Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines.
The room-temperature reactions of stannocene, Cp*(2)Sn, with a range of primary phosphines, RPH(2), result in diphosphanes [RP(H)P(H)R]. The reactions involving Cp*(2)SnCl(2), however, result in catalytic dehydrocoupling; the first example of main group metal catalysed dehydrocoupling to be identified.
Naseri
Vesal
V
Chemistry Department, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, UK. vn226@cam.ac.uk
Less
Robert J
RJ
Mulvey
Robert E
RE
McPartlin
Mary
M
Wright
Dominic S
DS