Palladium-catalyzed tandem diperoxidation/C-H activation resulting in diperoxy-oxindole in air.
A highly efficient and facile palladium-catalyzed tandem diperoxidation and C-H activation process was reported, which provides a new pathway for the synthesis of biologically active diperoxides as well as oxindole derivatives from readily available starting materials in excellent chemical yields.
An
Guanghui
G
School of Chemistry and Chemical Engineering, State Key Laboratory of Coordination Nanjing University, Nanjing, 210093, China.
Zhou
Wei
W
Zhang
Guangqian
G
Sun
Hao
H
Han
Jianlin
J
Pan
Yi
Y
D000388:Air; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D006859:Hydrogen / Q000737:chemistry*; D007211:Indoles / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction; D000078183:Oxindoles; D010165:Palladium / Q000737:chemistry*; D010545:Peroxides / Q000737:chemistry*
D007211:Indoles; D000078183:Oxindoles; D010545:Peroxides; C022960:2-oxindole; D010165:Palladium; D002244:Carbon; D006859:Hydrogen