Characterization of an unprecedented organomercury adduct via Hg(II)-mediated cyclization of N9-propargylguanine.
This communication describes mercury(II)-mediated cyclization of N9-propargylguanine under hydrothermal conditions. The structural investigations reported here confirm cyclization and reveal simultaneous formation of a unique organomercury adduct of a tricyclic guanine derivative.
Department of Chemistry, Indian Institute of Technology Kanpur, Kanpur 208016 (UP), India.
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Nagapradeep
Sandeep
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Verma
D002413:Cations, Divalent / Q000737:chemistry; D018360:Crystallography, X-Ray; D003500:Cyclization; D006147:Guanine / Q000031:analogs & derivatives / Q000737:chemistry*; D006860:Hydrogen Bonding; D008628:Mercury / Q000737:chemistry*; D015394:Molecular Structure; D009941:Organomercury Compounds / Q000737:chemistry*
D002413:Cations, Divalent; D009941:Organomercury Compounds; D006147:Guanine; D008628:Mercury