Stabilization of 3:1 site-differentiated cubane-type clusters in the [Fe(4)S(4)](1+) core oxidation state by tertiary phosphine ligation: synthesis, core structural diversity, and S = 1/2 ground states.
Deng
Liang
L
Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138, United States.
Majumdar
Amit
A
Lo
Wayne
W
Holm
R H
RH
D018360:Crystallography, X-Ray; D058085:Iron Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010720:Phosphines / Q000138:chemical synthesis / Q000737:chemistry*; D013457:Sulfur Compounds / Q000138:chemical synthesis / Q000737:chemistry*
D058085:Iron Compounds; D010720:Phosphines; D013457:Sulfur Compounds; C044646:phosphine