title: Self-assembled thermally highly stable 1-dimensional proton arrays.
abstract: From a red proton complex of aldehyde derivatives of polyaromatic hydrocarbon with strong intermolecular hydrogen bonding, which are novel examples of intermolecular proton-bonded aldehydes of polyaromatic hydrocarbons, we find one-dimensional proton arrangement. The complex formed as 9-antraldehyde (Ant-CHO) reacts with HAuCl(4) to form [(Ant-CHO)(2)H](+)[AuCl(4)](-) under dry condition, which are confirmed by single-crystal structure determination and infrared spectra analysis at varying temperatures. Since the compounds of distinctively hydrophobic nature are soluble only in limited organic polar solvents, the strong hydrogen bonds are clearly observed from both the electron density of X-ray analysis and the characteristic signature of the IR frequency. The proton complex units have the typical O-H(+)-O distance of the strong hydrogen bond similar to the Zundel-like cationic hydrogen bond (where two O atoms share a proton in the midpoint of the short O-O distance of approximately 2.4 A). The chemical shift of 20.18 ppm originated from the protons of the O-H(+)-O hydrogen bonds would be the largest downfield shifted value among those of protons in O-H...O bonds reported in various solid materials, indicating very short strong hydrogen bonds for the O-H(+)-O. The complexes are stabilized with the pi-pi intermolecular interactions of the polyaromatic hydrocarbon ligands, resulting in layered structures. The spectral signatures around approximately 900, approximately 1200, and approximately 1700 cm(-1) for the Zundel-like proton bond are clearly characterized.
authors.affiliation: Department of Chemistry, Center for Superfunctional Materials, Pohang University of Science and Technology, Pohang 790-784, Korea.
authors.forename: In-Chul
authors.initials: IC
authors.lastname: Hwang
authors.forename: Sung Woo
authors.initials: SW
authors.lastname: Heo
authors.forename: N Jiten
authors.initials: NJ
authors.lastname: Singh
authors.forename: Jung Woo
authors.initials: JW
authors.lastname: Lee
authors.forename: Young
authors.initials: Y
authors.lastname: Chun
authors.forename: Seung Bin
authors.initials: SB
authors.lastname: Baek
authors.forename: Kyeong Sik
authors.initials: KS
authors.lastname: Jin
authors.forename: Moonhor
authors.initials: M
authors.lastname: Ree
authors.forename: Hee Cheon
authors.initials: HC
authors.lastname: Lee
authors.forename: Seung Bin
authors.initials: SB
authors.lastname: Kim
authors.forename: Kwang S
authors.initials: KS
authors.lastname: Kim