Emission of organic compounds from mould and core binders used for casting iron, aluminium and bronze in sand moulds.
Emissions from mould and core sand binders commonly used in the foundry industry have been investigated. Degradation of three different types of binders was investigated: Furfuryl alcohol (FA), phenolic urethane (PU) and resol-CO2 (RC). In each group of binders, at least two different binder compositions were tested. A test method that provides uniform test conditions is described. The method can be used as a general test method to analyse off gases from binders. Moulds, containing a standard size casting, were produced and the amount and type of organic compounds, resulting from thermal degradation of binders, was monitored when cast iron, bronze and aluminium was poured in the moulds. Binder degradation was measured by collecting off gases in a specially designed ventilation hood at a constant flow rate. Samples were taken from the ventilation system and analysed for hydrocarbons and CO content. It is shown how off-gases vary with time after pouring and shake out. Also the composition of off-gases is analysed and shown. It is further shown how the composition of off-gasses varies between different types of binders and with varying composition of the binders as well as function of the thermal load on the moulding sand.
Tiedje
Niels
N
Department of Mechanical Engineering, Technical University of Denmark, Kgs. Lyngby, Denmark. nsti@mek.dtu.dk
Crepaz
Rudolf
R
Eggert
Torben
T
Bey
Niki
N
D000395:Air Pollutants, Occupational / Q000032:analysis*; D000497:Alloys; D000535:Aluminum; D003718:Denmark; D004784:Environmental Monitoring / Q000379:methods; D005663:Furans / Q000737:chemistry; D007501:Iron; D008669:Metallurgy; D009930:Organic Chemicals / Q000032:analysis*; D012822:Silicon Dioxide; D014520:Urethane / Q000737:chemistry
D000395:Air Pollutants, Occupational; D000497:Alloys; D005663:Furans; D009930:Organic Chemicals; D014520:Urethane; D012822:Silicon Dioxide; D000535:Aluminum; C012986:furfuryl alcohol; D007501:Iron