Highly efficient procedure for the synthesis of fructone fragrance using a novel carbon based acid.
The novel carbon based acid has been synthesized via one-step hydrothermal carbonization of furaldehyde and hydroxyethylsulfonic acid. A highly efficient procedure for the synthesis of fructone has been developed using the novel carbon based acid. The results showed that the catalyst possessed high activity for the reaction, giving a yield of over 95%. The advantages of high activity, stability, reusability and low cost for a simple synthesis procedure and wide applicability to various diols and beta-keto esters make this novel carbon based acid one of the best choices for the reaction.
Hu
Baowei
B
Shaoxing University, Shaoxing, China.
Li
Chunqing
C
Zhao
Sheng-Xian
SX
Rong
Lin-Mei
LM
Lv
Shao-Qin
SQ
Liang
Xuezheng
X
Qi
Chenze
C
D000090:Acetoacetates / Q000737:chemistry*; D000438:Alcohols / Q000737:chemistry; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D002625:Chemistry, Organic / Q000379:methods*; D004952:Esters / Q000737:chemistry; D006573:Heterocyclic Compounds, 1-Ring / Q000138:chemical synthesis* / Q000737:chemistry; D007513:Isethionic Acid / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D008855:Microscopy, Electron, Scanning; D010476:Perfume / Q000138:chemical synthesis* / Q000737:chemistry; D012997:Solvents / Q000737:chemistry; D013055:Spectrophotometry, Infrared; D013997:Time Factors
D000090:Acetoacetates; D000438:Alcohols; D004952:Esters; D006573:Heterocyclic Compounds, 1-Ring; D007659:Ketones; D010476:Perfume; D012997:Solvents; D002244:Carbon; D007513:Isethionic Acid