Synthesis, characterization and property of a mixed-valent Ag(I)/Ag(II) coordination polymer.
A novel mixed-valent Ag(I)/Ag(II) coordination polymer {[Ag(I)(2)Ag(II)(0.5)(SO(4))(HSO(4))(pyz)(2.5)]·H(2)O}(n) (1, pyz = pyrazine) was synthesized and characterized. The results show it presents semiconducting and photoluminescent properties.
Sun
Di
D
Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Yang
Cheng-Feng
CF
Xu
Hao-Ran
HR
Zhao
Hai-Xia
HX
Wei
Zhan-Hua
ZH
Zhang
Na
N
Yu
La-Jia
LJ
Huang
Rong-Bin
RB
Zheng
Lan-Sun
LS