title: 'One-pot' ultrasound irradiation promoted synthesis and spectral characterization of an array of novel 1,1'-(5,5'-(1,4-phenylene)bis(3-aryl-1H-pyrazole-5,1(4H,5H)-diyl))diethanones, a bis acetylated pyrazoles derivatives.
abstract: An array of novel 1,1'-(5,5'-(1,4-phenylene)bis(3-aryl-1H-pyrazole-5,1(4H,5H)-diyl))diethanones, a bis acetylated pyrazoles derivatives are synthesized in 'one-pot' by ultrasound irradiation method and are characterized by melting point, elemental analysis, MS, FT-IR, one-dimensional NMR (1H and 13C) and two-dimensional NOESY spectra. The methylene and methane protons of pyrazoles moiety splits signal as ABX pattern in the proton NMR spectra and the key nOe correlations are confirmed by NOESY spectrum.
authors.affiliation: Energetics Research Institute, Nanyang Technological University, 50, Nanyang Avenue, Singapore 639 798, Republic of Singapore.
authors.forename: V
authors.initials: V
authors.lastname: Kanagarajan
authors.forename: M R
authors.initials: MR
authors.lastname: Ezhilarasi
authors.forename: M
authors.initials: M
authors.lastname: Gopalakrishnan
mesh_terms: D000107:Acetylation / Q000528:radiation effects; D009682:Magnetic Resonance Spectroscopy; D008968:Molecular Conformation; D011720:Pyrazoles / Q000138:chemical synthesis* / Q000737:chemistry*; D012545:Schiff Bases / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D014465:Ultrasonics / Q000379:methods*
chemical_list: D011720:Pyrazoles; D012545:Schiff Bases