Structurally disfavoured pseudopeptidic macrocycles through anion templation.
An anionic dicarboxylate is able to template the formation of geometrically disfavoured macrocycles from a dynamic covalent mixture of open chain oligoimines.
Bru
Miriam
M
Departamento de Química Inorgánica y Orgánica, Universidad Jaume I, Avenida Sos Baynat s/n, E-12071, Castellón, Spain.
Alfonso
Ignacio
I
Bolte
Michael
M
Burguete
M Isabel
MI
Luis
Santiago V
SV
D000838:Anions / Q000737:chemistry; D018360:Crystallography, X-Ray; D003998:Dicarboxylic Acids / Q000737:chemistry*; D047028:Macrocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D013237:Stereoisomerism
D000838:Anions; D003998:Dicarboxylic Acids; D047028:Macrocyclic Compounds