title: Studies on highly regio- and stereoselective hydration of 1,2-allenylic sulfoxides.
abstract: A highly regio- and stereoselective hydration of 1,2-allenylic sulfoxides in which proton served as the electrophile was reported. Through the X-ray diffraction study, it was concluded that the reaction may proceed via a 5-membered cyclic intermediate following by attack of the (-)OH at the sulfur atom.
authors.affiliation: Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou 310027, , Zhejiang, PR China.
authors.forename: Zhao
authors.initials: Z
authors.lastname: Fang
authors.forename: Chao
authors.initials: C
authors.lastname: Zhou
authors.forename: Chunling
authors.initials: C
authors.lastname: Fu
authors.forename: Shengming
authors.initials: S
authors.lastname: Ma