Zinc germanates incorporating organic amine ligands: solvothermal synthesis and structural characterization of Zn2Ge4O10(NH2CH2CH2CH2NH2) and ZnGe2O5(NH2CH2CH2NH2).
Two zinc germanates incorporating bidentate-bridging organic amine ligands have been synthesized under solvothermal conditions by using the amines as solvents. Their structural features are infinite chains formed of edge-sharing ZnO(4)N trigonal bipyramids and unbranched vierer single layers with the composition [Ge(4)O(10)] and discrete ZnO(2)N(2) tetrahedra and unbranched zweier double chains with the composition [Ge(2)O(5)], respectively.
Wang
Chih-Min
CM
Department of Chemistry, National Central University, Jhongli, Taiwan 320, Republic of China.
Lin
Chia-Hui
CH
Yang
Ciao-Wei
CW
Lii
Kwang-Hwa
KH