title: Theory of optically forbidden d-d transitions in strongly correlated crystals.
abstract: A general multiband formulation of the linear and nonlinear optical response functions for realistic models of correlated crystals is presented. Dipole-forbidden d-d optical transitions originate from vertex functions, which we consider assuming the locality of an irreducible four-leg vertex. The unified formulation for second- and third-order response functions in terms of the three-leg vertex is suitable for practical calculations in solids. We illustrate the general approach by consideration of intra-atomic spin-flip contributions, with an energy of 2J, where J is a Hund exchange, in the simplest two-orbital model.
authors.affiliation: Radboud University of Nijmegen, Institute for Molecules and Materials, Heijendaalseweg 135, 6525 AJ Nijmegen, The Netherlands.
authors.forename: M I
authors.initials: MI
authors.lastname: Katsnelson
authors.forename: A I
authors.initials: AI
authors.lastname: Lichtenstein