusa
K
Okuyama
Sachiko
S
Nishiyabu
Ryuhei
R
Fujihara
Takashi
T
D001896:Boron Compounds / Q000737:chemistry*; D047250:Calixarenes / Q000737:chemistry*; D002412:Cations / Q000032:analysis; D005456:Fluorescent Dyes / Q000737:chemistry*; D015394:Molecular Structure; D010649:Phenylalanine / Q000031:analogs & derivatives* / Q000737:chemistry; D000644:Quaternary Ammonium Compounds / Q000032:analysis*; D013237:Stereoisomerism
D001896:Boron Compounds; D002412:Cations; D005456:Fluorescent Dyes; D000644:Quaternary Ammonium Compounds; C466160:resorcinarene; D047250:Calixarenes; D010649:Phenylalanine