title: Effect of moisture and compost on fate of azoxystrobin in soils.
abstract: The effect of compost-amendment and moisture status on the persistence of azoxystrobin [methyl (E)-2-{2-(6-(2-cyanophenoxy) pyrimidin-4-yloxy) phenyl}-3-methoxyacrylate], a strobilurin fungicide, in two rice-growing soils was studied. Azoxystrobin is more sorbed in the silt loam (K f – 4.66) soil than the sandy loam (K f – 2.98) soil. Compost-amendment at 5 % levels further enhanced the azoxystrobin sorption and the respective Kf values in silt loam and sandy loam soils were 8.48 and 7.6. Azoxystrobin was more persistent in the sandy loam soil than the silt loam soil. The half–life values of azoxystrobin in nonflooded and flooded silt loam soil were 54.7 and 46.3 days, respectively. The corresponding half–life values in the sandy loam soils were 64 and 62.7 days, respectively. Compost application enhanced persistence of azoxystrobin in the silt loam soil under both moisture regimes and half-life values in non–flooded and flooded soils were 115.7 and 52.8 days, respectively. However, compost enhanced azoxystrobin degradation in the sandy loam soil and half-life values were 59 (nonflooded) and 54.7 days (flooded). The study indicates that compost amendment enhanced azoxystrobin sorption in the soils. Azoxystrobin is more persistent in non-flooded soils than the flooded soils. Compost applications to soils had mixed effect on the azoxystrobin degradation.
authors.affiliation: Division of Agricultural Chemicals, Indian Agricultural Research Institute, New Delhi, India. drneerasingh@yahoo.com
authors.forename: Neera
authors.initials: N
authors.lastname: Singh
authors.forename: Shashi B
authors.initials: SB
authors.lastname: Singh
mesh_terms: D000327:Adsorption; D005659:Fungicides, Industrial / Q000737:chemistry*; D007700:Kinetics; D008689:Methacrylates / Q000737:chemistry*; D011743:Pyrimidines / Q000737:chemistry*; D012987:Soil / Q000032:analysis*; D000073739:Strobilurins; D014867:Water / Q000032:analysis*
chemical_list: D005659:Fungicides, Industrial; D008689:Methacrylates; D011743:Pyrimidines; D012987:Soil; D000073739:Strobilurins; D014867:Water; C087670:azoxystrobin