title: Highly regio- and diastereoselective anionic [3 + 2] cycloaddition under phase transfer catalytic conditions.
abstract: A highly trans and regioselective anionic formal [3 + 2] cycloaddition was achieved with allylic sulfones having an MBH acrylamide backbone under phase transfer organocatalytic conditions giving rise to the formation of unprecedented densely substituted cyclopentene derivatives.
authors.affiliation: CNRS UMR COBRA, Université et INSA de Rouen, FR INC3M 3038, IRCOF (Research Institute in Fine Organic Chemistry), rue Tesnière, 76821 Mont Saint Aignan cedex, France.
authors.forename: Vincent
authors.initials: V
authors.lastname: Gembus
authors.forename: Svetlana
authors.initials: S
authors.lastname: Postikova
authors.forename: Vincent
authors.initials: V
authors.lastname: Levacher
authors.forename: Jean-François
authors.initials: JF
authors.lastname: Brière
mesh_terms: D020106:Acrylamide / Q000737:chemistry; D002384:Catalysis; D003517:Cyclopentanes / Q000737:chemistry; D013237:Stereoisomerism; D013379:Substrate Specificity; D013450:Sulfones / Q000737:chemistry*
chemical_list: D003517:Cyclopentanes; D013450:Sulfones; D020106:Acrylamide