title: (4-Cyano-phenolato)(subphthalocyaninato)boron.
abstract: The crystal structure of the title compound, C(31)H(16)BN(7)O, (CNPhO-BsubPc) is characterized by pairs of π-π stacking inter-actions between the concave faces of inversion-related BsubPc fragments with a centroid-centroid distance of 3.600 (1) Å. In addition, these pairs of mol-ecules are linked into chains along [101] through further weak π-π stacking inter-actions with a centroid-centroid distance of 3.8587 (9) Å. There are also weak C-H⋯π(arene) inter-actions within the chains.
authors.forename: Andrew S
authors.initials: AS
authors.lastname: Paton
authors.forename: Alan J
authors.initials: AJ
authors.lastname: Lough
authors.forename: Timothy P
authors.initials: TP
authors.lastname: Bender