title: Copper-catalyzed C-P bond construction via direct coupling of phenylboronic acids with H-phosphonate diesters.
abstract: A mild and efficient method was developed for the copper-catalyzed additions of H-phosphonate diesters to boronic acids under the copper catalyst system Cu(2)O/1,10-phenanthroline. To the best of our knowledge this finding is the first example of a copper-catalyzed synthesis of aryl phosphonates from arylboronic acids and H-phosphonate dialkyl esters.
authors.affiliation: Department of Chemistry and Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, Fujian, China.
authors.forename: Rongqiang
authors.initials: R
authors.lastname: Zhuang
authors.forename: Jian
authors.initials: J
authors.lastname: Xu
authors.forename: Zhenshi
authors.initials: Z
authors.lastname: Cai
authors.forename: Guo
authors.initials: G
authors.lastname: Tang
authors.forename: Meijuan
authors.initials: M
authors.lastname: Fang
authors.forename: Yufen
authors.initials: Y
authors.lastname: Zhao
mesh_terms: D001897:Boronic Acids / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D004952:Esters / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D063065:Organophosphonates / Q000737:chemistry*; D010758:Phosphorus / Q000737:chemistry*
chemical_list: D001897:Boronic Acids; D004952:Esters; D008024:Ligands; D063065:Organophosphonates; D010758:Phosphorus; D002244:Carbon; D003300:Copper; C010686:benzeneboronic acid