title: [Simple analytical method of bromine in fruits and grain products with wavelength dispersive X-ray fluorescence spectrometer].
abstract: A simple analytical method was developed for the determination of total bromine in fruits and grain products by means of wavelength dispersive X-ray fluorescence spectrometry (WDXRF).Five gram samples of fresh fruits, frozen fruits, dried fruits and grain products were extracted with distilled water twice and diluted to 25 mL with distilled water. The sample solution (0.5 mL) was dripped onto the filter paper, which was dried and analyzed by WDXRF. The working curve was linear in the range of 0 to 10 microg/mL. Recoveries at the level of 5 microg/g were 76-104%. The detection limit was 0.5 microg/g and the determination limit was 1.5 microg/g in foods. Compared to the GC-ECD method, this method gave equivalent results for fresh fruits, frozen fruits and grain products. In addition, some dried fruits, in which a slightly high level was detected, gave almost the same results with the GC-ECD method. Therefore, this method is considered to be available as an alternative to the GC-ECD method.
authors.affiliation: Tokyo Metropolitan Institute of Public Health, 3-24-1 Hyakunin-cho, Shinjuku-ku, Tokyo 169-0073, Japan.
authors.forename: Yukinari
authors.initials: Y
authors.lastname: Tateishi
authors.forename: Tsuneo
authors.initials: T
authors.lastname: Hashimoto
authors.forename: Keiko
authors.initials: K
authors.lastname: Ushiyama
authors.forename: Naoko
authors.initials: N
authors.lastname: Sakai
authors.forename: Itoko
authors.initials: I
authors.lastname: Baba
authors.forename: Toshihiro
authors.initials: T
authors.lastname: Nagayama
mesh_terms: D017605:Bromine Compounds / Q000032:analysis*; D002849:Chromatography, Gas / Q000379:methods; D002523:Edible Grain / Q000737:chemistry*; D004563:Electrochemistry / Q000379:methods; D005504:Food Analysis / Q000379:methods*; D005638:Fruit / Q000737:chemistry*; D010573:Pesticide Residues / Q000032:analysis*; D013052:Spectrometry, X-Ray Emission / Q000379:methods*
chemical_list: D017605:Bromine Compounds; D010573:Pesticide Residues