[Fe(F(20)TPP)Cl] catalyzed intramolecular C-N bond formation for alkaloid synthesis using aryl azides as nitrogen source.
The syntheses of alkaloids including indoles, indolines, tetrahydroquinolines, dihydroquinazolinones and quinazolinones have been accomplished in moderate to excellent yields via [Fe(F(20)TPP)Cl] catalyzed intramolecular C-N bond formation using aryl azides as nitrogen source.
Liu
Yungen
Y
Department of Chemistry and Open Laboratory of Chemical Biology of the Institute of Molecular Technology for Drug Discovery and Synthesis, The University of Hong Kong, Pokfulam Road, Hong Kong, China.
Wei
Jinhu
J
Che
Chi-Ming
CM
D000470:Alkaloids / Q000138:chemical synthesis* / Q000737:chemistry; D001386:Azides / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D058085:Iron Compounds / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
D000470:Alkaloids; D001386:Azides; D058085:Iron Compounds