title: C-N bond-forming self-condensation of amide promoted by MoCl5 at room temperature.
abstract: The acylamidinium complex MoOCl(4)[MeC(O)N(Ph)C(Me)═NHPh] (2) was obtained by selective self-condensation of MeC(O)NHPh promoted by MoCl(5). Otherwise, the stable chloroiminium salt [MoOCl(4){HC(O)NMe(2)}][CH(Cl)═NMe(2)] (3) was isolated from HC(O)NMe(2)/MoCl(5).
authors: Dipartimento di Chimica e Chimica Industriale, Università di Pisa, Via Risorgimento 35, I-56126 Pisa, Italy.
authors: Sara
authors: S
authors: Dolci
authors: Fabio
authors: F
authors: Marchetti
authors: Guido
authors: G
authors: Pampaloni
authors: Stefano
authors: S
authors: Zacchini