Mechanisms of Mn(OAc)(3)-based oxidative free-radical additions and cyclizations.
The mechanistic details of Mn(OAc)(3)-based oxidative free-radical additions and cyclizations are reviewed. The mechanisms of electron transfer to generate radicals, electron transfer to convert the radicals to oxidized products, and further oxidation of the products are covered.
Snider
Barry B
BB
Department of Chemistry MS 015, Brandeis University, Waltham MA 02454-9110.