On the origin of the cation templated self-assembly of uranyl-peroxide nanoclusters.
Uranyl-peroxide nanoclusters display different topologies based on square, pentagonal and hexagonal building blocks. Computed complexation energies of different cations (Li(+), Na(+), K(+), Rb(+), and Cs(+)) with [UO(2)(O(2))(H(2)O)](n) (n = 4, 5, and 6) macrocycles suggest a strong cation templating effect. The inherent bent structure of a U-O(2)-U model dimer is demonstrated and justified through the analysis of its electronic structure, as well as of the inherent curvature of the four-, five-, and six-uranyl macrocyles. The curvature is enhaced by cation coordination, which is suggested to be the driving force for the self-assembly of the nanocapsules.
Institute of Chemical Research of Catalonia, ICIQ, Avda. Països Catalans 16, 43007 Tarragona, Spain.
Pere
P
Miró
Simon
S
Pierrefixe
Mickaël
M
Gicquel
Adrià
A
Gil
Carles
C
Bo