title: Nafion as cosurfactant: solubilization of nafion in water in the presence of Pluronics.
abstract: Incorporation of Nafion to aqueous solutions of Pluronics adversely impacts micellization due to extensive Nafion/copolymer interactions. Light scattering and zeta potential measurements provide evidence for the formation of sizable and stable Nafion/copolymer complexes, in expense of the neat copolymer micelles. At high copolymer concentrations, the overall interaction diagram of Nafion/copolymer reflects the competitive action of the release of packing constraints due to micellar destabilization induced by Nafion on one hand and the gelator nature of the Nafion on the other. Measurements using a quartz crystal microbalance (QCM-D) show that aqueous solutions of Pluronics (even at very low concentration) can dissolve the Nafion coating on the crystal resonator, while typical low molecular weight ionic surfactants fail to induce similar effects. These studies demonstrate that complexation with this class of copolymers is a facile route to impart dispersibility to Nafion in aqueous environments that otherwise can be achieved through tedious and harsh treatments.
authors.affiliation: Department of Materials Science and Engineering, Cornell University, Bard Hall, Ithaca, New York 14853, United States.
authors.forename: Antonios
authors.initials: A
authors.lastname: Kelarakis
authors.forename: Emmanuel P
authors.initials: EP
authors.lastname: Giannelis
mesh_terms: D005465:Fluorocarbon Polymers / Q000737:chemistry*; D020442:Poloxamer / Q000737:chemistry*; D012995:Solubility; D013501:Surface-Active Agents / Q000737:chemistry*; D014867:Water / Q000737:chemistry*
chemical_list: D005465:Fluorocarbon Polymers; D013501:Surface-Active Agents; D014867:Water; D020442:Poloxamer; C040402:perfluorosulfonic acid