Three-dimensional metal-organic frameworks based on tetrahedral and square-planar building blocks: hydrogen sorption and dye uptake studies.
Two three-dimensional metal-organic frameworks (MOFs) with tetraphenylmethane-derived tetracarboxylate linkers and copper paddle-wheel secondary building units were synthesized and characterized by single-crystal X-ray crystallographic studies. The two MOFs show a similar 4,4-connectivity but very different homocrossing and interpenetrating PtS network topologies and exhibit permanent porosity as probed by gas adsorption and dye inclusion experiments.
Liu
Demin
D
Department of Chemistry, CB#3290, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599, USA.
Xie
Zhigang
Z
Ma
Liqing
L
Lin
Wenbin
W
D002264:Carboxylic Acids / Q000737:chemistry*; D004396:Coloring Agents / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006859:Hydrogen / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*
D002264:Carboxylic Acids; D004396:Coloring Agents; D008024:Ligands; D009942:Organometallic Compounds; D003300:Copper; D006859:Hydrogen