title: Implementation of an MgO-based metal removal step in the passive treatment system of Shilbottle, UK: column experiments.
abstract: Three laboratory column experiments were performed to test the suitability of two different MgO-rich reagents for removal of Mn and Al from the out-flowing waters of Shilbottle passive treatment system (Northumberland, UK). The input water was doped with 100 mg/L Zn in order to extrapolate results to waters in sulphide mining districts. One column was filled with a Dispersed Alkaline Substrate (DAS) containing 12.5% (v/v) caustic magnesia precipitator dust (CMPD) from Spain mixed with wood shavings, two columns were filled with DAS containing wood shavings and 12.5% or 25% (v/v), respectively, of dolomitic lime precipitator dust (DLPD) from Thrislington, UK. The two columns containing 12.5% of CMPD or DLPD completely removed the contaminants from the inflow water during the first 6 weeks of the experiment (mean removal of 88 mg/L Al, 96 mg/L Zn and 37 mg/L Mn), operating at an acidity load of 140 g acidity/m(2)day. At this moment, a substantial increase of the Al and Mn water concentration in the out-flowing waters of Shilbottle occurred (430 g acidity/m(2)day), leading to passivation of the reactive material and to the development of preferential flow paths within less than another 6 weeks, probably mainly due to Al precipitates. Al should be removed prior to MgO treatment.
authors.affiliation: Geology Department, University of Huelva, Huelva, Spain. manuel.caraballo@dgeo.uhu.es
authors.forename: Manuel A
authors.initials: MA
authors.lastname: Caraballo
authors.forename: Tobias S
authors.initials: TS
authors.lastname: Rötting
authors.forename: Verónica
authors.initials: V
authors.lastname: Silva
mesh_terms: D000535:Aluminum / Q000302:isolation & purification; D011232:Chemical Precipitation; D004867:Equipment Design; D008277:Magnesium Oxide; D008345:Manganese / Q000302:isolation & purification; D008670:Metals / Q000302:isolation & purification*; D008906:Mining; D006113:United Kingdom; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods
chemical_list: D008670:Metals; D014874:Water Pollutants, Chemical; D008277:Magnesium Oxide; D008345:Manganese; D000535:Aluminum