title: A simple metric to predict stream water quality from storm runoff in an urban watershed.
abstract: The contribution of runoff from various land uses to stream channels in a watershed is often speculated and used to underpin many model predictions. However, these contributions, often based on little or no measurements in the watershed, fail to appropriately consider the influence of the hydrologic location of a particular landscape unit in relation to the stream network. A simple model was developed to predict storm runoff and the phosphorus (P) status of a perennial stream in an urban watershed in New York State using the covariance structure of runoff from different landscape units in the watershed to predict runoff in time. One hundred and twenty-seven storm events were divided into parameterization (n = 85) and forecasting (n = 42) data sets. Runoff, dissolved P (DP), and total P (TP) were measured at nine sites distributed among three land uses (high maintenance, unmaintained, wooded), three positions in the watershed (near the outlet, midwatershed, upper watershed), and in the stream at the watershed outlet. The autocorrelation among runoff and P concentrations from the watershed landscape units (n = 9) and the covariance between measurements from the landscape units and measurements from the stream were calculated and used to predict the stream response. Models, validated using leave-one-out cross-validation and a forecasting method, were able to correctly capture temporal trends in streamflow and stream P chemistry (Nash-Sutcliffe efficiencies, 0.49-0.88). The analysis suggests that the covariance structure was consistent for all models, indicating that the physical processes governing runoff and P loss from these landscape units were stationary in time and that landscapes located in hydraulically active areas have a direct hydraulic link to the stream. This methodology provides insight into the impact of various urban landscape units on stream water quantity and quality.
authors.affiliation: Dep. of Biological and Environmental Engineering, Riley Robb Hall, Cornell Univ., Ithaca, NY 14853, USA. zme2@cornell.edu
authors.forename: Zachary M
authors.initials: ZM
authors.lastname: Easton
authors.forename: Patrick J
authors.initials: PJ
authors.lastname: Sullivan
authors.forename: M Todd
authors.initials: MT
authors.lastname: Walter
authors.forename: Daniel R
authors.initials: DR
authors.lastname: Fuka
authors.forename: A Martin
authors.initials: AM
authors.lastname: Petrovic
authors.forename: Tammo S
authors.initials: TS
authors.lastname: Steenhuis
mesh_terms: D002947:Cities; D004784:Environmental Monitoring / Q000379:methods*; D005544:Forecasting; D008962:Models, Theoretical; D010758:Phosphorus / Q000737:chemistry; D011891:Rain; D045483:Rivers / Q000737:chemistry*; D014872:Water Movements; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: D014874:Water Pollutants, Chemical; D010758:Phosphorus