title: Mathematical modeling of MSW combustion and SNCR in a full-scale municipal incinerator and effects of grate speed and oxygen-enriched atmospheres on operating conditions.
abstract: The rising popularity of incineration of municipal solid waste (MSW) calls for detailed mathematical modeling and accurate prediction of pollutant emissions. In this paper, mathematical modeling methods for both solid and gaseous phases were employed to simulate the operation of a 450 t/d MSW-burning incinerator to obtain detailed information on the flow and combustion characteristics in the furnace and to predict the amount of pollutant emissions. The predicted data were compared to on-site measurements of gas temperature, gas composition and SNCR de-NO(X) system. The major operating conditions considered in this paper were grate speed and oxygen concentration. A suitable grate speed ensures complete waste combustion. The predictions are as follows: volatile release increases with increasing grate speed, and the maximal value is within the range of 700-800 kg/m(2)h; slow grate speeds result in incomplete combustion of fixed carbon; the gas temperature at slow grate speeds is higher due to adequate oxygenation for fixed carbon combustion, and the deviation reaches 200K; NO(X) emission decreases, but CO emission and O(2) concentrations increase, and the deviation is 63%, 34% and 35%, respectively. Oxygen-enriched atmospheres promote the destruction of most pollutants due to the high oxygen partial pressure and temperature. The furnace temperature, NO production and CO emission increase as the oxygen concentration increases, and the deviation of furnace exit temperature, NO and CO concentration is 38.26%, 58.43% and 86.67%, respectively. Finally, oxygen concentration is limited to below 35% to prevent excessive CO and NO(X) emission without compromising plant performance. The current work greatly helps to understand the operating characteristics of large-scale MSW-burning plants.
authors.affiliation: School of Electric Power, Guangdong Key Laboratory of Clean Energy Technology, South China University of Technology, Guangzhou 510640, China. zengyingliang@yahoo.cn
authors.forename: Zengying
authors.initials: Z
authors.lastname: Liang
authors.forename: Xiaoqian
authors.initials: X
authors.lastname: Ma
mesh_terms: D001272:Atmosphere / Q000737:chemistry*; D002947:Cities; D017745:Incineration / Q000295:instrumentation / Q000379:methods*; D008956:Models, Chemical; D008962:Models, Theoretical; D009589:Nitrogen Oxides / Q000032:analysis; D010100:Oxygen / Q000737:chemistry*
chemical_list: D009589:Nitrogen Oxides; D010100:Oxygen