title: Urea, glycolic acid, and glycerol in an organic residue produced by ultraviolet irradiation of interstellar/pre-cometary ice analogs.
abstract: More than 50 stable organic molecules have been detected in the interstellar medium (ISM), from ground-based and onboard-satellite astronomical observations, in the gas and solid phases. Some of these organics may be prebiotic compounds that were delivered to early Earth by comets and meteorites and may have triggered the first chemical reactions involved in the origin of life. Ultraviolet irradiation of ices simulating photoprocesses of cold solid matter in astrophysical environments have shown that photochemistry can lead to the formation of amino acids and related compounds. In this work, we experimentally searched for other organic molecules of prebiotic interest, namely, oxidized acid labile compounds. In a setup that simulates conditions relevant to the ISM and Solar System icy bodies such as comets, a condensed CH(3)OH:NH(3) = 1:1 ice mixture was UV irradiated at approximately 80 K. The molecular constituents of the nonvolatile organic residue that remained at room temperature were separated by capillary gas chromatography and identified by mass spectrometry. Urea, glycolic acid, and glycerol were detected in this residue, as well as hydroxyacetamide, glycerolic acid, and glycerol amide. These organics are interesting target molecules to be searched for in space. Finally, tentative mechanisms of formation for these compounds under interstellar/pre-cometary conditions are proposed.
authors.affiliation: Institut d'Astrophysique Spatiale, Université Paris-Sud, Orsay, France. michel.nuevo-1@nasa.gov
authors.forename: Michel
authors.initials: M
authors.lastname: Nuevo
authors.forename: Jan Hendrik
authors.initials: JH
authors.lastname: Bredehöft
authors.forename: Uwe J
authors.initials: UJ
authors.lastname: Meierhenrich
authors.forename: Louis
authors.initials: L
authors.lastname: d'Hendecourt
authors.forename: Wolfram H-P
authors.initials: WH
authors.lastname: Thiemann
mesh_terms: D000081:Acetamides / Q000737:chemistry; D000143:Acids / Q000737:chemistry; D000577:Amides / Q000737:chemistry; D018534:Earth, Planet; D018559:Exobiology / Q000295:instrumentation / Q000379:methods*; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods; D005990:Glycerol / Q000737:chemistry*; D006016:Glycolates / Q000737:chemistry*; D007053:Ice; D019110:Meteoroids; D008956:Models, Chemical; D000069497:Origin of Life; D013696:Temperature; D014466:Ultraviolet Rays; D014508:Urea / Q000737:chemistry*
chemical_list: D000081:Acetamides; D000143:Acids; D000577:Amides; D006016:Glycolates; D007053:Ice; C031149:glycolic acid; D014508:Urea; C030686:acetamide; D005990:Glycerol