Three's company: co-crystallization of a self-assembled S(4) metallacyclophane with two diastereomeric metallacycle intermediates.
Three discrete supramolecular self-assembled arsenic(iii) complexes including an unusual S(4)-symmetric tetranuclear [As(4)L(2)Cl(4)] metallacyclophane and two diastereomeric cis/trans-[As(2)LCl(2)] metallacycle intermediates co-crystallize within a single crystal lattice.
Lindquist
Nathan R
NR
Department of Chemistry and Material Science Institute, University of Oregon, and the Oregon Nanoscience and Microtechnologies Institute (ONAMI), Eugene, OR 97403-1253, USA.
Carter
Timothy G
TG
Cangelosi
Virginia M
VM
Zakharov
Lev N
LN
Johnson
Darren W
DW
D001151:Arsenic / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry*; D003460:Crystallization; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D013438:Sulfhydryl Compounds / Q000737:chemistry*
D002712:Chlorides; D008024:Ligands; D013438:Sulfhydryl Compounds; D001151:Arsenic