title: Specific derivatization of lysozyme in aqueous solution with Re(CO)3(H2O)3(+).
abstract: The reaction of Re(CO)(3)(H(2)O)(3)(+) with hen egg lysozyme in aqueous solution results in a single covalent adduct; single crystal X-ray diffraction shows that the rhenium tricarbonyl cation binds to His15 in two significantly populated rotamer conformations.
authors.affiliation: Department of Chemistry, University of Akron, Akron, OH 44325-3601, USA.
authors.forename: Sarah L
authors.initials: SL
authors.lastname: Binkley
authors.forename: Christopher J
authors.initials: CJ
authors.lastname: Ziegler
authors.forename: Richard S
authors.initials: RS
authors.lastname: Herrick
authors.forename: Roger S
authors.initials: RS
authors.lastname: Rowlett
mesh_terms: D000818:Animals; D002412:Cations / Q000737:chemistry / Q000378:metabolism; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D008968:Molecular Conformation; D009113:Muramidase / Q000737:chemistry / Q000378:metabolism*; D009942:Organometallic Compounds / Q000737:chemistry / Q000378:metabolism*; D011485:Protein Binding; D011487:Protein Conformation; D019275:Radiopharmaceuticals / Q000737:chemistry / Q000378:metabolism*; D012211:Rhenium / Q000737:chemistry / Q000378:metabolism*
chemical_list: D002412:Cations; D009942:Organometallic Compounds; D019275:Radiopharmaceuticals; D012211:Rhenium; C421864:hen egg lysozyme; D009113:Muramidase
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