Structure and magnetism of new lanthanide 6-wheel compounds utilizing triethanolamine as a stabilizing ligand.
The reaction of Ln(NO(3))(3).6H(2)O (Ln = Gd, Dy) with triethanolamine (teaH(3)) and triethylamine in MeOH gives two isostructural hexanuclear wheels of formula [Ln(6)(teaH)(6)(NO(3))(6)].8MeOH, the magnetic properties of which show slow magnetisation relaxation in the Dy case.
Langley
Stuart K
SK
School of Chemistry, Monash University, Clayton, Victoria 3800, Australia.
Moubaraki
Boujemaa
B
Forsyth
Craig M
CM
Gass
Ian A
IA
Murray
Keith S
KS
D004983:Ethanolamines / Q000737:chemistry*; D006860:Hydrogen Bonding; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008024:Ligands; D008280:Magnetics; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*
D004983:Ethanolamines; D028581:Lanthanoid Series Elements; D008024:Ligands; D009942:Organometallic Compounds