title: Spontaneous symmetry breaking during self-assembly of a double stranded biphenolate-based Ti(IV)-helicate.
abstract: A binuclear Ti(IV)-based helicate synthesized from a symmetric tetrahydroxyheptaphenylene strand was self-assembled in solution and shown to undergo a spontaneous head-to-tail differentiation according to single-crystal X-ray diffraction.
authors.affiliation: Laboratoire de Chimie moléculaire de l'Etat Solide, UMR 7140, Strasbourg, France.
authors.forename: Carine
authors.initials: C
authors.lastname: Diebold
authors.forename: Pierre
authors.initials: P
authors.lastname: Mobian
authors.forename: Clarisse
authors.initials: C
authors.lastname: Huguenard
authors.forename: Lionel
authors.initials: L
authors.lastname: Allouche
authors.forename: Marc
authors.initials: M
authors.lastname: Henry