Electrophilic reaction of Ag(III) N-confused porphyrin with alcohols.
Experimental studies demonstrated that alcohols and amines can undergo a CF(3)COOAg-catalyzed nucleophilic addition at the outer C=N position of Ag(III) NCPs, leading to C-3-alkoxylated Ag(III) NCPs, which supports the computational result that the C=N bond on the periphery of Ag(III) NCPs is partially isolated from the 18 pi-electron macrocyclic conjugation system and is the active electrophilic center.
Jiang
Hua-Wei
HW
Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road 200032, PR China.
Hao
Fei
F
Chen
Qing-Yun
QY
Xiao
Ji-Chang
JC
Liu
Shu-Bin
SB
Gu
Yu-Cheng
YC
D000438:Alcohols / Q000737:chemistry*; D000588:Amines / Q000737:chemistry*; D003198:Computer Simulation; D008665:Metalloporphyrins / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D012834:Silver / Q000737:chemistry*; D013237:Stereoisomerism
D000438:Alcohols; D000588:Amines; D008665:Metalloporphyrins; D012834:Silver