A universal approach to fabricate ordered colloidal crystals arrays based on electrostatic self-assembly.
We present a novel and simple method to fabricate two-dimensional (2D) poly(styrene sulfate) (PSS, negatively charged) colloidal crystals on a positively charged substrate. Our strategy contains two separate steps: one is the three-dimensional (3D) assembly of PSS particles in ethanol, and the other is electrostatic adsorption in water. First, 3D assembly in ethanol phase eliminates electrostatic attractions between colloids and the substrate. As a result, high-quality colloidal crystals are easily generated, for electrostatic attractions are unfavorable for the movement of colloidal particles during convective self-assembly. Subsequently, top layers of colloidal spheres are washed away in the water phase, whereas well-packed PSS colloids that are in contact with the substrate are tightly linked due to electrostatic interactions, resulting in the formation of ordered arrays of 2D colloidal spheres. Cycling these processes leads to the layer-by-layer assembly of 3D colloidal crystals with controllable layers. In addition, this strategy can be extended to the fabrication of patterned 2D colloidal crystals on patterned polyelectrolyte surfaces, not only on planar substrates but also on nonplanar substrates. This straightforward method may open up new possibilities for practical use of colloidal crystals of excellent quality, various patterns, and controllable fashions.
Zhang
Xun
X
State Key Laboratory of Supramolecular Structure and Materials, College of Chemistry, Jilin University, Changchun 130012, PR China.
Zhang
Junhu
J
Zhu
Difu
D
Li
Xiao
X
Zhang
Xuemin
X
Wang
Tieqiang
T
Yang
Bai
B
D003102:Colloids / Q000737:chemistry*; D003460:Crystallization; D004129:Dimethylpolysiloxanes / Q000737:chemistry; D000431:Ethanol / Q000737:chemistry; D008855:Microscopy, Electron, Scanning / Q000379:methods; D053758:Nanoparticles / Q000737:chemistry; D036103:Nanotechnology / Q000379:methods; D010316:Particle Size; D011137:Polystyrenes / Q000737:chemistry; D012825:Silicon / Q000737:chemistry; D055672:Static Electricity; D013499:Surface Properties; D013784:Textiles
D003102:Colloids; D004129:Dimethylpolysiloxanes; D011137:Polystyrenes; D000431:Ethanol; C013830:baysilon; D012825:Silicon