title: Homeotropic alignment and director structures in thin films of triphenylamine-based discotic liquid crystals controlled by supporting nanostructured substrates and surface confinement.
abstract: We explore the effects of nanoscale morphology of supporting solid substrates on alignment, defects, and director structures exhibited by thin films of triphenylamine-based discotic liquid crystals. Fluorescence confocal polarizing microscopy and intrinsic polarized fluorescence properties of studied molecules are used to visualize three-dimensional director fields in the liquid crystal films. We demonstrate that, by controlling surface anchoring on supporting or confining solid substrates such as those of carbon nanotube electrodes on glass plates, both uniform homeotropic and in-plane (edge-on) alignment and nonuniform structures with developable domains can be achieved for the same discotic liquid crystal material.
authors.affiliation: Department of Chemistry, Assam University, Silchar-788011, Assam, India.
authors.forename: Trirup Dutta
authors.initials: TD
authors.lastname: Choudhury
authors.forename: Nandiraju V S
authors.initials: NV
authors.lastname: Rao
authors.forename: Robert
authors.initials: R
authors.lastname: Tenent
authors.forename: Jeffrey
authors.initials: J
authors.lastname: Blackburn
authors.forename: Brian
authors.initials: B
authors.lastname: Gregg
authors.forename: Ivan I
authors.initials: II
authors.lastname: Smalyukh