title: Analysis of the unresolved organic fraction in atmospheric aerosols with ultrahigh-resolution mass spectrometry and nuclear magnetic resonance spectroscopy: organosulfates as photochemical smog constituents.
abstract: Complementary molecular and atomic signatures obtained from Fourier transform ion cyclotron resonance (FTICR) mass spectra and NMR spectra provided unequivocal attribution of CHO, CHNO, CHOS, and CHNOS molecular series in secondary organic aerosols (SOA) and high-resolution definition of carbon chemical environments. Sulfate esters were confirmed as major players in SOA formation and as major constituents of its water-soluble fraction (WSOC). Elevated concentrations of SO(2), sulfate, and photochemical activity were shown to increase the proportion of SOA sulfur-containing compounds. Sulfonation of CHO precursors by means of heterogeneous reactions between carbonyl derivatives and sulfuric acid in gas-phase photoreactions was proposed as a likely formation mechanism of CHOS molecules. In addition, photochemistry induced oligomerization processes of CHOS molecules. Methylesters found in methanolic extracts of a SOA subjected to strong photochemical exposure were considered secondary products derived from sulfate esters by methanolysis. The relative abundance of nitrogen-containing compounds (CHNO and CHNOS series) appeared rather dependent on local effects such as biomass burning. Extensive aliphatic branching and disruption of extended NMR spin-systems by carbonyl derivatives and other heteroatoms were the most significant structural motifs in SOA. The presence of heteroatoms in elevated oxidation states suggests a clearly different SOA formation trajectory in comparison with established terrestrial and aqueous natural organic matter.
authors.affiliation: Department of BioGeoChemistry and Analytics, Institute of Ecological Chemistry, Helmholtz Zentrum München, German Research Center for Environmental Health, Ingolstaedter Landstrasse 1, 85764 Neuherberg, Germany. schmitt-kopplin@helmholtz-muenchen.de
authors.forename: Philippe
authors.initials: P
authors.lastname: Schmitt-Kopplin
authors.forename: Andras
authors.initials: A
authors.lastname: Gelencsér
authors.forename: Ewa
authors.initials: E
authors.lastname: Dabek-Zlotorzynska
authors.forename: Gyula
authors.initials: G
authors.lastname: Kiss
authors.forename: Norbert
authors.initials: N
authors.lastname: Hertkorn
authors.forename: Mourad
authors.initials: M
authors.lastname: Harir
authors.forename: Yang
authors.initials: Y
authors.lastname: Hong
authors.forename: Istvan
authors.initials: I
authors.lastname: Gebefügi
mesh_terms: D000336:Aerosols / Q000737:chemistry*; D000393:Air Pollutants / Q000737:chemistry*; D005583:Fourier Analysis; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D013058:Mass Spectrometry / Q000379:methods*; D055668:Photochemical Processes; D012905:Smog / Q000032:analysis*; D013431:Sulfates / Q000737:chemistry*
chemical_list: D000336:Aerosols; D000393:Air Pollutants; D012905:Smog; D013431:Sulfates