title: Unexpected preparation of (Z)-chloromethyleneketals and their sulfur analogues by a novel three-component condensation.
abstract: A novel multicomponent condensation, leading to the rare (Z)-chloromethyleneketals and their sulfur analogues, has been discovered. The mechanism of this reaction has been studied in some detail and subsequent modifications were performed on the adducts, leading to unusual Umpolung transforms.
authors.affiliation: Université catholique de Louvain, Bâtiment Lavoisier, Place Louis Pasteur 1 bte2, 1348 Louvain-la-Neuve, Belgium. Florian.schevenels@uclouvain.be
authors.forename: Florian
authors.initials: F
authors.lastname: Schevenels
authors.forename: István E
authors.initials: IE
authors.lastname: Markó
mesh_terms: D002384:Catalysis; D007659:Ketones / Q000737:chemistry*; D008670:Metals / Q000737:chemistry; D013237:Stereoisomerism; D013455:Sulfur / Q000737:chemistry*
chemical_list: D007659:Ketones; D008670:Metals; D013455:Sulfur