title: Catalytic hydrodefluorination of pentafluorobenzene by [Ru(NHC)(PPh3)2(CO)H2]: a nucleophilic attack by a metal-bound hydride ligand explains an unusual ortho-regioselectivity.
authors.affiliation: School of EPS, Chemistry, Heriot-Watt University, Edinburgh, UK.
authors.forename: Julien A
authors.initials: JA
authors.lastname: Panetier
authors.forename: Stuart A
authors.initials: SA
authors.lastname: Macgregor
authors.forename: Michael K
authors.initials: MK
authors.lastname: Whittlesey
mesh_terms: D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry*; D005461:Fluorine / Q000737:chemistry*; D008024:Ligands; D008697:Methane / Q000031:analogs & derivatives / Q000737:chemistry; D011789:Quantum Theory; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D056831:Coordination Complexes; D008024:Ligands; C030011:carbene; D005461:Fluorine; D012428:Ruthenium; D008697:Methane