title: Heterobimetallic porphyrin-based single-chain magnet constructed from manganese(III)-porphyrin and trans-dicyanobis(acetylacetonato) ruthenate(III) containing co-crystallized bulk anions and cations.
abstract: Two cyanide-bridged alternated 1 : 1 Ru(III)/Mn(III) complexes structurally characterized as single-chain containing co-crystallized bulk anions and cations have been successfully assembled from [Mn(TPP)(H(2)O)(2)](+) and [Ru(acac)(2)(CN)(2)](-) blocks. Systematic investigation of their magnetic properties reveals typical single-chain magnet (SCM) behaviors for both of them.
authors.affiliation: Department of Chemistry, Shandong University, Jinan 250100, China.
authors.forename: Daopeng
authors.initials: D
authors.lastname: Zhang
authors.forename: Li-Fang
authors.initials: LF
authors.lastname: Zhang
authors.forename: Yuting
authors.initials: Y
authors.lastname: Chen
authors.forename: Hailong
authors.initials: H
authors.lastname: Wang
authors.forename: Zhong-Hai
authors.initials: ZH
authors.lastname: Ni
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Wernsdorfer
authors.forename: Jianzhuang
authors.initials: J
authors.lastname: Jiang
mesh_terms: D000838:Anions / Q000737:chemistry; D002412:Cations / Q000737:chemistry; D003460:Crystallization; D018360:Crystallography, X-Ray; D008280:Magnetics; D008345:Manganese / Q000737:chemistry*; D008665:Metalloporphyrins / Q000737:chemistry*; D008958:Models, Molecular; D012428:Ruthenium / Q000737:chemistry*
chemical_list: D000838:Anions; D002412:Cations; D008665:Metalloporphyrins; D008345:Manganese; D012428:Ruthenium