title: Importance of the position of the chromophore group on the dissociation process of light sensitive alkoxyamines.
abstract: New photosensitive alkoxyamines have been designed using molecular orbital calculations to improve the selective CO versus NO cleavage. The targeted light-sensitive alkoxyamine is synthesized in one step and its reactivity under UV has been investigated using both ESR and LFP. The ability of this alkoxyamine to control the photopolymerization of n-butyl acrylate is evidenced through a process called nitroxide-mediated photopolymerization NMP(2) . The selected alkoxyamine is finally used to prepare covalently bonded multilayered micropatterns. This original application highlights the high potential of this technique for some specific applications that require spatial control.
authors.affiliation: Laboratoire Chimie Provence, UMR 6264, Université de Provence, campus Saint Jérôme, Case 542, 13397 Marseille Cedex 20, France. yohann.guillaneuf@univ-provence.fr.
authors.forename: Yohann
authors.initials: Y
authors.lastname: Guillaneuf
authors.forename: Davy-Louis
authors.initials: DL
authors.lastname: Versace
authors.forename: Denis
authors.initials: D
authors.lastname: Bertin
authors.forename: Jacques
authors.initials: J
authors.lastname: Lalevée
authors.forename: Didier
authors.initials: D
authors.lastname: Gigmes
authors.forename: Jean-Pierre
authors.initials: JP
authors.lastname: Fouassier