title: Separation of trace amount of silver using dispersive liquid-liquid based on solidification of floating organic drop microextraction.
abstract: In the present work, dispersive liquid-liquid microextraction based on solidification of floating organic drop was developed as a simple and rapid technique for separation of silver ions from aqueous samples. In this technique, 700 μL 0.02% of 5-(4'-dimethylamino benzyliden)-rhodanine (chelating agent) was added into the 10 mL analyte sample in a test tube and 30.0 μL 1-undecanol (extraction solvent) was injected shortly thereafter. The test tubes were sonicated, centrifuged and then some effective parameters on extraction and complex formation, such as type and volume of extraction and disperser solvent, pH, the amount of chelating agent and extraction time were optimized. The effect of the interfering ions on the analytes recovery was also investigated. The calibration graph was linear in the range of 0.10-10.0 ng mL(-1) with detection limit of 0.056 ng mL(-1) (n=8). The relative standard deviation (RSD) was ±4.3% (n=8, C=5.0 ng mL(-1)) and the enrichment factor was 250.0. The proposed method was applied for extraction and determination of silver in different water samples.
authors.affiliation: Environment and Nanochemistry Department, Research Institute of Environmental Sciences, International Center for Science, High Technology & Environmental Sciences, Kerman, Iran. daryoush afzali@yahoo.com
authors.forename: Daryoush
authors.initials: D
authors.lastname: Afzali
authors.forename: Ali Reza
authors.initials: AR
authors.lastname: Mohadesi
authors.forename: Behnoosh Bahadori
authors.initials: BB
authors.lastname: Jahromi
authors.forename: Masoumeh
authors.initials: M
authors.lastname: Falahnejad
mesh_terms: D002138:Calibration; D002614:Chelating Agents / Q000737:chemistry*; D005591:Chemical Fractionation / Q000379:methods*; D006863:Hydrogen-Ion Concentration; D057230:Limit of Detection; D012236:Rhodanine / Q000031:analogs & derivatives*; D045483:Rivers / Q000737:chemistry; D012834:Silver / Q000032:analysis / Q000302:isolation & purification*; D012997:Solvents / Q000737:chemistry; D013054:Spectrophotometry, Atomic / Q000379:methods; D014867:Water / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000302:isolation & purification*
chemical_list: D002614:Chelating Agents; D012997:Solvents; D014874:Water Pollutants, Chemical; D014867:Water; D012834:Silver; D012236:Rhodanine