title: Assembly of pi-conjugated phosphole azahelicene derivatives into chiral coordination complexes: an experimental and theoretical study.
abstract: Aza[n]helicene phosphole derivatives have been prepared from aza[n]helicene diynes by the Fagan-Nugent route. Their photophysical properties (UV/Vis absorption and emission behavior) have been evaluated. Their behavior as P,N chelates towards coordination to Pd(II) and Cu(I) has been investigated: metal-bis(aza[n]helicene phosphole) assemblies are formed by a highly stereoselective coordination process, as demonstrated by X-ray crystallography. An aza[6]helicene phosphole bearing an enantiopure helicene part has been obtained, which allows the preparation of enantiopure Pd(II) and Cu(I) complexes with original topologies and high molar rotation (MR) and circular dichroism (CD). The structure-property relationship established from the experimental data has been studied in detail by theoretical studies (TDDFT calculations of UV/Vis, CD, and MR). Aza[n]helicene phosphole derivatives show pi conjugation extended over the entire molecule, and its influence on the MR of aza[6]helicene phosphole 5 c has been demonstrated. Finally, it has been shown that the nature of the metal (coordination geometry and electronic interaction) can have a great impact on the amplitude of the chiroptical properties in metal-bis(aza[n]helicene phosphole) assemblies.
authors.affiliation: Sciences Chimiques de Rennes, UMR 6226 CNRS, Université de Rennes 1, Campus de Beaulieu, 35042 Rennes Cedex, France.
authors.forename: Sebastien
authors.initials: S
authors.lastname: Graule
authors.forename: Mark
authors.initials: M
authors.lastname: Rudolph
authors.forename: Wenting
authors.initials: W
authors.lastname: Shen
authors.forename: J A Gareth
authors.initials: JA
authors.lastname: Williams
authors.forename: Christophe
authors.initials: C
authors.lastname: Lescop
authors.forename: Jochen
authors.initials: J
authors.lastname: Autschbach
authors.forename: Jeanne
authors.initials: J
authors.lastname: Crassous
authors.forename: Régis
authors.initials: R
authors.lastname: Réau