title: Ethyl 2-{4-[(1,5-dibenzyl-2,4-dioxo-2,3,4,5-tetra-hydro-1H-1,5-benzo-diazepin-3-yl)meth-yl]-1H-1,2,3-triazol-1-yl}acetate.
abstract: The reaction of 1,5-dibenzyl-3-propargyl-1,5-benzodiazepine-2,4-dione with ethyl azido-acetate in the presence of copper sulfate pentahydrate and sodium ascorbate leads to the formation of the title regioisomer, C(30)H(29)N(5)O(4), which features a phenyl-ene ring fused with a seven-membered diazepinyl ring. The latter ring adopts a boat conformation (with the methyl-triazolylacetate-bearing C atom as the prow and the fused-ring C atoms as the stern). The benzyl groups connected to the diazepinyl ring jprotrude from the sides; the methyl-triazolylacetate substituent occupies an axial position.
authors.forename: Hind
authors.initials: H
authors.lastname: Jabli
authors.forename: Y
authors.initials: Y
authors.lastname: Kandri Rodi
authors.forename: Sonia
authors.initials: S
authors.lastname: Ladeira
authors.forename: El Mokhtar
authors.initials: el M
authors.lastname: Essassi
authors.forename: Seik Weng
authors.initials: SW
authors.lastname: Ng