title: Iridium/chiral diene-catalyzed asymmetric 1,6-addition of arylboroxines to alpha,beta,gamma,delta-unsaturated carbonyl compounds.
abstract: Iridium-catalyzed asymmetric 1,6-addition of arylboroxines to alpha,beta,gamma,delta-unsaturated carbonyl compounds to give delta-arylated carbonyl compounds in high yields with 90-99% enantioselectivity was realized by use of an iridium/chiral diene complex.
authors.affiliation: Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502, Japan. tnishi@kuchem.kyoto-u.ac.jp
authors.forename: Takahiro
authors.initials: T
authors.lastname: Nishimura
authors.forename: Yuichi
authors.initials: Y
authors.lastname: Yasuhara
authors.forename: Takahiro
authors.initials: T
authors.lastname: Sawano
authors.forename: Tamio
authors.initials: T
authors.lastname: Hayashi