title: Synthesis and cross-coupling of sulfonamidomethyltrifluoroborates.
abstract: Sulfonamidomethyltrifluoroborates were successfully synthesized and cross-coupled with a wide range of aryl and heteroaryl chlorides, allowing the construction of a sulfonamidomethyl aryl linkage through a new disconnection, thus offering a new way to access such structurally interesting motifs.
authors.affiliation: Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, United States. gmolandr@sas.upenn.edu
authors.forename: Gary A
authors.initials: GA
authors.lastname: Molander
authors.forename: Nicolas
authors.initials: N
authors.lastname: Fleury-Brégeot
authors.forename: Marie-Aude
authors.initials: MA
authors.lastname: Hiebel
mesh_terms: D000577:Amides / Q000737:chemistry*; D001888:Boric Acids / Q000138:chemical synthesis*; D017611:Fluorine Compounds / Q000138:chemical synthesis*; D008745:Methylation; D015394:Molecular Structure; D013457:Sulfur Compounds / Q000138:chemical synthesis*
chemical_list: D000577:Amides; D001888:Boric Acids; D017611:Fluorine Compounds; D013457:Sulfur Compounds; C032688:boric acid