Nickel-catalysed cross-coupling reaction of aryl(trialkyl)silanes with aryl chlorides and tosylates.
Using highly stable, readily accessible, and recyclable 2-(2-hydroxyprop-2-yl)cyclohexyl-substituted arylsilanes activated by a mild carbonate base, nickel-catalysed silicon-based aryl-aryl cross-coupling reaction proceeds for the first time with inexpensive aryl chlorides and tosylates in a highly chemoselective manner.
Tang
Shi
S
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan.
Takeda
Masahide
M
Nakao
Yoshiaki
Y
Hiyama
Tamejiro
T
D002384:Catalysis; D003500:Cyclization; D006843:Hydrocarbons, Chlorinated / Q000737:chemistry*; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D012821:Silanes / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism; D014105:Tosyl Compounds / Q000138:chemical synthesis / Q000737:chemistry*
D006843:Hydrocarbons, Chlorinated; D009942:Organometallic Compounds; D012821:Silanes; D014105:Tosyl Compounds; D009532:Nickel