title: Tetra-kis(N,N-diethyl-carbamato)titanium(IV).
abstract: The mononuclear title compound, [Ti(C(5)H(10)NO(2))(4)], is a rare example of an eight-coordinate Ti(IV) compound in which all donor atoms are O atoms. The coordination geometry around Ti(IV) is pseudo-dodeca-hedral and the O-C-O angles of the carbamate ligands are slightly compressed [range 115.3 (2)-116.7 (2)°], apparently on account of the high coordination number. One ethyl group is disordered over two positions; the site occupancy factors are 0.64 and 0.36.
authors.forename: Nicholas A
authors.initials: NA
authors.lastname: Straessler
authors.forename: M Tyler
authors.initials: MT
authors.lastname: Caudle
authors.forename: Thomas L
authors.initials: TL
authors.lastname: Groy