Dinaphthoporphycenes.
Naphthobipyrrole is a potentially useful building block for porphyrin and porphyrin analogue synthesis. Reported here is a simple, generalizable synthetic route to α-formylated, β-substituted naphthobipyrroles and their use in the preparation of binaphthoporphycenes. The resulting binaphthoporphycenes possess a planar geometry as determined via a single-crystal X-ray diffraction analysis; they also display absorption maxima that are bathochromically shifted compared to simple porphycenes.
Roznyatovskiy
Vladimir
V
Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, Texas 78712, USA.
Lynch
Vincent
V
Sessler
Jonathan L
JL
D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D009284:Naphthols / Q000737:chemistry*; D011166:Porphyrins / Q000138:chemical synthesis*
D009284:Naphthols; D011166:Porphyrins; C051407:porphycene
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