title: Synthesis and thermal behaviour of gallium-substituted aluminosilicate inorganic polymers.
abstract: A combined sol-gel and solid-state method reported for the synthesis of gallium silicate analogues of aluminosilicate inorganic polymers has also been extended to the formation of related compounds with a range of Al-for Ga substitutions. Homogeneous, robust products were obtained at an optimum composition of SiO(2):(Ga(2)O(3) + Al(2)O(3)) = 7. After curing at 40 °C, all the products were typically X-ray amorphous, and the Al and Ga was shown by (27)Al and (71)Ga MAS NMR spectroscopy to be in solely tetrahedral coordination. The (29)Si MAS NMR spectra were as expected for silicate inorganic polymers, but also indicated the presence of some unreacted silica. Electron microscopy in conjunction with EDS elemental mapping showed that the Ga, Al and Si was homogeneously distributed in the products. Thermal treatment of these compounds results in endothermic water loss at about 75-160 °C followed by an exothermic event at about 950 °C corresponding to crystallization of KGaSi(2)O(6) in the gallium end-member. By contrast, the Al-substituted compounds never fully crystallised, but melted at 1200 °C to an X-ray amorphous product.
authors.affiliation: School of Chemical and Physical Sciences, Victoria University of Wellington, New Zealand.
authors.forename: Andrew T
authors.initials: AT
authors.lastname: Durant
authors.forename: Kenneth J D
authors.initials: KJ
authors.lastname: MacKenzie
authors.forename: Hideki
authors.initials: H
authors.lastname: Maekawa