title: Chiral sulfur derivatives in the allylation of acyl hydrazones: C(2)-symmetric bis-sulfinamides as enhanced chiral organic promoters.
abstract: Monosulfinamides and C(2)-symmetric bis-sulfinamides are convenient neutral chiral promoters in the allylation of acyl hydrazones, the nature of the spacer and the substituent at the sulfinyl sulfur are key elements for the enantioselectivity of the process.
authors.affiliation: Departamento de Química Orgánica y Farmacéutica, Facultad de Farmacia, Universidad de Sevilla, 41012 Sevilla, Spain. inmaff@us.es
authors.forename: Inmaculada
authors.initials: I
authors.lastname: Fernández
authors.forename: Ana
authors.initials: A
authors.lastname: Alcudia
authors.forename: Beatrice
authors.initials: B
authors.lastname: Gori
authors.forename: Victoria
authors.initials: V
authors.lastname: Valdivia
authors.forename: Rocío
authors.initials: R
authors.lastname: Recio
authors.forename: María Victoria
authors.initials: MV
authors.lastname: García
authors.forename: Noureddine
authors.initials: N
authors.lastname: Khiar
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D000577:Amides / Q000737:chemistry; D006835:Hydrazones / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism; D013457:Sulfur Compounds / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D000577:Amides; D006835:Hydrazones; D013457:Sulfur Compounds