A new family of oxime-based hexanuclear manganese(III) single molecule magnets with high anisotropy energy barriers.
A magneto-structural study of two salicylamidoxime-based {Mn(6)} single-molecule magnets revealed that their anisotropy energy barriers, which can reach the current record for d-transition metal complexes, are strongly dependent upon the precise arrangement of ligands and the solvation state.
Tomsa
Adrian-Raul
AR
Institut Parisien de Chimie Moléculaire, UMR CNRS 7201, Case courrier 42, Université Pierre et Marie Curie Paris 6, Place Jussieu, 75252 Paris Cedex 05, France.
Martínez-Lillo
José
J
Li
Yanling
Y
Chamoreau
Lise-Marie
LM
Boubekeur
Kamal
K
Farias
Fernanda
F
Novak
Miguel A
MA
Cremades
Eduard
E
Ruiz
Eliseo
E
Proust
Anna
A
Verdaguer
Michel
M
Gouzerh
Pierre
P