title: Structural diversity and magnetic properties in 1D and 2D azido-bridged cobalt(II) complexes with 1,2-bis(2-pyridyl)ethylene.
abstract: By utilizing a flexible co-ligand 1,2-bis(2-pyridyl)ethylene (2,2'-bpe), two new azido-bridged cobalt(II) complexes with the formulae [Co₃(N₃)₆(OH₂)₂(2,2'-bpe)₂](n)(2,2'-bpe)(n) (1) and [Co(N₃)₂(2,2'-bpe)₂](n) (2) have been synthesized and structurally characterized. Compound 1 shows an uncommon 1D chain comprised of double EO azido bridged five- and six-coordinated Co(II) geometries in a unique (-5-5-6-)(n) sequence of the coordination number. The 2,2'-bpe acts as a terminal co-ligand and an uncoordinated molecule in the crystal lattice. Moreover the adjacent 1D chain is assembled by C-Hπ interactions and the intermolecular hydrogen bonding between uncoordinated 2,2'-bpe and coordinated water molecules building a 2D layer. Whereas, compound 2 is a 2D coordination network containing the alternating double EO and double EE bridging modes of azides and ditopic 2,2'-bpe bridges. The magnetic investigation of 1 reveals dominant intra-chain ferromagnetic interactions, with the double EO azide-bridge and weak inter-chain antiferromagnetic interactions, with overall metamagnetic behaviour, having magnetic ordering at 6 K. The magnetic behaviour of 2 shows spin-canted antiferromagnetism below a T(N) of 12 K.
authors.affiliation: Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Khon Kaen University, Khon Kaen 40002, Thailand.
authors.forename: Jaursup
authors.initials: J
authors.lastname: Boonmak
authors.forename: Motohiro
authors.initials: M
authors.lastname: Nakano
authors.forename: Sujittra
authors.initials: S
authors.lastname: Youngme