title: 14C tebuconazole degradation in Colombian soils.
abstract: Tebuconazole is a fungicide used on onion crops (Allium Fistulosum L) in Colombia. Persistence of pesticides in soils is characterized by the half-life (DT50), which is influenced by their chemical structure, the physical and chemical properties of the soil and the previous soil history. Based on its structural and chemical properties, tebuconazole should be expected to be relatively persistent in soils. Laboratory incubation studies were conducted to evaluate persistence and bond residues of 14C tebuconazole in three soils, two inceptisol (I) and one histosol (H). Textural classifications were: loam (101), loamy sand (102) and loam (H03), respectively. Data obtained followed a first-order degradation kinetics (R2 > or = 0.899) with DT50 values between 158 and 198 days. The production of 14CO2 from the 14C-ring-labelled test chemicals was very low and increased slightly during 63 days in all cases. The methanol extractable 14C-residues were higher than aqueous ones and both decreased over incubation time for the three soils. The formation of bound 14C-residues increased with time and final values were 11.3; 5.55 and 7.87% for 101, 102 and H03 respectively. Soil 101 showed the lowest mineralization rate and the highest bound residues formation, which might be explained by the clay fraction content. In contrast, an inverse behavior was found for soils 102 and H03, these results might be explained by the higher soil organic carbon content.
authors.affiliation: Universidad Nacional de Colombia, Facultad de Ciencias. Dpto Química, Colombia. csmosquerav@unal.edu.co
authors.forename: C S
authors.initials: CS
authors.lastname: Mosquera
authors.forename: M J
authors.initials: MJ
authors.lastname: Martínez
authors.forename: J A
authors.initials: JA
authors.lastname: Guerrero
mesh_terms: D002247:Carbon Isotopes / Q000032:analysis; D003105:Colombia; D005659:Fungicides, Industrial / Q000032:analysis / Q000378:metabolism*; D006207:Half-Life; D012987:Soil / Q000737:chemistry*; D012989:Soil Pollutants / Q000032:analysis / Q000378:metabolism; D014230:Triazoles / Q000032:analysis* / Q000378:metabolism*
chemical_list: D002247:Carbon Isotopes; D005659:Fungicides, Industrial; D012987:Soil; D012989:Soil Pollutants; D014230:Triazoles; C087114:tebuconazole