High-performance single CdS nanowire (nanobelt) Schottky junction solar cells with Au/graphene Schottky electrodes.
High-performance single CdS nanowire (NW) as well as nanobelt (NB) Schottky junction solar cells were fabricated. Au (5 nm)/graphene combined layers were used as the Schottky contact electrodes to the NWs (NBs). Typical as-fabricated NW solar cell shows excellent photovoltaic behavior with an open circuit voltage of ∼0.15 V, a short circuit current of ∼275.0 pA, and an energy conversion efficiency of up to ∼1.65%. The physical mechanism of the combined Schottky electrode was discussed. We attribute the prominent capability of the devices to the high-performance Schottky combined electrode, which has the merits of low series resistance, high transparency, and good Schottky contact to the CdS NW (NB). Besides, a promising site-controllable patterned graphene transfer method, which has the advantages of economizing graphene material and free from additional etching process, was demonstrated in this work. Our results suggest that semiconductor NWs (NBs) are promising materials for novel solar cells, which have potential application in integrated nano-optoelectronic systems.
Yu
Y
Ye
Yu
Y
Dai
Lun
L
Dai
Zujin
Z
Shi
Nan
N
Liu
Fei
F
Wang
Lei
L
Fu
Ruomin
R
Peng
Xiaonan
X
Wen
Zhijian
Z
Chen
Zhongfan
Z
Liu
Guogang
G
Qin
D019187:Cadmium Compounds / Q000737:chemistry*; D011211:Electric Power Supplies; D004566:Electrodes; D004867:Equipment Design; D019544:Equipment Failure Analysis; D006046:Gold / Q000737:chemistry*; D006108:Graphite / Q000737:chemistry*; D008422:Materials Testing; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure; D012666:Semiconductors; D012993:Solar Energy; D013440:Sulfides / Q000737:chemistry*
D019187:Cadmium Compounds; D013440:Sulfides; C034939:cadmium sulfide; D006046:Gold; D006108:Graphite