title: Crystal structures, EPR and magnetic properties of 2-ClC6H4CNSSN˙ and 2,5-Cl2C6H3CNSSN˙.
abstract: The β-sheet structure associated with chlorinated aromatics (d(Cl···Cl)≈ 4.0 Å) has been implemented to drive formation of π-stacked structures of dithiadiazolyl radicals. Both title compounds exhibit an increase in paramagnetism above 150 K but solid-state EPR studies indicate that the origin of the paramagnetism in these two systems is different.
authors.affiliation: Departamento De Quimica Fisica I Analitica-Quimica Fisica, Universitat Jaume I, Castello de la Plana, Spain.
authors.forename: Antonio
authors.initials: A
authors.lastname: Alberola
authors.forename: Emma
authors.initials: E
authors.lastname: Carter
authors.forename: Christos P
authors.initials: CP
authors.lastname: Constantinides
authors.forename: Dana J
authors.initials: DJ
authors.lastname: Eisler
authors.forename: Damien M
authors.initials: DM
authors.lastname: Murphy
authors.forename: Jeremy M
authors.initials: JM
authors.lastname: Rawson