title: Fipronil mobility and transformation in undisturbed soil columns.
abstract: The downward movement of fipronil and its two toxic metabolites i.e. sulfone and desulfinyl were studied in undisturbed soil columns. Mobility behavior of two different formulations of fipronil viz granular and suspension concentrate were also studied. The undisturbed columns containing sandy loam soil were leached with water equivalent to 400 mm rainfall. Results revealed that although majority of the fipronil (approximately 80%) remained in top 0-5 cm layer, substantial amount (approximately 15%) moved to 5-10 cm depth. In case of metabolites sulfone and desulfinyl >90% of the residues remained in 0-5 cm core indicating low mobility of these metabolites in comparison to fipronil. Results of mobility behavior of fipronil in granular and SC formulations revealed low mobility in granular formulation. Sulfide was detected as the major degradation product in both the formulations and was found to be distributed throughout the column. A little amount of sulfone (0.1% of the total recovered) was also detected upto 10 cm depth.
authors.affiliation: Division of Agricultural Chemicals, Indian Agricultural Research Institute, New Delhi, India.
authors.forename: Niladri Sekhar
authors.initials: NS
authors.lastname: Chatterjee
authors.forename: Suman
authors.initials: S
authors.lastname: Gupta
mesh_terms: D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods; D007306:Insecticides / Q000737:chemistry* / Q000378:metabolism; D011720:Pyrazoles / Q000737:chemistry* / Q000378:metabolism; D012987:Soil / Q000032:analysis*; D012989:Soil Pollutants / Q000737:chemistry*; D013450:Sulfones / Q000737:chemistry; D014867:Water / Q000737:chemistry; D014872:Water Movements; D014876:Water Pollution / Q000032:analysis
chemical_list: D007306:Insecticides; D011720:Pyrazoles; D012987:Soil; D012989:Soil Pollutants; D013450:Sulfones; D014867:Water; C082360:fipronil