title: Speciation of heptavalent technetium in sulfuric acid: structural and spectroscopic studies.
abstract: The speciation of Tc(vii) was studied in 12 M H(2)SO(4) by NMR, UV-visible and XAFS spectroscopy. Experimental results and density functional calculations show the formation of TcO(3)(OH)(H(2)O)(2).
authors: Department of Chemistry, University of Nevada Las Vegas, Las Vegas, NV 89154, USA. poineauf@unlv.nevada.edu
authors: Frederic
authors: F
authors: Poineau
authors: Philippe F
authors: PF
authors: Weck
authors: Konstantin
authors: K
authors: German
authors: Alesya
authors: A
authors: Maruk
authors: Gayane
authors: G
authors: Kirakosyan
authors: Wayne
authors: W
authors: Lukens
authors: Daniel B
authors: DB
authors: Rego
authors: Alfred P
authors: AP
authors: Sattelberger
authors: Kenneth R
authors: KR
authors: Czerwinski
mesh_terms: D009682:Magnetic Resonance Spectroscopy; D013056:Spectrophotometry, Ultraviolet; D013464:Sulfuric Acids / Q000737:chemistry*; D013667:Technetium / Q000737:chemistry*; D013816:Thermodynamics; D056928:X-Ray Absorption Spectroscopy
chemical_list: D013464:Sulfuric Acids; D013667:Technetium; C033158:sulfuric acid