Dielectric properties of (Ba,Sr)TiO₃ thin films with varied microstructures prepared by the chemical solution deposition method for thin-film capacitors and ferroelectric varactors.
We prepared epitaxially grown three-axis-oriented (Ba₀.₇S₀.₃)TiO₃ thin films on (100) platinum-coated (100) MgO single-crystal substrates by the chemical solution deposition method, using a solution derived from Ba(CH₃COO)₂, Sr(CH₃COO)₂, and Ti(O-i-C₃H₇)₄. Microstructures of fabricated thin films depend strongly on the fabrication process, especially on the annealing condition. A (Ba,Sr)TiO₃ thin film fabricated with an annealing temperature of 1073K was found to be a single crystal by transmission electron microscopy. The single-crystal (Ba,Sr)TiO₃ thin film exhibited a (100) three-axis-orientation, which followed the (100) orientation of the platinum electrode on the MgO single-crystal substrate. A (100) three-axis-oriented (Ba,Sr)TiO₃ thin film may be useful for preparing a thin-film capacitor.
Kageyama
Keisuke
K
Murata Manufacturing Co., Ltd., Nagaokakyoshi, Japan. kageyama_kis@murata.co.jp
Hosokura
Tadasu
T
Nakaiso
Toshiyuki
T
Takagi
Hiroshi
H