A double-walled triangular metal-organic macrocycle based on a [Cu(2)(COO)(4)] square paddle-wheel secondary building unit.
A metal-organic macrocycle (MOM), [(Cu(2))(3)L(6)(DMF)(2)(H(2)O)(4)], was prepared using a long and "pseudo-rigid" dicarboxylic acid, 1,4-bis(3-carboxylphenylethynyl)benzene (H(2)L), with some rotational flexibility, where the MOM has a double-walled triangular geometry with three Cu paddle-wheel secondary building units (SBUs) doubly connected by the ligands in a cis-conformation.
Department of Chemistry and Applied Chemistry, Hanyang University, Ansan, Kyunggi-do, 426-791, Korea.
Xiaokai
X
Song
Xinfang
X
Liu
Minhak
M
Oh
Myoung Soo
MS
Lah