Remarkable Mg2+-selective emission of an azacrown receptor based on Ir(III) complex.
A new aza-15-crown-5 ether-appended iridium complex was synthesized and showed promising on-off selective emission-triggering by inhibition of photoinduced electron transfer (PET) upon binding of Mg(2+).
Brandel
Jeremy
J
Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan.
Sairenji
Masaki
M
Ichikawa
Kyoko
K
Nabeshima
Tatsuya
T
D056831:Coordination Complexes / Q000737:chemistry*; D043844:Crown Ethers / Q000737:chemistry*; D004579:Electron Transport; D007495:Iridium / Q000737:chemistry*; D008274:Magnesium / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet
D056831:Coordination Complexes; D043844:Crown Ethers; C042148:15-crown-5; D007495:Iridium; D008274:Magnesium