title: μ-Bis(diphenyl-phosphan-yl)borato-κP:P'-bis-[dicarbon-yl(η-cyclo-penta-dien-yl)iron(II)] tetrachloridoferrate(III) chloro-form solvate.
abstract: The title compound, [Fe(2)(C(5)H(5))(2)(C(24)H(22)BP(2))(CO)(4)][FeCl(4)]·CHCl(3), is an oxidation product of CpFe(CO)(2)PPh(2)BH(3). One pair of phenyl rings attached to the two different P atoms are almost parallel, as are the other pair [dihedral angles = 8.7 (5) and 8.9 (5)°]. The planes of the two cyclo-penta-dienyl rings are inclined by 26.8 (7)° with respect to each other. The carbonyl groups at each Fe atom are almost perpendicular [C-Fe-C = 92.6 (6) and 94.3 (5)°].
authors.affiliation: Institut für Anorganische Chemie, J. W. Goethe-Universität Frankfurt, Max-von-Laue-Strasse 7, 60438 Frankfurt/Main, Germany.
authors.forename: Franz
authors.initials: F
authors.lastname: Dornhaus
authors.forename: Hans-Wolfram
authors.initials: HW
authors.lastname: Lerner
authors.forename: Michael
authors.initials: M
authors.lastname: Bolte