title: Pyrene-fused subphthalocyanine.
abstract: A pyrene-fused subphthalocyanine synthesized from a reaction of 2,7-di-tert-butyl-4,5,9,10-tetracyanopyrene and tetrafluorophthalonitrile exhibits red-shifted Q-band absorption and a unique linear arrangement in the solid state caused by a π-π stacking interaction. The concave conjugation of the SubPc moiety and the planar conjugation of the pyrene moiety enhanced its co-crystallization with C(60) molecules.
authors: Department of Chemistry, Graduate School of Science, Tohoku University, Sendai 980-8578, Japan. ssoji@m.tohoku.ac.jp
authors: Soji
authors: S
authors: Shimizu
authors: Shota
authors: S
authors: Nakano
authors: Takahisa
authors: T
authors: Hosoya
authors: Nagao
authors: N
authors: Kobayashi
mesh_terms: D018360:Crystallography, X-Ray; D037741:Fullerenes / Q000737:chemistry; D007211:Indoles / Q000138:chemical synthesis* / Q000737:chemistry; D054833:Isoindoles; D008958:Models, Molecular; D056004:Molecular Dynamics Simulation; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry*; D011721:Pyrenes / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: C556579:2,7-di-tert-butyl-4,5,9,10-tetracyanopyrene; D037741:Fullerenes; D007211:Indoles; D054833:Isoindoles; D009570:Nitriles; D011721:Pyrenes; C069837:fullerene C60; C013647:phthalocyanine