title: Germanium(II) hydride mediated reduction of carbon dioxide to formic acid and methanol with ammonia borane as the hydrogen source.
abstract: LGeOC(O)H (3) (L = CH{(CMe)(2,6-iPr(2)C(6)H(3)N)}(2)), from the straightforward conversion of LGeH (2) with CO(2), reacts with LiH(2)NBH(3) giving 2 and LiOC(O)H (4), while the corresponding reaction of 3 with H(3)NBH(3) after aqueous workup releases 2 and CH(3)OH (5). This opens the possibility to use hydride 2 as a mediator in the reduction of carbon dioxide to formic acid and methanol.
authors.affiliation: Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077, Göttingen, Germany.
authors.forename: Anukul
authors.initials: A
authors.lastname: Jana
authors.forename: Gašper
authors.initials: G
authors.lastname: Tavčar
authors.forename: Herbert W
authors.initials: HW
authors.lastname: Roesky
authors.forename: Michael
authors.initials: M
authors.lastname: John