title: [M(dap)3]InSb3S7 (M = Co, Ni): two novel open-framework thioindate-thioantimonates with 8-, 12-, and 16-ring intersecting channels.
abstract: Two novel open-framework thioindate-thioantimonates [M(dap)3]InSb3S7 [M = Co(1), Ni (2); dap = 1,2-diaminopropane] have been solvothermally synthesized and structurally characterized. 1 and 2 consist of InS4 tetrahedra and SbS3(3-) trigonal pyramids, which are interconnected to form the first examples of three-dimensional In-Sb-S open frameworks with 8-, 12-, and 16-ring intersecting channels.
authors.affiliation: Department of Chemistry and Biology, Yulin Normal University, Yulin 537000, China.
authors.forename: Jian
authors.initials: J
authors.lastname: Zhou
authors.forename: Litao
authors.initials: L
authors.lastname: An
authors.forename: Feng
authors.initials: F
authors.lastname: Zhang
mesh_terms: D000965:Antimony / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry*; D007204:Indium / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D009532:Nickel / Q000737:chemistry*; D012997:Solvents; D013056:Spectrophotometry, Ultraviolet; D013438:Sulfhydryl Compounds / Q000737:chemistry; D014961:X-Ray Diffraction
chemical_list: D056831:Coordination Complexes; D012997:Solvents; D013438:Sulfhydryl Compounds; D007204:Indium; D003035:Cobalt; D009532:Nickel; D000965:Antimony