title: Pd-diimine: a highly selective catalyst system for the base-free oxidative Heck reaction.
abstract: Pd(OAc)(2)/3 is an efficient catalyst system for the base-free oxidative Heck reaction that outperforms the currently available catalysts for the more challenging substrates studied. The catalyst system is highly selective, and works at room temperature with dioxygen as the oxidant.
authors.affiliation: Stratingh Institute for Chemistry, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands.
authors.forename: Aditya L
authors.initials: AL
authors.lastname: Gottumukkala
authors.forename: Johannes F
authors.initials: JF
authors.lastname: Teichert
authors.forename: Dorus
authors.initials: D
authors.lastname: Heijnen
authors.forename: Niek
authors.initials: N
authors.lastname: Eisink
authors.forename: Simon
authors.initials: S
authors.lastname: van Dijk
authors.forename: Catalina
authors.initials: C
authors.lastname: Ferrer
authors.forename: Adri
authors.initials: A
authors.lastname: van den Hoogenband
authors.forename: Adriaan J
authors.initials: AJ
authors.lastname: Minnaard
mesh_terms: D002384:Catalysis; D007097:Imines / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010165:Palladium / Q000737:chemistry*; D013379:Substrate Specificity
chemical_list: D007097:Imines; D009942:Organometallic Compounds; D010165:Palladium