UV-vis spectroscopy and semiempirical quantum chemical studies on methyl derivatives of annulated analogues of azafluoranthene and azulene dyes.
Paper reports the measured optical absorption and fluorescence spectra of 4-(2-chlorophenyl)-7-methyl-1,3-diphenyl-1H-pyrazolo[3,4-b]quinoline (MCPDPPQ), as well as 6-methyl-1,3-diphenyl-3H-indeno[1,2,3-de]pyrazolo[3,4-b]quinoline (MDPIPQ) and 9-methyl-6-phenyl-6H-5,6,7-triazadibenzo[f,h]naphtho[3,2,1-cd]azulene (MPTNA) representing cyclized five- or seven-membered regioisomeric products of MCPDPPQ, respectively. The spectra has been recorded in solvents of different polarity and compared with the results of quantum chemical calculations performed by means of the semiempirical method PM3 in combination with molecular dynamics (MD) simulations. Cyclization of MCPDPPQ into MDPIPQ or MPTNA is accompanied by a significant red shift of the first optical absorption and fluorescence bands. While the solvent polarity rises all the dyes exhibit the blue shift of the first absorption band and the red shift of the fluorescence band. These trends have been reproduced within the semiempirical calculations in combination with the Lippert-Mataga dielectric polarization model and explained by specific orientations of the dipole moments in the ground and excited states. All dyes may be considered as candidates for the luminescent or electroluminescent applications. Depending on solvent polarity they emit light in the green-yellow range of the visible spectra.
Department of Chemistry, University of Agriculture, Balicka str. 122, 30-149 Kraków, Poland.
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Danel
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Gasiorski
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Matusiewicz
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Kityk
D001372:Aza Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D052176:Azulenes / Q000138:chemical synthesis / Q000737:chemistry*; D004396:Coloring Agents / Q000737:chemistry*; D005449:Fluorenes / Q000138:chemical synthesis / Q000737:chemistry*; D007700:Kinetics; D008968:Molecular Conformation; D055620:Optical Phenomena; D011789:Quantum Theory; D011804:Quinolines / Q000138:chemical synthesis / Q000737:chemistry; D012996:Solutions; D013050:Spectrometry, Fluorescence; D013056:Spectrophotometry, Ultraviolet; D013816:Thermodynamics
D001372:Aza Compounds; D052176:Azulenes; D004396:Coloring Agents; D005449:Fluorenes; D011804:Quinolines; D012996:Solutions; C007738:fluoranthene; C037219:quinoline