title: Hydrothermal Tm3+-Lu2O3 nanorods with highly efficient 2 μm emission.
abstract: Cubic Ia3Tm-Lu(2)O(3) porous nanorods of ∼45 μm length and 90 nm diameter have been prepared with precise compositions through a soft hydrothermal route (i.e., autogenic pressure, neutral pH, and 185 °C for 24 h) by using chloride reagents. For these nanorods, room temperature excitation and photoluminescence spectra of Tm(3+) multiplets related to the eye-safe (3)F(4)→(3)H(6) laser transition at ∼1.85-2.05 μm are similar to those of bulk crystals. Room-temperature luminescence decays of (3)H(4) and (3)F(4) exhibit nonexponential dynamics analytically reproduced by the sum of two exponential regimes, which are ascribed to the different rates of nonradiative relaxations in defects at the surface and in the body of the nanocrystals, respectively. Measured fluorescence lifetimes τ ∼ 200-260 μs and τ ∼ 2.3-2.9 ms for (3)H(4) and (3)F(4), respectively, in 0.2% mol Tm-Lu(2)O(3) nanorods, are considerably larger than in previous nanocrystalline Tm-doped sesquioxides, and they are close to values of bulk sesquioxide crystals with equivalent Tm(3+) content.
authors.affiliation: Instituto de Ciencia de Materiales de Madrid, Consejo Superior de Investigaciones Científicas, Madrid, Spain.
authors.forename: Fátima
authors.initials: F
authors.lastname: Esteban-Betegón
authors.forename: Carlos
authors.initials: C
authors.lastname: Zaldo
authors.forename: Concepción
authors.initials: C
authors.lastname: Cascales