Lewis acid catalyzed inverse electron-demand Diels-Alder reaction of 1,2-diazines.
A systematic approach toward Lewis acid catalyzed inverse electron-demand Diels-Alder (IEDDA) reactions of 1,2-diazines is described. The general concept is first investigated by DFT calculations, supported by spectroscopic data, and finally proven in the experiment.
Kessler
Simon N
SN
Department of Chemistry, University of Basel, St. Johanns-Ring 19, Basel 4056, Switzerland.
Wegner
Hermann A
HA
D002384:Catalysis; D004583:Electrons; D006573:Heterocyclic Compounds, 1-Ring / Q000737:chemistry*; D058116:Lewis Acids / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure
D006573:Heterocyclic Compounds, 1-Ring; D058116:Lewis Acids