Orthogonal photocleavage of a monochromophoric linker.
The 4-acetyl-2-nitrobenzyl moiety, substituted in both benzylic and phenacyl positions with leaving groups, has been proposed as a monochromophoric photocleavable linker. The attached groups can be disconnected selectively and orthogonally upon irradiation.
Kammari
Laxminarayana
L
Department of Chemistry, Faculty of Science, Masaryk University, Kamenice 5/A8, 625 00 Brno, Czech Republic.
Solomek
Tomás
T
Ngoy
Bokolombe Pitchou
BP
Heger
Dominik
D
Klán
Petr
P
D015394:Molecular Structure; D009578:Nitrobenzenes / Q000138:chemical synthesis* / Q000737:chemistry; D010777:Photochemistry; D013237:Stereoisomerism
D009578:Nitrobenzenes