title: Gold(III)-catalyzed tandem reaction of O-arylhydroxylamines with 1,3-dicarbonyl compounds: highly selective synthesis of 3-carbonylated benzofuran derivatives.
abstract: A highly regioselective protocol for the synthesis of 3-carbonylated benzofuran derivatives has been developed involving the gold(III)-catalyzed tandem condensation/rearrangement/cyclization reaction of O-arylhydroxylamines with 1,3-dicarbonyl compounds.
authors: State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, People's Repubilc of China. ykuiliu@zjut.edu.cn
authors: Yunkui
authors: Y
authors: Liu
authors: Jianqiang
authors: J
authors: Qian
authors: Shaojie
authors: S
authors: Lou
authors: Zhenyuan
authors: Z
authors: Xu
mesh_terms: D001572:Benzofurans / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D003500:Cyclization; D006046:Gold / Q000737:chemistry*; D006898:Hydroxylamines / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D001572:Benzofurans; D006898:Hydroxylamines; D007659:Ketones; D006046:Gold