title: A comparison of complexation of Li+ ion with macrocyclic ligands 15-crown-5 and 12-crown-4 in binary nitromethane-acetonitrile mixtures by using lithium-7 NMR technique and ab initio calculation.
abstract: Lithium-7 NMR measurements were used to investigate the stoichiometry and stability of Li+ complexes with 15-crown-5 (15C5), benzo-15-crown-5 (B15C5), dibenzo-15-crown-5 (DB15C5) and 12-crown-4 (12C4) in a number of nitromethane (NM)-acetonitrile (AN) binary mixtures. In all cases, the exchange between the free and complexed lithium ion was fast on the NMR time scale and a single population average resonance was observed. While all crown ethers form 1:1 complexes with Li+ ion in the binary mixtures used, both 1:1 and 2:1 (sandwich) complexes were observed between lithium ion and 12C4 in pure nitromethane solution. Stepwise formation constants of the 1:1 and 2:1 (ligand/metal) complexes were evaluated from computer fitting of the NMR-mole ratio data to equations which relate the observed metal ion chemical shifts to formation constants. There is an inverse linear relationship between the logarithms of the stability constants and the mole fraction of acetonitrile in the solvent mixtures. The stability order of the 1:1 complexes was found to be 15C5·Li+>B15C5·Li+>DB15C5·Li+>12C4·Li+. The optimized structures of the free ligands and their 1:1 and 2:1 complexes with Li+ ion were predicted by ab initio theoretical calculations using the Gaussian 98 software, and the results are discussed.
authors.affiliation: Department of Chemistry, University of Guilan, Namjoo Street, Rasht 41335-1914, Iran. nializadeh@yahoo.com
authors.forename: Nina
authors.initials: N
authors.lastname: Alizadeh
mesh_terms: D000097:Acetonitriles / Q000737:chemistry*; D043844:Crown Ethers / Q000737:chemistry*; D007477:Ions; D008024:Ligands; D008094:Lithium / Q000737:chemistry*; D047028:Macrocyclic Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008956:Models, Chemical; D008968:Molecular Conformation; D009595:Nitroparaffins / Q000737:chemistry*
chemical_list: D000097:Acetonitriles; D043844:Crown Ethers; D007477:Ions; D008024:Ligands; D047028:Macrocyclic Compounds; D009595:Nitroparaffins; C042148:15-crown-5; D008094:Lithium; C557123:12-crown-4; D008697:Methane; C008640:nitromethane; C032159:acetonitrile