title: Stepwise assembly of two 3d-4d heterometallic coordination polymers based on a hexanuclear silver(I) metalloligand.
abstract: Two novel 3d-4d heterometallic coordination polymers {[Cu(3)(bipy)(3)(H(2)O)(5)][Ag(6)(mna)(6)]·11.5H(2)O}(n) (1) and {[Zn(3)(eda)(3)(H(2)O)(4)][Ag(6)(mna)(6)]·8H(2)O}(n) (2) were synthesized based on a hexanuclear silver(I) metalloligand by a three-step synthetic method (bipy = 2, 2'-bipyridine, eda = ethylenediamine and H(2)mna = 2-mercaptonicotinic acid). The photoluminescence behaviors of 1 and 2 were also discussed.
authors.affiliation: Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
authors.forename: Di
authors.initials: D
authors.lastname: Sun
authors.forename: Dan-Feng
authors.initials: DF
authors.lastname: Wang
authors.forename: Xi-Guang
authors.initials: XG
authors.lastname: Han
authors.forename: Na
authors.initials: N
authors.lastname: Zhang
authors.forename: Rong-Bin
authors.initials: RB
authors.lastname: Huang
authors.forename: Lan-Sun
authors.initials: LS
authors.lastname: Zheng