Rare oxidation-state combinations and unusual structural motifs in hexanuclear Mn complexes using 2-pyridyloximate ligands.
The use of phenyl-2-pyridyl ketone oxime and di-2-pyridyl ketone oxime in Mn chemistry has led to hexanuclear clusters with unprecedented (Mn(II)(4)Mn(III)Mn(IV)) or extremely rare (Mn(II)Mn(III)(5) and Mn(II)(3)Mn(III)(3)) metal oxidation-state combinations and uncommon structural motifs.
Stoumpos
Constantinos C
CC
Department of Chemistry, University of Patras, 265 04 Patras, Greece.
Inglis
Ross
R
Roubeau
Olivier
O
Sartzi
Harikleia
H
Kitos
Alexandros A
AA
Milios
Constantinos J
CJ
Aromí
Guillem
G
Tasiopoulos
Anastasios J
AJ
Nastopoulos
Vasilios
V
Brechin
Euan K
EK
Perlepes
Spyros P
SP