Facile synthesis of hypersilylated aromatic compounds by palladium-mediated arylation reaction.
The treatment of aryl iodides with tris(trimethylsilyl)silane in the presence of Pd(P(tBu)(3))(2) and the Hünig base leads to the formation of hypersilylated aromatic products in good to excellent yields without cleavage of weak Si-Si bonds under mild conditions.
Lesbani
Aldes
A
Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Kondo
Hitoshi
H
Sato
Jun-Ichi
J
Yamanoi
Yoshinori
Y
Nishihara
Hiroshi
H