A new family of oxime-based hexanuclear manganese(III) single molecule magnets with high anisotropy energy barriers.
A magneto-structural study of two salicylamidoxime-based {Mn(6)} single-molecule magnets revealed that their anisotropy energy barriers, which can reach the current record for d-transition metal complexes, are strongly dependent upon the precise arrangement of ligands and the solvation state.
Institut Parisien de Chimie Moléculaire, UMR CNRS 7201, Case courrier 42, Université Pierre et Marie Curie Paris 6, Place Jussieu, 75252 Paris Cedex 05, France.
Adrian-Raul
AR
Tomsa
José
J
Martínez-Lillo
Yanling
Y
Li
Lise-Marie
LM
Chamoreau
Kamal
K
Boubekeur
Fernanda
F
Farias
Miguel A
MA
Novak
Eduard
E
Cremades
Eliseo
E
Ruiz
Anna
A
Proust
Michel
M
Verdaguer
Pierre
P
Gouzerh