Enhanced adsorption of Methylene Blue from aqueous solution by chitosan-g-poly (acrylic acid)/vermiculite hydrogel composites.
A series of chitosan-g-poly (acrylic acid)/vermiculite hydrogel composites were synthesized and used as adsorbents for the investigation of the effect of process parameters such as vermiculite content, pH of dye solution, contact time, initial concentration of dye solution, temperature, ionic strength and concentration of surfactant sodium dodecyl sulfate on the removal of Methylene Blue (MB) from aqueous solution. The results showed that the adsorption capacity for dye increased with increasing pH, contact time and initial dye concentration, but decreased with increasing temperature, ionic strength and sodium dodecyl sulfate concentration in the present of the surfactant. The adsorption kinetics of MB onto the hydrogel composite followed pseudo second-order kinetics and the adsorption equilibrium data obeyed Langmuir isotherm. By introducing 10 wt.% vermiculite into chitosan-g-poly (acrylic acid) polymeric network, the obtaining hydrogel composite showed the highest adsorption capacity for MB, and then could be regarded as a potential adsorbent for cationic dye removal in a wastewater treatment process.
Liu
Yi
Y
Center of Eco-material and Green Chemistry, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China. liuyiyongcheng@163.com
Zheng
Yian
Y
Wang
Aiqin
A
D000180:Acrylic Resins / Q000737:chemistry*; D000327:Adsorption; D000538:Aluminum Silicates / Q000737:chemistry*; D048271:Chitosan / Q000737:chemistry*; D020100:Hydrogels / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D008751:Methylene Blue / Q000737:chemistry*; D009994:Osmolar Concentration; D012967:Sodium Dodecyl Sulfate / Q000737:chemistry; D013696:Temperature; D013997:Time Factors; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D018508:Water Purification / Q000379:methods
D000180:Acrylic Resins; D000538:Aluminum Silicates; D020100:Hydrogels; D014874:Water Pollutants, Chemical; C065246:chitosan-poly(acrylic acid); C003760:vermiculite; D012967:Sodium Dodecyl Sulfate; D048271:Chitosan; D008751:Methylene Blue