title: Recycling of aluminium scrap for secondary Al-Si alloys.
abstract: An increasing amount of recycled aluminium is going into the production of aluminium alloy used for automotive applications. In these applications, it is necessary to control and remove alloy impurities and inclusions. Cleaning and fluxing processes are widely used during processing of the alloys for removal of inclusions, hydrogen and excess of magnesium. These processes use salt fluxes based in the system NaCl-KCl, injection of chlorine or mixture of chlorine with an inert gas. The new systems include a graphite wand and a circulation device to force convection in the melt and permit the bubbling and dispersion of reactive and cleaning agents. This paper discusses the recycling of aluminium alloys in rotary and reverberatory industrial furnaces. It focuses on the removal of magnesium during the melting process. In rotary furnaces, the magnesium lost is mainly due to the oxidation process at high temperatures. The magnesium removal is carried out by the reaction between chlorine and magnesium, with its efficiency associated to kinetic factors such as concentration of magnesium, mixing, and temperature. These factors are also related to emissions generated during the demagging process. Improvements in the metallic yield can be reached in rotary furnaces if the process starts with a proper salt, with limits of addition, and avoiding long holding times. To improve throughput in reverberatories, start the charging with high magnesium content material and inject chlorine gas if the molten metal is at the right temperature. Removal of magnesium through modern technologies can be efficiently performed to prevent environmental problems.
authors.affiliation: Texas State University, Department of Engineering Technology, San Marcos, TX 78666, USA. ev15@txstate.edu
authors.forename: Eulogio
authors.initials: E
authors.lastname: Velasco
authors.forename: Jose
authors.initials: J
authors.lastname: Nino
mesh_terms: D000497:Alloys / Q000302:isolation & purification*; D000535:Aluminum / Q000737:chemistry*; D008274:Magnesium / Q000737:chemistry; D010084:Oxidation-Reduction; D059027:Recycling / Q000379:methods*; D012825:Silicon / Q000737:chemistry*; D014866:Waste Products
chemical_list: D000497:Alloys; D014866:Waste Products; D000535:Aluminum; D008274:Magnesium; D012825:Silicon