title: 4-Carbethoxy-1-[4-(N,N-dimethylamino)benzoyl]thiosemicarbazide.
abstract: The mol-ecular structure of the title compound, C(13)H(18)N(4)O(3)S, (systematic name: ethyl N-{2-[4-(dimethyl-amino)benzo-yl]hydrazinethio-carbon-yl}carbamate) is stabilized by intra-molecular N-H⋯O=C hydrogen bonding arranged in an S(6) graph-set motif. In the crystal, inversion dimers connected via inter-molecular N-H⋯S=C hydrogen bonds [R(2) (2)(8) graph-set motif] form sheets parallel to the (21) plane. Dimers are also formed by the mol-ecules via weak inter-molecular N-H⋯S=C hydrogen bonds [R(2) (2)(10) graph-set motif] connecting the sheets.
authors.forename: Hriday
authors.initials: H
authors.lastname: Bera
authors.forename: Anton V
authors.initials: AV
authors.lastname: Dolzhenko
authors.forename: Geok Kheng
authors.initials: GK
authors.lastname: Tan
authors.forename: Lip Lin
authors.initials: LL
authors.lastname: Koh
authors.forename: Wai Keung
authors.initials: WK
authors.lastname: Chui