Electrophilic functionalization of well-behaved manganese monoanions supported by m-terphenyl isocyanides.
The m-terphenyl isocyanides CNAr(Mes2) and CNAr(Dipp2) support five-coordinate, isocyanide/carbonyl monoanions of manganese. For CNAr(Dipp2), a bis-isocyanide anion is available that is remarkably well behaved upon reaction with electrophiles. Most notable is the formation of an unprecedented chloride-substituted metallostannylene.
Stewart
Mason A
MA
Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, Mail Code 0358, La Jolla, California 92093-0358, USA.
Moore
Curtis E
CE
Ditri
Treffly B
TB
Labios
Liezel A
LA
Rheingold
Arnold L
AL
Figueroa
Joshua S
JS
D000838:Anions / Q000737:chemistry; D018360:Crystallography, X-Ray; D003486:Cyanides / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D056004:Molecular Dynamics Simulation; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013237:Stereoisomerism; D013730:Terphenyl Compounds / Q000737:chemistry*
D000838:Anions; D003486:Cyanides; D009942:Organometallic Compounds; D013730:Terphenyl Compounds; D008345:Manganese