Quantum stochastic resonance in parity violating chiral molecules.
In order to explore parity violating effects in chiral molecules, of interest in some models of evolution towards homochirality, quantum stochastic resonance (QSR) is studied for the population difference between the two enantiomers of a chiral molecule (hence for the optical activity of the sample), under low viscous friction and in the deep quantum regime. The molecule is described by a two-state model in an asymmetric double well potential where the asymmetry is given by the known predicted parity violating energy difference (PVED) between enantiomers. In the linear response to an external driving field that lowers and rises alternatively each one of the minima of the well, a signal of QSR is predicted only in the case that the PVED is different from zero, the resonance condition being independent on tunneling between the two enantiomers. It is shown that, at resonance, the fluctuations of the first order contribution to the internal energy are zero. Due to the small value of the PVED, the resonance would occur in the ultracold regime. Some proposals concerning the external driving field are suggested.
Instituto de Física Fundamental (CSIC), Serrano 123, 28006 Madrid, Spain. pbdr@iff.csic.es
Pedro
P
Bargueño
Salvador
S
Miret-Artés
Isabel
I
Gonzalo
D006861:Hydrogen Peroxide / Q000737:chemistry; D006862:Hydrogen Sulfide / Q000737:chemistry; D008956:Models, Chemical; D011789:Quantum Theory; D013237:Stereoisomerism; D013816:Thermodynamics
D006861:Hydrogen Peroxide; D006862:Hydrogen Sulfide