Design of thermally stable versions of the burgess reagent: stability and reactivity study.
Three new versions of the Burgess reagent were synthesized and their thermal stability investigated by NMR. The new reagents exhibited improved reactivity toward epoxides, diols, and vinyl oxiranes as compared with the original version.
Metcalf
Thomas A
TA
Department of Chemistry and Centre for Biotechnology, Brock University, 500 Glenridge Avenue, St. Catharines, Ontario L2S 3A1, Canada.
Simionescu
Razvan
R
Hudlicky
Tomas
T
D015394:Molecular Structure; D013237:Stereoisomerism; D013449:Sulfonamides / Q000138:chemical synthesis / Q000737:chemistry*; D013696:Temperature
D013449:Sulfonamides