Bimetallic nickel aluminum mediated para-selective alkenylation of pyridine: direct observation of eta2,eta1-pyridine Ni(0)-Al(III) intermediates prior to C-H bond activation.
We have presented new amino-NHC Ni-Al complex mediated para C-H bond activation for pyridine and quinolin, and isolated for the first time the intermediate structure of a bimetallic eta(2),eta(1)-pyridine nickel aluminum complex prior to its C-H activation, which serves as key evidence for bimetallic catalysis.
Tsai
Chung-Chih
CC
Institute of Chemistry, Academia Sinica, Nangang, Taipei, Taiwan, Republic of China.
Shih
Wei-Chih
WC
Fang
Cyong-Hui
CH
Li
Chia-Yi
CY
Ong
Tiow-Gan
TG
Yap
Glenn P A
GP
D000478:Alkylation; D000480:Alkynes / Q000737:chemistry*; D000535:Aluminum / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D011725:Pyridines / Q000138:chemical synthesis* / Q000737:chemistry*; D011804:Quinolines / Q000737:chemistry
D000480:Alkynes; D009942:Organometallic Compounds; D011725:Pyridines; D011804:Quinolines; D009532:Nickel; D000535:Aluminum; C023666:pyridine