Reactions of a β-diketiminate zinc hydride complex with heterocumulenes.
The β-diketiminate zinc hydride MesnacnacZnH (1) reacts with CO(2), C(Ni-Pr)(2) and t-BuNCO at ambient temperature with insertion into the Zn-H bond and subsequent formation of the corresponding formato (2), formamido (3) and formamidinato (4) complexes.
Schulz
Stephan
S
University of Duisburg-Essen, Universitätsstr. 5-7, S07 S03 C30, 45117 Essen, Germany. stephan.schulz@uni-due.de
Eisenmann
Tamara
T
Schmidt
Sarah
S
Bläser
Dieter
D
Westphal
Ulrich
U
Boese
Roland
R