Synthesis, structures and electrochemistry studies of 2Fe2S-Fe(ii)(S-2N)(2) models for H-cluster of [FeFe]-hydrogenase.
A series of model complexes [(μ-pdt)Fe(2)(CO)(5)](2)M(sip)(2) (M = Fe, Ni) were synthesized as H-cluster analogues of [FeFe]-hydrogenase. Their electrochemical behaviours were investigated and it is proposed that the bridging metal bis(tris-chelate) groups act as electron transfer sites in theses mimics.
Hu
Ming-Qiang
MQ
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, PR China.
Wen
Hui-Min
HM
Ma
Cheng-Bing
CB
Li
Na
N
Yan
Qing-Yun
QY
Chen
Hui
H
Chen
Chang-Neng
CN
D056831:Coordination Complexes / Q000138:chemical synthesis* / Q000737:chemistry; D055664:Electrochemical Techniques; D004579:Electron Transport; D006864:Hydrogenase / Q000737:chemistry* / Q000378:metabolism; D007506:Iron-Sulfur Proteins / Q000737:chemistry* / Q000378:metabolism; D008958:Models, Molecular; D008968:Molecular Conformation
D056831:Coordination Complexes; D007506:Iron-Sulfur Proteins; C118830:iron hydrogenase; D006864:Hydrogenase