A new nano-TiO2 immobilized biodegradable polymer with self-cleaning properties.
This study concentrated on the direct immobilization of anatase nano titanium dioxide particles (TiO(2), 10nm particle size) into or onto a biodegradable polymer, polycaprolactone, by solvent-cast processes. The self-cleaning, namely photocatalytic properties of the produced materials were tested by photocatalytic removal of methylene blue as model compound and antimicrobial properties were investigated using Candida albicans as model microorganism. Produced TiO(2) immobilized polymer successfully removed methylene blue (MB, 1 × 10(-5)M) from aqueous solution without additional pH arrangement employing a UV-A light (365 nm) source. Almost 83.2% of dye was removed or decomposed by 5 wt% TiO(2) immobilized into PCL (0.08 g) and removal percentage reached to 94.2% with 5 wt% TiO(2) immobilized onto PCL after a 150 min exposure period. Although removal percentage decrease with increased ionic strength and usage of a visible light source, produced materials were still effective. TiO(2) immobilized onto PCL (5 wt%) was quite effective killing almost 54% of C. albicans (2 × 10(6)CFU/mL) after only 60 min exposure with a near visible light source. Control experiments employing PCL alone in the presence and absence of light were ineffective under the same condition.
Department of Chemistry, Faculty of Science, Karadeniz Technical University, 61080 Trabzon, Turkey.
Münevver
M
Sökmen
Ilknur
I
Tatlıdil
Chris
C
Breen
Francis
F
Clegg
Celal Kurtuluş
CK
Buruk
Tuğba
T
Sivlim
Senay
S
Akkan
D002384:Catalysis; D053768:Metal Nanoparticles; D008855:Microscopy, Electron, Scanning; D011108:Polymers / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*
D011108:Polymers; C009495:titanium dioxide; D014025:Titanium