Hydrogen spillover measurements of unbridged and bridged metal-organic frameworks--revisited.
The room-temperature hydrogen uptake of unbridged and bridged composites formed by a physical mixture of either (IRMOF-1)-(AC/Pt catalyst) or (IRMOF-1)-(AC/Pt catalyst) and sucrose, respectively, has been carefully measured and compared with previous results reported by Li and Yang. Contrary to their findings, no enhanced hydrogen uptake in the composite was found as compared to the initial IRMOF-1. If any spillover effect occurred it was below the detection limit.
Campesi
Renato
R
Chimie Métallurgique des Terres Rares, ICMPE, UMR7182, CNRS, 2 rue Henri Dunant, 94320 Thiais Cedex, France.
Cuevas
Fermín
F
Latroche
Michel
M
Hirscher
Michael
M
D000327:Adsorption; D006859:Hydrogen / Q000737:chemistry*; D008853:Microscopy; D009584:Nitrogen / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry; D013499:Surface Properties; D014961:X-Ray Diffraction
D009942:Organometallic Compounds; D010984:Platinum; D006859:Hydrogen; D009584:Nitrogen