title: An Efficient Synthesis of de novo Imidates via Aza-Claisen Rearrangements of N-Allyl Ynamides.
abstract: A novel thermal 3-aza-Claisen rearrangement of N-allyl ynamides for the synthesis of α-allyl imidates is described. Also, a sequential aza-Claisen, Pd-catalyzed Overman rearrangement is described for the synthesis of azapine-2-ones.
authors.affiliation: Division of Pharmaceutical Sciences and Department of Chemistry, 777 Highland Avenue, Rennebohm Hall, University of Wisconsin, Madison, WI 53705.
authors.forename: Kyle A
authors.initials: KA
authors.lastname: Dekorver
authors.forename: Troy D
authors.initials: TD
authors.lastname: North
authors.forename: Richard P
authors.initials: RP
authors.lastname: Hsung