title: Synthesis, electronic properties and self-assembly on Au{111} of thiolated (oligo)phenothiazines.
abstract: (Oligo)phenothiazinyl thioacetates, synthesized by a one-pot sequence, are electrochemically oxidizable and highly fluorescent. SAMs can be readily formed from thiols prepared by in situ deprotection of the thioacetates in the presence of a gold-coated silicon wafer. Monolayer formation is confirmed by ellipsometry and the results compared to those obtained by force field and DFT calculations.
authors: Institut für Organische Chemie und Makromolekulare Chemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstr. 1, D-40225 Düsseldorf, Germany.
authors: Adam W
authors: AW
authors: Franz
authors: Svetlana
authors: S
authors: Stoycheva
authors: Michael
authors: M
authors: Himmelhaus
authors: Thomas J J
authors: TJ
authors: Müller