Conversion of sugars to lactic acid derivatives using heterogeneous zeotype catalysts.
Presently, very few compounds of commercial interest are directly accessible from carbohydrates by using nonfermentive approaches. We describe here a catalytic process for the direct formation of methyl lactate from common sugars. Lewis acidic zeotypes, such as Sn-Beta, catalyze the conversion of mono- and disaccharides that are dissolved in methanol to methyl lactate at 160 degrees C. With sucrose as the substrate, methyl lactate yield reaches 68%, and the heterogeneous catalyst can be easily recovered by filtration and reused multiple times after calcination without any substantial change in the product selectivity.
Holm
Martin Spangsberg
MS
Centre for Catalysis and Sustainable Chemistry, Department of Chemistry, Technical University of Denmark, Anker Engelundsvej 1, 2800 Kongens Lyngby, Denmark.
Saravanamurugan
Shunmugavel
S
Taarning
Esben
E