Synthesis and coordination behaviors of P-stereogenic polymers.
Optically active polymers containing P-stereogenic bisphosphine and 1,2,3-triazole units in the main chain were obtained by copper-catalyzed Huisgen cycloaddition. The repeating unit of the polymer adopted bidentate as well as tetradentate coordination, leading to the change in the conformations of the polymer via complexation with transition metals.
Imoto
Hiroaki
H
Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Morisaki
Yasuhiro
Y
Chujo
Yoshiki
Y