title: Fluorous tagging of DABCO through halogen bonding: recyclable catalyst for the Morita-Baylis-Hillman reaction.
abstract: The halogen-bonded adduct between DABCO and two molecules of perfluorooctyl iodide (DABCO·(C(8)F(17)I)(2)) acts as a recyclable organocatalyst for the Morita-Baylis-Hillman reaction. This "supramolecular fluorous catalyst" is readily accessible and can be recovered by simple precipitation/filtration.
authors.affiliation: Laboratoire BioCIS-CNRS, Faculté de Pharmacie, Univ Paris Sud, 5 rue J.B. Clément, F-92296, Châtenay-Malabry, France.
authors.forename: Sophie
authors.initials: S
authors.lastname: Dordonne
authors.forename: Benoit
authors.initials: B
authors.lastname: Crousse
authors.forename: Danièle
authors.initials: D
authors.lastname: Bonnet-Delpon
authors.forename: Julien
authors.initials: J
authors.lastname: Legros
mesh_terms: D002384:Catalysis; D005461:Fluorine / Q000737:chemistry*; D005466:Fluorocarbons / Q000737:chemistry*; D006219:Halogens / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D005466:Fluorocarbons; D006219:Halogens; D005461:Fluorine