Removal of manganese ions from synthetic groundwater by oxidation using KMnO(4) and the characterization of produced MnO(2) particles.
The aim of this study is to investigate the conditions for the removal of manganese ions from synthetic groundwater by oxidation using KMnO(4) to keep the concentration below the allowed level (0.05 mg/L). The process includes low-level aeration and addition of KMnO(4) in a Jar test system with Mn(2 + ) concentration of 0.50 mg/L, similar to that of natural groundwater in Taiwan. Different parameters such us aeration-pH, oxidant dose, and stirring speed were studied. Aeration alone was not sufficient to remove Mn(2 + ) ions completely even when the pH was increased. When a stoichiometric amount of KMnO(4) (0.96 mg/L) was used, a complete Mn(2 + ) removal was achieved within 15 min at an optimum pH of 8.0. As the amount of KMnO(4) was doubled, lower removal efficiency was obtained because the oxidant also generated manganese ions. The removal of Mn(2 + ) ions could be completed at pH 9.0 using an oxidant dose of 0.48 mg/L because Mn(2 + ) could be sorbed onto the MnO(2) particles. Finally, The MnO(2) particles were characterized using scanning electron microscopy (SEM) and energy dispersive X-ray analysis (EDX).
Phatai
P
P
School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000, Thailand. piawtee99@hotmail.com
Wittayakun
J
J
Grisdanurak
N
N
Chen
W H
WH
Wan
M W
MW
Kan
C C
CC
D002413:Cations, Divalent; D005618:Fresh Water / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D008345:Manganese / Q000737:chemistry / Q000302:isolation & purification*; D017895:Manganese Compounds / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D008956:Models, Chemical; D010084:Oxidation-Reduction; D010087:Oxides / Q000737:chemistry*; D011196:Potassium Permanganate / Q000737:chemistry*; D013499:Surface Properties; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods*
D002413:Cations, Divalent; D017895:Manganese Compounds; D010087:Oxides; D014874:Water Pollutants, Chemical; D011196:Potassium Permanganate; D008345:Manganese; C016552:manganese dioxide