Amphiphilic photo-isomerisable phosphanes for aqueous organometallic catalysis.
Water-soluble phosphanes were tagged with a light-responding diazo group. Upon UV exposure, the diazo-isomerisation led to phosphane morphology change, resulting in an increase in the reaction rate of an aqueous palladium-catalysed cleavage reaction.
Bricout
Hervé
H
Université de Lille Nord de France, CNRS UMR 8181, UArtois UCCS, Faculté des Sciences Jean Perrin, rue Jean Souvraz, SP 18, F-62307 Lens Cedex, France.
Banaszak
Estelle
E
Len
Christophe
C
Hapiot
Frédéric
F
Monflier
Eric
E
D002384:Catalysis; D057927:Hydrophobic and Hydrophilic Interactions; D007536:Isomerism; D009942:Organometallic Compounds / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D055668:Photochemical Processes; D014867:Water / Q000737:chemistry*
D009942:Organometallic Compounds; D010720:Phosphines; D014867:Water; C044646:phosphine