title: Azonium-ammonium tautomerism and inclusion complexation of 1-(2,4-diamino phenylazo) naphthalene and 4-aminoazobenzene.
abstract: Spectral characteristics of 1-(2,4-diamino phenylazo) naphthalene (FBRR, fat brown RR) and 4-aminoazobenzene (AAB) have been studied in various solvents, varying hydrogen ion concentrations and in β-cyclodextrin (β-CD). The inclusion complex of FBRR and AAB with β-CD were analysed by UV-visible, fluorometry and CAche-DFT methods. Solvent study reveals that only azo tautomer is present in both compounds and the large red shifted absorption and emission maxima of FBRR indicate naphthalene ring effectively increases the π-π* transition. Unusual red shift is observed in acid solutions suggests azonium-ammonium tautomer is present in both molecules. In β-CD solutions, the large hypsochromic shift is observed in S(0) and S(1) states indicates ortho amino group of FBRR molecule is entrapped in the β-CD cavity and the large bathochromic shift for AAB in the S(1) state indicates 1:1 inclusion complex is formed.
authors.affiliation: Department of Chemistry, Annamalai University, Annamalai Nagar 608 002 Tamilnadu, India.
authors.forename: G
authors.initials: G
authors.lastname: Venkatesh
authors.forename: A Antony Muthu
authors.initials: AA
authors.lastname: Prabhu
authors.forename: N
authors.initials: N
authors.lastname: Rajendiran
mesh_terms: D001391:Azo Compounds / Q000737:chemistry*; D005453:Fluorescence; D006863:Hydrogen-Ion Concentration; D009281:Naphthalenes / Q000737:chemistry*; D011789:Quantum Theory; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*; D013816:Thermodynamics; D047392:beta-Cyclodextrins / Q000737:chemistry; D010128:p-Aminoazobenzene / Q000737:chemistry*
chemical_list: C568744:1-(2,4-diamino phenylazo)naphthalene; D001391:Azo Compounds; D009281:Naphthalenes; D000644:Quaternary Ammonium Compounds; D047392:beta-Cyclodextrins; D010128:p-Aminoazobenzene; C031215:betadex