Radicals and radical ions derived from indole, indole-3-carbinol and diindolylmethane.
The primary products, i.e., the radical cations and radicals obtained on oxidation of the glucobrassicin metabolites (and dietary supplements), indole-3-carbinol (I3C) and diindolylmethane (DIM), and those from parent indole (I) are characterized in an ionic liquid and in Ar matrices. The radical cations of I and I3C are stable toward (photo)deprotonation under these conditions, but the resulting radicals can be generated by UV-photolysis of the neutral precursors. Two types of radicals, obtained by loss of hydrogen from N- and C-atoms, respectively, are found for I3C and DIM.
Błoch-Mechkour
Anna
A
Department of Chemistry, University of Fribourg, CH-1700 Fribourg, Switzerland.
Bally
Thomas
T
Sikora
Adam
A
Michalski
Radosław
R
Marcinek
Andrzej
A
Gebicki
Jerzy
J
D005609:Free Radicals / Q000737:chemistry; D007211:Indoles / Q000737:chemistry*; D010782:Photolysis; D011789:Quantum Theory
D005609:Free Radicals; D007211:Indoles; C016517:indole-3-carbinol; C016392:3,3'-diindolylmethane