title: Increasing arsenic concentrations in runoff from 12 small forested catchments (Czech Republic, Central Europe): patterns and controls.
abstract: The 40-year long period of heavy industrialization in Central Europe (1950-1990) was accompanied by burning of arsenic-rich lignite in thermal power plants, and accumulation of anthropogenic arsenic in forest soils. There are fears that retreating acidification may lead to arsenic mobilization into drinking water, caused by competitive ligand exchange. We present monthly arsenic concentrations in surface runoff from 12 headwater catchments in the Czech Republic for a period of 13 years (1996-2008). The studied area was characterized by a north-south gradient of decreasing pollution. Acidification, caused mainly by SOx and NOx emissions from power plants, has been retreating since 1987. Between 1996 and 2003, maximum arsenic concentrations in runoff did not change, and were < 1 ppb in the rural south and < 2 ppb in the industrial north. During the subsequent two years, 2004-2005, maximum arsenic concentrations in runoff increased, reaching 60% of the drinking water limit (10 ppb). Starting in 2006, maximum arsenic concentrations returned to lower values at most sites. We discuss three possible causes of the recent arsenic concentration maximum in runoff. We rule out retreating acidification and a pulse of high industrial emission rates as possible controls. The pH of runoff has not changed since 1996, and is still too low (<6.5) at most sites for an As-OH(-) ligand exchange to become significant. Elevated arsenic concentrations in runoff in 2004-2005 may reflect climate change through changing hydrological conditions at some, but not all sites. Dry conditions may result in elevated production of DOC and sulfur oxidation in the soil. Subsequent wet conditions may be accompanied by acidification leading to faster dissolution of arsenic-bearing sulfides, dissolution of arsenic-bearing Fe-oxyhydroxides, and elevated transport of arsenic sorbed on organic matter. Anaerobic domains exist in normally well-aerated upland soils for hours-to-days following precipitation events.
authors.affiliation: Department of Geochemistry, Czech Geological Survey, Geologicka 6, 15200 Prague 5, Czech Republic. martin.novak@geology.cz
authors.forename: Martin
authors.initials: M
authors.lastname: Novak
authors.forename: Lucie
authors.initials: L
authors.lastname: Erbanova
authors.forename: Daniela
authors.initials: D
authors.lastname: Fottova
authors.forename: Petra
authors.initials: P
authors.lastname: Voldrichova
authors.forename: Eva
authors.initials: E
authors.lastname: Prechova
authors.forename: Vladimir
authors.initials: V
authors.lastname: Blaha
authors.forename: Frantisek
authors.initials: F
authors.lastname: Veselovsky
authors.forename: Michael
authors.initials: M
authors.lastname: Krachler
mesh_terms: D001151:Arsenic / Q000032:analysis*; D018153:Czech Republic; D004784:Environmental Monitoring; D005618:Fresh Water / Q000737:chemistry*; D007053:Ice; D012914:Snow / Q000737:chemistry; D012989:Soil Pollutants / Q000032:analysis; D014197:Trees; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014877:Water Pollution, Chemical / Q000517:prevention & control / Q000706:statistics & numerical data
chemical_list: D007053:Ice; D012989:Soil Pollutants; D014874:Water Pollutants, Chemical; D001151:Arsenic