State-to-state inelastic scattering of Stark-decelerated OH radicals with Ar atoms.
The Stark deceleration method exploits the concepts of charged particle accelerator physics to produce molecular beams with a tunable velocity. These tamed molecular beams offer interesting perspectives for precise crossed beam scattering studies as a function of the collision energy. The method has advanced sufficiently to compete with state-of-the-art beam methods that are used for scattering studies throughout. This is demonstrated here for the scattering of OH radicals (X(2)Pi(3/2), J = 3/2, f) with Ar atoms, a benchmark system for the scattering of open-shell molecules with atoms. Parity-resolved integral state-to-state inelastic scattering cross sections are measured at collision energies between 80 and 800 cm(-1). The threshold behavior and collision energy dependence of 13 inelastic scattering channels is accurately determined. Excellent agreement is obtained with the cross sections predicted by close-coupling scattering calculations based on the most accurate ab initio OH + Ar potential energy surfaces to date.
Scharfenberg
Ludwig
L
Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany.
Kłos
Jacek
J
Dagdigian
Paul J
PJ
Alexander
Millard H
MH
Meijer
Gerard
G
van de Meerakker
Sebastiaan Y T
SY