Two similarly substituted benzo[h]pyrazolo[3,4-b]quinoline-5,6(10H)-diones: supramolecular structures in two and three dimensions.
The molecules of 8-methyl-7,10-diphenyl-5H-benzo[h]pyrazolo[3,4-b]quinoline-5,6(10H)-dione, C(27)H(17)N(3)O(2), (I), are weakly linked into chains by a single C-H...O hydrogen bond, and these chains are linked into sheets by a pi-pi stacking interaction involving pyridyl and aryl rings. In 8-methyl-7-(4-methylphenyl)-10-phenyl-5H-benzo[h]pyrazolo[3,4-b]quinoline-5,6(10H)-dione, C(28)H(19)N(3)O(2), (II), the molecules are linked into a three-dimensional framework structure by a combination of C-H...N, C-H...O and C-H...pi(arene) hydrogen bonds, together with a pi-pi stacking interaction analogous to that in (I).
Díaz
Yurina
Y
Departamento de Química, Universidad de Valle, AA 25360 Cali, Colombia.
Quiroga
Jairo
J
Cobo
Justo
J
Glidewell
Christopher
C
D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D046911:Macromolecular Substances / Q000737:chemistry*; D008968:Molecular Conformation; D011720:Pyrazoles / Q000737:chemistry*; D015363:Quinolones / Q000737:chemistry*
C550419:8-methyl-7,10-diphenyl-5H-benzo(h)pyrazolo(3,4-b)quinoline-5,6(10H)-dione; C550421:8-methyl-7-(4-methylphenyl)-10-phenyl-5H-benzo(h)pyrazolo(3,4-b)quinoline-5,6(10H)-dione; D046911:Macromolecular Substances; D011720:Pyrazoles; D015363:Quinolones