Hydrogen fluoride adduct of an ambiphilic phosphine-borane: NMR characterization and theoretical analysis of the bonding situation.
The HF adduct of the ambiphilic phosphine-borane [o-iPr(2)P(C(6)H(4))BMes(2)] has been spectroscopically characterized and the nature of the interaction between the ensuing hydrogenophosphonium and fluoroborate moieties has been analyzed computationally.
Moebs-Sanchez
Sylvie
S
Université de Toulouse, UPS, LHFA, 118 route de Narbonne, F-31062, Toulouse, France.
Saffon
Nathalie
N
Bouhadir
Ghenwa
G
Maron
Laurent
L
Bourissou
Didier
D