Entrapment of nanoscale zero-valent iron in chitosan beads for hexavalent chromium removal from wastewater.
Nanoscale zero-valent iron (NZVI) was successfully entrapped in chitosan (CS) beads for reduction of Cr (VI) from wastewater. The removal mechanism may include both physical adsorption of Cr (VI) on the surface or inside of CS-NZVI beads and subsequent reduction of Cr (VI) to Cr (III). The free amino groups and hydroxyl groups on CS may contribute little to hinder the formation of Fe(III)-Cr(III) precipitate. Entrapment of NZVI in CS beads prevents the particles from aggregation and oxidation. The results indicate that there is no significant difference between the reaction rates of bare NZVI and entrapped NZVI. Cr (VI) reduction kinetics follows a pseudo-first-order rate expression. The reduction capacity for Cr (VI) increases with increasing temperature and NZVI dosage but decreases with the increase in initial concentration of Cr (VI) and pH values. This study demonstrates that entrapment of NZVI in CS beads has the potential to become a promising technique for in situ groundwater remediation.
Liu
Tingyi
T
School of Environmental Science and Engineering, Tianjin University, No. 92, Weijin Rd., Nankai District, Tianjin 300072, China.
Zhao
Lin
L
School of Environmental Science and Engineering, Tianjin University, No. 92, Weijin Rd., Nankai District, Tianjin 300072, China. Electronic address: zhaolin@tju.edu.cn.
Sun
Desheng
D
School of Environmental Science and Engineering, Tianjin University, No. 92, Weijin Rd., Nankai District, Tianjin 300072, China.
Tan
Xin
X
School of Environmental Science and Engineering, Tianjin University, No. 92, Weijin Rd., Nankai District, Tianjin 300072, China.
D048271:Chitosan / Q000737:chemistry*; D002857:Chromium / Q000302:isolation & purification*; D007501:Iron / Q000737:chemistry*; D053768:Metal Nanoparticles; D008855:Microscopy, Electron, Scanning; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
D014874:Water Pollutants, Chemical; D002857:Chromium; D048271:Chitosan; D007501:Iron