NMR study of the Mott transitions to superconductivity in the two Cs3C60 phases.
We report a NMR and magnetometry study on the expanded intercalated fulleride Cs3C60 in both its A15 and face centered cubic structures. NMR allowed us to evidence that both exhibit a first-order Mott transition to a superconducting state, occurring at distinct critical pressures p{c} and temperatures T{c}. Though the ground state magnetism of the Mott phases differs, their high T paramagnetic and superconducting properties are found similar, and the phase diagrams versus unit volume per C60 are superimposed. Thus, as expected for a strongly correlated system, the interball distance is the relevant parameter driving the electronic behavior and quantum transitions of these systems.
Ihara
Y
Y
Laboratoire de Physique des Solides, Universite Paris-Sud 11, CNRS UMR 8502, 91405 Orsay, France. ihara@lps.u-psud.fr
Alloul
H
H
Wzietek
P
P
Pontiroli
D
D
Mazzani
M
M
Riccò
M
M