Al3+ selective an efficient colorimetric receptor derived from 5-aminouracil.
An interference-free naked-eye recognition of Al(3+) at its micromolar level has been done in 5% aqueous DMSO solution employing a Schiff base 5-[(2-hydroxy-5-nitro-benzylidene)-amino]-1H-pyrimidine-2,4-dione (receptor 1) which is an intramolecular charge transfer (ICT) probe. The pyrimidine and nitrophenyl groups serve as electron rich (donor) and deficient (acceptor) pockets in receptor 1 exhibiting a broad ICT band at 434 nm (olive green). The concomitant additions of Al(3+) as its chloride salt to the 5x10(-5) M aqueous DMSO solution of the receptor 1 lead hypsochromic shifting of its ICT band to 395 nm (colorless). The same ICT band undergoes a marginal bathochromic shifting (6 nm) along with a hyperchromic shift on separate additions of a basic anion like F(-), CH(3)COO(-) and H(2)PO(4)(-) to the receptor 1 and faced almost similar fate on concomitant additions of Al(3+) as mentioned above.
Upadhyay
K K
KK
Department of Chemistry, Faculty of Science, Banaras Hindu University, Varanasi, Uttar Pradesh, India. drkaushalbhu@yahoo.co.in
Kumar
Ajit
A
D000535:Aluminum / Q000032:analysis* / Q000737:chemistry; D003124:Colorimetry / Q000379:methods*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D014498:Uracil / Q000031:analogs & derivatives* / Q000737:chemistry
D014498:Uracil; D000535:Aluminum; C011166:5-aminouracil