In-situ Dimanganese Catalyst for Fast Screening of Molecular Recognition Catalysts for Regioselective Oxygenation of an sp C-H Bond.
We report a rapid method for assembling our di-μ-oxo dimanganese catalyst, verified by ESI-MS and EPR, assessing its water oxidation activity by a Clark electrode O(2)-assay study and its regioselective C-H activation activity by product analysis in catalytic runs.
Das
Siddhartha
S
Department of Chemistry, Yale University, P.O. Box 208107, New Haven, Connecticut, 06520-8107.
Brudvig
Gary W
GW
Crabtree
Robert H
RH