title: The unexpected mechanism of carbonyl hydrosilylation catalyzed by (Cp)(ArN[double bond, length as m-dash])Mo(H)(PMe(3)).
abstract: Complex (Cp)(ArN[double bond, length as m-dash])Mo(H)(PMe(3)) (2, Ar = 2,6-diisopropylphenyl) catalyzes the hydrosilylation of carbonyls by an unexpected associative mechanism. Complex 2 also reacts with PhSiH(3) by a σ-bond metathesis mechanism to give the silyl derivative (Cp)(ArN[double bond, length as m-dash])Mo(SiH(2)Ph)(PMe(3)).
authors.affiliation: Chemistry Department, Brock University, 500 Glenridge Avenue, St. Catharines, ON, Canada, L2S 3A1. gnikonov@brocku.ca.
authors.forename: Oleg
authors.initials: O
authors.lastname: Sherbrooke
authors.affiliation: Center for Catalysis Research and Innovation, University of Ottawa, 30 Marie Curie Street, Ottawa, ON, Canada, K1N 6N5. gorelsky@gmail.com.
authors.forename: Serge I
authors.initials: SI
authors.lastname: Gorelsky
authors.affiliation: Chemistry Department, Brock University, 500 Glenridge Avenue, St. Catharines, ON, Canada, L2S 3A1. gnikonov@brocku.ca.
authors.forename: Razvan
authors.initials: R
authors.lastname: Simionescu
authors.affiliation: Kurnakov Institute of General and Inorganic Chemistry, 31 Leninsky prospect, Moscow, 119991, Russia. kuzmina@igic.ras.ru.
authors.forename: Lyudmila G
authors.initials: LG
authors.lastname: Kuzmina
authors.affiliation: Chemistry Department, Brock University, 500 Glenridge Avenue, St. Catharines, ON, Canada, L2S 3A1. gnikonov@brocku.ca.
authors.forename: Georgii I
authors.initials: GI
authors.lastname: Nikonov