Microwave-assisted, Pd(0)-catalyzed cross-coupling of diazirines with aryl halides.
Pd(0)-catalyzed cross-coupling reactions of diazirines with aryl halides under microwave heating conditions afford a series of substituted olefins. A reaction mechanism involving the migratory insertion of the Pd carbene intermediate is proposed.
Beijing National Laboratory of Molecular Sciences (BNLMS) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.
Xia
X
Zhao
Guojiao
G
Wu
Chong
C
Yan
Kui
K
Lu
Hui
H
Li
Yan
Y
Zhang
Jianbo
J
Wang