Theory of Polymer Entrapped Enzyme Ultramicroelectrodes: Application to Glucose and Adenosine Triphosphate Detection.
We validate, by comparison with experimental data, a theoretical description of the amperometric response of microbiosensors formed via enzyme entrapment. The utility of the theory is further illustrated with two relevant examples supported by experiments: (1) quantitative detection of glucose and (2) quantitative detection of adenosine triphosphate (ATP).
Kottke
Peter A
PA
Georgia Institute of Technology, G. W. Woodruff School of Mechanical Engineering, Atlanta, GA 30332-0405.
Kranz
Christine
C
Kwon
Yong Koo
YK
Masson
Jean-Francois
JF
Mizaikoff
Boris
B
Fedorov
Andrei G
AG
Anal Chem. 2002 Jan 15;74(2):355-61
11811408
J Biol Chem. 1971 Nov;246(21):6611-9
5132674
Anal Chim Acta. 1973 May;64(3):439-55
4701057
Biochim Biophys Acta. 1996 Oct 24;1291(2):115-21
8898871
Biosens Bioelectron. 1997 Dec 30;12(12):1157-67
9474766
J Biol Chem. 1964 May;239:1625-34
14189901
Anal Chem. 2006 Jun 15;78(12):3965-84
16771535
Philos Trans R Soc Lond B Biol Sci. 1987 Aug 28;316(1176):85-94
2889233
Biotechnol Bioeng. 1974 Feb;16(2):159-68
4817138
J Electroanal Chem (Lausanne). 2008 Jan 15;612(2):208-218
20445818
Biosens Bioelectron. 2007 Oct 31;23(3):355-61
17560101
Biochem J. 1987 Jun 1;244(2):351-7
3663127
Biochemistry. 1982 Mar 16;21(6):1295-302
7041974
Science. 2006 Mar 17;311(5767):1570-4
16543451
Angew Chem Int Ed Engl. 2005 May 30;44(22):3419-22
15861452
Biosens Bioelectron. 2004 May 15;19(10):1301-7
15046763
J Biol Chem. 1970 Jan 10;245(1):198-204
5460798
Biosens Bioelectron. 2006 Oct 15;22(4):461-72
16797958
Biochemistry. 1980 Jul 8;19(14):3131-7
6996699
J Am Chem Soc. 2006 May 10;128(18):6014-5
16669652
Bioelectrochemistry. 2004 Jun;63(1-2):207-15
15110274
Trends Biotechnol. 2005 Aug;23(8):420-8
15950302
Mini Rev Med Chem. 2005 Mar;5(3):231-9
15777257
Biosens Bioelectron. 2005 Aug 15;21(2):346-53
16023962
Biotechnol Bioeng. 1987 Oct 20;30(6):724-35
18581491
Anal Chem. 2005 May 15;77(10):3267-73
15889918
J Biol Chem. 1986 Feb 25;261(6):2567-74
3081495
J Biol Chem. 1962 Oct;237:3027-32
13945795
J Biol Chem. 1969 Jul 10;244(13):3625-34
5794229
J Biol Chem. 1964 Nov;239:3927-34
14257628