Nickel/lanthanide single-molecule magnets: {Ni(3)Ln} "stars" with a ligand derived from the metal-promoted reduction of di-2-pyridyl ketone under solvothermal conditions.
Unusual {Ni(II)(3)Ln(III)(μ-OR)(6)}(3+) complexes with a "star" topology have been prepared with ligands derived from the metal-promoted reduction of di-2-pyridyl ketone under solvothermal conditions; the Dy(III) member shows weak single-molecule-magnet behavior.
Efthymiou
Constantinos G
CG
Department of Chemistry, University of Florida, Gainesville, Florida 32611-7200, United States.
Stamatatos
Theocharis C
TC
Papatriantafyllopoulou
Constantina
C
Tasiopoulos
Anastasios J
AJ
Wernsdorfer
Wolfgang
W
Perlepes
Spyros P
SP
Christou
George
G
D015082:2,2'-Dipyridyl / Q000031:analogs & derivatives* / Q000737:chemistry; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008024:Ligands; D008280:Magnetics; D008958:Models, Molecular; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D010084:Oxidation-Reduction; D013696:Temperature
C418768:2,2'-dipyridylketone; D028581:Lanthanoid Series Elements; D008024:Ligands; D015082:2,2'-Dipyridyl; D009532:Nickel