Synthesis and characterization of a coupled binuclear Cu(I)/Cu(III) complex.
The synthesis through reaction of a C(alpha),C(ortho) dilithiated phosphazene with CuBr and structural characterization of the first example of a binuclear mixed valence [Cu(I)(N(2))/Cu(III)(C(4))] complex showing a metal-metal bond, as well as its applications in cyclopropanation and oxidation reactions, are described.
García-López
Jesús
J
Area de Química Orgánica, Universidad de Almería, 04120 Almería, Spain.
Yañez-Rodríguez
Víctor
V
Roces
Laura
L
García-Granda
Santiago
S
Martínez
Ana
A
Guevara-García
Alfredo
A
Castro
German R
GR
Jiménez-Villacorta
Félix
F
Iglesias
María J
MJ
López Ortiz
Fernando
F
D001388:Aziridines / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism
D001388:Aziridines; D009942:Organometallic Compounds; C008880:phosphazine; D003300:Copper