title: Stereoselective Negishi-like couplings between alkenyl and alkyl halides in water at room temperature.
abstract: Mix in water and then stir. That is all that is required in this new approach to stereoselective sp(3)-sp(2) cross-couplings between an alkyl and alkenyl halide. Prior formation of organozinc reagents is not required.
authors.affiliation: Department of Chemistry & Biochemistry, University of California, Santa Barbara, California 93106, United States.
authors.forename: Arkady
authors.initials: A
authors.lastname: Krasovskiy
authors.forename: Christophe
authors.initials: C
authors.lastname: Duplais
authors.forename: Bruce H
authors.initials: BH
authors.lastname: Lipshutz
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000480:Alkynes / Q000737:chemistry*; D001966:Bromine / Q000737:chemistry*; D007455:Iodine / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism; D013696:Temperature; D014867:Water / Q000737:chemistry
chemical_list: D000475:Alkenes; D000480:Alkynes; D014867:Water; D007455:Iodine; D001966:Bromine