Highly efficient catalytic dehydrative S-allylation of thiols and thioic S-acids.
A SH-selective allylation method using [CpRu(2-quinolinecarboxylato)(eta(3)-C(3)H(5))]PF(6) has been realized in various solvents including aqueous media to give allyl sulfides and allyl S-thioates, demonstrating the potential applicability to lipopeptide chemistry.
Tanaka
Shinji
S
Research Center for Materials Science and the Department of Chemistry, Nagoya University, Chikusa, Nagoya 464-8602, Japan.
Pradhan
Prasun Kanti
PK
Maegawa
Yusuke
Y
Kitamura
Masato
M
D000498:Allyl Compounds / Q000737:chemistry*; D002384:Catalysis; D012428:Ruthenium / Q000737:chemistry; D012997:Solvents / Q000737:chemistry; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D013440:Sulfides / Q000737:chemistry*
D000498:Allyl Compounds; D012997:Solvents; D013438:Sulfhydryl Compounds; D013440:Sulfides; C038491:allyl sulfide; D012428:Ruthenium