title: catena-Poly[[bromidocopper(I)]-μ-η,σ-3-(2-allyl-2H-tetra-zol-5-yl)pyridine].
abstract: The title compound, [CuBr(C(9)H(9)N(5))](n), has been prepared by the solvothermal treatment of CuBr with 3-(2-allyl-2H-tetra-zol-5-yl)pyridine. It is a new homometallic Cu(I) olefin coord-ination polymer in which the Cu(I) atoms are linked by the 3-(2-allyl-2H-tetra-zol-5-yl)pyridine ligands and bonded to one terminal Br atom each. The organic ligand acts as a bidentate ligand connecting two neighboring Cu centers through the N atom of the pyridine ring and the double bond of the allyl group. A three-dimensional structure is formed through weak Cu-Br [3.1579 (8) Å], C-H⋯Br and C-H⋯N inter-actions.
authors.affiliation: Ordered Matter Science Research Center, Southeast University, Nanjing 210096, People's Republic of China.
authors.forename: Wei
authors.initials: W
authors.lastname: Wang