title: Enhanced photocatalytic activity of C-N-codoped TiO2 films prepared via an organic-free approach.
abstract: An organic-free sol-gel method was developed to synthesize crack-free, high surface roughness and visible-light-active C-N-codoped TiO(2) films. These films were subsequently evaluated for its photodegradation efficient using stearic acid as the model pollutant compound. The current approach avoids the use of hazardous organic solvents and employs carbon black as the carbon source as well as a template to increase the surface roughness. The presence of carbon and nitrogen species in TiO(2) was studied and discussed. The concentrations of carbon and nitrogen dopants in the TiO(2) films were affected by calcination temperature and the concentration of carbon black. Optimal visible light photocatalytic activity was observed for C-N-codoped TiO(2) film at 10.0 wt.% C, which was more than double that of the N-doped TiO(2) film. The enhancement in visible light photocatalytic activities of the C-N-codoped TiO(2) films was attributed to the synergistic effects of carbon and nitrogen dopants, and high surface roughness of the prepared films.
authors.affiliation: School of Chemical and Biomedical Engineering, Nanyang Technological University, 62 Nanyang Drive, Singapore 637459, Singapore.
authors.forename: Qing Chi
authors.initials: QC
authors.lastname: Xu
authors.forename: Diana V
authors.initials: DV
authors.lastname: Wellia
authors.forename: Shi
authors.initials: S
authors.lastname: Yan
authors.forename: Dai Wei
authors.initials: DW
authors.lastname: Liao
authors.forename: Tuti Mariana
authors.initials: TM
authors.lastname: Lim
authors.forename: Timothy Thatt Yang
authors.initials: TT
authors.lastname: Tan
mesh_terms: D002244:Carbon; D002384:Catalysis; D004785:Environmental Pollutants / Q000737:chemistry*; D052918:Environmental Restoration and Remediation / Q000379:methods*; D009584:Nitrogen; D010777:Photochemistry; D010782:Photolysis; D013229:Stearic Acids; D014025:Titanium / Q000737:chemistry*
chemical_list: D004785:Environmental Pollutants; D013229:Stearic Acids; C009495:titanium dioxide; C031183:stearic acid; D002244:Carbon; D014025:Titanium; D009584:Nitrogen