py(2)P(2)S(7): a bis(pyridine)adduct stabilized phosphorus sulfide.
The new phosphorus sulfide P(2)S(7), stabilized as the bis(pyridinium) adduct, was obtained from the reaction of P(4)S(10) and sulfur in pyridine, and could be isolated in the form of colourless block-shaped crystals which were characterized using single crystal X-ray diffraction. Coordination of pyridine is weak (d(P-N) = 187 pm) which is supported also by quantum chemical calculations.
Department of Chemistry, Ludwig-Maximilian University of Munich, Butenandtstr. 5-13 (D), D-81377 Munich, Germany.
Christiane
C
Rotter
Camilla
C
Evangelisti
Stefanie
S
Schönberger
Thomas M
TM
Klapötke
Konstantin
K
Karaghiosoff