title: Synthesis of C-glycosylated amino acids by hetero-Diels-Alder addition of ethyl 2-nitrosoacrylate to exo-glycals.
abstract: C-Glycoamino acids bearing a variety of sugar moieties were prepared by the hetero-Diels-Alder addition of ethyl 2-nitrosoacrylate to exo-glycals. The reaction proceeds smoothly to yield spirocyclic oxazines that can be converted into useful products by several hydrogenolytic techniques.
authors.affiliation: Department of Chemistry, Aristotle University of Thessaloniki, Thessaloniki 54124, Greece.
authors.forename: Zoe S
authors.initials: ZS
authors.lastname: Massen
authors.forename: Vassiliki C
authors.initials: VC
authors.lastname: Sarli
authors.forename: Evdoxia
authors.initials: E
authors.lastname: Coutouli-Argyropoulou
authors.forename: John K
authors.initials: JK
authors.lastname: Gallos
mesh_terms: D000179:Acrylates / Q000737:chemistry*; D000596:Amino Acids / Q000138:chemical synthesis*; D006031:Glycosylation; D009603:Nitroso Compounds / Q000737:chemistry*
chemical_list: D000179:Acrylates; D000596:Amino Acids; D009603:Nitroso Compounds