title: Temperature and light induced bistability in a Co3[Os(CN)6]2 6 H2O Prussian blue analog.
abstract: To expand the field of new cyanide materials of the 5d elements, we incorporated the [Os(CN)(6)](3-) anion into PB architectures in combination with the Co(II) cation. Herein, we report the first example of a photomagnetic PB analog containing Os(III) ions. In a similar vein as the prototypical CoFe PB analogs, this compound exhibits a wide variety of properties including Charge Transfer Induced Spin Transition (CTIST), Temperature Induced Excited Spin State Trapping (TIESST), and magnetic ordering.
authors.affiliation: Texas A&M University, Department of Chemistry, College Station, Texas 77843, USA.
authors.forename: Carolina
authors.initials: C
authors.lastname: Avendano
authors.forename: Matthew G
authors.initials: MG
authors.lastname: Hilfiger
authors.forename: Andrey
authors.initials: A
authors.lastname: Prosvirin
authors.forename: Codi
authors.initials: C
authors.lastname: Sanders
authors.forename: Darryl
authors.initials: D
authors.lastname: Stepien
authors.forename: Kim R
authors.initials: KR
authors.lastname: Dunbar