title: Unprecedented H-atom transfer from water to ketyl radicals mediated by Cp(2)TiCl.
abstract: The H-atom transfer (HAT) from water to ketyl radicals, mediated by titanocene(iii) aqua-complexes, can explain the Ti(III)-promoted reduction of ketones in aqueous medium better than the conventional House mechanism. Moreover, we also report novel evidences supporting the existence of these titanocene(iii) aqua-complexes.
authors: Department of Organic Chemistry, Faculty of Sciences, University of Granada, Campus Fuentenueva s/n, E-18071, Granada, Spain.
authors: Miguel
authors: M
authors: Paradas
authors: Araceli G
authors: AG
authors: Campaña
authors: Maria Luisa
authors: ML
authors: Marcos
authors: Jose
authors: J
authors: Justicia
authors: Ali
authors: A
authors: Haidour
authors: Rafael
authors: R
authors: Robles
authors: Diego J
authors: DJ
authors: Cárdenas
authors: J Enrique
authors: JE
authors: Oltra
authors: Juan M
authors: JM
authors: Cuerva