title: Chelate-Modified Fenton Reaction for the Degradation of Trichloroethylene in Aqueous and Two-Phase Systems.
abstract: The primary objective of this research was to model and understand the chelate-modified Fenton reaction for the destruction of trichloroethylene (TCE) present in both the aqueous and organic (in the form of droplets) phases. The addition of a nontoxic chelate (L), such as citrate or gluconic acid, allows for operation at near-neutral pH and controlled release of Fe(II)/Fe(III). For the standard Fenton reaction at low pH in two-phase systems, an optimum H(2)O(2):Fe(II) molar ratio was found to be between 1:1 and 2:1. Experimentation proved the chelate-modified Fenton reaction effectively dechlorinated TCE in both the aqueous and organic phases at pH 6-7 using low H(2)O(2):Fe(II) molar ratios (4:1 to 8:1). Increasing the L:Fe ratio was found to decrease the rate of H(2)O(2) degradation in both Fe(II) and Fe(III) systems at near-neutral pH. Generalized models were developed to predict the concentration of TCE in the aqueous phase and TCE droplet radius as a function of time using literature-reported hydroxyl radical reaction kinetics and mass transfer relationships. Additional aspects of this work include the reusability of the Fe-citrate complex under repeated H(2)O(2) injections in real water systems as well as packed column studies for simulated groundwater injection.
authors.affiliation: Department of Chemical and Materials Engineering, University of Kentucky, Lexington, Kentucky.
authors.forename: Scott
authors.initials: S
authors.lastname: Lewis
authors.forename: Andrew
authors.initials: A
authors.lastname: Lynch
authors.forename: Leonidas
authors.initials: L
authors.lastname: Bachas
authors.forename: Steve
authors.initials: S
authors.lastname: Hampson
authors.forename: Lindell
authors.initials: L
authors.lastname: Ormsbee
authors.forename: Dibakar
authors.initials: D
authors.lastname: Bhattacharyya