title: Simultaneous degradation of disinfection byproducts and earthy-musty odorants by the UV/H2O2 advanced oxidation process.
abstract: Advanced treatment technologies that control multiple contaminants are beneficial to drinking water treatment. This research applied UV/H(2)O(2) for the simultaneous degradation of geosmin, 2-methylisoborneol, four trihalomethanes and six haloacetic acids. Experiments were conducted in de-ionized water at 24 ± 1.0 °C with ng/L amounts of odorants and μg/L amounts of disinfection byproducts. UV was applied with and without 6 mg/L H(2)O(2.) The results demonstrated that brominated trihalomethanes and brominated haloacetic acids were degraded to a greater extent than geosmin and 2-methylisoborneol. Tribromomethane and dibromochloromethane were degraded by 99% and 80% respectively at the UV dose of 1200 mJ/cm(2) with 6 mg/L H(2)O(2), whereas 90% of the geosmin and 60% of the 2-methylisoborneol were removed. Tribromoacetic acid and dibromoacetic acid were degraded by 99% and 80% respectively under the same conditions. Concentrations of trichloromethane and chlorinated haloacetic acids were not substantially reduced under these conditions and were not effectively removed at doses designed to remove geosmin and 2-methylisoborneol. Brominated compounds were degraded primarily by direct photolysis and cleavage of the C-Br bond with pseudo first order rate constants ranging from 10(-3) to 10(-2) s(-1). Geosmin and 2-methylisoborneol were primarily degraded by reaction with hydroxyl radical with direct photolysis as a minor factor. Perchlorinated disinfection byproducts were degraded by reaction with hydroxyl radicals. These results indicate that the UV/H(2)O(2) can be applied to effectively control both odorants and brominated disinfection byproducts.
authors.affiliation: Department of Civil and Environmental Engineering, Virginia Polytechnic Institute and State University, VA 24061, USA.
authors.forename: Chang Hyun
authors.initials: CH
authors.lastname: Jo
authors.forename: Andrea M
authors.initials: AM
authors.lastname: Dietrich
authors.forename: James M
authors.initials: JM
authors.lastname: Tanko
mesh_terms: D000085:Acetates / Q000032:analysis / Q000737:chemistry; D001892:Camphanes / Q000032:analysis / Q000737:chemistry; D062845:Chloroacetates; D004202:Disinfectants / Q000032:analysis / Q000737:chemistry*; D006842:Hydrocarbons, Brominated; D006861:Hydrogen Peroxide / Q000737:chemistry*; D009284:Naphthols / Q000032:analysis / Q000737:chemistry; D009812:Odorants / Q000032:analysis*; D014238:Trichloroacetic Acid / Q000032:analysis / Q000737:chemistry; D014466:Ultraviolet Rays; D018508:Water Purification / Q000379:methods*
chemical_list: D000085:Acetates; D001892:Camphanes; D062845:Chloroacetates; D004202:Disinfectants; D006842:Hydrocarbons, Brominated; D009284:Naphthols; C005536:2-methylisoborneol; D014238:Trichloroacetic Acid; C017766:tribromoacetic acid; C088674:dibromoacetic acid; D006861:Hydrogen Peroxide; C001278:geosmin