title: Olefin epoxidation by hydrogen peroxide catalysed by molybdenum complexes in ionic liquids and structural characterisation of the proposed intermediate dioxoperoxomolybdenum species.
abstract: The complex [Mo(4)O(16)(dmpz)(6)] (1) has been isolated as part of a study of oxodiperoxomolybdenum catalysed epoxidation of olefin substrates with hydrogen peroxide in ionic liquids. Notably, 1 is the first dioxoperoxomolybdenum species to be structurally characterised.
authors.affiliation: Departamento de Química Inorgánica, Facultad de Química, Universidad de Sevilla, Aptdo 1203, 41071 Sevilla, Spain.
authors.forename: Matthew
authors.initials: M
authors.lastname: Herbert
authors.forename: Eleuterio
authors.initials: E
authors.lastname: Alvarez
authors.forename: David J
authors.initials: DJ
authors.lastname: Cole-Hamilton
authors.forename: Francisco
authors.initials: F
authors.lastname: Montilla
authors.forename: Agustín
authors.initials: A
authors.lastname: Galindo