Water hydrogen bond structure near highly charged interfaces is not like ice.
Imaginary chi(2) spectra of HOD at air/charged surfactant/aqueous interfaces highly resemble the IR spectrum of the bulk liquid HOD, showing no indication of the "ice-like" structure. Clearly, the hydrogen bond structures at highly charged interfaces are not like ice but very similar to the structure in the bulk.
Nihonyanagi
Satoshi
S
Molecular Spectroscopy Laboratory, Advanced Science Institute, RIKEN, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan.
Yamaguchi
Shoichi
S
Tahara
Tahei
T
D004583:Electrons; D006860:Hydrogen Bonding; D007053:Ice; D008958:Models, Molecular; D008968:Molecular Conformation; D012997:Solvents / Q000737:chemistry; D014867:Water / Q000737:chemistry*
D007053:Ice; D012997:Solvents; D014867:Water