Synthesis of Chiral Nonracemic Tertiary α-Thio and α-Sulfonyl Acetic Esters via S(N)2 reactions of Tertiary Mesylates.
Syntheses of enantioenriched sulfides and sulfones via substitution of tertiary mesylate with thiolate nucleophile with modest to excellent success.
Weaver
Jimmie D
JD
Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, KS, 66045-7582.
Morris
David K
DK
Tunge
Jon A
JA