title: Reaction-driven surface restructuring and selectivity control in allylic alcohol catalytic aerobic oxidation over Pd.
abstract: Synchronous, time-resolved DRIFTS/MS/XAS cycling studies of the vapor-phase selective aerobic oxidation of crotyl alcohol over nanoparticulate Pd have revealed surface oxide as the desired catalytically active phase, with dynamic, reaction-induced Pd redox processes controlling selective versus combustion pathways.
authors: Cardiff Catalysis Institute, School of Chemistry, Cardiff University, Cardiff CF10 3AT, UK. leeaf@cardiff.ac.uk
authors: Adam F
authors: AF
authors: Lee
authors: Christine V
authors: CV
authors: Ellis
authors: James N
authors: JN
authors: Naughton
authors: Mark A
authors: MA
authors: Newton
authors: Christopher M A
authors: CM
authors: Parlett
authors: Karen
authors: K
authors: Wilson