title: Synthesis of fatty acid methyl ester from crude jatropha (Jatropha curcas Linnaeus) oil using aluminium oxide modified Mg-Zn heterogeneous catalyst.
abstract: The synthesis of fatty acid methyl esters (FAME) as a substitute to petroleum diesel was investigated in this study from crude jatropha oil (CJO), a non-edible, low-cost alternative feedstock, using aluminium modified heterogeneous basic oxide (Mg-Zn) catalyst. The transesterification reaction with methanol to methyl esters yielded 94% in 6h with methanol-oil ratio of 11:1, catalyst loading of 8.68 wt.% at 182°C and the properties of CJO fuel produced were determine and found to be comparable to the standards according to ASTM. In the range of experimental parameters investigated, it showed that the catalyst is selective to production of methyl esters from oil with high free fatty acid (FFA) and water content of 7.23% and 3.28%, respectively in a single stage process. Thus, jatropha oil is a promising feedstock for methyl ester production and large scale cultivation will help to reduce the product cost.
authors.affiliation: School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia.
authors.forename: M A
authors.initials: MA
authors.lastname: Olutoye
authors.forename: B H
authors.initials: BH
authors.lastname: Hameed
mesh_terms: D000537:Aluminum Oxide / Q000737:chemistry*; D002384:Catalysis; D004951:Esterification; D004952:Esters / Q000138:chemical synthesis*; D005227:Fatty Acids / Q000138:chemical synthesis*; D031286:Jatropha / Q000737:chemistry*; D008274:Magnesium / Q000737:chemistry*; D010578:Petroleum / Q000032:analysis*; D010938:Plant Oils / Q000737:chemistry*; D016062:Porosity; D059027:Recycling; D013696:Temperature; D015032:Zinc / Q000737:chemistry*
chemical_list: D004952:Esters; D005227:Fatty Acids; D010578:Petroleum; D010938:Plant Oils; D008274:Magnesium; D015032:Zinc; D000537:Aluminum Oxide