title: Chlorido{6,6'-dimethyl-2,2'-[1,2-phenyl-enebis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III) mono-hydrate.
abstract: In the title complex, [Mn(C(22)H(18)N(2)O(2))Cl]·H(2)O, the Mn(III) center is in a distorted square-pyramidal configuration, with the N(2)O(2) dianionic tetra-dentate Schiff base ligand in the basal plane and the chloride ion in the apical position. The dihedral angle between the two outer phenolate rings of the tetra-dentate ligand is 8.25 (8)°. The central benzene ring makes dihedral angles of 4.31 (8) and 7.37 (8)° with the two outer phenolate rings. The water mol-ecule links to the complex via an O-H⋯Cl hydrogen bond. In addition, in the crystal structure, weak C-H⋯O inter-actions link the mol-ecules into infinite one-dimensional chains along [010]. The crystal is further stabilized by O-H⋯O and O-H⋯Cl hydrogen bonds, together with weak C-H⋯π inter-actions.
authors.forename: Naser Eltaher
authors.initials: NE
authors.lastname: Eltayeb
authors.forename: Siang Guan
authors.initials: SG
authors.lastname: Teoh
authors.forename: Suchada
authors.initials: S
authors.lastname: Chantrapromma
authors.forename: Hoong-Kun
authors.initials: HK
authors.lastname: Fun
authors.forename: Rohana
authors.initials: R
authors.lastname: Adnan