Proton affinities of phosphines versus N-heterocyclic carbenes.
The gas-phase proton affinities of unusually basic phosphines and N-heterocyclic carbenes are compared and contrasted both computationally and experimentally.
Liu
Min
M
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, New Brunswick, New Jersey 08901, United States.
Yang
Ill
I
Buckley
Brian
B
Lee
Jeehiun K
JK
D019281:Dimerization; D006571:Heterocyclic Compounds / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D015394:Molecular Structure; D010720:Phosphines / Q000737:chemistry*; D011522:Protons
D006571:Heterocyclic Compounds; D010720:Phosphines; D011522:Protons; C030011:carbene; D008697:Methane