title: cis-(Pyridin-2-ylcarbonimidodithio-ato-κS,S')bis-(triphenyl-phosphane-κP)palladium(II).
abstract: The title compound, [Pd(C(6)H(4)N(2)S(2))(C(18)H(15)P)(2)], was obtained as a minor product from the reaction of trans-PdCl(2)(PPh(3))(2) with piperazine-1,4-dicarbothioic acid bis-(pyridin-2-yl)amide. The Pd(II) atom displays a slightly distorted square-planar PdP(2)S(2) geometry with a bidentately coordinated pyridin-2-ylcarbonimidodithio-ate ligand and two triphenyl-phosphine mol-ecules, coordinated in cis positions. The crystal structure features weak π-π [centroid-centroid distance =3.7327(15) Å] and C-H⋯π inter-actions and contains an almost spherically shaped void of 50.4 Å(3) per unit cell.
authors.affiliation: Institute of General and Inorganic Chemistry, NAS Ukraine, Kyiv, prosp. Palladina 32/34, 03680, Ukraine.
authors.forename: Vladimir V
authors.initials: VV
authors.lastname: Bon
authors.forename: Svitlana I
authors.initials: SI
authors.lastname: Orysyk
authors.forename: Vasily I
authors.initials: VI
authors.lastname: Pekhnyo