title: Observations on the methane oxidation capacity of landfill soils.
abstract: The objective of this study was to determine the role of CH(4) loading to a landfill cover in the control of CH(4) oxidation rate (gCH(4)m(-2)d(-1)) and CH(4) oxidation efficiency (% CH(4) oxidation) in a field setting. Specifically, we wanted to assess how much CH(4) a cover soil could handle. To achieve this objective we conducted synoptic measurements of landfill CH(4) emission and CH(4) oxidation in a single season at two Southeastern USA landfills. We hypothesized that percent oxidation would be greatest at sites of low CH(4) emission and would decrease as CH(4) emission rates increased. The trends in the experimental results were then compared to the predictions of two differing numerical models designed to simulate gas transport in landfill covers, one by modeling transport by diffusion only and the second allowing both advection and diffusion. In both field measurements and in modeling, we found that percent oxidation is a decreasing exponential function of the total CH(4) flux rate (CH(4) loading) into the cover. When CH(4) is supplied, a cover's rate of CH(4) uptake (gCH(4)m(-2)d(-2)) is linear to a point, after which the system becomes saturated. Both field data and modeling results indicate that percent oxidation should not be considered as a constant value. Percent oxidation is a changing quantity and is a function of cover type, climatic conditions and CH(4) loading to the bottom of the cover. The data indicate that an effective way to increase the % oxidation of a landfill cover is to limit the amount of CH(4) delivered to it.
authors.affiliation: Department of Earth, Ocean and Atmospheric Science, Florida State University, Tallahassee, FL 32306-4320, USA. jchanton@mailer.fsu.edu
authors.forename: Jeffrey
authors.initials: J
authors.lastname: Chanton
authors.forename: Tarek
authors.initials: T
authors.lastname: Abichou
authors.forename: Claire
authors.initials: C
authors.lastname: Langford
authors.forename: Kurt
authors.initials: K
authors.lastname: Spokas
authors.forename: Gary
authors.initials: G
authors.lastname: Hater
authors.forename: Roger
authors.initials: R
authors.lastname: Green
authors.forename: Doug
authors.initials: D
authors.lastname: Goldsmith
authors.forename: Morton A
authors.initials: MA
authors.lastname: Barlaz
mesh_terms: D000393:Air Pollutants / Q000032:analysis / Q000378:metabolism*; D000397:Air Pollution / Q000706:statistics & numerical data; D004784:Environmental Monitoring; D008697:Methane / Q000032:analysis / Q000378:metabolism*; D010084:Oxidation-Reduction; D012037:Refuse Disposal / Q000706:statistics & numerical data*; D012987:Soil / Q000737:chemistry; D012988:Soil Microbiology
chemical_list: D000393:Air Pollutants; D012987:Soil; D008697:Methane