title: Core-shell nanoparticle based SERS from hydrogen adsorbed on a rhodium(111) electrode.
abstract: We present the first in situ surface Raman spectra of hydrogen on rhodium under electrochemical conditions using gold-core rhodium-shell (Au@Rh) nanoparticles for SERS or gold-core silica-shell (Au@SiO(2)) nanoparticles for SHINERS. The advantage of SHINERS lies in the versatility to study single crystal surfaces such as the H-Rh(111) system.
authors.affiliation: State Key Laboratory of Physical Chemistry of Solid Surfaces and College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005, China.
authors.forename: Jian-Feng
authors.initials: JF
authors.lastname: Li
authors.forename: Jason R
authors.initials: JR
authors.lastname: Anema
authors.forename: Ying-Chao
authors.initials: YC
authors.lastname: Yu
authors.forename: Zhi-Lin
authors.initials: ZL
authors.lastname: Yang
authors.forename: Yi-Fan
authors.initials: YF
authors.lastname: Huang
authors.forename: Xiao-Shun
authors.initials: XS
authors.lastname: Zhou
authors.forename: Bin
authors.initials: B
authors.lastname: Ren
authors.forename: Zhong-Qun
authors.initials: ZQ
authors.lastname: Tian