title: Intensification of degradation of aqueous solutions of rhodamine B using sonochemical reactors at operating capacity of 7 L.
abstract: In the present work, degradation of rhodamine B, a typical dye effluent commonly observed in chemical processing wastewaters has been investigated using a sonochemical reactor with capacity of 7 L. The reactor consists of an ultrasonic bath equipped with a single large transducer having longitudinal vibrations with operating frequency of 25 kHz and rated power output of 1 kW. The effect of operational conditions such as the rhodamine B initial concentration, operating pH and use of additives such as H(2)O(2), CCl(4) and TiO(2) has been investigated initially. A mathematical model has also been fitted to estimate the rate constant for rhodamine B removal under different operating conditions. Intensification studies have been carried by combining sonochemical oxidation with photocatalytic oxidation under optimized conditions. In all the investigated systems, complete removal of rhodamine B (10 ppm initial concentration) was obtained using a combination of sonochemical reactor and CCl(4). Sonocatalysis (in the presence of TiO(2)) of rhodamine B showed 92% degradation, while sonophotocatalysis gave degradation of 93%. TOC analysis at various optimum conditions was also performed to quantify the extent of mineralization and it was observed that the extent of mineralization is always lower than the extent of removal of parent compound.
authors.affiliation: Chemical Engineering Department, Institute of Chemical Technology, Matunga, Mumbai-400019, India.
authors.forename: Kashyap P
authors.initials: KP
authors.lastname: Mishra
authors.forename: Parag R
authors.initials: PR
authors.lastname: Gogate
mesh_terms: D002251:Carbon Tetrachloride; D006861:Hydrogen Peroxide; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D008956:Models, Chemical; D012235:Rhodamines / Q000737:chemistry*; D013010:Sonication / Q000295:instrumentation* / Q000379:methods*; D014025:Titanium; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D018508:Water Purification / Q000379:methods*
chemical_list: D012235:Rhodamines; D014874:Water Pollutants, Chemical; C009495:titanium dioxide; D006861:Hydrogen Peroxide; D002251:Carbon Tetrachloride; D014025:Titanium; C029773:rhodamine B