Dynamic changes in dimensional structures of co-complex crystals.
A two-dimensional flexible porous coordination polymer (2D-PCP) that shows expansion/shrinkage structural transformation accompanied by molecular accommodation was synthesized by control of dimensionality in zero-dimensional and one-dimensional PCPs: The dynamic structural transformation cooperatively proceeds in the solid state with a drastic molecular rearrangement. Kinetics of the structural transformation was investigated.
Kondo
Atsushi
A
Collaborative Innovation Center for Nanotech FIBER (nanoFIC), Shinshu University, Ueda Nagano 386-8567, Japan.
Nakagawa
Tomohiro
T
Kajiro
Hiroshi
H
Chinen
Ayako
A
Hattori
Yoshiyuki
Y
Okino
Fujio
F
Ohba
Tomonori
T
Kaneko
Katsumi
K
Kanoh
Hirofumi
H