title: Rhodium-catalyzed tandem heterocyclization and carbonylative [(3+2)+1] cyclization of diyne-enones.
abstract: A simple and highly efficient rhodium-catalyzed tandem heterocyclization and carbonylative [(3+2)+1] cyclization reaction of readily available diyne-enone and carbon monoxide was developed, leading to a novel polycyclic furan scaffold. Synthetically useful highly substituted phenols can also be easily prepared via a straightforward one-pot synthetic strategy.
authors.affiliation: Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, 3663 North Zhongshan Road, Shanghai 200062, P. R. China.
authors.forename: Wanxiang
authors.initials: W
authors.lastname: Zhao
authors.forename: Junliang
authors.initials: J
authors.lastname: Zhang