Oxidative dimerization of N-protected and free indole derivatives toward 3,3-biindoles via Pd-catalyzed direct C-H transformations.
An oxidative homo dimerization of N-protected and free indole derivatives toward bioactive 3,3-linked biindolyl scaffolds via Pd-catalyzed direct C-H transformations was first successfully demonstrated.
Li
Yang
Y
Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 10087, China.
Wang
Wen-Hua
WH
Yang
Shang-Dong
SD
Li
Bi-Jie
BJ
Feng
Chun
C
Shi
Zhang-Jie
ZJ
D002384:Catalysis; D018360:Crystallography, X-Ray; D019281:Dimerization; D007211:Indoles / Q000138:chemical synthesis / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*
D007211:Indoles; D009942:Organometallic Compounds; D010165:Palladium