title: Decoding stereocontrol during the photooxygenation of oxazolidinone-functionalized enecarbamates.
abstract: Systematically designed oxazolidinone-derived enecarbamates reveal that solvent and temperature effects on the stereoselectivity during photooxygenation are likely due to the conformational flexibility of the chiral phenethyl side chain (entropy factors); the extent of enantiomeric excess in the photoproduct is dictated by the alkene geometry.
authors.affiliation: Department of Chemistry, Columbia University, 3000 Broadway, New York, New York 10027, USA.
authors.forename: Marissa R
authors.initials: MR
authors.lastname: Solomon
authors.forename: J
authors.initials: J
authors.lastname: Sivaguru
authors.forename: Steffen
authors.initials: S
authors.lastname: Jockusch
authors.forename: Waldemar
authors.initials: W
authors.lastname: Adam
authors.forename: Nicholas J
authors.initials: NJ
authors.lastname: Turro