Controlling optical properties and function of BODIPY by using asymmetric substitution effects.
Asymmetrically substituted BODIPY analogues of the dye PM567 have been synthesised from 2-acylpyrroles and pyrroles that bear indene, fluorene or difluorene units. The type of linkage between the fluorene and the BODIPY core plays an important role in the photophysics of the BODIPY chromophore. Indeed, an aliphatic bridge gives rise to an energy-transfer process between the chromophores, whereas a vinyl spacer allows an electronic interaction between them, leading to a large red shift of the spectral bands. The laser action of the new dyes has been analysed under transversal pumping at 10 Hz repetition rate, in both liquid phase and incorporated into solid polymeric matrices. Lasing efficiencies of up to 40% were reached with high photostabilities with the laser output remaining at the initial level after 1×10(5) pump pulses in the same position of the sample. The laser action of the new dyes outperforms the laser behaviour of commercial dyes that emit in the same spectral region. The replacement of fluorene by indene quenches the fluorescence and laser emission, but allows the development of an iron cation fluorescent sensor.
Departamento de Quimica Fisica, UPV-EHU, Apartado 644, 48080 Bilbao, Spain. jorge.banuelos@ehu.es
Jorge
J
Bañuelos-Prieto
Antonia R
AR
Agarrabeitia
Inmaculada
I
Garcia-Moreno
Iñigo
I
Lopez-Arbeloa
Angel
A
Costela
Lourdes
L
Infantes
M Eugenia
ME
Perez-Ojeda
Marta
M
Palacios-Cuesta
María J
MJ
Ortiz