Unprecedented formation of an N-benzamidobisthiourea derivative and its role in the formation of a new CT state specific towards fluoride ion.
A novel N-benzamidobisthiourea derivative (1) was synthesized. Tuning of its emission from the locally excited (LE) state to the charge transfer (CT) state was observed specifically for fluoride ion.
Koteeswari
Ranganathan
R
National Centre for Ultrafast Processes, University of Madras, Taramani Campus, Chennai-600 113, India.
Ashokkumar
Pichandi
P
Ramakrishnan
Vayalakkavoor T
VT
Malar
E J Padma
EJ
Ramamurthy
Perumal
P
D003198:Computer Simulation; D005459:Fluorides / Q000737:chemistry*; D007477:Ions / Q000737:chemistry; D008956:Models, Chemical; D015394:Molecular Structure; D044367:Phase Transition; D011789:Quantum Theory; D013890:Thiourea / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry
D007477:Ions; C511234:N-benzamidothiourea; D013890:Thiourea; D005459:Fluorides