High yield C-derivatization of weakly coordinating carborane anions.
Unlike the "parent" carborane anion CHB(11)H(11)(-), halogenated carborane anions such as CHB(11)H(5)Br(6)(-) can be readily C-functionalized in high yield and purity, enhancing their utility as weakly coordinating anions.
Nava
Matthew J
MJ
Center for S and P Block Chemistry, Department of Chemistry, University of California, Riverside, California 92651, USA.
Reed
Christopher A
CA
D000838:Anions / Q000737:chemistry; D001880:Boranes / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D000838:Anions; D001880:Boranes; D009942:Organometallic Compounds
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