Direct arylations of electron-deficient (hetero)arenes with aryl or alkenyl tosylates and mesylates.
A palladium catalyst derived from the ligand X-Phos enabled generally applicable direct arylations of electron-deficient heteroarenes and arenes with aryl and alkenyl tosylates or mesylates.
Ackermann
Lutz
L
Institut fuer Organische und Biomolekulare Chemie, Georg-August-Universitaet, Tammannstrasse 2, 37077 Goettingen, Germany. Lutz.Ackermann@chemie.uni-goettingen.de
Fenner
Sabine
S
D003497:Cyclic N-Oxides / Q000138:chemical synthesis* / Q000737:chemistry*; D004583:Electrons; D008698:Mesylates / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry; D010165:Palladium / Q000737:chemistry; D013237:Stereoisomerism; D014105:Tosyl Compounds / Q000737:chemistry*
D003497:Cyclic N-Oxides; D008698:Mesylates; D009942:Organometallic Compounds; D014105:Tosyl Compounds; D010165:Palladium