ROMP-derived oligomeric phosphates for application in facile benzylation.
The development of new ROMP-based oligomeric benzyl phosphates (OBP(n)) is reported for use as soluble, stable benzylating reagents. These oligomeric reagents are readily synthesized from commercially available materials and conveniently polymerized and purified in a one-pot process, affording bench-stable, pure white, free-flowing solids on multigram scale. Utilization in benzylation reactions with a variety of nucleophiles is reported.
Long
Toby R
TR
Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, Kansas 66045-7582, USA.
Maity
Pradip K
PK
Samarakoon
Thiwanka B
TB
Hanson
Paul R
PR
D001593:Benzyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D008968:Molecular Conformation; D010710:Phosphates / Q000737:chemistry*; D013237:Stereoisomerism
D001593:Benzyl Compounds; D010710:Phosphates