title: Highly integrated flow assembly for automated dynamic extraction and determination of readily bioaccessible chromium(VI) in soils exploiting carbon nanoparticle-based solid-phase extraction.
abstract: An automated dynamic leaching test integrated in a portable flow-based setup is herein proposed for reliable determination of readily bioaccessible Cr(VI) under worst-case scenarios in soils containing varying levels of contamination. The manifold is devised to accommodate bi-directional flow extraction followed by processing of extracts via either in-line clean-up/preconcentration using multi-walled carbon nanotubes or automatic dilution at will, along with Cr(VI) derivatization and flow-through spectrophotometric detection. The magnitude of readily mobilizable Cr(VI) pools was ascertained by resorting to water extraction as promulgated by current standard leaching tests. The role of carbon nanomaterials for the uptake of Cr(VI) in soil leachates and the configuration of the packed column integrated in the flow manifold were investigated in detail. The analytical performance of the proposed system for in vitro bioaccessibility tests was evaluated in chromium-enriched soils at environmentally relevant levels and in a standard reference soil material (SRM 2701) with a certified value of total hexavalent chromium. The automated method was proven to afford unbiased assessment of water-soluble Cr(VI) in soils as a result of the minimization of the chromium species transformation. By combination of the kinetic leaching profile and a first-order leaching model, the water-soluble Cr(VI) fraction in soils was determined in merely 6 h against >24 h taken in batchwise steady-state standard methods.
authors.affiliation: Department of Chemistry, University of the Balearic Islands, Carreteta de Valldemossa km 7.5, 07122, Palma de Mallorca, Spain.
authors.forename: María
authors.initials: M
authors.lastname: Rosende
authors.forename: Manuel
authors.initials: M
authors.lastname: Miró
authors.forename: Marcela A
authors.initials: MA
authors.lastname: Segundo
authors.forename: José L F C
authors.initials: JL
authors.lastname: Lima
authors.forename: Víctor
authors.initials: V
authors.lastname: Cerdà
mesh_terms: D002244:Carbon / Q000737:chemistry*; D002857:Chromium / Q000737:chemistry*; D053758:Nanoparticles; D012989:Soil Pollutants / Q000032:analysis*
chemical_list: D012989:Soil Pollutants; D002857:Chromium; D002244:Carbon