title: A tailor-made ligand to mimic the active site of diiron enzymes: an air-oxidized high-valent Fe(III) h.s.(μ-O)2Fe(IV) h.s. species.
abstract: The design and first application of a new dinucleating ligand system to mimic high-valent oxidation states of O(2)-dependent diiron enzymes is presented.
authors.affiliation: Lehrstuhl für Anorganische Chemie I, Fakultät für Chemie, Universität Bielefeld, Universitätsstr. 25, D-33615 Bielefeld, Germany.
authors.forename: Julia B H
authors.initials: JB
authors.lastname: Strautmann
authors.forename: Stephan
authors.initials: S
authors.lastname: Walleck
authors.forename: Hartmut
authors.initials: H
authors.lastname: Bögge
authors.forename: Anja
authors.initials: A
authors.lastname: Stammler
authors.forename: Thorsten
authors.initials: T
authors.lastname: Glaser
mesh_terms: D040761:Biomimetic Materials / Q000737:chemistry; D020134:Catalytic Domain; D056831:Coordination Complexes / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007501:Iron / Q000737:chemistry*; D008024:Ligands; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry; D010105:Oxygenases / Q000737:chemistry* / Q000378:metabolism; D015204:Spectroscopy, Mossbauer
chemical_list: D056831:Coordination Complexes; D008024:Ligands; D007501:Iron; D010105:Oxygenases; C021555:methane monooxygenase; D010100:Oxygen