Synthesis of 2-aza[6]helicene and attempts to synthesize 2,14-diaza[6]helicene utilizing metal-catalyzed cycloisomerization.
A modular synthetic approach leading to 2-aza[6]helicene is reported. It involves assembly of key hetero biphenylylnaphthalenes from functionalized building blocks and study of their metal catalyzed cycloisomerization.
Storch
Jan
J
Institute of Chemical Process Fundamentals of the AS CR, v.v.i., Rozvojová 135, CZ-16502 Prague 6, Czech Republic. storchj@icpf.cas.cz
Cermák
Jan
J
Karban
Jindrich
J
Císarová
Ivana
I
Sýkora
Jan
J