title: Chlorido(2,3,7,8,12,13,17,18-octa-ethyl-porphyrinato)iron(III) dichloro-methane sesquisolvate.
abstract: The title mol-ecule, [Fe(C(36)H(44)N(4))Cl]·1.5CH(2)Cl(2), is a high-spin square-pyramidal iron(III) porphyrinate with an average value for the equatorial Fe-N bond lengths of 2.065 (3) Å and an axial Fe-Cl distance of 2.2430 (13) Å. The iron cation is displaced by 0.518 (1) Å from the 24-atom mean plane of the porphyrin ring. These values are typical for high-spin iron(III) porphyrinates.
authors.affiliation: Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, USA.
authors.forename: Martin K
authors.initials: MK
authors.lastname: Safo
authors.forename: Kristin E
authors.initials: KE
authors.lastname: Buentello
authors.forename: Allen G
authors.initials: AG
authors.lastname: Oliver
authors.forename: W Robert
authors.initials: WR
authors.lastname: Scheidt