title: Penta-carbonyl-2κC-chlorido-1κCl-bis-[1(η)-cyclo-penta-dien-yl](μ-α-oxido-benzyl-idene-1:2κO:C)titanium(IV)tungsten(0).
abstract: The title compound, [TiW(C(5)H(5))(2)(C(7)H(5)O)Cl(CO)(5)], consists of two metal centres, with a (tungstenpenta-carbon-yl)oxy-phenyl-carbene unit coordinated by a titanocene chloride. The oxycarbene group is nearly planar, with the phenyl ring twisted by an angle of 39.1 (2)° with respect to this plane. One of the cyclo-penta-dienyl rings undergoes an offset face-to-face π-π inter-action [3.544 (6) Å] with the symmetry-related cyclo-penta-dienyl ring of a neighbouring mol-ecule.
authors.affiliation: Department of Chemistry and Polymer Science, University of Stellenbosch, Private Bag X1, Matieland 7602, South Africa.
authors.forename: Catharine
authors.initials: C
authors.lastname: Esterhuysen
authors.forename: I B Jacques
authors.initials: IB
authors.lastname: Nel
authors.forename: Matthias W
authors.initials: MW
authors.lastname: Esterhuysen
authors.forename: Stephanie
authors.initials: S
authors.lastname: Cronje