Isotruxene-derived cone-shaped organic dyes for dye-sensitized solar cells.
The synthesis, electronic properties, and performance in dye-sensitized solar cells (DSSCs) of four cone-shaped organic dyes (ITD, ITD-Th, ITD-Hx, and ITD-OM) containing the isotruxene π-scaffold are reported. Selective substitution of the unsymmetrical isotruxene core with two diarylamino donors and one cyanocarboxylic acid acceptor was achieved by using a prefunctionalized dibromoisotruxene building block. The ortho-para-branched isotruxene core allows strong electronic couplings among the donors and the acceptor, leading to red-shifted absorption profiles with significant charge-transfer character. All four isotruxene dyes display reversible anodic waves in cyclic voltammagrams with both HOMO and LUMO potentials suitable for application in DSSCs. The DSSCs fabricated with these cone-shaped organic dyes exhibited high open-circuit voltages (0.67-0.76 V) and fill factors (0.67-0.72) with a power conversion efficiency (η) up to 5.45%, which is 80% of the ruthenium dye N719-based standard cell fabricated and measured under the same conditions.
Lin
Shih-Hsun
SH
Department of Chemistry, National Taiwan University, Taipei, 10617 Taiwan.
Hsu
Ying-Chan
YC
Lin
Jiann T
JT
Lin
Cheng-Kai
CK
Yang
Jye-Shane
JS