Intramolecular charge transfer in a trinuclear iron ene-triyne complex.
A trinuclear redox-active complex with an unprecedented ene-triyne backbone has been isolated and structurally characterized. The mono-oxidized mixed-valent species exhibits electronic delocalization necessary for molecular circuitry.
Hoffert
Wesley A
WA
Department of Chemistry, Colorado State University, Fort Collins, CO, USA.
Rappé
Anthony K
AK
Shores
Matthew P
MP