title: In-situ Dimanganese Catalyst for Fast Screening of Molecular Recognition Catalysts for Regioselective Oxygenation of an sp C-H Bond.
abstract: We report a rapid method for assembling our di-μ-oxo dimanganese catalyst, verified by ESI-MS and EPR, assessing its water oxidation activity by a Clark electrode O(2)-assay study and its regioselective C-H activation activity by product analysis in catalytic runs.
authors.affiliation: Department of Chemistry, Yale University, P.O. Box 208107, New Haven, Connecticut, 06520-8107.
authors.forename: Siddhartha
authors.initials: S
authors.lastname: Das
authors.forename: Gary W
authors.initials: GW
authors.lastname: Brudvig
authors.forename: Robert H
authors.initials: RH
authors.lastname: Crabtree