Asymmetric total synthesis of caribenol A.
A unified strategy toward the asymmetric total synthesis of carbenol A is reported, featuring intramolecular Diels-Alder (IMDA) and biomimetic oxidation reactions as key steps.
Liu
Lian-Zhu
LZ
Laboratory of Chemical Genomics, Shenzhen Graduate School of Peking University, Shenzhen 518055, China.
Han
Jin-Chun
JC
Yue
Guo-Zong
GZ
Li
Chuang-Chuang
CC
Yang
Zhen
Z
D000900:Anti-Bacterial Agents / Q000138:chemical synthesis* / Q000737:chemistry; D018360:Crystallography, X-Ray; D004224:Diterpenes / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D013237:Stereoisomerism
D000900:Anti-Bacterial Agents; D004224:Diterpenes; C555112:caribenol A