Formic acid acting as an efficient oxygen scavenger in four-electron reduction of oxygen catalyzed by a heterodinuclear iridium-ruthenium complex in water.
A heterodinuclear iridium-ruthenium complex [Ir(III)(Cp*)(H(2)O)(bpm)Ru(II)(bpy)(2)](SO(4))(2) (Cp* = eta(5)-pentamethyl-cyclopentadienyl, bpm = 2,2'-bipyrimidine, bpy = 2,2'-bipyridine) acts as an effective catalyst for removal of dissolved O(2) by the four-electron reduction of O(2) with formic acid in water at an ambient temperature.
Fukuzumi
Shunichi
S
Department of Material and Life Science, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan. fukuzumi@chem.eng.osaka-u.ac.jp
Kobayashi
Takeshi
T
Suenobu
Tomoyoshi
T
D002384:Catalysis; D004583:Electrons; D005561:Formates / Q000737:chemistry*; D016166:Free Radical Scavengers / Q000737:chemistry*; D007495:Iridium / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry; D013237:Stereoisomerism; D013696:Temperature; D014867:Water / Q000737:chemistry*
D005561:Formates; D016166:Free Radical Scavengers; D009942:Organometallic Compounds; D014867:Water; C030544:formic acid; D007495:Iridium; D012428:Ruthenium; D010100:Oxygen