Single-crystal to single-crystal transformation of 1D coordination polymer via photochemical [2+2] cycloaddition reaction.
Photochemical single-crystal to single-crystal transformation of one 1D polymer [Cd(bpe)(CBA)(2)](n) afforded a new 1D polymer [Cd(rctt-tpcb)(0.5)(CBA)(2)](n) which underwent hydrothermal reaction in strong acidic solution to form a 3D coordination polymer {[Cd(rtct-tpcb)Cl(2)]·2H(2)O}(n).
College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou, Jiangsu, P R China.
Dong
D
Liu
Ni-Ya
NY
Li
Jian-Ping
JP
Lang