title: Molybdenum-mediated carbonylation of aryl halides with nucleophiles using microwave irradiation.
abstract: A new, efficient, and practical molybdenum-mediated carbonylation of aryl and heteroaryl halides with a variety of nucleophiles is described using microwave irradiation. A range of reactions illustrating the wide scope of this chemistry were carried out and proceeded in good to excellent yields.
authors.affiliation: Department of Chemistry, AstraZeneca R&D Charnwood, Bakewell Road, Loughborough, Leics LE11 5RH, United Kingdom. bryan.roberts@astrazeneca.com
authors.forename: Bryan
authors.initials: B
authors.lastname: Roberts
authors.forename: David
authors.initials: D
authors.lastname: Liptrot
authors.forename: Lilian
authors.initials: L
authors.lastname: Alcaraz
authors.forename: Tim
authors.initials: T
authors.lastname: Luker
authors.forename: Michael J
authors.initials: MJ
authors.lastname: Stocks
mesh_terms: D002255:Carbonic Acid / Q000737:chemistry*; D006219:Halogens / Q000737:chemistry*; D008872:Microwaves; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry*
chemical_list: D006219:Halogens; D002255:Carbonic Acid; D008982:Molybdenum