title: A comparative toxicity assessment of materials used in aquatic construction.
abstract: Comparative toxicity testing was performed on selected materials that may be used in aquatic construction projects. The tests were conducted on the following materials: (1) untreated wood species (hemlock [Tsuga ssp], Western red cedar (Thuja plicata), red oak [Quercus rubra], Douglas fir [Pseudotsuga menziesii], red pine [Pinus resinosa], and tamarack [Larix ssp]); (2) plastic wood; (3) Ecothermo wood hemlock stakes treated with preservatives (e.g., chromated copper arsenate [CCA], creosote, alkaline copper quaternary [ACQ], zinc naphthenate, copper naphthenate, and Lifetime Wood Treatment); (4) epoxy-coated steel; (5) hot-rolled steel; (6) zinc-coated steel; and (7) concrete. Those materials were used in acute lethality tests with rainbow trout, Daphnia magna, Vibrio fischeri and threespine stickleback. The results indicated the following general ranking of the materials (from the lowest to highest LC(50) values); ACQ > creosote > zinc naphthenate > copper naphthenate > CCA (treated at 22.4 kg/m(3)) > concrete > red pine > western red cedar > red oak > zinc-coated steel > epoxy-coated steel > CCA (6.4 kg/m(3)). Furthermore, the toxicity results indicated that plastic wood, certain untreated wood species (hemlock, tamarack, Douglas fir, and red oak), hot-rolled steel, Ecothermo wood, and wood treated with Lifetime Wood Treatment were generally nontoxic to the test species.
authors.affiliation: Water Science and Technology Directorate, Environment Canada, 45 Alderney Dr, Dartmouth, NS B2Y 2N6, Canada. benoit.lalonde@ec.gc.ca
authors.forename: Benoit A
authors.initials: BA
authors.lastname: Lalonde
authors.forename: William
authors.initials: W
authors.lastname: Ernst
authors.forename: Gary
authors.initials: G
authors.lastname: Julien
authors.forename: Paula
authors.initials: P
authors.lastname: Jackman
authors.forename: Ken
authors.initials: K
authors.lastname: Doe
authors.forename: Rebecca
authors.initials: R
authors.lastname: Schaefer
mesh_terms: D048908:Aliivibrio fischeri / Q000187:drug effects; D000818:Animals; D001149:Arsenates / Q000032:analysis / Q000633:toxicity; D002264:Carboxylic Acids / Q000032:analysis / Q000633:toxicity; D003252:Construction Materials / Q000633:toxicity*; D003407:Creosote / Q000032:analysis / Q000633:toxicity; D003621:Daphnia / Q000187:drug effects; D004784:Environmental Monitoring / Q000379:methods; D028221:Larix / Q000737:chemistry; D028223:Pinus / Q000737:chemistry; D010969:Plastics / Q000032:analysis / Q000633:toxicity; D028224:Pseudotsuga / Q000737:chemistry; D029963:Quercus / Q000737:chemistry; D029783:Thuja / Q000737:chemistry; D018675:Toxicity Tests / Q000379:methods*; D028225:Tsuga / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000633:toxicity; D014934:Wood / Q000737:chemistry*
chemical_list: D001149:Arsenates; D002264:Carboxylic Acids; D010969:Plastics; D014874:Water Pollutants, Chemical; C092401:copper naphthenate; C040890:chromated copper arsenate; D003407:Creosote