In situ formation of N,O-bidentate ligand via the hydrogen bond for highly efficient Suzuki reaction of aryl chlorides.
A highly efficient protocol for the Pd(OAc)2-catalyzed aerobic Suzuki reaction of aryl chlorides is reported, which is proposed to be promoted by the N,O-bidentate ligand formed in situ via the hydrogen bond of solvents.
Yang
Weibo
W
State Key Laboratory of Fine Chemicals, Dalian University of Technology, Zhongshan Road 158, 116012, Dalian, China.
Liu
Chun
C
Qiu
Jieshan
J
D001897:Boronic Acids / Q000737:chemistry; D002712:Chlorides / Q000737:chemistry*; D006860:Hydrogen Bonding; D008024:Ligands; D009584:Nitrogen / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry; D012997:Solvents / Q000737:chemistry
D001897:Boronic Acids; D002712:Chlorides; D008024:Ligands; D012997:Solvents; D010165:Palladium; D009584:Nitrogen; D010100:Oxygen