Secondary orbital interactions in the propagation steps of lipid peroxidation.
Calculations on the propagation steps in the radical chain oxidation of lipids (H-atom abstraction, O(2) addition) show that secondary orbital interactions play an important role in the structure and energetics of the transition states of these reactions.
Hu
Di
D
Department of Chemistry, Queen's University, 90 Bader Crescent, Kingston, Ontario, Canada K7L 3N6.
Pratt
Derek A
DA
D005227:Fatty Acids / Q000737:chemistry; D005609:Free Radicals / Q000737:chemistry; D015227:Lipid Peroxidation; D010084:Oxidation-Reduction; D011789:Quantum Theory; D013261:Sterols / Q000737:chemistry
D005227:Fatty Acids; D005609:Free Radicals; D013261:Sterols