title: Glassy dynamics under superhigh pressure.
abstract: Nearly all glass-forming liquids feature, along with the structural alpha-relaxation process, a faster secondary process (beta relaxation), whose nature belongs to the great mysteries of glass physics. However, for some of these liquids, no well-pronounced secondary relaxation is observed. A prominent example is the archetypical glass-forming liquid glycerol. In the present work, by performing dielectric spectroscopy under superhigh pressures up to 6 GPa, we show that in glycerol a significant secondary relaxation peak appears in the dielectric loss at P>3 GPa. We identify this beta relaxation to be of Johari-Goldstein type and discuss its relation to the excess wing. We provide evidence for a smooth but significant increase in glass-transition temperature and fragility on increasing pressure.
authors.affiliation: General Physics Institute, Russian Academy of Sciences, Vavilov Street 38, Moscow 119991, Russia.
authors.forename: A A
authors.initials: AA
authors.lastname: Pronin
authors.forename: M V
authors.initials: MV
authors.lastname: Kondrin
authors.forename: A G
authors.initials: AG
authors.lastname: Lyapin
authors.forename: V V
authors.initials: VV
authors.lastname: Brazhkin
authors.forename: A A
authors.initials: AA
authors.lastname: Volkov
authors.forename: P
authors.initials: P
authors.lastname: Lunkenheimer
authors.forename: A
authors.initials: A
authors.lastname: Loidl