title: Gold promoted S,N-doped TiO(2): an efficient catalyst for CO adsorption and oxidation.
abstract: Mesoporous S,N-TiO(2) nanocomposite was prepared by a one-pot template free homogeneous coprecipitation technique using titanium oxysulfate sulfuric acid complex hydrate, thiourea, ethanol, and water. Nano gold deposition on mesoporous S,N-TiO(2) was preformed by a borohydrate reduction method. To evaluate the structural and electronic properties, these catalysts were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), high-resolution transmission electron microscopy (HR-TEM), UV-vis DRS, photoluminescent (PL) spectra, Fourier transform infrared (FTIR), and TPO/TPD. CO adsorption and CO + O(2) interaction over these catalysts were investigated by in situ FTIR. Sulfur and nitrogen doping enhances the catalytic activity of Au/TiO(2.) Higher catalytic activity of Au/S,N-TiO(2) compared to Au/TiO(2) was attributed to the presence of oxygen vacancy and creation of new adsorption sites at Au/TiO(2) interfaces for the adsorption and activation of O(2) molecules.
authors.affiliation: Colloids and Materials Chemistry Department, Institute of Minerals and Materials Technology (CSIR), Bhubaneswar, Orissa, India. paridakulaman@yahoo.com
authors.forename: K M
authors.initials: KM
authors.lastname: Parida
authors.forename: Nruparaj
authors.initials: N
authors.lastname: Sahu
authors.forename: A K
authors.initials: AK
authors.lastname: Tripathi
authors.forename: V S
authors.initials: VS
authors.lastname: Kamble
mesh_terms: D000327:Adsorption; D002248:Carbon Monoxide / Q000737:chemistry*; D006046:Gold / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry*; D010084:Oxidation-Reduction; D017550:Spectroscopy, Fourier Transform Infrared; D013455:Sulfur / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*
chemical_list: C009495:titanium dioxide; D013455:Sulfur; D006046:Gold; D002248:Carbon Monoxide; D014025:Titanium; D009584:Nitrogen