New laboratory intercomparison of the ozone absorption coefficients in the mid-infrared (10 μm) and ultraviolet (300-350 nm) spectral regions.
Knowing the ozone absorption cross sections in the ultraviolet and infrared spectral range, with an accuracy of better than 1%, is of the utmost importance for atmospheric remote-sensing applications. For this reason, various ozone intensity intercomparisons and measurements have been published these last years. However, the corresponding results proved not to be consistent and thus have raised a controversial discussion in the community of atmospheric remote-sensing. This study, where great care has been taken to avoid any possible error, reports a new laboratory intercomparison of the ozone absorption coefficients in the mid-infrared (10 μm) and ultraviolet (300-350 nm) spectral regions. It gives a new piece of information to the puzzling problem concerning the ozone IR and UV cross sections and confirms that the IR and UV cross sections recommended in the literature are in disagreement of about 4%.
Gratien
A
A
Laboratoire Interuniversitaire des Systèmes Atmosphériques, UMR-CNRS 7583, Université Paris-Est et Université Paris Diderot, Institut Pierre Simon Laplace (IPSL), Créteil, France.
Picquet-Varrault
B
B
Orphal
J
J
Doussin
J-F
JF
Flaud
J-M
JM
D007753:Laboratories; D010126:Ozone / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared
D010126:Ozone