Monomer-on-monomer (MoM) Mitsunobu reaction: facile purification utilizing surface-initiated sequestration.
A monomer-on-monomer (MoM) Mitsunobu reaction utilizing norbornenyl-tagged (Nb-tagged) reagents is reported, whereby purification was rapidly achieved by employing ring-opening metathesis polymerization, which was initiated by any of three methods utilizing Grubbs catalyst: (i) free catalyst in solution, (ii) surface-initiated catalyst-armed silica, or (iii) surface-initiated catalyst-armed Co/C magnetic nanoparticles.
Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, Kansas 66045, United States.
Pradip K
PK
Maity
Alan
A
Rolfe
Thiwanka B
TB
Samarakoon
Saqib
S
Faisal
Ryan D
RD
Kurtz
Toby R
TR
Long
Alexander
A
Schätz
Daniel L
DL
Flynn
Robert N
RN
Grass
Wendelin J
WJ
Stark
Oliver
O
Reiser
Paul R
PR
Hanson
D008280:Magnetics; D053768:Metal Nanoparticles / Q000737:chemistry; D011108:Polymers / Q000138:chemical synthesis*
D011108:Polymers