title: Alkylphenols and polycyclic aromatic hydrocarbons in eastern Mediterranean Spanish coastal marine bivalves.
abstract: This paper reports the first results on alkylphenol pollution in edible bivalves from the Spanish coast. Two sampling campaigns (July 2006 and July 2007) were carried out to determine the concentration of nonylphenol (NP), octylphenol (OP), and eight polycyclic aromatic hydrocarbons (PAHs) in wild mussels (Mytilus galloprovincialys) and clams (Donax trunculus) at 14 sampling sites along the eastern Mediterranean Spanish coast. The results show that NP is the predominant alkylphenol, being the port of Valencia the most polluted area (up to 147 μg/kg wet weight in clams). Moving away from the ports the concentration of NP in bivalves decreased. OP concentration was below its detection limit in most of the studied areas and its maximum concentration (6 μg/kg w/w) was measured in clams from the port of Sagunto. The presence of low levels of PAHs was observed in most of the studied areas. The total PAHs concentration (i.e., sum of the eight measured PAHs) achieved a maximum value of 10.09 μg/kg w/w in the north coast of Valencia city. The distribution pattern of the individual PAHs showed that both pollution sources petrogenic and pyrolytic were present in the sampled areas. Fluoranthene was the most abundant PAH in mussels while benzo(b)fluoranthene in clams. The maximum concentration of 10 μg/kg w/w for benzo(a)pyrene established by the European Commission was never reached, indeed sampled bivalves showed concentrations 10 times lower than this reference value. Thus, they can be considered safe for human consumption. Despite the low contamination levels, the results show an overall pollution of bivalves by alkylphenol and PAHs as well as an increment in the number of polluted areas from 2006 to 2007. Thus, periodical sampling campaigns should be carried out to monitor the long-term tendency of these toxic and persistent pollutants.
authors.affiliation: Dpto. Ingeniería Química, Universidad de Valencia, Doctor Moliner 50, 46100, Burjassot, Valencia, Spain.
authors.forename: Alberto
authors.initials: A
authors.lastname: Bouzas
authors.forename: Daniel
authors.initials: D
authors.lastname: Aguado
authors.forename: Nuria
authors.initials: N
authors.lastname: Martí
authors.forename: José Manuel
authors.initials: JM
authors.lastname: Pastor
authors.forename: Rosa
authors.initials: R
authors.lastname: Herráez
authors.forename: Pilar
authors.initials: P
authors.lastname: Campins
authors.forename: Aurora
authors.initials: A
authors.lastname: Seco
mesh_terms: D000818:Animals; D049872:Bivalvia / Q000378:metabolism*; D004784:Environmental Monitoring / Q000379:methods*; D010636:Phenols / Q000032:analysis / Q000378:metabolism; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis* / Q000378:metabolism*; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000378:metabolism*
chemical_list: D010636:Phenols; D011084:Polycyclic Aromatic Hydrocarbons; D014874:Water Pollutants, Chemical; C474055:octylphenol; C025256:nonylphenol