title: Rapid and simple low density miniaturized homogeneous liquid-liquid extraction and gas chromatography/mass spectrometric determination of pesticide residues in sediment.
abstract: A simple, rapid and environmentally friendly analytical methodology is developed for extraction of pesticides (diazinon, chlorpyrifos and trifluralin) from sediment samples based on a technique called low density miniaturized homogenous liquid-liquid extraction (LDMHLLE) prior gas chromatography mass spectrometry determination. The method based on homogeneous liquid-liquid extraction with methanol containing n-hexane as a solvent of lower density than water (n-hexane). After addition of water, n-hexane solvent immediately forms a distinct water immiscible phase at the top of the vial, which can be easily separated and injected to the GC/MS instrument for quantification. Acquisition was performed in the selected ion monitoring mode. The limits of detection were estimated for the individual pesticides as 3S(b) (three times of the standard deviation of baseline) of the measured chromatogram for pesticides. The proposed method is very fast, simple, and sensitive without any need for stirring and centrifugation and applied to real sediment samples, successfully.
authors.affiliation: Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, Tehran, Iran. Electronic address: hassan_jal@yahoo.com.
authors.forename: Jalal
authors.initials: J
authors.lastname: Hassan
authors.affiliation: Department of Environmental, Iranian Mineral Processing Research Center, Ministry of Industry and Mineral, Karaj, Iran.
authors.forename: Abolfazl
authors.initials: A
authors.lastname: Farahani
authors.affiliation: Department of Chemistry, Razi University, Kermanshah, Iran.
authors.forename: Mojtaba
authors.initials: M
authors.lastname: Shamsipur
authors.affiliation: Department of Environmental, Iranian Mineral Processing Research Center, Ministry of Industry and Mineral, Karaj, Iran.
authors.forename: Fatemeh
authors.initials: F
authors.lastname: Damerchili
mesh_terms: D002853:Chromatography, Liquid / Q000379:methods*; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods*; D019015:Geologic Sediments / Q000032:analysis*; D006586:Hexanes / Q000737:chemistry; D057230:Limit of Detection; D010573:Pesticide Residues / Q000032:analysis*; D012997:Solvents / Q000737:chemistry
chemical_list: D006586:Hexanes; D010573:Pesticide Residues; D012997:Solvents; C026385:n-hexane