A new oxomolybdate component extracted from the "virtual dynamic library" yielding the macrocyclic anion [(Mo(VI)(8)O(28))(4)(Mo(V)(2)O(2)S(2))(4)](24-).
A rare isomer of the {Mo(8)O(28)}(8-) anion has been trapped from an acidified aqueous solution of molybdate by using the {Mo(2)O(2)S(2)}(2+) oxothio cation as the linker and isolated as a part of a unique macrocyclic anion, which consists of four isopolyoxomolybdate fragments {Mo(8)O(28)} bridged by four {Mo(2)O(2)S(2)} units.
Korenev
Vladimir S
VS
Institut Lavoisier de Versailles, Université de Versailles Saint Quentin, UMR 8180, 45 avenue des Etats Unis, 78035 Versailles, France.
Boulay
Antoine G
AG
Dolbecq
Anne
A
Sokolov
Maxim N
MN
Hijazi
Akram
A
Floquet
Sébastien
S
Fedin
Vladimir P
VP
Cadot
Emmanuel
E
D000838:Anions / Q000737:chemistry; D047028:Macrocyclic Compounds / Q000737:chemistry*; D008958:Models, Molecular; D008982:Molybdenum / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry*
D000838:Anions; D047028:Macrocyclic Compounds; C044659:molybdate; D013455:Sulfur; D008982:Molybdenum