Single and binary adsorption of reactive dyes from aqueous solutions onto clinoptilolite.
The adsorption of Reactive Blue 21 (RB21) and Reactive Red 195 (RR195) onto clinoptilolite type natural zeolite (ZEC) has been investigated at 298.15K. The uptake of single and binary reactive dyes from aqueous solutions has been determined by UV-vis spectroscopy. Two mono-component (RB21 and RR195) and binary component (RB21 with RR195, and RR195 with RB21), isotherms were determined. The mono-component Langmuir isotherm model was applied to experimental data and the isotherm constants were calculated for RB21 and RR195 dyes. The monolayer coverage capacities of clinoptilolite for RB21 and RR195 dyes in single solution system were found as 9.652 and 3.186 mg/g, respectively. Equilibrium adsorption for binary systems was analyzed by using the extended Langmuir models. The rate of kinetic processes of single and binary dye systems onto clinoptilolite was described by using two kinetics adsorption models. The pseudo-second-order model was the best choice among the kinetic models to describe the adsorption behaviour of single and binary dyes onto clinoptilolite.
Sismanoglu
Tuba
T
Istanbul University, Engineering Faculty, Department of Chemistry, Avcilar, 34850 Istanbul, Turkey. Electronic address: tusase@istanbul.edu.tr.
Kismir
Yasemin
Y
Istanbul University, Engineering Faculty, Department of Chemistry, Avcilar, 34850 Istanbul, Turkey.
Karakus
Selcan
S
Istanbul University, Engineering Faculty, Department of Chemistry, Avcilar, 34850 Istanbul, Turkey.
D000327:Adsorption; D001391:Azo Compounds / Q000737:chemistry*; D003116:Color; D004396:Coloring Agents / Q000737:chemistry*; D007700:Kinetics; D008665:Metalloporphyrins / Q000737:chemistry*; D009282:Naphthalenesulfonates / Q000737:chemistry*; D012996:Solutions; D013056:Spectrophotometry, Ultraviolet; D013816:Thermodynamics; D014867:Water; D017641:Zeolites / Q000737:chemistry*
D001391:Azo Compounds; D004396:Coloring Agents; D008665:Metalloporphyrins; D009282:Naphthalenesulfonates; D012996:Solutions; C545303:reactive red 195; D014867:Water; C083175:clinoptilolite; D017641:Zeolites; C471069:reactive blue 21