title: Recovery of polypropylene and polyethylene from packaging plastic wastes without contamination of chlorinated plastic films by the combination process of wet gravity separation and ozonation.
abstract: Wet gravity separation technique has been regularly practiced to separate the polypropylene (PP) and polyethylene (PE) (light plastic films) from chlorinated plastic films (CP films) (heavy plastic films). The CP films including poly vinyl chloride (PVC) and poly vinylidene chloride (PVDC) would float in water even though its density is more than 1.0g/cm(3). This is because films are twisted in which air is sometimes entrapped inside the twisted CP films in real existing recycling plant. The present research improves the current process in separating the PP and PE from plastic packaging waste (PPW), by reducing entrapped air and by increasing the hydrophilicity of the CP films surface with ozonation. The present research also measures the hydrophilicity of the CP films. In ozonation process mixing of artificial films up to 10min reduces the contact angle from 78° to 62°, and also increases the hydrophilicity of CP films. The previous studies also performed show that the artificial PVDC films easily settle down by the same. The effect of ozonation after the wet gravity separation on light PPW films obtained from an actual PPW recycling plant was also evaluated. Although actual light PPW films contained 1.3% of CP films however in present case all the CP films were removed from the PPW films as a settled fraction in the combination process of ozonation and wet gravity separation. The combination process of ozonation and wet gravity separation is the more beneficial process in recovering of high purity PP and PE films from the PPW films.
authors.affiliation: Environmental Research and Management Center, Hiroshima University, 1-5-3 Kagamiyama, Higashi-Hiroshima, Hiroshima 739-8513, Japan.
authors.forename: Mallampati Srinivasa
authors.initials: MS
authors.lastname: Reddy
authors.forename: Tetsuji
authors.initials: T
authors.lastname: Okuda
authors.forename: Satoshi
authors.initials: S
authors.lastname: Nakai
authors.forename: Wataru
authors.initials: W
authors.lastname: Nishijima
authors.forename: Mitsumasa
authors.initials: M
authors.lastname: Okada
mesh_terms: D005591:Chemical Fractionation / Q000379:methods*; D006843:Hydrocarbons, Chlorinated; D057927:Hydrophobic and Hydrophilic Interactions; D010126:Ozone; D010969:Plastics / Q000737:chemistry*; D020959:Polyethylene; D011126:Polypropylenes; D019064:Product Packaging; D059027:Recycling / Q000379:methods*; D013046:Specific Gravity; D018505:Waste Management / Q000379:methods
chemical_list: D006843:Hydrocarbons, Chlorinated; D010969:Plastics; D011126:Polypropylenes; D010126:Ozone; D020959:Polyethylene