title: Why hybrid porous solids capture greenhouse gases?
abstract: Hybrid porous solids, with their tunable structures, their multifunctional properties and their numerous applications, are currently topical, particularly in the domain of adsorption and storage of greenhouse gases. Most of the data reported so far concern the performances of these solids in this domain, particularly in terms of adsorbed amounts of gas but do not explain at the atomic level why and how adsorption and storage occur. From a combination of structural, spectroscopic, thermodynamic experiments and of molecular simulations, this tutorial review proposes answers to these open questions with a special emphasis on CO(2) and CH(4) storage by some rigid and flexible hybrid porous materials.
authors.affiliation: Institut Lavoisier, CNRS 8180, Université de Versailles-St-Quentin, 45 Avenue des Etats-Unis, 78035 Versailles cedex, France. gferey@wanadoo.fr
authors.forename: Gérard
authors.initials: G
authors.lastname: Férey
authors.forename: Christian
authors.initials: C
authors.lastname: Serre
authors.forename: Thomas
authors.initials: T
authors.lastname: Devic
authors.forename: Guillaume
authors.initials: G
authors.lastname: Maurin
authors.forename: Hervé
authors.initials: H
authors.lastname: Jobic
authors.forename: Philip L
authors.initials: PL
authors.lastname: Llewellyn
authors.forename: Guy
authors.initials: G
authors.lastname: De Weireld
authors.forename: Alexandre
authors.initials: A
authors.lastname: Vimont
authors.forename: Marco
authors.initials: M
authors.lastname: Daturi
authors.forename: Jong-San
authors.initials: JS
authors.lastname: Chang