title: Utilization of steel, pulp and paper industry solid residues in forest soil amendment: relevant physicochemical properties and heavy metal availability.
abstract: Industrial residue application to soil was investigated by integrating granulated blast furnace or converter steel slag with residues from the pulp and paper industry in various formulations. Specimen analysis included relevant physicochemical properties, total element concentrations (HCl+HNO3 digestion, USEPA 3051) and chemical speciation of chosen heavy metals (CH3COOH, NH2OH·HCl and H2O2+H2O2+CH3COONH4, the BCR method). Produced matrices showed liming effects comparable to commercial ground limestone and included significant quantities of soluble vital nutrients. The use of converter steel slag, however, led to significant increases in the total concentrations of Cr and V. Subsequently, total Cr was attested to occur as Cr(III) by Na2CO3+NaOH digestion followed by IC UV/VIS-PCR (USEPA 3060A). Additionally, 80.6% of the total concentration of Cr (370 mg kg(-1), d.w.) occurred in the residual fraction. However, 46.0% of the total concentration of V (2470 mg kg(-1), d.w.) occurred in the easily reduced fraction indicating potential bioavailability.
authors.affiliation: Department of Forest Products Technology, Aalto University, School of Chemical Technology, P.O. Box 16400, Tekniikantie 3, FI-00076 Aalto, Espoo, Finland. mikko.makela@aalto.fi
authors.forename: Mikko
authors.initials: M
authors.lastname: Mäkelä
authors.forename: Gary
authors.initials: G
authors.lastname: Watkins
authors.forename: Risto
authors.initials: R
authors.lastname: Pöykiö
authors.forename: Hannu
authors.initials: H
authors.lastname: Nurmesniemi
authors.forename: Olli
authors.initials: O
authors.lastname: Dahl
mesh_terms: D001682:Biological Availability; D052918:Environmental Restoration and Remediation; D007220:Industrial Waste; D019216:Metals, Heavy / Q000302:isolation & purification*; D010209:Paper; D010944:Plants / Q000378:metabolism; D012989:Soil Pollutants / Q000302:isolation & purification* / Q000493:pharmacokinetics; D013232:Steel; D014197:Trees
chemical_list: D007220:Industrial Waste; D019216:Metals, Heavy; D012989:Soil Pollutants; D013232:Steel