Cyclic alternating ring-opening metathesis polymerization (CAROMP). Rapid access to functionalized cyclic polymers.
Catalysis of alternating ROMP with (H(2)IMes)Cl(2)Ru=CHPh(OiPr), the second generation Hoveyda-Grubbs catalyst, provided an entirely cyclic alternating polymer. Conditions for the cyclic AROMP were used to prepare a polymer in which one of the repeat units bore a primary alkyl chloride that was used for further elaboration.
Song
Airong
A
Department of Chemistry, Stony Brook University, Stony Brook, New York 11794-3400, USA.
Parker
Kathlyn A
KA
Sampson
Nicole S
NS
D000473:Alkanes / Q000737:chemistry; D002384:Catalysis; D003500:Cyclization; D006843:Hydrocarbons, Chlorinated / Q000737:chemistry; D015394:Molecular Structure; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D012428:Ruthenium / Q000737:chemistry*
D000473:Alkanes; D006843:Hydrocarbons, Chlorinated; D011108:Polymers; D012428:Ruthenium