title: Chlorido(eta(5)-cyclopentadienyl)bis(dimethylamido)titanium, [TiCl(eta5-C5H5)(NMe2)2].
abstract: The title complex, [Ti(C(5)H(5))(C(2)H(6)N)(2)Cl], exhibits two nearly planar dimethylamide groups oriented approximately perpendicular to each other. The Ti-->cyclopentadienyl centroid vector lies nearly in the plane of one of the dimethylamide groups. Long-range contacts between Ti-Cl and cyclopentadienyl H-C groups give rise to geometric ordering in the extended solid.
authors.affiliation: Department of Chemistry, Harvey Mudd College, 301 Platt Boulevard, Claremont, CA 91711, USA.
authors.forename: Brette M
authors.initials: BM
authors.lastname: Chapin
authors.forename: Lauren D
authors.initials: LD
authors.lastname: Hughs
authors.forename: James A
authors.initials: JA
authors.lastname: Golen
authors.forename: Arnold L
authors.initials: AL
authors.lastname: Rheingold
authors.forename: Adam R
authors.initials: AR
authors.lastname: Johnson