Unprecedented cubane-type silver cluster with a novel phosphinite functionalized N-heterocyclic carbene ligand.
A novel heterodifunctional phosphinite imidazolium salt was synthesized and reacted with Ag(I) to afford an unusual tetrasilver cubane-type cluster with two P-NHC ligands bridging between the Ag(I) centres of opposite Ag(2)I(2) faces.
Raynal
Matthieu
M
Laboratoire de Chimie de Coordination, Institut de Chimie, UMR 7177 CNRS, Université de Strasbourg, 4 rue Blaise Pascal, F-67070, Strasbourg Cedex, France.
Liu
Xianghao
X
Pattacini
Roberto
R
Vallée
Christophe
C
Olivier-Bourbigou
Hélène
H
Braunstein
Pierre
P
D018360:Crystallography, X-Ray; D006571:Heterocyclic Compounds / Q000737:chemistry*; D007093:Imidazoles / Q000138:chemical synthesis / Q000737:chemistry; D008024:Ligands; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010720:Phosphines / Q000138:chemical synthesis / Q000737:chemistry*; D012492:Salts / Q000138:chemical synthesis / Q000737:chemistry; D012834:Silver / Q000737:chemistry*; D013237:Stereoisomerism
D006571:Heterocyclic Compounds; D007093:Imidazoles; D008024:Ligands; D009942:Organometallic Compounds; D010720:Phosphines; D012492:Salts; C030011:carbene; D012834:Silver; D008697:Methane