Shorter still: compressing C-C single bonds.
How short can a C-C single bond get? The bonding in a set of molecules that are related structurally to previously synthesized or theoretically examined systems with short C-C bonds is investigated. According to calculations, a single C-C bond could be compressed to 1.313 Å! To the best of our knowledge, this is the shortest single C-C bond reported to date. This shortening is a consequence of a change in the C-C-C bond angle, θ, to minimize strain in the cages and an effort to offset the tension in the surrounding bridges.
Martínez-Guajardo
Gerardo
G
Departamento de Química, División de Ciencias Naturales y Exactas, Universidad de Guanajuato, Col. Noria Alta s/n C.P. 36050, Guanajuato, Gto., México.
Donald
Kelling J
KJ
Wittmaack
Bernard K
BK
Vazquez
Miguel Angel
MA
Merino
Gabriel
G