Rhodium-catalyzed oxidative coupling of aromatic imines with internal alkynes via regioselective C-H bond cleavage.
The rhodium-catalyzed oxidative coupling of aromatic imines with alkynes effectively proceeds via regioselective C-H bond cleavage to produce indenone imine and isoquinoline derivatives.
Fukutani
Tatsuya
T
Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.
Umeda
Nobuyoshi
N
Hirano
Koji
K
Satoh
Tetsuya
T
Miura
Masahiro
M
D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D007097:Imines / Q000138:chemical synthesis / Q000737:chemistry*; D007192:Indenes / Q000138:chemical synthesis / Q000737:chemistry; D007546:Isoquinolines / Q000138:chemical synthesis / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
D000480:Alkynes; D007097:Imines; D007192:Indenes; D007546:Isoquinolines; D012238:Rhodium