title: Synthesis of sulfuric macrocycles and a rotaxane through thiol-yne click and dithiol coupling reactions.
abstract: A macrocycle and a rotaxane were constructed by virtue of the thiol-yne click reaction under the irradiation of light in high yield, which can proceed at ambient temperature and humidity under an air atmosphere. Two disulfide macrocycles were synthesized through a simple dithiol coupling reaction, which exhibited high stability and a weak assembly interaction with a dialkylammonium ion.
authors: National Laboratory for Molecular Sciences, Institute of Chemistry and Graduate School, Chinese Academy of Sciences, Beijing, 100190, PR China.
authors: Weidong
authors: W
authors: Zhou
authors: Haiyan
authors: H
authors: Zheng
authors: Yongjun
authors: Y
authors: Li
authors: Huibiao
authors: H
authors: Liu
authors: Yuliang
authors: Y
authors: Li
mesh_terms: D047028:Macrocyclic Compounds / Q000138:chemical synthesis*; D015394:Molecular Structure; D043862:Rotaxanes / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000138:chemical synthesis*; D014050:Toluene / Q000031:analogs & derivatives* / Q000737:chemistry
chemical_list: D047028:Macrocyclic Compounds; D043862:Rotaxanes; D013438:Sulfhydryl Compounds; D014050:Toluene; C004848:dithiol