A three-dimensional network of two-electron-transferred [Ru2]2TCNQ exhibiting anomalous conductance due to charge fluctuations.
A new D(2)A-type charge-transfer three-dimensional network with a charge distribution of [{Ru(2)}(δ+)-(BTDA-TCNQ(2δ-))-{Ru(2)}(δ+)] where δ ≈ 1, which exhibits a sudden decrease in electronic resistance, formed from the assembly of a paddlewheel diruthenium(II, II) complex ([Ru(2)]) as a donor (D) and bis(1,2,5-thiadiazolo)tetracyanoquinodimethane (BTDA-TCNQ) as an acceptor (A).
Miyasaka
Hitoshi
H
Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-ku, Sendai, Miyagi 980-8578, Japan. miyasaka@agnus.chem.tohoku.ac.jp
Morita
Takaumi
T
Yamashita
Masahiro
M
D018360:Crystallography, X-Ray; D004553:Electric Conductivity; D008280:Magnetics; D008958:Models, Molecular; D009570:Nitriles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D013696:Temperature
D009570:Nitriles; D009942:Organometallic Compounds; C013703:tetracyanoquinodimethane; D012428:Ruthenium