title: Flavin-cyclodextrin conjugates as catalysts of enantioselective sulfoxidations with hydrogen peroxide in aqueous media.
abstract: β-Cyclodextrin-flavin conjugates are highly efficient catalysts for the sulfoxidation of methyl phenyl sulfides with hydrogen peroxide in neat aqueous media operating at loadings down to 0.2 mol% and allowing for enantioselectivities up to 80% ee.
authors.affiliation: Department of Organic Chemistry, Institute of Chemical Technology, Prague, Technická 5, Prague 6, Czech Republic.
authors.forename: Viktor
authors.initials: V
authors.lastname: Mojr
authors.forename: Vladimír
authors.initials: V
authors.lastname: Herzig
authors.forename: Miloš
authors.initials: M
authors.lastname: Buděšínský
authors.forename: Radek
authors.initials: R
authors.lastname: Cibulka
authors.forename: Tomáš
authors.initials: T
authors.lastname: Kraus
mesh_terms: D002384:Catalysis; D005415:Flavins / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D010084:Oxidation-Reduction; D013237:Stereoisomerism; D013440:Sulfides / Q000737:chemistry*; D014867:Water / Q000737:chemistry; D047392:beta-Cyclodextrins / Q000737:chemistry*
chemical_list: D005415:Flavins; D013440:Sulfides; D047392:beta-Cyclodextrins; D014867:Water; C093850:methylphenylsulfide; D006861:Hydrogen Peroxide; C031215:betadex