title: Coupling of demixing and magnetic ordering phase transitions probed by turbidimetric measurements in a binary mixture doped with magnetic nanoparticles.
abstract: We present a novel study on the effect of a magnetic field applied on a binary mixture doped with magnetic nanoparticles close to its demixing transition. Turbidity measurements in the Faraday configuration show that the effect of applying an external field produces changes in the critical opalescence of the mixture that allow us to track an aggregation produced by critical Casimir forces and a reversible aggregation due to the formation of chain-like flocks in response to the external magnetic field. The observation of a crossover of the aggregation curves through optical signals is interpreted as the evolution from low to high power dispersion nuclei due to an increase in the radius of the condensation seed brought about by Casimir or magnetic interactions. Finally, evidence of an enhanced magnetocaloric effect due to the coupling between mixing and ordering phase transitions is presented which opens up a nonsolid state approach of designing refrigerating cycles and devices.
authors.affiliation: Instituto de Física, Universidad Autónoma de San Luis Potosí, San Luis Potosí, Mexico.
authors.forename: Lorenzo
authors.initials: L
authors.lastname: Hernández-Díaz
authors.forename: Juan Carlos
authors.initials: JC
authors.lastname: Hernández-Reta
authors.forename: Armando
authors.initials: A
authors.lastname: Encinas
authors.forename: Yuri
authors.initials: Y
authors.lastname: Nahmad-Molinari
mesh_terms: D045424:Complex Mixtures / Q000737:chemistry; D058185:Magnetite Nanoparticles / Q000737:chemistry*; D008422:Materials Testing; D009391:Nephelometry and Turbidimetry / Q000379:methods*; D044367:Phase Transition; D012996:Solutions / Q000737:chemistry*
chemical_list: D045424:Complex Mixtures; D058185:Magnetite Nanoparticles; D012996:Solutions