title: Enantioselective synthesis of (Z)-1,2-anti-2,5-anti-triol monosilyl ethers using a cross-metathesis allylboration sequence.
abstract: The enantioselective synthesis of (Z)-1,2-anti-2,5-anti-triol monosilyl ethers via a two-step sequence involving olefin cross-metathesis of β-alkoxyallylboronate 4 and subsequent allylboration of the derived bisboryl intermediate 6 provides triol monoethers 7 with good to excellent diastereoselectivity.
authors.affiliation: Department of Chemistry, The Scripps Research Institute, Scripps Florida, Jupiter, Florida 33458, USA.
authors.forename: SusAnn M
authors.initials: SM
authors.lastname: Winbush
authors.forename: William R
authors.initials: WR
authors.lastname: Roush
mesh_terms: D001896:Boron Compounds / Q000737:chemistry*; D004987:Ethers / Q000138:chemical synthesis*; D015394:Molecular Structure; D012821:Silanes / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D001896:Boron Compounds; D004987:Ethers; D012821:Silanes
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