Synthesis of sugar-derived spiroaminals via lactamization and metathesis reactions.
A series of sugar-derived spiroaminals has been synthesized by utilizing cross metathesis, ring closing metathesis and lactamization reactions as key steps from 1-C-alkylated glycosyl azides and important correlations in the spectral data between spiroaminals and their respective anomers are reported.
Department of Chemistry, Indian Institute of Technology, Kanpur, 208 016, India.
Adabala Pal
AP
John Pal
Parasuraman
P
Kadigachalam
Asadulla
A
Mallick
Venkata Ramana
VR
Doddi
Yashwant D
YD
Vankar
D002241:Carbohydrates / Q000737:chemistry*; D003500:Cyclization; D007769:Lactams / Q000737:chemistry*; D015394:Molecular Structure; D013141:Spiro Compounds / Q000138:chemical synthesis*
D002241:Carbohydrates; D007769:Lactams; D013141:Spiro Compounds