Optimization of bio-diesel production from soybean and wastes of cooked oil: combining dielectric microwave irradiation and a SrO catalyst.
This work offers an optimized method in the transesterification of pristine (soybean) oil and cooked oil to bio-diesel, based on microwave dielectric irradiation as a driving force for the transesterification reaction and SrO as a catalyst. This combination has demonstrated excellent catalytic activity and stability. The transesterification was carried out with and without stirring. According to 1H NMR spectroscopy and TLC results, this combination accelerates the reaction (to less than 60 s), maintaining a very high conversion (99%) and high efficiency. The catalytic activity of SrO under atmospheric pressure in the presence of air and under the argon atmosphere is demonstrated. The optimum conversion of cooked oil (99.8%) is achieved under MW irradiation of 1100 W output with magnetic stirring after only 10 s. The optimum method decreases the cost of bio-diesel production and has the potential for industrial application in the transesterification of cooked oil to bio-diesel.
Koberg
Miri
M
Department of Chemistry and Kanbar Laboratory for Nanomaterials at the Bar-Ilan University Center for Advanced Materials and Nanotechnology, Bar-Ilan University, Ramat-Gan 52900, Israel.
Abu-Much
Riam
R
Gedanken
Aharon
A
D000388:Air; D001128:Argon; D001274:Atmospheric Pressure; D056804:Biofuels / Q000032:analysis*; D001709:Biotechnology / Q000379:methods*; D002384:Catalysis; D003296:Cooking; D004560:Electricity; D004951:Esterification; D006878:Hydroxides / Q000737:chemistry; D008872:Microwaves; D010087:Oxides / Q000737:chemistry*; D017680:Potassium Compounds / Q000737:chemistry; D013024:Soybean Oil / Q000737:chemistry*; D013025:Glycine max / Q000737:chemistry*; D013324:Strontium / Q000737:chemistry*; D013997:Time Factors; D014866:Waste Products / Q000032:analysis*
D056804:Biofuels; D006878:Hydroxides; D010087:Oxides; D017680:Potassium Compounds; D014866:Waste Products; D001128:Argon; D013024:Soybean Oil; C029943:potassium hydroxide; D013324:Strontium