title: Copper-phthalocyanine based metal-organic interfaces: the effect of fluorination, the substrate, and its symmetry.
abstract: Metal-organic interfaces based on copper-phthalocyanine monolayers are studied in dependence of the metal substrate (Au versus Cu), of its symmetry [hexagonal (111) surfaces versus fourfold (100) surfaces], as well as of the donor or acceptor semiconducting character associated with the nonfluorinated or perfluorinated molecules, respectively. Comparison of the properties of these systematically varied metal-organic interfaces provides new insight into the effect of each of the previously mentioned parameters on the molecule-substrate interactions.
authors.affiliation: Donostia International Physics Center, Paseo Manuel Lardizabal 4, 20018 San Sebastián, Spain. dgoteyza@lbl.gov
authors.forename: D G
authors.initials: DG
authors.lastname: de Oteyza
authors.forename: A
authors.initials: A
authors.lastname: El-Sayed
authors.forename: J M
authors.initials: JM
authors.lastname: Garcia-Lastra
authors.forename: E
authors.initials: E
authors.lastname: Goiri
authors.forename: T N
authors.initials: TN
authors.lastname: Krauss
authors.forename: A
authors.initials: A
authors.lastname: Turak
authors.forename: E
authors.initials: E
authors.lastname: Barrena
authors.forename: H
authors.initials: H
authors.lastname: Dosch
authors.forename: J
authors.initials: J
authors.lastname: Zegenhagen
authors.forename: A
authors.initials: A
authors.lastname: Rubio
authors.forename: Y
authors.initials: Y
authors.lastname: Wakayama
authors.forename: J E
authors.initials: JE
authors.lastname: Ortega
mesh_terms: D003300:Copper / Q000737:chemistry*; D006046:Gold / Q000737:chemistry; D054879:Halogenation; D007211:Indoles / Q000737:chemistry*; D054833:Isoindoles; D008567:Membranes, Artificial; D008958:Models, Molecular; D015394:Molecular Structure; D010316:Particle Size; D011789:Quantum Theory; D013499:Surface Properties
chemical_list: D007211:Indoles; D054833:Isoindoles; D008567:Membranes, Artificial; D006046:Gold; D003300:Copper; C013647:phthalocyanine