title: Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction.
abstract: This study describes a heteroligated, hemilabile Pt(II)-P,S tweezer coordination complex that combines a chiral Jacobsen-Katsuki Mn(III)-salen epoxidation catalyst with an amidopyridine receptor, which leads to an inversion of the major epoxide product compared to catalysts without a recognition group.
authors.affiliation: Department of Chemistry and the International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA.
authors.forename: Pirmin A
authors.initials: PA
authors.lastname: Ulmann
authors.forename: Adam B
authors.initials: AB
authors.lastname: Braunschweig
authors.forename: One-Sun
authors.initials: OS
authors.lastname: Lee
authors.forename: Michael J
authors.initials: MJ
authors.lastname: Wiester
authors.forename: George C
authors.initials: GC
authors.lastname: Schatz
authors.forename: Chad A
authors.initials: CA
authors.lastname: Mirkin
mesh_terms: D002384:Catalysis; D005029:Ethylenediamines / Q000737:chemistry; D008024:Ligands; D046911:Macromolecular Substances / Q000138:chemical synthesis / Q000737:chemistry; D008345:Manganese / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010984:Platinum / Q000737:chemistry; D011725:Pyridines / Q000737:chemistry*
chemical_list: D005029:Ethylenediamines; D008024:Ligands; D046911:Macromolecular Substances; D009942:Organometallic Compounds; D011725:Pyridines; D008345:Manganese; D010984:Platinum; C011452:disalicylaldehyde ethylenediamine
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