title: Matrix infrared spectroscopic and computational investigations of the lanthanide-methylene complexes CH2LnF2 with single Ln-C bonds.
abstract: Laser-ablated lanthanide metal atoms were condensed with CH(2)F(2) in excess argon at 6 K or neon at 4 K. New infrared absorption bands are assigned to the oxidative addition product methylene lanthanide difluorides on the basis of deuterium substitution and vibrational frequency calculations with density functional theory (DFT). Two dominant absorptions in the 500 cm(-1) region are identified as lanthanide-fluoride stretching modes for this very strong infrared absorption. The predominantly lanthanide-carbon stretching modes follow a similar trend of increasing with metal size and have characteristic 30 cm(-1) deuterium and 14 cm(-1) (13)C isotopic shifts. The electronic structure calculations show that these CH(2)LnF(2) complexes are not analogous to the simple transition and actinide metal methylidenes with metal-carbon double bonds that have been investigated previously, because the lanthanide metals (in the +2 or +3 oxidation state) do not appear to form a π-type bond with the CH(2) group. The DFT and ab initio correlated molecular orbital theory calculations predict that these complexes exist as multiradicals, with a Ln-C σ bond and a single electron on C-2p weakly coupled with f(x) (x = 1 (Ce), 2 (Pr), 3(Nd), etc.) electrons in the adjacent Ln-4f orbitals. The Ln-C σ bond is composed of about 15% Ln-5d,6s and 85% C-sp(2) hybrid orbital. The Ln orbital has predominantly 6s and 5d character with more d-character for early lanthanides and increasing amounts of s-character across the row. The Ln-F bonds are almost purely ionic. Accordingly, the argon-neon matrix shifts are large (13-16 cm(-1)) for the ionic Ln-F bond stretching modes and small (∼1 cm(-1)) for the more covalent Ln-C bond stretching modes.
authors.affiliation: Department of Chemistry, University of Virginia, Charlottesville, Virginia 22904-4319, USA.
authors.forename: Xuefeng
authors.initials: X
authors.lastname: Wang
authors.forename: Han-Gook
authors.initials: HG
authors.lastname: Cho
authors.forename: Lester
authors.initials: L
authors.lastname: Andrews
authors.forename: Mingyang
authors.initials: M
authors.lastname: Chen
authors.forename: David A
authors.initials: DA
authors.lastname: Dixon
authors.forename: Han-Shi
authors.initials: HS
authors.lastname: Hu
authors.forename: Jun
authors.initials: J
authors.lastname: Li