CuH-catalyzed enantioselective 1,2-reductions of alpha,beta-unsaturated ketones.
The first study on a general technology for arriving at valued nonracemic allylic alcohols using asymmetric ligand-accelerated catalysis by copper hydride is described.
Moser
Ralph
R
Department of Chemistry and Biochemistry, University of California, Santa Barbara, California 93106, USA.
Bosković
Zarko V
ZV
Crowe
Christopher S
CS
Lipshutz
Bruce H
BH
D000438:Alcohols / Q000737:chemistry; D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D010084:Oxidation-Reduction; D013237:Stereoisomerism; D013379:Substrate Specificity
D000438:Alcohols; D056831:Coordination Complexes; D007659:Ketones