title: A simple topological identification method for highly (3,12)-connected 3D MOFs showing anion exchange and luminescent properties.
abstract: Reaction of a semi-rigid tripodal ligand 1,1',1''-(2,4,6-trimethylbenzene-1,3,5-triyl)tris(methylene)tripyridinium-4-olate) (TTP) with Ln(3+) (Ln = Eu, Gd) afforded rare (3,12)-connected metal-organic frameworks (MOFs). A topological simplification of such highly connected 3D MOFs on the basis of 2D CdI(2) (3,6)-nets is proposed. The luminescent and anion exchange properties of the compounds were determined.
authors.affiliation: KLGHEI of Environment and Energy Chemistry, MOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
authors.forename: Qing-Yuan
authors.initials: QY
authors.lastname: Yang
authors.forename: Kang
authors.initials: K
authors.lastname: Li
authors.forename: Jian
authors.initials: J
authors.lastname: Luo
authors.forename: Mei
authors.initials: M
authors.lastname: Pan
authors.forename: Cheng-Yong
authors.initials: CY
authors.lastname: Su