Palladium(II)-catalyzed asymmetric hydrophosphination of enones: efficient access to chiral tertiary phosphines.
Chiral tertiary phosphines were synthesized by asymmetric hydrophosphination of aromatic enones catalyzed by an organopalladium complex with high yields and stereoselectivity. The procedure offers practical access to chiral tertiary phosphines.
Huang
Yinhua
Y
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.
Pullarkat
Sumod A
SA
Li
Yongxin
Y
Leung
Pak-Hing
PH
D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D013237:Stereoisomerism
D000475:Alkenes; D007659:Ketones; D009942:Organometallic Compounds; D010720:Phosphines; D010165:Palladium