Aryl(sulfonyl)amino group: a convenient and stable yet activated modification of amino group for its intramolecular displacement.
Aryl(sulfonyl)amino groups, readily derived from sulfonyl- or arylamines by standard methods as well as the recently introduced methods of sulfonylation and arylation, proved to be good leaving groups in intramolecular substitution reactions by various nitrogen, oxygen, and carbon nucleophiles.
Kato
Yuzo
Y
Department of Biomolecular Engineering, Graduate School of Bioscience and Biotechnology, Tokyo Institute of Technology, 4259-B-59 Nagatsuta-cho, Midori-ku, Yokohama, Kanagawa 226-8501, Japan.
Yen
Dinh Hoang
DH
Fukudome
Yasuhiro
Y
Hata
Takeshi
T
Urabe
Hirokazu
H
D000588:Amines / Q000737:chemistry*; D015394:Molecular Structure; D013440:Sulfides / Q000737:chemistry*
D000588:Amines; D013440:Sulfides