title: Hydrophilicity, the major determining factor influencing the solvation environment of protic ionic liquids.
abstract: The study of solubility of 4-nitroaniline and its N,N-diethyl derivative in ionic liquids (ILs) of varying water content has shown that it is the interaction between water and the ILs' ions, and not with the solute, that is the most important factor determining the solute's preferential hydration parameter and thus the solvation shell structure.
authors.affiliation: York Structural Biology Laboratory, Department of Chemistry, University of York, Heslington, York YO10 5YW, UK.
authors.forename: Lawrence
authors.initials: L
authors.lastname: Wright
authors.forename: Marc W
authors.initials: MW
authors.lastname: Sanders
authors.forename: Lauren
authors.initials: L
authors.lastname: Tate
authors.forename: Gayle
authors.initials: G
authors.lastname: Fairless
authors.forename: Lorna
authors.initials: L
authors.lastname: Crowhurst
authors.forename: Neil C
authors.initials: NC
authors.lastname: Bruce
authors.forename: Adam J
authors.initials: AJ
authors.lastname: Walker
authors.forename: Guy A
authors.initials: GA
authors.lastname: Hembury
authors.forename: Seishi
authors.initials: S
authors.lastname: Shimizu
mesh_terms: D000814:Aniline Compounds / Q000737:chemistry; D052578:Ionic Liquids / Q000737:chemistry*; D012995:Solubility; D012997:Solvents / Q000737:chemistry; D013816:Thermodynamics
chemical_list: D000814:Aniline Compounds; D052578:Ionic Liquids; D012997:Solvents; C019498:4-nitroaniline