title: Reactive compatibilization of polycarbonate and poly(methyl methacrylate) in the presence of a novel transesterification catalyst SnCl2·2H2O.
abstract: We compare the effectiveness of various known organometallic transesterification catalysts with a novel SnCl(2)·2H(2)O transesterification catalyst in the formation of homogeneous PC/PMMA blends with single T(g). It is shown that SnCl(2)·2H(2)O works more efficiently than the other organometallic transesterification catalysts. Even 0.1% (wt/wt) of SnCl(2)·2H(2)O is enough to establish an interaction between PC and PMMA phases, leading to the formation of a homogeneous PC/PMMA blend with single T(g) and single degradation temperature. FTIR, (1)H NMR, and XRD studies provide evidence of the formation of PC-g-PMMA graft copolymer, which acts as a compatibilizer between the PC and PMMA phases. A significant improvement in the optical transparency of the PC/10PMMA blend prepared using SnCl(2)·2H(2)O catalyst as compared with PC/10PMMA without any catalyst is observed. There is also a change in the morphology from granular in uncompatibilized blends to lamellar in the compatibilized blends.
authors.affiliation: School of Materials Science & Technology, Institute of Technology, Banaras Hindu University, Varanasi-221005, India.
authors.forename: A K
authors.initials: AK
authors.lastname: Singh
authors.forename: Rajiv
authors.initials: R
authors.lastname: Prakash
authors.forename: Dhananjai
authors.initials: D
authors.lastname: Pandey
mesh_terms: D002384:Catalysis; D011076:Polycarboxylate Cement / Q000737:chemistry*; D019904:Polymethyl Methacrylate / Q000737:chemistry*; D013696:Temperature; D017971:Tin Compounds / Q000737:chemistry*
chemical_list: D011076:Polycarboxylate Cement; D017971:Tin Compounds; C023599:stannous chloride; C005506:polycarbonate; D019904:Polymethyl Methacrylate