The coordination preferences of metal centres modulate superexchange coupling interactions in a metallo-supramolecular helical assembly.
A method to modulate the strength of the superexchange coupling interaction in dinuclear helical assemblies based on the coordination preferences of the metal centres is described.
Pedrido
Rosa
R
Departamento de Química Inorgánica, Facultad de Química, Universidad de Santiago de Compostela, 15782 Santiago de Compostela, Spain. rosa.pedrido@usc.es
Vázquez López
Miguel
M
Sorace
Lorenzo
L
González-Noya
Ana M
AM
Cwiklinska
Magdalena
M
Suárez-Gómez
Vanesa
V
Zaragoza
Guillermo
G
Bermejo
Manuel R
MR