Platinum-catalyzed hydrative cyclization of 1,6-diynes for the synthesis of 3,5-substituted conjugated cyclohexenones.
We have developed a Pt(COD)Cl(2)-catalyzed hydrative cyclization of 1,6-diynes leading to the formation of functionalized cyclohexenones in good yields.
Zhang
Chen
C
School of Pharmaceutical Sciences, Zhejiang University, Hangzhou 310058, China.
Qi
Jian-Feng
JF
Cui
Dong-Mei
DM
Wang
Qian
Q
Wang
Xiu-Li
XL
D002384:Catalysis; D003500:Cyclization; D053280:Diynes / Q000737:chemistry*; D006588:Hexanones / Q000138:chemical synthesis*; D010984:Platinum / Q000737:chemistry*
D053280:Diynes; D006588:Hexanones; D010984:Platinum