title: Chlorido{N-[2-(diphenylphosphanyl)benz-ylidene]-2-(2-thienyl)ethanamine-κN,P}methylpalladium(II) dichloromethane hemisolvate.
abstract: In the title compound, [Pd(CH(3))Cl(C(25)H(22)NPS)]·0.5C(2)H(2)Cl(2), the Pd(II) atom is coordinated by the N,P-bidentate ligand, a methyl group and a chloride ion, generating a distorted square-planar PdCClNS coordination geometry, with the N and Cl atoms trans. The thio-phene ring is equally disordered over two orientations and the dichloro-methane solvent mol-ecule is disordered about an inversion centre.
authors.forename: Martin O
authors.initials: MO
authors.lastname: Onani
authors.forename: William M
authors.initials: WM
authors.lastname: Motswainyana
authors.forename: Emmanuel I
authors.initials: EI
authors.lastname: Iwuoha
authors.forename: James
authors.initials: J
authors.lastname: Darkwa
authors.forename: Roger A
authors.initials: RA
authors.lastname: Lalancette