title: Palladium-catalyzed aryl-aryl bond formation through double C-H activation.
abstract: Aryl-aryl bond formation constitutes one of the most important subjects in organic synthesis. The recently developed direct arylation reactions for the formation of aryl-aryl bond have emerged as very attractive alternatives to traditional cross-coupling reactions. Particularly, the direct arylation through double C-H activation using the simple arenes as both coupling partners is a highly economic and attractive method. In this chapter, the recent progress of Pd-catalyzed aryl-aryl oxidative coupling reactions through double C-H activation is presented.
authors.affiliation: State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Lu, Shanghai 200032, China. slyou@mail.sioc.ac.cn
authors.forename: Shu-Li
authors.initials: SL
authors.lastname: You
authors.forename: Ji-Bao
authors.initials: JB
authors.lastname: Xia
mesh_terms: D002384:Catalysis; D002625:Chemistry, Organic / Q000379:methods; D006841:Hydrocarbons, Aromatic / Q000138:chemical synthesis*; D006859:Hydrogen / Q000737:chemistry*; D058451:Oxidative Coupling; D010100:Oxygen / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*
chemical_list: D006841:Hydrocarbons, Aromatic; D010165:Palladium; D006859:Hydrogen; D010100:Oxygen