title: Silver nanoparticle-initiated chemiluminescence reaction of luminol-AgNO3 and its analytical application.
abstract: Ag(+) has been regarded as an inert chemiluminescent oxidant. In this work, it was found that in the presence of silver nanoparticles (AgNPs), AgNO(3) could react with luminol to produce strong chemiluminescence (CL). The AgNPs with smaller size could initiate stronger CL emission. To investigate the CL mechanism of the AgNPs-luminol-AgNO(3) system, the UV-visible spectra and the CL spectrum of the CL system were obtained. The CL reaction mechanism involving catalysis was proposed. Compared with the reported nanoparticles-luminol-H(2)O(2) CL system, the AgNPs-luminol-AgNO(3) CL system has the advantages of low background and good stability. Moreover, the new CL system was used in immunoassay for IgG.
authors.affiliation: Key Laboratory of Analytical Chemistry for Life Science of Shaanxi Province, School of Chemistry and Materials Science, Shaanxi Normal University, Xi'an, China.
authors.forename: Cui
authors.initials: C
authors.lastname: Liu
authors.forename: Baoxin
authors.initials: B
authors.lastname: Li
mesh_terms: D006801:Humans; D007118:Immunoassay / Q000379:methods; D007074:Immunoglobulin G / Q000032:analysis*; D049408:Luminescent Agents / Q000737:chemistry; D008163:Luminescent Measurements / Q000379:methods*; D008165:Luminol / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry*; D012680:Sensitivity and Specificity; D012834:Silver / Q000737:chemistry*; D012835:Silver Nitrate / Q000737:chemistry*
chemical_list: D007074:Immunoglobulin G; D049408:Luminescent Agents; D012834:Silver; D008165:Luminol; D012835:Silver Nitrate