Two-step selective photoionization of rubidium by using a Ti:sapphire laser.
A pulsed Ti:sapphire laser (TSL) is applied for what is, to our knowledge, the first time to laser isotope separation. A collimated beam of a rubidium atom with a natural isotope composition ((85)Rb, 72%; (87)Rb, 28%) is excited selectively from the ground state to the 5(2)P(3/2) state by irradiation of the single-longitudinalmode TSL, and is photoionized by successive UV radiation. Ion spectra of each isotope indicate that each isotope is selectively photoionized.
Tamura
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Oba
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Arisawa
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