title: Assessment of aided phytostabilization of copper-contaminated soil by X-ray absorption spectroscopy and chemical extractions.
abstract: Field plots were established at a timber treatment site to evaluate remediation of Cu contaminated topsoils with aided phytostabilization. Soil containing 2600 mg kg⁻¹ Cu was amended with a combination of 5 wt% compost and 2 wt% iron grit, and vegetated. Sequential extraction was combined with extended X-ray absorption fine structure (EXAFS) spectroscopy to correlate changes in Cu distribution across five fractions with changes in the predominant Cu compounds two years after treatment in parallel treated and untreated field plots. Exchangeable Cu dominated untreated soil, most likely as Cu(II) species non-specifically bound to natural organic matter. The EXAFS spectroscopic results are consistent with the sequential extraction results, which show a major shift in Cu distribution as a result of soil treatment to the fraction bound to poorly crystalline Fe oxyhydroxides forming binuclear inner-sphere complexes.
authors: Waste Science and Technology, Department of Civil, Environmental and Natural Resources Engineering, Luleå University of Technology, Luleå SE-97187, Sweden. jurate.kumpiene@ltu.se
authors: Jurate
authors: J
authors: Kumpiene
authors: Michel
authors: M
authors: Mench
authors: Clémence M
authors: CM
authors: Bes
authors: Jeffrey P
authors: JP
authors: Fitts
mesh_terms: D001673:Biodegradation, Environmental; D005591:Chemical Fractionation; D003300:Copper / Q000032:analysis* / Q000737:chemistry / Q000378:metabolism; D052918:Environmental Restoration and Remediation / Q000379:methods*; D063245:Plant Development; D010944:Plants / Q000378:metabolism*; D012987:Soil / Q000737:chemistry; D012989:Soil Pollutants / Q000032:analysis* / Q000737:chemistry / Q000378:metabolism; D056928:X-Ray Absorption Spectroscopy
chemical_list: D012987:Soil; D012989:Soil Pollutants; D003300:Copper