Rearrangement of 2,3-epoxy alcohol dimethylthiocarbamate derivatives. Synthesis of 2,3-epithio alcohol derivatives under mild conditions.
Transformation of representative 2,3-epoxy alcohols, including 3-trimethylsilyl- and 3-triphenylsilylglycidols, into the corresponding 2,3-epithio alcohol dimethylthiocarbamate derivatives under mild alkaline conditions is reported.
Kalicki
Przemysław
P
Institute of Organic Chemistry, Polish Academy of Sciences, ul. Kasprzaka 44/52, 01-224 Warsaw 48, Poland.
Karchier
Michał
M
Michalak
Karol
K
Wicha
Jerzy
J
D000438:Alcohols / Q000138:chemical synthesis* / Q000737:chemistry; D002851:Chromatography, High Pressure Liquid; D018360:Crystallography, X-Ray; D013057:Spectrum Analysis; D013859:Thiocarbamates / Q000737:chemistry*
D000438:Alcohols; D013859:Thiocarbamates; C492475:dimethylthiocarbamate