A hetero-stranded double helix composed of m-diethynylbenzene-based complementary molecular strands stabilized by amidinium-carboxylate salt bridges.
A hetero-stranded double helix with a controlled helix sense was designed and synthesized from an optically active dimeric amidine and its complementary achiral dicarboxylic acid strand with conjugated m-diethynylbenzene backbones, being stabilized by the salt bridges.
Department of Molecular Design and Engineering, Graduate School of Engineering, Nagoya University, Chikusa-ku, Nagoya 464-8603, Japan.
Zong-Quan
ZQ
Wu
Yoshio
Y
Furusho
Hidekazu
H
Yamada
Eiji
E
Yashima
D000578:Amidines / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D002942:Circular Dichroism; D019281:Dimerization; D008968:Molecular Conformation; D012492:Salts / Q000737:chemistry; D013237:Stereoisomerism
D000578:Amidines; D002264:Carboxylic Acids; D012492:Salts