title: Synthesis and reactivity of ferrocenyl functionalized Sn/S cages.
abstract: Depending on the solvent used, the mono-stannylated FcSnCl(3) (1) reacts with Na(2)S to give ionic [Na(6)(Me(2)CO)(4)(OH(2))(6)] [(FcSn)(3)S(6)](2) (2), with a yet unprecedented thiostannate anion, or the adamantane-type Sn/S-cluster [(FcSn)(4)S(6)] (3). Complex 2 reacts readily with [Ni(acac)(2)], yielding the mixed-metallic complex [{Na(thf)(3.5)}(2){(FcSn)(8)Ni(3)S(16)}] x 2 THF (4 x 2 THF); the structures of 1-4 are discussed as well as Mössbauer spectra.
authors.affiliation: Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse, 35043 Marburg, Germany.
authors.forename: Christopher
authors.initials: C
authors.lastname: Pöhlker
authors.forename: Inga
authors.initials: I
authors.lastname: Schellenberg
authors.forename: Rainer
authors.initials: R
authors.lastname: Pöttgen
authors.forename: Stefanie
authors.initials: S
authors.lastname: Dehnen