Liquid/vapor coexistence and surface tension of the Sutherland fluid with a variable range of interaction: computer simulation and perturbation theory studies.
The liquid-vapor phase diagram and surface tension for the Sutherland fluids with a variable range of interaction have been determined by canonical Monte Carlo simulations and compared with the augmented van der Waals analytic theory. The theory, based on a short-range Yukawa reference, performs well for medium-range models but its accuracy deteriorates with the shortening range due to deteriorating accuracy of the underlined analytic mean spherical approximation solution for the reference Yukawa potential. The simulation results are also analyzed from the point of the extended principle of corresponding states and it is shown that the surface tension and also, to a certain degree of accuracy, the vapor-liquid coexistence curve satisfy the principle.
Melnyk
Roman
R
Institute for Condensed Matter Physics, National Academy of Sciences of Ukraine, Lviv 79011, Ukraine.
Orea
Pedro
P
Nezbeda
Ivo
I
Trokhymchuk
Andrij
A