title: Calcium carbonate phase transformations during the carbonation reaction of calcium heavy alkylbenzene sulfonate overbased nanodetergents preparation.
abstract: The preparation and application of overbased nanodetergents with excess alkaline calcium carbonate is a good example of nanotechnology in practice. The phase transformation of calcium carbonate is of extensive concern since CaCO(3) serves both as an important industrial filling material and as the most abundant biomineral in nature. Industrially valuable overbased nanodetergents have been prepared based on calcium salts of heavy alkylbenzene sulfonate by a one-step process under ambient pressure, the carbonation reaction has been monitored by the instantaneous temperature changes and total base number (TBN). A number of analytical techniques such as TGA, DLS, SLS, TEM, FTIR, and XRD have been utilized to explore the carbonation reaction process and phase transformation mechanism of calcium carbonate. An enhanced understanding on the phase transformation of calcium carbonate involved in calcium sulfonate nanodetergents has been achieved and it has been unambiguously demonstrated that amorphous calcium carbonate (ACC) transforms into the vaterite polymorph rather than calcite, which would be of crucial importance for the preparation and quality control of lubricant additives and greases. Our results also show that a certain amount of residual Ca(OH)(2) prevents the phase transformation from ACC to crystalline polymorphs. Moreover, a vaterite nanodetergent has been prepared for the first time with low viscosity, high base number, and uniform particle size, nevertheless a notable improvement on its thermal stability is required for potential applications.
authors.affiliation: Key Laboratory of Mesoscopic Chemistry of Ministry of Education and Department of Polymer Science and Engineering, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, PR China.
authors.forename: Zhaocong
authors.initials: Z
authors.lastname: Chen
authors.forename: Shan
authors.initials: S
authors.lastname: Xiao
authors.forename: Feng
authors.initials: F
authors.lastname: Chen
authors.forename: Dongzhong
authors.initials: D
authors.lastname: Chen
authors.forename: Jianglin
authors.initials: J
authors.lastname: Fang
authors.forename: Min
authors.initials: M
authors.lastname: Zhao
mesh_terms: D017738:Alkanesulfonic Acids / Q000737:chemistry*; D002118:Calcium / Q000737:chemistry*; D002119:Calcium Carbonate / Q000737:chemistry*; D003902:Detergents / Q000138:chemical synthesis* / Q000737:chemistry; D049329:Nanostructures / Q000737:chemistry*; D010316:Particle Size; D044367:Phase Transition; D013499:Surface Properties
chemical_list: D017738:Alkanesulfonic Acids; D003902:Detergents; C030641:alkylbenzyl sulfonic acid; D002119:Calcium Carbonate; D002118:Calcium