Correlation between proton transfer and (35)Cl NQR frequency as well as molecular geometry of chloranilic acid in co-crystals with some organic bases.
Proton transfer in hydrogen-bonded organic co-crystals of chloranilic acid with some organic bases was investigated by nuclear quadrupole resonance (NQR) spectroscopy. The (35)Cl NQR frequencies of chloranilic acid molecule as well as (14)N NQR frequencies of the organic base molecule were measured with the conventional pulse methods as well as double-resonance methods, respectively. The extent of proton transfer in the O...H...N hydrogen bond was estimated from Townes-Dailey analysis of the (14)N NQR parameters. The (35)Cl NQR frequency and molecular geometry of chloranilic acid are correlated to the extent of proton transfer in the protonation process of the organic base molecule. It is shown that the hydrogen bond affects the pi-electron system of chloranilic acid. Geometry dependence of the O...H...N hydrogen bond, i.e. the H-N valence bond order versus the hydrogen-bond geometry correlation is also discussed.
Asaji
Tetsuo
T
Department of Chemistry, College of Humanities and Sciences, Nihon University, Sakurajosui, Setagaya-ku, 3-25-40, Tokyo 156-8550, Japan. asaji@chs.nihon-u.ac.jp
Seliger
Janez
J
Zagar
Veselko
V
Ishida
Hiroyuki
H