Cellulose whisker/epoxy resin nanocomposites.
New nanocomposites composed of cellulose nanofibers or "whiskers" and an epoxy resin were prepared. Cellulose whiskers with aspect ratios of approximately 10 and approximately 84 were isolated from cotton and sea animals called tunicates, respectively. Suspensions of these whiskers in dimethylformamide were combined with an oligomeric difunctional diglycidyl ether of bisphenol A with an epoxide equivalent weight of 185-192 and a diethyl toluenediamine-based curing agent. Thin films were produced by casting these mixtures and subsequent curing. The whisker content was systematically varied between 4 and 24% v/v. Electron microscopy studies suggest that the whiskers are evenly dispersed within the epoxy matrix. Dynamic mechanical thermoanalysis revealed that the glass transition temperature (T(g)) of the materials was not significantly influenced by the incorporation of the cellulose filler. Between room temperature and 150 degrees C, i.e., below T(g), the tensile storage moduli (E') of the nanocomposites increased modestly, for example from 1.6 GPa for the neat polymer to 4.9 and 3.6 GPa for nanocomposites comprising 16% v/v tunicate or cotton whiskers. The relative reinforcement was more significant at 185 degrees C (i.e., above T(g)), where E' was increased from approximately 16 MPa (neat polymer) to approximately 1.6 GPa (tunicate) or approximately 215 MPa (cotton). The mechanical properties of the new materials are well-described by the percolation model and are the result of the formation of a percolating whisker network in which stress transfer is facilitated by strong interactions between the whiskers.
Tang
Liming
L
Department of Macromolecular Science and Engineering, Case Western Reserve University, Cleveland, Ohio 44106, USA.
Weder
Christoph
C
D001559:Benzhydryl Compounds; D002482:Cellulose / Q000737:chemistry*; D004126:Dimethylformamide / Q000737:chemistry; D004853:Epoxy Resins / Q000737:chemistry*; D004986:Ether / Q000737:chemistry; D008422:Materials Testing; D053761:Nanocomposites / Q000737:chemistry*; D057139:Nanofibers / Q000737:chemistry*; D036103:Nanotechnology / Q000379:methods; D010636:Phenols / Q000737:chemistry; D013314:Stress, Mechanical; D013696:Temperature; D013718:Tensile Strength; D000098826:Bisphenol A Compounds
D001559:Benzhydryl Compounds; D002482:Cellulose; D004126:Dimethylformamide; D004853:Epoxy Resins; D004986:Ether; D010636:Phenols; C006780:bisphenol A; D000098826:Bisphenol A Compounds