Experimental characterization and computational study of unique C,N-chelated lithium dianions.
The structure of a unique C,N-chelated dilithio dianion has been established as a solvated monomeric species using a combination of NMR and computational techniques. The highly ordered structure of the dianion may be important in its reactivity in an oxidative C-N bond-forming process.
Gruver
Jocelyn M
JM
Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, USA.
West
Scott P
SP
Collum
David B
DB
Sarpong
Richmond
R
D000838:Anions; D018020:Lithium Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular
D000838:Anions; D018020:Lithium Compounds
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