title: Trigonal bipyramidal magnetic molecules based on [Mo(III)(CN)(6)](3-).
abstract: The trigonal bipyramidal molecules [M(tmphen)(2)](3)[Mo(CN)(6)](2).(solvent) (M = Co, Ni; tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) based on the [Mo(III)(CN)(6)](3-) unit were prepared by loss of a cyanide ligand from [Mo(III)(CN)(7)](4-) and found to exhibit ferromagnetic interactions between the M(II) and Mo(III) centers.
authors.affiliation: Department of Chemistry, Texas A&M University, College Station, Texas 77840, USA.
authors.forename: Xin-Yi
authors.initials: XY
authors.lastname: Wang
authors.forename: Matthew G
authors.initials: MG
authors.lastname: Hilfiger
authors.forename: Andrey
authors.initials: A
authors.lastname: Prosvirin
authors.forename: Kim R
authors.initials: KR
authors.lastname: Dunbar
mesh_terms: D008024:Ligands; D008280:Magnetics; D008958:Models, Molecular; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D008024:Ligands; D009942:Organometallic Compounds; D008982:Molybdenum