title: A new ZnO nanotetrapods/SnO2 nanoparticles composite photoanode for high efficiency flexible dye-sensitized solar cells.
abstract: We report a new photoanode for flexible dye sensitized solar cells based on a judicious combination of SnO(2) nanoparticles and ZnO nanotetrapods and the development of an effective low temperature fabrication technique of "acetic acid gelation-mechanical press-ammonia activation". A 4.91% efficiency has been achieved on an ITO-coated polyethylenenaphthalate (ITO/PEN) substrate under 1 sun equivalent illumination. The peculiar symmetrical branching morphology of ZnO nanotetrapods is beneficial to charge collection of the SnO(2)/ZnO composite photoanode. The formation of a thin ZnO shell on SnO(2) nanoparticles, after ammonia activation, is critical to boosting the open-circuit photovoltage and to improving inter-particle contacts as well as photoelectron injection. The mechanical press, apart from enhancing film durability, has also significantly improved charge collection.
authors.affiliation: Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, People's Republic of China.
authors.forename: Wei
authors.initials: W
authors.lastname: Chen
authors.forename: Yongcai
authors.initials: Y
authors.lastname: Qiu
authors.forename: Shihe
authors.initials: S
authors.lastname: Yang