title: Bis(μ-N-benzyl-N-methyl-dithio-carbamato)-1:2κS,S':S';1:2κS:S,S'-bis-[bis-(N-benzyl-N-methyl-dithio-carbamato-κS,S')thallium(III)].
abstract: The molecule of the dinuclear title compound, [Tl(2)(C(9)H(10)NS(2))(6)], possesses a crystallographically imposed centre of symmetry. Each Tl(III) atom is seven-coordinated by S atoms of four different dithio-carbamate anions in a distorted penta-gonal-bipyramidal coordination geometry. The crystal structure is stabilized by a C-H⋯S hydrogen-bond inter-action linking complex mol-ecules into chains running parallel to the b axis. Intramolecular C-H⋯S hydrogen bonds are also present.
authors.forename: Corrado
authors.initials: C
authors.lastname: Rizzoli
authors.forename: Kuppukkannu
authors.initials: K
authors.lastname: Ramalingam
authors.forename: Nagarajan
authors.initials: N
authors.lastname: Alexander