title: Fluorine substituted conjugated polymer of medium band gap yields 7% efficiency in polymer-fullerene solar cells.
abstract: Recent research advances on conjugated polymers for photovoltaic devices have focused on creating low band gap materials, but a suitable band gap is only one of many performance criteria required for a successful conjugated polymer. This work focuses on the design of two medium band gap (~2.0 eV) copolymers for use in photovoltaic cells which are designed to possess a high hole mobility and low highest occupied molecular orbital and lowest unoccupied molecular orbital energy levels. The resulting fluorinated polymer PBnDT-FTAZ exhibits efficiencies above 7% when blended with [6,6]-phenyl C(61)-butyric acid methyl ester in a typical bulk heterojunction, and efficiencies above 6% are still maintained at an active layer thicknesses of 1 μm. PBnDT-FTAZ outperforms poly(3-hexylthiophene), the current medium band gap polymer of choice, and thus is a viable candidate for use in highly efficient tandem cells. PBnDT-FTAZ also highlights other performance criteria which contribute to high photovoltaic efficiency, besides a low band gap.
authors.affiliation: Department of Chemistry, University of North Carolina at Chapel Hill, Chapel Hill, North Carolina 27599-3287, USA.
authors.forename: Samuel C
authors.initials: SC
authors.lastname: Price
authors.forename: Andrew C
authors.initials: AC
authors.lastname: Stuart
authors.forename: Liqiang
authors.initials: L
authors.lastname: Yang
authors.forename: Huaxing
authors.initials: H
authors.lastname: Zhou
authors.forename: Wei
authors.initials: W
authors.lastname: You
mesh_terms: D011211:Electric Power Supplies; D037741:Fullerenes / Q000737:chemistry*; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis / Q000737:chemistry*; D015394:Molecular Structure; D011108:Polymers / Q000737:chemistry*
chemical_list: D037741:Fullerenes; D006845:Hydrocarbons, Fluorinated; D011108:Polymers