title: Electronic effects in iridium C-H borylations: insights from unencumbered substrates and variation of boryl ligand substituents.
abstract: Experiment and theory favour a model of C-H borylation where significant proton transfer character exists in the transition state.
authors.affiliation: Department of Chemistry, Michigan State University, East Lansing, Michigan 48824-1322, USA.
authors.forename: Britt A
authors.initials: BA
authors.lastname: Vanchura
authors.forename: Sean M
authors.initials: SM
authors.lastname: Preshlock
authors.forename: Philipp C
authors.initials: PC
authors.lastname: Roosen
authors.forename: Venkata A
authors.initials: VA
authors.lastname: Kallepalli
authors.forename: Richard J
authors.initials: RJ
authors.lastname: Staples
authors.forename: Robert E
authors.initials: RE
authors.lastname: Maleczka
authors.forename: Daniel A
authors.initials: DA
authors.lastname: Singleton
authors.forename: Milton R
authors.initials: MR
authors.lastname: Smith
mesh_terms: D001895:Boron / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D004583:Electrons; D006859:Hydrogen / Q000737:chemistry*; D007495:Iridium / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D008968:Molecular Conformation; D013237:Stereoisomerism
chemical_list: D008024:Ligands; D007495:Iridium; D002244:Carbon; D006859:Hydrogen; D001895:Boron