title: The application of frequency swept pulses for the acquisition of nuclear quadrupole resonance spectra.
abstract: The acquisition of nuclear quadrupole resonance (NQR) spectra with wideband uniform rate and smooth truncation (WURST) pulses is investigated. (75)As and (35)Cl NQR spectra acquired with the WURST echo sequence are compared to those acquired with standard Hahn-echo sequences and echo sequences which employ composite refocusing pulses. The utility of WURST pulses for locating NQR resonances of unknown frequency is investigated by monitoring the integrated intensity and signal to noise of (35)Cl and (75)As NQR spectra acquired with transmitter offsets of several hundreds kilohertz from the resonance frequencies. The WURST echo sequence is demonstrated to possess superior excitation bandwidths in comparison to the pulse sequences which employ conventional monochromatic rectangular pulses. The superior excitation bandwidths of the WURST pulses allows for differences in the characteristic impedance of the receiving and excitation circuits of the spectrometer to be detected. Impedance mismatches have previously been reported by Marion and Desvaux [D.J.Y. Marion, H. Desvaux, J. Magn. Reson. (2008) 193(1) 153-157] and Muller et al. [M. Nausner, J. Schlagnitweit, V. Smrecki, X. Yang, A. Jerschow, N. Muller, J. Magn. Reson. (2009) 198(1) 73-79]. In this regard, WURST pulse sequences may afford an efficient new method for experimentally detecting impedance mismatches between receiving and excitation circuits, allowing for the optimization of solids and solution NMR and NQR spectrometer systems. The use of the Carr-Purcell Meiboom-Gill (CPMG) pulse sequence for signal enhancement of NQR spectra acquired with WURST pulses and conventional pulses is also investigated. Finally, the utility of WURST pulses for the acquisition of wideline NQR spectra is demonstrated by acquiring part of the (63/65)Cu NQR spectrum of CuCN.
authors.affiliation: Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario, Canada.
authors.forename: Aaron J
authors.initials: AJ
authors.lastname: Rossini
authors.forename: Hiyam
authors.initials: H
authors.lastname: Hamaed
authors.forename: Robert W
authors.initials: RW
authors.lastname: Schurko
mesh_terms: D000465:Algorithms; D001151:Arsenic; D002713:Chlorine; D003301:Copper Radioisotopes; D003486:Cyanides / Q000737:chemistry; D007554:Isotopes; D009682:Magnetic Resonance Spectroscopy / Q000295:instrumentation / Q000379:methods*
chemical_list: D003301:Copper Radioisotopes; D003486:Cyanides; D007554:Isotopes; D002713:Chlorine; D001151:Arsenic