Charge stabilization in a closely spaced ferrocene-boron dipyrrin-fullerene triad.
New molecular triads composed of closely spaced ferrocene-boron dipyrrin-fullerene, 1 and triphenylamine-boron dipyrrin-fullerene, 2 are synthesized, and photoinduced electron transfer leading to charge stabilization is demonstrated using a femtosecond transient spectroscopic technique.
Wijesinghe
Channa A
CA
Department of Chemistry, Wichita State University, 1845, Fairmount, Wichita, KS 67260, USA.
El-Khouly
Mohamed E
ME
Blakemore
James D
JD
Zandler
Melvin E
ME
Fukuzumi
Shunichi
S
D'Souza
Francis
F
D001895:Boron / Q000737:chemistry*; D003198:Computer Simulation; D005296:Ferrous Compounds / Q000737:chemistry*; D037741:Fullerenes / Q000737:chemistry*; D000075163:Metallocenes; D015394:Molecular Structure; D011758:Pyrroles / Q000737:chemistry*
D005296:Ferrous Compounds; D037741:Fullerenes; D000075163:Metallocenes; D011758:Pyrroles; D001895:Boron; C004998:ferrocene