Kinetic study of the fast thermal cis-to-trans isomerisation of para-, ortho- and polyhydroxyazobenzenes.
The thermal cis-to-trans isomerisation process has been studied for a series of para-, ortho- and polyhydroxy-substituted azobenzenes in different solvents. The kinetics of the thermal back reaction for the p-hydroxy-substituted azobenzenes depend strongly on the nature of the solvent used, with relaxation times ranging from 200-300 milliseconds in ethanol to half an hour in toluene. Otherwise, the process rate is mainly independent of the solvent nature for the ortho substituted analogues. Polyhydroxy-substituted azobenzenes show very much faster kinetics than the para- and ortho- monohydroxyazoderivatives. With relaxation times of 6-12 milliseconds in ethanol, they are optimal molecules for designing fast optical switching devices. All the hydroxyazoderivatives thermally isomerise from the metastable cis form to the thermodynamically stable trans isomer through a rotational mechanism.
Garcia-Amorós
Jaume
J
Grup de Materials Orgànics, Institut de Nanociència i Nanotecnologia, Departament de Química Orgànica, Facultat de Química, Universitat de Barcelona, Martí i Franquès 1-11, E-08028, Barcelona, Spain.
Sánchez-Ferrer
Antoni
A
Massad
Walter A
WA
Nonell
Santi
S
Velasco
Dolores
D