Synthesis of Chiral Nonracemic Tertiary α-Thio and α-Sulfonyl Acetic Esters via S(N)2 reactions of Tertiary Mesylates.
Syntheses of enantioenriched sulfides and sulfones via substitution of tertiary mesylate with thiolate nucleophile with modest to excellent success.
Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, KS, 66045-7582.
Jimmie D
JD
Weaver
David K
DK
Morris
Jon A
JA
Tunge