title: Temperature dependence of binary and ternary recombination of D3+ ions with electrons.
abstract: Flowing and stationary afterglow experiments were performed to study the recombination of D(3)(+) ions with electrons at temperatures from 77 to 300 K. A linear dependence of apparent (effective) binary recombination rate coefficients on the pressure of the helium buffer gas was observed. Binary (D(3)(+)+e(-)) and ternary (D(3)(+)+e(-)+He) recombination rate coefficients were derived. The obtained binary rate coefficient agrees with recent theoretical values for dissociative recombination of D(3)(+). We describe the observed ternary process by a mechanism with two rate determining steps. In the first step, a rotationally excited long-lived neutral D(3)* is formed in D(3)(+)-e(-) collisions. As the second step, the D(3)* collides with a helium atom that prevents autoionization of D(3)*. We calculate lifetimes of D(3)* formed from ortho-, para-, or metastates of D(3)(+) and use the lifetimes to calculate ternary recombination rate coefficients.
authors.affiliation: Faculty of Mathematics and Physics, Charles University, 12116 Prague, Czech Republic.
authors.forename: T
authors.initials: T
authors.lastname: Kotrík
authors.forename: P
authors.initials: P
authors.lastname: Dohnal
authors.forename: I
authors.initials: I
authors.lastname: Korolov
authors.forename: R
authors.initials: R
authors.lastname: Plasil
authors.forename: S
authors.initials: S
authors.lastname: Roucka
authors.forename: J
authors.initials: J
authors.lastname: Glosík
authors.forename: Chris H
authors.initials: CH
authors.lastname: Greene
authors.forename: V
authors.initials: V
authors.lastname: Kokoouline