title: Theoretical investigation of rotationally inelastic collisions of CH2(ã) with helium.
abstract: Rotationally inelastic collisions of the CH(2) molecule in its ã(1)A(1) electronic state have been investigated. We have determined a potential energy surface (PES) for the interaction of rigid CH(2)(ã), frozen at its equilibrium geometry, with a helium atom, using a coupled-cluster method that includes all single and double excitations, as well as perturbative contributions of connected triple excitations [RSSCD(T)]. The PES is quite anisotropic, due to lack of electron density in the unoccupied CH(2) non-bonding orbital perpendicular to the molecular plane. Quantum scattering calculations have been carried out to compute state-to-state rotational energy transfer and elastic depolarization cross sections at collision energies up to 2400 cm(-1). These cross sections were thermally averaged to derive room-temperature rate constants. The total removal and elastic depolarization rate constants for the ortho k(a) = 1 levels agree well with recent experimental measurements by Hall, Sears, and their co-workers. We observe a strong even-odd alternation in the magnitude of the total rate constants which we attribute to the asymmetry splitting of the k(a) = 1 levels.
authors.affiliation: Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742-2021, USA.
authors.forename: Lifang
authors.initials: L
authors.lastname: Ma
authors.forename: Millard H
authors.initials: MH
authors.lastname: Alexander
authors.forename: Paul J
authors.initials: PJ
authors.lastname: Dagdigian