title: Graphene-encapsulated Fe3O4 nanoparticles with 3D laminated structure as superior anode in lithium ion batteries.
abstract: Fe(3)O(4)-graphene composites with three-dimensional laminated structures have been synthesised by a simple in situ hydrothermal method. From field-emission and transmission electron microscopy results, the Fe(3)O(4) nanoparticles, around 3-15 nm in size, are highly encapsulated in a graphene nanosheet matrix. The reversible Li-cycling properties of Fe(3)O(4)-graphene have been evaluated by galvanostatic discharge-charge cycling, cyclic voltammetry and impedance spectroscopy. Results show that the Fe(3)O(4)-graphene nanocomposite with a graphene content of 38.0 wt % exhibits a stable capacity of about 650 mAh  g(-1) with no noticeable fading for up to 100 cycles in the voltage range of 0.0-3.0 V. The superior performance of Fe(3)O(4)-graphene is clearly established by comparison of the results with those from bare Fe(3)O(4). The graphene nanosheets in the composite materials could act not only as lithium storage active materials, but also as an electronically conductive matrix to improve the electrochemical performance of Fe(3)O(4).
authors.affiliation: Institute for Superconducting and Electronic Materials, University of Wollongong, Squires Way, Fairy Meadow, NSW 2519, Australia. jiazhao@uow.edu.au
authors.forename: Jia-Zhao
authors.initials: JZ
authors.lastname: Wang
authors.forename: Chao
authors.initials: C
authors.lastname: Zhong
authors.forename: David
authors.initials: D
authors.lastname: Wexler
authors.forename: Nurul Hayati
authors.initials: NH
authors.lastname: Idris
authors.forename: Zhao-Xiang
authors.initials: ZX
authors.lastname: Wang
authors.forename: Li-Quan
authors.initials: LQ
authors.lastname: Chen
authors.forename: Hua-Kun
authors.initials: HK
authors.lastname: Liu
mesh_terms: D011211:Electric Power Supplies; D004563:Electrochemistry / Q000295:instrumentation* / Q000379:methods; D004566:Electrodes; D052203:Ferrosoferric Oxide / Q000138:chemical synthesis / Q000737:chemistry*; D006108:Graphite / Q000138:chemical synthesis / Q000737:chemistry; D008094:Lithium / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure
chemical_list: D006108:Graphite; D008094:Lithium; D052203:Ferrosoferric Oxide