title: A new synthetic route, characterization and vibrational studies of manganese hypophosphite monohydrate at ambient temperature.
abstract: The manganese hypophosphite monohydrate (Mn(H₂PO₂)₂·H₂O) was synthesized by using the energy saving method in acetone medium for controlling the exothermic process of H₂ gas releasing. The thermal analysis (TG/DTG/DTA), atomic absorption spectrophotometry (AAS) and X-ray powder diffraction (XRD) were employed to characterize this compound. These methods confirm the formula of the title compound. The SEM data in this work agree well with the previously reported work. The vibrational behavior was studied by using the FTIR and FT Raman methods. The correlation field splitting analysis of H₂O in Mn(H₂PO₂)₂·H₂O symbolized as C₂v)-C₁-C₂h⁵ and C₂v-C(i)-C₂h⁵) suggested the number of vibrational modes to be: Γ(vib,H₂O)=3A(g)+3B(g)+3A(u)+3B(u). While the case of hypophosphite anion can be suggested to exhibit 16 (infrared) [A(u)(8)+B(u)(8)] and 18 Raman [A(g)(9)+B(g)(9)] bands which agree well with the observed FT IR spectra. However, the Raman spectra could not be fully identified. The coupling between these modes with the appropriate vibrations of neighboring species at each sites in the unit cell can further influence the vibrational spectra.
authors.affiliation: Department of Chemistry, Center of Excellence for Innovation in Chemistry, Faculty of Science, Khon Kaen University, Khon Kaen 40002, Thailand.
authors.forename: Pittayagorn
authors.initials: P
authors.lastname: Noisong
authors.forename: Chanaiporn
authors.initials: C
authors.lastname: Danvirutai
mesh_terms: D008345:Manganese / Q000737:chemistry*; D010721:Phosphinic Acids / Q000138:chemical synthesis / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman; D013696:Temperature; D014732:Vibration
chemical_list: D010721:Phosphinic Acids; D008345:Manganese