title: Iron-catalyzed sulfonyl radical formations from sulfonylhydrazides and oxidative addition to alkenes.
abstract: Generation of sulfonyl radicals from sulfonylhydrazides has been achieved in the presence of a non-toxic iron catalyst and oxygen. The intermolecular addition of resultant sulfonyl radicals to alkenes affords β-hydroxysulfone compounds.
authors: School of Pharmaceutical Sciences, Institute of Medical, Pharmaceutical and Health Sciences, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan. tsuyoshi@p.kanazawa-u.ac.jp
authors: Tsuyoshi
authors: T
authors: Taniguchi
authors: Atsushi
authors: A
authors: Idota
authors: Hiroyuki
authors: H
authors: Ishibashi
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D005609:Free Radicals / Q000138:chemical synthesis; D006834:Hydrazines / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013450:Sulfones / Q000138:chemical synthesis*
chemical_list: D000475:Alkenes; D005609:Free Radicals; D006834:Hydrazines; D013450:Sulfones; D007501:Iron