Oxygenation chemistry at a mononuclear copper(II) hydroquinone system with O2.
Aerobic treatment of a copper(II) complex supported by a bis(pyridin-2-ylmethyl)amine ligand containing a p-hydroquinone moiety on one of the pyridine donor groups in CH(3)OH induces oxygenation reaction of the ligand to give a hydroxylated p-quinone derivative.
Tabuchi
Kae
K
Department of Material and Life Science, Division of Advanced Science and Biotechnology, Graduate School of Engineering, Osaka University, 2-1 Yamada-oka, Suita, Osaka 565-0871, Japan.
Sugimoto
Hideki
H
Kunishita
Atsushi
A
Fujieda
Nobutaka
N
Itoh
Shinobu
S
D000332:Aerobiosis; D003300:Copper / Q000737:chemistry*; D006873:Hydroquinones / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*
D006873:Hydroquinones; D009942:Organometallic Compounds; D003300:Copper; D010100:Oxygen; C031927:hydroquinone