title: Metsulfuron-methyl sorption/desorption behavior on volcanic ash-derived soils. effect of phosphate and pH.
abstract: Metsulfuron-methyl sorption/desorption behavior was studied through batch sorption experiments in three typical volcanic ash-derived soils belonging to Andisol and Ultisol orders. Their distinctive physical and chemical properties are acidic pH and variable surface charge. Organic matter content and mineral composition affected in different ways sorption of metsulfuron-methyl (K(OC) ranging from 113 to 646 mL g(-1)): organic matter and iron and aluminum oxides mainly through hydrophilic rather than hydrophobic interactions in Andisols, and Kaolinite group minerals, as major constituents of Ultisols, and iron and aluminum oxides only through hydrophilic interactions. The Freundlich model described metsulfuron-methyl behavior in all cases (R(2) > 0.992). K(f) values (3.1-14.4 microg(1-1/n) mL(1/n) g(-1)) were higher than those reported for different class of soils including some with variable charge. Hysteresis was more significant in Ultisols. A strong influence of pH and phosphate was established for both kinds of soil, intensive soil fertilization and liming being the most probable scenario for leaching of metsulfuron-methyl, particularly in Ultisols.
authors.affiliation: Facultad de Ciencias Básicas, Universidad Metropolitana de Ciencias de la Educación, Av José Pedro Alessandri 540, Santiago de Chile.
authors.forename: Lizethly
authors.initials: L
authors.lastname: Cáceres
authors.forename: Roxana
authors.initials: R
authors.lastname: Fuentes
authors.forename: Mauricio
authors.initials: M
authors.lastname: Escudey
authors.forename: Edwar
authors.initials: E
authors.lastname: Fuentes
authors.forename: María E
authors.initials: ME
authors.lastname: Báez
mesh_terms: D000327:Adsorption; D001190:Arylsulfonates / Q000737:chemistry*; D006540:Herbicides / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D010710:Phosphates / Q000032:analysis*; D012987:Soil / Q000032:analysis*; D018707:Volcanic Eruptions / Q000032:analysis*
chemical_list: D001190:Arylsulfonates; D006540:Herbicides; D010710:Phosphates; D012987:Soil; C050296:metsulfuron methyl