Enantioselective rhodium-catalyzed addition of arylboronic acids to alkenylheteroarenes.
In the presence of a rhodium complex containing a newly developed chiral diene ligand, alkenes activated by a range of π-deficient or π-excessive heteroarenes engage in highly enantioselective conjugate additions with various arylboronic acids.
Pattison
Graham
G
School of Chemistry, University of Edinburgh, Joseph Black Building, The King's Buildings, West Mains Road, Edinburgh, EH9 3JJ, United Kingdom.
Piraux
Guillaume
G
Lam
Hon Wai
HW
D000147:Acids, Heterocyclic / Q000737:chemistry*; D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
D000147:Acids, Heterocyclic; D001897:Boronic Acids; D012238:Rhodium