High-nuclearity, mixed-valence Mn₁₇, Mn₁₈ and {Mn₆₂}n complexes from the use of triethanolamine.
The use of both azide and triethanolamine, with or without the presence of carboxylate groups, has provided new Mn(17), Mn(18) and {Mn(62)}(n) complexes with aesthetically-pleasing cage, layered, and linked-chain-type structures; two are also new single-molecule magnets.
Stamatatos
Theocharis C
TC
Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, USA.
Foguet-Albiol
Dolos
D
Wernsdorfer
Wolfgang
W
Abboud
Khalil A
KA
Christou
George
G
D001386:Azides / Q000737:chemistry; D004983:Ethanolamines / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*
D001386:Azides; D004983:Ethanolamines; D009942:Organometallic Compounds; D008345:Manganese