title: Copper(I) complexes with N-(diisopropoxythiophosphoryl)thiobenzamide PhC(S)NHP(S)(OiPr)2.
abstract: Reaction of the potassium salt of N-thiophosphorylthiobenzamide PhC(S)NHP(S)(OiPr)(2) (HL) with CuI in aqueous EtOH leads to the tetranuclear [Cu(4)L(4)] and the polynuclear [KCuL(2)](n) complexes, while the same reactions using the lithium or sodium salts of HL exclusively lead to the tetramer [Cu(4)L(4)]. Reaction of KL with the mixture of CuI and 2,2'-bipyridine (bpy) or 1,10-phenanthroline (phen) leads to the mononuclear complexes [Cu(bpy)L] and [Cu(phen)L]. The same complexes were obtained by the reaction of [Cu(4)L(4)] with bpy or phen.
authors.affiliation: Institut für Anorganische Chemie, Universität zu Köln, Greinstrasse 6, D-50939, Köln, Germany.
authors.forename: Maria G
authors.initials: MG
authors.lastname: Babashkina
authors.forename: Damir A
authors.initials: DA
authors.lastname: Safin
authors.forename: Franck
authors.initials: F
authors.lastname: Fayon
authors.forename: Aydar I
authors.initials: AI
authors.lastname: Rakhmatullin
authors.forename: Felix D
authors.initials: FD
authors.lastname: Sokolov
authors.forename: Axel
authors.initials: A
authors.lastname: Klein
authors.forename: Dmitriy B
authors.initials: DB
authors.lastname: Krivolapov
authors.forename: Tania
authors.initials: T
authors.lastname: Pape
authors.forename: F Ekkehardt
authors.initials: FE
authors.lastname: Hahn
authors.forename: Henryk
authors.initials: H
authors.lastname: Kozlowski
mesh_terms: D015082:2,2'-Dipyridyl / Q000737:chemistry; D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D010618:Phenanthrolines / Q000737:chemistry
chemical_list: D056831:Coordination Complexes; D009942:Organometallic Compounds; D010618:Phenanthrolines; D015082:2,2'-Dipyridyl; D003300:Copper; C025205:1,10-phenanthroline