title: A new stable monomeric lead(ii) dithiolate Pb(SCH(2)CH(2)NMe(2))(2): an interplay between a dynamic "flip-flop" process in solution and conformational isomerism in the solid-state.
abstract: The structure and dynamic behaviour of monomeric lead(ii) dithiolate Pb(SCH(2)CH(2)NMe(2))(2) are studied by multi-nuclear NMR, IR and Raman spectroscopy in solution, as well as variable-temperature Raman spectroscopy and X-ray diffraction analysis in the solid-state, revealing an unusual dynamic "flip-flop" process in solution and reversible conformational isomerism of the chelated five-membered rings in the solid-state.
authors.affiliation: A. N. Nesmeyanov Institute of Organoelement Compounds RAS, Vavilov St., 28, Moscow, 119991, Russian Federation. vkh@xray.ineos.ac.ru
authors.forename: Victor N
authors.initials: VN
authors.lastname: Khrustalev
authors.forename: Rinat R
authors.initials: RR
authors.lastname: Aysin
authors.forename: Irina V
authors.initials: IV
authors.lastname: Borisova
authors.forename: Alexander S
authors.initials: AS
authors.lastname: Peregudov
authors.forename: Larissa A
authors.initials: LA
authors.lastname: Leites
authors.forename: Nikolai N
authors.initials: NN
authors.lastname: Zemlyansky