title: Unprecedented diastereoselective generation of chiral-at-metal, half sandwich Ir(III) and Rh(III) complexes via anomeric isomerism on "sugar-coated" N-heterocyclic carbene ligands.
abstract: The first example of the diastereoselective synthesis induced by anomeric isomerism of sugar units in ligands of metal complexes was demonstrated. S and R configurations of chiral-at-metal Ir(III) and Rh(III) complexes were selectively obtained by using chelate-type NHC ligands with α- and β-glucopyranosyl units, respectively.
authors: Department of Chemistry, Graduate School of Science, Osaka City University, 3-3-138 Sugimoto, Sumiyoshi-ku, Osaka 558-8585, Japan.
authors: Teppei
authors: T
authors: Shibata
authors: Hideki
authors: H
authors: Hashimoto
authors: Isamu
authors: I
authors: Kinoshita
authors: Shigenobu
authors: S
authors: Yano
authors: Takanori
authors: T
authors: Nishioka