title: Reinvestigation of aminomethyltrifluoroborates and their application in Suzuki-Miyaura cross-coupling reactions.
abstract: A reinvestigation into the chemical composition of potassium aminomethyltrifluoroborates is reported. These trifluoroborato salts have been reassigned as zwitterionic ammoniomethyltrifluoroborates. Minor adjustments to the previously disclosed reaction conditions are reported that permit a similar level of activity as nucleophiles in Suzuki-Miyaura cross-coupling reactions.
authors.affiliation: Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, United States.
authors.forename: Jessica
authors.initials: J
authors.lastname: Raushel
authors.forename: Deidre L
authors.initials: DL
authors.lastname: Sandrock
authors.forename: Kanth V
authors.initials: KV
authors.lastname: Josyula
authors.forename: Deborah
authors.initials: D
authors.lastname: Pakyz
authors.forename: Gary A
authors.initials: GA
authors.lastname: Molander
mesh_terms: D000588:Amines / Q000737:chemistry; D001881:Borates / Q000138:chemical synthesis*; D002384:Catalysis; D017611:Fluorine Compounds / Q000737:chemistry; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry; D011188:Potassium / Q000737:chemistry; D011522:Protons; D013237:Stereoisomerism
chemical_list: D000588:Amines; D001881:Borates; D017611:Fluorine Compounds; D011522:Protons; D010165:Palladium; D011188:Potassium