title: Comprehensive multidimensional separation methods by hyphenation of single-photon ionization time-of-flight mass spectrometry (SPI-TOF-MS) with GC and GCxGC.
abstract: One- and comprehensive two-dimensional gas chromatography were hyphenated with soft photoionization mass spectrometry. The characteristics of these two- and three-dimensional comprehensive separation techniques are discussed in detail. Using the innovative electron beam pumped excimer light source (EBEL) for single-photon ionization (SPI), organic molecules with ionization energies (E ( i )) of below 9.8 eV can be detected by a time-of-flight mass spectrometer (TOF-MS). SPI with 126 nm vacuum ultraviolet (VUV) photons enables the universal and soft ionization of organic molecules. SPI-TOF-MS hyphenated to one-dimensional gas chromatography results in a comprehensive two-dimensional separation method (GCxMS). To demonstrate this, diesel fuel was analyzed, and the resulting GCxMS chromatograms are discussed in depth. A three-dimensional separation method was also realized by combining comprehensive two-dimensional gas chromatography (GCxGC) with SPI-MS. In the resulting separation space, constituents originating from mineral oil diesel blended with biodiesel were dispersed along the two GC separation axes, while the molecular mass axis served as a third separation dimension.
authors.affiliation: Joint Mass Spectrometry Center, Cooperation Group Analysis of Complex Molecular Systems, Institute of Ecological Chemistry, Helmholtz Zentrum München, Ingolstädter Landstr. 1, 85764, Neuherberg, Germany.
authors.forename: Markus S
authors.initials: MS
authors.lastname: Eschner
authors.forename: Werner
authors.initials: W
authors.lastname: Welthagen
authors.forename: Thomas M
authors.initials: TM
authors.lastname: Gröger
authors.forename: Marc
authors.initials: M
authors.lastname: Gonin
authors.forename: Katrin
authors.initials: K
authors.lastname: Fuhrer
authors.forename: Ralf
authors.initials: R
authors.lastname: Zimmermann