title: Coatings to reduce wood preservative leaching.
abstract: The efficiency of semitransparent penetrating stains to reduce leaching of wood preservative components was evaluated. Five commercial wood deck finishes were applied to untreated and chromated copper arsenate (CCA), alkaline copper quat (ACQ), and copper azole (CA) treated wood, and leachates were collected and analyzed during 3 years of natural weathering exposure in Toronto, Canada. All stains evaluated effectively reduced the cumulative leaching of all inorganic preservative components by about 60% on average. Although most coatings showed significant film degradation starting around 12 months, the reduced leaching persisted even after 3 years. This suggests that temporary protection of wood with a coating during the early stages of use resulted in long-term reduction in preservative leaching potential. A two-week screening leaching test was able to predict the long-term leaching performance of different coatings reasonably well. Cured coating glass transition temperature (Tg) and liquid coating viscosity were the most important variables affecting a leaching prediction model. To effectively reduce leaching of preservative components from treated wood, coatings should have Tg low enough to withstand stresses caused by freezing in winter and have adequate viscosity to form a barrier film layer on the wood surface.
authors: University of Toronto, 33 Willcocks State, Toronto, Ontario M5S 3B3, Canada. m.nejad@utoronto.ca
authors: Mojgan
authors: M
authors: Nejad
authors: Paul
authors: P
authors: Cooper
mesh_terms: D001151:Arsenic / Q000032:analysis; D003300:Copper / Q000032:analysis; D005615:Freezing; D016018:Least-Squares Analysis; D008956:Models, Chemical; D009864:Ontario; D010150:Paint / Q000032:analysis; D012621:Seasons; D014783:Viscosity; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000737:chemistry; D014887:Weather; D014934:Wood / Q000737:chemistry*
chemical_list: D014874:Water Pollutants, Chemical; D003300:Copper; D001151:Arsenic