title: μ-Hydroxido-bis-[(2,2'-bipyridine)tricarbonyl-rhenium(I)] perrhenate.
abstract: The title compound, [Re(2)(OH)(C(10)H(8)N(2))(2)(CO)(6)][ReO(4)], is a mixed-valence rhenium compound containing discrete anions and cations. The Re(I) atoms are in a slightly distorted octa-hedral environment, whereas the Re(VII) atoms show the typical tetra-hedral coordination mode. The dihedral angle between the two bipyridine groups is 34.3 (7)°.
authors.affiliation: Institut für Anorganische Chemie, J. W. Goethe-Universität Frankfurt, Max-von-Laue-Strasse 7, 60438 Frankfurt/Main, Germany.
authors.forename: Kai
authors.initials: K
authors.lastname: Ruth
authors.forename: Thorsten
authors.initials: T
authors.lastname: Morawitz
authors.forename: Hans-Wolfram
authors.initials: HW
authors.lastname: Lerner
authors.forename: Michael
authors.initials: M
authors.lastname: Bolte