title: Stannylated allyl carbonates as versatile building blocks for the diversity oriented synthesis of allylic amines and amides.
abstract: Stannylated allylic carbonates are suitable substrates for Pd-catalyzed allylic aminations. In DMF and with [allylPdCl](2) as catalyst the stannylated allyl amines formed can be directly coupled with electrophiles according to the Stille protocol, giving rise to highly functionalized building blocks in excellent yields.
authors.affiliation: Institut für Organische Chemie, Universität des Saarlandes, D-66123, Saarbrücken, Germany.
authors.forename: Christian
authors.initials: C
authors.lastname: Bukovec
authors.forename: Uli
authors.initials: U
authors.lastname: Kazmaier
mesh_terms: D000577:Amides / Q000138:chemical synthesis*; D000588:Amines / Q000138:chemical synthesis*; D002254:Carbonates / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D017971:Tin Compounds / Q000737:chemistry*
chemical_list: D000577:Amides; D000588:Amines; D002254:Carbonates; D017971:Tin Compounds; C031525:stannane