title: {2,2'-[5-Bromo-pyridine-2,3-diylbis(nitrilo-methyl-idyne)]diphenolato}chlorido(dimethyl-formamide)manganese(III).
abstract: In the title complex, [Mn(C(19)H(12)BrN(3)O(2))Cl(C(3)H(7)NO)], the Mn(III) ion is coordinated by two N and two O atoms from the tetra-dentate Schiff base ligand, one O atom from the dimethyl-formamide ligand and a Cl anion in a distorted octa-hedral geometry. In the crystal structure, weak inter-molecular C-H⋯Cl hydrogen bonds link the mol-ecules into centrosymmetric dimers with a short distance of 3.878 (3) Å between the centroids of the aromatic rings.
authors.affiliation: College of Chemistry & Chemical Engineering, Shanxi Datong University, Shanxi 037009, People's Republic of China.
authors.forename: Hai
authors.initials: H
authors.lastname: Xie
authors.forename: Shuangming
authors.initials: S
authors.lastname: Meng
authors.forename: Yongjun
authors.initials: Y
authors.lastname: Zhu
authors.forename: Peiwan
authors.initials: P
authors.lastname: Bai