Novel functionalized metal-organic framework based on unique hexagonal prismatic clusters.
The novel porous 3D metal-organic framework synthesized from fluorenone-2,7-dicarboxylate contains zinc-glycolate-carboxylate layers in which the unique hexagonal prismatic [Zn(6)(OCH(2)CH(2)O)(6)] clusters are connected by planar [Zn(3)(OCH(2)CH(2)O)(COO)(2)] motifs; the pore surface is furnished with carbonyl groups and open metal sites.
Yue
Qi
Q
Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China.
Yan
Li
L
Zhang
Jian-Yong
JY
Gao
En-Qing
EQ
D003998:Dicarboxylic Acids / Q000737:chemistry*; D005449:Fluorenes / Q000737:chemistry*; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D016062:Porosity; D013499:Surface Properties; D015032:Zinc / Q000737:chemistry*
D003998:Dicarboxylic Acids; D005449:Fluorenes; D009942:Organometallic Compounds; D015032:Zinc