title: Chemoselective and regiospecific Suzuki coupling on a multisubstituted sp(3)-carbon in 1,1-diborylalkanes at room temperature.
abstract: The palladium-catalyzed Suzuki-Miyaura cross-coupling on a multisubstituted sp(3)-carbon in 1,1-diborylalkanes was achieved at room temperature. The generation of a monoborate intermediate by virtue of the adjacent B atom could result in the chemoselective coupling reaction under ambient conditions.
authors.affiliation: Waseda Institute for Advanced Study, Shinjuku, Tokyo, 169-8050, Japan. kendo@aoni.waseda.jp
authors.forename: Kohei
authors.initials: K
authors.lastname: Endo
authors.forename: Takahiro
authors.initials: T
authors.lastname: Ohkubo
authors.forename: Munenao
authors.initials: M
authors.lastname: Hirokami
authors.forename: Takanori
authors.initials: T
authors.lastname: Shibata