Rigorous surface enhanced Raman spectral characterization of large-area high-uniformity silver-coated tapered silica nanopillar arrays.
Surface enhanced Raman spectroscopy (SERS) has been increasingly utilized as an analytical technique with significant chemical and biological applications (Qian et al 2008 Nat. Biotechnol. 26 83; Fujita et al 2009 J. Biomed. Opt. 14 024038; Chou et al 2008 Nano Lett.8 1729; Culha et al 2003 Anal. Chem. 75 6196; Willets K A 2009 Anal. Bioanal. Chem. 394 85; Han et al 2009 Anal. Bioanal. Chem. 394 1719; Sha et al 2008 J. Am. Chem. Soc. 130 17214). However, production of a robust, homogeneous and large-area SERS substrate with the same ultrahigh sensitivity and reproducibility still remains an important issue. Here, we describe a large-area ultrahigh-uniformity tapered silver nanopillar array made by laser interference lithography on the entire surface of a 6 inch wafer. Also presented is the rigorous optical characterization method of the tapered nanopillar substrate to accurately quantify the Raman enhancement factor, uniformity and repeatability. An average homogeneous enhancement factor of close to 10(8) was obtained for benzenethiol adsorbed on a silver-coated nanopillar substrate.
Gartia
Manas R
MR
Department of Electrical and Computer Engineering, University of Illinois at Urbana-Champaign, IL, USA.
Xu
Zhida
Z
Behymer
Elaine
E
Nguyen
Hoang
H
Britten
Jerald A
JA
Larson
Cindy
C
Miles
Robin
R
Bora
Mihail
M
Chang
Allan S-P
AS
Bond
Tiziana C
TC
Liu
G Logan
GL
D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure; D010636:Phenols; D015203:Reproducibility of Results; D012822:Silicon Dioxide / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D013059:Spectrum Analysis, Raman / Q000379:methods*; D013438:Sulfhydryl Compounds; D013499:Surface Properties
D010636:Phenols; D013438:Sulfhydryl Compounds; D012834:Silver; D012822:Silicon Dioxide; C042983:thiophenol