title: One-pot metal-free syntheses of acetophenones from styrenes through aerobic photo-oxidation and deiodination with iodine.
abstract: A one-pot synthetic protocol of acetophenones from styrenes with molecular oxygen, visible light, and molecular iodine is reported. This procedure involves aerobic photo-oxidation and deiodination in one pot and provides the first report of metal-free direct syntheses of acetophenones from styrenes.
authors.affiliation: Gifu Pharmaceutical University, Gifu, Japan.
authors.forename: Tomoya
authors.initials: T
authors.lastname: Nobuta
authors.forename: Shin-ichi
authors.initials: S
authors.lastname: Hirashima
authors.forename: Norihiro
authors.initials: N
authors.lastname: Tada
authors.forename: Tsuyoshi
authors.initials: T
authors.lastname: Miura
authors.forename: Akichika
authors.initials: A
authors.lastname: Itoh
mesh_terms: D000098:Acetophenones / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D002625:Chemistry, Organic / Q000379:methods; D020650:Combinatorial Chemistry Techniques; D007455:Iodine / Q000737:chemistry*; D010084:Oxidation-Reduction; D055668:Photochemical Processes; D013343:Styrenes / Q000737:chemistry*
chemical_list: D000098:Acetophenones; D013343:Styrenes; D007455:Iodine