Biosorption of bovine serum albumin by Ulva lactuca biomass from industrial wastewater: equilibrium, kinetic and thermodynamic study.
Batch biosorption experiments have been carried out for the removal of bovine serum albumin (BSA) from simulated industrial wastewater onto Ulva lactuca seaweed. Various vital parameters influencing the biosorption process such as initial concentration of BSA, pH of the solution, adsorbent dosage and temperature have been determined. The biosorption kinetics follows a pseudo-second order kinetic model. Equilibrium isotherm studies demonstrate that the biosorption followed the Freundlich isotherm model, which implies a heterogeneous sorption phenomenon. Various thermodynamic parameters such as changes in enthalpy, free energy and entropy have been calculated. The positive value of ΔH° and the negative value of ΔG° show that the sorption process is endothermic and spontaneous. The positive value of change in entropy ΔS° shows increased randomness at the solid-liquid interface during the biosorption of BSA onto U. lactuca seaweed.
Rathinam
Aravindhan
A
Chemical Laboratory, Central Leather Research Institute, Adyar, Chennai 600020, India.
Zou
Linda
L
SA Water Centre for Water Management and Reuse, University of South Australia, Mawson Lakes Campus, Adelaide, SA 5095, Australia. Electronic address: linda.zou@unisa.edu.au.
D000327:Adsorption; D018533:Biomass; D006863:Hydrogen-Ion Concentration; D007220:Industrial Waste; D007700:Kinetics; D012624:Seaweed; D012710:Serum Albumin, Bovine / Q000378:metabolism*; D013816:Thermodynamics; D044445:Ulva / Q000378:metabolism*
D007220:Industrial Waste; D012710:Serum Albumin, Bovine