Two luminescent enantiomorphic 3D metal-organic frameworks with 3D homochiral double helices.
Two enantiomorphic Cd(II) coordination polymers with three-dimensional homochiral double helices have been assembled respectively from two tripodal enantiopure amino acid derivatives, which exhibit (3,4)-connected (6(3))(6(3).10(3)) topology and strong purple fluorescence.
Zhu
Qilong
Q
State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, China.
Sheng
Tianlu
T
Fu
Ruibiao
R
Tan
Chunhong
C
Hu
Shengmin
S
Wu
Xintao
X
D002104:Cadmium / Q000737:chemistry*; D002942:Circular Dichroism; D049408:Luminescent Agents / Q000138:chemical synthesis*; D009942:Organometallic Compounds; D011108:Polymers / Q000737:chemistry; D013237:Stereoisomerism
D049408:Luminescent Agents; D009942:Organometallic Compounds; D011108:Polymers; D002104:Cadmium