py(2)P(2)S(7): a bis(pyridine)adduct stabilized phosphorus sulfide.
The new phosphorus sulfide P(2)S(7), stabilized as the bis(pyridinium) adduct, was obtained from the reaction of P(4)S(10) and sulfur in pyridine, and could be isolated in the form of colourless block-shaped crystals which were characterized using single crystal X-ray diffraction. Coordination of pyridine is weak (d(P-N) = 187 pm) which is supported also by quantum chemical calculations.
Rotter
Christiane
C
Department of Chemistry, Ludwig-Maximilian University of Munich, Butenandtstr. 5-13 (D), D-81377 Munich, Germany.
Evangelisti
Camilla
C
Schönberger
Stefanie
S
Klapötke
Thomas M
TM
Karaghiosoff
Konstantin
K