title: Holographic detection of hydrocarbon gases and other volatile organic compounds.
abstract: There is a need to develop sensors for real-time monitoring of volatile organic compounds (VOCs) and hydrocarbon gases in both external and indoor environments, since these compounds are of growing concern in human health and welfare. Current measurement technology for VOCs requires sophisticated equipment and lacks the prospect for rapid real-time monitoring. Holographic sensors can give a direct reading of the analyte concentration as a color change. We report a technique for recording holographic sensors by laser ablation of silver particles formed in situ by diffusion. This technique allows a readily available hydrophobic silicone elastomer to be transformed into an effective sensor for hydrocarbon gases and other volatile compounds. The intermolecular interactions present between the polymer and molecules are used to predict the sensor performance. The hydrophobicity of this material allows the sensor to operate without interference from water and other atmospheric gases and thus makes the sensor suitable for biomedical, industrial, or environmental analysis.
authors.affiliation: University of Cambridge, Department of Chemical Engineering and Biotechnology, Tennis Court Rd, CB2 1QT, Cambridge, United Kingdom.
authors.forename: J L
authors.initials: JL
authors.lastname: Martínez-Hurtado
authors.forename: C A B
authors.initials: CA
authors.lastname: Davidson
authors.forename: J
authors.initials: J
authors.lastname: Blyth
authors.forename: C R
authors.initials: CR
authors.lastname: Lowe
mesh_terms: D005740:Gases; D006838:Hydrocarbons / Q000032:analysis*; D055549:Volatile Organic Compounds / Q000032:analysis*
chemical_list: D005740:Gases; D006838:Hydrocarbons; D055549:Volatile Organic Compounds