title: Synthesis of bimetallic uranium and neptunium complexes of a binucleating macrocycle and determination of the solid-state structure by magnetic analysis.
abstract: Syntheses of the bimetallic uranium(III) and neptunium(III) complexes [(UI)(2)(L)], [(NpI)(2)(L)], and [{U(BH(4))}(2)(L)] of the Schiff-base pyrrole macrocycles L are described. In the absence of single-crystal structural data, fitting of the variable-temperature solid-state magnetic data allows the prediction of polymeric structures for these compounds in the solid state.
authors.affiliation: School of Chemistry, University of Edinburgh, Edinburgh EH9 3JJ, UK. polly.arnold@ed.ac.uk
authors.forename: Polly L
authors.initials: PL
authors.lastname: Arnold
authors.forename: Natalie A
authors.initials: NA
authors.lastname: Potter
authors.forename: Nicola
authors.initials: N
authors.lastname: Magnani
authors.forename: Christos
authors.initials: C
authors.lastname: Apostolidis
authors.forename: Jean-Christophe
authors.initials: JC
authors.lastname: Griveau
authors.forename: Eric
authors.initials: E
authors.lastname: Colineau
authors.forename: Alfred
authors.initials: A
authors.lastname: Morgenstern
authors.forename: Roberto
authors.initials: R
authors.lastname: Caciuffo
authors.forename: Jason B
authors.initials: JB
authors.lastname: Love
mesh_terms: D008024:Ligands; D047028:Macrocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D008280:Magnetics; D015394:Molecular Structure; D009405:Neptunium / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013696:Temperature; D014501:Uranium / Q000737:chemistry*
chemical_list: D008024:Ligands; D047028:Macrocyclic Compounds; D009942:Organometallic Compounds; D014501:Uranium; D009405:Neptunium