title: Alternative photoinduced release of HNO or NO from an acyl nitroso compound, depending on environmental polarity.
abstract: A hydrophilic hetero-Diels-Alder cycloadduct was synthesized as a novel photocontrollable donor of reactive nitrogen species. Production of either nitric oxide (NO) or nitroxyl (HNO) was photoinduced from this compound, depending on the environmental polarity.
authors.affiliation: Graduate School of Pharmaceutical Sciences, Nagoya City University, 3-1 Tanabe-dori, Mizuho-ku, Nagoya, Aichi 467-8603, Japan.
authors.forename: Kazuya
authors.initials: K
authors.lastname: Matsuo
authors.forename: Hidehiko
authors.initials: H
authors.lastname: Nakagawa
authors.forename: Yusuke
authors.initials: Y
authors.lastname: Adachi
authors.forename: Eri
authors.initials: E
authors.lastname: Kameda
authors.forename: Hiroki
authors.initials: H
authors.lastname: Tsumoto
authors.forename: Takayoshi
authors.initials: T
authors.lastname: Suzuki
authors.forename: Naoki
authors.initials: N
authors.lastname: Miyata
mesh_terms: D004578:Electron Spin Resonance Spectroscopy; D008401:Gas Chromatography-Mass Spectrometry; D009569:Nitric Oxide / Q000737:chemistry*; D009589:Nitrogen Oxides / Q000737:chemistry*; D009603:Nitroso Compounds / Q000737:chemistry*; D055668:Photochemical Processes; D026361:Reactive Nitrogen Species / Q000737:chemistry; D014466:Ultraviolet Rays
chemical_list: D009589:Nitrogen Oxides; D009603:Nitroso Compounds; D026361:Reactive Nitrogen Species; D009569:Nitric Oxide; C039900:nitroxyl