title: A unique 2D → 3D polycatenation cobalt(II)-based molecule magnet showing coexistence of paramagnetism and canted antiferromagnetism.
abstract: A novel entangled architecture [Co(1.5)(bpmp)(Hcda)(cda)(H(2)O)] (1) based on 4(4)-sql subunits, showing an interesting 2D → 3D inclined polycatenation structure feature, is reported. Magnetic investigation shows that compound 1 exhibits coexistence of paramagnetism and canted antiferromagnetism with Tc of 48 K.
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou 350002, PR China.
authors.forename: Bo
authors.initials: B
authors.lastname: Xu
authors.forename: Xi
authors.initials: X
authors.lastname: Lin
authors.forename: Zhangzhen
authors.initials: Z
authors.lastname: He
authors.forename: Zujin
authors.initials: Z
authors.lastname: Lin
authors.forename: Rong
authors.initials: R
authors.lastname: Cao