Carboxylic acid appended dipyrrin for the formation of a hexanuclear iridium/copper paddlewheel complex.
Reaction of a heteroleptic cyclometalated iridium complex incorporating a carboxylic acid appended dipyrrin with copper acetate leads to the formation of a hexanuclear species with the paddlewheel structure.
Bronner
Catherine
C
Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université de Strasbourg, F-67000 Strasbourg, France.
Baudron
Stéphane A
SA
Hosseini
Mir Wais
MW
D002264:Carboxylic Acids / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003500:Cyclization; D007495:Iridium / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D011758:Pyrroles / Q000737:chemistry*
D002264:Carboxylic Acids; D009942:Organometallic Compounds; D011758:Pyrroles; C015092:cupric acetate; D007495:Iridium