Bis[S-benzyl-3-(4-n-octyloxybenzylidene)dithiocarbazato-κ(2)N(3),S']palladium(II).
In the title compound, [Pd(C(23)H(29)N(2)OS(2))(2)], the Pd(II) atom displays the expected square-planar coordination geometry. However, the trans configuration, which allows the Pd(II) atom to be located on a crystallographic inversion centre, is unusual with respect to the cis arrangement found in analogous Pd complexes comprising similar N,S-chelating ligands.
Department of Chemistry, Rajshahi University, Rajshahi 6205, Bangladesh.
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Tarafder
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Islam
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Howlader
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Guidolin
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Zangrando
D002614:Chelating Agents / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*
D002614:Chelating Agents; D008024:Ligands; D009942:Organometallic Compounds; C554872:bis(S-benzyl-3-(4-n-octyloxybenzylidene)dithiocarbazato-kappa(2)N(3),S')palladium(II); D010165:Palladium