title: Multistep electron transfer systems based on silicon phthalocyanine, [60]fullerene and trinitrofluorenone.
abstract: The synthesis and photodynamics in the absence and in the presence of Mg(2+) ions of a novel TNF-C(60)-SiPc-C(60)-TNF pentad are reported. The redox gradient approach allows to obtain a long-lived CS state of 160 ns and 200 micros in the absence and in the presence of Mg(2+) ions, respectively.
authors.affiliation: División de Química Orgánica, Instituto de Bioingeniería, Universidad Miguel Hernández, Elche 03202, Spain.
authors.forename: Luis
authors.initials: L
authors.lastname: Martín-Gomis
authors.forename: Kei
authors.initials: K
authors.lastname: Ohkubo
authors.forename: Fernando
authors.initials: F
authors.lastname: Fernández-Lázaro
authors.forename: Shunichi
authors.initials: S
authors.lastname: Fukuzumi
authors.forename: Angela
authors.initials: A
authors.lastname: Sastre-Santos
mesh_terms: D004579:Electron Transport; D005449:Fluorenes / Q000737:chemistry*; D037741:Fullerenes / Q000737:chemistry*; D007211:Indoles / Q000737:chemistry*; D008274:Magnesium / Q000737:chemistry; D017646:Organosilicon Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D013997:Time Factors
chemical_list: D005449:Fluorenes; D037741:Fullerenes; D007211:Indoles; D017646:Organosilicon Compounds; C082854:silicon phthalocyanine; C005644:2,4,7-trinitrofluorenone; D008274:Magnesium; C069837:fullerene C60