title: Mixture quantification using PLS in plastic scintillation measurements.
abstract: This article reports the capability of plastic scintillation (PS) combined with multivariate calibration (Partial least squares; PLS) to detect and quantify alpha and beta emitters in mixtures. While several attempts have been made with this purpose in mind using liquid scintillation (LS), no attempt was done using PS that has the great advantage of not producing mixed waste after the measurements are performed. Following this objective, ternary mixtures of alpha and beta emitters ((241)Am, (137)Cs and (90)Sr/(90)Y) have been quantified. Procedure optimisation has evaluated the use of the net spectra or the sample spectra, the inclusion of different spectra obtained at different values of the Pulse Shape Analysis parameter and the application of the PLS1 or PLS2 algorithms. The conclusions show that the use of PS+PLS2 applied to the sample spectra, without the use of any pulse shape discrimination, allows quantification of the activities with relative errors less than 10% in most of the cases. This procedure not only allows quantification of mixtures but also reduces measurement time (no blanks are required) and the application of this procedure does not require detectors that include the pulse shape analysis parameter.
authors.affiliation: Departament de Química Analítica, Universitat de Barcelona, Spain.
authors.forename: H
authors.initials: H
authors.lastname: Bagán
authors.forename: A
authors.initials: A
authors.lastname: Tarancón
authors.forename: G
authors.initials: G
authors.lastname: Rauret
authors.forename: J F
authors.initials: JF
authors.lastname: García
mesh_terms: D000465:Algorithms; D000512:Alpha Particles; D000576:Americium / Q000032:analysis* / Q000737:chemistry; D001610:Beta Particles; D002138:Calibration; D002588:Cesium Radioisotopes / Q000032:analysis* / Q000737:chemistry; D045424:Complex Mixtures / Q000032:analysis* / Q000737:chemistry; D016018:Least-Squares Analysis; D010969:Plastics / Q000737:chemistry; D011868:Radioisotopes / Q000032:analysis* / Q000737:chemistry; D012588:Scintillation Counting / Q000379:methods*; D013326:Strontium Radioisotopes / Q000032:analysis* / Q000737:chemistry; D015021:Yttrium Radioisotopes / Q000032:analysis* / Q000737:chemistry
chemical_list: D002588:Cesium Radioisotopes; D045424:Complex Mixtures; D010969:Plastics; D011868:Radioisotopes; D013326:Strontium Radioisotopes; D015021:Yttrium Radioisotopes; D000576:Americium