title: Platinum-catalyzed cross-dehydrogenative coupling reaction in the absence of oxidant.
abstract: A third strategy for cross-dehydrogenative coupling reaction has been reported via platinum-catalyzed sp(3) C-H and sp(3) C-H coupling reaction in the absence of oxidant. Nitroalkanes as well as dialkyl malonate derivatives, beta-keto esters and malononitrile are active participants in this coupling reaction. Both cyclic and acyclic non-activated simple ketones are good reactants in this reaction.
authors.affiliation: State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000, PR China.
authors.forename: Xing-Zhong
authors.initials: XZ
authors.lastname: Shu
authors.forename: Yan-Fang
authors.initials: YF
authors.lastname: Yang
authors.forename: Xiao-Feng
authors.initials: XF
authors.lastname: Xia
authors.forename: Ke-Gong
authors.initials: KG
authors.lastname: Ji
authors.forename: Xue-Yuan
authors.initials: XY
authors.lastname: Liu
authors.forename: Yong-Min
authors.initials: YM
authors.lastname: Liang
mesh_terms: D000473:Alkanes / Q000737:chemistry*; D002384:Catalysis; D004952:Esters / Q000737:chemistry*; D006865:Hydrogenation; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry*; D009574:Nitro Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010984:Platinum / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000473:Alkanes; D004952:Esters; D007659:Ketones; D009570:Nitriles; D009574:Nitro Compounds; D010984:Platinum; C000945:dicyanmethane