Rotational analysis for the Doppler-free photoelectron spectrum of water using the spectator model.
A photoelectron spectrum of H(2)O has been recorded at a resolution of 2 meV under Doppler-free conditions. Complex rotational structures appear in the individual vibrational states of the electronic X̃(+ 2)B(1) and Ã(+ 2)A(2) states in H(2)O(+). The rotational structures are analyzed and well reproduced using a spectator orbital model developed for rotationally resolved photoelectron spectroscopy.
Ford
Mark S
MS
The Photon Science Institute and School of Chemistry, The University of Manchester, Alan Turing Building, Oxford Road, Manchester M13 9PL, UK.
Müller-Dethlefs
Klaus
K
Kitajima
M
M
Tanaka
H
H
Tamenori
Y
Y
De Fanis
A
A
Ueda
Kyoshi
K
D056004:Molecular Dynamics Simulation; D011789:Quantum Theory; D012399:Rotation; D013057:Spectrum Analysis; D014867:Water / Q000737:chemistry*
D014867:Water