Ruthenium(0) nanoclusters supported on hydroxyapatite: highly active, reusable and green catalyst in the hydrogenation of aromatics under mild conditions with an unprecedented catalytic lifetime.
The preparation of ruthenium(0) nanoclusters supported on hydroxyapatite and their characterization by a combination of complementary techniques are described. The resultant ruthenium(0) nanoclusters provide high activity and reusability in the complete hydrogenation of aromatics under mild conditions (at 25 degrees C and with 42 psi initial H(2) pressure).
Zahmakiran
Mehmet
M
Department of Chemistry, Middle East Technical University, 06531 Ankara, Turkey.
Tonbul
Yalcin
Y
Ozkar
Saim
S