title: Bio-supramolecular photochirogenesis with molecular chaperone: enantiodifferentiating photocyclodimerization of 2-anthracenecarboxylate mediated by prefoldin.
abstract: Photocyclodimerization of 2-anthracenecarboxylate mediated by molecular chaperone protein was performed for the first time to afford chiral syn-head-to-tail and anti-head-to-head dimers (2 and 3) in 10% and 16% enantiomeric excess, respectively, with enhanced yields of sterically and electrostatically less-favored head-to-head dimers (3 and 4).
authors.affiliation: Department of Applied Chemistry, Osaka University, 2-1 Yamada-oka, Suita, 565-0871, Japan.
authors.forename: Kazuki
authors.initials: K
authors.lastname: Bando
authors.forename: Tamotsu
authors.initials: T
authors.lastname: Zako
authors.forename: Masafumi
authors.initials: M
authors.lastname: Sakono
authors.forename: Mizuo
authors.initials: M
authors.lastname: Maeda
authors.forename: Takehiko
authors.initials: T
authors.lastname: Wada
authors.forename: Masaki
authors.initials: M
authors.lastname: Nishijima
authors.forename: Gaku
authors.initials: G
authors.lastname: Fukuhara
authors.forename: Cheng
authors.initials: C
authors.lastname: Yang
authors.forename: Tadashi
authors.initials: T
authors.lastname: Mori
authors.forename: Tamara C S
authors.initials: TC
authors.lastname: Pace
authors.forename: Cornelia
authors.initials: C
authors.lastname: Bohne
authors.forename: Yoshihisa
authors.initials: Y
authors.lastname: Inoue
mesh_terms: D000873:Anthracenes / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003500:Cyclization; D019281:Dimerization; D008958:Models, Molecular; D018832:Molecular Chaperones / Q000737:chemistry*; D015394:Molecular Structure; D010777:Photochemistry; D013237:Stereoisomerism
chemical_list: C476641:2-anthracenecarboxylate; D000873:Anthracenes; D002264:Carboxylic Acids; D018832:Molecular Chaperones; C112806:prefoldin