title: Quantification of H(2)O(2) concentrations in aqueous solutions by means of combined NMR and pH measurements.
abstract: The NMR transverse relaxation time T(2), determined by a CPMG multipulse sequence, of aqueous hydrogen peroxide (H(2)O(2)) solutions strongly depends on the rate of exchange of the spin-bearing protons between the H(2)O(2) and H(2)O molecules. For pulse separations exceeding the inverse exchange rate, this value becomes a constant only depending on proton exchange time and magnetic field strength. Since this exchange time depends in a non-analytical way on the concentration of H(2)O(2) and on the pH value, a measurement of T(2) and pH allows the inversion of the data for the non-invasive determination of the H(2)O(2) concentration. The generation of calibration data for a range of concentrations and pH values is presented and is applied to a heterogeneously catalyzed H(2)O(2) decomposition involving commercial catalyst pellets. The evolution of the concentration during the course of reactions is monitored and the long-time deactivation of the pellet is demonstrated using this technique. The method is suggested as a means for contact-free and non-invasive on-line monitoring of H(2)O(2) concentrations.
authors.affiliation: Inst. of Technical Chemistry and Macromolecular Chemistry ITMC, RWTH Aachen, D-52074 Aachen, Germany. buljubasich@mpip-mainz.mpg.de
authors.forename: Lisandro
authors.initials: L
authors.lastname: Buljubasich
authors.forename: Bernhard
authors.initials: B
authors.lastname: Blümich
authors.forename: Siegfried
authors.initials: S
authors.lastname: Stapf