Highly luminescent bis-cyclometalated iridium(III) ethylenediamine complex: synthesis and correlation between the solid state polymorphism and the photophysical properties.
The solvent induced polymorphism observed in a cyclometalated iridium(iii) ethylenediamine ionic complex is a new tool to modulate and enhance emission in the solid crystalline state.
Talarico
Anna Maria
AM
Centro di Eccellenza CEMIF.CAL, LASCAMM CR-INSTM and Laboratorio Regionale Licryl, CNR-INFM, Dipartimento di Chimica, Università della Calabria, 87030 Arcavacata di Rende, Italy.
Aiello
Iolinda
I
Bellusci
Anna
A
Crispini
Alessandra
A
Ghedini
Mauro
M
Godbert
Nicolas
N
Pugliese
Teresa
T
Szerb
Elisabeta
E
D018360:Crystallography, X-Ray; D007495:Iridium / Q000737:chemistry*; D049449:Luminescence; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D010777:Photochemistry; D012997:Solvents / Q000737:chemistry
D009942:Organometallic Compounds; D012997:Solvents; D007495:Iridium