title: Speciation and distribution of vanadium in drinking water iron pipe corrosion by-products.
abstract: Vanadium (V) when ingested from drinking water in high concentrations (>15 μg L(-1)) is a potential health risk and is on track to becoming a regulated contaminant. High concentrations of V have been documented in lead corrosion by-products as Pb(5)(V(5+)O(4))(3)Cl (vanadinite) which, in natural deposits is associated with iron oxides/oxyhydroxides, phases common in iron pipe corrosion by-products. The extent of potential reservoirs of V in iron corrosion by-products, its speciation, and mechanism of inclusion however are unknown. The aim of this study is to assess these parameters in iron corrosion by-products, implementing synchrotron-based μ-XRF mapping and μ-XANES along with traditional physiochemical characterization. The morphologies, mineralogies, and chemistry of the samples studied are superficially similar to typical iron corrosion by-products. However, we found V present as discrete grains of Pb(5)(V(5+)O(4))(3)Cl likely embedded in the surface regions of the iron corrosion by-products. Concentrations of V observed in bulk XRF analysis ranged from 35 to 899 mg kg(-1). We calculate that even in pipes with iron corrosion by-products with low V concentration, 100 mg kg(-1), as little as 0.0027% of a 0.1-cm thick X 100-cm long section of that corrosion by-product needs to be disturbed to increase V concentrations in the drinking water at the tap to levels well above the 15 μg L(-1) notification level set by the State of California and could adversely impact human health. In addition, it is likely that large reservoirs of V are associated with iron corrosion by-products in unlined cast iron mains and service branches in numerous drinking water distribution systems.
authors.affiliation: Department of Geology, University of Cincinnati, Cincinnati, OH 45221-0013, USA. Tammie.Gerke@uc.edu
authors.forename: Tammie L
authors.initials: TL
authors.lastname: Gerke
authors.forename: Kirk G
authors.initials: KG
authors.lastname: Scheckel
authors.forename: J Barry
authors.initials: JB
authors.lastname: Maynard
mesh_terms: D003343:Corrosion; D004326:Drinking; D004784:Environmental Monitoring; D007501:Iron / Q000737:chemistry*; D014639:Vanadium / Q000032:analysis* / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014881:Water Supply / Q000032:analysis*
chemical_list: D014874:Water Pollutants, Chemical; D014639:Vanadium; D007501:Iron