Palladium-catalysed direct arylation of thiophenes tolerant to silyl groups.
The palladium catalysed 5-arylation of 2-(trimethylsilyl)thiophene with aryl bromides via C-H bond functionalisation allows the synthesis of arylated silylthiophenes in only one step.
Institut Sciences Chimiques de Rennes, UMR 6226 CNRS-Université de Rennes Catalyse et Organométalliques, 35042 Rennes, France.
Lu
L
Chen
Julien
J
Roger
Christian
C
Bruneau
Pierre H
PH
Dixneuf
Henri
H
Doucet