title: 3-Chloro-2-methyl-anilinium dihydrogenphosphate.
abstract: The structure of the title compound, C(7)H(9)ClN(+)·H(2)PO(4) (-), contains inorganic layers built by (H(2)PO(4))(-) anions and which are parallel to the ab planes around z = . 3-Chloro-2-methyl-anilinium cations are anchored between the inorganic layers through N-H⋯O hydrogen bonds. Electrostatic and van der Waals inter-actions, as well as hydrogen bonds, maintain the structural cohesion.
authors.affiliation: Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna Bizerte, Tunisia.
authors.forename: Hamed
authors.initials: H
authors.lastname: Khemiri
authors.forename: Samah
authors.initials: S
authors.lastname: Akriche
authors.forename: Mohamed
authors.initials: M
authors.lastname: Rzaigui