title: Tetra-μ-benzoato-bis-[(6-methyl-quino-line)-copper(II)].
abstract: In the title compound, [Cu(2)(C(7)H(5)O(2))(4)(C(10)H(9)N)(2)], the paddle-wheel-type dinuclear complex is constructed by four bridging benzoate groups and two terminal 6-methyl-quinoline ligands. The asymmetric unit contains one-half of the whole mol-ecule, and there is an inversion center at the mid-point of the Cu⋯Cu bond. The octa-hedral coordination of each Cu atom, with four O atoms in the equatorial plane, is completed by the N atom of the 6-methyl-quinoline mol-ecule [Cu-N = 2.212 (2) Å] and by another Cu atom [Cu⋯Cu = 2.6939 (13) Å]. The Cu atom lies 0.234 Å out of the plane of the four O atoms. The molecular packing is stabilized by one intramolecular C-H⋯O as well as C-H⋯π and π-π interactions.
authors.forename: Seung Man
authors.initials: SM
authors.lastname: Yu
authors.forename: Chi-Ho
authors.initials: CH
authors.lastname: Park
authors.forename: Pan-Gi
authors.initials: PG
authors.lastname: Kim
authors.forename: Cheal
authors.initials: C
authors.lastname: Kim
authors.forename: Youngmee
authors.initials: Y
authors.lastname: Kim