A concise total synthesis of (±)-cipadonoid B from synthetic azedaralide.
The tetranortriterpene cipadonoid B was efficiently constructed from synthetic azedaralide in a one-pot cascade, via the underutilised ketal-Claisen rearrangement.
School of Chemistry and Molecular Biosciences, University of Queensland, Brisbane, 4072, Queensland, Australia.
Jonathan M
JM
Faber
Craig M
CM
Williams
D018360:Crystallography, X-Ray; D036701:Limonins / Q000138:chemical synthesis* / Q000737:chemistry; D008968:Molecular Conformation; D013237:Stereoisomerism; D014315:Triterpenes / Q000138:chemical synthesis / Q000737:chemistry*
D036701:Limonins; D014315:Triterpenes