title: Fabrication of crystalline silicon spheres by selective laser heating in liquid medium.
abstract: Micrometer and submicrometer crystalline silicon spheres were fabricated by selective laser heating of irregular silicon particles in liquid medium. TEM, SEM, XRD, and XPS characterized the structure and morphology of the prepared silicon spheres. The results suggested that they were spherical with a single crystalline structure. In this study, the formation mechanism of the spheres is analyzed, and the process parameters are optimized to obtain high-quality silicon spheres. A theoretical deduction regarding the relationship between critical laser energy density and particle size is also discussed, by which we can predict that larger spheres can be obtained at higher laser energy densities.
authors.affiliation: Nanosystem Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan.
authors.forename: Xiangyou
authors.initials: X
authors.lastname: Li
authors.forename: Alexander
authors.initials: A
authors.lastname: Pyatenko
authors.forename: Yoshiki
authors.initials: Y
authors.lastname: Shimizu
authors.forename: Hongqiang
authors.initials: H
authors.lastname: Wang
authors.forename: Kenji
authors.initials: K
authors.lastname: Koga
authors.forename: Naoto
authors.initials: N
authors.lastname: Koshizaki