title: Fate of carbosulfan and monocrotophos in sandy loam soils of Pakistan under field conditions at different watertable depths.
abstract: Information regarding pesticide mobility is critical for the evaluation of pesticide management practices. For this purpose, lysimetric studies were conducted to develop assessment schemes to protect groundwater from unacceptable effects caused by pesticide use. By using these studies, specific monitoring actions and prevention measures for the protection of waters can be studied, and the results thus obtained can provide the local authorities and the decision makers with an identification tool for demarcating risk areas. Pesticide residues were found at the bottom of lysimeters in the following pattern i.e., 1.52 > 2.1 > 2.74 m which could represent an "index of risk" for groundwater pollution. Regressions built for carbofuran and monocrotophos against watertable depths showed a decreasing trend of pesticide in higher watertable treatments. These findings support the existence of a significant role for chromatographic flow in sandy texture soil. Moreover, the higher values of pesticide residue at the bottom of lysimeters reflect that chromatographic flow as well as preferential flow pattern prevails during higher precipitation events. The precipitation received during the study was higher than the 10 year average and can be considered relatively as a worst case scenario. Finally, the authors have recommended a standardized pesticide monitoring scheme for groundwater in accordance with the already validated generic schemes in developed countries.
authors.affiliation: Department of Chemistry, University of Sargodha, Sargodha, Pakistan. tariqmi2000@yahoo.com
authors.forename: Muhammad Ilyas
authors.initials: MI
authors.lastname: Tariq
authors.forename: Shahzad
authors.initials: S
authors.lastname: Afzal
authors.forename: Farina
authors.initials: F
authors.lastname: Shahzad
mesh_terms: D002219:Carbamates / Q000032:analysis*; D002235:Carbofuran / Q000032:analysis; D004784:Environmental Monitoring / Q000379:methods*; D007306:Insecticides / Q000032:analysis; D008999:Monocrotophos / Q000032:analysis*; D010154:Pakistan; D010573:Pesticide Residues / Q000032:analysis; D012044:Regression Analysis; D012987:Soil / Q000737:chemistry; D012989:Soil Pollutants / Q000032:analysis*; D014872:Water Movements; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D002219:Carbamates; D007306:Insecticides; D010573:Pesticide Residues; D012987:Soil; D012989:Soil Pollutants; D014874:Water Pollutants, Chemical; D008999:Monocrotophos; D002235:Carbofuran; C035038:carbosulfan