title: Three-dimensional nanocrystal superlattices grown in nanoliter microfluidic plugs.
abstract: We studied the self-assembly of inorganic nanocrystals (NCs) confined inside nanoliter droplets (plugs) into long-range ordered superlattices. We showed that a capillary microfluidic platform can be used for the optimization of growth conditions for NC superlattices and can provide insights into the kinetics of the NC assembly process. The utility of our approach was demonstrated by growing large (up to 200 μm) three-dimensional (3D) superlattices of various NCs, including Au, PbS, CdSe, and CoFe(2)O(4). We also showed that it is possible to grow 3D binary nanoparticle superlattices in the microfluidic plugs.
authors.affiliation: Department of Chemistry, University of Chicago, Chicago, Illinois 60637, USA.
authors.forename: Maryna I
authors.initials: MI
authors.lastname: Bodnarchuk
authors.forename: Liang
authors.initials: L
authors.lastname: Li
authors.forename: Alice
authors.initials: A
authors.lastname: Fok
authors.forename: Sigrid
authors.initials: S
authors.lastname: Nachtergaele
authors.forename: Rustem F
authors.initials: RF
authors.lastname: Ismagilov
authors.forename: Dmitri V
authors.initials: DV
authors.lastname: Talapin