Heterogeneous catalytic transesterification of phosphatidylcholine.
The transesterification of phosphatidylcholine (PC) via homogeneous and heterogeneous catalysis was investigated for the production of fatty acid methyl esters (FAME) i.e. biodiesel. Calcium methoxide and calcium oxide were used as heterogeneous catalysts, and KOH as a homogeneous catalyst for the transesterification of phosphatidylcholine (PC)--a polar phospholipid prevalent in eukaryotic organisms. The initial reaction rate was higher for KOH (24.23 g of FAME/g of catalyst.min) than for calcium methoxide (17.06 g of FAME/g of catalyst.min) and calcium oxide (1.06 g of FAME/g of catalyst.min). PC was then mixed with soybean oil at different proportions (i.e. 10%, 30% and 50%, PC10, PC30 and PC50, respectively) which was then used as the feedstock for transesterification using calcium methoxide. When the mass fraction of PC was increased in the feedstock reaction rate also increased. Phosphorus content of the FAME layer of PC100, PC50, PC30 and PC10 was 0.081, 0.041, 0.035 and 0.028% (w/w), respectively.
Balasubramanian
Rajesh Kumar
RK
Division of Environmental Science and Engineering, National University of Singapore, Singapore 117576, Singapore. rajeshkumar_bala@ices.a-star.edu.sg
Obbard
Jeffrey Philip
JP
D001709:Biotechnology / Q000379:methods*; D017610:Calcium Compounds / Q000737:chemistry; D002384:Catalysis; D004951:Esterification; D004952:Esters / Q000032:analysis; D010713:Phosphatidylcholines / Q000737:chemistry*; D010758:Phosphorus / Q000302:isolation & purification; D014280:Triglycerides / Q000737:chemistry
D017610:Calcium Compounds; D004952:Esters; D010713:Phosphatidylcholines; D014280:Triglycerides; D010758:Phosphorus