title: [(1-Azulen-yl)methane-thiol-ato-κS](1,4,8,12-tetra-azacyclo-penta-decane-κN)zinc(II) perchlorate.
abstract: In the title compound, [Zn(C(11)H(26)N(4))(C(11)H(9)S)]ClO(4), the Zn(II) atom is five-coordinated by four N atoms from a neutral 1,4,8,12-tetra-azacyclo-penta-decane aza-macrocycle mol-ecule, and one S atom from an azulenylmethane-thiol-ate ligand. Only monomers are found in the crystal. The coordination geometry can be described as trigonal bipyramidal, with the thiol-ate group in an equatorial position. The Zn-N and Zn-S distances are in the usual ranges for this type of complex.
authors.forename: Helmar
authors.initials: H
authors.lastname: Görls
authors.forename: Johannes
authors.initials: J
authors.lastname: Notni
authors.forename: Ernst
authors.initials: E
authors.lastname: Anders