Catalytic dehydrocoupling of Me2NHBH3 with Al(NMe2)3.
The catalytic dehydrocoupling reaction of Me(2)NHBH(3) with Al(NMe(2))(3) gives the dimer [Me(2)NBH(2)](2) and the chain [(Me(2)N)(2)BH], involving the thermally-stable Al(III) hydride catalyst [{(Me(2)N)(2)BH(2)}(2)AlH].
Chemistry Department, Cambridge University, Cambridge, UK.
Hugh J
HJ
Cowley
Mark S
MS
Holt
Rebecca L
RL
Melen
Jeremy M
JM
Rawson
Dominic S
DS
Wright
D000641:Ammonia / Q000737:chemistry; D001880:Boranes / Q000737:chemistry*; D002384:Catalysis; D019281:Dimerization; D008968:Molecular Conformation
D001880:Boranes; D000641:Ammonia