title: Evaluation of the particle measurement programme (PMP) protocol to remove the vehicles' exhaust aerosol volatile phase.
abstract: European regulation for Euro 5/6 light duty emissions introduced the measurement of non-volatile particles with diameter >23 nm. The volatile phase is removed by using a heated dilution stage (150 degrees C) and a heated tube (at 300-400 degrees C). We investigated experimentally the removal efficiency for volatile species of the specific protocol by conducting measurements with two Euro 3 diesel light duty vehicles, a Euro 2 moped, and a Euro III heavy duty vehicle with the system's heaters on and off. The particle number distributions were measured with a Scanning Mobility Particle Sizer (SMPS) and a Fast Mobility Particle Sizer (FMPS). An Aerosol Mass Spectrometer (AMS) was used to identify the non-refractory chemical composition of the particles. A Multi-Angle Absorption Photometer (MAAP) was used to measure the black carbon concentration. The results showed that the condensed material in the accumulation mode (defined here as particles in the diameter range of approximately 50-500 nm) was removed with an efficiency of 50-90%. The (volatile) nucleation mode was also completely evaporated or was decreased to sizes <23 nm; thus these particles wouldn't be counted from the particle counter, indicating the robustness of the protocol.
authors.affiliation: EC Joint Research Centre Ispra, Institute for Environment and Sustainability, Transport and Air Quality Unit, 21027 Ispra (VA), Italy.
authors.forename: B
authors.initials: B
authors.lastname: Giechaskiel
authors.forename: R
authors.initials: R
authors.lastname: Chirico
authors.forename: P F
authors.initials: PF
authors.lastname: Decarlo
authors.forename: M
authors.initials: M
authors.lastname: Clairotte
authors.forename: T
authors.initials: T
authors.lastname: Adam
authors.forename: G
authors.initials: G
authors.lastname: Martini
authors.forename: M F
authors.initials: MF
authors.lastname: Heringa
authors.forename: R
authors.initials: R
authors.lastname: Richter
authors.forename: A S H
authors.initials: AS
authors.lastname: Prevot
authors.forename: U
authors.initials: U
authors.lastname: Baltensperger
authors.forename: C
authors.initials: C
authors.lastname: Astorga
mesh_terms: D000336:Aerosols / Q000032:analysis* / Q000737:chemistry; D000393:Air Pollutants / Q000032:analysis* / Q000737:chemistry; D000397:Air Pollution / Q000331:legislation & jurisprudence / Q000517:prevention & control*; D004777:Environment; D004784:Environmental Monitoring / Q000379:methods*; D052918:Environmental Restoration and Remediation / Q000295:instrumentation* / Q000331:legislation & jurisprudence; D033161:Government Regulation; D052638:Particulate Matter / Q000032:analysis* / Q000737:chemistry; D001335:Vehicle Emissions / Q000032:analysis / Q000517:prevention & control*
chemical_list: D000336:Aerosols; D000393:Air Pollutants; D052638:Particulate Matter; D001335:Vehicle Emissions