title: 7-Bromo-1-(4-chloro-phenyl-sulfan-yl)-2-phenyl-naphtho[2,1-b]furan.
abstract: In the title compound, C(24)H(14)BrClOS, the S-bound 4-chloro-phenyl ring is nearly perpendicular to the plane of the naphthofuran fragment [dihedral angle = 83.34 (3)°] and the phenyl ring in the 2-position is rotated out of the naphthofuran plane by a dihedral angle of 15.23 (5)°. The crystal structure is stabilized by aromatic π-π inter-actions between the furan and the central benzene rings of the neighbouring naphthofuran fragments, and between the outer benzene rings of the neighbouring naphthofuran fragments; the centroid-centroid distances within the stack are 3.879 (2) and 3.857 (2) Å. In addition, inter-molecular C-Cl⋯π inter-actions [3.505 (2) Å] between the Cl atom and the 2-phenyl ring are present.
authors.forename: Hong Dae
authors.initials: HD
authors.lastname: Choi
authors.forename: Pil Ja
authors.initials: PJ
authors.lastname: Seo
authors.forename: Byung Ki
authors.initials: BK
authors.lastname: Kim
authors.forename: Byeng Wha
authors.initials: BW
authors.lastname: Son
authors.forename: Uk
authors.initials: U
authors.lastname: Lee