title: The effects of ultrasound on organoclay dispersion in the PP matrix.
abstract: PP/MMT nanocomposites were prepared by solution intercalation using sonication and quiescent conditions, and the effects on the morphological, thermal and mechanical properties were evaluated by WAXD, TEM, DMA, TGA and DSC analyses. The present study aims to clarify the effects of ultrasound use on the organoclay surface with different amounts of organic modifiers and on the exfoliation processes. The sonication process decreased around of 200 nm the aspect ratio of C15A organoclay. Besides, the effectiveness of the ultrasound process was only achieved with the C15A system because there is a small energetic barrier between their layers (clay with larger d 001). The sonication process increased the exfoliation and distribution of the C15A platelets in the PP matrix, increasing by 5% its reinforcement capacity. However, for I44P system, the use of ultrasound did not show any significant effect on the morphology and consequently on the final properties of the PP matrix. The T(c) temperature and the thermal stability of the PP nanocomposites were increased, independent of the clay type or of the ultrasound use.
authors.affiliation: Instituto de Química, Universidade Federal do Rio Grande do Sul, Porto Alegre-RS, Brazil.
authors.forename: K S
authors.initials: KS
authors.lastname: Santos
authors.forename: E
authors.initials: E
authors.lastname: Bischoff
authors.forename: S A
authors.initials: SA
authors.lastname: Liberman
authors.forename: M A S
authors.initials: MA
authors.lastname: Oviedo
authors.forename: R S
authors.initials: RS
authors.lastname: Mauler
mesh_terms: D000538:Aluminum Silicates / Q000737:chemistry* / Q000528:radiation effects*; D000077215:Clay; D004655:Emulsions / Q000737:chemistry* / Q000528:radiation effects*; D009930:Organic Chemicals / Q000737:chemistry* / Q000528:radiation effects*; D011829:Radiation Dosage; D013010:Sonication / Q000379:methods*
chemical_list: D000538:Aluminum Silicates; D004655:Emulsions; D009930:Organic Chemicals; D000077215:Clay