Unexpected fluorescence properties in an axially sigma-bonded ferrocenyl-containing porphyrin.
Molecular structure, redox, and unexpected fluorescence properties of a tetraphenylporphyrin tin(iv) complex axially sigma-bonded with two ferrocene substituents were investigated using UV-vis, MCD, electro- and spectroelectrochemical methods as well as DFT calculations and X-ray crystallography.
Solntsev
Pavlo V
PV
Department of Chemistry & Biochemistry, 1039 University Drive, University of Minnesota Duluth, Duluth, MN 55812, USA.
Sabin
Jared R
JR
Dammer
Samantha J
SJ
Gerasimchuk
Nikolay N
NN
Nemykin
Victor N
VN