title: Organic multiferroic tunnel junctions with ferroelectric poly(vinylidene fluoride) barriers.
abstract: Organic materials are promising for applications in spintronics due to their long spin-relaxation times in addition to their chemical flexibility and relatively low production costs. Most studies of organic materials for spintronics focus on nonpolar dielectrics or semiconductors, serving as passive elements in spin transport devices. Here, we demonstrate that employing organic ferroelectrics, such as poly(vinylidene fluoride) (PVDF), as barriers in magnetic tunnel junctions (MTJs) allows new functionality in controlling the tunneling spin polarization via the ferroelectric polarization of the barrier. Using first-principles methods based on density functional theory we investigate the spin-resolved conductance of Co/PVDF/Co and Co/PVDF/Fe/Co MTJs as model systems. We show that these tunnel junctions exhibit multiple resistance states associated with different magnetization configurations of the electrodes and ferroelectric polarization orientations of the barrier. Our results indicate that organic ferroelectrics may open a new and promising route in organic spintronics with implications for low-power electronics and nonvolatile data storage.
authors.affiliation: Department of Physics, Institute for Functional Nanomaterials, University of Puerto Rico, San Juan, Puerto Rico 00931.
authors.forename: Juan M
authors.initials: JM
authors.lastname: López-Encarnación
authors.forename: J D
authors.initials: JD
authors.lastname: Burton
authors.forename: Evgeny Y
authors.initials: EY
authors.lastname: Tsymbal
authors.forename: Julian P
authors.initials: JP
authors.lastname: Velev
mesh_terms: D003460:Crystallization / Q000379:methods; D004553:Electric Conductivity; D004867:Equipment Design; D019544:Equipment Failure Analysis; D008839:Microelectrodes; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000295:instrumentation*; D009930:Organic Chemicals / Q000737:chemistry*; D010316:Particle Size; D011145:Polyvinyls / Q000737:chemistry*; D012666:Semiconductors; D005465:Fluorocarbon Polymers
chemical_list: D009930:Organic Chemicals; D011145:Polyvinyls; C024865:polyvinylidene fluoride; D005465:Fluorocarbon Polymers