Use of gas push-pull tests for the measurement of methane oxidation in different landfill cover soils.
In order to optimise methane oxidation in landfill cover soils, it is important to be able to accurately quantify the amount of methane oxidised. This research considers the gas push-pull test (GPPT) as a possible method to quantify oxidation rates in situ. During a GPPT, a gas mixture consisting of one or more reactive gases (e.g., CH(4), O(2)) and one or more conservative tracers (e.g., argon), is injected into the soil. Following this, the mixture of injected gas and soil air is extracted from the same location and periodically sampled. The kinetic parameters for the biological oxidation taking place in the soil can be derived from the differences in the breakthrough curves. The original method of Urmann et al. (2005) was optimised for application in landfill cover soils and modified to reduce the analytical effort required. Optimised parameters included the flow rate during the injection phase and the duration of the experiment. 50 GPPTs have been conducted at different landfills in Germany during different seasons. Generally, methane oxidation rates ranged between 0 and 150 g m(soil air)(-3)h(-1). At one location, rates up to 440 g m(soil air)(-3)h(-1) were measured under particularly favourable conditions. The method is simple in operation and does not require expensive equipment besides standard laboratory gas chromatographs.
Institute of Environmental Technology and Energy Economics, Bioconversion and Emission Control Group, Hamburg University of Technology - Harburger Schlossstrasse 36, 21079 Hamburg, Germany. streese@tu-harburg.de
Jan
J
Streese-Kleeberg
Ingke
I
Rachor
Julia
J
Gebert
Rainer
R
Stegmann
D000393:Air Pollutants / Q000032:analysis* / Q000378:metabolism; D000397:Air Pollution / Q000706:statistics & numerical data; D004784:Environmental Monitoring / Q000379:methods*; D008697:Methane / Q000032:analysis* / Q000378:metabolism; D010084:Oxidation-Reduction; D012037:Refuse Disposal / Q000379:methods*; D012987:Soil / Q000737:chemistry*; D012988:Soil Microbiology
D000393:Air Pollutants; D012987:Soil; D008697:Methane