Application of the powder of porous titanium carbide ceramics to a reusable adsorbent for environmental pollutants.
The aim of this study is to investigate the utilization of the powder of porous titanium carbide (TiC) ceramics as a novel adsorbent or a material for solid-phase extraction (SPE). The adsorption and elution of inorganic and organic pollutants, Pb(II), 2,4,6-trichlorophenol (TCP), perfluorooctane sulfonate (PFOS), and perfluorooctanoic acid (PFOA), to the material were evaluated. The cartridge packed with TiC ceramics powder was used for the extraction test of pollutants. The solution containing pollutants at 1.0 μg mL(-1) was passed through the TiC cartridge, and the substances were almost quantitatively removed. Furthermore, the pollutants retained in the cartridge were eluted with 3N HCl for Pb(II) and with methanol for organic pollutants. The recoveries of pollutants were over 80%. In addition, we used the TiC cartridge for the solid-phase extraction of water samples (500 mL each of the distilled water and the river water) by adding pollutants at determined concentrations. Every pollutant was adsorbed almost quantitatively, and eluted by 3N HCl or methanol. From these results, we concluded that the powder of porous TiC ceramics is a useful reusable adsorbent for the water cleanup and solid-phase extraction.
Moriwaki
Hiroshi
H
Shinshu University, Faculty of Textile Science and Technology, Division of Applied Biology, 3-15-1 Tokida, Ueda, Nagano 386-8567, Japan. moriwaki@shinshu-u.ac.jp
Kitajima
Shiori
S
Shirai
Koji
K
Kiguchi
Kenji
K
Yamada
Osamu
O
D000327:Adsorption; D017738:Alkanesulfonic Acids / Q000737:chemistry / Q000302:isolation & purification; D002210:Caprylates / Q000737:chemistry / Q000302:isolation & purification; D002516:Ceramics; D002733:Chlorophenols / Q000737:chemistry / Q000302:isolation & purification; D004785:Environmental Pollutants / Q000737:chemistry*; D005466:Fluorocarbons / Q000737:chemistry / Q000302:isolation & purification; D007854:Lead / Q000737:chemistry / Q000302:isolation & purification; D008855:Microscopy, Electron, Scanning; D016062:Porosity; D011208:Powders; D052616:Solid Phase Extraction; D014025:Titanium / Q000737:chemistry*
D017738:Alkanesulfonic Acids; D002210:Caprylates; D002733:Chlorophenols; D004785:Environmental Pollutants; D005466:Fluorocarbons; D011208:Powders; C096521:titanium carbide; D007854:Lead; C023036:perfluorooctanoic acid; C076994:perfluorooctane sulfonic acid; D014025:Titanium; C024564:2,4,6-trichlorophenol