title: A new oxomolybdate component extracted from the "virtual dynamic library" yielding the macrocyclic anion [(Mo(VI)(8)O(28))(4)(Mo(V)(2)O(2)S(2))(4)](24-).
abstract: A rare isomer of the {Mo(8)O(28)}(8-) anion has been trapped from an acidified aqueous solution of molybdate by using the {Mo(2)O(2)S(2)}(2+) oxothio cation as the linker and isolated as a part of a unique macrocyclic anion, which consists of four isopolyoxomolybdate fragments {Mo(8)O(28)} bridged by four {Mo(2)O(2)S(2)} units.
authors.affiliation: Institut Lavoisier de Versailles, Université de Versailles Saint Quentin, UMR 8180, 45 avenue des Etats Unis, 78035 Versailles, France.
authors.forename: Vladimir S
authors.initials: VS
authors.lastname: Korenev
authors.forename: Antoine G
authors.initials: AG
authors.lastname: Boulay
authors.forename: Anne
authors.initials: A
authors.lastname: Dolbecq
authors.forename: Maxim N
authors.initials: MN
authors.lastname: Sokolov
authors.forename: Akram
authors.initials: A
authors.lastname: Hijazi
authors.forename: Sébastien
authors.initials: S
authors.lastname: Floquet
authors.forename: Vladimir P
authors.initials: VP
authors.lastname: Fedin
authors.forename: Emmanuel
authors.initials: E
authors.lastname: Cadot
mesh_terms: D000838:Anions / Q000737:chemistry; D047028:Macrocyclic Compounds / Q000737:chemistry*; D008958:Models, Molecular; D008982:Molybdenum / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry*
chemical_list: D000838:Anions; D047028:Macrocyclic Compounds; C044659:molybdate; D013455:Sulfur; D008982:Molybdenum