title: 4-Amino-13-(1-naphth-yl)-[2,2]paracyclo-phane.
abstract: THE TITLE COMPOUND [SYSTEMATIC NAME: 1(2)-amino-4(2)-(1-naphth-yl)-1,4(1,4)-dibenzenacyclo-hexa-phane], C(26)H(23)N, was synthesized from 4-amino-13-bromo-[2,2]paracyclo-phane and 1-naphthalene-boronic acid in the presence of 1,4-dioxane. It is a new cyclo-phane-derived compound which can be regarded as a prospective ligand for asymmetric synthesis and catalysis. The benzene rings of the paracyclo-phane units are very slightly deformed from planarity as shallow boats.
authors.forename: Junshan
authors.initials: J
authors.lastname: Sun
authors.forename: Yanmin
authors.initials: Y
authors.lastname: Huo
authors.forename: Rentao
authors.initials: R
authors.lastname: Wu
authors.forename: Jikun
authors.initials: J
authors.lastname: Li
authors.forename: Yudao
authors.initials: Y
authors.lastname: Ma