title: First proton triggered C-ON bond homolysis in alkoxyamines.
abstract: Rate constants k(d) of the C-ON bond homolysis in a new type of alkoxyamines (initiator/controller for Nitroxide Mediated Polymerization) carrying alkyl fragments capable of protonation were measured. A 20-fold increase was reported for the protonated alkoxyamine compared to the non-protonated homologue as predicted (Chem. Soc. Rev., 2011).
authors.affiliation: Laboratoire Chimie Provence LCP-UMR6264, Université Aix-Marseille 1-3, case 521, Avenue Escadrille Normandie-Niemen, 13397 Marseille Cedex 20, France.
authors.forename: Paul
authors.initials: P
authors.lastname: Brémond
authors.forename: Sylvain R A
authors.initials: SR
authors.lastname: Marque