Property and reactivity of fluoro(silyl)acetylenes and fluoro(stannyl)acetylenes.
Fluoro(silyl)acetylenes and fluoro(stannyl)acetylenes underwent a radical addition reaction of THF to furnish the corresponding fluorinated cyclic ethers in moderate to good yields. These intriguing addition reaction proved to proceed via a radical reaction mechanism.
Department of Chemistry and Applied Chemistry, Saga University, Honjyo-machi 1, Saga 840-8502, Japan.
Masahiro
M
Shiosaki
Masashi
M
Unno
Takeshi
T
Hanamoto