title: Two three-dimensional 2p-3d-4f heterometallic frameworks featuring a Ln6Cu24Na12 cluster as a node.
abstract: Two three-dimensional 2p-3d-4f heterometallic frameworks featuring a nanosized Ln(6)Cu(24)Na(12) (Ln = Gd, Dy) cluster as a node have been obtained under microwave irradiation conditions through the reaction of H(2)ANMA (H(2)ANMA = L-alanine-N-monoacetic acid), Cu(NO(3))(2), and Ln(NO(3))(3) (Ln = Gd for 1, Dy for 2) with NaOH in deionized water. Investigations on the magnetic properties show that 1 exhibits ferrimagnetic behavior. The electrical conductivity measurements reveal that 1 behaves as a proton conductor.
authors: State Key Laboratory of Physical Chemistry of Solid Surface and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
authors: Gui-Lin
authors: GL
authors: Zhuang
authors: Wen-Xian
authors: WX
authors: Chen
authors: Hai-Xia
authors: HX
authors: Zhao
authors: Xiang-Jian
authors: XJ
authors: Kong
authors: La-Sheng
authors: LS
authors: Long
authors: Rong-Bin
authors: RB
authors: Huang
authors: Lan-Sun
authors: LS
authors: Zheng