title: Palladium-catalyzed carbo-heterofunctionalization of alkenes for the synthesis of oxindoles and spirooxindoles.
abstract: A palladium-catalyzed oxidative carbo-heterofunctionalization of aniline derivatives involving concomitant direct C-H functionalization and C-X bond formation was developed. By simply changing the reaction conditions (solvent and catalyst), either 3,3'-disubstituted oxindole or spirooxindole was accessible from the same starting material.
authors.affiliation: Centre de Recherche de Gif, Institut de Chimie des Substances Naturelles, CNRS, 91198 Gif-sur-Yvette Cedex, France.
authors.forename: Stéphanie
authors.initials: S
authors.lastname: Jaegli
authors.forename: Jeremy
authors.initials: J
authors.lastname: Dufour
authors.forename: Hai-long
authors.initials: HL
authors.lastname: Wei
authors.forename: Tiffany
authors.initials: T
authors.lastname: Piou
authors.forename: Xin-Hua
authors.initials: XH
authors.lastname: Duan
authors.forename: Jean-Pierre
authors.initials: JP
authors.lastname: Vors
authors.forename: Luc
authors.initials: L
authors.lastname: Neuville
authors.forename: Jieping
authors.initials: J
authors.lastname: Zhu
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D007211:Indoles / Q000138:chemical synthesis*; D010084:Oxidation-Reduction; D000078183:Oxindoles; D010165:Palladium / Q000737:chemistry*; D013141:Spiro Compounds / Q000138:chemical synthesis*
chemical_list: D000475:Alkenes; D007211:Indoles; D000078183:Oxindoles; D013141:Spiro Compounds; C022960:2-oxindole; D010165:Palladium