Rhodium-catalyzed annulation of ynamides with bifunctional arylboron reagents.
Annulation of ynamides with arylboronic acids or esters containing an electrophilic functional group at the ortho-position proceeds under the action of rhodium catalysis to generate 2-amidoindenols or 2-amidoindenes, usually with good regioselectivity.
Gourdet
Benoit
B
School of Chemistry, University of Edinburgh, The King's Buildings, West Mains Road, Edinburgh EH9 3JJ, UK.
Rudkin
Mairi E
ME
Lam
Hon Wai
HW
D000480:Alkynes / Q000737:chemistry*; D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D004952:Esters; D007192:Indenes / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D012238:Rhodium / Q000737:chemistry*
D000480:Alkynes; D001897:Boronic Acids; D004952:Esters; D007192:Indenes; D012238:Rhodium