A structural and functional mimic of the active site of NiFe hydrogenases.
The structural mimic of the active site of NiFe hydrogenases, [Ni(xbsms)FeCp(CO)](BF(4)), is an electrocatalyst for hydrogen evolution from trifluoroacetic acid in DMF.
Canaguier
Sigolène
S
Laboratoire de Chimie et Biologie des Métaux, Université Joseph Fourier, Grenoble, France.
Field
Martin
M
Oudart
Yohan
Y
Pécaut
Jacques
J
Fontecave
Marc
M
Artero
Vincent
V
D040761:Biomimetic Materials / Q000737:chemistry*; D002384:Catalysis; D020134:Catalytic Domain; D006859:Hydrogen / Q000737:chemistry; D006864:Hydrogenase / Q000737:chemistry*; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D014269:Trifluoroacetic Acid / Q000737:chemistry
D009942:Organometallic Compounds; D006859:Hydrogen; D014269:Trifluoroacetic Acid; C043296:nickel-iron hydrogenase; D006864:Hydrogenase