Indium-mediated catalytic enantioselective allylation of N-benzoylhydrazones using a protonated chiral amine.
A catalytic enantioselective indium-mediated allylation of N-benzoylhydrazones in conjunction with a protonated chiral amine affording enantioenriched homoallylic amines with an extremely high level of enantioselectivity and chemical yield was developed.
Kim
Sung Jun
SJ
Department of Chemistry, Yonsei University, Wonju, Gangwon 220-710, Korea.
Jang
Doo Ok
DO
D000478:Alkylation; D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D006835:Hydrazones / Q000138:chemical synthesis* / Q000737:chemistry; D007204:Indium / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
D000588:Amines; D006835:Hydrazones; D007204:Indium