Accelerated hole transfer across a molecular double barrier.
We report on a dyad in which photoinduced hole transfer through a non-uniform molecular double barrier is more than one order of magnitude more rapid than hole transfer across a comparable uniform (rectangular) tunneling barrier.
Hanss
David
D
Department of Inorganic, Analytical and Applied Chemistry, University of Geneva, 30 quai Ernest-Ansermet, CH-1211, Geneva, Switzerland.
Walther
Mathieu E
ME
Wenger
Oliver S
OS
D000840:Anisoles / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010640:Phenothiazines / Q000737:chemistry*; D010777:Photochemistry; D012211:Rhenium / Q000737:chemistry*; D014992:Xylenes / Q000737:chemistry
D000840:Anisoles; D009942:Organometallic Compounds; D010640:Phenothiazines; D014992:Xylenes; C031286:4-xylene; D012211:Rhenium; C060998:anisole; C031637:phenothiazine