Sub-Doppler spectroscopy of mixed state levels in CH(2).
Perturbations in the 7(16) and 8(18) mixed singlet/triplet levels of ã (1)A(1)(0,0,0) methylene, CH(2), have been reinvestigated by frequency-modulated laser sub-Doppler saturation spectroscopy. The hyperfine structure was completely resolved for both the predominantly singlet and the predominantly triplet components of these mixed rotational levels using b̃ (1)B(1)-ã (1)A(1) optical transitions near 12 200 cm(-1) with megahertz resolution. The mixing coefficients were obtained from the observed hyperfine splittings and a two-level deperturbation model. The analysis also determines the energy separation of the unperturbed zero-order levels and the unperturbed hyperfine splittings for the triplet perturbing levels 6(15) X̃ (3)B(1)(0,3,0) and 9(37) X̃ (3)B(1)(0,2,0).
Department of Chemistry, Brookhaven National Laboratory, Upton, New York 11973, USA.
Chih-Hsuan
CH
Chang
Gregory E
GE
Hall
Trevor J
TJ
Sears