title: Laser-induced fluorescence of rhodamine 6G cations in the gas phase: a lower bound to the lifetime of the first triplet state.
abstract: We have studied the gas-phase laser-induced fluorescence of an ensemble of buffer gas-cooled Rhodamine 6G cations (R6G(+)) stored in a quadrupole ion trap at 90 K. The fluorescence resulting from excitation with continuous-wave 488 nm radiation was observed to disappear almost completely on a time scale of seconds, dependent in detail on the excitation laser fluence. Such decay can be explained by the accumulation of R6G(+) in a dark triplet state. This in turn facilitates the first lifetime determination of the lowest triplet state of free R6G(+) by direct ground-state recovery measurements. A lower bound for the half-life was found to be approximately 2 s. Adding oxygen in a volume fraction of 1% to the buffer gas leads to efficient quenching of the triplet state and correspondingly to complete suppression of the fluorescence intensity decay. Different rare gases were applied as buffers for collisional cooling, but no significant changes in the fluorescence properties were found.
authors.affiliation: Institut für Nanotechnologie, Karlsruher Institut für Technologie, Postfach 3640, 76021 Karlsruhe, Germany.
authors.forename: Mattias
authors.initials: M
authors.lastname: Kordel
authors.forename: Detlef
authors.initials: D
authors.lastname: Schooss
authors.forename: Christian
authors.initials: C
authors.lastname: Neiss
authors.forename: Lars
authors.initials: L
authors.lastname: Walter
authors.forename: Manfred M
authors.initials: MM
authors.lastname: Kappes