title: Two-dimensional dysprosium(III) triiodate(V) dihydrate, Dy(IO(3))(3)(H(2)O)·H(2)O.
abstract: During our research into novel nonlinear optical materials using 1,10-phenanthroline as an appending ligand on lanthanide iodates, crystals of an infinite layered Dy(III) iodate compound, Dy(IO(3))(3)(H(2)O)·H(2)O, were obtained under hydro-thermal conditions. The Dy(III) cation has a dicapped trigonal prismatic coordination environment consisting of one water O atom and seven other O atoms from seven iodate anions. These iodate anions bridge the Dy(III) cations into a two-dimensional structure. Through O-H⋯O hydrogen bonds, all of these layers stack along [111], giving a supra-molecular channel, with the solvent water mol-ecules filling the voids.
authors.forename: Wenxiang
authors.initials: W
authors.lastname: Chai
authors.forename: Li
authors.initials: L
authors.lastname: Song
authors.forename: Hongsheng
authors.initials: H
authors.lastname: Shi
authors.forename: Laishun
authors.initials: L
authors.lastname: Qin
authors.forename: Kangying
authors.initials: K
authors.lastname: Shu