title: Studies on degradation of glyphosate by several oxidative chemical processes: ozonation, photolysis and heterogeneous photocatalysis.
abstract: Several different Advanced Oxidation Processes (AOPs) including ozonation at pH 6.5 and 10, photolysis and heterogeneous photocatalysis using TiO(2) as semiconductor and dissolved oxygen as electron acceptor were applied to study the degradation of glyphosate (N-phosphonomethyl glycine) in water. The degree of glyphosate degradation, the reactions kinetic and the formation of the major metabolite, aminomethyl phosphonic acid (AMPA), were evaluated. Ozonation at pH 10 resulted in the maximum mineralization of glyphosate. It was observed that under the experimental conditions used in this study the degradation of glyphosate followed the first-order kinetics. The half-life obtained for glyphosate degradation in the O(3)/pH 10 process was 1.8 minutes.
authors.affiliation: Laboratório de Resíduos e Contaminantes-Embrapa Meio Ambiente, Jaguariúna, SP, Brazil. massalin@cnpma.embrapa.br
authors.forename: Marcia R
authors.initials: MR
authors.lastname: Assalin
authors.forename: Sandra G
authors.initials: SG
authors.lastname: De Moraes
authors.forename: Sonia C N
authors.initials: SC
authors.lastname: Queiroz
authors.forename: Vera L
authors.initials: VL
authors.lastname: Ferracini
authors.forename: Nelson
authors.initials: N
authors.lastname: Duran
mesh_terms: D002384:Catalysis; D052918:Environmental Restoration and Remediation; D005998:Glycine / Q000031:analogs & derivatives* / Q000737:chemistry; D006540:Herbicides / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D010084:Oxidation-Reduction; D010126:Ozone / Q000737:chemistry; D055668:Photochemical Processes; D010782:Photolysis; D014025:Titanium / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D000097797:Glyphosate
chemical_list: D005998:Glycine; D006540:Herbicides; D010126:Ozone; D014025:Titanium; D014874:Water Pollutants, Chemical; D000097797:Glyphosate; C009495:titanium dioxide