title: Time-optimal control of spin 1/2 particles in the presence of radiation damping and relaxation.
abstract: We consider the time-optimal control of an ensemble of uncoupled spin 1/2 particles in the presence of relaxation and radiation damping effects, whose dynamics is governed by nonlinear equations generalizing the standard linear Bloch equations. For a single spin, the optimal control strategy can be fully characterized analytically. However, in order to take into account the inhomogeneity of the static magnetic field, an ensemble of isochromats at different frequencies must be considered. For this case, numerically optimized pulse sequences are computed and the dynamics under the corresponding optimal field is experimentally demonstrated using nuclear magnetic resonance techniques.
authors.affiliation: Department of Chemistry, Technische Universität München, Lichtenbergstrasse 4, D-85747 Garching, Germany.
authors.forename: Y
authors.initials: Y
authors.lastname: Zhang
authors.forename: M
authors.initials: M
authors.lastname: Lapert
authors.forename: D
authors.initials: D
authors.lastname: Sugny
authors.forename: M
authors.initials: M
authors.lastname: Braun
authors.forename: S J
authors.initials: SJ
authors.lastname: Glaser