Technological behaviour and recycling potential of spent foundry sands in clay bricks.
The feasibility of recycling spent foundry sand in clay bricks was assessed in laboratory, pilot line and industrial trials, using naturally occurring sand as a reference. Raw materials were analyzed by X-ray fluorescence, X-ray diffraction, particle size distribution, and leaching and combined to produce bodies containing up to 35% wt. sand. The extrusion, drying and firing behaviour (plasticity, drying sensitivity, mechanical strength, bulk density, water absorption, and shrinkage) were determined. The microstructure, phase composition, durability and leaching (EN 12457, granular materials, end-life step, European Waste Landfill Directive; NEN 7345, monolithic materials, use-life step, Dutch Building Material Decree) were evaluated for bricks manufactured at optimal firing temperature. These results demonstrate that spent foundry sand can be recycled in clay bricks. There are no relevant technological drawbacks, but the feasibility strongly depends on the properties of the raw materials. Spent foundry sand may be introduced into bricks up to 30% wt. Most of the hazardous elements from the spent foundry sand are inertized during firing and the concentrations of hazardous components in the leachates are below the standard threshold for inert waste category landfill excepting for chromium and lead; however, their environmental risk during their use-life step can be considered negligible.
Department of Chemical Engineering and Inorganic Chemistry, University of Cantabria, Avda. Los Castros s/n, 39005 Santander, Spain. alonsor@unican.es
R
R
Alonso-Santurde
A
A
Andrés
J R
JR
Viguri
M
M
Raimondo
G
G
Guarini
C
C
Zanelli
M
M
Dondi
D000042:Absorption; D000538:Aluminum Silicates; D000077215:Clay; D059027:Recycling; D012822:Silicon Dioxide; D013030:Spain; D014867:Water
D000538:Aluminum Silicates; D014867:Water; D012822:Silicon Dioxide; D000077215:Clay