Rh(I)-catalyzed carbonylative carbocyclization of tethered ene- and yne-cyclopropenes.
Rh(I)-catalyzed carbonylative carbocyclization of ene- and yne-cyclopropene systems provides cyclohexenones and phenols with high efficiency, respectively.
Beijing National Laboratory of Molecular Sciences, College of Chemistry, Peking University, Beijing 100871, China.
Changkun
C
Li
Hang
H
Zhang
Jiajie
J
Feng
Yan
Y
Zhang
Jianbo
J
Wang
D002384:Catalysis; D018360:Crystallography, X-Ray; D003500:Cyclization; D003512:Cyclohexanones / Q000138:chemical synthesis* / Q000737:chemistry; D003521:Cyclopropanes / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D010636:Phenols / Q000138:chemical synthesis* / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
D003512:Cyclohexanones; D003521:Cyclopropanes; D010636:Phenols; D012238:Rhodium