title: Non-cyclic geometric phase of nuclear quadrupole resonance signals of powdered samples.
abstract: The non-cyclic geometric phase of ¹⁴N and ³⁵Cl NQR signals induced by the character of trajectory of nuclear magnetization motion upon pulse r.f. excitation of powdered samples is studied. Analytical expressions for the geometric phases of NQR signals of the nuclei of spins I=1 and 3/2 upon nuclear magnetization rotation induced by means of r.f. pulses with frequency detuned from the resonance and for any impulse duration for a separate crystallite are obtained. It is shown that the geometric phase recorded for the signal from a powdered sample at Δω=0 can be different from zero and can oscillate upon changes in duration of the r.f. excitation pulse. An alternative variant of the nutation experiment aimed at obtaining the asymmetry parameter η from locations of frequency singularities in the nutation phase spectrum for nuclei of spin I=3/2 in powder substances is proposed.
authors.affiliation: Department of Physics, Adam Mickiewicz University, Umultowska 85, 61-614 Poznań, Poland. glotova@amu.edu.pl
authors.forename: O
authors.initials: O
authors.lastname: Glotova
authors.forename: N
authors.initials: N
authors.lastname: Ponamareva
authors.forename: N
authors.initials: N
authors.lastname: Sinyavsky
authors.forename: B
authors.initials: B
authors.lastname: Nogaj