title: Exopericyclic stereocontrol in Johnson-Claisen rearrangements of allylic sulfides.
abstract: A study of the effects of exopericyclic stereocentres on the stereoselectivity of Johnson-Claisen rearrangements of thioether-containing allylic alcohols shows that selectivity is highly dependent upon allylic substitution patterns.
authors: Department of Chemistry, Imperial College London, South Kensington Campus, London, SW7 2AZ, UK. d.craig@imperial.ac.uk
authors: Donald
authors: D
authors: Craig
authors: John W
authors: JW
authors: Harvey
authors: Alexander G
authors: AG
authors: O'Brien
authors: Andrew J P
authors: AJ
authors: White
mesh_terms: D000498:Allyl Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003500:Cyclization; D004952:Esters / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D013237:Stereoisomerism; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D013440:Sulfides / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D004952:Esters; D013438:Sulfhydryl Compounds; D013440:Sulfides