[Thermodynamics adsorption and its influencing factors of chlorpyrifos and triazophos on the bentonite and humus].
The adsorption of chlorpyrifos and triazophos on bentonite and humus was investigated by using the equilibrium oscillometry. The adsorption capacity of chlorpyrifos and triazophos on humus was great higher than bentonite at the same concentration. Equilibrium data of Langmuir, Freundlich isotherms showed significant relationship to the adsorption of chlorpyrifos and triazophos on humus (chlorpyrifos: R2 0.996 4, 0.996 3; triazophos: R2 0.998 9, 0.992 4). Langmuir isotherm was the best for chlorpyrifos and triazophos on bentonite (chlorpyrifos: R2 = 0.995 7, triazophos: R2 = 0.998 9). The pH value, adsorption equilibrium time and temperature were the main factors affecting adsorption of chlorpyrifos and triazophos on bentonite and humus. The adsorption equilibrium time on mixed adsorbent was 12h for chlorpyrifos and 6h for triazophos respectively. The mass ratio of humus and bentonite was 12% and 14% respectively, the adsorption of chlorpyrifos and triazophos was the stronglest and tended to saturation. At different temperatures by calculating the thermodynamic parameters deltaG, deltaH and deltaS, confirmed that the adsorption reaction was a spontaneous exothermic process theoretically. The adsorption was the best when the pH value was 6.0 and the temperature was 15 degrees C.
College of Science, Nanjing Forestry University, Nanjing 210037, China. lxyzlj@njfu.edu.cn
Li-Jun
LJ
Zhu
Wei
W
Zhang
Jin-Chi
JC
Zhang
De-Xin
DX
Zai
Rong
R
Zhao
D000327:Adsorption; D001546:Bentonite / Q000737:chemistry*; D004390:Chlorpyrifos / Q000737:chemistry / Q000302:isolation & purification*; D004785:Environmental Pollutants / Q000737:chemistry / Q000302:isolation & purification; D006812:Humic Substances / Q000032:analysis*; D063086:Organothiophosphates / Q000737:chemistry / Q000302:isolation & purification*; D013816:Thermodynamics; D014230:Triazoles / Q000737:chemistry / Q000302:isolation & purification*
D004785:Environmental Pollutants; D006812:Humic Substances; D063086:Organothiophosphates; D014230:Triazoles; D001546:Bentonite; C012584:triazophos; D004390:Chlorpyrifos