title: A sodalite-type porous metal-organic framework with polyoxometalate templates: adsorption and decomposition of dimethyl methylphosphonate.
abstract: A sodalite-type porous metal-organic framework with polyoxometalate templates, H(3)[(Cu(4)Cl)(3)(BTC)(8)](2)[PW(12)O(40)]·(C(4)H(12)N)(6)·3H(2)O (NENU-11; BTC = 1,3,5-benzenetricarboxylate), was obtained by a hydrothermal reaction. As a reasonable candidate for eliminating nerve gas, NENU-11 displays good adsorption behavior for dimethyl methylphosphonate (15.5 molecules per formula unit). In virtue of the catalytic activity of polyoxometalate guests, this nerve gas mimic could be facilely decomposed by a hydrolysis reaction.
authors.affiliation: Key Laboratory of Polyoxometalate Science of the Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, Jilin 130024, China.
authors.forename: Feng-Ji
authors.initials: FJ
authors.lastname: Ma
authors.forename: Shu-Xia
authors.initials: SX
authors.lastname: Liu
authors.forename: Chun-Yan
authors.initials: CY
authors.lastname: Sun
authors.forename: Da-Dong
authors.initials: DD
authors.lastname: Liang
authors.forename: Guo-Jian
authors.initials: GJ
authors.lastname: Ren
authors.forename: Feng
authors.initials: F
authors.lastname: Wei
authors.forename: Ya-Guang
authors.initials: YG
authors.lastname: Chen
authors.forename: Zhong-Min
authors.initials: ZM
authors.lastname: Su
mesh_terms: D000327:Adsorption; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000737:chemistry*; D016062:Porosity; D013499:Surface Properties; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
chemical_list: D009942:Organometallic Compounds; D009943:Organophosphorus Compounds; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates