title: Spin-crossover in [Fe(3-bpp)2][BF4]2 in different solvents--a dramatic stabilisation of the low-spin state in water.
abstract: The temperature of spin-crossover in [Fe(3-bpp)(2)][BF(4)](2) (3-bpp = 2,6-di{pyrazol-3-yl}pyridine) tends to increase in associating solvents. In particular, T(½) shifts to 60-70 K higher temperature in water compared to organic solvents.
authors.affiliation: School of Chemistry, University of Leeds, Woodhouse Lane, Leeds, UK LS2 9JT.
authors.forename: Simon A
authors.initials: SA
authors.lastname: Barrett
authors.forename: Colin A
authors.initials: CA
authors.lastname: Kilner
authors.forename: Malcolm A
authors.initials: MA
authors.lastname: Halcrow