title: First synthesis of 3-aryl-4-unsubstituted-6-CF(3)-pyridin-2-ones via aryl migration reaction in the presence of PhI(OAc)(2)/NaOH.
abstract: 3-Aryl-4-unsubstituted-6-CF(3)-pyridin-2-ones have been efficiently synthesized from readily available 4-aryl-3-carbamoyl-6-CF(3)-pyridin-2(1H)-ones by treatment with PhI(OAc)(2) in the presence of NaOH.
authors: Department of Chemistry, School of Science, Shanghai University, 99 Shangda Road, Shanghai 200444, PR China.
authors: Hai
authors: H
authors: Yi
authors: Liping
authors: L
authors: Song
authors: Wei
authors: W
authors: Wang
authors: Jianning
authors: J
authors: Liu
authors: Shizheng
authors: S
authors: Zhu
authors: Hongmei
authors: H
authors: Deng
authors: Min
authors: M
authors: Shao
mesh_terms: D000085:Acetates / Q000737:chemistry*; D007462:Iodobenzenes / Q000737:chemistry*; D015394:Molecular Structure; D011728:Pyridones / Q000138:chemical synthesis* / Q000737:chemistry; D012972:Sodium Hydroxide / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000085:Acetates; D007462:Iodobenzenes; D011728:Pyridones; C008857:phenyliodosodiacetate; D012972:Sodium Hydroxide