title: Tris[2-meth-oxy-6-(4-methyl-phenyl-iminio-meth-yl)phenolato-κO,O']tris-(thio-cyanato-κN)neodymium(III).
abstract: In the title compound, [Nd(NCS)(3)(C(15)H(15)NO(2))(3)], the Nd(III) ion is coordinated by three thio-cyanate anions [Nd-N = 2.489 (8)-2.530 (7) Å] and six O atoms [Nd-O = 2.375 (4)-2.843 (5) Å] from three zwitterionic 2-meth-oxy-6-(4-methyl-phenyl-iminiometh-yl)phenolate ligands in a tricapped trigonal-prismatic geometry. Intra-molecular N-H⋯O hydrogen bonds occur. The crystal packing exhibits weak inter-molecular C-H⋯S hydrogen bonds, π-π inter-actions with a distance of 3.904 (7) Å between the centroids of the aromatic rings, and voids of 101 Å(3).
authors.affiliation: Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, People's Republic of China, and College of Chemistry and Life Science, Zhejiang Normal University, Jinhua 321004, Zhejiang, People's Republic of China.
authors.forename: Jia-Lu
authors.initials: JL
authors.lastname: Liu
authors.forename: Jin-Bei
authors.initials: JB
authors.lastname: Shen
authors.forename: Guo-Liang
authors.initials: GL
authors.lastname: Zhao