title: Trinuclear rhodium hydride complexes.
abstract: Three novel trinuclear rhodium hydride complexes of the type {[Rh(PP*)H](3)(μ(2)-H)(3)(μ(3)-H)}[BF(4)](2) containing diphosphines Tangphos, t-Bu-BisP* and Me-DuPHOS have been synthesised. The new compounds are very stable. Their structures have been characterized by X-ray analysis in the solid state and by NMR-spectroscopic investigations in solution.
authors.affiliation: Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Straße 29a, 18059, Rostock, Germany.
authors.forename: Christian
authors.initials: C
authors.lastname: Fischer
authors.forename: Christina
authors.initials: C
authors.lastname: Kohrt
authors.forename: Hans-Joachim
authors.initials: HJ
authors.lastname: Drexler
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Baumann
authors.forename: Detlef
authors.initials: D
authors.lastname: Heller