title: Chloridobis(1,10-phenanthroline-κN,N')copper(I) dichloridocopper(II).
abstract: The asymmetric unit of the title compound, [CuCl(C(12)H(8)N(2))(2)]·[CuCl(2)], contains two complex Cu(II) cations and two cuprate(I) anions. The Cu(II) atom is coordinated by two phenanthroline (phen) mol-ecules and one chloride anion in a distorted trigonal-bipyramidal geometry. The Cu(II) complex cations form layers through π-π stacking [interplanar distance = 3.481 (2) Å]. The dichloridocuprate(I) anions are located between the layers, forming a sandwich-like structure.
authors.forename: Qingfen
authors.initials: Q
authors.lastname: Meng
authors.forename: Yanmei
authors.initials: Y
authors.lastname: Chen
authors.forename: Bing
authors.initials: B
authors.lastname: Li
authors.forename: Sanping
authors.initials: S
authors.lastname: Chen
authors.forename: Shengli
authors.initials: S
authors.lastname: Gao