Collective molecular reorientation of a calamitic liquid crystal (12CB) confined in alumina nanochannels.
We study the smectic director structure of the rodlike liquid crystal 4-n-dodecyl-4'-cyanobiphenyl (12CB) confined in cylindrical cavities of 200 nm diameter in porous alumina templates by means of combined broadband dielectric spectroscopy, optical birefringence, and neutron scattering measurements. We show that the collective molecular orientation differs between entering the smectic A phase upon cooling from the isotropic state and entering the same phase upon heating while melting the confined crystal. We discuss this collective molecular realignment in terms of a competition between weak planar anchoring at the p-Al2O3/12CB interface and a preferred texture typical of the crystallization of rodlike molecules in nanochannels (Bridgman growth).
Chahine
Gilbert
G
Institut de Physique de Rennes, UMR 6251, Université de Rennes 1, 35042 Rennes, France.
Kityk
Andriy V
AV
Démarest
Nathalie
N
Jean
Fabien
F
Knorr
Klaus
K
Huber
Patrick
P
Lefort
Ronan
R
Zanotti
Jean-Marc
JM
Morineau
Denis
D