title: The synergistic effect of [WZn(VO)2(ZnW9O34)2]12- cores and peripheral metal sites in catalytic oxidative cyclization of acetylacetone.
abstract: Three anionic polyoxometalates contain catalytically active vanadium(IV) centers and peripheral metal sites of Mn(2+), Co(2+) or Ni(2+) cations, which synergistically affect the catalytic selectivities of unprecedented oxidative cyclization of acetylacetone to form two interesting multifunctional furan derivatives.
authors.affiliation: Department of Chemistry, Zhejiang University, Hangzhou, 310027, P. R. China.
authors.forename: Lian-Xu
authors.initials: LX
authors.lastname: Shi
authors.forename: Xian-Wei
authors.initials: XW
authors.lastname: Zhang
authors.forename: Chuan-De
authors.initials: CD
authors.lastname: Wu