title: Reactivity of alkynylzirconates towards allyl bromides: selective formation of β-allyl-zirconacyclopentadienes.
abstract: Reaction of alkynylzirconates with allyl bromides afforded β-allyl-zirconacyclopentadienes with high selectivity in unique reaction site.
authors.affiliation: Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China.
authors.forename: Xiaoyu
authors.initials: X
authors.lastname: Yan
authors.forename: Yiqing
authors.initials: Y
authors.lastname: Zhou
authors.forename: Chanjuan
authors.initials: C
authors.lastname: Xi
mesh_terms: D000466:Alkadienes / Q000737:chemistry*; D000480:Alkynes / Q000737:chemistry*; D000498:Allyl Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D013379:Substrate Specificity; D015040:Zirconium / Q000737:chemistry*
chemical_list: D000466:Alkadienes; D000480:Alkynes; D000498:Allyl Compounds; D015040:Zirconium; C050431:allyl bromide