Application of PET deprotection for orthogonal photocontrol of aqueous solution viscosity.
Photorelease and photoisomerization of trans-cinnamic acid in aqueous CTAB solutions induces a bulk solution viscosity increase and decrease, respectively, triggered by orthogonal irradiation wavelengths.
Borak
J Brian
JB
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA.
Lee
Hee-Young
HY
Raghavan
Srinivasa R
SR
Falvey
Daniel E
DE
D015082:2,2'-Dipyridyl / Q000031:analogs & derivatives / Q000737:chemistry; D000077286:Cetrimonium; D002593:Cetrimonium Compounds / Q000737:chemistry; D002934:Cinnamates / Q000737:chemistry; D004579:Electron Transport; D007536:Isomerism; D009682:Magnetic Resonance Spectroscopy; D009942:Organometallic Compounds / Q000737:chemistry; D014783:Viscosity; D014867:Water / Q000737:chemistry*
D002593:Cetrimonium Compounds; D002934:Cinnamates; D009942:Organometallic Compounds; C103599:bis(bipyridyl)ruthenium(II); D014867:Water; C029010:cinnamic acid; D015082:2,2'-Dipyridyl; D000077286:Cetrimonium