title: Electrophilic reaction of Ag(III) N-confused porphyrin with alcohols.
abstract: Experimental studies demonstrated that alcohols and amines can undergo a CF(3)COOAg-catalyzed nucleophilic addition at the outer C=N position of Ag(III) NCPs, leading to C-3-alkoxylated Ag(III) NCPs, which supports the computational result that the C=N bond on the periphery of Ag(III) NCPs is partially isolated from the 18 pi-electron macrocyclic conjugation system and is the active electrophilic center.
authors.affiliation: Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road 200032, PR China.
authors.forename: Hua-Wei
authors.initials: HW
authors.lastname: Jiang
authors.forename: Fei
authors.initials: F
authors.lastname: Hao
authors.forename: Qing-Yun
authors.initials: QY
authors.lastname: Chen
authors.forename: Ji-Chang
authors.initials: JC
authors.lastname: Xiao
authors.forename: Shu-Bin
authors.initials: SB
authors.lastname: Liu
authors.forename: Yu-Cheng
authors.initials: YC
authors.lastname: Gu
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D000588:Amines / Q000737:chemistry*; D003198:Computer Simulation; D008665:Metalloporphyrins / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D012834:Silver / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000438:Alcohols; D000588:Amines; D008665:Metalloporphyrins; D012834:Silver