title: Heterolytic dissociation of water demonstrated by crystal-to-crystal core interconversion from (μ-oxo)divanadium to bis(μ-hydroxo)divanadium substituted polyoxometalates.
abstract: The heterolytic dissociation of water with the previously unknown four-coordinated syn-linear (μ-oxo)divanadium core to form the five-coordinated bis(μ-hydroxo)divanadium core was confirmed by a crystal-to-crystal transformation.
authors.affiliation: Department of Applied Chemistry, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
authors.forename: Kazuhiro
authors.initials: K
authors.lastname: Uehara
authors.forename: Noritaka
authors.initials: N
authors.lastname: Mizuno