title: Enhanced CO2 binding affinity of a high-uptake rht-type metal-organic framework decorated with acylamide groups.
abstract: An rht-type metal-organic framework (MOF) prepared from M(2)(carboxylate)(4) (M = Cu, Co) paddlewheel clusters and a flexible C(3)-symmetric hexacarboxylate ligand with acylamide groups exhibits larger CO(2) uptake, an enhanced heat of adsorption, and higher selectivity toward CO(2)/N(2) in comparison with what was previously observed for an analogous MOF with alkyne groups.
authors.affiliation: State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
authors.forename: Baishu
authors.initials: B
authors.lastname: Zheng
authors.forename: Junfeng
authors.initials: J
authors.lastname: Bai
authors.forename: Jingui
authors.initials: J
authors.lastname: Duan
authors.forename: Lukasz
authors.initials: L
authors.lastname: Wojtas
authors.forename: Michael J
authors.initials: MJ
authors.lastname: Zaworotko