A novel polyoxochromium borophosphate with new 6-membered ring crown-shaped clusters.
A novel chromium borophosphate with anionic clusters has been synthesized using boric acid as flux. X-ray diffraction analysis on a single crystal reveals that its structure comprises of crown-shaped 6-membered ring clusters [NaCr(8)B(4)P(12)O(60)H(8)](15-), which are built from [Cr(4)O(18)] groups, [BP(2)O(10)] anions and PO(4) tetrahedra with Na(+) cations encapsulated in the clusters. Magnetic investigation showed strong antiferromagnetic interactions between Cr(3+)-Cr(3+) dimers at low temperature.
Liu
Wei
W
Institute of Materials Science and Engineering, The Ocean University of China, Qingdao, 266100, PR China. weiliu@ouc.edu.cn
Zhang
Lan
L
Su
Ge
G
Cao
Li-Xin
LX
Wang
Yong-Gang
YG
D001888:Boric Acids / Q000737:chemistry*; D002857:Chromium / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008280:Magnetics; D008968:Molecular Conformation; D010710:Phosphates / Q000737:chemistry*; D013696:Temperature
D001888:Boric Acids; D010710:Phosphates; D002857:Chromium; C032688:boric acid