title: Preparation and reactions of (beta-trifluoromethyl)vinyl sulfonium salt.
abstract: (Beta-trifluoromethyl)vinyl sulfonium salt as a novel three-carbon fluorinated building block was conveniently prepared from easily available (beta-trifluoromethyl)vinyl sulfide and diphenyl iodonium salt in excellent yield. This easily handled crystalline reagent displayed two types of useful transformation involving aziridination and vinylation to afford the corresponding trifluoromethylated compounds in excellent yields.
authors.affiliation: Department of Chemistry and Applied Chemistry, Saga University, Honjyo-machi 1, Saga 840-8502, Japan.
authors.forename: Ryoko
authors.initials: R
authors.lastname: Maeda
authors.forename: Kyoko
authors.initials: K
authors.lastname: Ooyama
authors.forename: Ryoko
authors.initials: R
authors.lastname: Anno
authors.forename: Masahiro
authors.initials: M
authors.lastname: Shiosaki
authors.forename: Takayuki
authors.initials: T
authors.lastname: Azema
authors.forename: Takeshi
authors.initials: T
authors.lastname: Hanamoto