title: (Eta6-arene) ruthenium(II) complexes and metallo-papain hybrid as Lewis acid catalysts of Diels-Alder reaction in water.
abstract: Covalent embedding of a (eta(6)-arene) ruthenium(II) complex into the protein papain gives rise to a metalloenzyme displaying a catalytic efficiency for a Lewis acid-mediated catalysed Diels-Alder reaction enhanced by two orders of magnitude in water.
authors.affiliation: Chimie ParisTech (Ecole Nationale Supérieure de Chimie de Paris), Laboratoire Charles Friedel, CNRS UMR 7223, 11 rue Pierre et Marie Curie, 75231, Paris cedex 05, France.
authors.forename: Barisa
authors.initials: B
authors.lastname: Talbi
authors.forename: Pierre
authors.initials: P
authors.lastname: Haquette
authors.forename: Annie
authors.initials: A
authors.lastname: Martel
authors.forename: Frédéric
authors.initials: F
authors.lastname: de Montigny
authors.forename: Céline
authors.initials: C
authors.lastname: Fosse
authors.forename: Stéphane
authors.initials: S
authors.lastname: Cordier
authors.forename: Thierry
authors.initials: T
authors.lastname: Roisnel
authors.forename: Gérard
authors.initials: G
authors.lastname: Jaouen
authors.forename: Michèle
authors.initials: M
authors.lastname: Salmain
mesh_terms: D000143:Acids / Q000737:chemistry*; D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D007700:Kinetics; D008968:Molecular Conformation; D010206:Papain / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D014867:Water / Q000737:chemistry*
chemical_list: D000143:Acids; D056831:Coordination Complexes; D014867:Water; D012428:Ruthenium; D010206:Papain