Amino acid ligand chirality for enantioselective syntheses.
Amino acids are attractive sources of chirality in stoichiometric or catalytic transition metal/organic chemistry. In spite of easy availability and other advantages, the application of these ligands is hindered by several problems. Now, at the dawn of emerging D-amino acid biochemistry, efforts in this direction are becoming increasingly important. The results of research on application of amino acid ligands for transition-metal reagents in organic syntheses are reviewed in the present work.
Micskei
Károly
K
Institute of Chemistry, University of Debrecen, Egyetem tér 1, H-4032 Debrecen, Hungary. kmicskei@delfin.unideb.hu
Patonay
Tamás
T
Caglioti
Luciano
L
Pályi
Gyula
G
D000596:Amino Acids / Q000138:chemical synthesis / Q000737:chemistry*; D002942:Circular Dichroism; D008024:Ligands; D013056:Spectrophotometry, Ultraviolet; D013237:Stereoisomerism; D028561:Transition Elements / Q000737:chemistry
D000596:Amino Acids; D008024:Ligands; D028561:Transition Elements