title: Emerging supramolecular synthons: C-H···π(chelate) interactions in metal bis(1,1-dithiolates).
abstract: Crystal structures of transition and main group element 1,1-dithiolates are shown to be partially sustained by C-H···π(chelate) interactions. For the planar binary bisdithiocarbamates, C-H···π(MS(2)C) interactions lead to aggregation patterns ranging from a 0-D four molecule aggregate to a 3-D architecture but with the majority of structures featuring 1-D or 2-D supramolecular assemblies.
authors: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia. Edward.Tiekink@gmail.com
authors: Edward R T
authors: ER
authors: Tiekink
authors: Julio
authors: J
authors: Zukerman-Schpector