title: Sequential insertion of three different organometallics into a versatile building block containing a PNA backbone.
abstract: In the view of developing a synthetic route for the controlled insertion of distinct organometallic moieties into peptide nucleic acid (PNA) oligomers, a proof-of-principle study of the chemoselective insertion of three different organometallics into a building block containing both a PNA backbone and an alkyne side-chain is presented in this study.
authors.affiliation: Lehrstuhl für Anorganische Chemie I, Fakultät für Chemie und Biochemie, Ruhr-Universität Bochum, Gebäude NC 3 Nord, Universitätsstr. 150, 44801, Bochum, Germany.
authors.forename: Malay
authors.initials: M
authors.lastname: Patra
authors.forename: Gilles
authors.initials: G
authors.lastname: Gasser
authors.forename: Dmytro
authors.initials: D
authors.lastname: Bobukhov
authors.forename: Klaus
authors.initials: K
authors.lastname: Merz
authors.forename: Alexander V
authors.initials: AV
authors.lastname: Shtemenko
authors.forename: Nils
authors.initials: N
authors.lastname: Metzler-Nolte
mesh_terms: D000480:Alkynes / Q000737:chemistry; D018360:Crystallography, X-Ray; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D020135:Peptide Nucleic Acids / Q000737:chemistry*; D012211:Rhenium / Q000737:chemistry
chemical_list: D000480:Alkynes; D009942:Organometallic Compounds; D020135:Peptide Nucleic Acids; D012211:Rhenium