title: A facile template-free approach for the large-scale solid-phase synthesis of CdS nanostructures and their excellent photocatalytic performance.
abstract: The simple, template-free, low-temperature, large-scale synthesis of nanostructured CdS with the hexagonal wurtzite phase from bulk cadmium oxide under solid-phase conditions is demonstrated for the first time. The novel approach involves the homogenization of cadmium oxide (CdO) and thiourea in various stoichiometric ratios at moderate temperature. Among the different molar ratios of CdO and thiourea studied, the CdO/NH(2) CSNH(2) molar ratio of 1:2 is found to be the best to obtain highly pure CdS. The obtained CdS nanostructures exhibit excellent cubic morphology and high specific surface area with a particle size in the range of 5-7 nm. The bandgap of the nanostructured CdS is in the range of 2.42 to 2.46 eV due to its nanocrystalline nature. In photoluminescence studies, emission is observed at 520.34 and 536.42 nm, which is characteristic of the greenish-yellow region of the visible spectrum. Considering the bandgap of the CdS is within the visible region, the photocatalytic activity for H(2) generation and organic dye degradation are performed under visible-light irradiation. The maximum H(2) evolution of 2945 μmol h(-1) is obtained using nanostructured CdS prepared in the 1:2 ratio, which is three times higher than that of bulk CdS (1010 μmol h(-1) ). CdS synthesized using the 1:2 molar ratio shows maximum methylene blue degradation (87.5%) over a period of 60 min, which is approximately four times higher than that of bulk CdS (22%). This amazing performance of the material is due to its nanocrystalline nature and the high surface area of the CdS. The proposed simple methodology is believed to be a significant breakthrough in the field of nanotechnology, and the method can be further generalized as a rational preparation scheme for the large-scale synthesis of various other nanostructured metal sulfides.
authors.affiliation: Centre for Materials for Electronics Technology, Department of Information and Technology, Govt. of India, Panchawati off Pashan Road, Pune 411008, India.
authors.forename: Sanjay K
authors.initials: SK
authors.lastname: Apte
authors.forename: Sunil N
authors.initials: SN
authors.lastname: Garaje
authors.forename: Gurudas P
authors.initials: GP
authors.lastname: Mane
authors.forename: Ajayan
authors.initials: A
authors.lastname: Vinu
authors.forename: Sonali D
authors.initials: SD
authors.lastname: Naik
authors.forename: Dinesh P
authors.initials: DP
authors.lastname: Amalnerkar
authors.forename: Bharat B
authors.initials: BB
authors.lastname: Kale
mesh_terms: D019187:Cadmium Compounds / Q000737:chemistry*; D002384:Catalysis; D046529:Microscopy, Electron, Transmission; D049329:Nanostructures / Q000737:chemistry*; D036103:Nanotechnology / Q000379:methods; D010087:Oxides / Q000737:chemistry; D010777:Photochemistry / Q000379:methods; D013440:Sulfides / Q000737:chemistry*
chemical_list: D019187:Cadmium Compounds; D010087:Oxides; D013440:Sulfides; C034939:cadmium sulfide; C029663:cadmium oxide