title: Determination of the absolute chirality of tellurium using resonant diffraction with circularly polarized x-rays.
abstract: Many proteins, sugars and pharmaceuticals crystallize into two forms that are mirror images of each other (enantiomers) like our right and left hands. Tellurium is one enantiomer having a space group pair, P3(1)21 (right-handed screw) and P3(2)21 (left-handed screw). X-ray diffraction with dispersion correction terms has been playing an important role in determining the handedness of enantiomers for a long time. However, this approach is not applicable for an elemental crystal such as tellurium or selenium. We have demonstrated that positive and negative circularly polarized x-rays at the resonant energy of tellurium can be used to absolutely distinguish right from left tellurium. This method is applicable to chiral motifs that occur in biomolecules, liquid crystals, ferroelectrics and antiferroelectrics, multiferroics, etc.
authors.affiliation: RIKEN SPring-8 Centre, Sayo, Hyogo 679-5148, Japan. ytanaka@riken.jp
authors.forename: Y
authors.initials: Y
authors.lastname: Tanaka
authors.forename: S P
authors.initials: SP
authors.lastname: Collins
authors.forename: S W
authors.initials: SW
authors.lastname: Lovesey
authors.forename: M
authors.initials: M
authors.lastname: Matsumami
authors.forename: T
authors.initials: T
authors.lastname: Moriwaki
authors.forename: S
authors.initials: S
authors.lastname: Shin
mesh_terms: D001703:Biophysics / Q000379:methods*; D004581:Electronics; D015233:Models, Statistical; D056951:Photoelectron Spectroscopy; D010825:Physics / Q000379:methods; D013237:Stereoisomerism; D013691:Tellurium / Q000737:chemistry*; D014961:X-Ray Diffraction; D014965:X-Rays
chemical_list: D013691:Tellurium