title: Bridging, terminal, free, anti and gauche BPA ligands in a 1D hybrid organic-inorganic Mn(II)-cyanate system.
abstract: A hybrid organic-inorganic chain compound of the family Mn(II)-bpa-(NCO) is presented. It contains, unusually, five different dispositions for the bpa [1,2-bis(4-pyridyl)ethane] ligand. Water molecules and free bpa ligands occupy the voids of the structure. The compound shows significant antiferromagnetic-type interactions as a consequence of different exchange pathways.
authors.affiliation: Departamento de Química Inorgánica, Fac. Ciencia y Tecnología, UPV/EHU, Aptdo. 644, 48080, Bilbao, Spain.
authors.forename: Noelia
authors.initials: N
authors.lastname: De la Pinta
authors.forename: Luz
authors.initials: L
authors.lastname: Fidalgo
authors.forename: Gotzon
authors.initials: G
authors.lastname: Madariaga
authors.forename: Franz A
authors.initials: FA
authors.lastname: Mautner
authors.forename: Luis
authors.initials: L
authors.lastname: Lezama
authors.forename: Roberto
authors.initials: R
authors.lastname: Cortés
mesh_terms: D015082:2,2'-Dipyridyl / Q000737:chemistry*; D004578:Electron Spin Resonance Spectroscopy; D008024:Ligands; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D009570:Nitriles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism; D013696:Temperature
chemical_list: D008024:Ligands; D009570:Nitriles; D009942:Organometallic Compounds; D008345:Manganese; D015082:2,2'-Dipyridyl