title: Supramolecular control on chemo- and regioselectivity via encapsulation of (NHC)-Au catalyst within a hexameric self-assembled host.
abstract: The encapsulation of a Au(I) catalyst within a self-assembled, hydrogen bonded, hexameric capsule dramatically changes its catalytic activity, leading to unusual products due to the steric requirements of the host's cavity.
authors.affiliation: Dipartimento di Scienze Molecolari e Nanosistemi, Università Ca' Foscari di Venezia, Calle Larga S Marta 2137, 30123, Venezia, Italy.
authors.forename: Alessandra
authors.initials: A
authors.lastname: Cavarzan
authors.forename: Alessandro
authors.initials: A
authors.lastname: Scarso
authors.forename: Paolo
authors.initials: P
authors.lastname: Sgarbossa
authors.forename: Giorgio
authors.initials: G
authors.lastname: Strukul
authors.forename: Joost N H
authors.initials: JN
authors.lastname: Reek
mesh_terms: D047250:Calixarenes / Q000737:chemistry; D002384:Catalysis; D006046:Gold / Q000737:chemistry*; D006860:Hydrogen Bonding; D008958:Models, Molecular; D010649:Phenylalanine / Q000031:analogs & derivatives / Q000737:chemistry; D012997:Solvents / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D012997:Solvents; C466160:resorcinarene; D047250:Calixarenes; D010649:Phenylalanine; D006046:Gold