Cerberus-type N-heterocyclic carbenes: synthesis and study of the first tritopic carbenes with D(3h)-symmetry.
The synthesis and characterization of tris(N-heterocyclic carbene)s with D(3h)-symmetry is reported; these tritopic molecules feature three independent carbene moieties that are geometrically isolated to prevent chelation.
Williams
Kyle A
KA
Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX 78712, USA.
Bielawski
Christopher W
CW