title: Bis(tetra-phenyl-phospho-nium) tris-[N-(methyl-sulfon-yl)dithio-carbimato(2-)-κS,S']stannate(IV).
abstract: In the title complex, (C(24)H(20)P)(2)[Sn(C(2)H(3)NO(2)S(3))(3)], the Sn(IV) atom is coordinated by three N-(methyl-sulfon-yl)dithio-carbimate bidentate ligands through the anionic S atoms in a slightly distorted octa-hedral coordination geometry. There is one half-mol-ecule in the asymmetric unit; the complex is located on a crystallographic twofold rotation axis passing through the cation and bis-ecting one of the (non-symmetric) ligands, which appears thus disordered over two sites of equal occupancy. In the crystal structure, weak inter-molecular C-H⋯O and C-H⋯S inter-actions contribute to the packing stabilization.
authors.forename: João P
authors.initials: JP
authors.lastname: Barolli
authors.forename: Marcelo R L
authors.initials: MR
authors.lastname: Oliveira
authors.forename: Rodrigo S
authors.initials: RS
authors.lastname: Corrêa
authors.forename: Javier
authors.initials: J
authors.lastname: Ellena