Diethynylbenzene-based liquid crystalline semiconductor for solution-processable organic thin-film transistors.
We report here the synthesis and characterization of novel diethynylbenzene-based liquid crystalline semiconductor (P1) for organic thin-film transistors (OTFTs). Compound P1 was synthesized by the Sonogashira coupling reaction between 2-bromo-5-(4-hexylthiophen-2-yl)thieno[3,2-b]thiophene and 1,4-bis(dodecyloxy)-2,5-diethynylbenzene. Top contact OTFTs were fabricated by spin casting with 2 wt% solution of P1 in chloroform and their best performance, which exhibited a hole mobility of 4.5 x 10(-5) cm2/Vs, was showed after annealing of the films at liquid crystalline temperature. Time-of-flight (TOF) mobility measured at liquid crystalline phase was observed to be 1.5 x 10(-6) cm2/Vs for both positive and negative carriers. These results indicate that the liquid crystallinity helps to improve the molecular packing and enhance charge mobility for P1. These advantages can be applicable to design and construct solution-processable OTFT materials for electronic applications.
Department of Advanced Materials, Hannam University, Daejeon 305-701, Korea.
Pramod Kandoth
PK
Madathil
Benoît
B
Heinrich
Bertrand
B
Donnio
Fabrice
F
Mathevet
Jean-Louis
JL
Fave
Daniel
D
Guillon
Andre-Jean
AJ
Attias
Changjin
C
Lee
Tae-Dong
TD
Kim
Kwang-Sup
KS
Lee