Interaction of hydrogen with accessible metal sites in the metal-organic frameworks M(2)(dhtp) (CPO-27-M; M = Ni, Co, Mg).
Hydrogen molecules adsorbed in the nickel, cobalt, and magnesium analogs of the CPO-27 metal-organic framework at low loadings interact significantly more strongly than those adsorbed successively as a consequence of the strong interaction of hydrogen with the coordinatively unsaturated metal cations in the framework.
Dietzel
Pascal D C
PD
SINTEF Materials and Chemistry, P.O. Box 124 Blindern, N-0314 Oslo, Norway. pascal.dietzel@sintef.no
Georgiev
Peter A
PA
Eckert
Juergen
J
Blom
Richard
R
Strässle
Thierry
T
Unruh
Tobias
T