Heterobimetallic porphyrin-based single-chain magnet constructed from manganese(III)-porphyrin and trans-dicyanobis(acetylacetonato) ruthenate(III) containing co-crystallized bulk anions and cations.
Two cyanide-bridged alternated 1 : 1 Ru(III)/Mn(III) complexes structurally characterized as single-chain containing co-crystallized bulk anions and cations have been successfully assembled from [Mn(TPP)(H(2)O)(2)](+) and [Ru(acac)(2)(CN)(2)](-) blocks. Systematic investigation of their magnetic properties reveals typical single-chain magnet (SCM) behaviors for both of them.
Zhang
Daopeng
D
Department of Chemistry, Shandong University, Jinan 250100, China.
Zhang
Li-Fang
LF
Chen
Yuting
Y
Wang
Hailong
H
Ni
Zhong-Hai
ZH
Wernsdorfer
Wolfgang
W
Jiang
Jianzhuang
J
D000838:Anions / Q000737:chemistry; D002412:Cations / Q000737:chemistry; D003460:Crystallization; D018360:Crystallography, X-Ray; D008280:Magnetics; D008345:Manganese / Q000737:chemistry*; D008665:Metalloporphyrins / Q000737:chemistry*; D008958:Models, Molecular; D012428:Ruthenium / Q000737:chemistry*
D000838:Anions; D002412:Cations; D008665:Metalloporphyrins; D008345:Manganese; D012428:Ruthenium