Molybdenum-mediated carbonylation of aryl halides with nucleophiles using microwave irradiation.
A new, efficient, and practical molybdenum-mediated carbonylation of aryl and heteroaryl halides with a variety of nucleophiles is described using microwave irradiation. A range of reactions illustrating the wide scope of this chemistry were carried out and proceeded in good to excellent yields.
Roberts
Bryan
B
Department of Chemistry, AstraZeneca R&D Charnwood, Bakewell Road, Loughborough, Leics LE11 5RH, United Kingdom. bryan.roberts@astrazeneca.com
Liptrot
David
D
Alcaraz
Lilian
L
Luker
Tim
T
Stocks
Michael J
MJ
D002255:Carbonic Acid / Q000737:chemistry*; D006219:Halogens / Q000737:chemistry*; D008872:Microwaves; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry*
D006219:Halogens; D002255:Carbonic Acid; D008982:Molybdenum