title: Study of antisite defects in hydrothermally prepared LiFePO₄ by in situ X-ray diffraction.
abstract: Hydrothermal synthesis has proven to be a cost-effective, energy-efficient approach for the manufacture of lithium iron phosphate (LiFePO₄) and its related materials. However, hydrothermally prepared LiFePO₄ typically suffers from antisite defects, where some of the iron resides on lithium sites and restricts lithium-ion mobility. A post-heat-treatment temperature of around 700 °C is generally used to eliminate cation disorder, but little is known about these antisite defects or their concentration as a function of the post-heat-treatment temperature. In this study, time-resolved, synchrotron X-ray diffraction reveals that antisite defects are completely eliminated above 500 °C, suggesting that the electrochemical performance may be significantly enhanced by a milder postsynthesis heat treatment. The preliminary electrochemical results show a significant enhancement in the electrochemical capacity with the defect-free material, with the specific capacity increasing by approximately 60% at a C/20 rate.
authors.forename: Jiajun
authors.initials: J
authors.lastname: Chen
authors.forename: Jason
authors.initials: J
authors.lastname: Graetz