title: Field emission and electrical bistable properties of CuTCPQ nanostructures.
abstract: The organic charge-transfer (CT) complex nanostructures of CuTCPQ (copper tetracyanopentacenequinodimethane) were first successfully fabricated by organic solid phase reaction. The morphologies of CuTCPQ nanosrods can be prepared by controlling the reaction temperature. The electron field-emission properties on these nanostructures were investigated. The current density and turn-on field are 3.5 mA cm(-2) and 2.70 V μm(-1) for the nanorods of CuTCPQ. The results demonstrate that the nanorods of CuTCPQ are potential candidates for field emission cathodes. Stable and reproducible current-controlled electrical switch has been observed in amorphous organic nanorods of CuTCPQ films. The current-voltage characteristics reveal an abrupt decrease in impedance form 1.2 MΩ to less than 1.1kΩ. The maximum ON/OFF ratio of CuTCPQ nanorod arrays is up to 1100.
authors.affiliation: CAS Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, PR China.
authors.forename: Canbin
authors.initials: C
authors.lastname: Ouyang
authors.forename: Huibiao
authors.initials: H
authors.lastname: Liu
authors.forename: Xuemin
authors.initials: X
authors.lastname: Qian
authors.forename: Haowei
authors.initials: H
authors.lastname: Lin
authors.forename: Nan
authors.initials: N
authors.lastname: Chen
authors.forename: Yuliang
authors.initials: Y
authors.lastname: Li