title: Hexakis(2-amino-4-methyl-pyridine-κN)dioxidohexa-μ(4)-sulfido-hexa-copper(I)divanadium(V).
abstract: The title compound, [Cu(6)V(2)O(2)S(6)(C(6)H(8)N(2))(6)], is constructed from six CuS(3)N and two VOS(3) distorted tetra-hedra, forming an octa-nuclear V/S/Cu cluster with C(i) symmetry. The geometry around the V atoms is slightly distorted tetra-hedral, while there are large distortions from ideal tetra-hedral geometry for the Cu atoms. Adjacent metal-metal distances range from 2.693 (1) to 2.772 (10) Å, indicating weak metal-metal inter-actions in the cluster.
authors.affiliation: Department of Chemistry, Huaiyin Teachers College, Huai'an 223300, Jiangsu, People's Republic of China.
authors.forename: Zhang
authors.initials: Z
authors.lastname: Yu
authors.forename: Guodong
authors.initials: G
authors.lastname: Tang
authors.forename: Jianying
authors.initials: J
authors.lastname: Zhao
authors.forename: Zhengjing
authors.initials: Z
authors.lastname: Jiang