title: Enhanced hydrogen storage by spillover on metal-doped carbon foam: an experimental and computational study.
abstract: A lightweight, oxygen-rich carbon foam was prepared and doped with Pd/Hg alloy nanoparticles. The composite revealed high H2 sorption capacity (5 wt%) at room temperature and moderate pressure (2 MPa). The results were explained on the basis of the H2 spillover mechanism using Density Functional Theory.
authors.affiliation: Department of Chemistry, University of Crete, PO Box 2208, Voutes, Heraklion Crete, 710 03, Greece.
authors.forename: George M
authors.initials: GM
authors.lastname: Psofogiannakis
authors.forename: Theodore A
authors.initials: TA
authors.lastname: Steriotis
authors.forename: Athanassios B
authors.initials: AB
authors.lastname: Bourlinos
authors.forename: Evangellos P
authors.initials: EP
authors.lastname: Kouvelos
authors.forename: Georgia Ch
authors.initials: GCh
authors.lastname: Charalambopoulou
authors.forename: Athanassios K
authors.initials: AK
authors.lastname: Stubos
authors.forename: George E
authors.initials: GE
authors.lastname: Froudakis
mesh_terms: D000042:Absorption; D002244:Carbon / Q000737:chemistry*; D003198:Computer Simulation; D005740:Gases / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry* / Q000302:isolation & purification*; D008628:Mercury / Q000737:chemistry*; D008956:Models, Chemical; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure; D010165:Palladium / Q000737:chemistry*; D010316:Particle Size
chemical_list: D005740:Gases; D010165:Palladium; D002244:Carbon; D006859:Hydrogen; D008628:Mercury