title: The synthesis, X-ray crystal structure and optical properties of novel 1-ferrocenyl-2-(3-phenyl-1H-1,2,4-triazol-5-ylthio)ethanone derivatives.
abstract: A series of novel 1-ferrocenyl-2-(3-phenyl-1H-1,2,4-triazol-5-ylthio)ethanone derivatives was synthesized by the reaction of 3-substituted-1H-1,2,4-triazole-5-thiol and chloroacetyl ferrocene in the presence of sodium hydride and potassium iodide at reflux. The structures of the new compounds were determined by IR and (1)H NMR spectroscopy and HRMS. The structure of compound 5c was established by X-ray crystallography. UV-vis absorption and fluorescence spectra were recorded in ethanol and dichloromethane. The results showed that compounds 5a-g display similar absorptions ranging from 300 to 500nm and maximal emission bands are about 566nm. The intensity of fluorescence and maximal emission bands are dependent on the groups bonded to triazole rings.
authors.affiliation: Institute of Organic Chemistry, School of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, PR China.
authors.forename: Wei-Yong
authors.initials: WY
authors.lastname: Liu
authors.forename: Yong-Sheng
authors.initials: YS
authors.lastname: Xie
authors.forename: Bao-Xiang
authors.initials: BX
authors.lastname: Zhao
authors.forename: Song
authors.initials: S
authors.lastname: Lian
authors.forename: Hong-Shui
authors.initials: HS
authors.lastname: Lv
authors.forename: Zhong-Liang
authors.initials: ZL
authors.lastname: Gong
authors.forename: Dong-Soo
authors.initials: DS
authors.lastname: Shin
mesh_terms: D018360:Crystallography, X-Ray; D005296:Ferrous Compounds / Q000737:chemistry*; D000075163:Metallocenes; D008958:Models, Molecular; D015394:Molecular Structure; D013057:Spectrum Analysis / Q000379:methods; D014230:Triazoles / Q000138:chemical synthesis* / Q000737:chemistry*
chemical_list: D005296:Ferrous Compounds; D000075163:Metallocenes; D014230:Triazoles; C045575:1,2,4-triazole; C004998:ferrocene