Polynuclear and mixed-ligand mononuclear Cu(I) complexes with N-thiophosphorylated thioureas and 1,10-phenanthroline or PPh3.
Deprotonation of the N-thiophosphorylated thioureas RC(S)NHP(S)(OiPr)(2) (R = Me(2)N, HL(I); iPrNH, HL(II); 2,6-Me(2)C(6)H(3)NH, HL(III), 2,4,6-Me(3)C(6)H(2)NH, HL(IV), aza-15-crown-5, HL(V)) and reaction with CuI or Cu(NO(3))(2) in aqueous EtOH leads to the polynuclear complexes [Cu(4)(L(I)-S,S')(4)], [Cu(8)(L(II)-S,S')(8)], and [Cu(3)(L(III-V)-S,S')(3)]. The structures of these compounds were investigated by IR, (1)H, (31)P{(1)H} NMR, UV-vis spectroscopy and elemental analyses. The crystal structures of [Cu(4)L(I)(4)], [Cu(8)L(II)(8)], [Cu(3)L(III,IV)(3)] were determined by single-crystal X-ray diffraction. Reaction of the deprotonated ligands (L(I-V))(-) with a mixture of CuI and 1,10-phenanthroline (phen) or PPh(3) leads to the mixed-ligand mononuclear complexes [Cu(phen)L(I-V)], [Cu(PPh(3))L(I-V)] or [Cu(PPh(3))(2)L(I-V)]. The same mixed-ligand complexes were obtained from the reaction of [Cu(4)L(I)(4)], [Cu(8)L(II)(8)], [Cu(3)L(III-V)(3)] with phen or PPh(3).
Institut für Anorganische Chemie, Universität zu Köln, Greinstrasse 6, D-50939, Köln, Germany.
Damir A
DA
Safin
Maria G
MG
Babashkina
Michael
M
Bolte
Tania
T
Pape
F Ekkehardt
FE
Hahn
Maxim L
ML
Verizhnikov
Airat R
AR
Bashirov
Axel
A
Klein
D001372:Aza Compounds / Q000737:chemistry; D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D043844:Crown Ethers / Q000737:chemistry; D018360:Crystallography, X-Ray; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D010618:Phenanthrolines / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013890:Thiourea / Q000737:chemistry*
D001372:Aza Compounds; D056831:Coordination Complexes; D043844:Crown Ethers; D008024:Ligands; D010618:Phenanthrolines; C042148:15-crown-5; D003300:Copper; D013890:Thiourea; C025205:1,10-phenanthroline