title: (η-Cyclo-penta-dien-yl)bis-(triphenyl-phosphane)cobalt(I)-toluene-n-hexane (1/0.20/0.25).
abstract: The title compound, [Co(C(5)H(5))(C(18)H(15)P)(2)]·0.2C(7)H(8)·0.25C(6)H(14), was synthesized by the reaction of cobaltocene, Cp(2)Co, with elemental lithium in tetra-hydro-furan in the presence of two equivalents of PPh(3). The mol-ecular structure displays a cobalt(I) center in a distorted trigonal-planar coordination environment, with one Cp and two phosphane ligands. There are two crystallographically independent mol-ecules in the asymmetric unit besides the disordered solvent molecules.
authors.affiliation: Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.
authors.forename: Marko
authors.initials: M
authors.lastname: Hapke
authors.forename: Anke
authors.initials: A
authors.lastname: Spannenberg