Chlorido(eta(5)-cyclopentadienyl)bis(dimethylamido)titanium, [TiCl(eta5-C5H5)(NMe2)2].
The title complex, [Ti(C(5)H(5))(C(2)H(6)N)(2)Cl], exhibits two nearly planar dimethylamide groups oriented approximately perpendicular to each other. The Ti-->cyclopentadienyl centroid vector lies nearly in the plane of one of the dimethylamide groups. Long-range contacts between Ti-Cl and cyclopentadienyl H-C groups give rise to geometric ordering in the extended solid.
Chapin
Brette M
BM
Department of Chemistry, Harvey Mudd College, 301 Platt Boulevard, Claremont, CA 91711, USA.
Hughs
Lauren D
LD
Golen
James A
JA
Rheingold
Arnold L
AL
Johnson
Adam R
AR