title: An efficient H2O2-based oxidative bromination of alkenes, alkynes, and aromatics by a divanadium-substituted phosphotungstate.
abstract: A divanadium-substituted phosphotungstate TBA(4)[γ-HPV(2)W(10)O(40)] (TBA = tetra-n-butylammonium) could act as an effective homogeneous catalyst for the H(2)O(2)-based oxidative bromination.
authors.affiliation: Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
authors.forename: Kazuhiro
authors.initials: K
authors.lastname: Yonehara
authors.forename: Keigo
authors.initials: K
authors.lastname: Kamata
authors.forename: Kazuya
authors.initials: K
authors.lastname: Yamaguchi
authors.forename: Noritaka
authors.initials: N
authors.lastname: Mizuno
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D054879:Halogenation; D006841:Hydrocarbons, Aromatic / Q000737:chemistry*; D006842:Hydrocarbons, Brominated / Q000138:chemical synthesis* / Q000737:chemistry; D006861:Hydrogen Peroxide / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010772:Phosphotungstic Acid / Q000737:chemistry*; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D013237:Stereoisomerism; D014639:Vanadium / Q000737:chemistry*
chemical_list: D000475:Alkenes; D000480:Alkynes; D006841:Hydrocarbons, Aromatic; D006842:Hydrocarbons, Brominated; D000644:Quaternary Ammonium Compounds; D014639:Vanadium; D010772:Phosphotungstic Acid; D006861:Hydrogen Peroxide