title: High heat of hydrogen adsorption and guest-responsive magnetic modulation in a 3D porous pillared-layer coordination framework.
abstract: A bimetallic pillared-layer coordination framework {[Mn(3)(bipy)(3)(H(2)O)(4)][Cr(CN)(6)](2)·2(bipy)·4(H(2)O)}(n) has been constructed using a cyanometallate anion ([Cr(CN)(6)](3-)) and an organic linker (4,4'-bipyridyl) that provides high heat of hydrogen adsorption (∼11.5 kJ mol(-1)) and shows guest dependent magnetic modulation.
authors.affiliation: Molecular Materials Laboratory, Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560 064, India.
authors.forename: Arpan
authors.initials: A
authors.lastname: Hazra
authors.forename: Prakash
authors.initials: P
authors.lastname: Kanoo
authors.forename: Tapas Kumar
authors.initials: TK
authors.lastname: Maji
mesh_terms: D000327:Adsorption; D006358:Hot Temperature; D006859:Hydrogen / Q000737:chemistry*; D008280:Magnetics; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D016062:Porosity; D013499:Surface Properties
chemical_list: D009942:Organometallic Compounds; D006859:Hydrogen