Structural characterization and electrochemical properties of novel salicylidene phosphonate derivatives.
In this study, three novel salicylidene phosphonate ligands, diethyl (4-{[(1E)-(2-hydroxyphenyl)methylidene]amino}benzyl)phosphonate (HL1), diethyl (4-{[(1E)-(2-hydroxy-3-methoxyphenyl)methylidene]amino}benzyl)phosphonate (HL2) and diethyl (4-{[(1E)-(2,4-dihydroxyphenyl)methylidene]amino}benzyl)phosphonate (HL3) were synthesized and characterized by the analytical and spectroscopic techniques. We obtained their single crystals from the ethanolic solution. There are intramolecular phenol-imine hydrogen bonds in all three compounds between O1 and N1 atoms. The ligand HL3 contains a second phenol group and this is makes an intermolecular hydrogen bond with the phosphine oxide of a neighbouring molecule O2-O3 (under symmetry operation -x, 0.5+y, 0.5-z). In order to investigate the redox behaviours of the salicylidene phosphonate ligands (HL1-HL3), we were studied electrochemical properties of the ligands at the different pH and scan rates.
Dolaz
Mustafa
M
Kahramanmaras Sutcu Imam University, Faculty of Engineering and Architecture, Department of Environmental Engineering, K. Maras, Turkey. mdolaz@ksu.edu.tr
McKee
Vickie
V
Köse
Muhammet
M
Gölcü
Ayşegül
A
Tümer
Mehmet
M
D018360:Crystallography, X-Ray; D004563:Electrochemistry; D006860:Hydrogen Bonding; D008024:Ligands; D008968:Molecular Conformation; D063065:Organophosphonates / Q000737:chemistry*; D020156:Salicylic Acid / Q000737:chemistry*; D013696:Temperature
D008024:Ligands; D063065:Organophosphonates; D020156:Salicylic Acid