title: Chiral BINOL-derived phosphoric acids: privileged Brønsted acid organocatalysts for C-C bond formation reactions.
abstract: BINOL-derived phosphoric acids have emerged during the last five years as powerful chiral Brønsted acid catalysts in many enantioselective processes. The most successful transformations carried out with chiral BINOL phosphates include C-C bond formation reactions. The recent advances have been reviewed in this article with a focus being placed on hydrocyanations, aldol-type, Mannich, Friedel-Crafts, aza-ene-type, Diels-Alder, as well as cascade and multi-component reactions.
authors.affiliation: Department of Chemistry and Pharmacy, University of Erlangen-Nuremberg, Henkestrasse 42, 91054 Erlangen, Germany.
authors.forename: Alexandru
authors.initials: A
authors.lastname: Zamfir
authors.forename: Sebastian
authors.initials: S
authors.lastname: Schenker
authors.forename: Matthias
authors.initials: M
authors.lastname: Freund
authors.forename: Svetlana B
authors.initials: SB
authors.lastname: Tsogoeva
mesh_terms: D000143:Acids / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D009281:Naphthalenes / Q000737:chemistry*; D010756:Phosphoric Acids / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000143:Acids; D009281:Naphthalenes; D010756:Phosphoric Acids; C475744:S(-)2,2'-dihydroxy-1,1'-binaphthyl; D002244:Carbon