A fluorinated dendritic TsDPEN-Ru(II) catalyst for asymmetric transfer hydrogenation of prochiral ketones in aqueous media.
The fluorinated dendritic chiral mono-N-tosylated 1,2-diphenylethlenediamine, FTsDPEN, has been synthesized and applied in the ruthenium(ii) complex-catalyzed asymmetric transfer hydrogenation of prochiral ketones in aqueous media.
Wang
Weiwei
W
Department of Chemistry, Fudan University, Shanghai 200433, PR China.
Wang
Quanrui
Q
D000438:Alcohols / Q000138:chemical synthesis / Q000737:chemistry; D002384:Catalysis; D050091:Dendrimers / Q000737:chemistry*; D005029:Ethylenediamines / Q000737:chemistry*; D005461:Fluorine / Q000737:chemistry*; D006865:Hydrogenation; D007659:Ketones / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D012996:Solutions; D013237:Stereoisomerism; D014050:Toluene / Q000031:analogs & derivatives* / Q000737:chemistry; D014867:Water / Q000737:chemistry
D000438:Alcohols; D050091:Dendrimers; D005029:Ethylenediamines; D007659:Ketones; C526626:N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine; D009942:Organometallic Compounds; D012996:Solutions; D014867:Water; D005461:Fluorine; D014050:Toluene; D012428:Ruthenium