Hard/soft heterometallic network complex of a macrocycle with endo/exocyclic coordination.
One-pot assembly reactions of an S(2)O(4) macrocycle with CuI in the absence and presence of KI afforded an emissive one-dimensional looped coordination polymer linked with a cubane-type copper iodide cluster and an endocoordinated potassium(I) coordination polymer linked with a ribbon-type copper iodide cluster, respectively.
Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University, Jinju 660-701, South Korea.
Yongnu
Y
Jin
Hyun Jee
HJ
Kim
Jai Young
JY
Lee
So Young
SY
Lee
Won Joon
WJ
Shim
Sang Hee
SH
Hong
Shim Sung
SS
Lee