Temperature dependent selective gas sorption of the microporous metal-imidazolate framework [Cu(L)] [H2L = 1,4-di(1H-imidazol-4-yl)benzene].
A highly stable copper(II) microporous framework with cylindrical channels constructed from 1,4-di(1H-imidazol-4-yl)benzene (H(2)L) and CuCl(2)·2H(2)O is composed of Cu(II)-imidazolate tubes interconnected by the 1,4-phenylene group of L(2-), and shows temperature dependent selective gas sorption properties.
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, China.
Shui-Sheng
SS
Chen
Min
M
Chen
Satoshi
S
Takamizawa
Man-Sheng
MS
Chen
Zhi
Z
Su
Wei-Yin
WY
Sun
D000042:Absorption; D001562:Benzimidazoles / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D005740:Gases / Q000737:chemistry*; D007093:Imidazoles / Q000737:chemistry*; D016062:Porosity; D013696:Temperature
C557157:1,4-di(1H-imidazol-4-yl)benzene; D001562:Benzimidazoles; D005740:Gases; D007093:Imidazoles; D003300:Copper; C029899:imidazole