title: Chlorophene degradation by combined ultraviolet irradiation and ozonation.
abstract: Ozonation combined with UV irradiation (UV/O(3)) is an advanced oxidation technique that is very promising for the destruction of organic compounds in aqueous solution. In this study, chlorophene was chosen as a model substrate to investigate the effects of pH, initial substrate concentration, ozone dose, and UV light intensity in degradation experiments. The pseudo-first-order rate constant for total organic carbon (TOC) removal was 2.4 × 10(-2), 9.8 × 10(-4), and 6.4 × 10(-2) min(-1) for O(3), UV, and UV/O(3) treatment, respectively. Clearly, UV-enhanced ozonation leads to a synergetic increase in the overall degradation efficiency. Comparative experiments were performed to investigate the effect of the matrix (distilled water or sewage) on chlorophene removal. The organic compounds in sewage retarded the rate of chlorophene removal by 38%, probably by competitively reacting with the oxidizing agent and screening light. The compound 2-benzoylbenzo-1,4-quinone, benzo-1,4-quinone, hydroquinone and maleic acid were identified as primary intermediates by gas chromatography-mass spectrometry. The concentrations of acetic, formic and oxalic anions were detected by ion chromatography. A possible degradation pathway is proposed on the basis of the reaction products identified.
authors.affiliation: College of Biological and Environmental Engineering, Zhejiang University of Technology, Hangzhou, People's Republic of China.
authors.forename: Zhiqiao
authors.initials: Z
authors.lastname: He
authors.forename: Angliang
authors.initials: A
authors.lastname: Zhang
authors.forename: Yu
authors.initials: Y
authors.lastname: Li
authors.forename: Shuang
authors.initials: S
authors.lastname: Song
authors.forename: Zhiwu
authors.initials: Z
authors.lastname: Liu
authors.forename: Jianmeng
authors.initials: J
authors.lastname: Chen
authors.forename: Xinhua
authors.initials: X
authors.lastname: Xu
mesh_terms: D004003:Dichlorophen / Q000031:analogs & derivatives* / Q000737:chemistry / Q000528:radiation effects; D010126:Ozone / Q000737:chemistry*; D014466:Ultraviolet Rays
chemical_list: D010126:Ozone; C004660:clorophene; D004003:Dichlorophen