title: [Oxidation of dermatan sulfate with a NaOCl-NaBr-2,2,6,6-tetramethylpiperidine-1-oxyl reagent in the water medium].
abstract: The oxidation of primary hydroxyl groups in dermatan sulfate with the NaOCl-NaBr-2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) reagent in an aqueous alkaline environment was carried out for the first time. Modified dermatan sulfates containing hydrated aldehyde (15-50%) and carboxyl (25-100%) groups were obtained.
authors.forename: I Iu
authors.initials: IIu
authors.lastname: Ponedel'kina
authors.forename: E A
authors.initials: EA
authors.lastname: Khaĭbrakhmanova
authors.forename: V N
authors.initials: VN
authors.lastname: Odinokov
authors.forename: L M
authors.initials: LM
authors.lastname: Khalilov
authors.forename: U M
authors.initials: UM
authors.lastname: Dzhemilev
mesh_terms: D001965:Bromides / Q000737:chemistry*; D003497:Cyclic N-Oxides / Q000737:chemistry*; D003871:Dermatan Sulfate / Q000031:analogs & derivatives* / Q000737:chemistry*; D010084:Oxidation-Reduction; D017670:Sodium Compounds / Q000737:chemistry*; D012973:Sodium Hypochlorite / Q000737:chemistry*; D014867:Water
chemical_list: D001965:Bromides; D003497:Cyclic N-Oxides; D017670:Sodium Compounds; D014867:Water; D003871:Dermatan Sulfate; D012973:Sodium Hypochlorite; C027938:sodium bromide; C003959:TEMPO