Group 3-centred dehydrocoupling of Me2NH·BH3.
Stoichiometric and catalytic reactions of group 3 (Sc, Y) amides with Me(2)NH·BH(3) result in formation of the corresponding amidoborane derivatives and dehydrogenative coupling of two amine borane fragments under mild conditions.
Hill
Michael S
MS
Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK. msh27@bath.ac.uk
Kociok-Köhn
Gabriele
G
Robinson
Thomas P
TP