title: (Acetone-2κO){μ-6,6'-dimeth-oxy-2,2'-[propane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κ1:2O,O,O,O:O,N,N',O}tris-(nitrato-1κO,O')copper(II)samarium(III).
abstract: In the title heteronuclear complex, [CuSm(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)COCH(3))], the Cu(II) ion is five-coordinated by two O and two N atoms from the 6,6'-dimeth-oxy-2,2'-[propane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolate ligand (L) and by an O atom from the acetone mol-ecule in a square-pyramidal geometry. The Sm(III) ion is ten-coordinated by six O atoms from the three nitrate ligands and four O atoms from the L ligand. In L, the C atoms of the diamino-propane fragment are disordered over two positions in a 0.674 (10):0.326 (10) ratio.
authors.affiliation: Key Laboratory of Functional Inorganic Material Chemistry (HLJU), Ministry of Education, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.
authors.forename: Wen-Bin
authors.initials: WB
authors.lastname: Sun
authors.forename: Peng-Fei
authors.initials: PF
authors.lastname: Yan
authors.forename: Hong-Feng
authors.initials: HF
authors.lastname: Li
authors.forename: Ting
authors.initials: T
authors.lastname: Gao
authors.forename: Guang-Ming
authors.initials: GM
authors.lastname: Li