title: Arginine-mediated synthesis of highly efficient catalysts for transfer hydrogenations of ketones.
abstract: Palladium-hydrotalcite catalysts were prepared by immobilizing Pd(2+) on hydrotalcite (HT) via an amino acid, arginine (Arg), followed by reduction with NaBH(4) at room temperature. The resulting composite was characterized by different techniques. X-ray photoelectron spectroscopy analysis showed that the loaded Pd on hydrotalcite mainly existed in the form of Pd(0), and distributed uniformly on the support with particle size around 4 nm, as confirmed by transmission electron microscopy examination. The HT-Arg-Pd composites were used to catalyze transfer hydrogenation of aromatic ketones, which exhibited high efficiency for this kind of reaction. It was demonstrated that arginine played an important role in the high activity and stability of the catalyst, which not only mediated Pd nanoparticles to be immobilized on the HT support firmly but also promoted the transfer hydrogenation reactions.
authors: Beijing National Laboratory of Molecular Sciences, Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100190, People's Republic of China.
authors: Ranting
authors: R
authors: Tao
authors: Yun
authors: Y
authors: Xie
authors: Guimin
authors: G
authors: An
authors: Kunlun
authors: K
authors: Ding
authors: Hongye
authors: H
authors: Zhang
authors: Zhenyu
authors: Z
authors: Sun
authors: Zhimin
authors: Z
authors: Liu
mesh_terms: D000438:Alcohols / Q000138:chemical synthesis* / Q000737:chemistry; D000536:Aluminum Hydroxide / Q000737:chemistry*; D001120:Arginine / Q000737:chemistry*; D001547:Benzaldehydes / Q000737:chemistry; D002384:Catalysis; D006865:Hydrogenation; D007659:Ketones / Q000737:chemistry*; D008276:Magnesium Hydroxide / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010316:Particle Size; D013499:Surface Properties
chemical_list: D000438:Alcohols; D001547:Benzaldehydes; D007659:Ketones; D009942:Organometallic Compounds; C010467:hydrotalcite; D000536:Aluminum Hydroxide; D010165:Palladium; D001120:Arginine; D008276:Magnesium Hydroxide; C032175:benzaldehyde