title: Multielectron redox reactions involving C-C coupling and cleavage in uranium Schiff base complexes.
abstract: The reaction of U(III) with Schiff base ligands and the reduction of U(IV) Schiff base complexes both promote C-C bond formation to afford dinuclear or mononuclear U(IV) amido complexes, which can release up to four electrons to substrates through the oxidative cleavage of the C-C bond.
authors.affiliation: Laboratoire de Reconnaissance Ionique et Chimie de Coordination, Service de Chimie Inorganique et Biologique, UMR E-3 CEA/UJF, FRE3200 CNRS, CEA-Grenoble, INAC, 17 rue des Martyrs, 38054 Grenoble cedex 9, France.
authors.forename: Clément
authors.initials: C
authors.lastname: Camp
authors.forename: Victor
authors.initials: V
authors.lastname: Mougel
authors.forename: Pawel
authors.initials: P
authors.lastname: Horeglad
authors.forename: Jacques
authors.initials: J
authors.lastname: Pécaut
authors.forename: Marinella
authors.initials: M
authors.lastname: Mazzanti
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D004583:Electrons; D008958:Models, Molecular; D010084:Oxidation-Reduction; D012545:Schiff Bases / Q000737:chemistry*; D014501:Uranium / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D012545:Schiff Bases; D014501:Uranium