title: Monofluorovinyl tosylate: a useful building block for the synthesis of terminal vinyl monofluorides via Suzuki-Miyaura coupling.
abstract: Monofluorovinyl tosylate was developed as a practical vinyl fluoride building block to couple with a variety of arylboronic acids in the presence of a palladium catalyst. The high stereoselectivity of 2-aryl-1-fluoroethene derivatives was achieved. This approach is also applicable to the synthesis of 2,2-diaryl-1-fluoroethenes in good yields.
authors.affiliation: Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, China.
authors.forename: He
authors.initials: H
authors.lastname: Zhang
authors.forename: Chang-Bing
authors.initials: CB
authors.lastname: Zhou
authors.forename: Qing-Yun
authors.initials: QY
authors.lastname: Chen
authors.forename: Ji-Chang
authors.initials: JC
authors.lastname: Xiao
authors.forename: Ran
authors.initials: R
authors.lastname: Hong