Making a [Co24] metallamacrocycle from the shuttlecock-like tetranuclear cobalt-calixarene building blocks.
A [Co(24)] metallamacrocycle with a [36-MC(Co)-12] periphery and an inner [24-MC(Co)-6] rim is constructed by linking six Co(4)-thiacalixarene shuttlecock-like SBUs with twelve 1,2,4-triazole molecules.
Bi
Yanfeng
Y
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China.
Xu
Guancheng
G
Liao
Wuping
W
Du
Shangchao
S
Wang
Xinwu
X
Deng
Ruiping
R
Zhang
Hongjie
H
Gao
Song
S
D047250:Calixarenes / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D047028:Macrocyclic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010316:Particle Size; D013499:Surface Properties; D014230:Triazoles / Q000737:chemistry
D047028:Macrocyclic Compounds; D009942:Organometallic Compounds; D014230:Triazoles; D047250:Calixarenes; C045575:1,2,4-triazole; D003035:Cobalt