title: Cold Pad-Batch dyeing method for cotton fabric dyeing with reactive dyes using ultrasonic energy.
abstract: Reactive dyes are vastly used in dyeing and printing of cotton fibre. These dyes have a distinctive reactive nature due to active groups which form covalent bonds with -OH groups of cotton through substitution and/or addition mechanism. Among many methods used for dyeing cotton with reactive dyes, the Cold Pad Batch (CPB) method is relatively more environment friendly due to high dye fixation and non requirement of thermal energy. The dyed fabric production rate is low due to requirement of at least twelve hours batching time for dye fixation. The proposed CPB method for dyeing cotton involves ultrasonic energy resulting into a one third decrease in batching time. The dyeing of cotton fibre was carried out with CI reactive red 195 and CI reactive black 5 by conventional and ultrasonic (US) method. The study showed that the use of ultrasonic energy not only shortens the batching time but the alkalis concentrations can considerably be reduced. In this case, the colour strength (K/S) and dye fixation (%F) also enhances without any adverse effect on colour fastness of the dyed fabric. The appearance of dyed fibre surface using scanning electron microscope (SEM) showed relative straightening of fibre convolutions and significant swelling of the fibre upon ultrasonic application. The total colour difference values ΔE (CMC) for the proposed method, were found within close proximity to the conventionally dyed sample.
authors.affiliation: Department of Textile Engineering, Mehran University of Engineering and Technology, Jamshoro, Pakistan. zeeshan.khatri@faculty.muet.edu.pk
authors.forename: Zeeshan
authors.initials: Z
authors.lastname: Khatri
authors.forename: Muhammad Hanif
authors.initials: MH
authors.lastname: Memon
authors.forename: Awais
authors.initials: A
authors.lastname: Khatri
authors.forename: Anwaruddin
authors.initials: A
authors.lastname: Tanwari
mesh_terms: D004396:Coloring Agents / Q000737:chemistry*; D032561:Cotton Fiber; D014465:Ultrasonics / Q000379:methods*
chemical_list: D004396:Coloring Agents