Definite coordination arrangement of organometallic palladium complexes accumulated on the designed interior surface of apo-ferritin.
Apo-ferritin (apo-Fr) mutants are used as scaffolds to accommodate palladium (allyl) complexes. Various coordination arrangements of the Pd complexes are achieved by adjusting the positions of cysteine and histidine residues on the interior surface of the apo-Fr cage.
Wang
Ziyue
Z
Department of Chemistry, Graduate School of Science, Nagoya University, Furo-cho, Nagoya, 464-8602, Japan.
Takezawa
Yusuke
Y
Aoyagi
Hiroki
H
Abe
Satoshi
S
Hikage
Tatsuo
T
Watanabe
Yoshihito
Y
Kitagawa
Susumu
S
Ueno
Takafumi
T
D000818:Animals; D001052:Apoferritins / Q000737:chemistry* / Q000235:genetics / Q000378:metabolism; D018360:Crystallography, X-Ray; D006736:Horses; D008958:Models, Molecular; D009154:Mutation; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry* / Q000378:metabolism; D010165:Palladium / Q000737:chemistry*; D013499:Surface Properties
D009942:Organometallic Compounds; D010165:Palladium; D001052:Apoferritins