Electrochemical behavior and voltammetric determination of 2,4,6-triaminopyrimidine at glassy carbon electrode modified with multi-walled carbon nanotubes/nafion.
A multi-wall carbon nanotubes (MWCNTs) composite with Nafion was modified on a glass carbon electrode. The modified electrode was then used as a voltammetric sensor in detecting 2,4,6-triaminopyrimidine (TAP). The surface morphology of the Nafion/MWCNTs composite film was characterized by atomic force microscopy (AFM), and the electrochemical behavior of TAP at this sensor was investigated in detail. The results indicated that the Nafion/MWCNTs modified electrode exhibited efficient electrocatalytic oxidation for TAP with relatively high sensitivity, stability and lifetime. Under the optimized condition using linear sweep voltammetry (LSV), the Nafion/MWCNTs modified electrode exhibited a linear voltammetric response for TAP in the concentration range of 2.0 × 10(-7) to 3.6 × 10(-5) mol L(-1), with a detection limit of 5.0 × 10(-8) mol L(-1). The electrode was applied to detect TAP added to human blood serum, with an average recovery value of 101.3%.
Department of Chemistry, Zhengzhou University, Zhengzhou 450001, P. R. China.
Baocheng
B
Yang
Fei
F
Wang
Sujuan
S
Guo
Baoxian
B
Ye
D002244:Carbon; D004566:Electrodes; D005465:Fluorocarbon Polymers; D005898:Glass; D006801:Humans; D037742:Nanotubes, Carbon; D010084:Oxidation-Reduction; D011199:Potentiometry; D011725:Pyridines; D011743:Pyrimidines / Q000097:blood; D044967:Serum
D005465:Fluorocarbon Polymers; D037742:Nanotubes, Carbon; D011725:Pyridines; D011743:Pyrimidines; C012070:2,4,6-triaminopyrimidine; C040402:perfluorosulfonic acid; D002244:Carbon; C023666:pyridine