Highly selective metalations of pyridines and related heterocycles using new frustrated Lewis pairs or tmp-zinc and tmp-magnesium bases with BF3.OEt2.
Jaric
Milica
M
Department Chemie, Ludwig-Maximilians-Universität München, Butenandtstrasse 5-13, Haus F, 81377 München, Germany.
Haag
Benjamin A
BA
Unsinn
Andreas
A
Karaghiosoff
Konstantin
K
Knochel
Paul
P
D001880:Boranes / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000737:chemistry; D017616:Magnesium Compounds / Q000737:chemistry*; D008670:Metals / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D013237:Stereoisomerism; D015032:Zinc / Q000737:chemistry*
D001880:Boranes; D006571:Heterocyclic Compounds; D017616:Magnesium Compounds; D008670:Metals; D011725:Pyridines; D015032:Zinc