title: On the significance of the anchoring group in the design of antenna materials based on phthalocyanine stopcocks and zeolite L.
abstract: The synthesis of stopcocks based on zinc phthalocyanine for selective adsorption at the channel entrances of zeolite L is reported. The introduction of either an inert SiMe₃ moiety, an imidazolium cation or a reactive isothiocyanate (NCS) group allows attachment to the channel entrances of zeolite L through van der Waals interactions, electrostatic interactions, or covalent binding, respectively. Stopcocks that rely on van-der-Waals-driven adsorption require careful selection of the solvent used for the deposition onto the zeolite surface to avoid a nonspecific distribution of the molecules. Regarding the design of photonic antenna systems, a stopcock with a cationic tail was found to be the most convenient, based on the observation that efficient energy transfer from molecules located in the zeolite nanochannels is more readily obtained than in the other cases.
authors.affiliation: Departamento de Química Orgánica, Universidad Autonoma de Madrid, Cantoblanco, 28049 Madrid, Spain.
authors.forename: Ismael
authors.initials: I
authors.lastname: López-Duarte
authors.forename: Le-Quyenh
authors.initials: LQ
authors.lastname: Dieu
authors.forename: Igor
authors.initials: I
authors.lastname: Dolamic
authors.forename: M Victoria
authors.initials: MV
authors.lastname: Martínez-Díaz
authors.forename: Tomás
authors.initials: T
authors.lastname: Torres
authors.forename: Gion
authors.initials: G
authors.lastname: Calzaferri
authors.forename: Dominik
authors.initials: D
authors.lastname: Brühwiler