Modifiable bidentate systems via N-C rearrangement in triazoles.
A new N-C rearrangement of substituted triazoles has been discovered. This process has been applied to the synthesis of diverse classes of mixed bidentate ligands and their metal complexes with highly modifiable backbones, including the first bisphosphine zwitterionic system based on a triazole frame.
Smith
Elana A Slutsky
EA
Schulich Faculty of Chemistry, Technion-Israel Institute of Technology, Technion City, Haifa 32000, Israel.
Molev
Gregory
G
Botoshansky
Mark
M
Gandelman
Mark
M
D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry; D014230:Triazoles / Q000138:chemical synthesis* / Q000737:chemistry
D008024:Ligands; D009942:Organometallic Compounds; D014230:Triazoles