CO insertion in lithiated diene-tricarbonyliron complexes.
Lithiated 1,3-diene-iron complexes undergo a CO insertion in the presence of trimethyl phosphite via a ferrate intermediate to give 3-formyl or 3-acetyl-1,3-diene-Fe(CO)(2)P(OMe)(3) complexes. Formylation proceeds when the reaction is quenched by a strong Brønsted acid, whereas the ketone is obtained after the treatment with iodomethane.
Okauchi
Tatsuo
T
Department of Applied Chemistry, Kyushu Institute of Technology, 1-1, Sensui-cho, Tobata, Kitakyushu 804-8550, Japan. okauchi@che.kyutech.ac.jp
Teshima
Takao
T
Sadoshima
Mitsuru
M
Kawakubo
Hidekazu
H
Kagimoto
Kouta
K
Sugahara
Yoko
Y
Kitamura
Mitsuru
M