title: Iron-catalyzed, directed oxidative arylation of olefins with organozinc and Grignard reagents.
abstract: Chelation-controlled arylation of olefins with organozinc or Grignard reagents proceeds in the presence of an iron catalyst, under mild conditions and typically without the need of external ligands, to afford substituted olefins in high yield and with complete regio- and stereocontrol.
authors.affiliation: Department of Chemistry, School of Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
authors.forename: Laurean
authors.initials: L
authors.lastname: Ilies
authors.forename: Jun
authors.initials: J
authors.lastname: Okabe
authors.forename: Naohiko
authors.initials: N
authors.lastname: Yoshikai
authors.forename: Eiichi
authors.initials: E
authors.lastname: Nakamura
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis / Q000737:chemistry*; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D007202:Indicators and Reagents; D007501:Iron / Q000737:chemistry*; D008274:Magnesium / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013237:Stereoisomerism; D015032:Zinc / Q000737:chemistry
chemical_list: D000475:Alkenes; D007202:Indicators and Reagents; D007501:Iron; D008274:Magnesium; D015032:Zinc