title: 2-[(4-Methyl-phen-yl)sulfan-yl]aniline.
abstract: The least-squares planes defined by the aromatic moieties in the title aniline derivative, C(13)H(13)NS, are nearly perpendicular to each other, forming a dihedral angle of 87.80 (7)°. Apart from a weak intramolecular N-H⋯S hydrogen bond, a co-operative set of N-H⋯N hydrogen bonds present in the crystal structure leads to the formation of tetra-meric units.
authors.affiliation: Nelson Mandela Metropolitan University, Summerstrand Campus, Department of Chemistry, University Way, Summerstrand, PO Box 77000, Port Elizabeth 6031, South Africa.
authors.forename: Richard
authors.initials: R
authors.lastname: Betz
authors.forename: Thomas
authors.initials: T
authors.lastname: Gerber
authors.forename: Henk
authors.initials: H
authors.lastname: Schalekamp