Controlled light emission in spin-assisted layer-by-layer assemblies with fluorophores.
We report controlled light emissions from spin-assisted layer-by-layer (LbL) thin films containing a donor-acceptor pair of fluorescent dyes. Based on their spectral overlap, we selected rhodamine 123 (R123) and rhodamine B (RB) as the donor and acceptor, respectively. For the construction of multilayered thin films, a complex of each dye and poly(sodium 4-sulfonate) (PSS-R123 and PSS-RB) was prepared and then alternately spin coated with poly(allyamine hydrochloride) (PAH). LbL assemblies were fabricated with a sequence of [PAH/PSS-RB]/([PAH/PSS])n/[PAH/PSS-R123]. Since the distance between R123 and RB was precisely adjusted by the number of bilayers (n) of [PAH/PSS] between them, we were able to tune the light emission from the thin film by controlling the efficiency of the energy transfer.
Department of Chemistry, NANO System Institute, Seoul National University, Seoul 151-747, Korea.
Ki-Se
KS
Kim
Seong Il
SI
Yoo
Taek Seung
TS
Lee
Byeong-Hyeok
BH
Sohn