Synthesis and theoretical studies of gallium complexes back-shielded by a cage-shaped framework of tris(m-oxybenzyl)arene.
Cage-shaped gallium complexes with a back-shielding framework of tris(m-oxybenzyl)arene were synthesized, their bottom arene rings tuned their characteristic Lewis acidity, which was supported by theoretical calculation as well as catalytic application in a hetero Diels-Alder reaction.
Nakajima
Hideto
H
Department of Applied Chemistry and Center for Atomic and Molecular Technologies, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
Yasuda
Makoto
M
Chiba
Kouji
K
Baba
Akio
A