title: Highly phosphorescent crystals of vaulted trans-bis(salicylaldiminato)platinum(II) complexes.
abstract: Unprecedented strong phosphorescent emission in the crystalline state is observed for a variety of vaulted trans-bis(salicylaldiminato)platinum(II) complexes which are newly synthesized as a third coordination mode of well-studied bis(salicylaldiminato) complexes. This Communication describes the dynamic photophysical properties of these complexes in the liquid and crystalline states and a mechanistic rationale for the strong emission in the crystalline state.
authors.affiliation: Department of Chemistry, Graduate School of Engineering Science, Osaka University, Machikaneyama, Toyonaka, Osaka 560-8531, Japan.
authors.forename: Naruyoshi
authors.initials: N
authors.lastname: Komiya
authors.forename: Minoru
authors.initials: M
authors.lastname: Okada
authors.forename: Kanako
authors.initials: K
authors.lastname: Fukumoto
authors.forename: Daisuke
authors.initials: D
authors.lastname: Jomori
authors.forename: Takeshi
authors.initials: T
authors.lastname: Naota