Pyridyldithiafulvenes as precursors of coordination-driven self-assembled redox active macrocycle.
A novel redox active macrocycle including two vinylogous tetrathiafulvalenes (TTFVs) and two molybdenum tetracarbonyl fragments has been synthezised thanks to the coordination-driven self-assembly of complementary angular derivatives. Pyridyl vinylogous TTFVs have been deliberately elaborated for that purpose, using the oxidative coupling of pyridyldithiafulvenes (DTF). Cyclic voltammetry, IR and NMR spectroscopies, and single-crystal X-ray crystallography of the target molecules have been investigated.
Gontier
Elodie
E
Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes 1, France.
Bellec
Nathalie
N
Brignou
Pierre
P
Gohier
Arnaud
A
Guerro
Michel
M
Roisnel
Thierry
T
Lorcy
Dominique
D
D018360:Crystallography, X-Ray; D003517:Cyclopentanes / Q000737:chemistry*; D047028:Macrocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D011725:Pyridines / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry*
D003517:Cyclopentanes; D047028:Macrocyclic Compounds; D009942:Organometallic Compounds; D011725:Pyridines; D013438:Sulfhydryl Compounds; C017332:fulvene; D008982:Molybdenum