Innocence and noninnocence of the ligands in bis(pyrazine-2,3-dithiolate and -diselonate) d⁸-metal complexes. A theoretical and experimental study for the Cu(III), Au(III) and Ni(II) cases.
In this paper we present an experimental and theoretical study to investigate the electronic structures of [ML₂]⁻ (M(III) = Cu, L = pdt and pds, pyrazine-2,3-dithiolate and -diselonate; M(III) = Au, L = pds) with the aim of elucidating the nature of the bonding and to establish the innocent-noninnocent character of the ligand in these complexes. Calculations based on DFT methods have been performed to obtain geometry optimizations, harmonic frequencies, IR intensities and Raman scattering activities. The experimental vibrational spectra are accurately reproduced by the calculations, which show that CC, CN, and CX (X = S, Se) vibrations are extensively mixed with other modes, and thus unsuitable to work as vibrational markers. Geometry optimization performed at the DFT level provides geometrical parameters in good agreement with the available structural data. The energetic sequence and nature of the redox-active molecular orbitals help to elucidate the observed electrochemical behaviour. Accordingly, the quasi-reversible redox couple for the reduction processes exhibited by [ML₂]²⁻ (L = pdt and pds), that appears at negative values and depends both on the ligand and on the metal, is related to the LUMO which is a σ antibonding combination of the ligand orbitals (sulfur or selenium atoms) and the 3d(xy) (Cu) and 5d(xy) (Au) metal orbitals. The HOMO is a π-orbital with a b(2g) symmetry, predominantly ligand in character with a small contribution of the nd(xz) atomic orbitals in antibonding combination with chalcogen atom orbitals. The low energy of the metal d-orbitals compared to the ligand orbitals, due to the high effective nuclear charge of the metals, explains their small participation to this orbital. Thus in [ML₂]⁻ the metals approach the oxidation state 3+ and the ligand a dichalcogenolate description and thus a prevalent innocent character. However the same ligand shows a noninnocent character in complexes with a different d⁸ metal such as Ni(II) whose d-orbitals lie at higher energies and mix at a higher extent with the ligand orbitals in the HOMO.
Bruno
Giuseppe
G
Dipartimento di Chimica Inorganica, Chimica Analitica e Chimica Fisica, Università di Messina, Vill. S. Agata, Salita Sperone 31, I-98166, Messina, Italy. giuseppe.bruno@unime.it
Almeida
Manuel
M
Artizzu
Flavia
F
Dias
João C
JC
Mercuri
Maria Laura
ML
Pilia
Luca
L
Rovira
Concepció
C
Ribas
Xavi
X
Serpe
Angela
A
Deplano
Paola
P
D056831:Coordination Complexes / Q000737:chemistry*; D003300:Copper / Q000737:chemistry; D006046:Gold / Q000737:chemistry; D008024:Ligands; D008670:Metals / Q000737:chemistry*; D008958:Models, Molecular; D008962:Models, Theoretical; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry; D010084:Oxidation-Reduction; D011719:Pyrazines / Q000737:chemistry*; D013059:Spectrum Analysis, Raman
D056831:Coordination Complexes; D008024:Ligands; D008670:Metals; D011719:Pyrazines; D006046:Gold; D003300:Copper; D009532:Nickel