Poly[bis(mu-4-benzoyl-1-isonicotinoylthiosemicarbazide-kappa2N:S)dichloridocadmium(II)].
The asymmetric unit of the title complex, [CdCl(2)(C(14)H(12)N(4)O(2)S)(2)](n), consists of one Cd(II) ion located on the crystallographic inversion centre, one 4-benzoyl-1-isonicotinoylthiosemicarbazide ligand and one chloride ligand. The central Cd(II) ion adopts a distorted octahedral coordination geometry formed by two pyridyl N atoms of two ligands, two S atoms of two other ligands and two chloride ligands. The thiosemicarbazide ligands act as bridges, linking the metal ions into a two-dimensional layered structure parallel to the bc plane. Intermolecular N-H...O hydrogen bonds and C-H...pi interactions exist between adjacent layers.
Wang
Yu-Bo
YB
State Key Laboratory Breeding Base of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350108, People's Republic of China.
Pan
Tong-Hen
TH
Liang
Qian
Q
Liu
Dong-Sheng
DS
Huang
Chang-Cang
CC
D002104:Cadmium / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D008024:Ligands; D009942:Organometallic Compounds; D002104:Cadmium