Solid-liquid interface synthesis of microcrystalline porous coordination networks.
Solid-liquid interface synthesis provided a unique way to selectively and efficiently prepare molecular complexes (ML(2)) and metastable porous coordination networks in short crystallization times. In sharp contrast, their solution reactions gave interpenetrated open-framework networks. We succeeded in solving a crystal structure of the metastable network by ab initio powder X-ray analysis.
Martí-Rujas
Javier
J
Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan.
Matsushita
Yoshitaka
Y
Izumi
Fujio
F
Fujita
Makoto
M
Kawano
Masaki
M