Synthesis and structure of Na+-intercalated WO3(4,4-bipyridyl)0.5.
WO3(4,4-bipyridyl)0.5 was doped with Na+ by ion implantation so as to alter the electronic structure. Single-crystal X-ray diffraction reveals layers of corner-shared WO5N octahedra linked by bipyridine. In the observed space group of Pbca, the fully-ordered bipyridyls form cages with Na+ disordered bimodally about the cage centre.
Islah-u-din
Institute of Fundamental Sciences, Massey University, Private Bag 11222, Palmerston North 4442, New Zealand.
Fox
Matthew R
MR
Martin
Hélène
H
Gainsford
Graeme J
GJ
Kennedy
John
J
Markwitz
Andreas
A
Telfer
Shane G
SG
Jameson
Geoffrey B
GB
Tallon
Jeffery L
JL