Introducing catalytic activity in helical nanostructures: microwave assisted oxathioacetalisation catalysed by Al-containing helical mesoporous silicas.
Al-containing helical mesoporous silicas have been synthesized and characterised by different techniques, showing outstanding activities (comparable to those obtained with sulfuric acid) in the oxathioacetalization of cyclohexane.
Department of Inorganic Chemistry, Molecular Nanotechnology Lab, University of Alicante, Carretera San Vicente s/n, E-03690 Alicante, Spain.
Adela I
AI
Carrillo
Elena
E
Serrano
Rafael
R
Luque
Javier
J
García Matínez
D000447:Aldehydes / Q000737:chemistry; D000535:Aluminum / Q000737:chemistry; D002384:Catalysis; D007659:Ketones / Q000737:chemistry; D008872:Microwaves; D049329:Nanostructures / Q000737:chemistry*; D016062:Porosity; D012822:Silicon Dioxide / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry*
D000447:Aldehydes; D007659:Ketones; D013438:Sulfhydryl Compounds; C008730:oxathiol; D012822:Silicon Dioxide; D000535:Aluminum