Hydrophilicity, the major determining factor influencing the solvation environment of protic ionic liquids.
The study of solubility of 4-nitroaniline and its N,N-diethyl derivative in ionic liquids (ILs) of varying water content has shown that it is the interaction between water and the ILs' ions, and not with the solute, that is the most important factor determining the solute's preferential hydration parameter and thus the solvation shell structure.
Wright
Lawrence
L
York Structural Biology Laboratory, Department of Chemistry, University of York, Heslington, York YO10 5YW, UK.
Sanders
Marc W
MW
Tate
Lauren
L
Fairless
Gayle
G
Crowhurst
Lorna
L
Bruce
Neil C
NC
Walker
Adam J
AJ
Hembury
Guy A
GA
Shimizu
Seishi
S
D000814:Aniline Compounds / Q000737:chemistry; D052578:Ionic Liquids / Q000737:chemistry*; D012995:Solubility; D012997:Solvents / Q000737:chemistry; D013816:Thermodynamics
D000814:Aniline Compounds; D052578:Ionic Liquids; D012997:Solvents; C019498:4-nitroaniline