Catalyst-free aziridination and unexpected homologation of aziridines from imines.
Aziridination and unpredicted homologation reaction of N-sulfonylimines were achieved easily with a very simple, rapid and mild procedure through the use of diazomethane without the presence of any catalyst. The method represents an attractive alternative to metal-catalyzed processes.
Branco
Paula Sério
PS
Chemistry Department, REQUIMTE, Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal. psb@dq.fct.unl.pt
Raje
Vivek Prabhakar
VP
Dourado
Jorge
J
Gordo
Joana
J
D001388:Aziridines / Q000737:chemistry*; D002384:Catalysis; D007097:Imines / Q000737:chemistry*; D007700:Kinetics
D001388:Aziridines; D007097:Imines; C033132:aziridine