Reactivity of alkynylzirconates towards allyl bromides: selective formation of β-allyl-zirconacyclopentadienes.
Reaction of alkynylzirconates with allyl bromides afforded β-allyl-zirconacyclopentadienes with high selectivity in unique reaction site.
Yan
Xiaoyu
X
Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China.
Zhou
Yiqing
Y
Xi
Chanjuan
C
D000466:Alkadienes / Q000737:chemistry*; D000480:Alkynes / Q000737:chemistry*; D000498:Allyl Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D013379:Substrate Specificity; D015040:Zirconium / Q000737:chemistry*
D000466:Alkadienes; D000480:Alkynes; D000498:Allyl Compounds; D015040:Zirconium; C050431:allyl bromide