title: Fluorocyanation of enamines.
abstract: A method for the fluorocyanation of enamines has been described. The reaction involves fluorination of the electron rich double bond with N-F reagent (Selectfluor or NFSI) accompanied by trapping of beta-fluoroiminium cationic intermediate with cyanide nucleophile.
authors.affiliation: N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation. adil25@mail.ru
authors.forename: Alexander D
authors.initials: AD
authors.lastname: Dilman
authors.forename: Pavel A
authors.initials: PA
authors.lastname: Belyakov
authors.forename: Marina I
authors.initials: MI
authors.lastname: Struchkova
authors.forename: Dmitry E
authors.initials: DE
authors.lastname: Arkhipov
authors.forename: Alexander A
authors.initials: AA
authors.lastname: Korlyukov
authors.forename: Vladimir A
authors.initials: VA
authors.lastname: Tartakovsky
mesh_terms: D000588:Amines / Q000737:chemistry*; D003486:Cyanides / Q000737:chemistry*; D005461:Fluorine / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy
chemical_list: D000588:Amines; D003486:Cyanides; D005461:Fluorine