title: Palladium-catalyzed 1,1-aryloxygenation of terminal olefins.
abstract: This paper describes the 1,1-arylacetoxylation of diverse α-olefins using organostannanes and hypervalent iodine oxidants. The reaction provides a convergent approach for generating a C-C and a C-O bond as well as a new stereocenter in a single catalytic transformation.
authors.affiliation: University of Michigan, Department of Chemistry, Ann Arbor, Michigan 48109-1055, USA.
authors.forename: Andrew D
authors.initials: AD
authors.lastname: Satterfield
authors.forename: Asako
authors.initials: A
authors.lastname: Kubota
authors.forename: Melanie S
authors.initials: MS
authors.lastname: Sanford
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D007455:Iodine / Q000737:chemistry; D009947:Organotin Compounds / Q000737:chemistry; D016877:Oxidants / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000475:Alkenes; D009947:Organotin Compounds; D016877:Oxidants; D010165:Palladium; D007455:Iodine