title: Molecular orientation of asphaltenes and PAH model compounds in Langmuir-Blodgett films using sum frequency generation spectroscopy.
abstract: Asphaltenes are an important class of compounds in crude oil whose surface activity is important for establishing reservoir rock wettability which impacts reservoir drainage. While many phenomenological interfacial studies with crude oils and asphaltenes have been reported, there is very little known about the molecular level interactions between asphaltenes and mineral surfaces. In this study, we analyze Langmuir-Blodgett films of asphaltenes and related model compounds with sum frequency generation (SFG) vibrational spectroscopy. In SFG, the polarization of the input (vis, IR) and output (SFG) beams can be varied, which allows the orientation of different functional groups at the interface to be determined. SFG clearly indicates that asphaltene polycyclic aromatic hydrocarbons (PAHs) are highly oriented in the plane of the interface and that the peripheral alkanes are transverse to the interface. In contrast, model compounds with oxygen functionality have PAHs oriented transverse to the interface. Computational quantum chemistry is used to support corresponding band assignments, enabling robust determination of functional group orientations.
authors.affiliation: Schlumberger-Doll Research, Cambridge, Massachusetts, United States. bandrews@slb.com
authors.forename: A Ballard
authors.initials: AB
authors.lastname: Andrews
authors.forename: Arthur
authors.initials: A
authors.lastname: McClelland
authors.forename: Oona
authors.initials: O
authors.lastname: Korkeila
authors.forename: Alexander
authors.initials: A
authors.lastname: Demidov
authors.forename: Amber
authors.initials: A
authors.lastname: Krummel
authors.forename: Oliver C
authors.initials: OC
authors.lastname: Mullins
authors.forename: Zhan
authors.initials: Z
authors.lastname: Chen