Chirality organization of aniline oligomers through hydrogen bonds of amino acid moieties.
Aniline oligomers bearing amino acid moieties were designed by the introduction of L/D-Ala-OMe into aniline oligomers to induce chirality organization of the π-conjugated aniline oligomer moieties, wherein the formation of intramolecular hydrogen bonds was demonstrated to play an important role to regulate the aniline oligomer moieties conformationally.
Ohmura
Satoshi D
SD
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan.
Moriuchi
Toshiyuki
T
Hirao
Toshikazu
T
D000596:Amino Acids / Q000737:chemistry*; D000814:Aniline Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008968:Molecular Conformation; D009842:Oligopeptides / Q000737:chemistry*; D013237:Stereoisomerism
D000596:Amino Acids; D000814:Aniline Compounds; D009842:Oligopeptides; C023650:aniline