title: Bis(propane-1,3-diaminium) hexa-fluoridoferrate(III) fluoride trihydrate.
abstract: The asymmetric unit of the title iron hybrid fluoride, (C(3)H(12)N(2))(2)[FeF(6)]F·3H(2)O, contains two propane-1,3-diamin-ium [(H(2)dap)(2+)] cations, an octa-hedral [FeF(6)](3-) anion, an isolated F(-) anion and three water mol-ecules of solvation. Each [FeF(6)](3-) anion is surrounded by four separate hydrogen-bonded water mol-ecules in the equatorial sites and by five separate aminium cation donor groups. The axial F atoms are only involved in N-H⋯F hydrogen bonds, resulting in a three-dimensional structure.
authors.forename: Aymen
authors.initials: A
authors.lastname: Zouaghi
authors.forename: Amor
authors.initials: A
authors.lastname: Benali
authors.forename: Vincent
authors.initials: V
authors.lastname: Maisonneuve
authors.forename: Marc
authors.initials: M
authors.lastname: Leblanc