Ortho-directed functionalization of arenes using magnesate bases.
Ortho-directed functionalisation of arenes using lithium alkylmagnesate bases were achieved, demonstrating the potential use of arylmagnesates as suitable arylanions, without a further transmetallation step, for challenging functionalizations such as fluorination, hydroxylation, arylation, vinylation and alkylation through epoxide ring-opening.
Bellamy
Estelle
E
Institut de Chimie Organique Fine associée au CNRS (UMR 6014), INSA et Université de Rouen, Place Emile Blondel, BP08 76131, Mont Saint Aignan, France.
Bayh
Omar
O
Hoarau
Christophe
C
Trécourt
Francois
F
Quéguiner
Guy
G
Marsais
Francis
F