A cubic, 12-connected, microporous metal-organometallic phosphate framework sustained by truncated tetrahedral nodes.
A rare example of a microporous metal-organic phosphate, [Co(12)(L)(6)(μ(3)-PO(4))(4)(μ(3)-F)(4)(μ-H(2)O)(6)][NO(3)](2) (1), is synthesized by the reaction of a [(η(5)-C(5)H(5))Fe(II)](+)-functionalized terephthalate ligand with Co(NO(3))(2)·6H(2)O and phosphate and fluoride ions generated from the in situ hydrolysis of hexafluorophosphate. 1 is a cubic, 12-connected, face-centered cubic framework sustained by the linear connection of unprecedented, dodecanuclear truncated tetrahedral coordination clusters.
Department of Chemistry, Georgetown University, Washington, DC 20057, United States.
Sayon A Kumalah
SA
Robinson
Marion-Vincent L
MV
Mempin
Amy J
AJ
Cairns
K Travis
KT
Holman