Nickel-catalyzed Tishchenko reaction via hetero-nickelacycles by oxidative cyclization of aldehydes with nickel(0) complex.
A Ni(0)-catalyzed Tishchenko reaction which can be applied to a variety of aliphatic aldehydes (primary, secondary, tertiary) and aromatic aldehydes was developed. The reaction might proceed via a hetero-nickelacycle intermediate.
Ogoshi
Sensuke
S
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan. ogoshi@chem.eng.osaka-u.ac.jp
Hoshimoto
Yoichi
Y
Ohashi
Masato
M
D000447:Aldehydes / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D010084:Oxidation-Reduction; D013237:Stereoisomerism
D000447:Aldehydes; D009942:Organometallic Compounds; D009532:Nickel