Further studies on vinamidinium salt amine exchange reactions, borohydride reductions and subsequent transformations.
Studies directed at the amine exchange reaction of vinamidinium salts followed by sodium borohydride reduction to secondary and tertiary allylic amines are described. The tertiary allylic amines were alkylated and subjected to base mediated rearrangement to yield a variety of highly functionalized tertiary homoallylic amines.
Department of Chemistry, University of Richmond, Richmond, VA 23173, USA.
John T
JT
Gupton
Nakul
N
Telang
Xin
X
Jia
Benjamin C
BC
Giglio
James E
JE
Eaton
Peter J
PJ
Barelli
Mona
M
Hovaizi
Kayleigh E
KE
Hall
R Scott
RS
Welden
Matthew J
MJ
Keough
Eric F
EF
Worrall
Kara L
KL
Finzel
Emily J
EJ
Kluball
Rene P F
RP
Kanters
Timothy M
TM
Smith
Stanton Q
SQ
Smith
Shane R
SR
Nunes
Mathew T
MT
Wright
Jennifer M
JM
Birnstihl