title: Bromido{dicyclo-hexyl[2'-(dimethyl-amino)biphenyl-2-yl]phosphine-κP}[2-(4,6-dimethyl-pyrimidin-2-yl)ferrocenyl-κC,N]palladium(II) dichloro-methane solvate.
abstract: In the title compound, [FePdBr(C(5)H(5))(C(11)H(10)N(2))(C(26)H(36)NP)]·CH(2)Cl(2), the Pd atom displays a distorted square-planar coordination environment. The five-membered metallacycle adopts an envelope conformation with the coordinated cyclo-penta-dienyl C atom 0.4222 (4) Å out of plane. The dihedral angle between the pyrimidinyl ring and substituted cyclo-penta-dienyl ring is 21.47 (2)°. In the crystal structure, the dimeric unit is generated through the C-H⋯π contact via a crystallographic inversion centre, while the C-H⋯Cl contacts in the dimeric centre link the dichlormethane mol-ecules with the Pd complex mol-ecules.
authors.forename: Xin-Qi
authors.initials: XQ
authors.lastname: Hao
authors.forename: Hong-Mei
authors.initials: HM
authors.lastname: Li
authors.forename: Hui
authors.initials: H
authors.lastname: Jiang
authors.forename: Yong-Tao
authors.initials: YT
authors.lastname: Ma
authors.forename: Mao-Ping
authors.initials: MP
authors.lastname: Song