title: Effects of gas composition on highly efficient surface modification of multi-walled carbon nanotubes by cation treatment.
abstract: High incident energy hydrogen and/or oxygen cations are generated by electron cyclotron resonance system, and then used to highly efficiently modify multi-walled carbon nanotubes (MWCNTs). The effects of various H2/O2 gas compositions on the modification process are studied. A systematic characterization method utilizing a combination of X-ray photoelectron spectroscopy (XPS), scanning electron microscopy, Raman spectroscopy, and thermogravimetric analysis (TGA) is used to evaluate the effects of various H2/O2gas compositions on MWCNT functionalization. The Raman results show that the ID/IG ratio is directly affected by H2 concentration in gas mixture, and the treatment applying a H2/O2 gas mixture with ratio of 40/10 (sccm/sccm) can yield the nanotubes with the highest ID/IG ratio (1.27). The XPS results suggest that the gas mixture with ratio of 25/25 (sccm/sccm) is most effective in introducing oxygen-containing functional groups and reducing amorphous carbon. The TGA suggests that the structural change of the treated nanotubes is marginal by this method with any gas condition.
authors.affiliation: Institute of Materials and Systems Engineering, MingDao University, ChangHua, Taiwan. marine.mse92g@g2.nctu.edu.tw.
authors.forename: Wen-Shou
authors.initials: WS
authors.lastname: Tseng
authors.forename: Chyuan-Yow
authors.initials: CY
authors.lastname: Tseng
authors.forename: Cheng-Tzu
authors.initials: CT
authors.lastname: Kuo