title: Facile synthesis of TiO2 inverse opal electrodes for dye-sensitized solar cells.
abstract: Engineering of TiO(2) electrode layers is critical to guaranteeing the photoconversion efficiency of dye-sensitized solar cells (DSSCs). Recently, a novel approach has been introduced for producing TiO(2) electrodes using the inverted structures of colloidal crystals. This paper describes a facile route to producing ordered macroporous electrodes from colloidal crystal templates for DSSCs. Using concentrated colloids dispersed in a volatile medium, the colloidal crystal templates were obtained within a few minutes, and the thickness of the template was easily controlled by changing the quantity of colloidal solution deposited. Here, the effects of the structural properties of the inverse opal TiO(2) electrodes on the photovoltaic parameters of DSSCs were investigated. The photovoltaic parameters were measured as a function of pore ordering and electrode film thickness. Moreover, DSSC applications that used either liquid or viscous polymer electrolyte solutions were investigated to reveal the effects of pore size on performance of an inverse opal TiO(2) electrode.
authors.affiliation: Department of Chemical and Biomolecular Engineering, Sogang University, Seoul 121-742, Republic of Korea.
authors.forename: Ju-Hwan
authors.initials: JH
authors.lastname: Shin
authors.forename: Ji-Hwan
authors.initials: JH
authors.lastname: Kang
authors.forename: Woo-Min
authors.initials: WM
authors.lastname: Jin
authors.forename: Jong Hyeok
authors.initials: JH
authors.lastname: Park
authors.forename: Young-Sang
authors.initials: YS
authors.lastname: Cho
authors.forename: Jun Hyuk
authors.initials: JH
authors.lastname: Moon
mesh_terms: D004396:Coloring Agents / Q000737:chemistry*; D004566:Electrodes; D010316:Particle Size; D012993:Solar Energy; D013499:Surface Properties; D014025:Titanium / Q000737:chemistry*
chemical_list: D004396:Coloring Agents; C009495:titanium dioxide; D014025:Titanium