Magnetic Fe₃O₄ nanoparticles for adsorptive removal of acid dye (new coccine) from aqueous solutions.
The ability of magnetic Fe₃O₄ nanoparticles (MFN) to remove new coccine (NC), an acidic dye, from aqueous solutions was studied. Parameters including ionic strength, pH, and temperature were evaluated. MFN, prepared by precipitation method, exhibits an average particle size of 12.5 nm, specific surface area of 85.5 m²/g, and pH(zpc) of 5.9. Results of kinetic adsorption experiments indicated that the pseudo-second-order rate of adsorption increased with increasing initial NC concentration. Findings also revealed that the equilibrium data could be fitted into Langmuir adsorption isotherm. The adsorption is favored at low pH, high temperature, and low ionic strength, whereupon a maximum adsorption capacity of 1.11 x 10⁻⁴ mol/g was determined for NC. Thermodynamic functions indicated that the adsorption process is spontaneous and exothermic in nature. Tests of regeneration showed that after 5 regeneration cycles the adsorption capacity of NC decreased to 35% to its original capacity.
Weng
Chih-Huang
CH
Department of Civil and Ecological Engineering, I-Shou University, Da-Hsu Township, Kaohsiung 84008, Chinese Taiwan. chweng@isu.edu.tw
Lin
Yao-Tung
YT
Yeh
Chia-Ling
CL
Sharma
Y C
YC
D000327:Adsorption; D001391:Azo Compounds / Q000737:chemistry / Q000302:isolation & purification*; D005290:Ferric Compounds; D052203:Ferrosoferric Oxide / Q000737:chemistry / Q000302:isolation & purification; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D008280:Magnetics; D008854:Microscopy, Electron; D008962:Models, Theoretical; D009282:Naphthalenesulfonates; D018508:Water Purification / Q000379:methods*
D001391:Azo Compounds; D005290:Ferric Compounds; D009282:Naphthalenesulfonates; C000499:ferric oxide; D052203:Ferrosoferric Oxide; C576297:ponceau 4R