title: New three-dimensional metal-organic framework with heterometallic [Fe-Ag] building units: synthesis, crystal structure, and functional studies.
abstract: A new three-dimensional metal-organic framework (MOF) containing Fe(II) and Ag(I) ions and 2-pyrazinecarboxylic acid (pcaH) was synthesized, and its magnetic and catalytic properties were studied. The MOF has a big window size of 12.1 × 12.0 Å, with 23.8% solvent-accessible space, and shows size selectivity toward Lewis acid catalysis.
authors.affiliation: Fachbereich Chemie, Philipps-Universität Marburg, Marburg, Germany.
authors.forename: Sanjit
authors.initials: S
authors.lastname: Nayak
authors.forename: Klaus
authors.initials: K
authors.lastname: Harms
authors.forename: Stefanie
authors.initials: S
authors.lastname: Dehnen
mesh_terms: D002264:Carboxylic Acids / Q000737:chemistry*; D018360:Crystallography, X-Ray; D007501:Iron / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*
chemical_list: D002264:Carboxylic Acids; D009942:Organometallic Compounds; D012834:Silver; D007501:Iron