title: Silver- and gold-mediated domino transformation: a strategy for synthesizing benzo[e]indolo[1,2-a]pyrrolo/pyrido[2,1-c][1,4]diazepine-3,9-diones.
abstract: We reported a strategy for the synthesis of fused heterocyclic compounds benzo[e]indolo[1,2-a]pyrrolo/pyrido[2,1-c][1,4]diazepine-3,9-diones via an AgSbF(6)/gold-complex catalyzed one-pot cascade transformation. The strategy is tolerant of a broad range of substrates and affords a series of intriguing fused diazepinedione heterocycles.
authors.affiliation: State Key Laboratory of Drug Research, Shanghai Institute of Materia Medica, Chinese Academy of Sciences, Shanghai 201203, China.
authors.forename: Yu
authors.initials: Y
authors.lastname: Zhou
authors.forename: Jian
authors.initials: J
authors.lastname: Li
authors.forename: Xun
authors.initials: X
authors.lastname: Ji
authors.forename: Wei
authors.initials: W
authors.lastname: Zhou
authors.forename: Xu
authors.initials: X
authors.lastname: Zhang
authors.forename: Wangke
authors.initials: W
authors.lastname: Qian
authors.forename: Hualiang
authors.initials: H
authors.lastname: Jiang
authors.forename: Hong
authors.initials: H
authors.lastname: Liu
mesh_terms: D000965:Antimony / Q000737:chemistry; D001381:Azepines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D006046:Gold / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D007211:Indoles / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D011725:Pyridines / Q000138:chemical synthesis* / Q000737:chemistry; D011758:Pyrroles / Q000138:chemical synthesis* / Q000737:chemistry; D012834:Silver / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D001381:Azepines; D006571:Heterocyclic Compounds; D007211:Indoles; D011725:Pyridines; D011758:Pyrroles; C558603:benzo(e)indolo(1,2-a)pyrido(2,1-c)(1,4)diazepine-3,9-dione; C558602:benzo(e)indolo(1,2-a)pyrrolo(2,1-c)(1,4)diazepine-3,9-dione; D012834:Silver; D006046:Gold; D000965:Antimony