title: catena-Poly[[sodium-di-μ-β-d-glucose] chloride].
abstract: The asymmetric unit of the title compound, {[Na(C(6)H(12)O(6))(2)]Cl}(n), contains six glucose mol-ecules, three Na(+) ions and three Cl(-) ions, i.e. three independent {[Na(C(6)H(12)O(6))(2)]Cl} units. Each of these units forms polymeric chains along the c axis. Each Na(+) ion is surrounded by six O atoms from four glucose mol-ecules, forming a distorted octa-hedral geometry. All glucose mol-ecules adopt chair conformations. The constituent units are linked into a three-dimensional framework by O-H⋯Cl and O-H⋯O hydrogen bonds, utilizing all the O-H groups.
authors.forename: K C
authors.initials: KC
authors.lastname: Wong
authors.forename: Abdul
authors.initials: A
authors.lastname: Hamid
authors.forename: S
authors.initials: S
authors.lastname: Baharuddin
authors.forename: Ching Kheng
authors.initials: CK
authors.lastname: Quah
authors.forename: Hoong-Kun
authors.initials: HK
authors.lastname: Fun