Effects of precursor and sulfation on OMS-2 catalyst for oxidation of ethanol and acetaldehyde at low temperatures.
Volatile organic compounds (VOCs) emitted from many industrial processes and transportation activities are major organic pollutants in the atmosphere and toxic to human health. Octahedral molecular sieve (OMS-2) catalysts with different precursors and sulfate-acidified OMS-2 catalysts were synthesized using refluxing methods. The catalysts were investigated on complete oxidation of ethanol and acetaldehyde, and both demonstrated good reactivity. However, acidification resulted in a decrease in activity. OMS-2 catalyst using MnSO(4) as precursor exhibited the best catalytic performance and, thus, was selected for catalyst deactivation by sulfur dioxide. The results of this study suggested that the Mn-O bond of OMS-2 catalysts was the main determinant of the catalytic activity toward oxygenated VOC oxidation and weaker acid sites benefited higher acetaldehyde selectivity. Catalyst deactivation resulted from a strong but slow chemical interaction between the Mn-O bond and sulfur dioxide, probably forming manganese sulfate.
Wang
Renhu
R
Department of Environmental Science and Engineering, Tsinghua University, Beijing 100084, China.
Li
Junhua
J
D000079:Acetaldehyde / Q000737:chemistry*; D002384:Catalysis; D003080:Cold Temperature; D000431:Ethanol / Q000737:chemistry*; D010084:Oxidation-Reduction; D013431:Sulfates / Q000737:chemistry*; D055549:Volatile Organic Compounds / Q000737:chemistry
D013431:Sulfates; D055549:Volatile Organic Compounds; D000431:Ethanol; D000079:Acetaldehyde