title: Metal-catalyzed synthesis of alternating copolymers.
abstract: The creation of polymers with a high degree of sequence and/or stereocontrol represents an exciting frontier in materials science. In order to obtain alternating polymers, coordination polymerization using well-defined metal complexes has played a leading role in the last two decades. In the following paper, we will describe selected published efforts to achieve these research goals using discrete, structurally well-characterized metal complexes.
authors: Chimie ParisTech, UMR CNRS 7223, 11 rue Pierre et Marie Curie, 75231 Paris, France.
authors: Emilie
authors: E
authors: Brulé
authors: Jia
authors: J
authors: Guo
authors: Geoffrey W
authors: GW
authors: Coates
authors: Christophe M
authors: CM
authors: Thomas
mesh_terms: D001388:Aziridines / Q000737:chemistry; D002248:Carbon Monoxide / Q000737:chemistry; D002384:Catalysis; D003035:Cobalt / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry*; D004852:Epoxy Compounds / Q000737:chemistry; D005030:Ethylenes / Q000737:chemistry; D007097:Imines / Q000737:chemistry; D007659:Ketones / Q000737:chemistry; D015394:Molecular Structure; D009757:Nylons / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D011091:Polyesters / Q000737:chemistry; D058105:Polymerization
chemical_list: D001388:Aziridines; D056831:Coordination Complexes; D004852:Epoxy Compounds; D005030:Ethylenes; D007097:Imines; D007659:Ketones; D009757:Nylons; D011091:Polyesters; D003035:Cobalt; D010165:Palladium; D002248:Carbon Monoxide; C036216:ethylene