Three-dimensional hydrogen-bonded structures in the guanidinium salts of the monocyclic dicarboxylic acids rac-trans-cyclohexane-1,2-dicarboxylic acid (2:1, anhydrous), isophthalic acid (1:1, monohydrate) and terephthalic acid (2:1, trihydrate).
The structures of bis(guanidinium) rac-trans-cyclohexane-1,2-dicarboxylate, 2CH(6)N(3)(+)·C(8)H(10)O(4)(2-), (I), guanidinium 3-carboxybenzoate monohydrate, CH(6)N(3)(+)·C(8)H(5)O(4)(-)·H(2)O, (II), and bis(guanidinium) benzene-1,4-dicarboxylate trihydrate, 2CH(6)N(3)(+)·C(8)H(4)O(4)(2-)·3H(2)O, (III), all reveal three-dimensional hydrogen-bonded framework structures. In anhydrous (I), both guanidinium cations form classic cyclic R(2)(2)(8) N-H...O,O'(carboxylate) and asymmetric cyclic R(2)(1)(6) hydrogen-bonding interactions, while one cation forms an unusual enlarged cyclic interaction with O-atom acceptors of separate ortho-related carboxylate groups [graph set R(2)(2)(11)]. Cations and anions also associate across inversion centres, giving cyclic R(4)(2)(8) motifs. In the 1:1 guanidinium salt, (II), the cation forms two separate cyclic R(2)(1)(6) interactions, one with a carboxyl O-atom acceptor and the other with the solvent water molecule. The structure is unusual in that both carboxyl groups form short interanion O...H...O contacts, one across a crystallographic inversion centre [O...O = 2.483 (2) Å] and the other about a twofold axis of rotation [O...O = 2.462 (2) Å], representing shared sites on these elements for the single acid H atom. The water molecule links the cation-anion ribbon structures into a three-dimensional framework. In (III), the repeating molecular unit comprises a benzene-1,4-dicarboxylate dianion which lies across a crystallographic inversion centre, two guanidinium cations and two solvent water molecules (each set related by twofold rotational symmetry), and a single water molecule which lies on a twofold axis. Each guanidinium cation forms three types of cyclic interaction with the dianions: one R(2)(1)(6), the others R(3)(2)(8) and R(3)(3)(10) (both of these involving the water molecules), giving a three-dimensional structure through bridges down the b-cell direction. The water molecule at the general site also forms an unusual cyclic R(2)(2)(4) homodimeric association across an inversion centre [O...O = 2.875 (2) Å]. The work described here provides further examples of the common cyclic guanidinium-carboxylate hydrogen-bonding associations, as well as featuring other less common cyclic motifs.
Faculty of Science and Technology, Queensland University of Technology, GPO Box 2434, Brisbane, Queensland 4001, Australia. g.smith@qut.edu.au
Graham
G
Smith
Urs D
UD
Wermuth
D018360:Crystallography, X-Ray; D003510:Cyclohexanes / Q000737:chemistry*; D003998:Dicarboxylic Acids / Q000737:chemistry*; D019791:Guanidine / Q000737:chemistry*; D006860:Hydrogen Bonding; D008968:Molecular Conformation; D015394:Molecular Structure; D010795:Phthalic Acids / Q000737:chemistry*; D012492:Salts / Q000737:chemistry; D012997:Solvents / Q000737:chemistry; D014867:Water / Q000737:chemistry
D003510:Cyclohexanes; D003998:Dicarboxylic Acids; D010795:Phthalic Acids; D012492:Salts; D012997:Solvents; D014867:Water; C059768:isophthalate; C506365:Cyclohexane; D019791:Guanidine