title: N-Heterocyclic carbene containing element organic frameworks as heterogeneous organocatalysts.
abstract: A bifunctional imidazolium linker was used for the production of highly crosslinked element organic frameworks by Suzuki-coupling with tetrafunctional boronic acids. The resulting porous materials are good heterogeneous organocatalysts in the N-heterocyclic carbene-catalyzed conjugated umpolung of α,β-unsaturated cinnamaldehyde.
authors.affiliation: Department of Inorganic Chemistry, Dresden University of Technology, Bergstrasse 66, D-01069 Dresden, Germany.
authors.forename: Marcus
authors.initials: M
authors.lastname: Rose
authors.forename: Andreas
authors.initials: A
authors.lastname: Notzon
authors.forename: Maja
authors.initials: M
authors.lastname: Heitbaum
authors.forename: Georg
authors.initials: G
authors.lastname: Nickerl
authors.forename: Silvia
authors.initials: S
authors.lastname: Paasch
authors.forename: Eike
authors.initials: E
authors.lastname: Brunner
authors.forename: Frank
authors.initials: F
authors.lastname: Glorius
authors.forename: Stefan
authors.initials: S
authors.lastname: Kaskel
mesh_terms: D000171:Acrolein / Q000031:analogs & derivatives* / Q000737:chemistry; D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D006571:Heterocyclic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D007093:Imidazoles / Q000138:chemical synthesis* / Q000737:chemistry; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D015394:Molecular Structure; D010316:Particle Size; D016062:Porosity; D013237:Stereoisomerism; D013499:Surface Properties
chemical_list: D001897:Boronic Acids; D006571:Heterocyclic Compounds; D007093:Imidazoles; C030011:carbene; D000171:Acrolein; D008697:Methane; C012843:cinnamaldehyde