title: The separation of uranium ions by natural and modified diatomite from aqueous solution.
abstract: In this work the natural and the surfactant modified diatomite has been tested for ability to remove uranium ions from aqueous solutions. Such controlling factors of the adsorption process as initial uranium concentration, pH, contact time and ionic strength have been investigated. Effect of ionic strength of solution has been examined using the solutions of NaCl, Na(2)CO(3) and K(2)SO(4). The pseudo-first order and the pseudo-second order models have been used to analyze the adsorption kinetic results, whereas the Langmuir and the Freundlich isotherms have been used to the equilibrium adsorption data. The effects of the adsorbent modification as well as uranium adsorption on the diatomite surface have been studied using X-ray powder diffraction, scanning electron microscopy and FTIR spectroscopy. The maximum adsorption capacities of the natural and the modified diatomite towards uranium were 25.63 micromol/g and 667.40 micromol/g, respectively. The desorptive solutions of HCl, NaOH, Na(2)CO(3), K(2)SO(4), CaCO(3), humic acid, cool and hot water have been tested to recover uranium from the adsorbent. The highest values of uranium desorption (86%) have been reached using 0.1M HCl.
authors.affiliation: Department of Environmental Chemistry and Bioanalytics, Faculty of Chemistry, Nicolaus Copernicus University, Torun, Poland. sprynsky@yahoo.com
authors.forename: Myroslav
authors.initials: M
authors.lastname: Sprynskyy
authors.forename: Iryna
authors.initials: I
authors.lastname: Kovalchuk
authors.forename: Bogusław
authors.initials: B
authors.lastname: Buszewski
mesh_terms: D000327:Adsorption; D007692:Diatomaceous Earth / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D009994:Osmolar Concentration; D012996:Solutions; D013501:Surface-Active Agents / Q000737:chemistry; D014501:Uranium / Q000302:isolation & purification*; D014875:Water Pollutants, Radioactive / Q000302:isolation & purification*
chemical_list: D012996:Solutions; D013501:Surface-Active Agents; D014875:Water Pollutants, Radioactive; D014501:Uranium; D007692:Diatomaceous Earth; C033787:diatomite