Parahydrogen-induced polarization in alkyne hydrogenation catalyzed by Pd nanoparticles embedded in a supported ionic liquid phase.
Parahydrogen-induced polarization was observed in the gas phase heterogeneous hydrogenation of propyne catalyzed by Pd(0) nanoparticles embedded in an ionic liquid phase supported on activated carbon fibers (Pd(0)/SILP/ACF). The results were markedly different from those obtained with a reference catalyst, Pd(0)/ACF, demonstrating the important role of the ionic liquid.
Kovtunov
Kirill V
KV
International Tomography Center, 3A Institutskaya St., Novosibirsk 630090, Russia.
Zhivonitko
Vladimir V
VV
Kiwi-Minsker
Lioubov
L
Koptyug
Igor V
IV