title: Cyclic alkenyl boronic half acid synthesis and applications.
abstract: The synthesis of cyclic alkenyl boronic half acids from vinyl and propenyl boronic esters and homoallylic alcohols by ring-closing metathesis is reported. The method is compatible with both conventional and microwave heating and comparable yields are obtained under both conditions. The cyclic alkenyl boronic acids participate in Suzuki-Miyaura coupling reactions in good yields.
authors.affiliation: Butler University, 4600 Sunset Avenue, Indianapolis, Indiana 46208, USA. lmcnulty@butler.edu
authors.forename: LuAnne
authors.initials: L
authors.lastname: McNulty
authors.forename: Kris
authors.initials: K
authors.lastname: Kohlbacher
authors.forename: Katie
authors.initials: K
authors.lastname: Borin
authors.forename: Bryan
authors.initials: B
authors.lastname: Dodd
authors.forename: Jeni
authors.initials: J
authors.lastname: Bishop
authors.forename: Lindsey
authors.initials: L
authors.lastname: Fuller
authors.forename: Zach
authors.initials: Z
authors.lastname: Wright
mesh_terms: D000438:Alcohols / Q000138:chemical synthesis* / Q000737:chemistry*; D001897:Boronic Acids / Q000138:chemical synthesis* / Q000737:chemistry*; D003500:Cyclization; D004952:Esters / Q000737:chemistry*; D008872:Microwaves; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D000438:Alcohols; D001897:Boronic Acids; D004952:Esters