Palladium nanoparticle catalyzed Hiyama coupling reaction of benzyl halides.
An efficient Hiyama coupling reaction between benzylic halide and aryltrialkoxysilane using Pd nanoparticles has been developed. This procedure accommodates various functional groups to yield a diverse range of diarylmethanes which are ubiquitous units of natural products and pharmaceuticals.
Srimani
Dipankar
D
Department of Organic Chemistry, Indian Association for the Cultivation of Science, Kolkata 700032.
Bej
Ansuman
A
Sarkar
Amitabha
A
D001593:Benzyl Compounds / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D053758:Nanoparticles / Q000737:chemistry*; D017646:Organosilicon Compounds / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*
D001593:Benzyl Compounds; D017646:Organosilicon Compounds; C410706:phenyltrimethoxysilane; D010165:Palladium; C021292:benzyl chloride; C038682:benzyl bromide