Photochromism of dithienylethene single crystals having anthracene substituents.
Three dithienylethene derivatives having anthracene substituents (connected at 1-, 2- and 9-positions) were prepared. Although these three derivatives exhibit photochromic reactivity in solution, only one of the derivatives (connected at 2-position) undergoes the photochromic reaction in the crystalline phase. X-Ray crystallographic analysis and DFT calculation revealed that conformation of the anthracene substituents plays an important role in the crystalline photochromism.
Ohara
Hiroki
H
Department of Chemistry and Research Center for Smart Molecules, Rikkyo University, 3-34-1 Nishi-Ikebukuro, Toshima-ku, Tokyo 171-8501, Japan.
Morimoto
Masakazu
M
Irie
Masahiro
M