title: 5-(3-Nitro-benz-yl)-1,3,4-thia-diazol-2-amine.
abstract: In the title mol-ecule, C(9)H(8)N(4)O(2)S, the dihedral angle between the thia-diazole and benzene rings is 73.92 (8)° and the thia-diazole group S atom is orientated towards the benzene ring, the central S-C-C-C torsion angle being 45.44 (18)°. In the crystal, supra-molecular tapes mediated by N-H⋯N hydrogen bonds and comprising alternating eight-membered {⋯HNCN}(2) and 10-membered {⋯HNH⋯NN}(2) synthons are formed along [010]. The tapes are consolidated into a three-dimensional network by a combination of C-H⋯O, C-H⋯S and C-H⋯π inter-actions.
authors.forename: Samir A
authors.initials: SA
authors.lastname: Carvalho
authors.forename: Larisse O
authors.initials: LO
authors.lastname: de Feitosa
authors.forename: Edson F
authors.initials: EF
authors.lastname: da Silva
authors.forename: Edward R T
authors.initials: ER
authors.lastname: Tiekink
authors.forename: James L
authors.initials: JL
authors.lastname: Wardell
authors.forename: Solange M S V
authors.initials: SM
authors.lastname: Wardell