title: Discontinuous shear thickening in confined dilute carbon nanotube suspensions.
abstract: A monotonic decrease in viscosity with increasing shear stress is a known rheological response to shear flow in complex fluids in general and for flocculated suspensions in particular. Here we demonstrate a discontinuous shear-thickening transition on varying shear stress where the viscosity jumps sharply by four to six orders of magnitude in flocculated suspensions of multiwalled carbon nanotubes (MWNT) at very low weight fractions (approximately 0.5%). Rheooptical observations reveal the shear-thickened state as a percolated structure of MWNT flocs spanning the system size. We present a dynamic phase diagram of the non-Brownian MWNT dispersions revealing a starting jammed state followed by shear-thinning and shear-thickened states. The present study further suggests that the shear-thickened state obtained as a function of shear stress is likely to be a generic feature of fractal clusters under flow, albeit under confinement. An understanding of the shear-thickening phenomena in confined geometries is pertinent for flow-controlled fabrication techniques in enhancing the mechanical strength and transport properties of thin films and wires of nanostructured composites as well as in lubrication issues.
authors.affiliation: Department of Physics, Indian Institute of Science, Bangalore 560012, India.
authors.forename: Sayantan
authors.initials: S
authors.lastname: Majumdar
authors.forename: Rema
authors.initials: R
authors.lastname: Krishnaswamy
authors.forename: A K
authors.initials: AK
authors.lastname: Sood
mesh_terms: D004553:Electric Conductivity; D009038:Motion; D036103:Nanotechnology / Q000379:methods*; D043942:Nanotubes / Q000737:chemistry; D037742:Nanotubes, Carbon / Q000737:chemistry*; D055095:Optics and Photonics; D010825:Physics / Q000379:methods; D012212:Rheology / Q000379:methods; D013314:Stress, Mechanical; D013535:Suspensions / Q000737:chemistry*; D013696:Temperature; D019415:Torque; D014783:Viscosity
chemical_list: D037742:Nanotubes, Carbon; D013535:Suspensions