Construction of hexagonal prisms of variable size via coordination-driven multicomponent self-assembly.
The coordination-driven self-assembly of supramolecular hexagonal prisms has been achieved upon mixing a hexakis[4-(4-pyridyl)phenyl]benzene donor ligand and carboxylate donor ligands such as sodium terephthalate, sodium (1,1'-biphenyl)-4,4'-dicarboxylate, sodium 4,4'-(diazene-1,2-diyl)dibenzoate, and 4,4'-dipyridyl with cis-Pt(PEt(3))(2)(OTf)(2) in a 1:3:6 ratio. Four assembled hexagonal prisms have been characterized by (31)P and (1)H NMR multinuclear spectroscopy as well as electrospray ionization mass spectrometry. Molecular force-field simulations provide the possible conformation and size of each structure.
Zhao
Zhigang
Z
Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, USA.
Zheng
Yao-Rong
YR
Wang
Ming
M
Pollock
J Bryant
JB
Stang
Peter J
PJ
D001555:Benzene Derivatives / Q000737:chemistry; D003500:Cyclization; D008024:Ligands; D046911:Macromolecular Substances / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D010316:Particle Size; D013237:Stereoisomerism
D001555:Benzene Derivatives; D008024:Ligands; D046911:Macromolecular Substances; D009942:Organometallic Compounds
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