title: Bias effects on the electronic spectrum of a molecular bridge.
abstract: In this paper the effect of bias and geometric symmetry breaking on the electronic spectrum of a model molecular system is studied. Geometric symmetry breaking can either enhance the dissipative effect of the bias, where spectral peaks are disabled, or enable new excitations that are absent under zero bias conditions. The spectral analysis is performed on a simple model system by solving for the electronic response to an instantaneously impulsive perturbation in the dipole approximation. The dynamical response is extracted from the electronic equations of motion as expressed by the Keldysh formalism. This expression provides for the accurate treatment of the electronic structure of a bulk-coupled system at the chosen model Hamiltonian electronic structure level.
authors.affiliation: Department of Chemistry, University of Michigan, Ann Arbor, Michigan 48109, USA.
authors.forename: Heidi
authors.initials: H
authors.lastname: Phillips
authors.forename: Alexander
authors.initials: A
authors.lastname: Prociuk
authors.forename: Barry D
authors.initials: BD
authors.lastname: Dunietz