Chirality organization of aniline oligomers through hydrogen bonds of amino acid moieties.
Aniline oligomers bearing amino acid moieties were designed by the introduction of L/D-Ala-OMe into aniline oligomers to induce chirality organization of the π-conjugated aniline oligomer moieties, wherein the formation of intramolecular hydrogen bonds was demonstrated to play an important role to regulate the aniline oligomer moieties conformationally.
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan.
Satoshi D
SD
Ohmura
Toshiyuki
T
Moriuchi
Toshikazu
T
Hirao
D000596:Amino Acids / Q000737:chemistry*; D000814:Aniline Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008968:Molecular Conformation; D009842:Oligopeptides / Q000737:chemistry*; D013237:Stereoisomerism
D000596:Amino Acids; D000814:Aniline Compounds; D009842:Oligopeptides; C023650:aniline