title: Microporous sensor: gas sorption, guest exchange and guest-dependant luminescence of metal-organic framework.
abstract: Zn(II)-containing metal-organic framework (MOF) [Zn(4)(dmf)(ur)(2)(ndc)(4)] (ndc(2-) = 2,6-naphtalenedicarboxylate, ur = urotropin, dmf = N,N'-dimethylformamide) was synthesized and characterized by X-ray crystallography and gas sorption analysis. Host MOF retains its crystallinity after guest removal and exchange. Single-crystal to single-crystal formation of different host-guest systems with benzene and ferrocene was investigated. Interesting guest-depended luminescence properties of the porous host framework were observed.
authors.affiliation: Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russian Federation.
authors.forename: Sergey A
authors.initials: SA
authors.lastname: Sapchenko
authors.forename: Denis G
authors.initials: DG
authors.lastname: Samsonenko
authors.forename: Danil N
authors.initials: DN
authors.lastname: Dybtsev
authors.forename: Maxim S
authors.initials: MS
authors.lastname: Melgunov
authors.forename: Vladimir P
authors.initials: VP
authors.lastname: Fedin