Pushing the limits of steric demand around a biaryl axis: synthesis of tetra-ortho-substituted biaryl naphthalenes.
The synthesis of tetra-ortho-substituted biaryl naphthalenes, including examples bearing multiple ortho-isopropyl groups, has been developed via a catalytic rearrangement process.
Glass
Adam C
AC
Department of Chemistry, University of Oregon, Eugene, Oregon 97403, USA.
Klonoski
Sam
S
Zakharov
Lev N
LN
Liu
Shih-Yuan
SY
D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D009281:Naphthalenes / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D009281:Naphthalenes