title: Pd-catalyzed desulfitative Heck coupling with dioxygen as the terminal oxidant.
abstract: A Pd-catalyzed desulfitative Heck-type reaction of aromatic sulfinic acid sodium salts with various olefins is developed with O(2) as the terminal oxidant under mild conditions. The presence of phosphane ligand DPEphos in anisole can significantly enhance the reaction selectivity.
authors.affiliation: Key Laboratory for Environmental Friendly Chemistry and Application of Ministry of Education, College of Chemistry, Xiangtan University, Xiangtan, 411105, China.
authors.forename: Xianya
authors.initials: X
authors.lastname: Zhou
authors.forename: Jiaying
authors.initials: J
authors.lastname: Luo
authors.forename: Jing
authors.initials: J
authors.lastname: Liu
authors.forename: Shengming
authors.initials: S
authors.lastname: Peng
authors.forename: Guo-Jun
authors.initials: GJ
authors.lastname: Deng
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry*; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D015394:Molecular Structure; D016877:Oxidants / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013329:Structure-Activity Relationship; D013441:Sulfinic Acids / Q000138:chemical synthesis* / Q000737:chemistry; D014867:Water / Q000737:chemistry
chemical_list: D000475:Alkenes; D016877:Oxidants; D013441:Sulfinic Acids; D014867:Water; D010165:Palladium; D010100:Oxygen