title: Mechanistic comparison of β-H elimination, β-OH elimination, and nucleophilic displacement reactions of β-hydroxy alkyl rhodium porphyrin complexes.
abstract: This article reports on kinetic studies for three alternate pathways, including β-hydrogen elimination, β-hydroxy elimination, and intramolecular nucleophilic displacement reactions, for rhodium porphyrin β-hydroxy alkyl reactions in water and DMSO to form ketone, alkene, and epoxide, respectively. Comparisons of activation parameters for these processes indicate that the β-hydroxy elimination process has the lowest activation enthalpy in water, but the intramolecular nucleophilic displacement pathway predominates in DMSO.
authors.affiliation: Beijing National Laboratory for Molecular Sciences, Peking University, Beijing, China.
authors.forename: Bing
authors.initials: B
authors.lastname: Wu
authors.forename: Jiadi
authors.initials: J
authors.lastname: Zhang
authors.forename: Lin
authors.initials: L
authors.lastname: Yun
authors.forename: Xuefeng
authors.initials: X
authors.lastname: Fu