Efficient photodegradation of dyes using light-induced self assembly TiO(2)/β-cyclodextrin hybrid nanoparticles under visible light irradiation.
A novel β-cyclodextrin (β-CD) grafted titanium dioxide (TiO(2)/β-CD) was synthesized through photo-induced self assembly methods, and its structure was characterized. The TiO(2)/β-CD hybrid nanomaterial showed high photoactivity under visible light irradiation (λ ≥ 400 nm and/or λ ≥ 420 nm) and simulated solar irradiation (λ ≥ 365 nm). Photodegradation of Orange II followed the Langmuir-Hinshelwood kinetics model. The initial rate R(0) of Orange II degradation increased by 6.9, 2.6 and 1.9 times in the irradiation conditions of λ ≥ 420nm, λ ≥ 400nm and λ ≥ 365 nm, respectively. β-CD increased the lifetimes of the excited states of the unreactive guests and facilitated the electron transfer from the excited dye to the TiO(2) conduction band, which enhanced the dye pollutant degradation. Superoxide radicals were shown to be the main reactive species that caused the degradation of Orange II under visible irradiation.
Zhang
Xu
X
School of Resources and Environmental Science, Hubei Key Laboratory of Biomass-Resources, Wuhan University, Wuhan 430079, PR China.
Wu
Feng
F
Deng
Nansheng
N
D000465:Algorithms; D002384:Catalysis; D004396:Coloring Agents / Q000737:chemistry* / Q000528:radiation effects*; D004583:Electrons; D006861:Hydrogen Peroxide / Q000737:chemistry; D017665:Hydroxyl Radical / Q000737:chemistry; D007700:Kinetics; D008027:Light; D046529:Microscopy, Electron, Transmission; D053758:Nanoparticles / Q000737:chemistry*; D010782:Photolysis; D011208:Powders; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013472:Sunlight; D013481:Superoxides / Q000737:chemistry; D014025:Titanium / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry; D014961:X-Ray Diffraction; D047392:beta-Cyclodextrins / Q000737:chemistry*
D004396:Coloring Agents; D011208:Powders; D014874:Water Pollutants, Chemical; D047392:beta-Cyclodextrins; D013481:Superoxides; C009495:titanium dioxide; D017665:Hydroxyl Radical; D006861:Hydrogen Peroxide; D014025:Titanium