title: Application potential of grapefruit peel as dye sorbent: kinetics, equilibrium and mechanism of crystal violet adsorption.
abstract: This study reports the sorption of crystal violet (CV) dye by grapefruit peel (GFP), which has application potential in the remediation of dye-contaminated wastewaters using a solid waste generated by the citrus fruit juice industry. Batch adsorption of CV was conducted to evaluate the effect of initial pH, contact time, temperature, initial dye concentration, GFP adsorbent dose, and removal of the adsorbate CV dye from aqueous solution to understand the mechanism of sorption involved. Sorption equilibrium reached rapidly with 96% CV removal in 60 min. Fit of the sorption experimental data was tested on the pseudo-first and pseudo-second-order kinetics mathematical equations, which was noted to follow the pseudo-second-order kinetics better, with coefficient of correlation > or = 0.992. The equilibrium process was well described by the Langmuir isotherm model, with maximum sorption capacity of 254.16 mg g(-1). The GFP was regenerated using 1 M NaOH, with up to 98.25% recovery of CV and could be reused as a dye sorbent in repeated cycles. GFP was also shown to be highly effective in removing CV from aqueous solution in continuous-flow fixed-bed column reactors. The study shows that GFP has the potential of application as an efficient sorbent for the removal of CV from aqueous solutions.
authors.affiliation: Environmental Biotechnology Group, Biotechnology and Food Research Centre, PCSIR Laboratories Complex, Ferozepur Road, Lahore 54600, Pakistan. asmadr@wol.net.pk
authors.forename: Asma
authors.initials: A
authors.lastname: Saeed
authors.forename: Mehwish
authors.initials: M
authors.lastname: Sharif
authors.forename: Muhammad
authors.initials: M
authors.lastname: Iqbal
mesh_terms: D000042:Absorption; D000465:Algorithms; D018533:Biomass; D032083:Citrus paradisi / Q000737:chemistry*; D004396:Coloring Agents / Q000302:isolation & purification*; D005638:Fruit / Q000737:chemistry; D005840:Gentian Violet / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D007220:Industrial Waste / Q000032:analysis; D007700:Kinetics; D015233:Models, Statistical; D012015:Reference Standards; D015203:Reproducibility of Results; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D013816:Thermodynamics; D014865:Waste Disposal, Fluid; D014874:Water Pollutants, Chemical / Q000302:isolation & purification
chemical_list: D004396:Coloring Agents; D007220:Industrial Waste; D014874:Water Pollutants, Chemical; D005840:Gentian Violet