title: Large interlayer relaxation at a metal-oxide interface: the case of a supported ultrathin alumina film.
abstract: The structure of the metal-oxide interface in the alumina/Ni{3}Al(111) system is investigated by comparing backscattering and forward-scattering photoelectron diffraction modulation functions of chemically nonequivalent aluminum and oxygen species with multiple-scattering simulations. We observe large relaxation effects at the metal-oxide interface layer: Al atoms of the Ni3Al alloy surface are lifted by more than 0.7 A above the ideal termination, thus creating a new, metallic layer between the oxide and the alloy. The effect of the interface atomic rearrangement on the properties of the supported ultrathin alumina oxide film is discussed.
authors.affiliation: Physics Department and CENMAT, University of Trieste, Via Valerio 2, I-34127 Trieste, Italy.
authors.forename: Erik
authors.initials: E
authors.lastname: Vesselli
authors.forename: Alessandro
authors.initials: A
authors.lastname: Baraldi
authors.forename: Silvano
authors.initials: S
authors.lastname: Lizzit
authors.forename: Giovanni
authors.initials: G
authors.lastname: Comelli