Intermediates in the catalytic cycle of methyl coenzyme M reductase: isotope exchange is consistent with formation of a σ-alkane-nickel complex.
Scheller
Silvan
S
Laboratory of Organic Chemistry, ETH Zurich, Wolfgang-Pauli-Strasse 10, 8093 Zurich, Switzerland.
Goenrich
Meike
M
Mayr
Stefan
S
Thauer
Rudolf K
RK
Jaun
Bernhard
B
D002384:Catalysis; D007554:Isotopes; D009532:Nickel / Q000737:chemistry*; D010088:Oxidoreductases / Q000737:chemistry*
D007554:Isotopes; D009532:Nickel; D010088:Oxidoreductases; C021572:methyl coenzyme M reductase