title: Time-dependent changes of zinc speciation in four soils contaminated with zincite or sphalerite.
abstract: The long-term speciation of Zn in contaminated soils is strongly influenced by soil pH, clay, and organic matter content as well as Zn loading. In addition, the type of Zn-bearing contaminant entering the soil may influence the subsequent formation of pedogenic Zn species, but systematic studies on such effects are currently lacking. We therefore conducted a soil incubation study in which four soils, ranging from strongly acidic to calcareous, were spiked with 2000 mg/kg Zn using either ZnO (zincite) or ZnS (sphalerite) as the contamination source. The soils were incubated under aerated conditions in moist state for up to four years. The extractability and speciation of Zn were assessed after one, two, and four years using extractions with 0.01 M CaCl(2) and Zn K-edge X-ray absorption fine structure (XAFS) spectroscopy, respectively. After four years, more than 90% of the added ZnO were dissolved in all soils, with the fastest dissolution occurring in the acidic soils. Contamination with ZnO favored the formation of Zn-bearing layered double hydroxides (LDH), even in acidic soils, and to a lesser degree Zn-phyllosilicates and adsorbed Zn species. This was explained by locally elevated pH and high Zn concentrations around dissolving ZnO particles. Except for the calcareous soil, ZnS dissolved more slowly than ZnO, reaching only 26 to 75% of the added ZnS after four years. ZnS dissolved more slowly in the two acidic soils than in the near-neutral and the calcareous soil. Also, the resulting Zn speciation was markedly different between these two pairs of soils: Whereas Zn bound to hydroxy-interlayered clay minerals (HIM) and octahedrally coordinated Zn sorption complexes prevailed in the two acidic soils, Zn speciation in the neutral and the calcareous soil was dominated by Zn-LDH and tetrahedrally coordinated inner-sphere Zn complexes. Our results show that the type of Zn-bearing contaminant phase can have a significant influence on the formation of pedogenic Zn species in soils. Important factors include the rate of Zn release from the contaminant phases and effects of the contaminant phase on bulk soil properties and on local chemical conditions around weathering contaminant particles.
authors.affiliation: Eawag, Swiss Federal Institute of Aquatic Science and Technology, Ueberlandstrasse 133, CH-8600 Duebendorf, Switzerland. andreas.voegelin@eawag.ch
authors.forename: Andreas
authors.initials: A
authors.lastname: Voegelin
authors.forename: Olivier
authors.initials: O
authors.lastname: Jacquat
authors.forename: Sabina
authors.initials: S
authors.lastname: Pfister
authors.forename: Kurt
authors.initials: K
authors.lastname: Barmettler
authors.forename: Andreas C
authors.initials: AC
authors.lastname: Scheinost
authors.forename: Ruben
authors.initials: R
authors.lastname: Kretzschmar
mesh_terms: D000327:Adsorption; D000538:Aluminum Silicates / Q000737:chemistry; D000077215:Clay; D004784:Environmental Monitoring; D006863:Hydrogen-Ion Concentration; D012987:Soil / Q000737:chemistry*; D012989:Soil Pollutants / Q000032:analysis / Q000737:chemistry*; D013440:Sulfides / Q000032:analysis / Q000737:chemistry*; D013995:Time; D015032:Zinc / Q000032:analysis / Q000737:chemistry*; D017967:Zinc Compounds / Q000032:analysis / Q000737:chemistry*; D015034:Zinc Oxide / Q000032:analysis / Q000737:chemistry*
chemical_list: D000538:Aluminum Silicates; D012987:Soil; D012989:Soil Pollutants; D013440:Sulfides; D017967:Zinc Compounds; D015032:Zinc; C031238:zinc sulfide; D015034:Zinc Oxide; D000077215:Clay