title: Broadening the reactivity spectrum of a phthalocyanine catalyst while suppressing its nucleophilic, electrophilic and radical degradation pathways.
abstract: A robust molecule that resists degradation via nucleophilic, electrophilic and radical attacks is described. Coordinated O(2) is reduced catalytically, producing efficiently thyil radicals in spite of the extreme electronic deficiency of the catalyst.
authors.affiliation: Department of Chemistry and Environmental Science, New Jersey Institute of Technology, Newark, NJ 07102, USA.
authors.forename: Andrei
authors.initials: A
authors.lastname: Loas
authors.forename: Robert
authors.initials: R
authors.lastname: Gerdes
authors.forename: Yongyi
authors.initials: Y
authors.lastname: Zhang
authors.forename: Sergiu M
authors.initials: SM
authors.lastname: Gorun