Sonochemical syntheses and characterization of nano-structured three-dimensional lead(II) coordination polymer constructed of fumaric acid.
Nano-structured three-dimensional lead(II) coordination polymer, [Pb(μ(6)-Fum)](n) (1); {Fum=Fumarate}, has been synthesized by sonochemical method and characterized by scanning electron microscopy, X-ray powder diffraction, elemental analyses and IR spectroscopy. Solvent effects on size and morphology of nano-structured compound 1 have been studied. Calcination of the nano-sized compound 1 at 600°C under air atmosphere yields PbO nanoparticles. The thermal stability of compound 1 both its bulk and nano-size has been studied by thermal gravimetric (TG) and differential thermal (DTA) analyses and compared each other.
Aboutorabi
Leila
L
Department of Chemistry, Payame Noor University, Abhar, Zanjan, Islamic Republic of Iran.
Morsali
Ali
A
D005650:Fumarates / Q000737:chemistry*; D007854:Lead / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010316:Particle Size; D011108:Polymers / Q000737:chemistry*; D013499:Surface Properties; D014465:Ultrasonics
D005650:Fumarates; D009942:Organometallic Compounds; D011108:Polymers; D007854:Lead; C032005:fumaric acid