title: Electrostatic and capillary force directed tunable 3D binary micro- and nanoparticle assemblies on surfaces.
abstract: We report a simple, rapid and cost-effective method based on evaporation induced assembly to grow 3D binary colloidal assemblies on a hydrophobic/hydrophilic substrate by simple drop casting. The evaporation of a mixed colloidal drop results in ring-like or uniform area deposition depending on the concentration of particles, and thus assembly occurs at the periphery of a ring or uniformly all over the drop area. Binary colloidal assemblies of different crystal structure are successfully prepared over a wide range of size ratios (γ = small/large) from 0.06 to 0.30 by tuning the γ of the micro- and nanoparticles used during assembly. The growth mechanism of 3D binary colloidal assemblies is investigated and it is found that electrostatic forces facilitate assembly formation until the end of the evaporation process, with capillary forces also playing a role. In addition, the effects of solvent type, humidity, and salt concentration on crystal formation and ordering behaviour are also examined. Furthermore, long range, highly ordered binary colloidal assemblies can be fabricated by the choice of a low conducting solvent combined with evaporation induced assembly.
authors: Interdisciplinary Nanoscience Center (iNANO), Aarhus University, Aarhus C, Denmark.
authors: G
authors: G
authors: Singh
authors: S
authors: S
authors: Pillai
authors: A
authors: A
authors: Arpanaei
authors: P
authors: P
authors: Kingshott