title: "Click"-capture, ring-opening metathesis polymerization (ROMP), release: facile triazolation utilizing ROMP-derived oligomeric phosphates.
abstract: Soluble, high-load ring-opening metathesis polymerization (ROMP)-derived oligomeric triazole phosphates (OTP) are reported for application as efficient triazolating reagents of nucleophilic species. Utilizing a "Click"-capture, ROMP, release protocol, the efficient and purification-free, direct triazolation of N-, O-, and S-nucleophilic species was successfully achieved. A variety of OTP derivatives were rapidly synthesized as free-flowing solids on a multigram scale from commercially available materials.
authors: Department of Chemistry, University of Kansas, 1251 Wescoe Hall Drive, Lawrence, Kansas 66045, USA.
authors: Toby R
authors: TR
authors: Long
authors: Saqib
authors: S
authors: Faisal
authors: Pradip K
authors: PK
authors: Maity
authors: Alan
authors: A
authors: Rolfe
authors: Ryan
authors: R
authors: Kurtz
authors: Sarra V
authors: SV
authors: Klimberg
authors: Muhammad-Rabbie
authors: MR
authors: Najjar
authors: Fatima Z
authors: FZ
authors: Basha
authors: Paul R
authors: PR
authors: Hanson
mesh_terms: D015394:Molecular Structure; D010710:Phosphates / Q000737:chemistry*; D058105:Polymerization; D014230:Triazoles / Q000737:chemistry*
chemical_list: D010710:Phosphates; D014230:Triazoles