title: 7-Deacetyl-gedunin.
abstract: THE TITLE COMPOUND [SYSTEMATIC NAME: (1S,3aS,4aR,4bS,5R,6aR,10aR,10bR,12aS)-1-(furan-3-yl)-5-hy-droxy-4b,7,7,10a,12a-penta-methyl-4b,5,6,6a,7,10a,10b,11,12,12a-deca-hydro-naphtho-[2,1-f]oxireno[2,3-d]isochromene-3,8(1H,3aH)-dione], C(26)H(32)O(6), which is a limonoid-type triterpene isolated from the seeds of X. moluccensis, crystallizes with three independent mol-ecules with very similar geometries in the asymmetric unit. In each mol-ecule, the four fused six-membered rings of the genudin core adopt distorted half-chair, chair, twist-boat and twisted half-chair conformations. In the crystal, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into helical chains propagated in [100]. Weak non-classical C-H⋯O contacts further consolidate the crystal packing.
authors.forename: Warin
authors.initials: W
authors.lastname: Ravangpai
authors.forename: Thapong
authors.initials: T
authors.lastname: Theerawattananond
authors.forename: Somjai
authors.initials: S
authors.lastname: Pengpreecha
authors.forename: Nongnuj
authors.initials: N
authors.lastname: Muangsin
authors.forename: Khanitha
authors.initials: K
authors.lastname: Pudhom