Platinum-mediated aryl-aryl bond formation and sp(3) C-H bond activation.
A novel process is described in which intramolecular oxidative addition is followed by aryl-aryl bond formation and sp(3) C-H bond activation leading to a six-membered platinacycle.
Crespo
Margarita
M
Departament de Química Inorgànica, Universitat de Barcelona, Diagonal 647, 08028, Barcelona, Spain. margarita.crespo@qi.ub.es
Calvet
Teresa
T
Font-Bardia
Mercè
M
D018360:Crystallography, X-Ray; D003500:Cyclization; D008958:Models, Molecular; D015394:Molecular Structure; D009944:Organoplatinum Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*
D009944:Organoplatinum Compounds; D010984:Platinum