title: Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalysts.
abstract: A series of bimetallic complexes have been synthesized that are supported by a 4-phosphino-substituted NHC ligand. The use of this stable ligand reduces the number of synthetic steps and allows for a wide range of metal combinations to be introduced into the complexes.
authors.affiliation: UCR-CNRS Joint Research Chemistry Laboratory, Department of Chemistry, University of California, Riverside, 92521-0403, USA.
authors.forename: Daniel
authors.initials: D
authors.lastname: Mendoza-Espinosa
authors.forename: Bruno
authors.initials: B
authors.lastname: Donnadieu
authors.forename: Guy
authors.initials: G
authors.lastname: Bertrand
mesh_terms: D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006571:Heterocyclic Compounds / Q000737:chemistry; D008024:Ligands; D008670:Metals / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008968:Molecular Conformation
chemical_list: D056831:Coordination Complexes; D006571:Heterocyclic Compounds; D008024:Ligands; D008670:Metals; C030011:carbene; D008697:Methane