Experimental characterization and modelization of ion exchange kinetics for a carboxylic resin in infinite solution volume conditions. Application to monovalent-trivalent cations exchange.
This study is devoted to the characterization of ion exchange inside a microsphere of carboxylic resin. It aims at describing the kinetics of this exchange reaction which is known to be controlled by interdiffusion in the particle. The fractional attainment of equilibrium function of time depends on the concentration of the cations in the resin which can be modelized by the Nernst-Planck equation. A powerful approach for the numerical resolution of this equation is introduced in this paper. This modeling is based on the work of Helfferich but involves an implicit numerical scheme which reduces the computational cost. Knowing the diffusion coefficients of the cations in the resin and the radius of the spherical exchanger, the kinetics can be hence completely determined. When those diffusion parameters are missing, they can be deduced by fitting experimental data of fractional attainment of equilibrium. An efficient optimization tool coupled with the implicit resolution has been developed for this purpose. A monovalent/trivalent cation exchange had been experimentally characterized for a carboxylic resin. Diffusion coefficients and concentration profiles in the resin were then deduced through this new model.
Picart
Sébastien
S
CEA, Nuclear Energy Division, RadioChemistry and Processes Department, Actinides Chemistry and Conversion Laboratory, F-30207 Bagnols-sur-Cèze, France. sebastien.picart@cea.fr
Ramière
Isabelle
I
Mokhtari
Hamid
H
Jobelin
Isabelle
I
D002412:Cations / Q000737:chemistry*; D004058:Diffusion; D007474:Ion Exchange; D007475:Ion Exchange Resins / Q000737:chemistry*; D007700:Kinetics; D008958:Models, Molecular; D009354:Neodymium / Q000737:chemistry; D011522:Protons; D000644:Quaternary Ammonium Compounds / Q000737:chemistry
D002412:Cations; D007475:Ion Exchange Resins; D011522:Protons; D000644:Quaternary Ammonium Compounds; D009354:Neodymium