Direct oxidative coupling of benzenes with acrylonitriles to cinnamonitriles catalyzed by Pd(OAc)(2)/HPMoV/O(2) system.
A facile direct synthesis of cinnamonitriles from acrylonitriles and benzenes is successfully achieved by using Pd(OAc)(2)/HPMoV/O(2) catalyst system via the direct C-H bond activation of benzenes using molecular oxygen as a terminal oxidant.
Obora
Yasushi
Y
Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, High Technology Research Center, Kansai University, Suita, Osaka 564-8680, Japan. obora@kansai-u.ac.jp
Okabe
Yoshihisa
Y
Ishii
Yasutaka
Y
D000085:Acetates / Q000737:chemistry; D000181:Acrylonitrile / Q000031:analogs & derivatives / Q000737:chemistry*; D001554:Benzene / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry; D009570:Nitriles / Q000138:chemical synthesis* / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry; D010756:Phosphoric Acids / Q000737:chemistry; D014639:Vanadium / Q000737:chemistry
D000085:Acetates; D009570:Nitriles; D009942:Organometallic Compounds; D010756:Phosphoric Acids; D014639:Vanadium; C516071:palladium(II) acetate; C002599:cinnamonitrile; D008982:Molybdenum; D001554:Benzene; D000181:Acrylonitrile; D010100:Oxygen