Dendronizing and metalating trans-2 C60 tetraaryl porphyrins--a versatile approach toward water-soluble donor-acceptor conjugates.
We have realized for the first time a series of truly water-soluble and tightly coupled porphyrin/C(60) electron-donor-acceptor conjugates in which the charge separation and charge recombination dynamics are controlled by modifying the nature of the dendrimer and/or the choice of the central metal atom.
Ruppert
Michaela
M
Department of Chemistry and Pharmacy and Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg, Henkestrasse 42, 91054 Erlangen, Germany.
Spänig
Fabian
F
Wielopolski
Mateusz
M
Jäger
Christof M
CM
Bauer
Walter
W
Clark
Timothy
T
Hirsch
Andreas
A
Guldi
Dirk M
DM
D050091:Dendrimers / Q000737:chemistry*; D004583:Electrons; D008665:Metalloporphyrins / Q000737:chemistry*; D008670:Metals / Q000737:chemistry*; D015394:Molecular Structure; D011166:Porphyrins / Q000737:chemistry*; D014867:Water / Q000737:chemistry
D050091:Dendrimers; D008665:Metalloporphyrins; D008670:Metals; D011166:Porphyrins; D014867:Water