title: Mechanistic analysis of trans C-N reductive elimination from a square-planar macrocyclic aryl-copper(III) complex.
abstract: A net trans C-N reductive elimination reaction is observed from a macrocyclic aryl-Cu(III) complex, and a mechanistic study of this reaction indicates that coordinating ligands play a role in mediating this unusual transformation.
authors.affiliation: University of Wisconsin-Madison, Department of Chemistry, 1101 University Avenue, Madison, WI, USA.
authors.forename: Lauren M
authors.initials: LM
authors.lastname: Huffman
authors.forename: Shannon S
authors.initials: SS
authors.lastname: Stahl
mesh_terms: D003300:Copper / Q000737:chemistry*; D008024:Ligands; D047028:Macrocyclic Compounds / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction
chemical_list: D008024:Ligands; D047028:Macrocyclic Compounds; D009942:Organometallic Compounds; D003300:Copper; D009584:Nitrogen