Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media.
Experimental studies and density functional theory (DFT) computations suggest that oxygen and proton reduction by decamethylferrocene (DMFc) in 1,2-dichloroethane involves protonated DMFc, DMFcH(+), as an active intermediate species, producing hydrogen peroxide and hydrogen in aerobic and anaerobic conditions, respectively.
Su
Bin
B
Laboratoire d'Electrochimie Physique et Analytique, Ecole Polytechnique Fédérale de Lausanne (EPFL), Station 6, CH-1015 Lausanne, Switzerland.
Hatay
Imren
I
Ge
Pei Yu
PY
Mendez
Manuel
M
Corminboeuf
Clemence
C
Samec
Zdenek
Z
Ersoz
Mustafa
M
Girault
Hubert H
HH