title: Aqua regia extracted metals in sediments from the industrial area and surroundings of Pančevo, Serbia.
abstract: Surface and buried sediments were analyzed for Ba, Ca, Cd, Co, Cr, Cu, Mn, Ni, Pb, Zn and V, as well as for total carbon and hydrogen to assess the distribution of sediment pollution due to the vicinity of the petrochemical complex. The samples, collected from 20 locations within the petrochemical complex and from 16 locations outside the complex, were aqua regia extracted and analyzed by ICP/OES. Metals were determined with an acceptable accuracy for certified metals of 82-113%. The precision for the aqua regia extraction was satisfactory, less than 20%, except for Cd where it was 28%. Comparison of the data from the petrochemical with those from the non-petrochemical areas showed different distributions of the metals. Metals that exceeded the baseline range; Ba, Cd, Cu, Zn and Pb, were detected in higher concentrations in sediments that were under the influence of the chlor-alkali plant within the petrochemical complex. Comparison with data from the petrochemical complex and its surroundings and their distribution demonstrated that the metal compositions of the sediments were modified by anthropogenic activities.
authors.affiliation: Faculty of Chemistry, Applied Chemistry, University of Belgrade, P.O. Box 51, Belgrade 11158, Serbia. dradman@chem.bg.ac.rs
authors.forename: Dubravka
authors.initials: D
authors.lastname: Relić
authors.forename: Dragana
authors.initials: D
authors.lastname: Đorđević
authors.forename: Sanja
authors.initials: S
authors.lastname: Sakan
authors.forename: Ivan
authors.initials: I
authors.lastname: Anđelković
authors.forename: Srđan
authors.initials: S
authors.lastname: Miletić
authors.forename: Jelena
authors.initials: J
authors.lastname: Đuričić
mesh_terms: D019015:Geologic Sediments / Q000737:chemistry*; D006851:Hydrochloric Acid / Q000737:chemistry*; D007220:Industrial Waste / Q000032:analysis*; D008670:Metals / Q000302:isolation & purification*; D008872:Microwaves; D017942:Nitric Acid / Q000737:chemistry*; D010578:Petroleum / Q000032:analysis; D025341:Principal Component Analysis; D055771:Serbia; D014131:Trace Elements / Q000032:analysis
chemical_list: D007220:Industrial Waste; D008670:Metals; D010578:Petroleum; D014131:Trace Elements; D017942:Nitric Acid; D006851:Hydrochloric Acid; C022102:aqua regia