title: State-to-state inelastic scattering of Stark-decelerated OH radicals with Ar atoms.
abstract: The Stark deceleration method exploits the concepts of charged particle accelerator physics to produce molecular beams with a tunable velocity. These tamed molecular beams offer interesting perspectives for precise crossed beam scattering studies as a function of the collision energy. The method has advanced sufficiently to compete with state-of-the-art beam methods that are used for scattering studies throughout. This is demonstrated here for the scattering of OH radicals (X(2)Pi(3/2), J = 3/2, f) with Ar atoms, a benchmark system for the scattering of open-shell molecules with atoms. Parity-resolved integral state-to-state inelastic scattering cross sections are measured at collision energies between 80 and 800 cm(-1). The threshold behavior and collision energy dependence of 13 inelastic scattering channels is accurately determined. Excellent agreement is obtained with the cross sections predicted by close-coupling scattering calculations based on the most accurate ab initio OH + Ar potential energy surfaces to date.
authors.affiliation: Fritz-Haber-Institut der Max-Planck-Gesellschaft, Faradayweg 4-6, 14195 Berlin, Germany.
authors.forename: Ludwig
authors.initials: L
authors.lastname: Scharfenberg
authors.forename: Jacek
authors.initials: J
authors.lastname: Kłos
authors.forename: Paul J
authors.initials: PJ
authors.lastname: Dagdigian
authors.forename: Millard H
authors.initials: MH
authors.lastname: Alexander
authors.forename: Gerard
authors.initials: G
authors.lastname: Meijer
authors.forename: Sebastiaan Y T
authors.initials: SY
authors.lastname: van de Meerakker