title: Template-free formation of vertically oriented TiO2 nanorods with uniform distribution for organics-sensing application.
abstract: High-density arrays of vertically oriented TiO(2) nanorods with uniform distribution on Ti foil have been formed through template-free oxidation of Ti in hydrogen peroxide solutions. Subsequent thermal treatment was applied for growing mixed crystal structures to pursue higher performance. Morphology characterization using field emission scanning electron microscopy (FESEM) shows a nanorod diameter in the range of 20-50 nm with a length of 1.5 μm. X-ray diffraction (XRD) measurement demonstrates the crystallization of the TiO(2) nanorods prior to thermal treatment and the formation of anatase and rutile mixed phase after thermal treatment. The mixed crystal TiO(2) nanorods show a much higher performance than pure anatase in photoelectrochemical experiments. Steady-state photocurrent resulted from photocatalytic oxidation of organic compounds by TiO(2) nanorods is employed as response signal in determination of the organics to yield a linear range of 0-1.1mM for glucose. For other organics, an excellent linear relationship between the net steady-state photocurrent and the concentration of electrons transferred in exhaustive oxidation for these organics is obtained, which empowers the mixed crystal TiO(2) nanorods to serve as versatile material in organics-sensing application.
authors.affiliation: State Key Laboratory for Modification of Chemical Fibers and Polymer Maters Donghua University, Shanghai 201620, PR China.
authors.forename: Qinghui
authors.initials: Q
authors.lastname: Mu
authors.forename: Yaogang
authors.initials: Y
authors.lastname: Li
authors.forename: Qinghong
authors.initials: Q
authors.lastname: Zhang
authors.forename: Hongzhi
authors.initials: H
authors.lastname: Wang
mesh_terms: D003460:Crystallization; D055664:Electrochemical Techniques; D005947:Glucose / Q000032:analysis*; D006861:Hydrogen Peroxide; D043942:Nanotubes / Q000737:chemistry*; D009930:Organic Chemicals / Q000032:analysis*; D010084:Oxidation-Reduction; D010777:Photochemistry / Q000379:methods; D014025:Titanium / Q000737:chemistry*
chemical_list: D009930:Organic Chemicals; C009495:titanium dioxide; D006861:Hydrogen Peroxide; D014025:Titanium; D005947:Glucose