title: Nitration of iron corrolates: further evidence for non-innocence of the corrole ligand.
abstract: Mono- and di-substituted β-nitro derivatives have been obtained from the reaction of ttcorrFeCl with sodium nitrite in refluxing DMF. This result is unprecedented for iron corrolates and further evidences the non-innocent character of the corrole ligand.
authors.affiliation: Dipartimento di Scienze e Tecnologie Chimiche, Università di Roma Tor Vergata, via della Ricerca Scientifica 1, 00133 Rome, Italy.
authors.forename: Manuela
authors.initials: M
authors.lastname: Stefanelli
authors.forename: Sara
authors.initials: S
authors.lastname: Nardis
authors.forename: Luca
authors.initials: L
authors.lastname: Tortora
authors.forename: Frank R
authors.initials: FR
authors.lastname: Fronczek
authors.forename: Kevin M
authors.initials: KM
authors.lastname: Smith
authors.forename: Silvia
authors.initials: S
authors.lastname: Licoccia
authors.forename: Roberto
authors.initials: R
authors.lastname: Paolesse
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry; D018360:Crystallography, X-Ray; D007501:Iron / Q000737:chemistry*; D008024:Ligands; D008968:Molecular Conformation; D010084:Oxidation-Reduction; D011166:Porphyrins / Q000737:chemistry*; D012977:Sodium Nitrite / Q000737:chemistry
chemical_list: D056831:Coordination Complexes; D008024:Ligands; D011166:Porphyrins; C431863:corrole; D007501:Iron; D012977:Sodium Nitrite