title: Rapid carbonylative coupling reactions using palladium(I) dimers: applications to 11CO-radiolabelling for the synthesis of PET tracers.
abstract: Palladium dimers with sterically hindered phosphines have been shown to be excellent pre-catalysts for the aminocarbonylation of aryl halides to yield amides and one of them has been successfully employed as a pre-catalyst for the synthesis of (11)C-radiolabelled amides for PET imaging.
authors: Department of Chemistry, Imperial College London, South Kensington, London, UK SW7 2AZ.
authors: Gabriella
authors: G
authors: Buscemi
authors: Philip W
authors: PW
authors: Miller
authors: Steven
authors: S
authors: Kealey
authors: Antony D
authors: AD
authors: Gee
authors: Nicholas J
authors: NJ
authors: Long
authors: Jan
authors: J
authors: Passchier
authors: Ramon
authors: R
authors: Vilar
mesh_terms: D000577:Amides / Q000138:chemical synthesis*; D002248:Carbon Monoxide / Q000737:chemistry*; D002250:Carbon Radioisotopes / Q000737:chemistry; D002384:Catalysis; D003432:Cross-Linking Reagents / Q000737:chemistry; D019281:Dimerization; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D049268:Positron-Emission Tomography; D013997:Time Factors
chemical_list: D000577:Amides; D002250:Carbon Radioisotopes; D003432:Cross-Linking Reagents; D010165:Palladium; D002248:Carbon Monoxide