title: Ag(I) organometallic coordination polymers and capsule with tris-allyl cyclotriveratrylene derivatives.
abstract: Tris-allyl-cyclotriguaiacylene combines with silver salts to give a range of crystalline network structures and one discrete complex. A number of different coordination modes are found within the complexes including η(2)-allyl, aryl, and OR groups binding to Ag(I). AgSbF(6) gives two types of three-dimensional (3-D) coordination polymer with unusual topologies, along with a discrete Ag(2)L(2) capsule dependent on reaction stoichiometry and reaction conditions. Isostructural coordination chain structures are found with AgBF(4) and AgClO(4), while use of Ag(CF(3)SO(3)) gives two-dimensional (2-D) and 3-D coordination polymers through bridging triflate anions.
authors.affiliation: School of Chemistry, University of Leeds, Leeds, LS2 9JT, UK.
authors.forename: Marc A
authors.initials: MA
authors.lastname: Little
authors.forename: Malcolm A
authors.initials: MA
authors.lastname: Halcrow
authors.forename: Lindsay P
authors.initials: LP
authors.lastname: Harding
authors.forename: Michaele J
authors.initials: MJ
authors.lastname: Hardie