title: 2-(2,2-Dibromo-ethen-yl)thio-phene.
abstract: The title compound, C(6)H(4)Br(2)S, represents a versatile building block for the preparation of π-conjugated redox-active thienyl oligomers and metal-mediated cross-coupling reactions. This is due to the presence of an electrochemically active thienyl heterocycle and a reactive dibromo-vinyl substituent, which easily undergoes dehydro-bromination in the presence of n-butyl-lithium to afford 2-ethynyl-thio-phene. In the molecule, the alkenyl unit and the thio-phene ring are almost coplanar with an angle of 3.5 (2)° between the normals of the best planes of the thio-phene ring and the vinyl moiety.
authors.forename: Sebastien
authors.initials: S
authors.lastname: Clément
authors.forename: Laurent
authors.initials: L
authors.lastname: Guyard
authors.forename: Michael
authors.initials: M
authors.lastname: Knorr
authors.forename: Prisca K
authors.initials: PK
authors.lastname: Eckert
authors.forename: Carsten
authors.initials: C
authors.lastname: Strohmann