Self-assembly of a nanosized, saddle-shaped, solution-stable polyoxometalate anion built from pentagonal building blocks: [H34W119Se8Fe2O420]54-.
Precise control of the "one-pot" reaction conditions is employed for the assembly of a nanosized 2.8 nm cluster, [H(34)W(119)Se(8)Fe(2)O(420)](54-) (1a), which is templated using eight selenite units and two iron(III) centers. Not only is this cluster characterized structurally using X-ray crystallography, it is the largest polyoxotungstate to be observed intact in solution using ESI-MS, with a molecular mass of ca. 30,000 Da.
Yan
Jun
J
WestCHEM, Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, UK.
Gao
Jing
J
Long
De-Liang
DL
Miras
Haralampos N
HN
Cronin
Leroy
L
D018360:Crystallography, X-Ray; D008958:Models, Molecular; D053758:Nanoparticles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D012996:Solutions; D021241:Spectrometry, Mass, Electrospray Ionization
D009942:Organometallic Compounds; D012996:Solutions