title: Catalyst-free functionalization for versatile modification of nonoxidized silicon structures.
abstract: Here, we report on a simple, catalyst-free route for obtaining highly versatile subsequent functionalization on Si nanowires and Si(111) substrates. The versatility of this approach allows subsequent functionalization not only for organic species but also for inorganic (nanomaterial) species. The method has the advantage of controlling the density of reactive cross-linkers without affecting the stability of the Si samples and without having metallic (or catalyst) residues on the surface. This method also allows formation of monolayers with a variety of termination groups and is expected to open up a wide range of opportunities for producing stable molecule-based (opto)electronic and (bio)sensing devices. Immobilization of inorganic nanomaterial on the Si samples offers advanced opportunities in molecular switches, (bio)sensors, molecular scale memory, and Si-based nanoelectronic devices.
authors.affiliation: The Department of Chemical Engineering and Russell Berrie Nanotechnology Institute, Technion-Israel Institute of Technology, Haifa 32000, Israel.
authors.forename: Sreenivasa Reddy
authors.initials: SR
authors.lastname: Puniredd
authors.forename: Ossama
authors.initials: O
authors.lastname: Assad
authors.forename: Thomas
authors.initials: T
authors.lastname: Stelzner
authors.forename: Silke
authors.initials: S
authors.lastname: Christiansen
authors.forename: Hossam
authors.initials: H
authors.lastname: Haick