A chiral 2,6-bis(oxazolinyl)pyridine ligand with amide groups to form isomorphous complexes through all the lanthanoid series.
We newly synthesized the chiral pybox ligand, 2,6-bis[(4S)-tert-butylcarbamoyl-2-oxazolin-2-yl]pyridine, whose lanthanoid(III) complexes have formed isomorphous crystals through all the lanthanoid series. The luminescence properties of the Eu(III) complex have been investigated.
Matsumoto
Kenji
K
Department of Materials and Life Science, Seikei University, 3-3-1 Kichijoji-kitamachi, Musashino, Tokyo, 180-8633, Japan.
Suzuki
Keita
K
Tsukuda
Toshiaki
T
Tsubomura
Taro
T
D018360:Crystallography, X-Ray; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010080:Oxazoles / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*
C551811:2,6-bis(tert-butylcarbamoyl-2-oxazolin-2-yl)pyridine; D028581:Lanthanoid Series Elements; D008024:Ligands; D009942:Organometallic Compounds; D010080:Oxazoles; D011725:Pyridines