title: Efficient assembly of 1-methylene-1H-indenes via palladium-catalyzed tandem reaction of 1-(2,2-dibromovinyl)-2-alkenylbenzene with arylboronic acid.
abstract: Highly efficient palladium-catalyzed reaction of 1-(2,2-dibromovinyl)-2-alkenylbenzene with arylboronic acid is disclosed, which generates the functionalized 1-methylene-1H-indenes in good yields. Tandem Suzuki-Miyaura coupling and Heck reactions are involved in this process.
authors.affiliation: Department of Chemistry, Fudan University, 220 Handan Road, Shanghai 200433, China.
authors.forename: Shengqing
authors.initials: S
authors.lastname: Ye
authors.forename: Hui
authors.initials: H
authors.lastname: Ren
authors.forename: Jie
authors.initials: J
authors.lastname: Wu
mesh_terms: D000085:Acetates / Q000737:chemistry*; D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D002934:Cinnamates / Q000138:chemical synthesis* / Q000737:chemistry; D020650:Combinatorial Chemistry Techniques; D003500:Cyclization; D007192:Indenes / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D014753:Vinyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D000085:Acetates; D001897:Boronic Acids; D002934:Cinnamates; D007192:Indenes; D009942:Organometallic Compounds; D014753:Vinyl Compounds; C516071:palladium(II) acetate