title: Multifunctional hybrid organic-inorganic catalytic materials with a hierarchical system of well-defined micro- and mesopores.
abstract: Novel layered zeolitic organic-inorganic materials (MWW-BTEB) have been synthesized by intercalation and stabilization of arylic silsesquioxane molecules between inorganic zeolitic MWW layers. The organic linkers are conformed by two condensed silyl-arylic groups from disilane molecules, such as 1,4-bis(triethoxysilyl)benzene (BTEB), which react with the external silanol groups of the zeolitic layers. The hybrids contain micropores within the inorganic layers and a well-defined mesoporous system in between the organic linkers. An amination post-treatment introduces basic groups in the organic linkers close to the acid sites present in the structural inorganic counterpart. Through this methodology it has been possible to prepare bifunctional acid-base catalysts where the acid sites are of zeolitic nature located in the inorganic building blocks and the basic sites are part of the organic structure. The resultant materials can act as bifunctional catalysts for performing a two-step cascade reaction that involves the catalytic conversion of benzaldehyde dimethylacetal into benzylidene malononitrile.
authors.affiliation: Instituto de Tecnología Química, UPV-CSIC, Universidad Politécnica de Valencia, Avenida de los Naranjos s/n, E-46022 Valencia, Spain. acorma@itq.upv.es
authors.forename: Avelino
authors.initials: A
authors.lastname: Corma
authors.forename: Urbano
authors.initials: U
authors.lastname: Díaz
authors.forename: Teresa
authors.initials: T
authors.lastname: García
authors.forename: Germán
authors.initials: G
authors.lastname: Sastre
authors.forename: Alexandra
authors.initials: A
authors.lastname: Velty