Catalytic asymmetric protonation of alpha-amino acid-derived ketene disilyl acetals using P-spiro diaminodioxaphosphonium barfates as chiral proton.
Chiral diaminodioxaphosphonium salts have been developed and their unique abilities as a chiral proton have been revealed through the establishment of a highly enantioselective protonation of alpha-amino acid-derived ketene disilyl acetals.
Uraguchi
Daisuke
D
Department of Applied Chemistry, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan.
Kinoshita
Natsuko
N
Ooi
Takashi
T
D000080:Acetals / Q000737:chemistry*; D000596:Amino Acids / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D004952:Esters / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009943:Organophosphorus Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011522:Protons; D012821:Silanes / Q000737:chemistry*
D000080:Acetals; D000596:Amino Acids; D004952:Esters; D009943:Organophosphorus Compounds; D011522:Protons; D012821:Silanes