Intramolecular sigma-bond metathesis/protonolysis on zirconium(IV) and hafnium(IV) pyridylamido olefin polymerization catalyst precursors: exploring unexpected reactivity paths.
A temperature-controlled metathesis/protonolysis takes place on group 4 amidopyridinate polymerization catalyst precursors. Unraveling this unprecedented reactivity path allowed us to highlight the importance of the metal precursor choice while preparing improved catalytic structures or studying new catalytic processes.
Luconi
Lapo
L
Institute of Chemistry of OrganoMetallic Compounds, ICCOM-CNR, Via Madonna del Piano 10, 50019 Sesto F.no, Florence, Italy.
Giambastiani
Giuliano
G
Rossin
Andrea
A
Bianchini
Claudio
C
Lledós
Agustí
A