Extreme conditions during multibubble cavitation: Sonoluminescence as a spectroscopic probe.
We review recent work on the use of sonoluminescence (SL) to probe spectroscopically the conditions created during cavitation, both in clouds of collapsing bubbles (multibubble sonoluminescence, (MBSL)) and in single bubble events. The effective MBSL temperature can be controlled by the vapor pressure of the liquid or the thermal conductivity of the dissolved gas over a range from ∼1600 to ∼9000K. The effective pressure during MBSL is ∼300bar, based on atomic line shifts. Given nanosecond emission times, this means that cooling rates are >10(12)K/s. In sulfuric and phosphoric acid, the low volatility and high solubility of any sonolysis products make bubble collapse more efficient and evidence for an optically opaque plasma core is found.
Department of Chemistry, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, IL 61801, USA. ksuslick@uiuc.edu
Kenneth S
KS
Suslick
Nathan C
NC
Eddingsaas
David J
DJ
Flannigan
Stephen D
SD
Hopkins
Hangxun
H
Xu