Synthesis of a 1-boratabenzene-(2,3,4,5-tetramethylphosphole): towards a planar monophosphole.
Novel boratabenzene-phosphole complexes have been prepared and structurally characterized. The electronic communication between the two heterocyclic rings linked by a P-B bond and the aromaticity of these systems were probed using crystallographic and density functional studies.
Bélanger-Chabot
Guillaume
G
Département de chimie, Université Laval, 1045 Avenue de la Médecine Cité Universitaire, Québec, Qc, G1V0A6, Canada.
Rioux
Philippe
P
Maron
Laurent
L
Fontaine
Frédéric-Georges
FG