Ligand effects in bimetallic high oxidation state palladium systems.
Ligand effects in bimetallic high oxidation state systems containing a X-Pd-Pd-Y framework have been explored with density functional theory (DFT). The ligand X has a strong effect on the dissociation reaction of Y to form [X-Pd-Pd](+) + Y(-). In the model system examined where Y is a weak σ-donor ligand and a good leaving group, we find that dissociation of Y is facilitated by greater σ-donor character of X relative to Y. We find that there is a linear correlation of the Pd-Y and Pd-Pd bond lengths with Pd-Y bond dissociation energy, and with the σ-donating ability of X. These results can be explained by the observation that the Pd d(z(2)) population in the PdY fragment increases as the donor ability of X increases. In these systems, the Pd(III)-Pd(III) arrangement is favored when X is a weak σ-donor ligand, while the Pd(IV)-Pd(II) arrangement is favored when X is a strong σ-donor ligand. Finally, we demonstrate that ligand exchange to form a bimetallic cationic species in which each Pd is six-coordinate should be feasible in a high polarity solvent.
Department of Chemistry, Faculty of Science, Central Tehran Branch, Islamic Azad University, Shahrak Gharb, Tehran, Iran.
Alireza
A
Ariafard
Christopher J T
CJ
Hyland
Allan J
AJ
Canty
Manab
M
Sharma
Nigel J
NJ
Brookes
Brian F
BF
Yates