Bis[3-(5-nitroimino-1,2,4-triazolate)]-based energetic salts: synthesis and promising properties of a new family of high-density insensitive materials.
Bis[3-(5-nitroimino-1,2,4-triazolate)]-based energetic salts were synthesized in a simple, straightforward manner. They exhibit low solubility in available solvents, high hydrolytic stability, excellent thermal stability, high density, positive heat of formation, low shock sensitivity, and excellent detonation properties. The physical and energetic properties of some salts are similar and even superior to those of RDX.
Wang
Ruihu
R
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China. ruihu@fjirsm ac.cn
Xu
Hongyan
H
Guo
Yong
Y
Sa
Rongjian
R
Shreeve
Jean'ne M
JM
D004736:Energy-Generating Resources; D007097:Imines / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D012492:Salts / Q000737:chemistry; D012995:Solubility; D012997:Solvents / Q000737:chemistry; D013696:Temperature; D014230:Triazoles / Q000138:chemical synthesis* / Q000737:chemistry*
D007097:Imines; D012492:Salts; D012997:Solvents; D014230:Triazoles