Synthesis, spectroscopy, electrochemistry and thermal study of Ni(II) and Cu(II) unsymmetrical N2O2 Schiff base complexes.
The new tetradentate unsymmetrical N(2)O(2) Schiff base ligands, Ni(II) and Cu(II) complexes were synthesised and chracterized by IR, UV-vis, (1)H NMR and elemental analysis. The electrochemical properties of the Ni(II) complexes were investigated. The thermogravimetry of the Ni(II) and Cu(II) complexes were carried out in the range of 20-700 degrees C. Decomposition of synthesised complexes is related to the Schiff base characteristics.
Kianfar
Ali Hossein
AH
Chemistry Department, Yasouj University, Yasouj, Iran. akianfar@mail.yu.ac.ir
Keramat
Liala
L
Dostani
Morteza
M
Shamsipur
Mojtaba
M
Roushani
Mahmoud
M
Nikpour
Farzad
F
D003300:Copper / Q000737:chemistry*; D055664:Electrochemical Techniques / Q000379:methods*; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D012545:Schiff Bases / Q000138:chemical synthesis* / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013818:Thermogravimetry
D012545:Schiff Bases; D003300:Copper; D009532:Nickel