title: Characteristics of phosphate adsorption onto granulated coal ash in seawater.
abstract: The deterioration of sediments is a serious environmental problem. Controlling nutrient release fluxes from sediments is important to alleviating eutrophication and to reducing terrigenous nutrient loads. The purpose of this study was to evaluate the phosphate removal performance of granulated coal ash (GCA) from seawater, which is produced from coal thermal electric power generation. Batch experiments were carried out to investigate the removal kinetics of phosphate from seawater under both oxic and anoxic conditions. Phosphate was removed well from seawater under both oxic and anoxic conditions. The adsorption isotherm for phosphate revealed that GCA could remove phosphate effectively from seawater above a concentration of 1.7micromolL(-1). GCA can reduce the concentration of phosphate in seawater effectively under anoxic conditions where iron type adsorbents cannot be applied. Therefore, GCA could potentially be used to adsorb phosphate in the organically-enriched sediment, which generally occurs under highly reductive conditions.
authors.affiliation: Graduate School of Biosphere Science, Hiroshima University, 1-4-4 Kagamiyama, Higashi-Hiroshima 739-8528, Japan. st-asaoka@hiroshima-u.ac.jp
authors.forename: Satoshi
authors.initials: S
authors.lastname: Asaoka
authors.forename: Tamiji
authors.initials: T
authors.lastname: Yamamoto
mesh_terms: D000327:Adsorption; D002244:Carbon / Q000737:chemistry*; D060729:Coal Ash; D052918:Environmental Restoration and Remediation; D005068:Eutrophication; D007700:Kinetics; D052638:Particulate Matter / Q000737:chemistry*; D010710:Phosphates / Q000032:analysis / Q000737:chemistry*; D012623:Seawater / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: D060729:Coal Ash; D052638:Particulate Matter; D010710:Phosphates; D014874:Water Pollutants, Chemical; D002244:Carbon