Platinum-catalyzed cross-dehydrogenative coupling reaction in the absence of oxidant.
A third strategy for cross-dehydrogenative coupling reaction has been reported via platinum-catalyzed sp(3) C-H and sp(3) C-H coupling reaction in the absence of oxidant. Nitroalkanes as well as dialkyl malonate derivatives, beta-keto esters and malononitrile are active participants in this coupling reaction. Both cyclic and acyclic non-activated simple ketones are good reactants in this reaction.
Shu
Xing-Zhong
XZ
State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000, PR China.
Yang
Yan-Fang
YF
Xia
Xiao-Feng
XF
Ji
Ke-Gong
KG
Liu
Xue-Yuan
XY
Liang
Yong-Min
YM
D000473:Alkanes / Q000737:chemistry*; D002384:Catalysis; D004952:Esters / Q000737:chemistry*; D006865:Hydrogenation; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry*; D009574:Nitro Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010984:Platinum / Q000737:chemistry*; D013237:Stereoisomerism
D000473:Alkanes; D004952:Esters; D007659:Ketones; D009570:Nitriles; D009574:Nitro Compounds; D010984:Platinum; C000945:dicyanmethane