title: Structure of silver(I) complex prepared from azobenzenonaphthalenophane, photochemical coordination change of silver(I) and silver(I)-induced acceleration of Z-E thermal isomerization of azobenzene unit.
abstract: A Ag(I) complex was prepared from azobenzenonaphthalenophane as a photoreactive multidentate ligand. The coordination of Ag(I) was reversibly controlled by photoisomerization of the azobenzene unit, and at the same time, Ag(I) accelerated the Z-E thermal isomerization of the azobenzene unit.
authors.affiliation: Nanotechnology Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, Higashi 1-1-1, Tsukuba, Ibaraki, Japan.
authors.forename: Yoshimi
authors.initials: Y
authors.lastname: Oka
authors.forename: Nobuyuki
authors.initials: N
authors.lastname: Tamaoki
mesh_terms: D001391:Azo Compounds / Q000737:chemistry*; D001952:Bridged-Ring Compounds / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010777:Photochemistry; D012834:Silver / Q000737:chemistry*; D013237:Stereoisomerism; D013696:Temperature
chemical_list: C551813:(5.5)(4,4')azobenzeno(1,5)naphthalenophane; D001391:Azo Compounds; D001952:Bridged-Ring Compounds; D009942:Organometallic Compounds; D012834:Silver; C009850:azobenzene