title: Ferrocene-1-carbaldehyde thio-semi-carbazone.
abstract: The asymmetric unit of the title compound, [Fe(C(5)H(5))(C(7)H(8)N(3)S)], consists of two crystallographically independent mol-ecules, A and B. The cyclo-penta-dienyl (Cp) rings in both mol-ecules adopt an eclipsed conformation and are parallel to each other, forming dihedral angles of 2.5 (3) and 1.1 (3)°, respectively. The mean plane of the semicarbazone group is coplanar with the attached Cp ring in mol-ecule A, whereas it is twisted away in mol-ecule B. In the crystal structure, inter-molecular N-H⋯S hydrogen bonds link the mol-ecules into two-dimensional planes parallel to the ab plane. The structure is further consolidated by C-H⋯π inter-actions.
authors.forename: M R
authors.initials: MR
authors.lastname: Vikneswaran
authors.forename: Siang Guan
authors.initials: SG
authors.lastname: Teoh
authors.forename: Chin Sing
authors.initials: CS
authors.lastname: Yeap
authors.forename: Hoong-Kun
authors.initials: HK
authors.lastname: Fun