Opaline backreflector coating in dye-sensitized solar cell.
Photonic crystals are ordered nanostructures that are designed to manipulate the propagation of light. The periodicity of a photonic crystal can be engineered to be highly reflective at selected wavelengths. In this work, a mono-layer and double-layer colloidal photonic crystal film were self-assembled on a glass substrate to be used as backreflectors in a dye-sensitized solar cell (DSSC). The colloidal photonic crystal film consists of different polystyrene monodispersed particles with sizes between 200 nm and 290 nm. Making use of flow controlled vertical deposition (FCVD) method, opaline films of Bragg's reflection wavelength between 450 nm to 750 nm were achieved. These wavelengths were designed to match the absorption spectrum of the Ruthenium-complex dye used in DSSC. An enhancement in incident photon-to-current conversion efficiency (IPCE) of the opaline backreflector DSSC of about 30% at Bragg's peak wavelength has been achieved.
School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798.
Lia Agustine
LA
Herman
Chan Hoe
CH
Yip
Chee Cheong
CC
Wong