title: 87Rb electron spin resonance on helium nanodroplets: the influence of optical pumping.
abstract: Hyperfine resolved electron spin resonance (ESR) measurements of single rubidium ((87)Rb) atoms isolated on superfluid helium nanodroplets are presented. In accordance with our previous work on (85)Rb, we find a relative increase of the hyperfine constant a(HFS) by about 400 ppm, depending on the size of the droplets. In order to optimize the ESR signal intensities, the processes of optical pumping of Rb atoms on helium droplets and of optical detection of the ESR transitions are investigated in detail. Both the laser intensity and polarization influences the ESR signal intensities. A simple model for optical pumping of Rb atoms on helium droplets is presented, which agrees well with the experimental results.
authors.affiliation: Institute of Experimental Physics, Graz University of Technology, Petersgasse 16, A-8010 Graz, Austria/EU.
authors.forename: Alexander
authors.initials: A
authors.lastname: Volk
authors.forename: Johannes
authors.initials: J
authors.lastname: Poms
authors.forename: Markus
authors.initials: M
authors.lastname: Koch
authors.forename: Wolfgang E
authors.initials: WE
authors.lastname: Ernst