title: Electrochemical sulfide removal from synthetic and real domestic wastewater at high current densities.
abstract: Hydrogen sulfide generation is the key cause of sewer pipe corrosion, one of the major issues in water infrastructure. Current abatement strategies typically involve addition of various types of chemicals to the wastewater, which incurs large operational costs. The transport, storage and application of these chemicals also constitute occupational and safety hazards. In this study, we investigated high rate electrochemical oxidation of sulfide at Ir/Ta mixed metal oxide (MMO) coated titanium electrodes as a means to remove sulfide from wastewater. Both synthetic and real wastewaters were used in the experiments. Electrochemical sulfide oxidation by means of indirect oxidation with in-situ produced oxygen appeared to be the main reaction mechanism at Ir/Ta MMO coated titanium electrodes. The maximum obtained sulfide removal rate was 11.8 ± 1.7 g S m(-2) projected anode surface h(-1) using domestic wastewater at sulfide concentrations of ≥ 30 mg L(-1) or higher. The final products of the oxidation were sulfate, thiosulfate and elemental sulfur. Chloride and acetate concentrations did not entail differences in sulfide removal, nor were the latter two components affected by the electrochemical oxidation. Hence, the use of electrodes to generate oxygen in sewer systems may constitute a promising method for reagent-free removal of sulfide from wastewater.
authors.affiliation: The University of Queensland, Advanced Water Management Centre (AWMC), St. Lucia, QLD 4072, Australia.
authors.forename: Ilje
authors.initials: I
authors.lastname: Pikaar
authors.forename: René A
authors.initials: RA
authors.lastname: Rozendal
authors.forename: Zhiguo
authors.initials: Z
authors.lastname: Yuan
authors.forename: Jürg
authors.initials: J
authors.lastname: Keller
authors.forename: Korneel
authors.initials: K
authors.lastname: Rabaey
mesh_terms: D000085:Acetates / Q000737:chemistry; D002021:Buffers; D002712:Chlorides / Q000737:chemistry; D004560:Electricity; D055664:Electrochemical Techniques / Q000379:methods*; D004583:Electrons; D010084:Oxidation-Reduction; D013440:Sulfides / Q000302:isolation & purification*; D014131:Trace Elements / Q000737:chemistry; D014865:Waste Disposal, Fluid; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods*
chemical_list: D000085:Acetates; D002021:Buffers; D002712:Chlorides; D013440:Sulfides; D014131:Trace Elements; D014874:Water Pollutants, Chemical