Copper-catalyzed rearrangement of tertiary amines through oxidation of aliphatic C-H bonds in air or oxygen: direct synthesis of α-amino acetals.
Tian
Jie-Sheng
JS
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371, Singapore.
Loh
Teck-Peng
TP
D000080:Acetals / Q000138:chemical synthesis* / Q000737:chemistry; D000388:Air; D000588:Amines / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D007553:Isotope Labeling; D009682:Magnetic Resonance Spectroscopy; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*
D000080:Acetals; D000588:Amines; D002244:Carbon; D003300:Copper; D006859:Hydrogen; D010100:Oxygen