title: Mn(C2O4)(H2O)(0.25): an antiferromagnetic oxalato-based cage compound.
abstract: An oxalato-based cage compound Mn(C(2)O(4))(H(2)O)(0.25) was obtained using a solvothermal method. Mn is pentagonal bipyramidal coordinated with O from oxalato with three-atom and one-atom bridges. There are hydrogen bonds between the framework and clathrated H(2)O. A 3D long-range magnetic ordering was observed at 10.9 K.
authors.affiliation: BNLMS, Organic Solid Laboratory, CMS & Institute of Chemistry, Chinese Academy of Science, Beijing, 100190, P. R. China. zhangbin@iccas.ac.cn
authors.forename: Bin
authors.initials: B
authors.lastname: Zhang
authors.forename: Yan
authors.initials: Y
authors.lastname: Zhang
authors.forename: Jinbiao
authors.initials: J
authors.lastname: Zhang
authors.forename: Xiang
authors.initials: X
authors.lastname: Hao
authors.forename: Daoben
authors.initials: D
authors.lastname: Zhu