title: Single-crystal-to-single-crystal transformations and selective adsorption of porous copper(II) frameworks.
abstract: A unique 4-fold interpenetrated (10,3)-b copper(II) framework exhibits reversible dehydration and rehydration in a single-crystal-to-single-crystal (SC-SC) process, and the dehydrated material can encapsulate CH(3)OH molecules, again in a SC-SC fashion, and shows selective adsorption of H(2) and CO(2) over N(2).
authors.affiliation: Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, China.
authors.forename: Man-Sheng
authors.initials: MS
authors.lastname: Chen
authors.forename: Min
authors.initials: M
authors.lastname: Chen
authors.forename: Satoshi
authors.initials: S
authors.lastname: Takamizawa
authors.forename: Taka-aki
authors.initials: TA
authors.lastname: Okamura
authors.forename: Jian
authors.initials: J
authors.lastname: Fan
authors.forename: Wei-Yin
authors.initials: WY
authors.lastname: Sun
mesh_terms: D000327:Adsorption; D002245:Carbon Dioxide / Q000302:isolation & purification*; D003300:Copper / Q000737:chemistry*; D003460:Crystallization; D006859:Hydrogen / Q000302:isolation & purification*; D008958:Models, Molecular; D009584:Nitrogen / Q000302:isolation & purification; D016062:Porosity
chemical_list: D002245:Carbon Dioxide; D003300:Copper; D006859:Hydrogen; D009584:Nitrogen