title: Chain stopper engineering for hydrogen bonded supramolecular polymers.
abstract: Supramolecular polymers are linear chains of low molar mass monomers held together by reversible and directional non-covalent interactions, which can form gels or highly viscous solutions if the self-assembled chains are sufficiently long and rigid. The viscosity of these solutions can be controlled by adding monofunctional compounds, which interact with the chain extremities: chain stoppers. We have synthesized new substituted ureas and thioureas and tested them as chain stoppers for a bis-urea based supramolecular polymer. In particular, the bis-thiourea analogue of the bis-urea monomer is shown not to form a supramolecular polymer, but a good chain stopper, because it is a strong hydrogen bond donor and a weak acceptor. Moreover, all substituted ureas tested reduce the viscosity of the supramolecular polymer solutions, but the best chain stopper is obtained when two hydrogen bond acceptors are placed in the same relative position as for the monomer and when no hydrogen bond donor is present.
authors.affiliation: UPMC Université Paris 06, UMR 7610, Chimie des Polymères, F-75005 Paris, France.
authors.forename: Thomas
authors.initials: T
authors.lastname: Pinault
authors.forename: Bruno
authors.initials: B
authors.lastname: Andrioletti
authors.forename: Laurent
authors.initials: L
authors.lastname: Bouteiller