Catalytic selective cyclizations of aminocyclopropanes: formal synthesis of aspidospermidine and total synthesis of goniomitine.
Laboratory of Catalysis and Organic Synthesis, Ecole Polytechnique Fédérale de Lausanne, EPFL SB ISIC LCSO, BCH 4306, 1015 Lausanne, Switzerland.
Filippo
F
De Simone
Jürg
J
Gertsch
Jérôme
J
Waser
D000970:Antineoplastic Agents / Q000138:chemical synthesis* / Q000737:chemistry / Q000633:toxicity; D002384:Catalysis; D045744:Cell Line, Tumor; D003500:Cyclization; D003521:Cyclopropanes / Q000737:chemistry*; D004354:Drug Screening Assays, Antitumor; D006801:Humans; D026121:Indole Alkaloids / Q000138:chemical synthesis* / Q000737:chemistry / Q000633:toxicity; D011804:Quinolines / Q000138:chemical synthesis* / Q000737:chemistry / Q000633:toxicity; D013237:Stereoisomerism
D000970:Antineoplastic Agents; D003521:Cyclopropanes; D026121:Indole Alkaloids; D011804:Quinolines; C409672:aspidospermidine; C526621:goniomitine; C030797:cyclopropane