title: Time of flight mass spectrometry for quantitative data analysis in fast transient studies using a Temporal Analysis of Products (TAP) reactor.
abstract: A Time of flight (ToF) mass spectrometer suitable in terms of sensitivity, detector response and time resolution, for application in fast transient Temporal Analysis of Products (TAP) kinetic catalyst characterization is reported. Technical difficulties associated with such application as well as the solutions implemented in terms of adaptations of the ToF apparatus are discussed. The performance of the ToF was validated and the full linearity of the specific detector over the full dynamic range was explored in order to ensure its applicability for the TAP application. The reported TAP-ToF setup is the first system that achieves the high level of sensitivity allowing monitoring of the full 0-200 AMU range simultaneously with sub-millisecond time resolution. In this new setup, the high sensitivity allows the use of low intensity pulses ensuring that transport through the reactor occurs in the Knudsen diffusion regime and that the data can, therefore, be fully analysed using the reported theoretical TAP models and data processing.
authors.affiliation: CenTACat, School of Chemistry and Chemical Engineering, Queen's University, Stranmillis Road, Belfast, BT9 5AG, Northern Ireland, UK. a.goguet@qub.ac.uk
authors.forename: Alexandre
authors.initials: A
authors.lastname: Goguet
authors.forename: Christopher
authors.initials: C
authors.lastname: Hardacre
authors.forename: Noleen
authors.initials: N
authors.lastname: Maguire
authors.forename: Kevin
authors.initials: K
authors.lastname: Morgan
authors.forename: Sergiy O
authors.initials: SO
authors.lastname: Shekhtman
authors.forename: Steve P
authors.initials: SP
authors.lastname: Thompson