title: Amphiphilic photo-isomerisable phosphanes for aqueous organometallic catalysis.
abstract: Water-soluble phosphanes were tagged with a light-responding diazo group. Upon UV exposure, the diazo-isomerisation led to phosphane morphology change, resulting in an increase in the reaction rate of an aqueous palladium-catalysed cleavage reaction.
authors.affiliation: Université de Lille Nord de France, CNRS UMR 8181, UArtois UCCS, Faculté des Sciences Jean Perrin, rue Jean Souvraz, SP 18, F-62307 Lens Cedex, France.
authors.forename: Hervé
authors.initials: H
authors.lastname: Bricout
authors.forename: Estelle
authors.initials: E
authors.lastname: Banaszak
authors.forename: Christophe
authors.initials: C
authors.lastname: Len
authors.forename: Frédéric
authors.initials: F
authors.lastname: Hapiot
authors.forename: Eric
authors.initials: E
authors.lastname: Monflier
mesh_terms: D002384:Catalysis; D057927:Hydrophobic and Hydrophilic Interactions; D007536:Isomerism; D009942:Organometallic Compounds / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D055668:Photochemical Processes; D014867:Water / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D010720:Phosphines; D014867:Water; C044646:phosphine