Oxidative addition of the bismuth-chloride bond: synthesis and structure of trans-[PtCl(PCy3)2{BiCl2}].
The synthesis and full characterisation of trans-[PtCl(PCy(3))(2){BiCl(2)}] is reported via the oxidative addition of the bismuth-chloride bond across [Pt(PCy(3))(2)]; this represents the first instance of such an oxidative addition reaction to be undertaken by a bismuth halide bond.
Braunschweig
Holger
H
Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, 97074 Würzburg, Germany. h.braunschweig@mail.uni-wuerzburg.de
Brenner
Peter
P
Cogswell
Paul
P
Kraft
Katharina
K
Schwab
Katrin
K