Amido-stabilized rare-earth metal mixed methyl methylidene complexes.
Donor(thf)-induced tetramethylaluminate cleavage of Ln(AlMe(4))(2)(NSiMe(3)Ar(iPr)) as well as the reaction of (LnMe(3))(n) (Ln = Y, Ho, Lu) with HNSiMe(3)Ar(iPr) in tetrahydrofuran affords unprecedented trinuclear rare-earth metal tetramethyl methylidene complexes which act as Schrock-type nucleophilic carbenes and methyl transfer agents.
Zimmermann
Melanie
M
Department of Chemistry, University of Bergen, Allégaten 41, 5007 Bergen, Norway.
Rauschmaier
Dorothea
D
Eichele
Klaus
K
Törnroos
Karl W
KW
Anwander
Reiner
R