Introducing catalytic activity in helical nanostructures: microwave assisted oxathioacetalisation catalysed by Al-containing helical mesoporous silicas.
Al-containing helical mesoporous silicas have been synthesized and characterised by different techniques, showing outstanding activities (comparable to those obtained with sulfuric acid) in the oxathioacetalization of cyclohexane.
Carrillo
Adela I
AI
Department of Inorganic Chemistry, Molecular Nanotechnology Lab, University of Alicante, Carretera San Vicente s/n, E-03690 Alicante, Spain.
Serrano
Elena
E
Luque
Rafael
R
García Matínez
Javier
J
D000447:Aldehydes / Q000737:chemistry; D000535:Aluminum / Q000737:chemistry; D002384:Catalysis; D007659:Ketones / Q000737:chemistry; D008872:Microwaves; D049329:Nanostructures / Q000737:chemistry*; D016062:Porosity; D012822:Silicon Dioxide / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry*
D000447:Aldehydes; D007659:Ketones; D013438:Sulfhydryl Compounds; C008730:oxathiol; D012822:Silicon Dioxide; D000535:Aluminum