title: 2-Amino-6-methyl-4,5,6,7-tetra-hydro-1-benzothio-phene-3-carbonitrile.
abstract: In the title compound, C(10)H(12)N(2)S, one of the C atoms of the cyclo-hexene ring (at position 6) and the methyl group attached to it are disordered over two sets of sites in a 0.650 (3):0.350 (3) ratio. The cyclo-hexene ring in both the major and minor occupancy conformers adopts a half-chair conformation. The thio-phene ring is essentially planar (r.m.s. deviation = 0.05 Å). In the crystal, N-H⋯N hydrogen bonds involving the amino groups result in inversion dimers with R(2) (2)(12) graph-set motif. Further N-H⋯N hydrogen bonds involving the amino and carbonitrile groups generate zigzag chains along the a axis.
authors.forename: Mohamed
authors.initials: M
authors.lastname: Ziaulla
authors.forename: Afshan
authors.initials: A
authors.lastname: Banu
authors.forename: Noor Shahina
authors.initials: NS
authors.lastname: Begum
authors.forename: Shridhar I
authors.initials: SI
authors.lastname: Panchamukhi
authors.forename: I M
authors.initials: IM
authors.lastname: Khazi