title: Polydimethylsiloxane as a macromolecular additive for enhanced performance of molecular bulk heterojunction organic solar cells.
abstract: The effect of the macromolecular additive, polydimethylsiloxane (PDMS), on the performance of solution processed molecular bulk heterojunction solar cells is investigated, and the addition of PDMS is shown to improve device power conversion efficiency by ∼70% and significantly reduce cell-to-cell variation, from a power conversion efficiency of 1.25 ± 0.37% with no PDMS to 2.16 ± 0.09% upon the addition of 0.1 mg/mL PDMS to the casting solution. The cells are based on a thiophene and isoindigo containing oligomer as the electron donor and [6,6]-phenyl-C61 butyric acid methyl ester (PC(61)BM) as the electron acceptor. PDMS is shown to have a strong influence on film morphology, with a significant decrease in film roughness and feature size observed. The morphology change leads to improved performance parameters, most notably an increase in the short circuit current density from 4.3 to 6.8 mA/cm(2) upon addition of 0.1 mg/mL PDMS. The use of PDMS is of particular interest, as this additive appears frequently as a lubricant in plastic syringes commonly used in device fabrication; therefore, PDMS may unintentionally be incorporated into device active layers.
authors.affiliation: The George and Josephine Butler Polymer Research Laboratory, Department of Chemistry and Center for Macromolecular Science and Engineering, University of Florida, Gainesville, Florida 32611-7200, USA.
authors.forename: Kenneth R
authors.initials: KR
authors.lastname: Graham
authors.forename: Jianguo
authors.initials: J
authors.lastname: Mei
authors.forename: Romain
authors.initials: R
authors.lastname: Stalder
authors.forename: Jae Won
authors.initials: JW
authors.lastname: Shim
authors.forename: Hyeunseok
authors.initials: H
authors.lastname: Cheun
authors.forename: Fred
authors.initials: F
authors.lastname: Steffy
authors.forename: Franky
authors.initials: F
authors.lastname: So
authors.forename: Bernard
authors.initials: B
authors.lastname: Kippelen
authors.forename: John R
authors.initials: JR
authors.lastname: Reynolds