Carborane-Bodipy scaffolds for through space energy transfer.
Use of a closo-1,12-dicarbadecaborane backbone to link two different organic dyes separated by ca. 37 Å promotes exclusive through space electronic energy transfer with an efficiency of 81 to 87% with Stoke shifts between 4750 and 2800 cm(-1) depending on the pH.
Ziessel
Raymond
R
LCOSA, ECPM/ULP, CNRS, 25 rue Becquerel, 67087 Strasbourg Cedex 02, France. ziessel@chimie.u-strasbg.fr
Ulrich
Gilles
G
Olivier
Jean Hubert
JH
Bura
Thomas
T
Sutter
Alexandra
A