title: Synthesis and characterisation of alkylaluminium benzimidazolates and their use in the ring-opening polymerisation of ε-caprolactone.
abstract: The stoichiometric reactions of 2-(benzimidazol-2-yl)-6-methylpyridine (L1) or 8-(benzimidazol-2-yl)quinaldine (L2) with trialkylaluminium reagents R(3)Al (R = Me, Et and iBu) afforded the corresponding dialkylaluminium benzimidazolate complexes R(2)AlL (L1, R = Me (1), Et (2), iBu (3); L2 R = Me (4), Et (5), iBu (6)). Treatment of L1 with one or two equivalents of Et(2)AlCl led to the adducts EtAl(L1)(2)·AlEtCl(2) (7) or Et(2)AlL1·AlEtCl(2) (8), respectively. Complex 7 was also available via treatment of 8 with one equivalent of L1. Reaction of L1 with two equivalents of AlR(3) (R = Me or Et) afforded R(2)AlL1·AlR(3) (R = Me, 9; R = Et, 10), which were also formed when 1 or 2 were reacted with AlR(3). Reaction of L2 with two equivalents of AlR(3) (R = Me or Et) gave the complexes R(2)AlL2·AlR(3) (R = Me, 11; R = Et, 12), which were also formed in the stoichiometric reaction of 4 or 5 with AlR(3) (R = Me or Et). Screening of these complexes in the presence of BnOH, for the ring-open polymerisation of ε-caprolactone, revealed appreciable activities. Only the aluminium compounds ligated by 2-(benzimidazol-2-yl)-6-methylpyridine maintained high activity in the absence of BnOH. In all cases, polymers with bi- or multi-modal characteristics were produced.
authors.affiliation: Key Laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
authors.forename: Miao
authors.initials: M
authors.lastname: Shen
authors.forename: Wei
authors.initials: W
authors.lastname: Huang
authors.forename: Wenjuan
authors.initials: W
authors.lastname: Zhang
authors.forename: Xiang
authors.initials: X
authors.lastname: Hao
authors.forename: Wen-Hua
authors.initials: WH
authors.lastname: Sun
authors.forename: Carl
authors.initials: C
authors.lastname: Redshaw