title: New access to (η(5)-cyclohexadienyl)Mn(CO)3 and cationic (η(6)-arene)Mn(CO)3 complexes by Suzuki-Miyaura reaction.
abstract: First Suzuki-Miyaura coupling reactions applied to (η(5)-chloro-cyclohexadienyl)Mn(CO)3 complexes are described and lead to the syntheses of (η(5)-aryl-cyclohexadienyl)Mn(CO)3 and of cationic (η(6)-arene)Mn(CO)3 complexes after rearomatization. The structures of two of the new complexes have been investigated by X-ray diffraction study.
authors.affiliation: UPMC Univ Paris, IPCM, CNRS UMR, France. francoise.rose@upmc.fr
authors.forename: Françoise
authors.initials: F
authors.lastname: Rose-Munch
authors.forename: Alex
authors.initials: A
authors.lastname: Marti
authors.forename: Derya
authors.initials: D
authors.lastname: Cetiner
authors.forename: Jean-Philippe
authors.initials: JP
authors.lastname: Tranchier
authors.forename: Eric
authors.initials: E
authors.lastname: Rose
mesh_terms: D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: C558269:(eta(5)-cyclohexadienyl)Mn(CO)3; D009942:Organometallic Compounds