title: Access to 1,2-diketones by an unusual radical cascade.
abstract: An unusual radical fragmentation of an unstrained cyclohexane structure was observed leading to complex 1,2-diketones.
authors.affiliation: Laboratoire de Synthèse Organique, CNRS UMR 7652, Ecole Polytechnique, F-91128 Palaiseau, France. heng@dcso.polytechnique.fr
authors.forename: Rama
authors.initials: R
authors.lastname: Heng
authors.forename: Samir Z
authors.initials: SZ
authors.lastname: Zard
mesh_terms: D003500:Cyclization; D003510:Cyclohexanes / Q000737:chemistry; D005609:Free Radicals / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D003510:Cyclohexanes; D005609:Free Radicals; D007659:Ketones; C506365:Cyclohexane