Aluminium-catalyzed intramolecular hydroamination of aminoalkenes.
A new aluminium complex bearing a dianionic phenylene-diamine based ligand has been synthesized and shown to catalyze the intramolecular hydroamination of various aminoalkenes.
Koller
Jürgen
J
Department of Chemistry, University of California, Berkeley, CA 94720, USA.
Bergman
Robert G
RG
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D000535:Aluminum / Q000737:chemistry*; D000586:Amination; D002384:Catalysis; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D000475:Alkenes; D009942:Organometallic Compounds; D000535:Aluminum