Flexibility of cubane-like Cu4I4 framework: temperature dependence of molecular structure and luminescence thermochromism of [Cu4I4(PPh3)4] in two polymorphic crystalline states.
Multitemperature X-ray structure analyses and photoemission spectra of [Cu(4)I(4)(PPh(3))(4)] in two polymorphic crystals reveal that the cubane-like framework is flexibly distorted effecting luminescence thermochromism.
Kitagawa
Hakuba
H
Graduate School of Material Science, University of Hyogo, 3-2-1, Kouto, Kamigori-cho, Hyogo 678-1297, Japan.
Ozawa
Yoshiki
Y
Toriumi
Koshiro
K
D056831:Coordination Complexes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D049449:Luminescence; D008958:Models, Molecular; D015394:Molecular Structure; D011108:Polymers / Q000737:chemistry*; D013696:Temperature
D056831:Coordination Complexes; D011108:Polymers