title: Secondary organic aerosol formation from a large number of reactive man-made organic compounds.
abstract: A photochemical trajectory model has been used to examine the relative propensities of a wide variety of volatile organic compounds (VOCs) emitted by human activities to form secondary organic aerosol (SOA) under one set of highly idealised conditions representing northwest Europe. This study applied a detailed speciated VOC emission inventory and the Master Chemical Mechanism version 3.1 (MCM v3.1) gas phase chemistry, coupled with an optimised representation of gas-aerosol absorptive partitioning of 365 oxygenated chemical reaction product species. In all, SOA formation was estimated from the atmospheric oxidation of 113 emitted VOCs. A number of aromatic compounds, together with some alkanes and terpenes, showed significant propensities to form SOA. When these propensities were folded into a detailed speciated emission inventory, 15 organic compounds together accounted for 97% of the SOA formation potential of UK man made VOC emissions and 30 emission source categories accounted for 87% of this potential. After road transport and the chemical industry, SOA formation was dominated by the solvents sector which accounted for 28% of the SOA formation potential.
authors.affiliation: rdscientific, Newbury, Berkshire, UK. r.derwent@btopenworld.com
authors.forename: Richard G
authors.initials: RG
authors.lastname: Derwent
authors.forename: Michael E
authors.initials: ME
authors.lastname: Jenkin
authors.forename: Steven R
authors.initials: SR
authors.lastname: Utembe
authors.forename: Dudley E
authors.initials: DE
authors.lastname: Shallcross
authors.forename: Tim P
authors.initials: TP
authors.lastname: Murrells
authors.forename: Neil R
authors.initials: NR
authors.lastname: Passant
mesh_terms: D000336:Aerosols; D009930:Organic Chemicals / Q000737:chemistry*
chemical_list: D000336:Aerosols; D009930:Organic Chemicals