Metal-organic frameworks with designed chiral recognition sites.
Linking struts containing Cram-like bisbinaphthyl[22]crown-6 with Zn(4)O(CO(2))(6) joints affords metal-organic frameworks with chiral recognition sites that are highly designed, ordered and placed in a precise manner throughout the entire crystal.
Valente
Cory
C
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA.
Choi
Eunwoo
E
Belowich
Matthew E
ME
Doonan
Christian J
CJ
Li
Qiaowei
Q
Gasa
Travis B
TB
Botros
Youssry Y
YY
Yaghi
Omar M
OM
Stoddart
J Fraser
JF