Femtosecond diffuse reflectance transient absorption for dye-sensitized solar cells under operational conditions: effect of electrolyte on electron injection.
By applying diffuse reflectance transient absorption spectroscopy to dye-sensitized solar cells under operational conditions, we were able to directly correlate interfacial electron injection kinetics from a Ru complex sensitizer to a TiO(2) nanocrystalline electrode with the incident photon to current efficiency values. It was revealed that ionic liquid electrolytes reduced the initial electron injection efficiency by suppression of the approximately 100 ps process.
Furube
Akihiro
A
National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. akihiro-furube@aist.go.jp
Wang
Zhong-Sheng
ZS
Sunahara
Kenji
K
Hara
Kohjiro
K
Katoh
Ryuzi
R
Tachiya
Masanori
M