title: 4-Amino-phenyl-sulfur penta-fluoride.
abstract: In the title compound, C(6)H(6)F(5)NS, the environment of the S atom is roughly octa-hedral. The axial F-S bond appears slightly elongated with respect to the four equatorial F-S bonds. Equatorial F atoms are staggered with respect to the benzene ring. The N atom is displaced from the benzene plane by 0.154 (4) Å. The F-S-C-C torsion angles differ greatly from the values observed in the related structure of 4-acetamido-phenyl-sulfur penta-fluoride. The packing is stabil-ized by weak N-H⋯F contacts.
authors.affiliation: Department of Inorganic Chemistry and Technology, Jozef Stefan Institute, Jamova 39 1000 Ljubljana, Slovenia.
authors.forename: Eva Lina
authors.initials: EL
authors.lastname: Nava
authors.forename: Adolf
authors.initials: A
authors.lastname: Jesih
authors.forename: Evgeny
authors.initials: E
authors.lastname: Goreshnik