La2Co2Se2O3: a quasi-two-dimensional mott insulator with unusual cobalt spin state and possible orbital ordering.
The new oxyselenide La(2)Co(2)Se(2)O(3), containing Co(2)O square-planar layers, has been successfully synthesized using solid-state reactions under vacuum. The compound crystallizes in space group I4/mmm with lattice parameters a = 4.0697(8) A and c = 18.419(4) A. Magnetic susceptibility measurements indicate an antiferromagnetic transition at approximately 220 K. The magnetic entropy associated with the transition is close to R ln 2, suggesting an unusual low-spin state for the Co(2+) ions. The as-prepared sample shows insulating behavior with room-temperature resistivity of approximately 10(7) ohms cm, which decreases by 4 orders of magnitude under a pressure of 7 GPa. Band structure calculations using the LSDA+U approach reproduce the insulating ground state with low spin for Co and suggest strong orbital polarization for the valence electrons near the Fermi level. It is also revealed that the spin and orbital degrees of freedom in the antiferromagnetic checkerboard spin-lattice are mutually coupled.
Wang
Cao
C
Department of Physics, Zhejiang University, Hangzhou 310027, People's Republic of China.
Tan
Ming-qiu
MQ
Feng
Chun-mu
CM
Ma
Zhi-feng
ZF
Jiang
Shuai
S
Xu
Zhu-an
ZA
Cao
Guang-han
GH
Matsubayashi
Kazuyuki
K
Uwatoko
Yoshiya
Y