Hydrogels with cylindrically symmetric structure at macroscopic scale by self-assembly of semi-rigid polyion complex.
A hydrogel with cylindrically symmetric structure at macroscopic scale has been developed by polymerization of a cationic monomer in the presence of a small amount of semi-rigid polyanion poly(2,2'-disulfonyl-4,4'-benzidine terephthalamide) (PBDT) in a cylinder glass tube. The polyion complex radially aligns in the outer region of the synthesized cylinder gel. On the other hand, it orients in concentric and axial directions in the inner region. To the authors' knowledge, this is the first report of such millimeter-scale ordered structure developed in a polymeric hydrogel. We elucidate that homeotropic alignment on the glass wall is energetically favorable for the semi-rigid polyion complex, resulting in the radial orientation in the outer region. In the inner region, the oriented structures result from the monomer difffusion (due to the heterogeneous polymerization) that induces PBDT orientation perpendicular to the diffusion direction. The structured gels showing sensitive response of birefringence to external force are expected to find applications in optical sensors.
Wu
Zi Liang
ZL
Division of Biological Sciences, Graduate School of Science, Hokkaido University, Sapporo 060-0810, Japan.
Kurokawa
Takayuki
T
Liang
Songmiao
S
Furukawa
Hidemitsu
H
Gong
Jian Ping
JP
D001718:Birefringence; D005898:Glass / Q000737:chemistry; D020100:Hydrogels / Q000737:chemistry*; D008853:Microscopy; D055668:Photochemical Processes; D010797:Phthalimides / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D012996:Solutions
D020100:Hydrogels; D010797:Phthalimides; D011108:Polymers; D012996:Solutions; C510713:poly(2,2'-disulfonylbenzidine terephthalamide)