Probing nitrobenzhydrol uncaging mechanisms using FerriCast.
The FerriCast derivative FC-NDBF was synthesized from 3-methyl-2-nitrodibenzofuran (NDBF). The photochemistry of the target Fe(3+) photocage and several related congeners provides mechanistic insight into the uncaging quantum yields of nitrobenzhydrol-derived ligands.
Kennedy
Daniel P
DP
Department of Chemisty, University of Connecticut, 55 North Eagleville Road U-3060, Storrs, Connecticut 06269, USA.
Brown
Daniel C
DC
Burdette
Shawn C
SC
D001559:Benzhydryl Compounds / Q000737:chemistry*; D005290:Ferric Compounds / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D017672:Nitrogen Compounds / Q000737:chemistry*
D001559:Benzhydryl Compounds; D005290:Ferric Compounds; D008024:Ligands; D017672:Nitrogen Compounds