title: Copper-catalyzed aminobromination/elimination process: an efficient access to alpha,beta-unsaturated vicinal haloamino ketones and esters.
abstract: A novel copper-catalyzed aminobromination-elimination process has been developed, which provides an easy access to alpha,beta-unsaturated vicinal haloamindes derivatives from readily available alpha,beta-unsaturated ketones and esters in good to excellent yields. The isolated intermediate discloses that the current system proceeds through the aminobromination process.
authors: School of Chemistry and Chemical Engineering; State of Key Laboratory of Coordination, Nanjing University, Nanjing, 210093, China.
authors: Hao
authors: H
authors: Sun
authors: Guangqian
authors: G
authors: Zhang
authors: Sanjun
authors: S
authors: Zhi
authors: Jianlin
authors: J
authors: Han
authors: Guigen
authors: G
authors: Li
authors: Yi
authors: Y
authors: Pan
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis / Q000737:chemistry*; D000586:Amination; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D004952:Esters / Q000138:chemical synthesis / Q000737:chemistry; D054879:Halogenation; D007659:Ketones / Q000138:chemical synthesis / Q000737:chemistry*; D008958:Models, Molecular
chemical_list: D000475:Alkenes; D004952:Esters; D007659:Ketones; D003300:Copper