title: A structural and functional mimic of the active site of NiFe hydrogenases.
abstract: The structural mimic of the active site of NiFe hydrogenases, [Ni(xbsms)FeCp(CO)](BF(4)), is an electrocatalyst for hydrogen evolution from trifluoroacetic acid in DMF.
authors.affiliation: Laboratoire de Chimie et Biologie des Métaux, Université Joseph Fourier, Grenoble, France.
authors.forename: Sigolène
authors.initials: S
authors.lastname: Canaguier
authors.forename: Martin
authors.initials: M
authors.lastname: Field
authors.forename: Yohan
authors.initials: Y
authors.lastname: Oudart
authors.forename: Jacques
authors.initials: J
authors.lastname: Pécaut
authors.forename: Marc
authors.initials: M
authors.lastname: Fontecave
authors.forename: Vincent
authors.initials: V
authors.lastname: Artero
mesh_terms: D040761:Biomimetic Materials / Q000737:chemistry*; D002384:Catalysis; D020134:Catalytic Domain; D006859:Hydrogen / Q000737:chemistry; D006864:Hydrogenase / Q000737:chemistry*; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D014269:Trifluoroacetic Acid / Q000737:chemistry
chemical_list: D009942:Organometallic Compounds; D006859:Hydrogen; D014269:Trifluoroacetic Acid; C043296:nickel-iron hydrogenase; D006864:Hydrogenase