Dimeric nanocapsule induces conformational change.
An induced cis-trans-trans (rctt) chair to cone structural rearrangement is forced by the addition of a pentacoordinate zinc(II) complex, overcoming thermodynamic and kinetic factors to produce the first phenyl-substituted zinc dimeric nanocapsule.
Maerz
Andrew K
AK
Department of Chemistry, University of Missouri-Columbia, 601 S, College Avenue, Columbia, MO 65211, USA.
Thomas
Haunani M
HM
Power
Nicholas P
NP
Deakyne
Carol A
CA
Atwood
Jerry L
JL
D047250:Calixarenes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D019281:Dimerization; D008958:Models, Molecular; D008968:Molecular Conformation; D053769:Nanocapsules / Q000737:chemistry*; D011748:Pyrogallol / Q000031:analogs & derivatives* / Q000737:chemistry; D013237:Stereoisomerism; D017967:Zinc Compounds / Q000737:chemistry*
D053769:Nanocapsules; D017967:Zinc Compounds; C522570:pyrogallol(4)arene; D011748:Pyrogallol; D047250:Calixarenes