An unprecedented 2D → 3D metal-organic polyrotaxane framework constructed from cadmium and a flexible star-like ligand.
An unprecedented 2D → 3D metal-organic polyrotaxane framework, based on a new star-like tri(4-imidazolylphenyl)amine ligand, has been synthesized and characterized, which represents the first example of 2D → 3D polyrotaxane entangled in a parallel fashion.
Key Lab of Polyoxometalate Science, Department of Chemistry, Northeast Normal University, Changchun 130024, People's Republic of China.
Hua
H
Wu
Hai-Yan
HY
Liu
Ying-Ying
YY
Liu
Jin
J
Yang
Bo
B
Liu
Jian-Fang
JF
Ma
D000814:Aniline Compounds / Q000737:chemistry; D002104:Cadmium / Q000737:chemistry*; D003505:Cyclodextrins / Q000737:chemistry*; D007093:Imidazoles / Q000737:chemistry; D008024:Ligands; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000032:analysis* / Q000138:chemical synthesis / Q000737:chemistry; D020442:Poloxamer / Q000737:chemistry*; D043862:Rotaxanes / Q000737:chemistry*
D000814:Aniline Compounds; D003505:Cyclodextrins; D007093:Imidazoles; D008024:Ligands; D009942:Organometallic Compounds; D043862:Rotaxanes; C475673:polyrotaxane; D002104:Cadmium; D020442:Poloxamer