Organoiodine(V) reagents in organic synthesis.
Organohypervalent iodine reagents have attracted significant recent interest as versatile and environmentally benign oxidants with numerous applications in organic synthesis. This Perspective summarizes synthetic applications of hypervalent iodine(V) reagents: 2-iodoxybenzoic acid (IBX), Dess-Martin periodinane (DMP), pseudocyclic iodylarenes, and their recyclable polymer-supported analogues. Recent advances in the development of new catalytic systems based on the generation of hypervalent iodine species in situ are also overviewed.
Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, Minnesota 55812, USA. vzhdanki@d.umn.edu
Viktor V
VV
Zhdankin
D007202:Indicators and Reagents / Q000138:chemical synthesis / Q000737:chemistry; D007462:Iodobenzenes / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D013237:Stereoisomerism
D007202:Indicators and Reagents; D007462:Iodobenzenes