title: Thiadiazoloquinoxalines: tuning physical properties through smart synthesis.
abstract: The synthesis of π-conjugated acceptors based on thiadiazoloquinoxaline (TQ) derivatives is described. Apart from reporting on the functionalization of the TQ core, the influence of the substituents was studied by UV-vis absorption and emission spectroscopy, cyclic voltammetry measurements, and DFT calculations. By changing the donor as well as the π-spacer, a fine-tuning of the photo- and electrochemical properties was achieved.
authors.affiliation: Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.
authors.forename: Timea
authors.initials: T
authors.lastname: Dallos
authors.forename: Manuel
authors.initials: M
authors.lastname: Hamburger
authors.forename: Martin
authors.initials: M
authors.lastname: Baumgarten