Yttrium bisphosphonate STA-13: a racemic phosphonate metal organic framework with permanent microporosity.
Crystallisation of yttrium and other trivalent metal cations of similar radius with racemic N,N'-2-methylpiperazinebis(methylene phosphonic acid) gives a small pore bisphosphonate metal-organic framework solid displaying coordinative and hydrogen bonding and permanent porosity.
Wharmby
Michael T
MT
School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St Andrews, Fife, UK KY16 9ST.
Miller
Stuart R
SR
Groves
John A
JA
Margiolaki
Irene
I
Ashbrook
Sharon E
SE
Wright
Paul A
PA