title: Tuning emission wavelength and redox properties through position of the substituent in iridium(III) cyclometallated complexes.
abstract: Cyclometallated phenyls with substituents para to the metal have a larger impact on the redox potentials and emission of complexes [Ir(R-ppz)(2)(bipy)][PF(6)] than substituents at the meta position and hence enable tuning of emission wavelength over a wider range using the same substituent.
authors.affiliation: Department of Chemistry, University of Leicester, Leicester, UK LE1 7RH. dld3@le.ac.uk
authors.forename: David L
authors.initials: DL
authors.lastname: Davies
authors.forename: Mark P
authors.initials: MP
authors.lastname: Lowe
authors.forename: Karl S
authors.initials: KS
authors.lastname: Ryder
authors.forename: Kuldip
authors.initials: K
authors.lastname: Singh
authors.forename: Shalini
authors.initials: S
authors.lastname: Singh