title: Carbon nanotube/raspberry hollow Pd nanosphere hybrids for methanol, ethanol, and formic acid electro-oxidation in alkaline media.
abstract: In this paper, raspberry hollow Pd nanospheres (HPNs)-decorated carbon nanotube (CNT) was developed for electro-oxidation of methanol, ethanol, and formic acid in alkaline media. The electrocatalyst was fabricated simply by attaching HPNs onto the surface of CNT which had been functionalized by polymer wrapping. The as-prepared HPN-CNTs (CHPNs) were characterized by transmission electron microscopy (TEM), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDX), and X-ray photoelectron spectroscopy (XPS). The increasing interest and intensive research on fuel cell inspire us to investigate the electrocatalytic properties of the prepared nanostructures. Besides that, previous reports about alkaline other than acidic media could supply a more active environment guide us to examine the electrocatalytic properties in alkaline electrolyte. It is found that this novel hybrid electrocatalyst exhibits excellent electrocatalytic properties and can be further applied in fuel cells, catalysts, and sensors.
authors.affiliation: State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, Jilin 130022, PR China.
authors.forename: Zhelin
authors.initials: Z
authors.lastname: Liu
authors.forename: Bo
authors.initials: B
authors.lastname: Zhao
authors.forename: Cunlan
authors.initials: C
authors.lastname: Guo
authors.forename: Yujing
authors.initials: Y
authors.lastname: Sun
authors.forename: Yan
authors.initials: Y
authors.lastname: Shi
authors.forename: Haibin
authors.initials: H
authors.lastname: Yang
authors.forename: Zhuang
authors.initials: Z
authors.lastname: Li
mesh_terms: D000468:Alkalies / Q000737:chemistry*; D002384:Catalysis; D004563:Electrochemistry; D004583:Electrons; D000431:Ethanol / Q000737:chemistry*; D005561:Formates / Q000737:chemistry*; D000432:Methanol / Q000737:chemistry*; D054118:Nanospheres / Q000737:chemistry; D037742:Nanotubes, Carbon / Q000737:chemistry*; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*; D010316:Particle Size; D016062:Porosity; D013499:Surface Properties
chemical_list: D000468:Alkalies; D005561:Formates; D037742:Nanotubes, Carbon; C030544:formic acid; D000431:Ethanol; D010165:Palladium; D000432:Methanol