Liquid crystals of gold(I) N-heterocyclic carbene complexes.
Three types of Au(I) N-heterocyclic carbene (NHC) and imidazole (Im) complexes, namely [Au(NHC)Cl], [Au(NHC)(Im)][NO(3)], and [Au(NHC)(2)][NO(3)], with two-, three-, and four-N-long alkyl chains, respectively, were synthesized and their mesomorphic properties investigated. Only the [Au(NHC)(Im)][NO(3)] series of compounds, adopting an m-shaped conformation in the solid state, showed liquid crystalline properties. For the molecules with three alkyl chains in particular, the Coulombic and hydrogen bonding interactions between the cationic head core and anionic NO(3)(-), and the hydrophobic chain-chain interactions facilitate in sustaining the partially ordered motion, which is not observed for those with two and four arms. These complexes were employed for preparation of stable nanomaterials in organic solvents.
Huang
Roy T W
RT
Department of Chemistry, National Dong Hwa University, Shoufeng, Hualien 974, Taiwan.
Wang
W C
WC
Yang
R Y
RY
Lu
J T
JT
Lin
Ivan J B
IJ
D018360:Crystallography, X-Ray; D006046:Gold / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000737:chemistry*; D007093:Imidazoles / Q000737:chemistry; D050866:Liquid Crystals / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D050607:Organogold Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010316:Particle Size; D013237:Stereoisomerism
D006571:Heterocyclic Compounds; D007093:Imidazoles; D050607:Organogold Compounds; C030011:carbene; D006046:Gold; D008697:Methane