Trigonal bipyramidal magnetic molecules based on [Mo(III)(CN)(6)](3-).
The trigonal bipyramidal molecules [M(tmphen)(2)](3)[Mo(CN)(6)](2).(solvent) (M = Co, Ni; tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) based on the [Mo(III)(CN)(6)](3-) unit were prepared by loss of a cyanide ligand from [Mo(III)(CN)(7)](4-) and found to exhibit ferromagnetic interactions between the M(II) and Mo(III) centers.
Wang
Xin-Yi
XY
Department of Chemistry, Texas A&M University, College Station, Texas 77840, USA.
Hilfiger
Matthew G
MG
Prosvirin
Andrey
A
Dunbar
Kim R
KR
D008024:Ligands; D008280:Magnetics; D008958:Models, Molecular; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; D008982:Molybdenum