A carbonyl-rich bridging hydride complex relevant to the Fe-Fe hydrogenase active site.
Protonation of Fe(2)(μ-S(2)C(3)H(6))(CO)(6) with an acid derived from [SiEt(3)][B(C(6)F(5))(4)] and HCl affords a hydride-bridged dimer.
Matthews
Steven L
SL
Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, United States.
Heinekey
D Michael
DM
D055162:Biocatalysis; D020134:Catalytic Domain; D018360:Crystallography, X-Ray; D019281:Dimerization; D005296:Ferrous Compounds / Q000737:chemistry / Q000378:metabolism*; D006851:Hydrochloric Acid / Q000737:chemistry; D006864:Hydrogenase / Q000737:chemistry* / Q000378:metabolism*; D007506:Iron-Sulfur Proteins / Q000737:chemistry* / Q000378:metabolism*; D008958:Models, Molecular; D008968:Molecular Conformation; D011522:Protons; D013237:Stereoisomerism
D005296:Ferrous Compounds; D007506:Iron-Sulfur Proteins; D011522:Protons; C118830:iron hydrogenase; D006864:Hydrogenase; D006851:Hydrochloric Acid