title: Photocatalytic reduction of NO pollutant using an optical-fibre photoreactor at room temperature.
abstract: Photo-assisted catalytic reduction of nitric oxide (NO) was studied over different metal-loaded TiO2 catalysts at room temperature. The activities of metal-loaded (Pt, Ag, Cu) TiO2 photocatalysts, prepared by the sol-gel method, were compared in a batch system using CH4 as the reducing agent. The Pt/TiO2 catalyst showed the highest activity for NO reduction. Thus, Pt/TiO2 was coated on optical fibres and used in a continuous-flow optical-fibre photoreactor. The optical-fibre photoreactor provides light irradiation on the photocatalyst through the optical fibre, thus improving the efficiency ofphotoreactions. Ten per cent conversion of NO was found using CH4 as the reducing agent. The NO conversions increased to 90% in the presence of water vapour and oxygen. However, most NO was oxidized to NO2. Hydrogen had superior reducing capabilities over CH4 on Pt/TiO2 photocatalyst, and the conversion of NO reached 85%. But the conversion of NO was substantially decreased to less than 10% in the presence of water vapour and oxygen. Our research proposed an alternative way to reduce NO pollutant to N2 at room temperature using an optical-fibre photoreactor, which could possibly utilize sunlight in the future.
authors.affiliation: Department of Chemical Engineering, National Taiwan University, Taipei, 10617, Taiwan.
authors.forename: Yi-Hui
authors.initials: YH
authors.lastname: Yu
authors.forename: I-Hsuan
authors.initials: IH
authors.lastname: Su
authors.forename: Jeffrey C S
authors.initials: JC
authors.lastname: Wu
mesh_terms: D000393:Air Pollutants / Q000737:chemistry*; D002384:Catalysis; D002849:Chromatography, Gas; D008855:Microscopy, Electron, Scanning; D009569:Nitric Oxide / Q000737:chemistry*; D055100:Optical Fibers; D010084:Oxidation-Reduction; D010777:Photochemistry; D013696:Temperature; D014961:X-Ray Diffraction
chemical_list: D000393:Air Pollutants; D009569:Nitric Oxide