Copper(I) complexes with N-(diisopropoxythiophosphoryl)thiobenzamide PhC(S)NHP(S)(OiPr)2.
Reaction of the potassium salt of N-thiophosphorylthiobenzamide PhC(S)NHP(S)(OiPr)(2) (HL) with CuI in aqueous EtOH leads to the tetranuclear [Cu(4)L(4)] and the polynuclear [KCuL(2)](n) complexes, while the same reactions using the lithium or sodium salts of HL exclusively lead to the tetramer [Cu(4)L(4)]. Reaction of KL with the mixture of CuI and 2,2'-bipyridine (bpy) or 1,10-phenanthroline (phen) leads to the mononuclear complexes [Cu(bpy)L] and [Cu(phen)L]. The same complexes were obtained by the reaction of [Cu(4)L(4)] with bpy or phen.
Babashkina
Maria G
MG
Institut für Anorganische Chemie, Universität zu Köln, Greinstrasse 6, D-50939, Köln, Germany.
Safin
Damir A
DA
Fayon
Franck
F
Rakhmatullin
Aydar I
AI
Sokolov
Felix D
FD
Klein
Axel
A
Krivolapov
Dmitriy B
DB
Pape
Tania
T
Hahn
F Ekkehardt
FE
Kozlowski
Henryk
H
D015082:2,2'-Dipyridyl / Q000737:chemistry; D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D010618:Phenanthrolines / Q000737:chemistry
D056831:Coordination Complexes; D009942:Organometallic Compounds; D010618:Phenanthrolines; D015082:2,2'-Dipyridyl; D003300:Copper; C025205:1,10-phenanthroline