Cationic Pd(II)/bipyridine-catalyzed conjugate addition of arylboronic acids to beta,beta-disubstituted enones: construction of quaternary carbon centers.
Cationic Pd(II)-catalyzed addition of arylboronic acids to beta,beta-disubstituted enones in high yields was developed. This method provided an efficient method for the construction of quaternary carbon centers, and only 0.5 mol % of Pd(II) catalyst was needed.
Lin
Shaohui
S
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China.
Lu
Xiyan
X