Synthesis of cis,syndiotactic ROMP polymers containing alternating enantiomers.
Ring-opening metathesis polymerization (ROMP) of rac-endo,exo-5,6-dicarbomethoxynorbornene (inter alia) yields a cis,syndio,alt-polymer, one in which the sequential units in the cis,syndiotactic polymer consist of alternating enantiomers. Cis selectivity arises through addition of the monomer to produce an all-cis-metallacyclobutane intermediate, while syndioselectivity and alternating enantiomer structures arise as a consequence of inversion of configuration at the metal center with each metathesis step.
Department of Chemistry 6-331, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139, United States.
Margaret M
MM
Flook
Victor W L
VW
Ng
Richard R
RR
Schrock