title: Indenyl-functionalised triethylborane adduct of N-heterocyclic carbene: stepwise coordination of indenyl and NHC ligands toward molybdenum fragment.
abstract: Indenyl-functionalised BEt(3)-adduct NHCs were prepared by the reaction of imidazolium pro-ligands with LiBEt(3)H. This compound was converted into the indenyl-coordinate molybdenum complex dangling the NHC·BEt(3) moiety as a substituent. The stepwise coordination of NHC afforded a chelate-type mononuclear complex as well as a bimetallic complex.
authors.affiliation: Department of Advanced Materials Chemistry, Yokohama National University, Japan.
authors.forename: Daichi
authors.initials: D
authors.lastname: Takaki
authors.forename: Tetsuya
authors.initials: T
authors.lastname: Okayama
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Shuto
authors.forename: Sawako
authors.initials: S
authors.lastname: Matsumoto
authors.forename: Yoshitaka
authors.initials: Y
authors.lastname: Yamaguchi
authors.forename: Shinya
authors.initials: S
authors.lastname: Matsumoto
mesh_terms: D001880:Boranes / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006571:Heterocyclic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D007093:Imidazoles / Q000737:chemistry; D007192:Indenes / Q000737:chemistry*; D008024:Ligands; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D001880:Boranes; D006571:Heterocyclic Compounds; D007093:Imidazoles; D007192:Indenes; D008024:Ligands; D009942:Organometallic Compounds; C030011:carbene; D008982:Molybdenum; D008697:Methane; C079756:triethylborane