An effective and catalytic oxidation using recyclable fluorous IBX.
Oxidation of alcohols in the presence of a catalytic amount of fluorous IBX and Oxone as a co-oxidant resulted in the corresponding carbonyl compounds in good to high yields. The fluorous IBX is readily recovered as insoluble fluorous IBA from the reaction mixture by simple filtration, and can be reused without significant loss of the catalytic activity.
Gifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, Japan. miura@gifu-pu.ac.jp
Tsuyoshi
T
Miura
Kosuke
K
Nakashima
Norihiro
N
Tada
Akichika
A
Itoh
D002384:Catalysis; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D007462:Iodobenzenes / Q000737:chemistry*; D008956:Models, Chemical; D016877:Oxidants / Q000737:chemistry; D010084:Oxidation-Reduction; D059027:Recycling; D012995:Solubility; D012997:Solvents / Q000737:chemistry; D013464:Sulfuric Acids / Q000737:chemistry
D006845:Hydrocarbons, Fluorinated; D007462:Iodobenzenes; D016877:Oxidants; D012997:Solvents; D013464:Sulfuric Acids; C476101:o-iodoxybenzoic acid; C048813:potassium peroxymonosulfuric acid