title: Kinetic resolution of racemic amines using provisional molecular chirality generated by spontaneous crystallization.
abstract: N-(2-methoxy-1-naphthoyl)pyrrolidine afforded chiral crystals by spontaneous crystallization. The molecular chirality in the crystal was retained after dissolving the crystals in a cooled solvent. Kinetic resolution of racemic amines was performed using the provisional chiral molecular conformation derived from chiral crystals.
authors.affiliation: Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, Chiba University, Yayoi-cho, Inage-ku, Chiba 263-8522, Japan. sakamotom@faculty.chiba-u.jp
authors.forename: Masami
authors.initials: M
authors.lastname: Sakamoto
authors.forename: Kazuyuki
authors.initials: K
authors.lastname: Fujita
authors.forename: Fumitoshi
authors.initials: F
authors.lastname: Yagishita
authors.forename: Atsushi
authors.initials: A
authors.lastname: Unosawa
authors.forename: Takashi
authors.initials: T
authors.lastname: Mino
authors.forename: Tsutomu
authors.initials: T
authors.lastname: Fujita