title: Reliable determination of 237Np in environmental solid samples using 242Pu as a potential tracer.
abstract: This paper reports an analytical method for rapid determination of neptunium ((237)Np) in environmental solid samples exploiting automated sequential injection (SI)-based anion exchange separation. Pivotal issues on analytical method performance were investigated including sorption behavior of (237)Np onto various AG 1-type anion exchangers; suitability of (242)Pu as a tracer for (237)Np determination in environmental solid samples; and long-term chemical stability of tetravalent Np. Experimental results revealed that the degree of resin cross-linking has a significant influence on the separation efficiency in terms of chemical yields of (237)Np and removal of interfering nuclides. Although ca. 30% of sorbed Np onto AG 1- × 4 was stripped out during HCl rinsing step for the removal of Th, chemical yield ratios of (237)Np to (242)Pu were proven steady with an average value of 0.67 ± 0.04 (n=15) under selected experimental conditions. Disulfite-8M HNO(3) was selected as a redox pair for valence adjustment to Np(IV) and the tetravalent Np in the sample solution was demonstrated to be stabilized for up to 5 days under 3°C. The analytical results for reference materials showed a good agreement with the expected values, thereby demonstrating the usefulness of (242)Pu as a non-isotopic tracer for (237)Np chemical yield monitoring. The on-column separation procedure fosters rapid analysis as required in emergency situations since each individual sample can be handled within 2.5h, and leads to a significant decrease in labor intensity compared to conventional batch-wise protocols.
authors.affiliation: Radiation Research Division, Risø National Laboratory for Sustainable Energy, Technical University of Denmark, DK-4000 Roskilde, Denmark. jiqi@risoe.dtu.dk
authors.forename: Jixin
authors.initials: J
authors.lastname: Qiao
authors.forename: Xiaolin
authors.initials: X
authors.lastname: Hou
authors.forename: Per
authors.initials: P
authors.lastname: Roos
authors.forename: Manuel
authors.initials: M
authors.lastname: Miró