title: Tuning the selectivity of polymeric ionic liquid sorbent coatings for the extraction of polycyclic aromatic hydrocarbons using solid-phase microextraction.
abstract: A new generation polymeric ionic liquid (PIL), poly(1-4-vinylbenzyl)-3-hexadecylimidazolium bis[(trifluoromethyl)sulfonyl]imide (poly(VBHDIm(+) NTf(2)(-))), was synthesized and is shown to exhibit impressive selectivity towards the extraction of 12 polycyclic aromatic hydrocarbons (PAHs) from aqueous samples when used as a sorbent coating in direct-immersion solid-phase microextraction (SPME) coupled to gas chromatography (GC). The PIL was imparted with aromatic character to enhance π-π interactions between the analytes and the sorbent coating. For comparison purposes, a PIL with similar structure but lacking the π-π interaction capability, poly(1-vinyl-3-hexadecylimidazolium bis[(trifluoromethyl)sulfonyl]imide) (poly(HDIm(+) NTf(2)(-))), as well as a commercial polydimethylsiloxane (PDMS) sorbent coating were evaluated and exhibited much lower extraction efficiencies. Extraction parameters, including stir rate and extraction time, were studied and optimized. The detection limits of poly(VBHDIm(+) NTf(2)(-)), poly(HDIm(+) NTf(2)(-)), and PDMS coatings varied between 0.003-0.07 μg L(-1), 0.02-0.6 μg L(-1), and 0.1-6 μg L(-1), respectively. The partition coefficients (logK(fs)) of eight PAHs to the three studied fiber coatings were estimated using a static SPME approach. This study represents the first report of analyte partition coefficients to any PIL-based material.
authors.affiliation: Department of Chemistry, The University of Toledo, 2801 W. Bancroft Street MS 602, Toledo, OH 43606, USA.
authors.forename: Yunjing
authors.initials: Y
authors.lastname: Meng
authors.forename: Jared L
authors.initials: JL
authors.lastname: Anderson
mesh_terms: D002849:Chromatography, Gas / Q000379:methods*; D052578:Ionic Liquids / Q000737:chemistry*; D019906:Nuclear Magnetic Resonance, Biomolecular; D011084:Polycyclic Aromatic Hydrocarbons / Q000737:chemistry* / Q000302:isolation & purification; D011108:Polymers / Q000737:chemistry; D012680:Sensitivity and Specificity; D052617:Solid Phase Microextraction / Q000379:methods*
chemical_list: D052578:Ionic Liquids; D011084:Polycyclic Aromatic Hydrocarbons; D011108:Polymers