Thermal expansivity of ionic clathrate hydrates including gaseous guest molecules.
Although thermal expansion is a key factor in relation to the host-guest interaction of clathrate hydrates, few studies have investigated the thermal behavior of ionic clathrate hydrates. The existence of ionic species in these hydrates creates a unique host-guest interaction compared to that of nonionic clathrate hydrates. It was revealed that X-ray diffraction cannot be used for research of tetramethylammonium hydroxide clathrate hydrates due to damage of the cations by the X-ray, which results in abnormal thermal expansion of the ionic clathrate hydrates. Hence, in the present work, the thermal expansivities of binary sII Me(4)NOD·16D(2)O and sI DClO(4)·5.5D(2)O were measured by neutron powder diffraction (NPD) in order to shed light on their thermal behavior. General correlations for the thermal behaviors of given structures were established and lattice expansions depending on the guests were compared between ionic and nonionic clathrate hydrates. The peculiar change in the thermal expansivity of binary DClO(4)·5.5D(2)O was also considered in relation to the host-guest configuration.
Department of Chemical and Biomolecular Engineering (BK21 Program), Graduate School of EEWS, Korea Advanced Institute of Science and Technology (KAIST), Yuseong-gu, Daejeon, Republic of Korea.
Kyuchul
K
Shin
Wonhee
W
Lee
Minjun
M
Cha
Dong-Yeun
DY
Koh
Yong Nam
YN
Choi
Heeju
H
Lee
Bae Soon
BS
Son
Seongsu
S
Lee
Huen
H
Lee