From metal-organic squares to porous zeolite-like supramolecular assemblies.
We report the synthesis, structure, and characterization of two novel porous zeolite-like supramolecular assemblies, ZSA-1 and ZSA-2, having zeolite gis and rho topologies, respectively. The two compounds were assembled from functional metal-organic squares (MOSs) via directional hydrogen-bonding interactions and exhibited permanent microporosity and thermal stability up to 300 °C.
State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, P. R. China.
Shuang
S
Wang
Tingting
T
Zhao
Guanghua
G
Li
Lukasz
L
Wojtas
Qisheng
Q
Huo
Mohamed
M
Eddaoudi
Yunling
Y
Liu