title: Ethane-1,2-diylbis(methyl-phosphinic acid).
abstract: In the title compound, C(4)H(12)O(4)P(2), there are two crystallographically independent half-mol-ecules in the asymmetric unit, both molecules lying on centres of symmetry. Each mol-ecule is connected on both sides to neighbouring mol-ecules via strong O-H⋯O hydrogen bonds. The -POOH groups accept and donate one hydrogen bond in interactions with the neighbouring -POOH group of the adjacent mol-ecule, to give one-dimensional chains along [10]. As each phosphinic acid group donates and accepts one hydrogen bond, the connection between the mol-ecules is best described by a ring motif which can be classified by the Etter symbol R(2) (2)(8).
authors.affiliation: Institut für Anorganische Chemie und Strukturchemie, Lehrstuhl für Material- und Strukturforschung, Heinrich-Heine-Universität Düsseldorf, Universitätsstrasse 1, D-40225 Düsseldorf, Germany.
authors.forename: Guido J
authors.initials: GJ
authors.lastname: Reiss
authors.forename: Judith S
authors.initials: JS
authors.lastname: Engel