Structural diversity in polyamine Lewis base stabilised lithium aryloxides.
Five new lithium aryloxide complexes stabilised by polyamine ligands have been synthesised by simple deprotonation reactions of the parent aryl alcohols H-OAr [OAr = OC(6)H(5), OC(6)H(2)-2,4,6-(Me)(3) and OC(6)H(2)-2,6-((t)Bu)(2)-4-(Me)] with LiN(SiMe(3))(2) in the presence of the Lewis bases N,N,N',N'-tetramethylethylenediamine (TMEDA) and N,N,N',N'',N''-pentamethyldiethylenetriamine (PMDETA). All the compounds have been characterised by multinuclear NMR and X-ray crystallographic studies. The PMDETA derivative of the phenol adopts a tetrameric ladder-like structural motif in the solid state, exhibiting an unusual bridging coordination mode of the N-donor ligand. The 2,4,6-trimethylphenol derivatives exhibit dimeric (TMEDA), and tetrameric (PMDETA) structural motifs in the solid state. Meanwhile, the TMEDA and PMDETA derivatives of the sterically hindered 2,6-di-tert-butyl-4-methylphenol exhibit a rare monomeric structural motifs, which appears to remain unaltered in C(6)D(6) solution.
Cousins
David M
DM
Department of Chemistry, University of Bath, Bath, UK BA2 7AY.
Davidson
Matthew G
MG
García-Vivó
Daniel
D
Mahon
Mary F
MF