Rapid sequential determination of Pu, 90Sr and 241Am nuclides in environmental samples using an anion exchange and Sr-Spec resins.
This paper presents a quantitative and rapid method of sequential separation of Pu, (90)Sr and (241)Am nuclides in environmental soil samples with an anion exchange resin and Sr Spec resin. After the sample solution was passed through an anion exchange column connected to a Sr Spec column, Pu isotopes were purified from the anion exchange column. Strontium-90 was separated from other interfering elements by the Sr Spec column. Americium-241 was purified from lanthanides by the anion exchange resin after oxalate co-precipitation. Measurement of Pu and Am isotopes was carried out using an α-spectrometer. Strontium-90 was measured by a low-level liquid scintillation counter. The radiochemical procedure of Pu, (90)Sr and (241)Am nuclides investigated in this study validated by application to IAEA reference materials and environmental soil samples.
Lee
M H
MH
Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, P.O. Box 105, Yuseong, Daejeon 305-353, Republic of Korea. mhlee@kaeri.re.kr
Ahn
H J
HJ
Park
J H
JH
Park
Y J
YJ
Song
K
K
D000576:Americium / Q000032:analysis*; D002852:Chromatography, Ion Exchange / Q000379:methods; D011005:Plutonium / Q000032:analysis*; D012987:Soil / Q000737:chemistry*; D012990:Soil Pollutants, Radioactive / Q000032:analysis*; D013326:Strontium Radioisotopes / Q000032:analysis*
D012987:Soil; D012990:Soil Pollutants, Radioactive; D013326:Strontium Radioisotopes; D011005:Plutonium; D000576:Americium