First emission studies of Tc2X8(2-) systems (X = Cl, Br).
The emission spectra of the solids [n-Bu(4)N](2)Tc(2)X(8) (X = Cl, Br) have been investigated at room temperature and 77 K. In each case, the emission originates in the (1)δ-δ* excited state, as with the rhenium homologues, but has a shorter lifetime.
Department of Chemistry, Purdue University, West Lafayette, IN 47907-2084, USA.
Breeze N
BN
Briggs
David R
DR
McMillin
Tanya K
TK
Todorova
Laura
L
Gagliardi
Frederic
F
Poineau
Kenneth R
KR
Czerwinski
Alfred P
AP
Sattelberger