title: Bis[μ-1,4-bis-(4,5-dihydro-1H-imidazol-2-yl)benzene-κN:N]silver(I) dinitrate dihydrate.
abstract: The reaction of 1,4-bis-(4,5-dihydro-1H-imidazol-2-yl)benzene (bib) with silver(I) nitrate in a 1:1 molar ratio generates the metallacyclic title complex, [Ag(2)(C(12)H(14)N(4))(2)](NO(3))(2)·2H(2)O, in which the bib ligand displays a cis configuration. Each bib ligand acts as a bidentate bridging ligand connecting a pair of Ag(I) ions to form a [2 + 2] metallamacrocycle in which the Ag⋯Ag distance is 6.77 (2) Å. Each Ag(I) ion has weak contacts (2.91 Å) with the nitrate anion. The uncoordinated water mol-ecules make hydrogen bonds with nitrate O atoms, forming chains. The H atoms attached to the uncoordinated nitro-gen inter-act with these chains through N-H⋯O hydrogen bonds, forming layers parallel to the (11) plane.
authors.affiliation: School of Chemical and Material Engineering, Jiangnan University, 1800 Lihu Road, Wuxi, Jiangsu Province 214122, People's Republic of China.
authors.forename: Hua
authors.initials: H
authors.lastname: Sun
authors.forename: Chun-Xia
authors.initials: CX
authors.lastname: Ren
authors.forename: Bin
authors.initials: B
authors.lastname: Shen
authors.forename: Zhi-Qiang
authors.initials: ZQ
authors.lastname: Liu
authors.forename: Yu-Qiang
authors.initials: YQ
authors.lastname: Ding