title: Synthesis of alkyl alkynyl ketones by Pd/light-induced three-component coupling reactions of iodoalkanes, CO, and 1-alkynes.
abstract: Under photoirradiation conditions using xenon light, in the presence of a catalytic amount of PdCl(2)(PPh(3))(2) with triethylamine as a base, a three-component coupling reaction of iodoalkanes, carbon monoxide, and terminal alkynes proceeded to give alkyl alkynyl ketones in good yields.
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan.
authors.forename: Akira
authors.initials: A
authors.lastname: Fusano
authors.forename: Takahide
authors.initials: T
authors.lastname: Fukuyama
authors.forename: Satoshi
authors.initials: S
authors.lastname: Nishitani
authors.forename: Takaya
authors.initials: T
authors.lastname: Inouye
authors.forename: Ilhyong
authors.initials: I
authors.lastname: Ryu
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D002248:Carbon Monoxide / Q000737:chemistry*; D006847:Hydrocarbons, Iodinated / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D008027:Light; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000480:Alkynes; D006847:Hydrocarbons, Iodinated; D007659:Ketones; D010165:Palladium; D002248:Carbon Monoxide