Atom-efficient synthesis of alpha-alkylidene-N-furylimines via catalytic vinylcarbene-transfer reactions to carbonyl-ene-nitrile compounds.
The reaction of carbonyl-ene-nitrile compounds with propargyl carboxylates in the presence of a catalytic amount of PtCl(2) afforded the alpha-alkylidene-N-furylimines with high stereoselectivities.
Murai
Masahito
M
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan.
Yoshida
Shotaro
S
Miki
Koji
K
Ohe
Kouichi
K
D002384:Catalysis; D007097:Imines / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009570:Nitriles / Q000138:chemical synthesis* / Q000737:chemistry; D017671:Platinum Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D014753:Vinyl Compounds / Q000737:chemistry*
D007097:Imines; D009570:Nitriles; D017671:Platinum Compounds; D014753:Vinyl Compounds; C516829:vinylcarbene; C030173:platinum chloride