A water reduction process performed by zinc metal under very mild conditions.
Water reduction can be electrochemically promoted by zinc under very mild conditions, as demonstrated by the formation of the complex [Zn(H(2)O)(6)][Zn(3)(L)(3)(mu(3)-O)], whose anion consists of a Zn(3)O(4) cluster incorporating a mu(3)-oxo anion.
Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, Santiago de Compostela, Galicia, E-15782, Spain.
María J
MJ
Romero
Rosa
R
Pedrido
Ana M
AM
González-Noya
Miguel
M
Martínez-Calvo
Guillermo
G
Zaragoza
Manuel R
MR
Bermejo
D056831:Coordination Complexes / Q000737:chemistry*; D055664:Electrochemical Techniques; D008968:Molecular Conformation; D010084:Oxidation-Reduction; D014867:Water / Q000737:chemistry*; D015034:Zinc Oxide / Q000737:chemistry*
D056831:Coordination Complexes; D014867:Water; D015034:Zinc Oxide