title: Assembly of [Mn(II)2Mn(III)2] S = 9 clusters via azido bridges: a new single-chain magnet.
abstract: In the present work, we report a new manganese single-chain magnet built from tetranuclear Mn(II)(2)Mn(III)(2) mixed-valence units linked by end-on azido and oximato bridges. All of the intra- and intercluster interactions involve end-on azido bridges, resulting in one ferromagnetic chain of ferromagnetic clusters with local ground state S = 9.
authors.affiliation: Departament de Química Inorgànica, Universitat de Barcelona, Barcelona, Spain. albert.escuer@ub.edu
authors.forename: Albert
authors.initials: A
authors.lastname: Escuer
authors.forename: Gina
authors.initials: G
authors.lastname: Vlahopoulou
authors.forename: Franz A
authors.initials: FA
authors.lastname: Mautner
mesh_terms: D001386:Azides / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D008280:Magnetics; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D013696:Temperature
chemical_list: D001386:Azides; D008024:Ligands; D009942:Organometallic Compounds; D008345:Manganese