Heterotopic silver-NHC complexes: from coordination polymers to supramolecular assemblies.
New coordination polymers based on different combinations of silver atoms and pyridyl-substituted N-heterocyclic carbene moieties are described. The addition of Zn(ii) templates leads to Ag-Zn supramolecular assemblies via selective ZnN interactions; a process that can be reverted.
Rubio
Miguel
M
Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, 1018WV, Amsterdam, The Netherlands.
Siegler
Maxime A
MA
Spek
Anthony L
AL
Reek
Joost N H
JN
D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008968:Molecular Conformation; D011108:Polymers / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry
D056831:Coordination Complexes; D011108:Polymers; C030011:carbene; D012834:Silver; D015032:Zinc; D008697:Methane