title: Pentafluoropyridine as a fluorinating reagent for preparing a hydrocarbon soluble β-diketiminatolead(II) monofluoride.
abstract: A well-designed method for the preparation of a β-diketiminatolead(II) monofluoride has been developed using LPbNMe(2) (L = [CH{C(Me)(2,6-iPr(2)C(6)H(3)N)}(2)]) and pentafluoropyridine (C(5)F(5)N). The resulting LPbF was used for the synthesis of amidinatosilicon(II) monofluoride. Moreover the activation of a ketone was observed when the LPbF was treated with PhCOCF(3).
authors.affiliation: Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, 37077 Göttingen, Germany.
authors.forename: Anukul
authors.initials: A
authors.lastname: Jana
authors.forename: Sankaranarayana Pillai
authors.initials: SP
authors.lastname: Sarish
authors.forename: Herbert W
authors.initials: HW
authors.lastname: Roesky
authors.forename: Dirk
authors.initials: D
authors.lastname: Leusser
authors.forename: Ina
authors.initials: I
authors.lastname: Objartel
authors.forename: Dietmar
authors.initials: D
authors.lastname: Stalke