Cu-catalyzed double S-alkenylation of potassium sulfide: a highly efficient method for the synthesis of various thiophenes.
An efficient synthetic approach to variously substituted thiophenes has been developed through copper-catalyzed tandem S-alkenylation of potassium sulfide with 1,4-diiodo-1,3-dienes.
You
Wei
W
Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China.
Yan
Xiaoyu
X
Liao
Qian
Q
Xi
Chanjuan
C
D000475:Alkenes / Q000737:chemistry; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D003300:Copper / Q000737:chemistry*; D003500:Cyclization; D015394:Molecular Structure; D011188:Potassium / Q000737:chemistry*; D013440:Sulfides / Q000737:chemistry*; D013876:Thiophenes / Q000138:chemical synthesis* / Q000737:chemistry
D000475:Alkenes; D013440:Sulfides; D013876:Thiophenes; D003300:Copper; D011188:Potassium