title: Recent advances in stereoselective glycosylation through intramolecular aglycon delivery.
abstract: Methodology toward the stereoselective 1,2-cis glycoside linkage using intramolecular aglycon delivery (IAD) has been extensively developed. In the last two decades, progress has been made using various mixed acetal linkages and a number of glycosyl donor moieties to develop novel IAD strategies, mainly based on formation of acetal linkages. This account summarizes the newest naphthylmethyl (NAP) ether-mediated IAD as well as all the types of mediations for stereospecific construction of various 1,2-cis linkages, not only for beta-mannopyranoside, but also for other linkages almost without exception, including beta-L-rhamnoside.
authors.affiliation: RIKEN Advanced Science Institute, 2-1 Hirosawa, Wako, Saitama 351-0198, Japan. aishiwa@riken.jp
authors.forename: Akihiro
authors.initials: A
authors.lastname: Ishiwata
authors.forename: Yong Joo
authors.initials: YJ
authors.lastname: Lee
authors.forename: Yukishige
authors.initials: Y
authors.lastname: Ito
mesh_terms: D000080:Acetals / Q000737:chemistry; D006027:Glycosides / Q000737:chemistry*; D006031:Glycosylation; D007659:Ketones / Q000737:chemistry; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D000080:Acetals; D006027:Glycosides; D007659:Ketones