Microporous polyphenylenes with tunable pore size for hydrogen storage.
A series of highly porous polymers with similar BET surface areas of higher than 1000 m(2) g(-1) but tunable pore ranging from 0.7 nm to 0.9 nm were synthesized through facile ethynyl trimerization reaction to demonstrate the surface property-hydrogen adsorption relationship.
Yuan
Shengwen
S
Chemical Sciences & Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue, Argonne, IL 60439, USA.
Dorney
Brian
B
White
Desiree
D
Kirklin
Scott
S
Zapol
Peter
P
Yu
Luping
L
Liu
Di-Jia
DJ
D000327:Adsorption; D006859:Hydrogen / Q000737:chemistry*; D015394:Molecular Structure; D010316:Particle Size; D011108:Polymers / Q000737:chemistry*; D016062:Porosity; D013499:Surface Properties
D011108:Polymers; D006859:Hydrogen; C041325:polyphenylene sulfide