title: Atropisomerism of aromatic carbamates.
abstract: ortho-Haloarylcarbamates like 1-4 show a high rotational barrier about the N--aryl bond of up to 91.6 kJ mol(-1) as found for 1, which was determined by 2D exchange NMR spectroscopy (EXSY). It was further demonstrated that the height of the barrier not only depends on the substituents at the axis of chirality, but is also influenced by electronic effects.
authors.affiliation: Institut für Organische und Biomolekulare Chemie der Georg-August-Universität Göttingen, Tammannstraße 2, 37077 Göttingen, Germany. ltietze@gwdg.de
authors.forename: Lutz F
authors.initials: LF
authors.lastname: Tietze
authors.forename: Heiko J
authors.initials: HJ
authors.lastname: Schuster
authors.forename: J Marian
authors.initials: JM
authors.lastname: von Hof
authors.forename: Sonja M
authors.initials: SM
authors.lastname: Hampel
authors.forename: Juan F
authors.initials: JF
authors.lastname: Colunga
authors.forename: Michael
authors.initials: M
authors.lastname: John