Cubic octanuclear Ni(II) clusters in highly porous polypyrazolyl-based materials.
Two highly porous coordination polymers, containing rare octanuclear hydroxo-nickel clusters and long bis-pyrazolyl spacers, are shown to possess, after mild thermal treatment, lattice cavities up to 72% of the total crystal volume.
Masciocchi
Norberto
N
Dipartimento di Scienze Chimiche e Ambientali, Università dell'Insubria, via Valleggio 11, I-22100 Como, Italy.
Galli
Simona
S
Colombo
Valentina
V
Maspero
Angelo
A
Palmisano
Giovanni
G
Seyyedi
Behnam
B
Lamberti
Carlo
C
Bordiga
Silvia
S