title: Enhanced photocurrents via redox modulation by fluoride binding to oxoporphyrinogen in a zinc porphyrin-oxoporphyrinogen surface modified TiO2 supramolecular solar cell.
abstract: A novel approach for improving photocurrent in a supramolecular solar cell, composed of zinc porphyrin-oxoporphyrinogen (ZnP-OxP) surface-modified TiO(2), by redox tuning through fluoride anion binding to the redox active host, OxP is demonstrated.
authors.affiliation: Department of Chemistry, Wichita State University, 1845, Fairmount, Wichita, KS 67260, USA.
authors.forename: Navaneetha K
authors.initials: NK
authors.lastname: Subbaiyan
authors.forename: Jonathan P
authors.initials: JP
authors.lastname: Hill
authors.forename: Katsuhiko
authors.initials: K
authors.lastname: Ariga
authors.forename: Shunichi
authors.initials: S
authors.lastname: Fukuzumi
authors.forename: Francis
authors.initials: F
authors.lastname: D'Souza
mesh_terms: D000838:Anions / Q000737:chemistry; D004579:Electron Transport; D005459:Fluorides / Q000737:chemistry*; D008027:Light; D053768:Metal Nanoparticles / Q000737:chemistry; D008665:Metalloporphyrins / Q000737:chemistry*; D010084:Oxidation-Reduction; D011165:Porphyrinogens / Q000737:chemistry*; D012993:Solar Energy; D014025:Titanium / Q000737:chemistry*
chemical_list: D000838:Anions; D008665:Metalloporphyrins; D011165:Porphyrinogens; C017802:zinc hematoporphyrin; C009495:titanium dioxide; D014025:Titanium; D005459:Fluorides