title: Facile synthesis of hypersilylated aromatic compounds by palladium-mediated arylation reaction.
abstract: The treatment of aryl iodides with tris(trimethylsilyl)silane in the presence of Pd(P(tBu)(3))(2) and the Hünig base leads to the formation of hypersilylated aromatic products in good to excellent yields without cleavage of weak Si-Si bonds under mild conditions.
authors.affiliation: Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
authors.forename: Aldes
authors.initials: A
authors.lastname: Lesbani
authors.forename: Hitoshi
authors.initials: H
authors.lastname: Kondo
authors.forename: Jun-Ichi
authors.initials: J
authors.lastname: Sato
authors.forename: Yoshinori
authors.initials: Y
authors.lastname: Yamanoi
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Nishihara