Effect of repeated steam hydration reactivation on CaO-based sorbents for CO2 capture.
Samples of natural limestone and commercial calcium carbonate were subjected to successive calcination and carbonation reactions in a TGA and to repeated activity restoration by steam hydration. Steam hydration of spent lime, followed by heating in CO(2), was shown to be an effective method for repeatedly restoring high CO(2) capture activity to spent lime during a large number of CO(2) capture cycles. Steam hydration was also shown to reduce the decay rate of the CO(2) capture activity by increasing the rate of carbonation in the diffusion controlled regime. Repeated hydration-carbonation-calcination cycles led to a considerable expansion of the particles through the formation of large vesicles, likely to lead to high attrition levels when applied in fluidized beds. Based on SEM observation of the particles during hydration-carbonation-calcination cycling, a model was proposed for their progressive weakening. It was concluded that strategies to reduce this weakening must limit the growth of the cracks in the crystal as they are cycled repeatedly.
Industrial Research Limited, 69 Gracefield Road, Seaview, Lower Hutt, New Zealand. v.materic@irl.cri.nz
By Vlatko
BV
Materić
Carolyn
C
Sheppard
Stuart I
SI
Smedley
D000327:Adsorption; D000397:Air Pollution / Q000517:prevention & control; D002119:Calcium Carbonate / Q000737:chemistry; D017610:Calcium Compounds / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry*; D052918:Environmental Restoration and Remediation / Q000379:methods*; D008855:Microscopy, Electron, Scanning; D010087:Oxides / Q000737:chemistry*; D013227:Steam; D013818:Thermogravimetry
D017610:Calcium Compounds; D010087:Oxides; D013227:Steam; D002245:Carbon Dioxide; C016538:lime; D002119:Calcium Carbonate