5-Hydroxy-2,2,6,6-tetramethyl-4-(2-methylprop-1-en-yl)cyclohex-4-ene-1,3-dione, a novel cheletropic trap for nitric oxide EPR detection.
The title compound behaves as an efficient cheletropic trap for both NO and NO(2) radicals in the presence of oxygen, yielding EPR observable nitroxide and alkoxynitroxide, respectively.
Lauricella
Robert
R
Laboratoire Chimie Provence, Equipe SACS, Aix-Marseille Université-CNRS-UMR 6264, 13397 Marseille Cedex 20, France.
Triquigneaux
Mathilde
M
André-Barrès
Christiane
C
Charles
Laurence
L
Tuccio
Béatrice
B
D003512:Cyclohexanones / Q000737:chemistry*; D004578:Electron Spin Resonance Spectroscopy; D009569:Nitric Oxide / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry
C551635:5-hydroxy-2,2,6,6-tetramethyl-4-(2-methylprop-1-enyl)cyclohex-4-ene-1,3-dione; D003512:Cyclohexanones; D009569:Nitric Oxide; D010100:Oxygen