title: Revealing the exciton fine structure of PbSe nanocrystal quantum dots using optical spectroscopy in high magnetic fields.
abstract: We measure the photoluminescence lifetime τ of excitons in colloidal PbSe nanocrystals (NCs) at low temperatures to 270 mK and in high magnetic fields to 15 T. For all NCs, τ increases sharply below 10 K but saturates by 500 mK. In contrast to the usual picture of well-separated "bright" and "dark" exciton states (found, e.g., in CdSe NCs), these dynamics fit remarkably well to a system having two exciton states with comparable--but small--oscillator strengths that are separated by only 300-900  μeV depending on NC size. Importantly, magnetic fields reduce τ below 10 K, consistent with field-induced mixing between the two states. Magnetic-circular dichroism studies reveal exciton g factors from 2-5, and magnetophotoluminescence shows >10% circularly polarized emission.
authors.affiliation: Chemistry Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545, USA.
authors.forename: R D
authors.initials: RD
authors.lastname: Schaller
authors.forename: S A
authors.initials: SA
authors.lastname: Crooker
authors.forename: D A
authors.initials: DA
authors.lastname: Bussian
authors.forename: J M
authors.initials: JM
authors.lastname: Pietryga
authors.forename: J
authors.initials: J
authors.lastname: Joo
authors.forename: V I
authors.initials: VI
authors.lastname: Klimov