Inversion of product selectivity in an enzyme-inspired metallosupramolecular tweezer catalyzed epoxidation reaction.
This study describes a heteroligated, hemilabile Pt(II)-P,S tweezer coordination complex that combines a chiral Jacobsen-Katsuki Mn(III)-salen epoxidation catalyst with an amidopyridine receptor, which leads to an inversion of the major epoxide product compared to catalysts without a recognition group.
Ulmann
Pirmin A
PA
Department of Chemistry and the International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA.
Braunschweig
Adam B
AB
Lee
One-Sun
OS
Wiester
Michael J
MJ
Schatz
George C
GC
Mirkin
Chad A
CA
D002384:Catalysis; D005029:Ethylenediamines / Q000737:chemistry; D008024:Ligands; D046911:Macromolecular Substances / Q000138:chemical synthesis / Q000737:chemistry; D008345:Manganese / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010984:Platinum / Q000737:chemistry; D011725:Pyridines / Q000737:chemistry*
D005029:Ethylenediamines; D008024:Ligands; D046911:Macromolecular Substances; D009942:Organometallic Compounds; D011725:Pyridines; D008345:Manganese; D010984:Platinum; C011452:disalicylaldehyde ethylenediamine
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