title: Flexible two-dimensional square-grid coordination polymers: structures and functions.
abstract: Coordination polymers (CPs) or metal-organic frameworks (MOFs) have attracted considerable attention because of the tunable diversity of structures and functions. A 4,4'-bipyridine molecule, which is a simple, linear, exobidentate, and rigid ligand molecule, can construct two-dimensional (2D) square grid type CPs. Only the 2D-CPs with appropriate metal cations and counter anions exhibit flexibility and adsorb gas with a gate mechanism and these 2D-CPs are called elastic layer-structured metal-organic frameworks (ELMs). Such a unique property can make it possible to overcome the dilemma of strong adsorption and easy desorption, which is one of the ideal properties for practical adsorbents.
authors.affiliation: Nippon Steel Corporation, 20-1Shintomi, Futtsu, Chiba 293-8511, Japan.
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Kajiro
authors.forename: Atsushi
authors.initials: A
authors.lastname: Kondo
authors.forename: Katsumi
authors.initials: K
authors.lastname: Kaneko
authors.forename: Hirofumi
authors.initials: H
authors.lastname: Kanoh
mesh_terms: D009942:Organometallic Compounds / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D011108:Polymers