Restricted rotation due to the lack of free space within a capsule translates into product selectivity: photochemistry of cyclohexyl phenyl ketones within a water-soluble organic capsule.
The rotational mobility of organic guest molecules when included within a confined capsule is restricted and this feature could be translated into product selectivity as established with the photochemical behavior of cyclohexyl phenyl ketones.
Department of Chemistry, University of Miami, Coral Gables, FL 33124, USA.
Revathy
R
Kulasekharan
Rajib
R
Choudhury
Rajeev
R
Prabhakar
V
V
Ramamurthy