title: Plasmonic metallic nanostructures by direct nanoimprinting of gold nanoparticles.
abstract: We demonstrated the plasmonic metallic nanostructure fabricated by direct nanoimprinting of gold nanoparticles (AuNPs). This approach combines the patterning and lift-off processes into a simple one-step process without the need for expensive patterning lithographies and the stringent requirement of the lift-off process for nanostructures. Good imprinting integrity was accomplished with a negligible residual layer. The dynamic optical responses of the imprinted gold pillars from AuNPs to the bulk material during the annealing process were investigated. The localized surface plasmon resonance (LSPR) properties of AuNPs or gold pillar arrays can be controlled and tuned during the annealing process. The sensitivity of the gold pillar array in terms of the wavelength shift per refractive index unit (RIU) reached 259 nm/RIU. The size of the imprinted gold pillars is highly scalable in our process. The corresponding resonance wavelengths can be widely tuned from the visible to infrared region by changing the size of the gold pillars, thus providing a wide range of sensing capability.
authors.affiliation: Institute of Electro-Optical Science and Engineering, Advanced Optoelectric Technology Center, National Cheng Kung University, Tainan, Taiwan.
authors.forename: Chia-Ching
authors.initials: CC
authors.lastname: Liang
authors.forename: Mei-Yi
authors.initials: MY
authors.lastname: Liao
authors.forename: Wen-Yu
authors.initials: WY
authors.lastname: Chen
authors.forename: Tsung-Chieh
authors.initials: TC
authors.lastname: Cheng
authors.forename: Wen-Huei
authors.initials: WH
authors.lastname: Chang
authors.forename: Chun-Hung
authors.initials: CH
authors.lastname: Lin
mesh_terms: D003460:Crystallization / Q000379:methods*; D006046:Gold / Q000737:chemistry*; D008422:Materials Testing; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure*; D020349:Surface Plasmon Resonance / Q000379:methods*; D013499:Surface Properties
chemical_list: D006046:Gold