Thermodynamic Origin of Prolyl Peptide Bond Isomers.
The thermodynamic preference for the trans isomer of prolyl peptide bonds arises almost entirely from enthalpy in aqueous buffer and in toluene.
Eberhardt
Eric S
ES
Department of Biochemistry, University of Wisconsin, Madison, WI 53706-1569 USA.
Loh
Stewart N
SN
Raines
Ronald T
RT