Palladium-catalyzed conversion of aryl and vinyl triflates to bromides and chlorides.
The palladium-catalyzed conversion of aryl and vinyl triflates to aryl and vinyl halides (bromides and chlorides) has been developed using dialkylbiaryl phosphine ligands. A variety of aryl, heteroaryl, and vinyl halides can be prepared via this method in good to excellent yields.
Shen
Xiaoqiang
X
Department of Chemistry, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.
Hyde
Alan M
AM
Buchwald
Stephen L
SL
D001965:Bromides / Q000737:chemistry*; D002384:Catalysis; D002712:Chlorides / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*
D001965:Bromides; D002712:Chlorides; D010165:Palladium