title: Total synthesis and absolute configuration determination of (+)-subincanadine F.
abstract: The first asymmetric synthesis of indole alkaloid (+)-subincanadine F was successfully accomplished with the uncommon 7-endo-trig stereoselective radical cyclization as the key step and its absolute configuration was thus assigned.
authors.affiliation: Key Laboratory of Synthetic Chemistry of Natural Substances, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, PR China.
authors.forename: Pinhong
authors.initials: P
authors.lastname: Chen
authors.forename: Lidong
authors.initials: L
authors.lastname: Cao
authors.forename: Wenhai
authors.initials: W
authors.lastname: Tian
authors.forename: Xinfeng
authors.initials: X
authors.lastname: Wang
authors.forename: Chaozhong
authors.initials: C
authors.lastname: Li
mesh_terms: D018360:Crystallography, X-Ray; D003500:Cyclization; D026121:Indole Alkaloids / Q000138:chemical synthesis* / Q000737:chemistry; D008968:Molecular Conformation; D010084:Oxidation-Reduction; D013237:Stereoisomerism
chemical_list: D026121:Indole Alkaloids; C522871:subincanadine F