Towards an environmentally-friendly laboratory: dimensionality and reactivity in the mechanosynthesis of metal-organic compounds.
We present a proof-of-principle study of an environmentally-friendly approach to laboratory research, in which the synthesis and structural characterisation of metal-organic complexes and frameworks are achieved without using bulk solvents; our study addresses the use of heteroditopic ligands for manipulating the dimensionality of metal-organic materials and describes how kinetic obstacles in such mechanosynthesis can be overcome.
Laboratory for Physical-Organic Chemistry, Division of Organic Chemistry and Biochemistry, Rudjer Bošković Institute, 10002 Zagreb, Croatia.
Vjekoslav
V
Strukil
László
L
Fábián
David G
DG
Reid
Melinda J
MJ
Duer
Graham J
GJ
Jackson
Mirjana
M
Eckert-Maksić
Tomislav
T
Friščić
D055772:Green Chemistry Technology / Q000379:methods*; D007700:Kinetics; D007753:Laboratories / Q000592:standards*; D008024:Ligands; D009942:Organometallic Compounds / Q000138:chemical synthesis*; D012106:Research
D008024:Ligands; D009942:Organometallic Compounds