title: Production of an ordered (B2) CuPd nanoalloy by low-temperature annealing under hydrogen atmosphere.
abstract: CuPd (1/1) nanoalloys composed of disordered body-centered-cubic crystals (crystal size = 1.6 nm) were prepared by synchronous reduction of Cu and Pd precursor ions with NaBH(4). In situ XRD measurement revealed that Cu and Pd atoms in the CuPd nanoalloys are arranged into an ordered B2 structure under exposure to H(2) (5 kPa) at 373 K. Ordering of Cu and Pd atoms over a longer distance (up to 3.6 nm) was achieved by annealing the nanoalloys for a longer time under a H(2) atmosphere.
authors.affiliation: Catalysis Research Center, Hokkaido University, Nishi 10, Kita 21, Sapporo, 001-0021, Japan. yamauchi@cat.hokudai.ac.jp
authors.forename: Miho
authors.initials: M
authors.lastname: Yamauchi
authors.forename: Tatsuya
authors.initials: T
authors.lastname: Tsukuda