title: Dynamics of colloids in confined geometries.
abstract: We discuss the Brownian dynamics of colloids in confinement with special emphasis on the influence of the solvent dynamics. We review the derivation of a dynamic density functional theory (DDFT) including some aspects of hydrodynamic interactions and its application to the micro-rheology of suspensions. In particular we discuss the failure of Stokes' law in suspensions and non-equilibrium solvent structure mediated interactions. With regard to hydrodynamic chromatography we also discuss the stationary transport of particles in narrow channels, and the reasons for the failure of DDFT in this situation.
authors.affiliation: Max-Planck-Institut für Metallforschung, Stuttgart, Germany.
authors.forename: L
authors.initials: L
authors.lastname: Almenar
authors.forename: M
authors.initials: M
authors.lastname: Rauscher
mesh_terms: D000465:Algorithms; D001703:Biophysics / Q000379:methods; D002845:Chromatography / Q000379:methods; D003102:Colloids / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D015233:Models, Statistical; D008962:Models, Theoretical; D011108:Polymers / Q000737:chemistry; D011336:Probability; D012212:Rheology / Q000379:methods*; D012997:Solvents
chemical_list: D003102:Colloids; D011108:Polymers; D012997:Solvents