title: Adeninium cytosinium sulfate.
abstract: In the title compound, C(5)H(6)N(5) (+)·C(4)H(6)N(3)O(+)·SO(4) (2-), the adeninium (AdH(+)) and cytosinium (CytH(+)) cations and sulfate dianion are involved in a three-dimensional hydrogen-bonding network with four different modes, viz. AdH(+)⋯AdH(+), AdH(+)⋯CytH(+), AdH(+)⋯SO(4) (2-) and CytH(+)⋯SO(4) (2-). The adeninium cations form N-H⋯N dimers through the Hoogsteen faces, generating a characteristic R(2) (2)(10) motif. This AdH(+)⋯AdH(+) hydrogen bond in combination with AdH(+)⋯CytH(+ )H-bonds leads to two-dimensional cationic ribbons parallel to the a axis. The sulfate anions inter-link the ribbons into a three-dimensional hydrogen-bonding network and thus reinforce the crystal structure.
authors.forename: Aouatef
authors.initials: A
authors.lastname: Cherouana
authors.forename: Raja
authors.initials: R
authors.lastname: Bousboua
authors.forename: Lamia
authors.initials: L
authors.lastname: Bendjeddou
authors.forename: Slimane
authors.initials: S
authors.lastname: Dahaoui
authors.forename: Claude
authors.initials: C
authors.lastname: Lecomte