Fabrication and transformation of novel two-dimensional tripod structures: structural modulation by alkyl chain length and tandem Claisen rearrangement.
Novel two-dimensional C3 symmetric (tripod) structures are fabricated from isobutenyl compounds possessing long alkyl chains. Alteration from tripod to wavy structures is accomplished by odd-even effect, and tandem Claisen rearrangement allows the transformation to the linear structures.
Omori
Kazuhiro
K
Department of Materials Technology, Industrial Technology Center of Tochigi Prefecture, 367-1 Karinuma, Utsunomiya, Tochigi 321-3224, Japan.
Kikkawa
Yoshihiro
Y
Kanesato
Masatoshi
M
Hiratani
Kazuhisa
K