Intramolecular heterolytic dihydrogen cleavage by a bifunctional frustrated pyrazolylborane Lewis pair.
The reaction of bis(pentafluorophenyl)borane, HB(C(6)F(5))(2), with 3,5-di-tert-butyl-1H-pyrazole (3) affords the zwitterionic pyrazolium-borate trans-5 and, after dehydrogenation by use of the frustrated carbene-borane Lewis pair 1/B(C(6)F(5))(3), the bifunctional pyrazolylborane 6, which is able to cleave dihydrogen heterolytically with the formation of a mixture of cis-5 and trans-5.
Theuergarten
Eileen
E
Institut für Anorganische und Analytische Chemie, Technische Universität Carolo-Wilhelmina, Hagenring 30, D-38106 Braunschweig, Germany.
Schlüns
Danny
D
Grunenberg
Jörg
J
Daniliuc
Constantin G
CG
Jones
Peter G
PG
Tamm
Matthias
M