Rationally controlled helical organization of a multiple-hydrogen-bonding oligothiophene: guest-induced transition of helical-to-twisted ribbons.
A cyanuric acid-functionalized quaterthiophene self-aggregates to form helical ribbons which are transformed into twisted ribbons upon complexing with a complementary bismelamine receptor.
Yagai
Shiki
S
Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, 1-33 Yayoi-cho, Inage-ku, Chiba 263-8522, Japan. yagai@faculty.chiba-u.jp
Gushiken
Marina
M
Karatsu
Takashi
T
Kitamura
Akihide
A
Kikkawa
Yoshihiro
Y
D006860:Hydrogen Bonding; D008958:Models, Molecular; D015394:Molecular Structure; D049329:Nanostructures / Q000737:chemistry; D010316:Particle Size; D013499:Surface Properties; D013876:Thiophenes / Q000138:chemical synthesis* / Q000737:chemistry; D014227:Triazines / Q000737:chemistry
D013876:Thiophenes; D014227:Triazines; C004632:cyanuric acid; C011907:melamine