title: One pot production of 5-hydroxymethylfurfural with high yield from cellulose by a Brønsted-Lewis-surfactant-combined heteropolyacid catalyst.
abstract: A Brønsted-Lewis-surfactant-combined heteropolyacid (HPA) Cr[(DS)H(2)PW(12)O(40)](3) has been synthesized, and is used as a heterogeneous catalyst for the conversion of cellulose to 5-hydroxymethylfurfural in one pot within 2 h at 150 °C with 77.1% conversion and 52.7% yield. This micellar HPA catalyst shows stability and can be recycled by simple separation process.
authors.affiliation: Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, 5268 Renmin Street, Changchun 130024, Jilin Province, PR China.
authors.forename: Shun
authors.initials: S
authors.lastname: Zhao
authors.forename: Mingxing
authors.initials: M
authors.lastname: Cheng
authors.forename: Junzi
authors.initials: J
authors.lastname: Li
authors.forename: Juan
authors.initials: J
authors.lastname: Tian
authors.forename: Xiaohong
authors.initials: X
authors.lastname: Wang
mesh_terms: D000143:Acids / Q000737:chemistry; D002384:Catalysis; D002482:Cellulose / Q000138:chemical synthesis / Q000737:chemistry*; D005662:Furaldehyde / Q000031:analogs & derivatives* / Q000138:chemical synthesis; D013501:Surface-Active Agents / Q000737:chemistry
chemical_list: D000143:Acids; D013501:Surface-Active Agents; C008046:5-hydroxymethylfurfural; D002482:Cellulose; D005662:Furaldehyde