Induction of axially chiral N-C bonds in N-aryl acridane and related complexes by chromium tricarbonyl migration reactions.
The thermal chromium tricarbonyl migration reaction induced axially chiral N-C bonds of N-aryl acridane and related complexes in good yield with outstanding enantiomeric excess.
Mori
Akiyoshi
A
Department of Chemistry, Graduate School of Science, Osaka Prefecture University, Sakai, Osaka 599-8531, Japan.
Kinoshita
Shunsuke
S
Furusyo
Masaru
M
Kamikawa
Ken
K
D000166:Acridines / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D002857:Chromium / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry; D008968:Molecular Conformation; D009584:Nitrogen / Q000737:chemistry*; D013237:Stereoisomerism; D013696:Temperature
D000166:Acridines; D056831:Coordination Complexes; D002857:Chromium; D002244:Carbon; C011633:acridan; D009584:Nitrogen