title: (Piperazin-1-ium-κN)tris-(thio-cyanato-κN)zinc(II).
abstract: Hydro-thermal reaction of NaSCN, piperazine, Zn(II) and 2,6-naphthalenedicarboxylic acid in aqueous solutions gave rise to the title complex, [Zn(NCS)(3)(C(4)H(11)N(2))]. The Zn(II) atom is four-coordinate with distorted tetra-hedral geometry and lies in a mirror plane. N-H⋯S hydrogen bonds assemble the mol-ecules to form a three-dimensional framework.
authors.affiliation: Department of Chemistry, College of Science, Shanghai University, Shanghai 200444, People's Republic of China.
authors.forename: Xiang
authors.initials: X
authors.lastname: He
authors.forename: Hong-Jiang
authors.initials: HJ
authors.lastname: Liu
authors.forename: Ming-Xing
authors.initials: MX
authors.lastname: Li