title: An extraction technique for analytical sample preparation in aqueous solution based on controlling dispersion of ionic surfactant assemblies in isotachophoretic migration.
abstract: An extraction technique for analytical sample preparation in aqueous solution has been developed based on controlling dispersion of ionic surfactant assemblies. An extraction technique was realized based on controlling dispersion of the ionic surfactant assemblies in their isotachophoretic migration during the extraction by arranging the solutions of leading electrolyte, ionic surfactant and terminating electrolyte in order and applying voltage. Potential of the technique for analytical sample preparation in aqueous solution has been demonstrated by extracting a model sample of four alkylphenones, which were analyzed by HPLC after the extraction. The extraction showed concentration effects on all the four alkylphenones of butyrophenone, valerophenone, hexanophenone and heptanophenone in the model sample. The enrichment factors were 5.29, 7.70, 7.25 and 7.49 for the four alkylphenones of butyrophenone, valerophenone, hexanophenone and heptanophenone, respectively. Linear relationship was obtained with all the four alkylphenones between their chromatographic peak areas before and after the extraction in the range of concentration from 0.05 ppm to 1.5 ppm. The RSD of the chromatographic peak areas in triplicate extractions was 7.97%, 3.75%, 2.91% and 4.45% for butyrophenone, valerophenone, hexanophenone and heptanophenone, respectively. Advantages of the extraction technique developed include ease of operation, low reagent cost, no consumption of organic solvents and no requirement for additional phase separation.
authors.affiliation: Department of Chemistry, Shanghai University, No. 99 Shangda Road, Shanghai 200444, China. zhxh401@yahoo.com.cn
authors.forename: Tianlin
authors.initials: T
authors.lastname: Wang
authors.forename: Yexin
authors.initials: Y
authors.lastname: Qin
authors.forename: Haibo
authors.initials: H
authors.lastname: He
authors.forename: Jun
authors.initials: J
authors.lastname: Lv
authors.forename: Yong
authors.initials: Y
authors.lastname: Fan
mesh_terms: D005591:Chemical Fractionation; D002851:Chromatography, High Pressure Liquid; D005942:Gluconates / Q000737:chemistry; D057625:Isotachophoresis / Q000379:methods*; D007659:Ketones / Q000737:chemistry / Q000302:isolation & purification; D016014:Linear Models; D008956:Models, Chemical; D012965:Sodium Chloride / Q000737:chemistry; D012967:Sodium Dodecyl Sulfate / Q000737:chemistry; D013501:Surface-Active Agents / Q000737:chemistry*
chemical_list: D005942:Gluconates; D007659:Ketones; D013501:Surface-Active Agents; D012967:Sodium Dodecyl Sulfate; D012965:Sodium Chloride; C030691:gluconic acid