title: A Sn(IV)-porphyrin-based metal-organic framework for the selective photo-oxygenation of phenol and sulfides.
abstract: A functional tin(IV)-porphyrin derivative was used as a building block to construct a novel 3D porous metal-organic framework (MOF). The MOF is built up from tin(IV)-porphyrin struts linking up Zn atoms and formates joining Sn(IV) centers. The immobilization of the photoactive Sn-porphyrins in the channel walls lets the MOF present remarkable photocatalytic activities for the oxygenation of phenol and sulfides, resulting in excellent yields and remarkable selectivity in heterogeneous phases.
authors.affiliation: Department of Chemistry, Zhejiang University, Hangzhou, 310027, PR China.
authors.forename: Ming-Hua
authors.initials: MH
authors.lastname: Xie
authors.forename: Xiu-Li
authors.initials: XL
authors.lastname: Yang
authors.forename: Chao
authors.initials: C
authors.lastname: Zou
authors.forename: Chuan-De
authors.initials: CD
authors.lastname: Wu
mesh_terms: D002384:Catalysis; D008665:Metalloporphyrins / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D010100:Oxygen / Q000737:chemistry*; D010636:Phenols / Q000737:chemistry*; D010777:Photochemistry; D016062:Porosity; D013237:Stereoisomerism; D013440:Sulfides / Q000737:chemistry*; D013499:Surface Properties; D014001:Tin / Q000737:chemistry*
chemical_list: D008665:Metalloporphyrins; D010636:Phenols; D013440:Sulfides; D014001:Tin; D010100:Oxygen