title: Rotational analysis for the Doppler-free photoelectron spectrum of water using the spectator model.
abstract: A photoelectron spectrum of H(2)O has been recorded at a resolution of 2 meV under Doppler-free conditions. Complex rotational structures appear in the individual vibrational states of the electronic X̃(+ 2)B(1) and Ã(+ 2)A(2) states in H(2)O(+). The rotational structures are analyzed and well reproduced using a spectator orbital model developed for rotationally resolved photoelectron spectroscopy.
authors.affiliation: The Photon Science Institute and School of Chemistry, The University of Manchester, Alan Turing Building, Oxford Road, Manchester M13 9PL, UK.
authors.forename: Mark S
authors.initials: MS
authors.lastname: Ford
authors.forename: Klaus
authors.initials: K
authors.lastname: Müller-Dethlefs
authors.forename: M
authors.initials: M
authors.lastname: Kitajima
authors.forename: H
authors.initials: H
authors.lastname: Tanaka
authors.forename: Y
authors.initials: Y
authors.lastname: Tamenori
authors.forename: A
authors.initials: A
authors.lastname: De Fanis
authors.forename: Kyoshi
authors.initials: K
authors.lastname: Ueda
mesh_terms: D056004:Molecular Dynamics Simulation; D011789:Quantum Theory; D012399:Rotation; D013057:Spectrum Analysis; D014867:Water / Q000737:chemistry*
chemical_list: D014867:Water