Metal ion driven formation of a light-harvesting antenna investigated by sensitized luminescence and fluorescence anisotropy.
Zn(ii) complexation drives the formation of a light-harvesting antenna constituted by two multicomponent luminescent ligands: a cyclam-cored dendrimer decorated at the periphery with 16 naphthyl units and an anthracene-based molecular clip.
Branchi
Barbara
B
Dipartimento di Chimica G. Ciamician, Università di Bologna, via Selmi 2, I-40126 Bologna, Italy.
Bergamini
Giacomo
G
Fiandro
Luca
L
Ceroni
Paola
P
Vögtle
Fritz
F
Klärner
Frank-Gerrit
FG
D016880:Anisotropy; D007477:Ions / Q000737:chemistry; D008024:Ligands; D045342:Light-Harvesting Protein Complexes / Q000737:chemistry*; D049449:Luminescence; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D015032:Zinc / Q000737:chemistry*
D007477:Ions; D008024:Ligands; D045342:Light-Harvesting Protein Complexes; D009942:Organometallic Compounds; D015032:Zinc