Spontaneous chiral resolution of mer-[Co(II)(N,N,O-L3)2] enantiomers mediated by pi-pi interactions.
Six possible isomers of mer-[M(II)(N,N,O-L)(2)] complex were observed in the solid state, in which spontaneous resolution of S,S-Lambda and R,R-Delta enantiomers of mer-[Co(N,N,O-L3)(2)] was achieved via pi-pi interactions.
Wu
Jin-Ji
JJ
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
Cao
Man-Li
ML
Ye
Bao-Hui
BH
D002942:Circular Dichroism; D003035:Cobalt / Q000737:chemistry*; D004583:Electrons; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D009942:Organometallic Compounds; D003035:Cobalt