title: Simultaneous elution of polycyclic aromatic hydrocarbons and heavy metals from contaminated soil by two amino acids derived from beta-cyclodextrins.
abstract: Two highly water-soluble amino acids, which derived from beta-CDs, i.e., glutamic acid-beta-cyclodextrin (GluCD) and ethylene-diamine-beta-cyclodextrin (EDCD), were synthesized and were examined for their effect on solubilization of anthracene (ANT), complexation of cadmium (Cd2+), and elution removal of ANT and Cd2+ in soil. The results showed that GluCD and EDCD were powerful complexant for ANT and Cd2+. In the presence of 10 g/L GluCD and EDCD, the solubilization of ANT increased by 47.04 and 23.85 times compared to the control, respectively. GluCD resulted in approximately 90% complexation of Cd2+ while 70% complexation was observed for EDCD. Simultaneously, GluCD and EDCD could greatly enhance the elution removal of ANT and Cd2+ from soil. GluCD resulted in the highest elution efficiency of ANT and Cd2+. With the addition of 10 g/L GluCD, 53.5% of ANT and 85.6% of Cd2+ were eluted, respectively. The ANT had a negligible effect on the Cd2+ removal due to different complexing sites of ANT and Cd2+, while Cd2+ enhanced the ANT removal under the addition of GluCD because Cd2+ neutralized the -COOH group of GluCD. Adversely, the removal of ANT was decreased with Cd2+ under the addition of EDCD, this was due to the fact that Cd2+ enhanced the polarity of EDCD molecule and inhibited the complexation between ANT and EDCD. The study suggested that GluCD could be preferred and be successfully applied to remediation of heavy metals or organic compounds in contaminated soil.
authors.affiliation: School of Environment & Municipal Engineering, Xi'an Architecture Science Technology University, Xi'an 710055, China. yangchengjian09@163.com
authors.forename: Chengjian
authors.initials: C
authors.lastname: Yang
authors.forename: Qingru
authors.initials: Q
authors.lastname: Zeng
authors.forename: Yunzhong
authors.initials: Y
authors.lastname: Wang
authors.forename: Bohan
authors.initials: B
authors.lastname: Liao
authors.forename: Jian
authors.initials: J
authors.lastname: Sun
authors.forename: Hui
authors.initials: H
authors.lastname: Shi
authors.forename: Xingdou
authors.initials: X
authors.lastname: Chen
mesh_terms: D000873:Anthracenes / Q000302:isolation & purification*; D002104:Cadmium / Q000302:isolation & purification*; D005029:Ethylenediamines / Q000138:chemical synthesis*; D018698:Glutamic Acid / Q000138:chemical synthesis*; D012989:Soil Pollutants / Q000302:isolation & purification*; D047392:beta-Cyclodextrins / Q000138:chemical synthesis*
chemical_list: D000873:Anthracenes; D005029:Ethylenediamines; D012989:Soil Pollutants; D047392:beta-Cyclodextrins; C557802:ethylene-diamine-beta-cyclodextrin; C557803:glutamic acid-beta-cyclodextrin; D002104:Cadmium; D018698:Glutamic Acid; C034020:anthracene