Asymmetric synthesis of allylsilanes by the borylation of lithiated carbamates: formal total synthesis of (-)-decarestrictine D.
Binanzer
Michael
M
School of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS UK.
Fang
Guang Yu
GY
Aggarwal
Varinder K
VK
D000475:Alkenes / Q000138:chemical synthesis*; D001895:Boron / Q000737:chemistry*; D002219:Carbamates / Q000737:chemistry*; D004852:Epoxy Compounds / Q000737:chemistry; D006900:Hydroxylation; D007783:Lactones / Q000138:chemical synthesis*; D018020:Lithium Compounds / Q000737:chemistry*; D015394:Molecular Structure; D012821:Silanes / Q000138:chemical synthesis*; D013237:Stereoisomerism
D000475:Alkenes; D002219:Carbamates; D004852:Epoxy Compounds; D007783:Lactones; D018020:Lithium Compounds; D012821:Silanes; C511847:allylsilane; C073577:decarestrictine D; D001895:Boron