Acetate-controlled demetalation in multiiron polyoxometalates: a triiron cluster trapped between beta- and gamma-Keggin isomers.
Acetate-induced demetalation of a {gamma-SiW(10)Fe(2)}-based dimer affords an acetato/hydroxo-bridged triiron cluster stabilized by two isomerically distinct Keggin units.
Botar
Bogdan
B
Institut für Festkörperforschung, Forschungszentrum Jülich GmbH, D-52425, Jülich, Germany. b.botar@fz-juelich.de
Ellern
Arkady
A
Kögerler
Paul
P