title: Insights into photoinduced electron transfer between [Ru(mptpy)2]4+ (mptpy = 4'(4-methylpyridinio)-2,2':6',2''-terpyridine) and [S2O8]2-: computational and experimental studies.
abstract: The mechanism and electron transfer dynamics of the reaction [Ru(II)(mptpy)(2)](4+) + hnu + [S(2)O(8)](2-) --> [Ru(III)(mptpy)(2)](5+) + SO(4)(2-) + SO(4)(-*) were studied using various computational (density functional and exciton interaction theories) and experimental (transient absorption, static and time-resolved fluorescence spectroscopy, and other) techniques. The results were compared with those recently reported for [Ru(bpy)(3)](2+) dye [ref 18]. It was found that the excitation energy of [Ru(mptpy)(2)](4+) is about 0.4-0.5 eV smaller than that of [Ru(bpy)(3)](2+), which is consistent with the measured absorption maxima of 445 and 507 nm, for [Ru(bpy)(3)](2+) and [Ru(mptpy)(2)](4+), respectively. The smaller excitation energy in [Ru(mptpy)(2)](4+) correlates with much slower electron transfer rates to persulfate compared to [Ru(bpy)(3)](2+). The quenching of the photoexcited [Ru(mptpy)(2)](4+) by [S(2)O(8)](2-) occurs via a unimolecular mechanism with formation of a weak ion-pair complex {[Ru(mptpy)(2)](4+)...([S(2)O(8)](2-))(n)}, where n = 1 and 2. The initial photon is absorbed by the [Ru(mptpy)(2)](4+) fragment forming an MLCT state, e.g., the bright singlet state S1. This S1 state undergoes a fast spin-orbit coupling induced intersystem crossing to a lower-lying triplet and rapid subsequent relaxation down to the lowest triplet T1 via internal conversion and collisions with solvent molecules. At this stage, the electron transfer from [Ru(mptpy)(2)](4+) to a loosely attached [S(2)O(8)](2-) occurs in a dark reaction via elongation of the O-O peroxo bond of the oxidant [S(2)O(8)](2-). The electron transfer lifetimes in water are calculated to be 1/kappa(1) = 199.4 ns and 1/kappa(2) = 108.4 ns, for the 1:1 and 1:2 complexes, respectively. The computed electron transfer lifetimes (1/kappa(1)) are in reasonable agreement with their experimental values of 298 and 149 ns for the 1:1 and 1:2 complexes, respectively. The effect of solvent polarity on electron transfer rates is found to be significant: the less polar acetonitrile slows the rate by an order of magnitude compared to water.
authors.affiliation: Cherry L. Emerson Center for Scientific Computation, Emory University, Atlanta, Georgia 30322, USA. akaledi@emory.edu
authors.forename: Alexey L
authors.initials: AL
authors.lastname: Kaledin
authors.forename: Zhuangqun
authors.initials: Z
authors.lastname: Huang
authors.forename: Qiushi
authors.initials: Q
authors.lastname: Yin
authors.forename: Emma L
authors.initials: EL
authors.lastname: Dunphy
authors.forename: Edwin C
authors.initials: EC
authors.lastname: Constable
authors.forename: Catherine E
authors.initials: CE
authors.lastname: Housecroft
authors.forename: Yurii V
authors.initials: YV
authors.lastname: Geletii
authors.forename: Tianquan
authors.initials: T
authors.lastname: Lian
authors.forename: Craig L
authors.initials: CL
authors.lastname: Hill
authors.forename: Djamaladdin G
authors.initials: DG
authors.lastname: Musaev