Rhodium-catalyzed activation of C(sp3)-X (X = Cl, Br) bond: an intermolecular halogen exchange case.
A RhCl(PPh(3))(3)-catalyzed halogen-exchange reaction between allyl and alkyl halides with β-H atoms was observed. The possible mechanism of the reaction involves oxidative addition and reductive elimination of the C(sp(3))-X bonds, which is not common in organometallic chemistry.
School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China.
Jianping
J
Wang
Xiaofeng
X
Tong
Xiaomin
X
Xie
Zhaoguo
Z
Zhang