title: Synthesis of fluorescent dye-tagged nanomachines for single-molecule fluorescence spectroscopy.
abstract: In an effort to elucidate the mechanism of movement of nanovehicles on nonconducting surfaces, the synthesis and optical properties of five fluorescently tagged nanocars are reported. The nanocars were specifically designed for studies by single-molecule fluorescence spectroscopy and bear a tetramethylrhodamine isothiocyanate fluorescent tag for excitation at 532 nm. The molecules were designed such that the arrangement of their molecular axles and p-carborane wheels relative to the chassis would be conducive to the control of directionality in the motion of these nanovehicles.
authors.affiliation: Department of Chemistry, Department of Mechanical Engineering and Materials Science, The Smalley Institute for Nanoscale Science and Technology, Rice University, MS 222, 6100 Main Street, Houston, Texas 77005, USA.
authors.forename: Guillaume
authors.initials: G
authors.lastname: Vives
authors.forename: Jason M
authors.initials: JM
authors.lastname: Guerrero
authors.forename: Jazmin
authors.initials: J
authors.lastname: Godoy
authors.forename: Saumyakanti
authors.initials: S
authors.lastname: Khatua
authors.forename: Yu-Pu
authors.initials: YP
authors.lastname: Wang
authors.forename: J L
authors.initials: JL
authors.lastname: Kiappes
authors.forename: Stephan
authors.initials: S
authors.lastname: Link
authors.forename: James M
authors.initials: JM
authors.lastname: Tour
mesh_terms: D005456:Fluorescent Dyes / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D049329:Nanostructures / Q000737:chemistry*; D012235:Rhodamines / Q000737:chemistry; D013050:Spectrometry, Fluorescence; D013237:Stereoisomerism
chemical_list: D005456:Fluorescent Dyes; D012235:Rhodamines; C009434:tetramethylrhodamine isothiocyanate