title: Step-wise synthesis of inorganic-organic hybrid based on γ-octamolybdate-based tectons.
abstract: With the bottom-up design principle, we use metal-ions to bridge the predesigned tectons (1 [(H(2)L(1))(2)(Mo(8)O(26))]·4H(2)O and 3 [(H(2)L(2))(L(2))(0.5)(Mo(8)O(26))(0.5)]·H(2)O) so that two higher dimensional γ-octamolybdate based inorganic-organic hybrid compounds 2 [Cu(I)(2)(L(1))(3)(Mo(8)O(26))(0.5)] and 4 [Ni(L(2))(2)(HL(2))(2)(Mo(8)O(26))]·4H(2)O are successfully obtained.
authors.affiliation: Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, People's Republic of China.
authors.forename: Hong-Ying
authors.initials: HY
authors.lastname: Zang
authors.forename: Ya-Qian
authors.initials: YQ
authors.lastname: Lan
authors.forename: Shun-Li
authors.initials: SL
authors.lastname: Li
authors.forename: Guang-Sheng
authors.initials: GS
authors.lastname: Yang
authors.forename: Kui-Zhan
authors.initials: KZ
authors.lastname: Shao
authors.forename: Xin-Long
authors.initials: XL
authors.lastname: Wang
authors.forename: Li-Kai
authors.initials: LK
authors.lastname: Yan
authors.forename: Zhong-Min
authors.initials: ZM
authors.lastname: Su
mesh_terms: D018360:Crystallography, X-Ray; D008968:Molecular Conformation; D008982:Molybdenum / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D019265:Spectroscopy, Near-Infrared; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
chemical_list: D008982:Molybdenum; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates