title: Palladium-catalyzed selective heck-type diarylation of allylic esters with aryl halides involving a β-OAc elimination process.
abstract: Palladium-catalyzed selective Heck-type diarylation of allylic esters with aryl halides has been developed. Allylic esters are reacted with aryl iodides to provide the corresponding 1,3-diaryl propenes through a β-OAc elimination process. It is noteworthy that the methodology can be applied in constructing the indole and benzofuran skeletons.
authors.affiliation: College of Chemistry and Materials Science, Wenzhou University, Wenzhou, China.
authors.forename: Yan
authors.initials: Y
authors.lastname: Liu
authors.forename: Bo
authors.initials: B
authors.lastname: Yao
authors.forename: Chen-Liang
authors.initials: CL
authors.lastname: Deng
authors.forename: Ri-Yuan
authors.initials: RY
authors.lastname: Tang
authors.forename: Xing-Guo
authors.initials: XG
authors.lastname: Zhang
authors.forename: Jin-Heng
authors.initials: JH
authors.lastname: Li
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D001572:Benzofurans / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D006847:Hydrocarbons, Iodinated / Q000138:chemical synthesis* / Q000737:chemistry; D007211:Indoles / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*
chemical_list: D000475:Alkenes; D001572:Benzofurans; D006847:Hydrocarbons, Iodinated; D007211:Indoles; D010165:Palladium; C013658:propylene