Highly enantioselective hydroformylation of dihydrofurans catalyzed by hybrid phosphine-phosphonite rhodium complexes.
Unprecedented regio- and enantioselectivities (>91%) are reported for the Rh-catalyzed asymmetric hydroformylation of 2,3- and 2,5-dihydrofuran using tunable hybrid phosphine-phosphonite ligands.
Chikkali
Samir H
SH
Supramolecular and Homogeneous Catalysis, van't Hoff Institute For Molecular Science, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV, Amsterdam, The Netherlands.
Bellini
Rosalba
R
Berthon-Gelloz
Guillaume
G
van der Vlugt
Jarl Ivar
JI
de Bruin
Bas
B
Reek
Joost N H
JN