Direct functionalization of polycyclic aromatics via radical perfluoroalkylation.
Direct functionalization of electron-deficient and electron-rich polycyclic aromatics via copper-mediated radical perfluoroalkylation was achieved in high yields.
Li
Yan
Y
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
Li
Cheng
C
Yue
Wan
W
Jiang
Wei
W
Kopecek
Ralf
R
Qu
Jianqiang
J
Wang
Zhaohui
Z
D000478:Alkylation; D003300:Copper / Q000737:chemistry; D018360:Crystallography, X-Ray; D004583:Electrons; D005466:Fluorocarbons / Q000737:chemistry*; D005609:Free Radicals / Q000737:chemistry; D008958:Models, Molecular; D011084:Polycyclic Aromatic Hydrocarbons / Q000737:chemistry*
D005466:Fluorocarbons; D005609:Free Radicals; D011084:Polycyclic Aromatic Hydrocarbons; D003300:Copper