title: CdS and CdTeS quantum dot decorated TiO2 nanowires. Synthesis and photoefficiency.
abstract: An easy process was developed to synthesize TiO(2) nanowires sensitized with CdS and CdTeS quantum dots (QDs) requiring no pretreatment of the TiO(2) nanowires prior to nanoparticle generation. CdS and CdTeS nanoparticles were firstly grown by an in situ colloidal method directly onto the TiO(2) surface, hence not requiring subsequent functionalization of the QDs. The resulting nanostructure assembly and composition was confirmed by transmission electron microscopy (TEM), x-ray photoelectron spectroscopy (XPS) and Raman spectroscopy. Successful decoration of the TiO(2) nanowires by the QDs was observed by TEM, while XPS spectra provided clear evidence for the coexistence of CdS and CdTeS QDs and TiO(2) nanowires. The electronic structure of the TiO(2) nanowires was preserved as indicated by Raman spectroscopy. Preliminary photocurrent measurements showed that inclusion of Te in CdS QDs improved the photocurrent efficiency. Compared to bare TiO(2) nanowires, CdS/TiO(2) nanoassemblies showed an enhancement in photocurrent efficiency of 300% while CdTeS/TiO(2) presented an improvement of 350%. This study indicates that the generation of strongly anchored CdS and CdTeS QDs on a TiO(2) nanowire surface is achievable without introduction of a linker molecule, whose presence is known to decrease the electron injection efficiency.
authors.affiliation: Department of Chemical and Biochemical Engineering, Faculty of Engineering, University of Western Ontario, London, ON, Canada. ymedina@uwo.ca
authors.forename: Yaocihuatl
authors.initials: Y
authors.lastname: Medina-Gonzalez
authors.forename: William Z
authors.initials: WZ
authors.lastname: Xu
authors.forename: Bo
authors.initials: B
authors.lastname: Chen
authors.forename: Nasrin
authors.initials: N
authors.lastname: Farhanghi
authors.forename: Paul A
authors.initials: PA
authors.lastname: Charpentier
mesh_terms: D019187:Cadmium Compounds / Q000737:chemistry*; D053770:Nanowires / Q000737:chemistry* / Q000648:ultrastructure; D010316:Particle Size; D055668:Photochemical Processes; D045663:Quantum Dots; D013059:Spectrum Analysis, Raman; D013440:Sulfides / Q000737:chemistry*; D013691:Tellurium / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D019187:Cadmium Compounds; D013440:Sulfides; C034939:cadmium sulfide; C009495:titanium dioxide; D014025:Titanium; D013691:Tellurium; C028337:cadmium telluride