Thermosensitive gating effect and selective gas adsorption in a porous coordination nanocage.
A porous coordination nanocage functionalized with 24 triisopropylsilyl groups exhibits a remarkable thermosensitive gate opening phenomenon and demonstrates a molecular sieving effect at a certain temperature range, which can be used for gas separation purposes.
Zhao
Dan
D
Department of Chemistry, Texas A&M University, College Station, TX 77843, USA.
Yuan
Daqiang
D
Krishna
Rajamani
R
van Baten
Jasper M
JM
Zhou
Hong-Cai
HC