title: Luminescent Gold Nanoparticles with Mixed Valence States Generated from Dissociation of Polymeric Au (I) Thiolates.
abstract: Dissociation process of glutathione-gold(I) polymers in aqueous solution resulted in the formation of a class of ~2 nm gold nanoparticles. Different from the same sized but NaBH(4) reduced gold nanoparticles, these nanoparticles exhibit strong luminescence but no surface plasmon absorption. Luminescence lifetimes of the nanoparticles were found strongly dependent on excitation wavelengths, and singlet and triplet excited states involving the emission were found degenerate in energy. X-ray photoelectron spectroscopic studies showed that nearly 40~50% gold atoms in the luminescent nanoparticles were in gold(I) state, which are responsible for the unique optical properties of the luminescent gold nanoparticles. These luminescent nanoparticles can be considered an intermediate state between luminescent gold(I) complexes and reduced nonluminescent gold nanoparticles.
authors.affiliation: Department of Chemistry, University of Texas at Dallas, Richardson, TX 75080.
authors.forename: Chen
authors.initials: C
authors.lastname: Zhou
authors.forename: Ce
authors.initials: C
authors.lastname: Sun
authors.forename: Mengxiao
authors.initials: M
authors.lastname: Yu
authors.forename: Yanping
authors.initials: Y
authors.lastname: Qin
authors.forename: Jinguo
authors.initials: J
authors.lastname: Wang
authors.forename: Moon
authors.initials: M
authors.lastname: Kim
authors.forename: Jie
authors.initials: J
authors.lastname: Zheng