title: Transparent conductors from layer-by-layer assembled SWNT films: importance of mechanical properties and a new figure of merit.
abstract: New transparent conductors (TCs) capable of replacing traditional indium tin oxide (ITO) are much needed for displays, sensors, solar cells, smart energy-saving windows, and flexible electronics. Technical requirements of TCs include not only high electrical conductivity and transparency but also environmental stability and mechanical property which are often overlooked in the research environment. Single-walled carbon nanotube (SWNT) coatings have been suggested as alternative TC materials but typically lack sufficient wear resistance compared to ITO. Balancing conductance, transparency, durability, and flexibility is a formidable challenge, which leads us to the introduction of a new TC figure of merit, PiTC, incorporating all these qualities. Maximization of PiTC to that of ITO or better can be suggested as an initial research goal. Fine tuning of SWNT layer-by-layer (LBL) polymeric nanocomposite structures makes possible integration of all the necessary properties. The produced TC demonstrated resistivity of 86 Omega/sq with 80.2% optical transmittance combined with tensile modulus, strength, and toughness of the film of 12.3+/-3.4 GPa, 218+/-13 MPa, and 8+/-1.7 J/g, respectively. A new transparent capping layer to conserve these properties in the hostile environment with matching or better strength, toughness, and transparency parameters was also demonstrated. Due to application demands, bending performance of TC made by LBL was of special interest and exceeded that of ITO by at least 100 times. Cumulative figure of merit PiTC for the produced coatings was 0.15 Omega(-1), whereas the conventional ITO showed PiTC<0.07 Omega(-1). With overall electrical and optical performance comparable to ITO and exceptional mechanical properties, the described coatings can provide an excellent alternative to ITO or other nanowire- and nanotube-based TC specifically in flexible electronics, displays, and sensors.
authors.affiliation: Department of Chemical Engineering, University of Michigan, Ann Arbor, MI 48109, USA.
authors.forename: Bong Sup
authors.initials: BS
authors.lastname: Shim
authors.forename: Jian
authors.initials: J
authors.lastname: Zhu
authors.forename: Edward
authors.initials: E
authors.lastname: Jan
authors.forename: Kevin
authors.initials: K
authors.lastname: Critchley
authors.forename: Nicholas A
authors.initials: NA
authors.lastname: Kotov
mesh_terms: D004553:Electric Conductivity; D055595:Mechanical Phenomena; D037742:Nanotubes, Carbon / Q000737:chemistry*; D055620:Optical Phenomena; D012993:Solar Energy; D017971:Tin Compounds / Q000737:chemistry
chemical_list: D037742:Nanotubes, Carbon; D017971:Tin Compounds; C109984:indium tin oxide