Triptycene: no homoconjugation effect for extending optical properties of π-conjugated oligomers.
1,5- and 1,8-bis(bifluorenyl)anthracene were synthesized and converted to their corresponding bis(bifluorenyl)triptycenes and bis(bifluorenyl)-9,10-dihydroanthracenes. Analysis of their optical properties shows no feature of extended conjugation in the triptycene pair. The electronic spectra of the triptycene and dihydroanthracene pairs are in fact superimposable. There is definite evidence that triptycene displays zero homoconjugation effect.
Gu
Xingwei
X
Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543.
Lai
Yee-Hing
YH