Complete scaling for inhomogeneous fluids.
"Complete scaling," which maps asymmetric fluid criticality onto the symmetric Ising model, is extended to spatially inhomogeneous fluids. This extension enables us to obtain a fluctuation-modified asymmetric interfacial density profile, which incorporates leading effects from the asymmetry of fluid phase coexistence and the asymmetry of the correlation length. The derived asymmetric interfacial profile is used to calculate Tolman's length, the diverging coefficient of the curvature correction to the surface tension. The amplitude of the divergent Tolman length is found to depend on the asymmetry of the correlation length.
Bertrand
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Department of Physics, University of Maryland, College Park, Maryland 20742, USA.
Anisimov
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