Vibrational spectroscopic investigations of some Hofmann-T(d)-type complexes: Ni(2-(1-cyclohexenyl)ethylamine)(2)M(CN)(4) (M=Cd or Hg).
New Hofmann-T(d)- type complexes in the form of Ni(CyHEA)(2)M(CN)(4) (where CyHEA=2-(1-cyclohexenyl)ethylamine and M=Cd or Hg) have been prepared in powder form and their infrared (4000-100cm(-1)) and Raman (2800-1650cm(-1)) spectra have been reported. The thermal behaviour of these complexes has been investigated by differential thermal analysis (DTA) and thermo-gravimetric analysis (TGA). The results suggest that these compounds are similar in structure to the Hofmann-T(d)-type complexes.
Izgi
Tekin
T
Department of Physics, Arts and Science Faculty, Inonu University, Malatya 44069, Turkey. tizgi@inonu.edu.tr
Parlak
Cemal
C
Senyel
Mustafa
M
D002104:Cadmium / Q000737:chemistry*; D003510:Cyclohexanes / Q000737:chemistry*; D005021:Ethylamines / Q000737:chemistry*; D008628:Mercury / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry*; D013055:Spectrophotometry, Infrared / Q000379:methods; D013059:Spectrum Analysis, Raman / Q000379:methods; D014732:Vibration
C524450:2-(1-cyclohexenyl)ethylamine; D003510:Cyclohexanes; D005021:Ethylamines; D002104:Cadmium; D009532:Nickel; D008628:Mercury