Mathematical models of the homochiralisation of crystals by grinding.
We review the existing mathematical models which describe physicochemical mechanisms capable of producing a symmetry-breaking transition to a state in which one chirality dominates the other. A new model is proposed, with the aim of elucidating the fundamental processes at work in the crystal grinding systems of Viedma (Phys Rev Lett 94:065504, 2005) and Noorduin (J Am Chem Soc 130:1158-1159, 2008). We simplify the model as far as possible to uncover the fundamental competitive process which causes the symmetry-breaking, and analyse other simplifications which might be expected to show symmetry-breaking.
Wattis
Jonathan A D
JA
Theoretical Mechanics, School of Mathematical Sciences, University of Nottingham, University Park, Nottingham, NG7 2RD, UK. Jonathan.Wattis@nottingham.ac.uk
D003460:Crystallization; D008956:Models, Chemical; D008962:Models, Theoretical; D013237:Stereoisomerism