Size-controlled synthesis of Pd nanocrystals using a specific multifunctional peptide.
Here we report a peptide-mediated synthesis of Pd NCs in aqueous solution with controllable size in the sub-10 nanometre regime. The specific multifunctional peptide Q7 selected using the phage display technique can bind to the Pd NC surface and act as a stabilizer to mediate Pd crystal nucleation and growth. At the nucleation stage, Q7 bound to and helped stabilize the different-sized small Pd NC nuclei achieved using different concentrations of the external reducing agent, NaBH4. At the growth stage, Q7 played the dual role of binding to and reducing the precursor onto the existing nuclei, which led to the further controllable growth of the Pd NCs. By using the variable sizes of nuclei as seeds, and by introducing different amounts of precursors Pd NCs with tunable sizes from 2.6 to 6.6 nm were achieved with good size distribution.
Chiu
Chin-Yi
CY
Department of Materials Science and Engineering, University of California, Los Angeles, California 90095, USA.
Li
Yujing
Y
Huang
Yu
Y
D001894:Borohydrides / Q000737:chemistry; D053768:Metal Nanoparticles / Q000737:chemistry*; D046529:Microscopy, Electron, Transmission; D010165:Palladium / Q000737:chemistry*; D010316:Particle Size; D019151:Peptide Library; D010455:Peptides / Q000737:chemistry*; D013499:Surface Properties
D001894:Borohydrides; D019151:Peptide Library; D010455:Peptides; D010165:Palladium; C025364:sodium borohydride