title: Experimental and theoretical study of a Diels-Alder reaction between a sugar-derived nitroalkene and cyclopentadiene.
abstract: The Diels-Alder reaction of a pyranose-derived nitroalkene 1 with cyclopentadiene is described, and the unexpected facial selectivity of the cycloaddition is analyzed by a computational study.
authors.affiliation: Instituto de Química de Rosario, Facultad de Ciencias Bioquímicas y Farmacéuticas, Universidad Nacional de Rosario-CONICET, Suipacha 531, Rosario, Argentina.
authors.forename: María I
authors.initials: MI
authors.lastname: Mangione
authors.forename: Ariel M
authors.initials: AM
authors.lastname: Sarotti
authors.forename: Alejandra G
authors.initials: AG
authors.lastname: Suárez
authors.forename: Rolando A
authors.initials: RA
authors.lastname: Spanevello
mesh_terms: D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000737:chemistry*; D002241:Carbohydrates / Q000737:chemistry*; D003517:Cyclopentanes / Q000737:chemistry*; D008956:Models, Chemical; D015394:Molecular Structure; D009574:Nitro Compounds / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D019086:Bridged Bicyclo Compounds, Heterocyclic; D002241:Carbohydrates; D003517:Cyclopentanes; D009574:Nitro Compounds