title: Synthesis and characterization of a coupled binuclear Cu(I)/Cu(III) complex.
abstract: The synthesis through reaction of a C(alpha),C(ortho) dilithiated phosphazene with CuBr and structural characterization of the first example of a binuclear mixed valence [Cu(I)(N(2))/Cu(III)(C(4))] complex showing a metal-metal bond, as well as its applications in cyclopropanation and oxidation reactions, are described.
authors.affiliation: Area de Química Orgánica, Universidad de Almería, 04120 Almería, Spain.
authors.forename: Jesús
authors.initials: J
authors.lastname: García-López
authors.forename: Víctor
authors.initials: V
authors.lastname: Yañez-Rodríguez
authors.forename: Laura
authors.initials: L
authors.lastname: Roces
authors.forename: Santiago
authors.initials: S
authors.lastname: García-Granda
authors.forename: Ana
authors.initials: A
authors.lastname: Martínez
authors.forename: Alfredo
authors.initials: A
authors.lastname: Guevara-García
authors.forename: German R
authors.initials: GR
authors.lastname: Castro
authors.forename: Félix
authors.initials: F
authors.lastname: Jiménez-Villacorta
authors.forename: María J
authors.initials: MJ
authors.lastname: Iglesias
authors.forename: Fernando
authors.initials: F
authors.lastname: López Ortiz
mesh_terms: D001388:Aziridines / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D001388:Aziridines; D009942:Organometallic Compounds; C008880:phosphazine; D003300:Copper