Rhodium-catalyzed arylzincation of terminal allenes providing allylzinc reagents and its application to versatile three-component coupling reaction.
Rhodium-catalyzed regioselective arylzincation of terminal allenes affords synthetically useful functionalized allylzinc reagents. The allylzinc reagents react with a variety of electrophiles such as acetonitrile, offering a more versatile three-component coupling reaction.
Yoshida
Yuji
Y
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Murakami
Kei
K
Yorimitsu
Hideki
H
Oshima
Koichiro
K