title: Allene functionalization via bicyclic methylene aziridines.
abstract: The oxidative functionalization of olefins is a common method for the formation of vicinal carbon-heteroatom bonds. However, oxidative methods to transform allenes into synthetic motifs containing three contiguous carbon-heteroatom bonds are much less developed. This paper describes the use of bicyclic methylene aziridines (MAs), prepared via intramolecular allene aziridination, as scaffolds for functionalization of all three allene carbons.
authors: Department of Chemistry, University of Wisconsin-Madison, Madison, Wisconsin 53706, USA.
authors: Luke A
authors: LA
authors: Boralsky
authors: Dagmara
authors: D
authors: Marston
authors: R David
authors: RD
authors: Grigg
authors: John C
authors: JC
authors: Hershberger
authors: Jennifer M
authors: JM
authors: Schomaker
mesh_terms: D000466:Alkadienes / Q000737:chemistry*; D001388:Aziridines / Q000737:chemistry*; D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000737:chemistry*; D008697:Methane / Q000737:chemistry; D015394:Molecular Structure
chemical_list: D000466:Alkadienes; D001388:Aziridines; D019086:Bridged Bicyclo Compounds, Heterocyclic; C025947:propadiene; D008697:Methane