Chiral magnetic metal-organic frameworks of Mn(II) with achiral tetrazolate-based ligands by spontaneous resolution.
The enantiomers of complex 1 (1a and 1b) have been obtained by spontaneous resolution upon crystallization in the absence of a chiral source. The enantiomeric nature of 1a and 1b was confirmed by circular dichroism (CD) spectra and theoretical investigation.
Tong
Xiao-Lan
XL
Department of Chemistry, and Tianjin Key Lab on Metal and Molecule-based Material Chemistry, Nankai University, Tianjin 300071, China.
Hu
Tong-Liang
TL
Zhao
Jiong-Peng
JP
Wang
Yue-Kui
YK
Zhang
Hui
H
Bu
Xian-He
XH