Synthesis of bimetallic uranium and neptunium complexes of a binucleating macrocycle and determination of the solid-state structure by magnetic analysis.
Syntheses of the bimetallic uranium(III) and neptunium(III) complexes [(UI)(2)(L)], [(NpI)(2)(L)], and [{U(BH(4))}(2)(L)] of the Schiff-base pyrrole macrocycles L are described. In the absence of single-crystal structural data, fitting of the variable-temperature solid-state magnetic data allows the prediction of polymeric structures for these compounds in the solid state.
Arnold
Polly L
PL
School of Chemistry, University of Edinburgh, Edinburgh EH9 3JJ, UK. polly.arnold@ed.ac.uk
Potter
Natalie A
NA
Magnani
Nicola
N
Apostolidis
Christos
C
Griveau
Jean-Christophe
JC
Colineau
Eric
E
Morgenstern
Alfred
A
Caciuffo
Roberto
R
Love
Jason B
JB
D008024:Ligands; D047028:Macrocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D008280:Magnetics; D015394:Molecular Structure; D009405:Neptunium / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013696:Temperature; D014501:Uranium / Q000737:chemistry*
D008024:Ligands; D047028:Macrocyclic Compounds; D009942:Organometallic Compounds; D014501:Uranium; D009405:Neptunium