Numerical analysis of relaxation times of multiple quantum coherences in the system with a large number of spins.
We study the decay of multiple quantum (MQ) NMR coherences in systems with the large number of equivalent spins. As being created on the preparation period of the MQ NMR experiment, they decay due to the dipole-dipole interactions (DDI) on the evolution period of this experiment. It is shown that the relaxation time decreases with the increase in MQ coherence order (according to the known results) and in the number of spins. We also consider the modified preparation period of the MQ NMR experiment [G. A. Alvarez and D. Suter, Phys. Rev. Lett. 104, 230403 (2010)] concatenating the short evolution periods under the secular DDI Hamiltonian (the perturbation) with the evolution period under the nonsecular averaged two-spin/two-quantum Hamiltonian. The influence of the perturbation on the decoherence rate is investigated for the systems consisting of 200-600 equivalent spins.
Institute of Problems of Chemical Physics, Russian Academy of Sciences, Chernogolovka, Moscow Region, 142432, Russia. s.i.doronin@gmail.com
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Doronin
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Fel'dman
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Zenchuk
D009682:Magnetic Resonance Spectroscopy; D011789:Quantum Theory