Two new dihydrobenzofuran lignans from Rabdosia lophanthoides (Buch.-Ham.ex D.Don) Hara.
Two new dihydrobenzofuran lignanosides, (7R,8S)-4,3',9'-trihydroxyl-3-methoxyl-7,8-dihydrobenzofuran-1'-propylneolignan-9-O-(6-O-syringoyl)-beta-D-glucopyranoside, named lophanthoside B (1) and (7R,8S)-4,9,9'-trihydroxyl-3-methoxyl-7,8-dihydrobenzofuran-1'-propylneolignan-3'-O-beta-D-glucopyranoside (2), an enantiomer of umbroside, along with four known dihydrobenzofuran lignans (3-6), were isolated from 50% acetone extract of Rabdosia lophanthoides (Buch.-Ham.ex D.Don) Hara. Their structures were elucidated by NMR and MS experiments.
Feng
Wei-Sheng
WS
School of Pharmaceutical Science, Henan University of Traditional Chinese Medicine, Zhengzhou, China. fwsh@hactcm.edu.cn
Zang
Xin-Yu
XY
Zheng
Xiao-Ke
XK
Wang
Yan-Zhi
YZ
Chen
Hui
H
Li
Zhen
Z
D001572:Benzofurans / Q000737:chemistry / Q000302:isolation & purification*; D004365:Drugs, Chinese Herbal / Q000737:chemistry; D006027:Glycosides / Q000737:chemistry / Q000302:isolation & purification*; D037602:Isodon / Q000737:chemistry*; D017705:Lignans / Q000737:chemistry / Q000302:isolation & purification*; D015394:Molecular Structure; D019906:Nuclear Magnetic Resonance, Biomolecular; D013237:Stereoisomerism
C551206:(7R,8S)-4,9,9'-trihydroxyl-3-methoxyl-7,8-dihydrobenzofuran-1'-propylneolignan-3'-O-beta-D-glucopyranoside; D001572:Benzofurans; D004365:Drugs, Chinese Herbal; D006027:Glycosides; D017705:Lignans; C551207:lophanthoside B