Bis(imino)phenoxide complexes of zirconium: synthesis, structural characterization and solvent-free ring-opening polymerization of cyclic esters and lactides.
Bis(imino)phenoxide complexes of zirconium possess spectacular reactivity towards the solvent-free polymerization of cyclic ester monomers and lactides. Polymerization of lactide is living and the resulting product has exceptionally high number average molecular weights (Mn). Polymerization of β-butyrolactone gives syndiotactic poly(3-hydroxybutyrate) with good Mn and molecular weight distribution (MWD).
Saha
Tanmoy Kumar
TK
Department of Chemistry, Indian Institute of Technology Madras, Chennai, 600 036, Tamil Nadu, India. dchakraborty@iitm.ac.in.
Rajashekhar
Bijja
B
Gowda
Ravikumar R
RR
Ramkumara
Venkatachalam
V
Chakraborty
Debashis
D
D018360:Crystallography, X-Ray; D004146:Dioxanes / Q000138:chemical synthesis* / Q000737:chemistry; D004952:Esters / Q000138:chemical synthesis* / Q000737:chemistry; D007097:Imines / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010636:Phenols / Q000737:chemistry*; D058105:Polymerization; D015040:Zirconium / Q000737:chemistry*
D004146:Dioxanes; D004952:Esters; D007097:Imines; D009942:Organometallic Compounds; D010636:Phenols; C000599033:bis(imino)phenoxide; C091880:dilactide; D015040:Zirconium