title: Novel layered crystalline zinc poly(styrene-phenylvinyl phosphonate)-phosphate synthesized by a simple route in a THF-water medium.
abstract: A novel type of organic polymer-inorganic hybrid material layered crystalline zinc poly(styrene-phenylvinyl phosphonate)-phosphate (ZnPSPPP) was prepared by the reaction of styrene-phenylvinyl phosphonic acid copolymer with zinc acetate dihydrate and sodium dihydrogen phosphate. The ZnPSPPP were characterized by FT-IR, diffusion reflection UV-Vis, AAS, N(2) volumetric adsorption, SEM, TEM and TG. Unexpectedly, the layered crystalline ZnPSPPP obtained was not synthesized with traditional methods as other zinc phosphonates, but with the ones for amorphous reactions without addition of any template. It can be deduced that the layered crystalline ZnPSPPP could have potential applications for heterogeneous catalyst supports.
authors.affiliation: The Key Laboratory of Applied Chemistry of Chongqing Municipality, Chongqing, 400715, China.
authors.forename: Jing
authors.initials: J
authors.lastname: Huang
authors.forename: Xiangkai
authors.initials: X
authors.lastname: Fu
authors.forename: Gang
authors.initials: G
authors.lastname: Wang
authors.forename: Chao
authors.initials: C
authors.lastname: Li
authors.forename: Xiaoyan
authors.initials: X
authors.lastname: Hu