An octacobalt cluster based, (3,12)-connected, magnetic, porous coordination polymer.
Solvothermal reaction of CoSO(4) with 2,6-di-p-carboxyphenyl-4,4'-bipyridine affords a novel, octacobalt cluster based, (3,12)-connected porous framework, which exhibits gas sorption and spin-glassy magnetic behaviour.
Hou
Lei
L
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
Zhang
Wei-Xiong
WX
Zhang
Jie-Peng
JP
Xue
Wei
W
Zhang
Yue-Biao
YB
Chen
Xiao-Ming
XM
D015082:2,2'-Dipyridyl / Q000031:analogs & derivatives* / Q000737:chemistry; D001565:Benzoates / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008280:Magnetics; D008958:Models, Molecular; D015394:Molecular Structure; D011108:Polymers / Q000737:chemistry*; D016062:Porosity; D013499:Surface Properties
D001565:Benzoates; D011108:Polymers; D003035:Cobalt; D015082:2,2'-Dipyridyl; C026305:cobalt sulfate