title: Stereoselective synthesis of tetrasubstituted alkenylboronates via 1,1-organodiboronates.
abstract: The stereoselective synthesis of tetrasubstituted alkenylboronates was established via the lithiation/nucleophilic addition reaction of 1,1-organodiboronates to carbonyl compounds. The present approach enables the facile and practical synthesis of tetrasubstituted olefins, which are useful synthetic intermediates for further functionalizations.
authors.affiliation: Department of Chemistry and Biochemistry, School of Advanced Science and Engineering, Waseda University, Shinjuku, Tokyo 169-8555, Japan. kendo@aoni.waseda.jp
authors.forename: Kohei
authors.initials: K
authors.lastname: Endo
authors.forename: Munenao
authors.initials: M
authors.lastname: Hirokami
authors.forename: Takanori
authors.initials: T
authors.lastname: Shibata
mesh_terms: D001897:Boronic Acids / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D001897:Boronic Acids