title: Plastic catalytic pyrolysis to fuels as tertiary polymer recycling method: effect of process conditions.
abstract: This paper presents results regarding the effect of various process conditions on the performance of a zeolite catalyst in pyrolysis of high density polyethylene. The results show that polymer catalytic degradation can be operated at relatively low catalyst content reducing the cost of a potential industrial process. As the polymer to catalyst mass ratio increases, the system becomes less active, but high temperatures compensate for this activity loss resulting in high conversion values at usual batch times and even higher yields of liquid products due to less overcracking. The results also show that high flow rate of carrier gas causes evaporation of liquid products falsifying results, as it was obvious from liquid yield results at different reaction times as well as the corresponding boiling point distributions. Furthermore, results are presented regarding temperature effects on liquid selectivity. Similar values resulted from different final reactor temperatures, which are attributed to the batch operation of the experimental equipment. Since polymer and catalyst both undergo the same temperature profile, which is the same up to a specific time independent of the final temperature. Obviously, this common temperature step determines the selectivity to specific products. However, selectivity to specific products is affected by the temperature, as shown in the corresponding boiling point distributions, with higher temperatures showing an increased selectivity to middle boiling point components (C(8)-C(9)) and lower temperatures increased selectivity to heavy components (C(14)-C(18)).
authors.affiliation: Institute of Chemical Sciences, University of Peshawar, Peshawar, Pakistan.
authors.forename: Hussain
authors.initials: H
authors.lastname: Gulab
authors.forename: Muhammad Rasul
authors.initials: MR
authors.lastname: Jan
authors.forename: Jasmin
authors.initials: J
authors.lastname: Shah
authors.forename: George
authors.initials: G
authors.lastname: Manos
mesh_terms: D002384:Catalysis; D003247:Conservation of Natural Resources; D009584:Nitrogen / Q000737:chemistry; D010969:Plastics / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D013696:Temperature; D017641:Zeolites / Q000737:chemistry
chemical_list: D010969:Plastics; D011108:Polymers; D017641:Zeolites; D009584:Nitrogen