A polyoxometalate-encapsulated 3D porous metal-organic pseudo-rotaxane framework.
A novel compound, [Cu(bimb)](2)(HPW(12)O(40)) x 3 H(2)O (bimb = 1,4-bis(imidazol-1-ylmethyl)biphenyl) with a polyoxometalate-encapsulated 3D metal-organic pseudo-rotaxane framework that can be described as a 2-fold dianet topology showing well-defined 1D nano-scale tunnels, has been synthesized hydrothermally, and its de-/rehydration behavior has been investigated.
Pang
Hai-jun
HJ
Key Lab of Polyoxometalate Science of the Ministry of Education Faculty of Chemistry, Northeast Normal University, Changchun 130024, PR China.
Peng
Jun
J
Zhang
Chun-jing
CJ
Li
Yang-guang
YG
Zhang
Peng-peng
PP
Ma
Hui-yuan
HY
Su
Zhong-min
ZM