title: Regio- and stereoselective copper-catalyzed β-borylation of allenoates by a preactivated diboron.
abstract: A mild and efficient copper-catalyzed borylation of electron deficient allenoates using an sp(2)-sp(3) mixed hybridized diboron regioselectively installs a boron moiety on the β-position with exclusive (Z)-double bond geometry.
authors.affiliation: Department of Chemistry, Virginia Tech, Blacksburg, Virginia 24061, USA.
authors.forename: Steven B
authors.initials: SB
authors.lastname: Thorpe
authors.forename: Xi
authors.initials: X
authors.lastname: Guo
authors.forename: Webster L
authors.initials: WL
authors.lastname: Santos
mesh_terms: D000466:Alkadienes / Q000737:chemistry*; D001897:Boronic Acids / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D000466:Alkadienes; D001897:Boronic Acids; D003300:Copper