Self-induced "electroclick" immobilization of a copper complex onto self-assembled monolayers on a gold electrode.
We report the self-induced "electroclick" immobilization of the [Cu(II)(6-ethynyl-TMPA)(H(2)O)](2+) complex, by its simple electro-reduction, onto a mixed azidoundodecane-/decane-thiol modified gold electrode. The redox response of the grafted [Cu(II/I)(TMPA)] at the modified electrode is fully reversible indicating no Cu coordination change and a fast electron transfer.
Laboratoire de Chimie, Electrochimie Moléculaires et Chimie Analytique, Université de Brest, UMR 6521 CNRS, 29238, Brest, France.
Antoine
A
Gomila
Nicolas
N
Le Poul
Nathalie
N
Cosquer
Jean-Michel
JM
Kerbaol
Jean-Marc
JM
Noël
Madhusudana T
MT
Reddy
Ivan
I
Jabin
Olivia
O
Reinaud
Francoise
F
Conan
Yves
Y
Le Mest
D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004566:Electrodes; D004578:Electron Spin Resonance Spectroscopy; D004579:Electron Transport; D006046:Gold / Q000737:chemistry*; D008968:Molecular Conformation; D010084:Oxidation-Reduction
D056831:Coordination Complexes; D006046:Gold; D003300:Copper