Azobenzene-based system for fluorimetric sensing of H(2)PO(4)(-) (Pi) that works as a molecular keypad lock.
A 'novel' and cost-effective 'on-off'-type monophosphate H(2)PO(4)(-) (Pi) chemosensor based on the mononuclear 2,2'-dihydroxyazobenzene (DHAB)-Zn(ii) complex was developed and a molecular keypad lock can be realized in the DHAB-based system by using Zn(ii) cations and Pi anions as inputs.
Wang
Jing
J
Department of Polymer Science and Engineering, Pusan National University, Busan, 609-735, Korea.
Ha
Chang-Sik
CS
D000838:Anions / Q000032:analysis*; D001391:Azo Compounds / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry; D005470:Fluorometry / Q000379:methods*; D010756:Phosphoric Acids / Q000032:analysis*; D015032:Zinc / Q000737:chemistry
D000838:Anions; D001391:Azo Compounds; D056831:Coordination Complexes; D010756:Phosphoric Acids; C030242:phosphoric acid; C009850:azobenzene; D015032:Zinc