title: Modifiable bidentate systems via N-C rearrangement in triazoles.
abstract: A new N-C rearrangement of substituted triazoles has been discovered. This process has been applied to the synthesis of diverse classes of mixed bidentate ligands and their metal complexes with highly modifiable backbones, including the first bisphosphine zwitterionic system based on a triazole frame.
authors: Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Technion City, Haifa 32000, Israel.
authors: Elana A Slutsky
authors: EA
authors: Smith
authors: Gregory
authors: G
authors: Molev
authors: Mark
authors: M
authors: Botoshansky
authors: Mark
authors: M
authors: Gandelman
mesh_terms: D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry; D014230:Triazoles / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D008024:Ligands; D009942:Organometallic Compounds; D014230:Triazoles