title: Synthesis, structure, and theoretical investigation of amidinato supported 1,4-disilabenzene.
abstract: Reaction of LSi-SiL (1) (L = PhC(NtBu)(2)) with diphenyl alkyne gave the first example of a room temperature stable 1,4-disilabenzene. The compound was characterized by means of single crystal X-ray diffraction studies. NICS (nucleus independent chemical shift) calculations showed that the compound has some aromatic character.
authors.affiliation: Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen, Germany.
authors.forename: Sakya S
authors.initials: SS
authors.lastname: Sen
authors.forename: Herbert W
authors.initials: HW
authors.lastname: Roesky
authors.forename: Kathrin
authors.initials: K
authors.lastname: Meindl
authors.forename: Daniel
authors.initials: D
authors.lastname: Stern
authors.forename: Julian
authors.initials: J
authors.lastname: Henn
authors.forename: A Claudia
authors.initials: AC
authors.lastname: Stückl
authors.forename: Dietmar
authors.initials: D
authors.lastname: Stalke