title: Heteroleptic [1]zirconametalloarenophanes: potential precursors to metal-enriched metallopolymers.
abstract: [1]Zirconametalloarenophanes [Cr(η(5)-C(5)H(4))ZrCp'(2)(η(7)-C(7)H(6))] and [Mn(η(5)-C(5)H(4))ZrCp'(2)(η(6)-C(6)H(5))] (Cp' = C(5)H(4)(t)Bu) have been isolated for the first time. These species represent potential precursors en route to metal-enriched metallopolymers by ROP. The electronic structure was assessed by means of UV-visible spectroscopy and TD-DFT calculations.
authors.affiliation: Institut für Anorganische Chemie, Julius-Maximilians-Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany. h.braunschweig@mail.uni-wuerzburg.de
authors.forename: Holger
authors.initials: H
authors.lastname: Braunschweig
authors.forename: Maria
authors.initials: M
authors.lastname: Friedrich
authors.forename: Thomas
authors.initials: T
authors.lastname: Kupfer
authors.forename: Krzysztof
authors.initials: K
authors.lastname: Radacki