Palladium-catalyzed C-H aminations of anilides with N-fluorobenzenesulfonimide.
The first amide-directed, palladium-catalyzed, intermolecular, highly selective C-H aminations with the non-nitrene-based nitrogen source N-fluorobenzenesulfonimide have been developed. This methodology might provide a new pathway for directed metal-catalyzed aromatic C-H amination.
Department of Chemistry, Northeast Normal University, Changchun 130024, China.
Kai
K
Sun
Yan
Y
Li
Tao
T
Xiong
Jingping
J
Zhang
Qian
Q
Zhang