Synthesis and structure of an aminoethyl-functionalized cyclopentadienyl vanadium(I) dinitrogen complex.
Reduction of a V(III) complex [(eta(5),eta(1)-C(5)H(4)CH(2)CH(2)NMe(2))VCl(2)(PMe(3))] in the presence of diphenylacetylene under nitrogen atmosphere yields a novel V(I) dinitrogen-bridged complex {[eta(5)-(C(5)H(4)CH(2)CH(2)NMe(2))]V(PhC[triple bond]CPh)(PMe(3))}(2)(mu-N(2)).
Liu
Guohua
G
The Key Laboratory of Resource Chemistry of Ministry of Education, Shanghai Normal University, Shanghai, China. ghliu@shnu.edu.cn
Liang
Xiaohui
X
Meetsma
Auke
A
Hessen
Bart
B