title: Characterization of adsorption removal of hydrogen sulfide by waste biocover soil, an alternative landfill cover.
abstract: Landfill is an important anthropogenic source of odorous gases. In this work, the adsorption characteristics of H(2)S on waste biocover soil, an alternative landfill cover, were investigated. The results showed that the adsorption capacity of H(2)S increased with the reduction of particle size, the increase of pH value and water content of waste biocover soil. The optimal composition of waste biocover soil, in regard to operation cost and H(2)S removal performance, was original pH value, water content of 40% (w/w) and particle size of ≤4 mm. A net increase was observed in the adsorption capacity of H(2)S with temperatures in the range of 4-35°C. The adsorption capacity of H(2)S on waste biocover soil with optimal composition reached the maximum value of 60±1 mg/kg at oxygen concentration of 10% (v/v). When H(2)S concentration was about 5% (v/v), the adsorption capacity was near saturation, maintaining at 383±40 mg/kg. Among the four experimental soils, the highest adsorption capacity of H(2)S was observed on waste biocover soil, followed by landfill cover soil, mulberry soil, and sand soil, which was only 9.8% of that of waste biocover soil.
authors.affiliation: Department of Environmental Engineering, Zhejiang University, Hangzhou, China. heruo@zju.edu.cn
authors.forename: Ruo
authors.initials: R
authors.lastname: He
authors.forename: Fang-Fang
authors.initials: FF
authors.lastname: Xia
authors.forename: Jing
authors.initials: J
authors.lastname: Wang
authors.forename: Chang-Liang
authors.initials: CL
authors.lastname: Pan
authors.forename: Cheng-Ran
authors.initials: CR
authors.lastname: Fang
mesh_terms: D000327:Adsorption; D006862:Hydrogen Sulfide / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D010100:Oxygen / Q000737:chemistry; D010316:Particle Size; D012037:Refuse Disposal; D012989:Soil Pollutants / Q000737:chemistry*; D013696:Temperature
chemical_list: D012989:Soil Pollutants; D010100:Oxygen; D006862:Hydrogen Sulfide