title: Release and fate of fluorocarbons in a shredder residue landfill cell: 2. Field investigations.
abstract: The shredder residues from automobiles, home appliances and other metal containing products are often disposed in landfills, as recycling technologies for these materials are not common in many countries. Shredder waste contains rigid and soft foams from cushions and insulation panels blown with fluorocarbons. The objective of this study was to determine the gas composition, attenuation, and emission of fluorocarbons in a monofill shredder residue landfill cell by field investigation. Landfill gas generated within the shredder waste primarily consisted of CH(4) (27%) and N(2) (71%), without CO(2), indicating that the gas composition was governed by chemical reactions in combination with anaerobic microbial reactions. The gas generated also contained different fluorocarbons (up to 27 μg L(-1)). The presence of HCFC-21 and HCFC-31 indicated that anaerobic degradation of CFC-11 occurred in the landfill cell, as neither of these compounds has been produced for industrial applications. This study demonstrates that a landfill cell containing shredder waste has a potential for attenuating CFC-11 released from polyurethane (PUR) insulation foam in the cell via aerobic and anaerobic biodegradation processes. In deeper, anaerobic zones of the cell, reductive dechlorination of CFCs to HCFCs was evident, while in the shallow, oxic zones, there was a high potential for biooxidation of both methane and lesser chlorinated fluorocarbons. These findings correlated well with both laboratory results (presented in a companion paper) and surface emission measurements that, with the exception from a few hot spots, indicated that surface emissions were negative or below detection.
authors.affiliation: Department of Environmental Engineering, Miljovej-Building 113, Technical University of Denmark, DK-2800 Kgs. Lyngby, Denmark.
authors.forename: Charlotte
authors.initials: C
authors.lastname: Scheutz
authors.forename: Anders M
authors.initials: AM
authors.lastname: Fredenslund
authors.forename: Jonas
authors.initials: J
authors.lastname: Nedenskov
authors.forename: Peter
authors.initials: P
authors.lastname: Kjeldsen
mesh_terms: D000393:Air Pollutants / Q000032:analysis; D004867:Equipment Design; D005466:Fluorocarbons / Q000032:analysis*; D005740:Gases; D040362:Geographic Information Systems; D006219:Halogens / Q000032:analysis; D008697:Methane / Q000032:analysis / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry; D011140:Polyurethanes / Q000737:chemistry; D012037:Refuse Disposal / Q000379:methods*; D014887:Weather
chemical_list: D000393:Air Pollutants; D005466:Fluorocarbons; D005740:Gases; D006219:Halogens; D011140:Polyurethanes; D008697:Methane; D010100:Oxygen