Diversity-oriented synthesis of dibenzoazocines and dibenzoazepines via a microwave-assisted intramolecular A(3)-coupling reaction.
An unprecedented, diversity-oriented strategy for the generation of 6,7-dihydro-5H-dibenzo[c,e]azepines and 5,6,7,8-tetrahydrodibenzo[c,e]azocines by a microwave-assisted copper-catalyzed intramolecular A(3)-coupling reaction is presented.
Bariwal
Jitender B
JB
Laboratory for Organic & Microwave-Assisted Chemistry (LOMAC), Katholieke Universiteit Leuven, Celestijnenlaan 200F, B-3001 Leuven, Belgium.
Ermolat'ev
Denis S
DS
Glasnov
Toma N
TN
Van Hecke
Kristof
K
Mehta
Vaibhav P
VP
Van Meervelt
Luc
L
Kappe
C Oliver
CO
Van der Eycken
Erik V
EV
D001381:Azepines / Q000138:chemical synthesis* / Q000737:chemistry; D001392:Azocines / Q000138:chemical synthesis* / Q000737:chemistry; D001965:Bromides / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D008872:Microwaves; D015394:Molecular Structure
D001381:Azepines; D001392:Azocines; D001965:Bromides; C408079:cupric bromide; D003300:Copper