Entropy-controlled catalytic asymmetric 1,4-type Friedel-Crafts reaction of phenols using conformationally flexible guanidine/bisthiourea organocatalyst.
Sohtome
Yoshihiro
Y
Department of Biotechnology and Life Science, Faculty of Technology, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8588, Japan. sohtomey@cc.tuat.ac.jp
Shin
Bongki
B
Horitsugi
Natsuko
N
Takagi
Rika
R
Noguchi
Keiichi
K
Nagasawa
Kazuo
K
D002384:Catalysis; D019277:Entropy; D019791:Guanidine / Q000737:chemistry*; D008954:Models, Biological; D008968:Molecular Conformation; D010636:Phenols / Q000737:chemistry*; D013890:Thiourea / Q000737:chemistry*
D010636:Phenols; D013890:Thiourea; D019791:Guanidine