Preparation and properties of hybrid monodispersed magnetic α-Fe2O3 based chitosan nanocomposite film for industrial and biomedical applications.
In this study, hydrothermally prepared magnetic α-Fe2O3 nanoparticles were dispersed in chitosan (CH) solution to fabricate nanocomposite film. X-ray diffraction (XRD) patterns indicated that the α-Fe2O3 nanoparticles were pure α-Fe2O3 with rhombohedral structures, and the fabrication of CH did not result in a phase change. The scanning electron microscopy (SEM) and transmission electron microscope (TEM) results showed that the hexagonal and spherical monodispersed α-Fe2O3 nanoparticles were encapsulated into the spherical dumb shaped CH-α-Fe2O3 nanocomposite film with a mean diameter of ∼87 and ∼110 nm respectively. The α-Fe2O3 nanoparticles and CH-α-Fe2O3 nanocomposite film were also characterized by Fourier transform infrared (FTIR) spectroscopy, thermogravimetric analysis (TGA), differential scanning calorimetry (DSC) and vibrating sample magnetometer (VSM). Magnetic measurements revealed that the saturated magnetization (Ms) and remanent magnetization (Mr) of the pure α-Fe2O3 nanoparticles reached 0.573 emu/g and 0.100 emu/g respectively and the nanoparticles showed the characteristics of weak ferromagnetic before and after coating with CH.
Department of Chemistry, Motilal Nehru National Institute of Technology, Allahabad, Allahabad 211004, India.
Jay
J
Singh
M
M
Srivastava
Joydeep
J
Dutta
P K
PK
Dutta
D001672:Biocompatible Materials / Q000138:chemical synthesis* / Q000737:chemistry; D002152:Calorimetry, Differential Scanning; D048271:Chitosan / Q000737:chemistry*; D005290:Ferric Compounds / Q000737:chemistry*; D007221:Industry; D058185:Magnetite Nanoparticles / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D046529:Microscopy, Electron, Transmission; D053761:Nanocomposites / Q000737:chemistry* / Q000648:ultrastructure; D017550:Spectroscopy, Fourier Transform Infrared; D013818:Thermogravimetry; D014961:X-Ray Diffraction
D001672:Biocompatible Materials; D005290:Ferric Compounds; D058185:Magnetite Nanoparticles; C000499:ferric oxide; D048271:Chitosan