title: Fabrication and biosensing with CNT/aligned mesostructured silica core-shell nanowires.
abstract: We report the synthesis of carbon nanotubes (CNTs)/mesostructured silica core-shell nanowires via an interfacial surfactant templating approach. The nanowires possess perpendicularly aligned and uniform accessible mesopores, high surface area and large pore volume. When dimethyl sulfoxide reductase (DMSOR) enzyme is immobilized on the core-shell nanowires, the complex can enhance the electrical communication between the active sites of the enzyme and the electrode surface in the presence of a mediator. The unique properties of the CNTs and the uniform accessible mesopores of the nanowires have made this material promising in the applications as carbon nanotubes field-effect transistors, electrochemical detection, and biosensors.
authors.affiliation: State Key Laboratory for Heavy Oil Processing, College of Chemistry and Chemical Engineering, China University of Petroleum, Qingdao, 266555, China.
authors.forename: Lei
authors.initials: L
authors.lastname: Zhang
authors.forename: Wang Chang
authors.initials: WC
authors.lastname: Geng
authors.forename: Shi Zhang
authors.initials: SZ
authors.lastname: Qiao
authors.forename: Hua Jun
authors.initials: HJ
authors.lastname: Zheng
authors.forename: Gao Qing Max
authors.initials: GQ
authors.lastname: Lu
authors.forename: Zi Feng
authors.initials: ZF
authors.lastname: Yan
mesh_terms: D001426:Bacterial Proteins / Q000737:chemistry*; D015374:Biosensing Techniques / Q000295:instrumentation / Q000379:methods*; D004800:Enzymes, Immobilized / Q000737:chemistry*; D007506:Iron-Sulfur Proteins / Q000737:chemistry*; D037742:Nanotubes, Carbon / Q000737:chemistry; D053770:Nanowires / Q000737:chemistry*; D010088:Oxidoreductases / Q000737:chemistry*; D012240:Rhodococcus / Q000201:enzymology*; D012822:Silicon Dioxide / Q000737:chemistry*
chemical_list: D001426:Bacterial Proteins; D004800:Enzymes, Immobilized; D007506:Iron-Sulfur Proteins; D037742:Nanotubes, Carbon; D012822:Silicon Dioxide; D010088:Oxidoreductases; C045664:dimethyl sulfoxide reductase