Room-temperature healing of a thermosetting polymer using the Diels-Alder reaction.
Self-healing materials are particularly desirable for load-bearing applications because they offer the potential for increased safety and material lifetimes. A furan-functionalized polymer network was designed that can heal via covalent bonding across the crack surface with the use of a healing agent consisting of a bismaleimide in solution. Average healing efficiencies of approximately 70% were observed. The healing ability of fiber-reinforced composite specimens was investigated with flexural, short beam shear, and double cantilever beam specimens. It was found that solvent amount and maleimide concentration play key roles in determining healing efficiency.
Peterson
Amy M
AM
Department of Chemical & Biological Engineering, Drexel University, Philadelphia, PA19104, USA.
Jensen
Robert E
RE
Palmese
Giuseppe R
GR
D032701:Biomimetics; D002152:Calorimetry, Differential Scanning / Q000379:methods; D002625:Chemistry, Organic / Q000379:methods*; D005898:Glass; D006358:Hot Temperature; D008422:Materials Testing; D008956:Models, Chemical; D011108:Polymers / Q000737:chemistry; D013499:Surface Properties; D013696:Temperature; D013718:Tensile Strength
D011108:Polymers