title: Polymer-supported ionic-liquid-like phases (SILLPs): transferring ionic liquid properties to polymeric matrices.
abstract: The physico-chemical properties of polymers with ionic-liquid-like moieties covalently bound to their surfaces (SILLPs) have been studied by thermal and spectroscopic techniques, as well as by direct impedance and dielectric measurements, and compared to those of the corresponding bulk ionic liquids. The effective transfer of properties from ionic liquids in solution to the supported species has thereby been demonstrated. The effects of the chemical nature of these tunable "solid solvents" on their macroscopic swelling and microwave heating, as well as the stabilities and activities of different catalytic moieties immobilized on the SILLPs, have been studied. Finally, the experimental effect observed in microwave heating can be directly correlated with the values of tan δ derived from dielectric measurements.
authors.affiliation: Dpto. Química Inorgánica y Orgánica Department, Universidad Jaume I, Avda. Sos Baynat s/n, 12071 Castellon, Spain.
authors.forename: Victor
authors.initials: V
authors.lastname: Sans
authors.forename: Naima
authors.initials: N
authors.lastname: Karbass
authors.forename: M Isabel
authors.initials: MI
authors.lastname: Burguete
authors.forename: Vicente
authors.initials: V
authors.lastname: Compañ
authors.forename: Eduardo
authors.initials: E
authors.lastname: García-Verdugo
authors.forename: Santiago V
authors.initials: SV
authors.lastname: Luis
authors.forename: Milena
authors.initials: M
authors.lastname: Pawlak