title: Scandium alkyl complex with phosphinimino-amine ligand: synthesis, structure and catalysis on ethylene polymerization.
abstract: The THF-free scandium dialkyl complex LSc(CH(2)SiMe(3))(2) (L = (2,6-iPr(2)C(6)H(3))NC(Me)CHPPh(2)N(2,6-Me(2)C(6)H(3))) bearing the phosphinimino-amine ligand was prepared, which under the activation of [Ph(3)C][B(C(6)F(5))(4)] initiated the polymerization of ethylene with high activity.
authors.affiliation: State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, China.
authors.forename: Danfeng
authors.initials: D
authors.lastname: Li
authors.forename: Shihui
authors.initials: S
authors.lastname: Li
authors.forename: Dongmei
authors.initials: D
authors.lastname: Cui
authors.forename: Xuequan
authors.initials: X
authors.lastname: Zhang
authors.forename: Alexander A
authors.initials: AA
authors.lastname: Trifonov