title: Charge-induced facial-selectivity in the formation of new cationic planar chiral iridacycles derived from aniline.
abstract: The reaction of chiral chlorido-iridacyclic 2-(4-N,N-dimethylaminophenyl)pyridines with solvato-type [Cp*M(S)(3)](q+) (M = Ru, S = MeCN, q = 1; M = Ir, S = MeC(O)Me, q = 2) complexes produces new cationic racemic planar chiral iridacycles in an efficient and diastereospecific way.
authors.affiliation: Laboratoire de Synthèses Métallo-induites, Institut de Chimie, Université de Strasbourg, 4 rue Blaise Pascal, F-67000 Strasbourg, France. djukic@unistra.fr
authors.forename: Jean-Pierre
authors.initials: JP
authors.lastname: Djukic
authors.forename: Wissam
authors.initials: W
authors.lastname: Iali
authors.forename: Michel
authors.initials: M
authors.lastname: Pfeffer
authors.forename: Xavier-Frédéric
authors.initials: XF
authors.lastname: Le Goff