Three polyoxygenated cyclohexenes from Uvaria calamistrata.
Three new polyoxygenated cyclohexenes, named uvacanols F, G, H (1-3), were isolated from the roots of Uvaria calamistrata (Annonaceae). Their structures were determined to be 2-acetoxyl-5-chlorine-benzoyloxymethylcyclohex-1 (6)-ene-4-ol-3-benzoate (1), benzoyloxy-methylcyclohex-1 (6)-ene-2,3,4-triols-5-benzoate (2), 3-acetoxyl-benzoyloxymethylcyclohex-1 (6)-ene-4,5-diols-2-benzoate (3) by spectroscopic methods and chemical derivatization.
Zhou
Guang-Xiong
GX
Key Laboratory of Pharmacodynamic Constituents of TCM and New Drug Research, Institute of Traditional Medicine and Natural Products, College of Pharmacy, Jinan University, Guangzhou, China. guangxzh@sina.com
Zhang
Yan-Jun
YJ
Chen
Ruo-Yun
RY
Yu
De-Quan
DQ
D001565:Benzoates / Q000737:chemistry / Q000302:isolation & purification*; D053138:Cyclohexenes / Q000737:chemistry / Q000302:isolation & purification*; D004365:Drugs, Chinese Herbal / Q000737:chemistry / Q000302:isolation & purification*; D015394:Molecular Structure; D019906:Nuclear Magnetic Resonance, Biomolecular; D010100:Oxygen / Q000737:chemistry; D018517:Plant Roots / Q000737:chemistry; D031046:Uvaria / Q000737:chemistry*
D001565:Benzoates; D053138:Cyclohexenes; D004365:Drugs, Chinese Herbal; C551930:uvacanol F; C551931:uvacanol G; C551932:uvacanol H; D010100:Oxygen