title: Coordination-insertion copolymerization of allyl monomers with ethylene.
abstract: Coordination-insertion copolymerization of allyl monomers with ethylene was developed by using a palladium/phosphine-sulfonate catalyst. A variety of allyl monomers, including allyl acetate, allyl alcohol, protected allylamines, and allyl halides, were copolymerized with ethylene to form highly linear copolymers that possess in-chain -CH(2)CH(CH(2)FG)- units.
authors.affiliation: Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
authors.forename: Shingo
authors.initials: S
authors.lastname: Ito
authors.forename: Masafumi
authors.initials: M
authors.lastname: Kanazawa
authors.forename: Kagehiro
authors.initials: K
authors.lastname: Munakata
authors.forename: Jun-ichi
authors.initials: J
authors.lastname: Kuroda
authors.forename: Yoshikuni
authors.initials: Y
authors.lastname: Okumura
authors.forename: Kyoko
authors.initials: K
authors.lastname: Nozaki