Solvent-dependent enantiodivergent Mannich-type reaction: utilizing a conformationally flexible guanidine/bisthiourea organocatalyst.
Department of Biotechnology and Life Science, Faculty of Technology, Tokyo University of Agriculture and Technology, 2-24-16 Naka-cho, Koganei, Tokyo 184-8588, Japan. sohtomey@cc.tuat.ac.jp
Yoshihiro
Y
Sohtome
Shinji
S
Tanaka
Keisuke
K
Takada
Takahisa
T
Yamaguchi
Kazuo
K
Nagasawa
D002384:Catalysis; D019791:Guanidine / Q000737:chemistry*; D007097:Imines / Q000737:chemistry*; D008968:Molecular Conformation; D012997:Solvents; D013237:Stereoisomerism; D013890:Thiourea / Q000737:chemistry*
D007097:Imines; D012997:Solvents; D013890:Thiourea; D019791:Guanidine