Kingianin A: a new natural pentacyclic compound from Endiandra kingiana.
A new natural pentacyclic compound, named kingianin A, was isolated as a racemic mixture from the barks of Endiandra kingiana (Lauraceae). Its structure was elucidated by comprehensive analysis of NMR spectroscopic data, X-ray crystallography, and ECD calculations. The pentacyclic skeleton may be formed by a Diels-Alder reaction between two monomers having a bicyclo[4.2.0]octadiene backbone formed by a stereospecific electrocyclization of a linear compound of polyketide origin.
Leverrier
Aurélie
A
Centre de Recherche de Gif, Institut de Chimie des Substances Naturelles, CNRS, 1, Avenue de la Terrasse, 91198 Gif-sur-Yvette Cedex, France.
Tran
Huu Dau Marie Elise
HD
Retailleau
Pascal
P
Awang
Khalijah
K
Guéritte
Françoise
F
Litaudon
Marc
M
D002942:Circular Dichroism; D018360:Crystallography, X-Ray; D019770:Lauraceae / Q000737:chemistry*; D015394:Molecular Structure; D011084:Polycyclic Aromatic Hydrocarbons / Q000737:chemistry / Q000302:isolation & purification*; D013237:Stereoisomerism
D011084:Polycyclic Aromatic Hydrocarbons; C553350:kingianin A