title: 4-(4-Bromo-benzyl-ideneamino)-3-{1-[4-(2-methyl-prop-yl)phen-yl]eth-yl}-1-(mor-phol-ino-meth-yl)-1H-1,2,4-triazole-5(4H)-thione.
abstract: There are two mol-ecules (A and B) in the asymmetric unit of the title compound, C(26)H(32)BrN(5)OS, with almost identical geometry. The morpholine ring adopts the usual chair conformation in both mol-ecules. The triazole ring forms dihedral angles of 4.84 (6) and 74.19 (6)°, respectively, with the bromo-phenyl and isobutylbenzene rings in mol-ecule A, and angles of 16.68 (7) and 87.29 (6)°, respectively, in mol-ecule B. Intra-molecular C-H⋯S hydrogen bonds generate S(5) and S(6) ring motifs in both independent mol-ecules. The crystal structure is stabilized by C-H⋯N, C-H⋯Br and C-H⋯O hydrogen-bonding inter-actions, together with C-H⋯π inter-actions.
authors.forename: Hoong-Kun
authors.initials: HK
authors.lastname: Fun
authors.forename: Samuel Robinson
authors.initials: SR
authors.lastname: Jebas
authors.forename: P S
authors.initials: PS
authors.lastname: Patil
authors.forename: B
authors.initials: B
authors.lastname: Kalluraya
authors.forename: A
authors.initials: A
authors.lastname: Muralidharan