Self-assembled cage as an endo-template for cyclophane synthesis.
An organic-pillared coordination cage templated the quantitative formation of siloxane-bridged cyclophanes within its cavity via hydrolysis and condensation of 1,6- and 1,8-bis(trimethoxysilyl)pyrene.
Yamauchi
Yoshihiro
Y
Department of Applied Chemistry, School of Engineering, The University of Tokyo and CREST, Japan Science and Technology Agency, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.
Fujita
Makoto
M