title: Nuclearity control of a trisaloph zinc cluster complex dependent on minute structural differences in the bridging anions.
abstract: The Zn(6) cluster complex 2 of the trisaloph ligand was synthesized using EtCO(2)(-) anions as bridging ligands. Complex 2 has a dimeric structure in the crystalline state, while two monomeric isomers were in equilibrium in solution. The anion-exchange reaction successfully resulted in nuclearity control from Zn(7) to Zn(6).
authors.affiliation: Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan.
authors.forename: Masaki
authors.initials: M
authors.lastname: Yamamura
authors.forename: Hayato
authors.initials: H
authors.lastname: Miyazaki
authors.forename: Masaya
authors.initials: M
authors.lastname: Iida
authors.forename: Shigehisa
authors.initials: S
authors.lastname: Akine
authors.forename: Tatsuya
authors.initials: T
authors.lastname: Nabeshima