New binuclear double-stranded manganese helicates as catalysts for alkene epoxidation.
New binuclear double-stranded helicates were formed between manganese(ii) perchlorate and chiral phenyl- and polyphenyl-bridged oligopyridines; they are active catalysts for alkene epoxidation.
Sham
Kiu-Chor
KC
Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong SAR.
Yeung
Ho-Lun
HL
Yiu
Shek-Man
SM
Lau
Tai-Chu
TC
Kwong
Hoi-Lun
HL
D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D002942:Circular Dichroism; D018360:Crystallography, X-Ray; D004852:Epoxy Compounds / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D008968:Molecular Conformation; D010472:Perchlorates / Q000737:chemistry; D011725:Pyridines / Q000737:chemistry; D021241:Spectrometry, Mass, Electrospray Ionization; D013237:Stereoisomerism
D000475:Alkenes; D004852:Epoxy Compounds; D010472:Perchlorates; D011725:Pyridines; D008345:Manganese; C494474:perchlorate