Single-crystal intermetallic M-Sn (M = Fe, Cu, Co, Ni) nanospheres as negative electrodes for lithium-ion batteries.
FeSn(2), Cu(6)Sn(5), CoSn(3), and Ni(3)Sn(4) single-crystalline nanospheres with a characteristic uniform particle size of approximately 40 nm have been synthesized via a modified polyol process, aiming at determining and understanding their intrinsic cycling performance as negative electrode materials for lithium-ion batteries. We find that, in this morphologically controlled condition, the reversible capacities follow FeSn(2) > Cu(6)Sn(5) approximately CoSn(3) > Ni(3)Sn(4), which is not directly decided by their theoretical capacities or lithium-driven volume changes. FeSn(2) exhibits the best electrochemical activity among these intermetallic nanospheres and an effective solid electrolyte interface, which explains its superior cycling performance. The small particle dimension also improves cycling stability and Li(+) diffusion.
Wang
Xiao-Liang
XL
Center for Functional Nanomaterials and Energy Sciences & Technology Department, Brookhaven National Laboratory, Upton, New York 11973, USA.
Han
Wei-Qiang
WQ
Chen
Jiajun
J
Graetz
Jason
J
D000838:Anions; D003460:Crystallization / Q000379:methods*; D011211:Electric Power Supplies; D004566:Electrodes; D004867:Equipment Design; D019544:Equipment Failure Analysis; D008094:Lithium / Q000737:chemistry*; D008670:Metals / Q000737:chemistry*; D054118:Nanospheres / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000295:instrumentation*
D000838:Anions; D008670:Metals; D008094:Lithium