title: Unprecedented copper(I)-catalyzed in situ double cycloaddition reaction based on 2-cyanopyrimidine.
abstract: The solvothermal in situ double cycloaddition reaction of 2-cyanopyrimidine, Cu(2)O and NaN(3) with aqueous ammonia additive generated a two dimensional copper(I) coordination polymer with 5-pyrimidyl-tetrazolate, 3,5-bispyrimidyl-1,2,4-triazolate and the cyano group as the ligands. This reaction can be tuned to yield two dimensional coordination polymers solely based on tetrazolate or 1,2,4-triazolate ligands.
authors.affiliation: Department of Chemistry, Shantou University, Guangdong 515063, PR China.
authors.forename: Tian
authors.initials: T
authors.lastname: Wen
authors.forename: Mian
authors.initials: M
authors.lastname: Li
authors.forename: Xiao-Ping
authors.initials: XP
authors.lastname: Zhou
authors.forename: Dan
authors.initials: D
authors.lastname: Li