title: Vinyl diazophosphonates as precursors to quaternary substituted indolines and cyclopentenes.
abstract: Vinyl diazophosphonates can be stereoselectively synthesized and, depending upon their substitution pattern, undergo intramolecular C-H insertion reactions or sulfonium ylide rearrangements when exposed to Rh(2)(OAc)(4).
authors.affiliation: Department of Chemistry, University of Utah, 315 South 1400 East, Salt Lake City, Utah 84112, USA.
authors.forename: Jin
authors.initials: J
authors.lastname: Wang
authors.forename: Vyacheslav
authors.initials: V
authors.lastname: Boyarskikh
authors.forename: Jon D
authors.initials: JD
authors.lastname: Rainier
mesh_terms: D001391:Azo Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D003500:Cyclization; D003517:Cyclopentanes / Q000138:chemical synthesis* / Q000737:chemistry; D007211:Indoles / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D063065:Organophosphonates / Q000138:chemical synthesis* / Q000737:chemistry; D014753:Vinyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D001391:Azo Compounds; D003517:Cyclopentanes; D007211:Indoles; D009942:Organometallic Compounds; D063065:Organophosphonates; D014753:Vinyl Compounds; C057812:indoline; C062962:dirhodium tetraacetate