title: One electron oxidation of triferrocenylmethanol: synthesis, metal atom dynamics, electron delocalization, and the crystal structure of [Fc3COH](+) PF6⁻.
abstract: The title compound 2 was prepared and its crystal structure was determined at 100 K. The neat solid was examined by temperature dependent (57)Fe Mössbauer effect (ME) spectroscopy over the interval 92 < T < 318 K, and evidences two diamagnetic Fe(II) sites and one paramagnetic Fe(III) site. The latter shows spin-lattice relaxation, but there is no evidence of electron delocalization among the three iron sites in the above temperature interval. The mean-square-amplitude-of-vibration of the diamagnetic iron site has been determined from the recoil-free fraction ME resonance, and compared to the neutral Fc(3)COH homologue (1). The ME dynamical data are in good agreement with the U(i,j) value at 100 K extracted from the crystallographic results. The ME parameters at 5 K have also been determined with the sample compound embedded in a paraffin wax matrix as well as pelletized with BN.
authors.affiliation: Institut für Organische Chemie, Leibniz Universität Hannover, D-30167, Hannover, Germany. holger.butenschoen@mbox.oci.uni-hannover.de
authors.forename: Holger
authors.initials: H
authors.lastname: Butenschön
authors.forename: Jingxiang
authors.initials: J
authors.lastname: Ma
authors.forename: Constantin G
authors.initials: CG
authors.lastname: Daniliuc
authors.forename: Israel
authors.initials: I
authors.lastname: Nowik
authors.forename: Rolfe H
authors.initials: RH
authors.lastname: Herber