Synthesis of a water-soluble 1,3-bis(diphenylene)-2-phenylallyl radical.
The design and synthesis of a water-soluble 1,3-bis(diphenylene)-2-phenylallyl (BDPA) radical via the conjugate addition of a derivatized fluorene nucelophile is described. The compound is designed for use in dynamic nuclear polarization NMR. Its 9 GHz EPR spectrum in glycerol/water is reported.
Dane
Eric L
EL
Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139, USA.
Swager
Timothy M
TM
D000498:Allyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D018360:Crystallography, X-Ray; D005609:Free Radicals / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D012995:Solubility; D014867:Water / Q000737:chemistry*
D000498:Allyl Compounds; D005609:Free Radicals; C416323:bis-diphenylene-phenyl-allyl; D014867:Water