title: Two-dimensional heterospectral correlation analysis of X-ray photoelectron spectra and infrared spectra for spin-coated films of biodegradable poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) copolymers.
abstract: We investigated the thermal behavior of spin-coated films of biodegradable poly(3-hydroxybutyrate-co-3-hydroxyhexanoate) (P(HB-co-HHx)) copolymers at the molecular level. To better understand details of thermal behavior of spin-coated films of P(HB-co-HHx) copolymers, we applied two-dimensional (2D) correlation analysis to the spectra of P(HB-co-HHx) (HHx = 12.0, 10.0, and 3.8 mol %) copolymers during the heating process from 30 to 150 degrees C as obtained by temperature-dependent infrared-reflection absorption spectroscopy and X-ray photoelectron spectroscopy (XPS). 2D IR and 2D XPS correlation spectra of spin-coated films of P(HB-co-HHx) copolymers clearly revealed the sequence of intensity changes with increasing temperature: an amorphous band increases first and then a band for less ordered secondary crystals decreases before a band for well-ordered primary crystals. Furthermore, the synchronous 2D heterospectral XPS/IR correlation spectrum elucidated the correlation between the IR and XPS bands, confirming their band assignments. The asynchronous 2D heterospectral correlation spectrum revealed the probe-dependent asynchronicity between XPS and IR signals arising from the same species even under identical perturbation conditions because of the different scales of molecular changes probed. It clearly provides a complete interpretation of the phase transition phenomenon of P(HB-co-HHx) copolymers, which could not have been obtained through XPS or IR study alone, and also, the results obtained thereof offer a new insight into the molecular interactions as well observed by two different probes.
authors.affiliation: Department of Chemistry, Chonnam National University, Gwangju 500-757, Korea.
authors.forename: Hyun Chul
authors.initials: HC
authors.lastname: Choi
authors.forename: Soo Ryeon
authors.initials: SR
authors.lastname: Ryu
authors.forename: Ho
authors.initials: H
authors.lastname: Ji
authors.forename: Seung Bin
authors.initials: SB
authors.lastname: Kim
authors.forename: Isao
authors.initials: I
authors.lastname: Noda
authors.forename: Young Mee
authors.initials: YM
authors.lastname: Jung
mesh_terms: D020155:3-Hydroxybutyric Acid / Q000737:chemistry*; D001672:Biocompatible Materials / Q000737:chemistry; D002208:Caproates / Q000737:chemistry*; D056951:Photoelectron Spectroscopy; D013055:Spectrophotometry, Infrared; D013696:Temperature; D000094122:Polyhydroxybutyrates
chemical_list: D020155:3-Hydroxybutyric Acid; D001672:Biocompatible Materials; D002208:Caproates; C115940:poly(3-hydroxybutyrate-co-3-hydroxyhexanoate); D000094122:Polyhydroxybutyrates