title: Construction of hexagonal prisms of variable size via coordination-driven multicomponent self-assembly.
abstract: The coordination-driven self-assembly of supramolecular hexagonal prisms has been achieved upon mixing a hexakis[4-(4-pyridyl)phenyl]benzene donor ligand and carboxylate donor ligands such as sodium terephthalate, sodium (1,1'-biphenyl)-4,4'-dicarboxylate, sodium 4,4'-(diazene-1,2-diyl)dibenzoate, and 4,4'-dipyridyl with cis-Pt(PEt(3))(2)(OTf)(2) in a 1:3:6 ratio. Four assembled hexagonal prisms have been characterized by (31)P and (1)H NMR multinuclear spectroscopy as well as electrospray ionization mass spectrometry. Molecular force-field simulations provide the possible conformation and size of each structure.
authors.affiliation: Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, USA.
authors.forename: Zhigang
authors.initials: Z
authors.lastname: Zhao
authors.forename: Yao-Rong
authors.initials: YR
authors.lastname: Zheng
authors.forename: Ming
authors.initials: M
authors.lastname: Wang
authors.forename: J Bryant
authors.initials: JB
authors.lastname: Pollock
authors.forename: Peter J
authors.initials: PJ
authors.lastname: Stang
mesh_terms: D001555:Benzene Derivatives / Q000737:chemistry; D003500:Cyclization; D008024:Ligands; D046911:Macromolecular Substances / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D010316:Particle Size; D013237:Stereoisomerism
chemical_list: D001555:Benzene Derivatives; D008024:Ligands; D046911:Macromolecular Substances; D009942:Organometallic Compounds
references.citation: J Am Chem Soc. 2010 Mar 31;132(12):4409-17
references.pmid: 20199079
references.citation: Inorg Chem. 2009 May 4;48(9):4098-107
references.pmid: 19284763
references.citation: Angew Chem Int Ed Engl. 2007;46(1-2):218-22
references.pmid: 17111445
references.citation: J Am Chem Soc. 2009 Sep 2;131(34):12028-9
references.pmid: 19663439
references.citation: J Org Chem. 2009 May 1;74(9):3554-7
references.pmid: 19348444
references.citation: Acc Chem Res. 2009 Oct 20;42(10):1650-9
references.pmid: 19591461
references.citation: Chem Soc Rev. 2009 Jun;38(6):1530-41
references.pmid: 19587949
references.citation: Chemistry. 2006 Oct 25;12(31):8136-49
references.pmid: 16862633
references.citation: Inorg Chem. 2008 Jun 2;47(11):4706-11
references.pmid: 18433099
references.citation: Acc Chem Res. 2005 Apr;38(4):349-58
references.pmid: 15835881
references.citation: Inorg Chem. 2009 Feb 2;48(3):822-4
references.pmid: 19128046
references.citation: Angew Chem Int Ed Engl. 2008;47(44):8455-9
references.pmid: 18830951
references.citation: Acc Chem Res. 2001 Oct;34(10):759-71
references.pmid: 11601960
references.citation: Org Lett. 2010 Apr 2;12(7):1380-3
references.pmid: 20218642
references.citation: J Am Chem Soc. 2010 Apr 7;132(13):4954-9
references.pmid: 20230033
references.citation: J Am Chem Soc. 2010 Jan 27;132(3):960-6
references.pmid: 20041719
references.citation: J Am Chem Soc. 2010 May 12;132(18):6282-3
references.pmid: 20405914
references.citation: Org Lett. 2000 May 4;2(9):1255-7
references.pmid: 10810721
references.citation: Acc Chem Res. 2001 Jun;34(6):477-87
references.pmid: 11412084
references.citation: Acc Chem Res. 2005 Apr;38(4):369-78
references.pmid: 15835883
references.citation: Chemistry. 2009 Jul 20;15(29):7203-14
references.pmid: 19544512
references.citation: Chem Commun (Camb). 2010 Apr 14;46(14):2382-4
references.pmid: 20309459
references.citation: Proc Natl Acad Sci U S A. 2009 Jun 30;106(26):10438-43
references.pmid: 19181859
references.citation: J Am Chem Soc. 2001 May 2;123(17):3872-7
references.pmid: 11457136
references.citation: Chem Soc Rev. 2010 May;39(5):1555-75
references.pmid: 20419210
references.citation: Angew Chem Int Ed Engl. 2006 Jun 19;45(25):4099-104
references.pmid: 16761307
references.citation: J Am Chem Soc. 2009 Jan 28;131(3):920-1
references.pmid: 19117483
references.citation: J Am Chem Soc. 2007 Nov 14;129(45):13978-86
references.pmid: 17956095
references.citation: Acc Chem Res. 2008 Dec;41(12):1618-29
references.pmid: 18642933
references.citation: J Org Chem. 2006 Aug 18;71(17):6662-5
references.pmid: 16901167
references.citation: Inorg Chem. 2008 Dec 1;47(23):11257-68
references.pmid: 18980302
references.citation: Acc Chem Res. 2007 Feb;40(2):103-12
references.pmid: 17309191
references.citation: Acc Chem Res. 2005 Jan;38(1):1-9
references.pmid: 15654731
references.citation: Acc Chem Res. 2009 Oct 20;42(10):1554-63
references.pmid: 19555073
references.citation: J Am Chem Soc. 2004 Dec 22;126(50):16569-74
references.pmid: 15600362
references.citation: Science. 2004 May 28;304(5675):1308-12
references.pmid: 15166376
references.citation: J Am Chem Soc. 2001 Apr 25;123(16):3818-9
references.pmid: 11457114
references.citation: Chem Soc Rev. 2007 Sep;36(9):1441-53
references.pmid: 17660877
references.citation: J Am Chem Soc. 2007 Sep 5;129(35):10652-3
references.pmid: 17685616
references.citation: Angew Chem Int Ed Engl. 2009;48(19):3418-38
references.pmid: 19391140
references.citation: Chem Rev. 2005 Apr;105(4):1445-89
references.pmid: 15826017
references.citation: J Am Chem Soc. 2010 Apr 14;132(14):5309-14
references.pmid: 20334379
references.citation: Science. 2007 Apr 6;316(5821):85-8
references.pmid: 17412953
references.citation: Nature. 1999 Apr 29;398(6730):796-9
references.pmid: 10235260
references.citation: Angew Chem Int Ed Engl. 1998 Aug 17;37(15):2082-2085
references.pmid: 29711041
references.citation: Angew Chem Int Ed Engl. 2001 Jun 1;40(11):2022-2043
references.pmid: 11433436
references.citation: Acc Chem Res. 2002 Nov;35(11):972-83
references.pmid: 12437322
references.citation: Angew Chem Int Ed Engl. 2004 Jul 12;43(28):3644-62
references.pmid: 15248266
references.citation: J Am Chem Soc. 1995 Feb;117(5):1649-1650
references.pmid: 28186743
references.citation: Science. 2001 Mar 23;291(5512):2331-2
references.pmid: 11269307
references.citation: Chem Rev. 2000 Mar 8;100(3):853-908
references.pmid: 11749254