TAPC-promoted oxidation of sulfides and deoxygenation of sulfoxides.
1,3,5-Triazo-2,4,6-triphosphorine-2,2,4,4,6,6-tetrachloride (TAPC) was found to be an efficient promoter for the oxidation of sulfides and deoxygenation of sulfoxides. Excellent yields, short reaction time, easy and quick isolation of the products, solvent-free process, and excellent chemoselectivity are the main advantages of this procedure.
Bahrami
Kiumars
K
Department of Chemistry, Razi University, Kermanshah 67149-67346, Iran.
Khodaei
Mohammad M
MM
Sheikh Arabi
Mehdi
M
D001391:Azo Compounds / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013237:Stereoisomerism; D013440:Sulfides / Q000737:chemistry*; D013454:Sulfoxides / Q000737:chemistry*
C554863:1,3,5-triazo-2,4,6-triphosphorine-2,2,4,4,6,6-tetrachloride; D001391:Azo Compounds; D013440:Sulfides; D013454:Sulfoxides