A new hexenol glycoside from leaves of Smallanthus sonchifolius.
A new hexenol glycoside with two known compounds was isolated from the leaves of Smallanthus sonchifolius. The structure of the new compound was elucidated as Z-hex-3-en-1-ol O-alpha-L-arabinopyransyl (1''-2')-beta-D-glucopyranoside (1) on the basis of spectroscopic analysis and chemical evidence. The two known compounds were identified as ent-15β-hydroxy-kaur-16-en-19-oic acid (2) and ent-18-hydroxy-kaur-16-en-19-oic acid (3) by comparison of their spectral data with the reported data. Compounds 2 and 3 were isolated for the first time from the title plant.
Zheng
Xiang
X
College of Pharmacy, Liaoning University of Traditional Chinese Medicine, Dalian 116600, China.
Kuo
Gai
G
De-Qiang
Dou
D
Gui-Rong
Chen
C
Ting-Guo
Kang
K
Yu-Yuan
Shi
S
Xing-Tai
Li
L
Feng
Dong
D
D000475:Alkenes / Q000737:chemistry / Q000302:isolation & purification*; D019659:Asteraceae / Q000737:chemistry*; D002853:Chromatography, Liquid; D006027:Glycosides / Q000737:chemistry / Q000302:isolation & purification*; D009682:Magnetic Resonance Spectroscopy; D018515:Plant Leaves / Q000737:chemistry*; D021241:Spectrometry, Mass, Electrospray Ionization; D013056:Spectrophotometry, Ultraviolet
D000475:Alkenes; D006027:Glycosides; C117224:1-hexene