title: An unexpected rearrangement giving a new thiosubstituted carbohydrate.
abstract: A new thiosubstituted 'd-arabino'-type derivative was obtained from an open carbohydrate via a cascade of four consecutive transformations in a single reaction process. Molecular orbital computations were also performed to explain the stereochemical outcome of the reaction.
authors.affiliation: Institut de Chimie Moléculaire de Reims, UMR CNRS, Université de Reims, Reims Cedex, France.
authors.forename: Agathe
authors.initials: A
authors.lastname: Martinez
authors.forename: Eric
authors.initials: E
authors.lastname: Hénon
authors.forename: Claire
authors.initials: C
authors.lastname: Coiffier
authors.forename: Aline
authors.initials: A
authors.lastname: Banchet
authors.forename: Dominique
authors.initials: D
authors.lastname: Harakat
authors.forename: Jean-Marc
authors.initials: JM
authors.lastname: Nuzillard
authors.forename: Arnaud
authors.initials: A
authors.lastname: Haudrechy
mesh_terms: D000447:Aldehydes / Q000737:chemistry; D002241:Carbohydrates / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D011789:Quantum Theory; D013237:Stereoisomerism; D013455:Sulfur / Q000737:chemistry*
chemical_list: D000447:Aldehydes; D002241:Carbohydrates; D013455:Sulfur