title: Vibrational spectroscopic study on some Hofmann type clathrates: M(2-(1-cyclohexenyl)ethylamine)2Ni(CN)4·2benzene (M=Ni and Cd).
abstract: New Hofmann type benzene clathrates in the form of M(CyHEA)2Ni(CN)4·2benzene (where CyHEA=2-(1-cyclohexenyl)ethylamine and M=Ni or Cd) have been prepared in powder form and FT-IR and Raman spectra have been reported. The results suggest that title compounds are similar in structure to Hofmann type clathrates and their structures consist of polymeric layers of |M-Ni(CN)4|∞ with the CyHEA molecule bounded to the metal atoms (M).
authors.affiliation: Department of Physics, Arts and Science Faculty, Inonu University, Malatya 44069, Turkey. tizgi@inonu.edu.tr
authors.forename: Tekin
authors.initials: T
authors.lastname: Izgi
authors.forename: Cemal
authors.initials: C
authors.lastname: Parlak
authors.forename: Mustafa
authors.initials: M
authors.lastname: Senyel
mesh_terms: D001554:Benzene / Q000737:chemistry*; D002104:Cadmium / Q000737:chemistry; D003510:Cyclohexanes / Q000737:chemistry*; D005021:Ethylamines / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman
chemical_list: C524450:2-(1-cyclohexenyl)ethylamine; D003510:Cyclohexanes; D005021:Ethylamines; D002104:Cadmium; D009532:Nickel; D001554:Benzene