title: A BODIPY-based fluorescent chemodosimeter for Cu(II) driven by an oxidative dehydrogenation mechanism.
abstract: A boradiazaindacene (BODIPY) derivative containing a simple NO bidentate ligand shows a Cu(2+)-selective fluorescence in aqueous media. This is promoted via a coordination of Cu(2+) followed by oxidative dehydrogenation of an amine moiety, leading to a formation of a fluorescent Cu(+)-Schiff base complex.
authors.affiliation: Research Center for Solar Energy Chemistry, Graduate School of Engineering Science, Osaka University, Toyonaka, Japan.
authors.forename: Dongping
authors.initials: D
authors.lastname: Wang
authors.forename: Yasuhiro
authors.initials: Y
authors.lastname: Shiraishi
authors.forename: Takayuki
authors.initials: T
authors.lastname: Hirai
mesh_terms: D001896:Boron Compounds / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D005456:Fluorescent Dyes / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D012545:Schiff Bases / Q000737:chemistry; D013050:Spectrometry, Fluorescence / Q000379:methods*; D013055:Spectrophotometry, Infrared; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: C095489:4,4-difluoro-4-bora-3a,4a-diaza-s-indacene; D001896:Boron Compounds; D005456:Fluorescent Dyes; D009942:Organometallic Compounds; D012545:Schiff Bases; D014874:Water Pollutants, Chemical; D003300:Copper; D006859:Hydrogen