title: Inhibition of herbicide photodegradation by plant products.
abstract: Pesticide reactivity toward light is rarely considered at the leaf surface after crop treatment; regardless, these degradation reactions directly impact the pesticide effectiveness. The use of sunscreen adjuvants to overcome photodegradation has presented some limitations so far. Raw hydroalcoholic plant extracts have been recently proposed to be used as photoprotecting adjuvants; on a model system they significantly decreased the photodegradation of pesticide. Here it is demonstrated that their use makes possible a dose reduction. Sulcotrione, a selective herbicide for use in maize, was tested in a growth chamber equipped with simulated solar light against a typical weed in maize. Sprayed weeds were monitored by biometrical and physiological parameters. Sulcotrione minimum dose required for a good herbicidal efficacy (ED(50), corresponding to 50% of chlorophyll content decay) was estimated to be 55 g ha(-1). In the presence of grape extract added in a 3-fold excess compared to the herbicide, the ED(50) decreased to 34 g ha(-1). The use of grape extract allows extension of sulcotrione herbicidal activity and reduction of the dose by 35% in controlled conditions. This is a promising result for the effective dose field adjustment.
authors.affiliation: Laboratoire de Photochimie Moléculaire et Macromoléculaire, Clermont Université, Université Blaise Pascal, Clermont-Ferrand, France.
authors.forename: Boris
authors.initials: B
authors.lastname: Eyheraguibel
authors.forename: Claire
authors.initials: C
authors.lastname: Richard
authors.forename: Gerard
authors.initials: G
authors.lastname: Ledoigt
authors.forename: Alexandra
authors.initials: A
authors.lastname: Ter Halle
mesh_terms: D000277:Adjuvants, Pharmaceutic / Q000737:chemistry*; D002626:Chemistry, Pharmaceutical / Q000379:methods*; D003512:Cyclohexanones / Q000737:chemistry*; D006540:Herbicides / Q000737:chemistry*; D007700:Kinetics; D008698:Mesylates / Q000737:chemistry*; D010782:Photolysis; D010936:Plant Extracts / Q000737:chemistry*; D027843:Vitis / Q000737:chemistry
chemical_list: D000277:Adjuvants, Pharmaceutic; D003512:Cyclohexanones; D006540:Herbicides; D008698:Mesylates; D010936:Plant Extracts; C079906:sulcotrione