title: Palladium-catalyzed propargylic substitution with phosphorus nucleophiles: efficient, stereoselective synthesis of allenylphosphonates and related compounds.
abstract: A new, efficient method is developed, based on a palladium(0)-catalyzed reaction of propargylic derivatives with various phosphorus nucleophiles, to produce allenylphosphonates and their analogues with defined stereochemistry in the allenic and the phosphonate moiety.
authors.affiliation: Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, S-106 91 Stockholm, Sweden.
authors.forename: Marcin
authors.initials: M
authors.lastname: Kalek
authors.forename: Tommy
authors.initials: T
authors.lastname: Johansson
authors.forename: Martina
authors.initials: M
authors.lastname: Jezowska
authors.forename: Jacek
authors.initials: J
authors.lastname: Stawinski
mesh_terms: D000466:Alkadienes / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D010710:Phosphates / Q000138:chemical synthesis*; D010758:Phosphorus / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000466:Alkadienes; D010710:Phosphates; D010758:Phosphorus; C025947:propadiene; D010165:Palladium