Orthogonal spin arrangement in quasi-two-dimensional La2Co2O3Se2.
The crystal, electronic, and magnetic structures of the cobalt oxyselenide La(2)Co(2)O(3)Se(2) were investigated through powder neutron diffraction measurements and band structure calculations. This oxyselenide crystallizes in a tetragonal layered structure with space group I4/mmm. The Co ion is sixfold-coordinated by two oxide ions and four selenide ions, and the face-sharing CoO(2)Se(4) octahedra form Co(2)OSe(2) layers. The band structure calculations revealed that the Co ion is in the divalent high-spin state. Rietveld analysis of the neutron diffraction profiles below 200 K demonstrated that the Co moments have a noncollinear antiferromagnetic structure with the propagation vector k = (½, ½, 0). The ordered magnetic moment was determined to be 3.5 μ(B) at 10 K, and the directions of the nearest-neighbor Co moments are orthogonal each other in the c plane.
Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo 060-0810, Japan.
Yayoi
Y
Fuwa
Takashi
T
Endo
Makoto
M
Wakeshima
Yukio
Y
Hinatsu
Kenji
K
Ohoyama