title: Sorption of nano-C60 clusters in soil: hydrophilic or hydrophobic interactions?
abstract: We studied the sorption behaviour of fullerene nano-C(60) particles (nC(60)) in soil from binary solvent mixtures of ethanol-water in order to critically evaluate the previous reports in the literature that the partitioning mechanism explains the soil sorption of fullerene C(60) as hydrophobic molecules. The sorption of nC(60) particles was studied in a range of solvent mixtures by changing volume fractions of ethanol from 20 to 100 percent. Sorption and particle characteristics were found to be very different in ethanol : water mixtures above and below 60% ethanol. In the range of 20-60% ethanol, sorption increased from 1.2 to 14.6 L kg(-1) accompanied by a change in zeta (ζ) potential from -32.4 to -7.2 mV. This observation can be attributed to hydrophilic interactions that negatively charged nC(60) particles undergo with soil colloids and water molecules. From 60% to 100% ethanol volume fractions, hydrophobic interactions of weakly charged nanoparticles may control the overall extent of soil sorption. The findings of this study indicate the importance of hydrophilic forces in controlling the sorption behaviour of nC(60) particles which are stabilized in water dominated solvent mixtures. The validity of the partitioning mechanism and K(OC) modelling approach in describing and estimating the sorption of nC(60) particles in soil (previously suggested in the literature) are, therefore, questioned.
authors.affiliation: Commonwealth Scientific and Industrial Research Organisation, Advanced Materials Transformational Capability Platform, PMB 2, Glen Osmond, 5064, Australia.
authors.forename: Mohsen
authors.initials: M
authors.lastname: Forouzangohar
authors.forename: Rai S
authors.initials: RS
authors.lastname: Kookana
mesh_terms: D000327:Adsorption; D000431:Ethanol / Q000737:chemistry; D037741:Fullerenes / Q000032:analysis / Q000737:chemistry*; D057927:Hydrophobic and Hydrophilic Interactions; D007700:Kinetics; D008956:Models, Chemical; D012987:Soil / Q000737:chemistry*; D012989:Soil Pollutants / Q000032:analysis / Q000737:chemistry*; D014867:Water / Q000737:chemistry
chemical_list: D037741:Fullerenes; D012987:Soil; D012989:Soil Pollutants; D014867:Water; D000431:Ethanol; C069837:fullerene C60