title: A new context for palladium mediated B-addition reaction: an open door to consecutive functionalization.
abstract: Palladium metal-catalyzed boron addition to unsaturated carbon-carbon bonds provides an efficient and convenient route for the preparation of organoboranes, which are versatile intermediates for organic synthesis. Palladium complexes are responsible for the exclusive catalytic performance and eventually allow access to selectively functionalized molecules by catalytic consecutive tandem sequences. The final objective is to find suitable palladium complexes that make it possible to perform a one-pot sequential reaction (B-addition/functionalization) by means of a multifaceted palladium catalyst. Mechanistic insights into the concatenated reactions through B chemistry are required if one wants to understand the experimental results.
authors.affiliation: Univeristy Rovira i Virgili, Química Física i Inorgànica, Marcelli Domingo s/n, Tarragona 43007, Spain.
authors.forename: Cristina
authors.initials: C
authors.lastname: Pubill-Ulldemolins
authors.forename: Amadeu
authors.initials: A
authors.lastname: Bonet
authors.forename: Carles
authors.initials: C
authors.lastname: Bo
authors.forename: Henrik
authors.initials: H
authors.lastname: Gulyás
authors.forename: Elena
authors.initials: E
authors.lastname: Fernández