title: Dicarbonyl-chlorido(phen-oxy-thio-carbonyl-κC,S)bis-(triphenyl-phosphane-κP)molybdenum(II).
abstract: In the title complex, [Mo(C(7)H(5)OS)Cl(C(18)H(15)P)(2)(CO)(2)], the geometry around the metal atom is a capped octa-hedron. The phen-oxy-thio-carbonyl ligand coordinates the Mo(II) atom through the C and S atoms. A one-dimensional structure is formed by π-π inter-molecular inter-actions and a supra-molecular aggregation is determined by inter-molecular C-H⋯O, C-H⋯Cl, C-H⋯π(arene) hydrogen bonds and CO⋯π(arene) inter-actions [O⋯centroid distances = 3.485 (4) and 3.722 (3) Å].
authors.forename: Gene-Hsiang
authors.initials: GH
authors.lastname: Lee
authors.forename: Hsiao-Fen
authors.initials: HF
authors.lastname: Wang
authors.forename: Kuang-Hway
authors.initials: KH
authors.lastname: Yih
authors.forename: Shou-Ling
authors.initials: SL
authors.lastname: Huang