31P,89Y shift correlation. Application to the speciation of yttrium complexes with triphenylphosphine oxide.
Correlation experiments between (89)Y and (31)P nuclei through scalar coupling using (31)P detection are described for the first time. The utility of the new method of characterizing (89)Y is demonstrated by identifying the species formed in the reaction of yttrium nitrate with triphenylphosphine oxide in THF solution.
Área de Química Orgánica, Universidad de Almería, Carretera de Sacramento, 04120, Almería, Spain.
Ignacio
I
Fernández
Víctor
V
Yañez-Rodríguez
Fernando
F
López Ortiz