title: Chirality delivery from a chiral copper(II) nucleotide complex molecule to its supramolecular architecture.
abstract: Chirality of a nucleotide-Cu(II) complex molecule, [CuNa(GMP)(HGMP)(H(2)O)(7)]·6(H(2)O)·CH(3)OH (GMP = guanosine 5'-monophosphate), is delivered to the three-dimensional supramolecular architecture by hydrogen bonding. Liquid- and solid-state circular dichroism (CD) spectroscopy are used to analyse the molecular and supramolecular chirality.
authors.affiliation: Key Laboratory of Clusters Science of Ministry of Education, School of Science, Beijing Institute of Technology, Beijing, 100081, P. R. China.
authors.forename: Pei
authors.initials: P
authors.lastname: Zhou
authors.forename: Hui
authors.initials: H
authors.lastname: Li
mesh_terms: D002942:Circular Dichroism; D056831:Coordination Complexes / Q000138:chemical synthesis / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D006157:Guanosine Monophosphate / Q000737:chemistry*; D006860:Hydrogen Bonding; D008968:Molecular Conformation; D013237:Stereoisomerism
chemical_list: D056831:Coordination Complexes; D003300:Copper; D006157:Guanosine Monophosphate