[Oxidation of dermatan sulfate with a NaOCl-NaBr-2,2,6,6-tetramethylpiperidine-1-oxyl reagent in the water medium].
The oxidation of primary hydroxyl groups in dermatan sulfate with the NaOCl-NaBr-2,2,6,6-tetramethylpiperidine-1-oxyl (TEMPO) reagent in an aqueous alkaline environment was carried out for the first time. Modified dermatan sulfates containing hydrated aldehyde (15-50%) and carboxyl (25-100%) groups were obtained.
Ponedel'kina
I Iu
IIu
Khaĭbrakhmanova
E A
EA
Odinokov
V N
VN
Khalilov
L M
LM
Dzhemilev
U M
UM
D001965:Bromides / Q000737:chemistry*; D003497:Cyclic N-Oxides / Q000737:chemistry*; D003871:Dermatan Sulfate / Q000031:analogs & derivatives* / Q000737:chemistry*; D010084:Oxidation-Reduction; D017670:Sodium Compounds / Q000737:chemistry*; D012973:Sodium Hypochlorite / Q000737:chemistry*; D014867:Water
D001965:Bromides; D003497:Cyclic N-Oxides; D017670:Sodium Compounds; D014867:Water; D003871:Dermatan Sulfate; D012973:Sodium Hypochlorite; C027938:sodium bromide; C003959:TEMPO