Directed self-assembly of a ring-in-ring complex.
A strategic modification to the corner ligands in Pd(II)-containing, electron-poor cyclophanes has profound repercussions for their assemblies with electron-rich aromatic crown ethers in both the solid and solution states; the formation of ring-in-ring complexes can override competing [3]catenane production on masking the hydrogen bond donor capabilities of the corner ligands.
Forgan
Ross S
RS
Center for the Chemistry of Integrated Systems, Department of Chemistry, Northwestern University, Evanston, IL 60208, USA.
Friedman
Douglas C
DC
Stern
Charlotte L
CL
Bruns
Carson J
CJ
Stoddart
J Fraser
JF