title: A passive sampling-based analytical strategy for the determination of volatile organic compounds in the air of working areas.
abstract: An analytical methodology based on the use of a polyethylene layflat tube filled with activated carbon and Florisil (ACFL-VERAM) was employed for the passive sampling of volatile organic compounds (VOCs) in the air of working areas of packing industries. VOCs amount in the ACFL-VERAM sampler was directly determined through head-space-gas chromatography-mass spectrometry (HS-GC-MS) allowing a direct determination in only 20 min without the need of any previous treatment. Uptake parameters, like sampling rate (R(S)) and sampler-air partition coefficient (K(SA)), were determined for every studied VOC from adsorption isotherm data. Additionally, experimental equations have been proposed to predict R(S) and K(SA) from the octanol-air partition coefficients reported in the literature. The proposed methodology reaches method detection levels from 0.007 to 0.2 mg m(-3) for the studied VOCs.
authors.affiliation: Analytical Chemistry Department, University of Valencia, Edifici Jeroni Muñoz, 50 Dr. Moliner, 46100 Burjassot, Valencia, Spain.
authors.forename: Saray
authors.initials: S
authors.lastname: Ly-Verdú
authors.forename: Francesc A
authors.initials: FA
authors.lastname: Esteve-Turrillas
authors.forename: Agustín
authors.initials: A
authors.lastname: Pastor
authors.forename: Miguel
authors.initials: M
authors.lastname: de la Guardia
mesh_terms: D000327:Adsorption; D000388:Air / Q000032:analysis*; D000395:Air Pollutants, Occupational / Q000032:analysis* / Q000737:chemistry; D004784:Environmental Monitoring / Q000379:methods*; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods; D007221:Industry; D057230:Limit of Detection; D055549:Volatile Organic Compounds / Q000032:analysis* / Q000737:chemistry; D014835:Volatilization
chemical_list: D000395:Air Pollutants, Occupational; D055549:Volatile Organic Compounds