title: Diethyl-enetriaminium hexa-fluorido-titanate(IV) fluoride.
abstract: The title compound, (C(6)H(21)N(4))[TiF(6)]F, was synthesized by the reaction of TiO(2), tris-(2-amino-ethyl)amine, HF and ethanol at 463 K in a microwave oven. The crystal structure consists of two crystallographically independent [TiF(6)](2-) anions, two fluoride anions and two triply-protonated tris-(2-amino-ethyl)-amine cations. The Ti atoms are coordinated by six F atoms within slightly distorted octa-hedra. The anions and cations are connected by inter-molecular N-H⋯F hydrogen bonds.
authors.affiliation: Laboratoire des Oxydes et Fluorures, UMR 6010 CNRS, Faculté des Sciences et Techniques, Université du Maine, Avenue Olivier Messiaen, 72085 Le Mans Cedex 9, France.
authors.forename: J
authors.initials: J
authors.lastname: Lhoste
authors.forename: K
authors.initials: K
authors.lastname: Adil
authors.forename: M
authors.initials: M
authors.lastname: Leblanc
authors.forename: V
authors.initials: V
authors.lastname: Maisonneuve