DABCO-functionalized metal-organic framework bearing a C2h-symmetric terphenyl dicarboxylate linker.
A Zn-MOF assembled from a new C(2h)-symmetric terphenyl dicarboxylate and DABCO was prepared and characterized by X-ray crystallography and gas sorption analysis: a preferential sorption of CO(2) over N(2) and H(2) was observed with an exceptionally high CO(2) adsorption enthalpy.
Gu
Ja-Min
JM
Department of Chemistry and Protein Research Center for Bio-Industry, Hankuk University of Foreign Studies, Yongin, 449-791, Korea.
Kwon
Tae-Hwan
TH
Park
Ji-Hyun
JH
Huh
Seong
S
D000327:Adsorption; D002245:Carbon Dioxide / Q000737:chemistry; D002264:Carboxylic Acids / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006859:Hydrogen / Q000737:chemistry; D008968:Molecular Conformation; D009584:Nitrogen / Q000737:chemistry; D016062:Porosity; D013696:Temperature; D013730:Terphenyl Compounds / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry
D002264:Carboxylic Acids; D013730:Terphenyl Compounds; D002245:Carbon Dioxide; D006859:Hydrogen; D015032:Zinc; D009584:Nitrogen