title: Efficient methodology for alkylation of vinylnitroso compounds with carbon nucleophiles.
abstract: A diverse array of nitrosoalkenes derived from both acyclic and cyclic ketones, as well as aldehydes, via the Denmark protocol using alpha-chloro-O-TBS-oximes can be trapped efficiently in situ by a wide variety of potassium ester enolates to afford conjugate addition products in good yields.
authors.affiliation: Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802 USA.
authors.forename: Puhui
authors.initials: P
authors.lastname: Li
authors.forename: Max M
authors.initials: MM
authors.lastname: Majireck
authors.forename: Jason A
authors.initials: JA
authors.lastname: Witek
authors.forename: Steven M
authors.initials: SM
authors.lastname: Weinreb
references.citation: J Am Chem Soc. 2007 Aug 29;129(34):10342-3
references.pmid: 17676743