title: Determination of polymer electrolyte membrane (PEM) degradation products in fuel cell water using electrospray ionization tandem mass spectrometry.
abstract: Within the scope of research of membrane degradation phenomena during fuel cell operation a reliable analytical procedure for the extraction, detection and quantification of possible membrane oxidation products has been developed. These oxidation products originate from the attack of hydroxyl or peroxyl radicals on the membrane polymer. Such radicals are formed in situ (during fuel cell operation) or ex situ (Fenton test as oxidative stress simulation). The analysis of membrane oxidation products was carried out by electrospray ionization tandem mass spectrometry. Five potential membrane oxidation products (4-hydroxybenzoic acid (4-HBA), 4-hydroxybenzaldehyde (4-HBAD), 4,4-biphenol (4,4-BP), 4-hydroxybenzenesulfonate (4-HBS), and 4,4-sulfonylbiphenol (4,4-SBP)) were selected based on the molecular structure of the sulfonated polyarylether membrane used. In conjunction with the development of a multiple reaction monitoring (MRM) method, the ionization and fragmentation of the selected compounds were investigated. For 4,4-BP a molecular ion (M(+•) ) was observed in the positive ionization mode and used for MRM method development. Reproducible extraction of the model compounds was achieved using a mixed-mode sorbent material with both weak anion-exchange and reversed-phase retention properties. By using the developed analytical procedure, the identities of two membrane degradation products (4-HBA and 4-HBAD) were determined in situ and ex situ. In addition to the investigation of membrane degradation phenomena, the combination of extraction on a mixed-mode sorbent material and tandem mass spectrometric detection is attractive for the analysis of aromatic sulfonic acids, phenolic acids and phenols.
authors.affiliation: Institut für Energie- und Umwelttechnik e.V., IUTA (Institute of Energy and Environmental Technology), Bliersheimer Str. 60, D-47229 Duisburg, Germany.
authors.forename: Marco
authors.initials: M
authors.lastname: Zedda
authors.forename: Jochen
authors.initials: J
authors.lastname: Tuerk
authors.forename: Stefan
authors.initials: S
authors.lastname: Peil
authors.forename: Torsten C
authors.initials: TC
authors.lastname: Schmidt