Organocatalytic asymmetric Michael addition of alpha-aryl cyclopentanones to nitroolefins for construction of adjacent quaternary and tertiary stereocenters.
The first asymmetric Michael addition of alpha-aryl cyclopentanones to nitroolefins for construction of adjacent quaternary and tertiary stereocenters has been achieved with excellent diastereo-/enantioselectivity.
Dong
Xiu-Qin
XQ
College of Chemistry and Molecular Sciences, Wuhan University, 430072, China.
Teng
Huai-Long
HL
Tong
Min-Chao
MC
Huang
He
H
Tao
Hai-Yan
HY
Wang
Chun-Jiang
CJ