Transesterification of palm oil to methyl ester on activated carbon supported calcium oxide catalyst.
In this study, methyl ester (ME) was produced by transesterification of palm oil (CPO) (cooking grade) using activated carbon supported calcium oxide as a solid base catalyst (CaO/AC). Response surface methodology (RSM) based on central composite design (CCD) was used to optimize the effect of reaction time, molar ratio of methanol to oil, reaction temperature and catalyst amount on the transesterification process. The optimum condition for CPO transesterification to methyl ester was obtained at 5.5 wt.% catalyst amount, 190°C temperature, 15:1 methanol to oil molar ratio and 1 h 21 min reaction time. At the optimum condition, the ME content was 80.98%, which is well within the predicted value of the model. Catalyst regeneration studies indicate that the catalyst performance is sustained after two cycles.
School of Chemical Engineering, Universiti Sains Malaysia, Nibong Tebal, Penang, Malaysia.
Zuraida
Z
Wan
B H
BH
Hameed
D000327:Adsorption; D017610:Calcium Compounds / Q000737:chemistry*; D002384:Catalysis; D002606:Charcoal / Q000737:chemistry*; D004951:Esterification; D004952:Esters / Q000138:chemical synthesis*; D010087:Oxides / Q000737:chemistry*; D000073878:Palm Oil; D010938:Plant Oils / Q000737:chemistry*
D017610:Calcium Compounds; D004952:Esters; D010087:Oxides; D010938:Plant Oils; D002606:Charcoal; D000073878:Palm Oil; C016538:lime