Synthesis of sulfuric macrocycles and a rotaxane through thiol-yne click and dithiol coupling reactions.
A macrocycle and a rotaxane were constructed by virtue of the thiol-yne click reaction under the irradiation of light in high yield, which can proceed at ambient temperature and humidity under an air atmosphere. Two disulfide macrocycles were synthesized through a simple dithiol coupling reaction, which exhibited high stability and a weak assembly interaction with a dialkylammonium ion.
Zhou
Weidong
W
National Laboratory for Molecular Sciences, Institute of Chemistry and Graduate School, Chinese Academy of Sciences, Beijing, 100190, PR China.
Zheng
Haiyan
H
Li
Yongjun
Y
Liu
Huibiao
H
Li
Yuliang
Y
D047028:Macrocyclic Compounds / Q000138:chemical synthesis*; D015394:Molecular Structure; D043862:Rotaxanes / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000138:chemical synthesis*; D014050:Toluene / Q000031:analogs & derivatives* / Q000737:chemistry
D047028:Macrocyclic Compounds; D043862:Rotaxanes; D013438:Sulfhydryl Compounds; D014050:Toluene; C004848:dithiol