Rapid nickel-catalyzed Suzuki-Miyaura cross-couplings of aryl carbamates and sulfamates utilizing microwave heating.
High-speed and scalable nickel-catalyzed cross-coupling of arylboronic acids with aryl carbamates and sulfamates is achieved by using sealed-vessel microwave processing.
Christian Doppler Laboratory for Microwave Chemistry (CDLMC) and Institute of Chemistry, Karl-Franzens-University, Graz, Heinrichstrasse 28, 8010 Graz, Austria.
Mostafa
M
Baghbanzadeh
Christian
C
Pilger
C Oliver
CO
Kappe
D000611:Aminobiphenyl Compounds / Q000138:chemical synthesis / Q000737:chemistry; D001897:Boronic Acids / Q000737:chemistry; D002219:Carbamates / Q000737:chemistry*; D002384:Catalysis; D008872:Microwaves; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009570:Nitriles / Q000138:chemical synthesis / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D013451:Sulfonic Acids / Q000737:chemistry*
D000611:Aminobiphenyl Compounds; D001897:Boronic Acids; D002219:Carbamates; D009570:Nitriles; D009942:Organometallic Compounds; D013451:Sulfonic Acids; D009532:Nickel; C005741:sulfamic acid; C014356:benzonitrile