title: Organic-inorganic hybrid materials starting from the novel nanoscaled bismuth oxido methacrylate cluster [Bi38O45(OMc)24(DMSO)9]·2DMSO·7H2O.
abstract: The reaction of the basic bismuth nitrate [Bi(6)O(4)(OH)(4)](NO(3))(6)·H(2)O with sodium methacrylate in DMSO gave [Bi(38)O(45)(OMc)(24)(DMSO)(9)]·2DMSO·7H(2)O (OMc = O(2)CC(3)H(5)), which is highly soluble in organic solvents. By copolymerization of the bismuth oxido cluster with methyl methacrylate transparent, radiopaque organic-inorganic hybrid materials were obtained.
authors.affiliation: Professur für Koordinationschemie, Technische Universität Chemnitz, Strasse der Nationen 62, 09111, Chemnitz, Germany.
authors.forename: Linda
authors.initials: L
authors.lastname: Miersch
authors.forename: Tobias
authors.initials: T
authors.lastname: Rüffer
authors.forename: Michael
authors.initials: M
authors.lastname: Mehring
mesh_terms: D001729:Bismuth / Q000737:chemistry*; D056831:Coordination Complexes / Q000737:chemistry*; D004121:Dimethyl Sulfoxide / Q000737:chemistry*; D008027:Light; D018625:Microscopy, Atomic Force; D049329:Nanostructures / Q000737:chemistry*; D019904:Polymethyl Methacrylate / Q000737:chemistry*; D012542:Scattering, Radiation
chemical_list: D056831:Coordination Complexes; D019904:Polymethyl Methacrylate; C033301:bismuth oxide; D001729:Bismuth; D004121:Dimethyl Sulfoxide