A well-defined silica-supported aluminium alkyl through an unprecedented, consecutive two-step protonolysis-alkyl transfer mechanism.
Impregnation of [(AliBu(3))(Et(2)O)] on partially dehydroxylated SBA-15 affords a mesoporous material bearing the well-defined single site surface aluminium species [(≡SiO)(2)Al(iBu)(Et(2)O)].
Chimie Organométallique de Surface/Laboratoire de Chimie, Catalyse, Polymères et Procédés (UMR-C2P2-5265 CNRS/ESCPE-Lyon/UCBL) ESCPE Lyon, F-308-43, Boulevard du 11 Novembre 1918, F-69616, Villeurbanne Cedex, France.
Jérémie
J
Pelletier
Jeff
J
Espinas
Nghiem
N
Vu
Sébastien
S
Norsic
Anne
A
Baudouin
Laurent
L
Delevoye
Julien
J
Trébosc
Erwan
E
Le Roux
Catherine
C
Santini
Jean-Marie
JM
Basset
Régis M
RM
Gauvin
Mostafa
M
Taoufik