title: Poly[(μ(2)-azido-κN:N)[μ(2)-5-(8-quinolyloxymeth-yl)tetra-zolato-κN,O,N:N]manganese(II)].
abstract: In the structure of the title compound, [Mn(C(11)H(8)N(5)O)(N(3))](n), the Mn atoms are hexa-coordinated by five N atoms and one O atom. The coordination polyhedron of the Mn atom is a slightly distorted octa-hedron. The Mn atoms are connected by azide anions with a μ(2)-1,1 mode and by 5-(8-quinolyloxymeth-yl)tetra-zolate ligands in a μ(2)-η(1)(N),η(3)-(N,N,O) fashion to form a two-dimensional framework parallel to the (100) plane. Geometric parameters of the organic ligand are in the normal ranges and the dihedral angle between the quinoline ring system and the tetra-zole unit is 7.41 (15)°. The structure involves intra- and inter-molecular C-H⋯N hydrogen bonds.
authors.affiliation: Ordered Matter Science Research Center, College of Chemistry and Chemical Engineering, Southeast University, Nanjing 210096, People's Republic of China.
authors.forename: Fang
authors.initials: F
authors.lastname: Chen
authors.forename: Heng-Yun
authors.initials: HY
authors.lastname: Ye