Conjugated Polymers Atypically Prepared in Water.
Processability remains a fundamental issue for the implementation of conducting polymer technology. A simple synthetic route towards processable precursors to conducting polymers (main chain and side chain) was developed using commercially available materials. These soluble precursor systems were converted to conjugated polymers electrochemically in aqueous media, offering a cheaper and greener method of processing. Oxidative conversion in aqueous and organic media each produced equivalent electrochromics. The precursor method enhances the yield of the electrochromic polymer obtained over that of electrodeposition, and it relies on a less corruptible electrolyte bath. However, electrochemical conversion of the precursor polymers often relies on organic salts and solvents. The ability to achieve oxidative conversion in brine offers a less costly and a more environmentally friendly processing step. It is also beneficial for biological applications. The electrochromics obtained herein were evaluated for electronic, spectral, and morphological properties.
Department of Chemistry and the Polymer Program, Institute of Materials Science, University of Connecticut, 97 N. Eagleville Rd., Storrs, CT 06269.
Michael A
MA
Invernale
Samuel A
SA
Pendergraph
Mustafa S
MS
Yavuz
Matthew
M
Ombaba
Gregory A
GA
Sotzing