title: Asymmetric synthesis of tertiary and quaternary allyl- and crotylsilanes via the borylation of lithiated carbamates.
abstract: Tertiary allyl- or crotylsilanes have been prepared in high er and dr via the lithiation-borylation reaction of alkyl carbamates with silaboronates. Using a related strategy, quaternary allylsilanes could be accessed in similarly high er.
authors.affiliation: School of Chemistry, University of Bristol, Cantock's Close, Bristol, BS8 1TS, UK. v.aggarwal@bristol.ac.uk
authors.forename: Varinder K
authors.initials: VK
authors.lastname: Aggarwal
authors.forename: Michael
authors.initials: M
authors.lastname: Binanzer
authors.forename: M Carolina
authors.initials: MC
authors.lastname: de Ceglie
authors.forename: Maddalena
authors.initials: M
authors.lastname: Gallanti
authors.forename: Ben W
authors.initials: BW
authors.lastname: Glasspoole
authors.forename: Stephanie J F
authors.initials: SJ
authors.lastname: Kendrick
authors.forename: Ravindra P
authors.initials: RP
authors.lastname: Sonawane
authors.forename: Ana
authors.initials: A
authors.lastname: Vázquez-Romero
authors.forename: Matthew P
authors.initials: MP
authors.lastname: Webster