title: BINEPINES: chiral binaphthalene-core monophosphepine ligands for multipurpose asymmetric catalysis.
abstract: The atropisomeric structure of 4,5-dihydro-3H-dinaphtho[2,1-c;1',2'-e]phosphepine is the common axially chiral scaffold of a library of monophosphine ligands nicknamed BINEPINES that have shown a quite remarkable stereoselection efficiency in a broad variety of enantioselective reactions involving the formation of new C-H or C-C or C-X bonds. In this critical review the properties and scope of this type of chiral ligands are illustrated (70 references).
authors.affiliation: Dipartimento di Chimica, Università di Sassari, via Vienna 2, 07100 Sassari, Italy. gladiali@uniss.it
authors.forename: Serafino
authors.initials: S
authors.lastname: Gladiali
authors.forename: Elisabetta
authors.initials: E
authors.lastname: Alberico
authors.forename: Kathrin
authors.initials: K
authors.lastname: Junge
authors.forename: Matthias
authors.initials: M
authors.lastname: Beller
mesh_terms: D002384:Catalysis; D008024:Ligands; D009281:Naphthalenes / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D008024:Ligands; D009281:Naphthalenes; D010720:Phosphines; C031721:naphthalene; C044646:phosphine