title: "n-Doping" of deltahedral Zintl ions.
abstract: We report a simple and efficient method for replacing germanium atoms in deltahedral Ge(9)(4-) clusters with Sb or Bi. While reactions of Ge(9)(4-) with EPh(3) (E = Sb, Bi) at room temperature are known to produce mono- and disubstituted clusters [Ph(2)E-Ge(9)-Ge(9)-EPh(2)](4-) and [Ph(2)E-Ge(9)-EPh(2)](2-), respectively, at elevated temperatures or with sonication they result in exchange of Ge cluster atoms with Sb or Bi. Structurally characterized from such reactions are the novel "n-doped" deltahedral Zintl ions [(EGe(8))-(Ge(8)E)](4-), (Sb(2)Ge(7))(2-), and [(SbGe(8))-SbPh(2)](2-).
authors.affiliation: Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, Indiana 46556, USA.
authors.forename: Miriam M
authors.initials: MM
authors.lastname: Gillett-Kunnath
authors.forename: Allen G
authors.initials: AG
authors.lastname: Oliver
authors.forename: Slavi C
authors.initials: SC
authors.lastname: Sevov