title: Aqua-azido-{3,3'-[o-phenyl-enebis(nitrilo-methyl-idyne)]di-2-naphtholato}manganese(III).
abstract: In the title complex, [Mn(C(28)H(18)N(2)O(2))(N(3))(H(2)O)], the Mn(III) ion adopts a distorted fac-MnO(3)N(3) octa-hedral geometry arising from the O,N,N',O'-tetra-dentate Schiff base ligand, an azide ion and a water mol-ecule. In the crystal, inter-molecular O-H⋯(O,O) and O-H⋯N hydrogen bonds and π-π inter-actions [centroid-centroid separation = 3.5535 (13) Å] link the mol-ecules into chains.
authors.affiliation: Department of Chemistry and Chemical Engineering, School of Bioengineering, SouthWest JiaoTong University, Chengdu, Sichuan 610031, People's Republic of China.
authors.forename: Cui-Juan
authors.initials: CJ
authors.lastname: Wang
authors.forename: Xian-Li
authors.initials: XL
authors.lastname: Zhou
authors.forename: Bing-Jun
authors.initials: BJ
authors.lastname: Zhang