Conversion of nonporous helical cadmium organic framework to a porous form.
Two novel cadmium-organic frameworks containing achiral helical nanotubular channels, [Cd(HImDC)(S)](n) (S = Im(1) and Py(2)), have been synthesized and characterized using single crystal X-ray diffraction, in which 1 converts to 2 upon refluxing 1 in pyridine solution with noticeable porosity and hydrogen uptake at medium pressure.
Gu
Zhi-Gang
ZG
School of Chemistry and Environment, Key Lab of Technology on Electrochemical Energy Storage and Power Generation in Guangdong Universities, Engineering Research Center of Materials and Technology for Electrochemical EnergyStorage (Ministry of Education), South China Normal University, Guangzhou 510006.
Cai
Yue-Peng
YP
Fang
Hua-Cai
HC
Zhou
Zheng-Yuan
ZY
Thallapally
Praveen K
PK
Tian
Jian
J
Liu
Jun
J
Exarhos
Gregory J
GJ