title: Self-assembly from metal-organic vesicles to globular networks: metallogel-mediated phenylation of indole with phenyl boronic acid.
abstract: Self-assembly of the conformationally flexible bismethylimidazolyl ligands with Pd(OAc)(2) is described. Depending on whether the ligands provide the hydrogen bonding donor, a switching of metal-organic vesicles to globular networks gelating solvents is achieved. The metallogels exhibit catalytic activity for the cross-coupling of indole with phenyl boronic acid.
authors.affiliation: Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Hospital, Sichuan University, Chengdu 610064, People's Republic of China.
authors.forename: Li
authors.initials: L
authors.lastname: Yang
authors.forename: Liang
authors.initials: L
authors.lastname: Luo
authors.forename: Shuai
authors.initials: S
authors.lastname: Zhang
authors.forename: Xiaoyu
authors.initials: X
authors.lastname: Su
authors.forename: Jingbo
authors.initials: J
authors.lastname: Lan
authors.forename: Chi-Tien
authors.initials: CT
authors.lastname: Chen
authors.forename: Jingsong
authors.initials: J
authors.lastname: You
mesh_terms: D001897:Boronic Acids / Q000737:chemistry*; D005782:Gels / Q000737:chemistry*; D007211:Indoles / Q000737:chemistry*; D008024:Ligands; D008051:Lipid Bilayers / Q000737:chemistry*; D008670:Metals / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry
chemical_list: D001897:Boronic Acids; D005782:Gels; D007211:Indoles; D008024:Ligands; D008051:Lipid Bilayers; D008670:Metals; D010165:Palladium; C030374:indole