title: Electrophilic functionalization of well-behaved manganese monoanions supported by m-terphenyl isocyanides.
abstract: The m-terphenyl isocyanides CNAr(Mes2) and CNAr(Dipp2) support five-coordinate, isocyanide/carbonyl monoanions of manganese. For CNAr(Dipp2), a bis-isocyanide anion is available that is remarkably well behaved upon reaction with electrophiles. Most notable is the formation of an unprecedented chloride-substituted metallostannylene.
authors.affiliation: Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, Mail Code 0358, La Jolla, California 92093-0358, USA.
authors.forename: Mason A
authors.initials: MA
authors.lastname: Stewart
authors.forename: Curtis E
authors.initials: CE
authors.lastname: Moore
authors.forename: Treffly B
authors.initials: TB
authors.lastname: Ditri
authors.forename: Liezel A
authors.initials: LA
authors.lastname: Labios
authors.forename: Arnold L
authors.initials: AL
authors.lastname: Rheingold
authors.forename: Joshua S
authors.initials: JS
authors.lastname: Figueroa
mesh_terms: D000838:Anions / Q000737:chemistry; D018360:Crystallography, X-Ray; D003486:Cyanides / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D056004:Molecular Dynamics Simulation; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013237:Stereoisomerism; D013730:Terphenyl Compounds / Q000737:chemistry*
chemical_list: D000838:Anions; D003486:Cyanides; D009942:Organometallic Compounds; D013730:Terphenyl Compounds; D008345:Manganese