Thermal reaction of a (hydrido)(selenolato)platinum(II) complex having a dibenzobarrelenyl group leading to three cyclometalations.
The thermal reaction of a (dibenzobarreleneselenolato)(hydrido)platinum(ii) complex gave two four-membered selenaplatinacycles, one of which is formed by hydroplatination of the Pt-H bond to the etheno bridge and the other is a vinylic C-H bond activation product, and a five-membered selenaplatinacycle formed by an aromatic C-H bond activation.
Department of Chemistry, Graduate School of Science and Engineering, Saitama University, Shimo-okubo 255, Sakura-ku, Saitama 338-8570, Japan. ishiiaki@chem.saitama-u.ac.jp
Akihiko
A
Ishii
Yuki
Y
Yamaguchi
Norio
N
Nakata