title: High capacity CO2 adsorption in a Mg(II)-based phosphine oxide coordination material.
abstract: The new porous phosphine coordination material, PCM-11, is an unusual 8,4-connected coordination polymer with an open 3-D pore structure, formed by reaction of Mg(II) with tris(para-carboxylato)triphenylphosphine oxide. The highly ionic nature of the metal-ligand bonding results in excellent thermal stability upon desolvation (>460 °C). PCM-11 is easily activated for small molecule sorption at low temperature without the requirement for solvent pre-exchange. It adsorbs 47.5 wt% CO(2) at 11.6 bar and 30 °C.
authors: Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX 78712-0165, USA.
authors: Alisha M
authors: AM
authors: Bohnsack
authors: Ilich A
authors: IA
authors: Ibarra
authors: Peter W
authors: PW
authors: Hatfield
authors: Ji Woong
authors: JW
authors: Yoon
authors: Young Kyu
authors: YK
authors: Hwang
authors: Jong-San
authors: JS
authors: Chang
authors: Simon M
authors: SM
authors: Humphrey