Polyoxometalate-supported Pd nanoparticles as efficient catalysts for the direct synthesis of hydrogen peroxide in the absence of acid or halide promoters.
A Keggin-type polyoxometalate (Cs(1.5)H(1.5)PW(12)O(40))-supported Pd catalyst is efficient for the direct synthesis of H(2)O(2) from H(2) and O(2) in the absence of any acid or halide additives under atmospheric pressure.
Sun
Miao
M
State Key Laboratory of Physical Chemistry of Solid Surfaces, Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Zhang
Jizhe
J
Zhang
Qinghong
Q
Wang
Ye
Y
Wan
Huilin
H
D002384:Catalysis; D006861:Hydrogen Peroxide / Q000138:chemical synthesis* / Q000737:chemistry; D053768:Metal Nanoparticles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
D006861:Hydrogen Peroxide; D009942:Organometallic Compounds; D010165:Palladium; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates