A novel approach for the simultaneous determination of iodide, iodate and organo-iodide for 127I and 129I in environmental samples using gas chromatography-mass spectrometry.
In aquatic environments, iodine mainly exists as iodide, iodate, and organic iodine. The high mobility of iodine in aquatic systems has led to (129)I contamination problems at sites where nuclear fuel has been reprocessed, such as the F-area of Savannah River Site. In order to assess the distribution of (129)I and stable (127)I in environmental systems, a sensitive and rapid method was developed which enables determination of isotopic ratios of speciated iodine. Iodide concentrations were quantified using gas chromatography-mass spectrometry (GC-MS) after derivatization to 4-iodo-N,N-dimethylaniline. Iodate concentrations were quantified by measuring the difference of iodide concentrations in the solution before and after reduction by Na(2)S(2)O(5). Total iodine, including inorganic and organic iodine, was determined after conversion to iodate by combustion at 900 °C. Organo-iodine was calculated as the difference between the total iodine and total inorganic iodine (iodide and iodate). The detection limits of iodide-127 and iodate-127 were 0.34 nM and 1.11 nM, respectively, whereas the detection limits for both iodide-129 and iodate-129 was 0.08 nM (i.e., 2pCi (129)I/L). This method was successfully applied to water samples from the contaminated Savannah River Site, South Carolina, and more pristine Galveston Bay, Texas.
Department of Oceanography and Marine Science, Texas A&M University, Galveston, Texas 77551, United States. saijinzhang03@hotmail.com
S
S
Zhang
K A
KA
Schwehr
Y-F
YF
Ho
C
C
Xu
K A
KA
Roberts
D I
DI
Kaplan
R
R
Brinkmeyer
C M
CM
Yeager
P H
PH
Santschi
D004784:Environmental Monitoring / Q000379:methods*; D005618:Fresh Water / Q000737:chemistry; D008401:Gas Chromatography-Mass Spectrometry; D006847:Hydrocarbons, Iodinated / Q000032:analysis; D007452:Iodates / Q000032:analysis*; D007454:Iodides / Q000032:analysis*; D007456:Iodine Isotopes / Q000032:analysis; D007457:Iodine Radioisotopes / Q000032:analysis; D009930:Organic Chemicals; D012987:Soil / Q000737:chemistry; D012989:Soil Pollutants / Q000032:analysis; D013974:Thyroxine / Q000032:analysis; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014875:Water Pollutants, Radioactive / Q000032:analysis
D006847:Hydrocarbons, Iodinated; D007452:Iodates; D007454:Iodides; D007456:Iodine Isotopes; D007457:Iodine Radioisotopes; D009930:Organic Chemicals; D012987:Soil; D012989:Soil Pollutants; D014874:Water Pollutants, Chemical; D014875:Water Pollutants, Radioactive; D013974:Thyroxine