title: A carbon-supported copper complex of 3,5-diamino-1,2,4-triazole as a cathode catalyst for alkaline fuel cell applications.
abstract: The performance of a novel carbon-supported copper complex of 3,5-diamino-1,2,4-triazole (Cu-tri/C) is investigated as a cathode material using an alkaline microfluidic H(2)/O(2) fuel cell. The absolute Cu-tri/C cathode performance is comparable to that of a Pt/C cathode. Furthermore, at a commercially relevant potential, the measured mass activity of an unoptimized Cu-tri/C-based cathode was significantly greater than that of similar Pt/C- and Ag/C-based cathodes. Accelerated cathode durability studies suggested multiple degradation regimes at various time scales. Further enhancements in performance and durability may be realized by optimizing catalyst and electrode preparation procedures.
authors: Department of Chemical & Biomolecular Engineering , University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, Illinois 61801, USA.
authors: Fikile R
authors: FR
authors: Brushett
authors: Matthew S
authors: MS
authors: Thorum
authors: Nicholas S
authors: NS
authors: Lioutas
authors: Matthew S
authors: MS
authors: Naughton
authors: Claire
authors: C
authors: Tornow
authors: Huei-Ru Molly
authors: HR
authors: Jhong
authors: Andrew A
authors: AA
authors: Gewirth
authors: Paul J A
authors: PJ
authors: Kenis
mesh_terms: D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D011211:Electric Power Supplies; D004563:Electrochemistry; D004566:Electrodes; D006859:Hydrogen / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry; D014230:Triazoles / Q000737:chemistry*
chemical_list: C500457:3,5-diamino-1,2,4-triazole; D009942:Organometallic Compounds; D014230:Triazoles; D002244:Carbon; D003300:Copper; D006859:Hydrogen; D010100:Oxygen