Multistep electron transfer systems based on silicon phthalocyanine, [60]fullerene and trinitrofluorenone.
The synthesis and photodynamics in the absence and in the presence of Mg(2+) ions of a novel TNF-C(60)-SiPc-C(60)-TNF pentad are reported. The redox gradient approach allows to obtain a long-lived CS state of 160 ns and 200 micros in the absence and in the presence of Mg(2+) ions, respectively.
Martín-Gomis
Luis
L
División de Química Orgánica, Instituto de Bioingeniería, Universidad Miguel Hernández, Elche 03202, Spain.
Ohkubo
Kei
K
Fernández-Lázaro
Fernando
F
Fukuzumi
Shunichi
S
Sastre-Santos
Angela
A
D004579:Electron Transport; D005449:Fluorenes / Q000737:chemistry*; D037741:Fullerenes / Q000737:chemistry*; D007211:Indoles / Q000737:chemistry*; D008274:Magnesium / Q000737:chemistry; D017646:Organosilicon Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D013997:Time Factors
D005449:Fluorenes; D037741:Fullerenes; D007211:Indoles; D017646:Organosilicon Compounds; C082854:silicon phthalocyanine; C005644:2,4,7-trinitrofluorenone; D008274:Magnesium; C069837:fullerene C60