title: Syntheses and structures of triazides of heavy group 15 elements.
abstract: Synthesis of group 15-triazides E(N(3))(3) (E = Sb 1, Bi 2) and Py(2)-Bi(N(3))(3)3 (Py = pyridine). Single crystals of 1 were in situ grown by an IR-laser-assisted technique on the diffractometer. The structure of 3, which represents the first structurally characterized neutral Bi-triazide, is influenced by crystal packing effects according to DFT calculations.
authors.affiliation: University of Duisburg-Essen, Universitätsstr. 5-7, S07 S03 C30, 45117 Essen, Germany. stephan.schulz@uni-due.de
authors.forename: Stephan
authors.initials: S
authors.lastname: Schulz
authors.forename: Benjamin
authors.initials: B
authors.lastname: Lyhs
authors.forename: Georg
authors.initials: G
authors.lastname: Jansen
authors.forename: Dieter
authors.initials: D
authors.lastname: Bläser
authors.forename: Christoph
authors.initials: C
authors.lastname: Wölper