Effect of different photo-initiators and light curing units on degree of conversion of composites.
The aim of this study was to evaluate: (i) the absorption of photo-initiators and emission spectra of light curing units (LCUs); and (ii) the degree of conversion (DC) of experimental composites formulated with different photo-initiators when activated by different LCUs. Blends of BisGMA, UDMA, BisEMA and TEGDMA with camphorquinone (CQ) and/ or 1-phenyl-1,2-propanedione (PPD) were prepared. Dimethylaminoethyl methacrylate (DMAEMA) was used as co-initiator. Each mixture was loaded with 65 wt% of silanated filler particles. One quartz-tungsten-halogen - QTH (XL 2500, 3M/ESPE) and two lightemitting diode (LED) LCUs (UltraBlue IS, DMC and UltraLume LED 5, Ultradent) were used for activation procedures. Irradiance (mW/cm²) was calculated by the ratio of the output power by the area of the tip, and spectral distribution with a spectrometer (USB 2000). The absorption curve of each photo-initiator was determined using a spectrophotometer (Varian Cary 5G). DC was assessed by Fourier transformed infrared spectroscopy. Data were submitted to two-way ANOVA and Tukey's test (5%). No significant difference was found for DC values when using LED LCUs regardless of the photo-initiator type. However, PPD showed significantly lower DC values than composites with CQ when irradiated with QTH. PPD produced DC values similar to those of CQ, but it was dependent on the LCU type.
Brandt
William Cunha
WC
Departamento de Dentística Restauradora, Área de Materiais Dentários Faculdade de Odontologia de Piracicaba, UNICAMP Av. Limeira, 901 Piracicaba - SP - Brazil. williamcbrandt@yahoo.com.br
Schneider
Luis Felipe Jochims
LF
Frollini
Elisabete
E
Correr-Sobrinho
Lourenço
L
Sinhoreti
Mário Alexandre Coelho
MA
D002164:Camphor / Q000031:analogs & derivatives; D047188:Chalcones / Q000737:chemistry / Q000528:radiation effects; D003188:Composite Resins / Q000737:chemistry / Q000528:radiation effects*; D055117:Curing Lights, Dental; D008422:Materials Testing; D008689:Methacrylates / Q000737:chemistry / Q000528:radiation effects*; D044367:Phase Transition; D055668:Photochemical Processes; D011092:Polyethylene Glycols / Q000737:chemistry / Q000528:radiation effects; D011109:Polymethacrylic Acids / Q000737:chemistry / Q000528:radiation effects; D017550:Spectroscopy, Fourier Transform Infrared; D013997:Time Factors
D047188:Chalcones; D003188:Composite Resins; D008689:Methacrylates; D011109:Polymethacrylic Acids; D011092:Polyethylene Glycols; D002164:Camphor