Magnetic metal-organic framework constructed from a paramagnetic metalloligand exhibiting a significant sorption and reversible magnetic conversions.
A Co(II)-Cu(II) framework based on a paramagnetic metalloligand [Co(Tt)(2)] shows a permanent porosity with a record high surface area for magnetic MOFs as well as a reversible magnetic transformation between a paramagnetic-like state and a short-range magnetic order in the low-temperature regime upon solvation-desolvation cyclings.
Department of Chemistry (BK21), Korea University, Seoul 136-7, 13, Korea.
Dae Won
DW
Ryu
Woo Ram
WR
Lee
Jin Wuk
JW
Lee
Jung Hee
JH
Yoon
Hyoung Chan
HC
Kim
Eui Kwan
EK
Koh
Chang Seop
CS
Hong
D000327:Adsorption; D001881:Borates / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D008024:Ligands; D008280:Magnetics; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D016062:Porosity; D013696:Temperature; D014230:Triazoles / Q000737:chemistry*
D001881:Borates; D008024:Ligands; D009942:Organometallic Compounds; D014230:Triazoles; D003035:Cobalt; D003300:Copper