title: Temperature and pressure influence on maximum rates of pressure rise during explosions of propane-air mixtures in a spherical vessel.
abstract: The maximum rates of pressure rise during closed vessel explosions of propane-air mixtures are reported, for systems with various initial concentrations, pressures and temperatures ([C(3)H(8)]=2.50-6.20 vol.%, p(0)=0.3-1.3 bar; T(0)=298-423 K). Experiments were performed in a spherical vessel (Φ=10 cm) with central ignition. The deflagration (severity) index K(G), calculated from experimental values of maximum rates of pressure rise is examined against the adiabatic deflagration index, K(G, ad), computed from normal burning velocities and peak explosion pressures. At constant temperature and fuel/oxygen ratio, both the maximum rates of pressure rise and the deflagration indices are linear functions of total initial pressure, as reported for other fuel-air mixtures. At constant initial pressure and composition, the maximum rates of pressure rise and deflagration indices are slightly influenced by the initial temperature; some influence of the initial temperature on maximum rates of pressure rise is observed only for propane-air mixtures far from stoichiometric composition. The differentiated temperature influence on the normal burning velocities and the peak explosion pressures might explain this behaviour.
authors.affiliation: Ilie Murgulescu Institute of Physical Chemistry, 202 Spl. Independentei, 060021 Bucharest, Romania. drazus@icf.ro
authors.forename: D
authors.initials: D
authors.lastname: Razus
authors.forename: V
authors.initials: V
authors.lastname: Brinzea
authors.forename: M
authors.initials: M
authors.lastname: Mitu
authors.forename: C
authors.initials: C
authors.lastname: Movileanu
authors.forename: D
authors.initials: D
authors.lastname: Oancea
mesh_terms: D000388:Air; D005107:Explosions; D007700:Kinetics; D011312:Pressure; D011407:Propane; D013696:Temperature; D013816:Thermodynamics
chemical_list: D011407:Propane