title: Co/Mn-mediated oxidative cross-coupling of indoles with β-keto esters via dioxygen activation: an efficient access to ketonization-olefination of indoles.
abstract: The Co/Mn-mediated oxidative cross-coupling of indoles with β-keto esters via dioxygen activation under mild conditions leads to ketonization-olefination of indoles. This reaction furnishes the highly functionalized products with excellent selectivity in good yields.
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
authors.forename: Wenliang
authors.initials: W
authors.lastname: Wu
authors.forename: Jing
authors.initials: J
authors.lastname: Xu
authors.forename: Shijun
authors.initials: S
authors.lastname: Huang
authors.forename: Weiping
authors.initials: W
authors.lastname: Su
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D004952:Esters; D007211:Indoles / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D058451:Oxidative Coupling; D010100:Oxygen / Q000737:chemistry*
chemical_list: D000475:Alkenes; D004952:Esters; D007211:Indoles; D007659:Ketones; D003035:Cobalt; D008345:Manganese; D010100:Oxygen