title: Nickel-catalysed cross-coupling reaction of aryl(trialkyl)silanes with aryl chlorides and tosylates.
abstract: Using highly stable, readily accessible, and recyclable 2-(2-hydroxyprop-2-yl)cyclohexyl-substituted arylsilanes activated by a mild carbonate base, nickel-catalysed silicon-based aryl-aryl cross-coupling reaction proceeds for the first time with inexpensive aryl chlorides and tosylates in a highly chemoselective manner.
authors: Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 615-8510, Japan.
authors: Shi
authors: S
authors: Tang
authors: Masahide
authors: M
authors: Takeda
authors: Yoshiaki
authors: Y
authors: Nakao
authors: Tamejiro
authors: T
authors: Hiyama
mesh_terms: D002384:Catalysis; D003500:Cyclization; D006843:Hydrocarbons, Chlorinated / Q000737:chemistry*; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D012821:Silanes / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism; D014105:Tosyl Compounds / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D006843:Hydrocarbons, Chlorinated; D009942:Organometallic Compounds; D012821:Silanes; D014105:Tosyl Compounds; D009532:Nickel