title: Ag-TiO2 nanoparticle codoped SiO2 films on ZrO2 barrier-coated glass substrates with antibacterial activity in ambient condition.
abstract: Anatase TiO2 and Ag nanoparticles (NPs) codoped SiO2 films were prepared by the sol-gel method. Proportionate amounts of 3-(glycidoxypropyl)trimethoxysilane (GLYMO), tetraethylorthosilicate (TEOS) and 3-(methacryloxypropyl)trimethoxysilane (MEMO) derived inorganic-organic silica sol, commercially available dispersed anatase TiO2 NPs, and AgNO3 were used to prepare the sols. The films were prepared on ZrO2 (cubic) precoated soda-lime glass substrates by a single-dipping technique and heat-treated at 450 °C in air and H2/Ar atmosphere to obtain hard, relatively porous, and transparent coatings of thickness>600 nm. The ZrO2 barrier layer was previously applied on soda-lime glass to restrict the diffusion of Ag into the substrate. The Ag-TiO2 NPs incorporated SiO2 films were intense yellow in color and found to be fairly stable at ambient condition for several days under fluorescent light. These films show a considerable growth inhibition on contact with the gram negative bacteria E. coli.
authors: Nano-Structured Materials Division, Central Glass and Ceramic Research Institute, 196 Raja S. C. Mullick Road, Kolkata 700032, India.
authors: Anindita
authors: A
authors: Mukhopadhyay
authors: Sujit
authors: S
authors: Basak
authors: Jugal Kishore
authors: JK
authors: Das
authors: Samar Kumar
authors: SK
authors: Medda
authors: Krishnananda
authors: K
authors: Chattopadhyay
authors: Goutam
authors: G
authors: De
mesh_terms: D000900:Anti-Bacterial Agents / Q000008:administration & dosage / Q000737:chemistry; D002470:Cell Survival / Q000187:drug effects; D020099:Coated Materials, Biocompatible / Q000737:chemistry; D004926:Escherichia coli / Q000166:cytology / Q000187:drug effects*; D005898:Glass / Q000737:chemistry; D008422:Materials Testing; D053758:Nanoparticles / Q000008:administration & dosage* / Q000737:chemistry / Q000648:ultrastructure; D012822:Silicon Dioxide / Q000737:chemistry*; D012834:Silver / Q000008:administration & dosage* / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*; D015040:Zirconium / Q000737:chemistry*
chemical_list: D000900:Anti-Bacterial Agents; D020099:Coated Materials, Biocompatible; C009495:titanium dioxide; D012834:Silver; D012822:Silicon Dioxide; D015040:Zirconium; D014025:Titanium; C028541:zirconium oxide