Electroconvection in nematic liquid crystals via nanoparticle doping.
It is known that a small fraction of nanoparticles dispersed in a liquid crystal can alter the electrooptic response, completely. The present study on gold nanoparticles dispersed in 5-n-heptyl-2-(4-n-octyloxy-phenyl)-pyrimidine shows that the contrast inversion observed earlier is initiated by a change from parallel to homeotropic anchoring, thereby causing an instability, which in turn leads to the appearance of convection rolls. After rapid cooling from the isotropic phase, the nanoparticle dispersion shows a regular field-induced Fréedericksz transition, like the pure liquid crystal. The electrohydrodynamic instability is presumably an example for the behavior of (+, -) systems that was predicted by de Gennes, and only recently observed experimentally for the first time.
Urbanski
Martin
M
Department of Chemistry, Faculty of Science, University of Paderborn, Warburger Str. 100, 33098, Paderborn, Germany.
Kinkead
Brandy
B
Qi
Hao
H
Hegmann
Torsten
T
Kitzerow
Heinz-S
HS
D006046:Gold / Q000737:chemistry; D050866:Liquid Crystals / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry*; D011743:Pyrimidines / Q000737:chemistry
D011743:Pyrimidines; D006046:Gold; C030986:pyrimidine