Abrupt spin transition around room temperature and light induced properties in Fe(II) complexes with N4O2 coordination sphere.
Mononuclear spin-crossover complex Fe(II)(L)(2) x CH(3)OH (1 x CH(3)OH) and its desolvated product 1 exhibit abrupt spin transitions around room temperature. 1 also shows a light induced excited spin state trapping (LIESST) effect and a light induced thermal hysteresis (LITH) phenomenon at low temperature.
Zhang
Li
L
Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing100871, PR China.
Xu
Guan-Cheng
GC
Xu
Hong-Bin
HB
Zhang
Teng
T
Wang
Zhe-Ming
ZM
Yuan
Mei
M
Gao
Song
S