Hexakis(adamantyltrimethylammonium) cyclooctasilicate tetratetracontahydrate.
The title compound, 6C(13)H(24)N(+)·H(2)Si(8)O(20)(6-)·44H(2)O, belongs to the class of cyclosilicate hydrates, which structurally can be positioned between the zeosils and the clathrate hydrates. [Si(8)O(18)(OH)(2)] cubes carrying six negative charges are located on crystallographic inversion centres and are surrounded by six adamantyltrimethylammonium cations.
Centre for Surface Chemistry and Catalysis, Katholieke Universiteit Leuven, Kasteelpark Arenberg 23, B-3001 Leuven, Belgium.
Pieter L H
PL
Verlooy
Koen
K
Robeyns
Luc
L
Van Meervelt
Christine E A
CE
Kirschhock
Johan A
JA
Martens
D000838:Anions / Q000737:chemistry*; D002412:Cations / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008958:Models, Molecular; D015394:Molecular Structure; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*; D017640:Silicates / Q000737:chemistry*
D000838:Anions; D002412:Cations; D000644:Quaternary Ammonium Compounds; D017640:Silicates; C554918:hexakis(adamantyltrimethylammonium) cyclooctasilicate tetratetracontahydrate