title: Reactivity of endo-3-bromocamphor with sulfur-centered nucleophiles by an electron transfer mechanism. Electrophilic behaviour of the 3-camphoryl radical.
abstract: The photostimulated reaction of arylthiolate ions with endo-3-bromocamphor produced both reduction and substitution products. The pK(a) and proton affinities of the conjugated acids were found to be good indicators of the reactivity.
authors.affiliation: INFIQC, Departamento de Química Orgánica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, Córdoba, 5000, Argentina.
authors.forename: Jorge G
authors.initials: JG
authors.lastname: Uranga
authors.forename: Ana N
authors.initials: AN
authors.lastname: Santiago