title: Poly[μ3-hydroxido-μ6-sulfato-μ3-(1,2,4-triazolato-κ3N1:N2:N4)-dicadmium(II)]: a cadmium-triazolate coordination polymer with a pseudo-cubane-like tetranuclear cluster.
abstract: The title complex, [Cd(2)(C(2)H(2)N(3))(OH)(SO(4))](n), is a three-dimensional metal-organic framework consisting of pseudo-cubane-like tetranuclear cadmium clusters, which are formed by four Cd(II) atoms, two sulfate groups and two hydroxide groups. The tetranuclear cadmium clusters are connected into a layered substructure by Cd-O bonds and adjacent layers are linked by triazolate ligands into a three-dimensional network. A photoluminescent study revealed that the complex exhibits a strong emission in the visible region which probably originates from a π-π* transition.
authors.affiliation: State Key Laboratory Breeding Base of Photocatalysis, College of Chemistry and Chemical Engineering, Fuzhou University, Fujian, People's Republic of China.
authors.forename: Qian
authors.initials: Q
authors.lastname: Liang
authors.forename: Tong-Hen
authors.initials: TH
authors.lastname: Pan
authors.forename: Chang-Cang
authors.initials: CC
authors.lastname: Huang