title: High-field pulsed EPR spectroscopy for the speciation of the reduced [PV(2)Mo(10)O(40)](6-) polyoxometalate catalyst used in electron-transfer oxidations.
abstract: An in-depth spectroscopic EPR investigation of a key intermediate, formally notated as [PV(IV)V(V)Mo(10)O(40)](6-) and formed in known electron-transfer and electron-transfer/oxygen-transfer reactions catalyzed by H(5)PV(2)Mo(10)O(40), has been carried out. Pulsed EPR spectroscopy have been utilized: specifically, W-band electron-electron double resonance (ELDOR)-detected NMR and two-dimensional (2D) hyperfine sub-level correlation (HYSCORE) measurements, which resolved (95)Mo and (17)O hyperfine interactions, and electron-nuclear double resonance (ENDOR), which gave the weak (51)V and (31)P interactions. In this way, two paramagnetic species related to [PV(IV)V(V)Mo(10)O(40)](6-) were identified. The first species (30-35 %) has a vanadyl (VO(2+))-like EPR spectrum and is not situated within the polyoxometalate cluster. Here the VO(2+) was suggested to be supported on the Keggin cluster and can be represented as an ion pair, [PV(V)Mo(10)O(39)](8-)[V(IV)O(2+)]. This species originates from the parent H(5)PV(2)Mo(10)O(40) in which the vanadium atoms are nearest neighbors and it is suggested that this isomer is more likely to be reactive in electron-transfer/oxygen-transfer reaction oxidation reactions. In the second (70-65 %) species, the V(IV) remains embedded within the polyoxometalate framework and originates from reduction of distal H(5)PV(2)Mo(10)O(40) isomers to yield an intact cluster, [PV(IV)V(V)Mo(10)O(40)](6-).
authors.affiliation: Department of Chemical Physics, Weizmann Institute of Science, Rehovot, 76100 Israel.
authors.forename: Ilia
authors.initials: I
authors.lastname: Kaminker
authors.forename: Hila
authors.initials: H
authors.lastname: Goldberg
authors.forename: Ronny
authors.initials: R
authors.lastname: Neumann
authors.forename: Daniella
authors.initials: D
authors.lastname: Goldfarb
mesh_terms: D002384:Catalysis; D004578:Electron Spin Resonance Spectroscopy / Q000379:methods*; D004579:Electron Transport; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
chemical_list: D010100:Oxygen; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates