Carbon-carbon cross coupling reactions in ionic liquids catalysed by palladium metal nanoparticles.
A brief summary of selected pioneering and mechanistic contributions in the field of carbon-carbon cross-coupling reactions with palladium nanoparticles (Pd-NPs) in ionic liquids (ILs) is presented. Five exemplary model systems using the Pd-NPs/ILs approach are presented: Heck, Suzuki, Stille, Sonogashira and Ullmann reactions which all have in common the use of ionic liquids as reaction media and the use of palladium nanoparticles as reservoir for the catalytically active palladium species.
Prechtl
Martin H G
MH
Laboratory of Molecular Catalysis, Universidade Federal do Rio Grande do Sul, Avenida Bento Gonçalves 9500, 91501-970 Porto Alegre/RS, Brazil. martin.prechtl@hu-berlin.de
Scholten
Jackson D
JD
Dupont
Jairton
J
D002244:Carbon / Q000737:chemistry; D002384:Catalysis; D052578:Ionic Liquids / Q000737:chemistry*; D053768:Metal Nanoparticles; D055601:Organic Chemistry Phenomena; D010165:Palladium / Q000737:chemistry*
D052578:Ionic Liquids; D010165:Palladium; D002244:Carbon