title: Highly enantioselective synthesis of cyclic sulfamidates and sulfamides via rhodium-catalyzed transfer hydrogenation.
abstract: We achieved highly enantioselective synthesis of cyclic 1,2-sulfamidates and -sulfamides via rhodium-catalyzed transfer hydrogenation, and also revealed one-pot preparation of cyclic N-sulfonylimines from α-hydroxy ketones.
authors.affiliation: Green Chemistry Division, Korea Research Institute of Chemical Technology, Taejon 305-600, Korea.
authors.forename: Sun Ah
authors.initials: SA
authors.lastname: Lee
authors.forename: Se Hun
authors.initials: SH
authors.lastname: Kwak
authors.forename: Kee-In
authors.initials: KI
authors.lastname: Lee
mesh_terms: D002384:Catalysis; D006865:Hydrogenation; D007097:Imines / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism; D013450:Sulfones / Q000737:chemistry*
chemical_list: D007097:Imines; D007659:Ketones; C482356:N-sulfonylimine; D013450:Sulfones; D012238:Rhodium