Supramolecular copper(I) halide complexes of O2S2X (X = S, O and NH) macrocycles exhibiting dinuclear, 1D- and 2D-coordination polymeric structures.
The effect of varying donor X in otherwise structurally similar O(2)S(2)X-macrocycles (L(1): X = S, L(2): X = O and L(3): X = NH) on the corresponding assembly reactions with Cu(I) halides has been demonstrated to yield three supramolecular complexes with different architectures: L(1) resulted in a discrete dimeric complex (1), while L(2) and L(3) gave respectively 1D (2) and 2D (3) coordination polymers; the solid state photoluminescence of 3 is also described.
Jo
Minhye
M
Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University, Jinju, 660-701, S. Korea.
Seo
Joobeom
J
Lindoy
Leonard F
LF
Sung Lee
Shim
S
D000588:Amines / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D008024:Ligands; D047028:Macrocyclic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D046911:Macromolecular Substances / Q000138:chemical synthesis / Q000737:chemistry; D015394:Molecular Structure; D010100:Oxygen / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry
D000588:Amines; D008024:Ligands; D047028:Macrocyclic Compounds; D046911:Macromolecular Substances; D011108:Polymers; D013455:Sulfur; D003300:Copper; D010100:Oxygen