Lithium pipecolinate as a facile and efficient ligand for copper-catalyzed hydroxylation of aryl halides in water.
Direct hydroxylation of a wide scope of aryl halides was catalyzed by a combination of CuI and lithium pipecolinate in water with yields up to 92%.
Jing
Linhai
L
Institute of Homogeneous Catalysis, College of Chemistry, Sichuan University, Chengdu 610064, China.
Wei
Jiangtao
J
Zhou
Li
L
Huang
Zhiyong
Z
Li
Zhengkai
Z
Zhou
Xiangge
X
D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D006219:Halogens / Q000737:chemistry*; D007462:Iodobenzenes / Q000737:chemistry; D008024:Ligands; D008094:Lithium / Q000737:chemistry*; D018020:Lithium Compounds / Q000737:chemistry*; D010875:Pipecolic Acids / Q000737:chemistry*; D014867:Water / Q000737:chemistry
D006219:Halogens; D007462:Iodobenzenes; D008024:Ligands; D018020:Lithium Compounds; D010875:Pipecolic Acids; D014867:Water; D003300:Copper; D008094:Lithium; C031905:iodobenzene