title: Enantioselective/anion-selective incorporation of tris(ethylenediamine) complexes into 2D coordination spaces between tripalladium(II) supramolecular layers with D-penicillaminate.
abstract: The formation of a cocrystallized coordination compound, [Pd(3)(D-pen)(3)](2)·[M(en)(3)](ClO(4))(3) (D-H(2)pen = D-penicillamine; M = Co(III) or Rh(III)), from [Pd(3)(D-pen)(3)] and [M(en)(3)](ClO(4))(3) is reported. In this compound, only the Δ-configurational [M(en)(3)](3+) cations were incorporated when its racemic (Δ/Λ) isomer was employed. Besides this enantioselective incorporation of complex cations, this compound was found to show the selective incorporation of ClO(4)(-) as the anion species.
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.
authors.forename: Yusuke
authors.initials: Y
authors.lastname: Hirai
authors.forename: Yoshinori
authors.initials: Y
authors.lastname: Nagao
authors.forename: Asako
authors.initials: A
authors.lastname: Igashira-Kamiyama
authors.forename: Takumi
authors.initials: T
authors.lastname: Konno
mesh_terms: D000838:Anions / Q000737:chemistry; D018360:Crystallography, X-Ray; D005029:Ethylenediamines / Q000737:chemistry*; D046911:Macromolecular Substances / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010396:Penicillamine / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000838:Anions; D005029:Ethylenediamines; D046911:Macromolecular Substances; D009942:Organometallic Compounds; D010165:Palladium; C031234:ethylenediamine; D010396:Penicillamine