title: Crystal structure and chiral recognition of supramolecular complex composed of tris(1,2-diaminoethane)cobalt(iii) carbonate and alpha-cyclodextrin, [Co(en)(3)](2)(CO(3))(3).2(alpha-CDX).
abstract: The novel Co(III)-CDX supramolecular complex [Co(en)(3)](2)(CO(3))(3).2(alpha-CDX) (1) was prepared and the circular dichroism spectrum showed that complex 1 is 25% Lambda-rich (Lambda : Delta = 62.5 : 37.5). X-ray crystallography revealed the crystal structure of complex 1 and the reasonable chiral recognition mechanism of this system.
authors.affiliation: Institute for Higher Education Research and Practice, Osaka University, Toyonaka, Osaka 560-0043, Japan.
authors.forename: Natsuki
authors.initials: N
authors.lastname: Ohta
authors.forename: Akira
authors.initials: A
authors.lastname: Fuyuhiro
authors.forename: Kazuaki
authors.initials: K
authors.lastname: Yamanari