title: Uniform PEO star polymers synthesized in water via free radical polymerization or atom transfer radical polymerization.
abstract: Amphiphilic star shaped polymers with poly(ethylene oxide) (PEO) arms and cross-linked hydrophobic core were synthesized in water via either conventional free radical polymerization (FRP) or atom transfer radical polymerization (ATRP) techniques using a simple "arm-first" method. In FRP, PEO based macromonomers (MM) were used as arm precursors, which were then cross-linked by divinylbenzene (DVB) using 2,2'-azoisobutyronitrile (AIBN). Uniform star polymers (Mw/Mn < 1.2) were achieved through adjustment of the ratio of PEO MM, DVB, and AIBN. While in case of ATRP, both PEO MM, and PEO based macroinitiator (MI) were used as arm precursors with ethylene glycol diacrylate as cross-linker. Even more uniform star polymers with less contamination by low MW polymers were obtained, as compared to the products synthesized by FRP.
authors: Department of Chemistry, Carnegie Mellon University, 4400 Fifth Avenue, Pittsburgh, Pennsylvania 15213, USA.
authors: Wenwen
authors: W
authors: Li
authors: Krzysztof
authors: K
authors: Matyjaszewski
mesh_terms: D005609:Free Radicals / Q000737:chemistry*; D009570:Nitriles / Q000737:chemistry; D011092:Polyethylene Glycols / Q000737:chemistry*; D058105:Polymerization; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D020058:Styrene / Q000737:chemistry; D014867:Water / Q000737:chemistry
chemical_list: D005609:Free Radicals; D009570:Nitriles; D011108:Polymers; D014867:Water; D011092:Polyethylene Glycols; D020058:Styrene; C004526:azobis(isobutyronitrile)