Measured physicochemical characteristics and biosolids-borne concentrations of the antimicrobial Triclocarban (TCC).
Triclocarban (TCC) is an active ingredient in antibacterial bar soaps, a common constituent of domestic wastewater, and the subject of recent criticism by consumer advocate groups and academic researchers alike. Activated sludge treatment readily removes TCC from the liquid waste stream and concentrates the antimicrobial in the solid fraction, which is often processed to produce biosolids intended for land application. Greater than half of the biosolids generated in the US are land-applied, resulting in a systematic release of biosolids-borne TCC into the terrestrial and, potentially, the aquatic environment. Multiple data gaps in the TCC literature (including basic physicochemical properties and biosolids concentrations) prevent an accurate, quantitative risk assessment of biosolids-borne TCC. We utilized the USEPA Office of Prevention, Pesticides, and Toxic Substances (OPPTS) harmonized test guidelines to measure TCC solubility and log K(ow) values as 0.045 mg L(-1) and 3.5, respectively. The measured physicochemical 2 properties differed from computer model predictions. The mean concentration of TCC in 23 biosolids representative of multiple sludge processing methods was 19+/-11 mg kg(-1).
Snyder
Elizabeth Hodges
EH
Soil and Water Science Department, University of Florida, Gainesville, FL 32611, USA. lizah@ufl.edu
O'Connor
George A
GA
McAvoy
Drew C
DC
D000891:Anti-Infective Agents, Local / Q000032:analysis* / Q000737:chemistry; D002224:Carbanilides / Q000032:analysis* / Q000737:chemistry; D007700:Kinetics; D012722:Sewage / Q000737:chemistry / Q000382:microbiology; D012995:Solubility; D014865:Waste Disposal, Fluid; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000737:chemistry
D000891:Anti-Infective Agents, Local; D002224:Carbanilides; D012722:Sewage; D014874:Water Pollutants, Chemical; C009540:triclocarban