Surface properties and adsorption characteristics to methylene blue and iodine of adsorbents from sludge.
Adsorbent materials created from wastewater sludge have unique surface characteristics and could be effective in adsorption applications. In this research, the sludge-adsorbents were generated by pyrolyzing mixtures of sewage sludge and H(2)SO(4). Scanning electron microscope (SEM), thermal analysis, X-ray diffraction (XRD) and X-ray photoelectron spectroscope (XPS) were used to analyze the properties of sludge-adsorbent. XPS results show that the adsorbent surface functional groups with high contents of oxygen-containing groups serve as active sites for the adsorption and affect the surface characteristics; the adsorption mechanism of methylene blue (MB) is mainly Brönsted acid-base reaction between the adsorbent surface and MB; and iodine atoms are bonded to the surface of the adsorbent mainly by dispersive interactions rather than by electrostatic interactions. The results also show that H(2)SO(4) level, pyrolysis temperature and sulfuric acid/sludge weight ratio actually affected the adsorption characteristics. Using the conditions (H(2)SO(4) level of 1-18 M, pyrolysis temperature of 650°C, and weight ratio of 0.8), the adsorption capacities for MB and iodine were 74.7-62.3 mg g(-1) and 169.5-209.3 mg g(-1), respectively.
State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, Harbin 150090, China.
L Y
LY
Deng
G R
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Xu
G B
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Li
D000327:Adsorption; D006358:Hot Temperature; D007455:Iodine / Q000737:chemistry / Q000302:isolation & purification*; D008751:Methylene Blue / Q000737:chemistry / Q000302:isolation & purification*; D008855:Microscopy, Electron, Scanning; D015394:Molecular Structure; D010084:Oxidation-Reduction; D056951:Photoelectron Spectroscopy; D012722:Sewage / Q000737:chemistry*; D013464:Sulfuric Acids / Q000737:chemistry; D013499:Surface Properties; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000302:isolation & purification*
D012722:Sewage; D013464:Sulfuric Acids; D014874:Water Pollutants, Chemical; D007455:Iodine; C033158:sulfuric acid; D008751:Methylene Blue