Design synthesis and photocatalytic activity of a novel lilac-like silver-vanadate hybrid solid based on dicyclic rings of [V4O12]4- with {Ag7}7+ cluster.
An unusual two-dimensional bicyclic [V(4)O(12)](4-)-based coordination polymer with a novel maximum {Ag(7)}(7+) cluster and containing five crystallographically-independent silver atoms was obtained and showed good photocatalytic activity for the degradation of methylene blue.
Key Lab of Polyoxometalate Science of Ministry of Education, Department of Chemistry, Northeast Normal University, Changchun 130024, P. R. China.
Yan
Y
Hu
Fang
F
Luo
Fangfang
F
Dong