Enantioselective synthesis of 3-azabicyclo[4.1.0]heptenes and 3-azabicyclo[3.2.0]heptenes by Ir-catalyzed asymmetric allylic amination of N-tosyl propynylamine and Pt-catalyzed cycloisomerization.
Xia
Ji-Bao
JB
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China.
Liu
Wen-Bo
WB
Wang
Tian-Min
TM
You
Shu-Li
SL
D000586:Amination; D053961:Azabicyclo Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D006536:Heptanes / Q000138:chemical synthesis* / Q000737:chemistry; D007495:Iridium / Q000737:chemistry*; D015394:Molecular Structure; D010293:Pargyline / Q000031:analogs & derivatives* / Q000737:chemistry; D010984:Platinum / Q000737:chemistry*; D013237:Stereoisomerism
D053961:Azabicyclo Compounds; D006536:Heptanes; C551519:N-tosyl propynylamine; D007495:Iridium; D010984:Platinum; D010293:Pargyline