title: Induction in urothermal synthesis of chiral porous materials from achiral precursors.
abstract: Special asymmetric crystallization of porous framework materials from achiral precursors under urothermal conditions is successfully achieved by using an enantiopure liquid as a co-solvent and chirality induction agent, which provides a new strategy for the synthesis of homochiral porous materials containing only achiral building blocks.
authors: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China.
authors: Yao
authors: Y
authors: Kang
authors: Shumei
authors: S
authors: Chen
authors: Fei
authors: F
authors: Wang
authors: Jian
authors: J
authors: Zhang
authors: Xianhui
authors: X
authors: Bu
mesh_terms: D000972:Antineoplastic Agents, Phytogenic / Q000737:chemistry*; D002384:Catalysis; D002942:Circular Dichroism; D003460:Crystallization; D000081005:Cyclohexane Monoterpenes; D008958:Models, Molecular; D015394:Molecular Structure; D039821:Monoterpenes / Q000737:chemistry*; D004364:Pharmaceutical Preparations / Q000138:chemical synthesis*; D016062:Porosity; D012997:Solvents / Q000737:chemistry; D013237:Stereoisomerism; D013696:Temperature; D014508:Urea / Q000031:analogs & derivatives / Q000138:chemical synthesis*
chemical_list: D000972:Antineoplastic Agents, Phytogenic; D000081005:Cyclohexane Monoterpenes; D039821:Monoterpenes; D004364:Pharmaceutical Preparations; D012997:Solvents; C006923:carvone; D014508:Urea