title: Copper-catalyzed olefin aminoacetoxylation.
abstract: A new catalyst system for intramolecular olefin aminoacetoxylation is described. In contrast to previously reported palladium- and copper-catalyzed systems, the conditions outlined in this communication favor piperdine formation with terminal olefin substrates and induce cyclization with traditionally less reactive disubstituted olefins.
authors.affiliation: Department of Chemistry, Emory University, Atlanta, Georgia 30322, USA.
authors.forename: Danny E
authors.initials: DE
authors.lastname: Mancheno
authors.forename: Aaron R
authors.initials: AR
authors.lastname: Thornton
authors.forename: Armin H
authors.initials: AH
authors.lastname: Stoll
authors.forename: Aidi
authors.initials: A
authors.lastname: Kong
authors.forename: Simon B
authors.initials: SB
authors.lastname: Blakey
mesh_terms: D000096:Acetone / Q000737:chemistry*; D000475:Alkenes / Q000737:chemistry*; D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D003500:Cyclization; D015394:Molecular Structure; D010084:Oxidation-Reduction
chemical_list: D000475:Alkenes; D000588:Amines; D000096:Acetone; D003300:Copper