Elastic properties of some selected two-monomer systems as studied by Brillouin spectroscopy.
We present results obtained by Brillouin scattering method for four two-component systems comprising of a high viscosity monomer and a low viscosity monomer. The monomers used were crosslinking (divinyl) or linear (monovinyl) ones. The investigated systems were: divinyl/divinyl-bis-GMA/TEGDM; divinyl/monovinyl-bis-GMA/PEGMM; monovinyl/divinyl-bis-MGMA/TEGDM and monovinyl/monovinyl-bis-MGMA/PEGMM; they were formulated at various molar ratios. The measurements have been performed in temperature range 293-353 K. The following physical parameters characterizing the investigated systems were estimated: hypersonic velocity V, attenuation coefficient α and adiabatic compressibility β, all as a function of temperature and monomer molar ratio. The obtained results have been discussed in terms of the influence of the system composition and viscosity on their elastic properties. Speed of changes of the adiabatic compressibility β as derivative have been also discussed in terms of both, the temperature as well as the component of molar ratio.
Ziobrowski
P
P
Faculty of Technical Physics, Poznan University of Technology, Nieszawska 13A, 60-965 Poznan, Poland.
Drozdowski
M
M
Andrzejewska
E
E
Marcinkowska
A
A
Łapsa
K
K
D017438:Bisphenol A-Glycidyl Methacrylate / Q000737:chemistry; D004548:Elasticity; D011092:Polyethylene Glycols / Q000737:chemistry*; D011109:Polymethacrylic Acids / Q000737:chemistry*; D013057:Spectrum Analysis / Q000379:methods*; D013696:Temperature
D011109:Polymethacrylic Acids; C020946:triethylene glycol dimethacrylate; D011092:Polyethylene Glycols; D017438:Bisphenol A-Glycidyl Methacrylate