Iodine-catalyzed one-pot acetalation-esterification reaction for the preparation of orthogonally protected glycosides.
An iodine-catalyzed one-pot tandem acetalation-esterification reaction of thio- and O-glycosides has been developed providing a fast and mild route to orthogonally protected glycosides ready to be used as building blocks in glycosylation reactions.
Jones
Rachel A
RA
School of Chemistry, University of Bristol, Bristol BS8 1TS, UK.
Davidson
Robert
R
Tran
Anh Tuan
AT
Smith
Nichola
N
Carmen Galan
M
M
D000080:Acetals / Q000737:chemistry*; D002384:Catalysis; D004951:Esterification; D006027:Glycosides / Q000737:chemistry*; D007455:Iodine / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry
D000080:Acetals; D006027:Glycosides; D013455:Sulfur; D007455:Iodine