Nickel-catalyzed ring-opening three-component coupling of methylenecyclopropane with aldehydes and silanes.
A nickel-catalyzed three-component coupling between methylenecyclopropane, aldehydes, and silanes afforded silylated allylic alcohols that possess an alkyl substituent at the 2-position via cleavage of the proximal C-C bond of methylenecyclopropane.
Ogata
Kenichi
K
Department of Applied Chemistry, Institute of Science and Engineering, Chuo University, 1-13-27 Kasuga, Bunkyo-ku, Tokyo 112-8551, Japan. kogata@kc.chuo-u.ac.jp
Atsuumi
Yuka
Y
Fukuzawa
Shin-ichi
S