title: 2-Chloro-5-(2-iodo-benzene-sulfonamido)-benzoic acid.
abstract: In the mol-ecule of the title compound, C(13)H(9)ClINO(4)S, the coordination around the S atom is distorted tetra-hedral. The aromatic rings are oriented at a dihedral angle of 74.46 (9)°. Intra-molecular C-H⋯O hydrogen bonds result in the formation of two five- and one six-membered rings, which adopt planar, envelope and twisted conformations, respectively. In the crystal structure, inter-molecular N-H⋯O and O-H⋯O hydrogen bonds link the mol-ecules to form R(2) (2)(8) ring motifs, which are further linked by C-H⋯O hydrogen bonds. π-π contacts between the benzene rings [centroid-centroid distances = 3.709 (3) and 3.772 (3) Å] may further stabilize the structure. The I atom is disordered over two positions, refined with occupancies of ca 0.75 and 0.25.
authors.forename: Muhammad Nadeem
authors.initials: MN
authors.lastname: Arshad
authors.forename: M Nawaz
authors.initials: MN
authors.lastname: Tahir
authors.forename: Islam Ullah
authors.initials: IU
authors.lastname: Khan
authors.forename: Waseeq Ahmad
authors.initials: WA
authors.lastname: Siddiqui
authors.forename: Muhammad
authors.initials: M
authors.lastname: Shafiq