Direct covalent post-synthetic chemical modification of Cr-MIL-101 using nitrating acid.
For the first time, functionality has been covalently introduced into the Cr-MIL-101 network by post-synthetic modification of the terephthalate linker molecule through nitration. The nitro group was reduced and the amino group was reacted with ethyl isocyanate to yield the corresponding urea derivative.
Institut für Anorganische Chemie, Christian-Albrechts-Universität zu Kiel, 24118 Kiel, Germany.
Stephan
S
Bernt
Vincent
V
Guillerm
Christian
C
Serre
Norbert
N
Stock