A new approach to internal Lewis pairs featuring a phosphenium acid and a pyridine base.
A bis(imino)acenaphthene (BIAN) ligand containing a pendant Lewis base has been used as a new framework to support a N-heterocyclic phosphenium cation (NHP). Reactivity studies demonstrate the ability of the ligand to act as a Lewis base, while the phosphorus centre provides a Lewis acidic site, giving new opportunities in NHP chemistry.
Brazeau
Allison L
AL
Department of Chemistry, The University of Western Ontario, 1151 Richmond St., London, ON N6A 5B7, Canada.
Caputo
Christine A
CA
Martin
Caleb D
CD
Jones
Nathan D
ND
Ragogna
Paul J
PJ