title: Upcycling: converting waste plastics into paramagnetic, conducting, solid, pure carbon microspheres.
abstract: The recent tremendous increase in the volume of waste plastics (WP) will have a harmful environmental impact on the health of living beings. Hundreds of years are required to degrade WP in atmospheric conditions. Hence, in coming years, in addition to traditional recycling services, innovative "upcycling" processes are necessary. This article presents an environmentally benign, solvent-free autogenic process that converts various WP [low density polyethylene (LDPE), high density polyethylene (HDPE), polyethylene terephthalate (PET), polystyrene (PS), or their mixtures] into carbon microspheres (CMSs), an industrially significant, value-added product. The thermal dissociation of these individual or mixed WP in a closed reactor under autogenic pressure ( approximately 1000 psi) produced dry, pure powder of CMSs. In this paper, the optimization of process parameters such as the effect of mixing of WP with other materials, and the role of reaction temperature and time are reported. Employing advanced analytical techniques, the atomic structure, composition, and morphology of as-obtained CMSs were analyzed. The room-temperature paramagnetism in CMSs prepared from waste LDPE, HDPE, and PS was further studied by electron paramagnetic resonance (EPR). The conducting and paramagnetic nature of CMSs holds promise for their potential applications in toners, printers, paints, batteries, lubricants, and tires.
authors.affiliation: Electrochemical Energy Storage Department, Chemical Sciences & Engineering Division, Argonne National Laboratory, Argonne, Illinois 60439, USA. pol@anl.gov
authors.forename: Vilas Ganpat
authors.initials: VG
authors.lastname: Pol
mesh_terms: D002244:Carbon / Q000737:chemistry*; D003247:Conservation of Natural Resources / Q000379:methods*; D004553:Electric Conductivity; D004578:Electron Spin Resonance Spectroscopy; D008280:Magnetics; D008855:Microscopy, Electron, Scanning; D008863:Microspheres; D053758:Nanoparticles / Q000737:chemistry; D010969:Plastics / Q000737:chemistry*; D020959:Polyethylene / Q000737:chemistry; D011312:Pressure; D013696:Temperature; D014866:Waste Products / Q000032:analysis*
chemical_list: D010969:Plastics; D014866:Waste Products; D002244:Carbon; D020959:Polyethylene