2D excitons as primary energy carriers in organic crystals: the case of oligoacenes.
A number of organic crystals show anisotropic excitonic couplings, with weak interlayer interactions between molecules that are more strongly coupled within the layers. The resulting energy carriers are intralayer 2D excitons that diffuse along the interlayer direction. We model this analytically for infinite layers and using quantum-chemical calculations of the electronic couplings for anthracene clusters. We show that the exciton hopping rates and diffusion lengths depend in a subtle manner on the size and shape of the interacting aggregates, temperature, and the presence of energetic disorder.
Emelianova
E V
EV
Laboratory for Chemistry of Novel Materials, University of Mons, Place du Parc 20, B-7000 Mons, Belgium. evguenia@averell.umh.ac.be
Athanasopoulos
S
S
Silbey
R J
RJ
Beljonne
D
D