title: 4-Amino-3-(o-tolyl-oxymeth-yl)-1H-1,2,4-triazole-5(4H)-thione.
abstract: The asymmetric unit of the title compound, C(10)H(12)N(4)OS, contains two independent mol-ecules, A and B, which differ significantly in the relative orientations of the benzene and triazole rings. The dihedral angle between the above two rings is 6.94 (5)° in mol-ecule A and 77.60 (5)° in mol-ecule B. In the crystal, mol-ecules are linked into a three-dimensional network by N-H⋯S, N-H⋯O, N-H⋯N and C-H⋯S hydrogen bonds and π-π inter-actions between the benzene and triazole rings [centroid-centroid distance = 3.5311 (6) Å] are also present.
authors.forename: Hoong-Kun
authors.initials: HK
authors.lastname: Fun
authors.forename: Wei-Ching
authors.initials: WC
authors.lastname: Liew
authors.forename: A M
authors.initials: AM
authors.lastname: Vijesh
authors.forename: Mahesh
authors.initials: M
authors.lastname: Padaki
authors.forename: Arun M
authors.initials: AM
authors.lastname: Isloor