title: Highly efficient procedure for the synthesis of fructone fragrance using a novel carbon based acid.
abstract: The novel carbon based acid has been synthesized via one-step hydrothermal carbonization of furaldehyde and hydroxyethylsulfonic acid. A highly efficient procedure for the synthesis of fructone has been developed using the novel carbon based acid. The results showed that the catalyst possessed high activity for the reaction, giving a yield of over 95%. The advantages of high activity, stability, reusability and low cost for a simple synthesis procedure and wide applicability to various diols and beta-keto esters make this novel carbon based acid one of the best choices for the reaction.
authors: Shaoxing University, Shaoxing, China.
authors: Baowei
authors: B
authors: Hu
authors: Chunqing
authors: C
authors: Li
authors: Sheng-Xian
authors: SX
authors: Zhao
authors: Lin-Mei
authors: LM
authors: Rong
authors: Shao-Qin
authors: SQ
authors: Lv
authors: Xuezheng
authors: X
authors: Liang
authors: Chenze
authors: C
authors: Qi
mesh_terms: D000090:Acetoacetates / Q000737:chemistry*; D000438:Alcohols / Q000737:chemistry; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D002625:Chemistry, Organic / Q000379:methods*; D004952:Esters / Q000737:chemistry; D006573:Heterocyclic Compounds, 1-Ring / Q000138:chemical synthesis* / Q000737:chemistry; D007513:Isethionic Acid / Q000737:chemistry*; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D008855:Microscopy, Electron, Scanning; D010476:Perfume / Q000138:chemical synthesis* / Q000737:chemistry; D012997:Solvents / Q000737:chemistry; D013055:Spectrophotometry, Infrared; D013997:Time Factors
chemical_list: D000090:Acetoacetates; D000438:Alcohols; D004952:Esters; D006573:Heterocyclic Compounds, 1-Ring; D007659:Ketones; D010476:Perfume; D012997:Solvents; D002244:Carbon; D007513:Isethionic Acid