title: Expeditious construction of a carbobicyclic skeleton via sp3-C-H functionalization: hydride shift from an aliphatic tertiary position in an internal redox process.
abstract: Described herein is the first example of an aliphatic, nonbenzylic hydride shift/cyclization sequence that contains two types of novel sp(3)-C-H functionalization: (1) construction of a tetraline skeleton via [1,5]-hydride shift/cyclization and (2) [1,6]-hydride shift/cyclization to form a five-membered ring (indane derivatives).
authors.affiliation: Department of Chemistry, Faculty of Science, Gakushuin University, Toshima-ku, Tokyo, Japan.
authors.forename: Keiji
authors.initials: K
authors.lastname: Mori
authors.forename: Shosaku
authors.initials: S
authors.lastname: Sueoka
authors.forename: Takahiko
authors.initials: T
authors.lastname: Akiyama
mesh_terms: D018360:Crystallography, X-Ray; D003500:Cyclization; D007189:Indans / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013237:Stereoisomerism
chemical_list: D007189:Indans