Thermoresponsive luminescent electrospun fibers prepared from poly(DMAEMA-co-SA-co-StFl) multifunctional random copolymers.
We report novel thermoresponsive electrospun (ES) fibers prepared from multifunctional random copolymers of poly((2-(dimethylamino)ethyl methacrylate)-co-(stearyl acrylate) -co-(9,9-dihexyl-2-(4-vinylpenyl)-9H-fluorene)) (poly(DMAEMA-co-SA-co-StFl)). The moieties of DMAEMA, SA, and StFl were designed to exhibit the thermoresponsive, physical cross-linking, and fluorescent functionality, respectively. The effects of the copolymer compositions on the morphology and photoluminescence of the prepared ES fibers were explored. The prepared P4 copolymer with the DMAEMA/SA/StFl mole ratio of 92/3/5 showed the lower critical solution temperature (LCST) of 32.5 °C. A significant temperature-dependent swelling and de-swelling behavior was found in the P4 ES fibers, which had the diameter of 753 ± 174 nm and 5-10 nm StFl aggregated domain. Accompanied with volume-changing on the P4 ES fibers, a reversible photoluminescence (PL) quenching was also observed during the heating and cooling cycle between 40 and 60 °C. Such reversible switching of the "on-off" PL intensity was probably due to the light absorption ability of the StFl moiety, resulted from the extended/compact structural transformation on the PDMAEMA moiety. Furthermore, the high surface/volume ratio of the ES fibers led a much better temperature response compared with the corresponding spin-coated film. The present study demonstrated that the ES fibers prepared from multifunctional copolymers exhibited the thermoreversible variation on both volume and photoluminescence intensity.
Department of Chemical Engineering and Institute of Polymer Science and Engineering, National Taiwan University, Taipei 106, Taiwan.
Yu-Cheng
YC
Chiu
Chi-Ching
CC
Kuo
Jung-Ching
JC
Hsu
Wen-Chang
WC
Chen