title: Poly[[aqua-μ(3)-picolinato-μ(2)-picolinato-dipicolinatopotassium(I)terbium(III)] 2.5-hydrate].
abstract: In the title compound, [KTb(C(6)H(4)NO(2))(4)(H(2)O)]·2.5H(2)O, each Tb(3+) centre is coordinated by four N and five O atoms from five distinct picolinate ligands in a geometry resembling a highly distorted tricapped trigonal prism. One of the ligands establishes a skew bridge between neighbouring Tb(3+) centres, leading to the formation of one-dimensional anionic polymeric chains, {[(C(6)H(4)NO(2))(4)Tb](-)}(n), running along the direction [010]. Each K(+) cation is seven-coordinated by six O atoms from one anionic polymeric chain and one water mol-ecule [K⋯O 2.676 (3)-3.208 (4) Å]. The uncoordinated water mol-ecules are involved in O-H⋯O hydrogen bonding.
authors.forename: Luís
authors.initials: L
authors.lastname: Cunha-Silva
authors.forename: Paula C R
authors.initials: PC
authors.lastname: Soares-Santos
authors.forename: Helena I S
authors.initials: HI
authors.lastname: Nogueira
authors.forename: Tito
authors.initials: T
authors.lastname: Trindade
authors.forename: Jacek
authors.initials: J
authors.lastname: Klinowski
authors.forename: João
authors.initials: J
authors.lastname: Rocha
authors.forename: Filipe A
authors.initials: FA
authors.lastname: Almeida Paz