title: trans-Bis(1,1,1,5,5,5-hexa-fluoro-pentane-2,4-dionato-κO,O')bis-(4-methyl-1,2,3-selenadiazole-κN)copper(II).
abstract: In the title compound, [Cu(C(5)HF(6)O(2))(2)(C(3)H(4)N(2)Se)(2)], the Cu(II) atom (site symmetry ) is coordinated by two O,O'-bidentate 1,1,1,5,5,5-hexa-fluoro-2,4-penta-nedione (hp) ligands and two 4-methyl-1,2,3-selenadiazole mol-ecules, resulting in a slightly distorted trans-CuN(2)O(4) octa-hedral geometry in which the cis angles deviate by less than 3° from 90°. The selenadiazole plane is canted at 73.13 (17)° to the square plane defined by the penta-nedionate O atoms. The F atoms of one of the hp ligands are disordered over two sets of sites in a 0.66 (3):0.34 (3) ratio. There are no significant inter-molecular inter-actions in the crystal.
authors.forename: Neil M
authors.initials: NM
authors.lastname: Boag
authors.forename: Andrew D
authors.initials: AD
authors.lastname: Jackson
authors.forename: Paul D
authors.initials: PD
authors.lastname: Lickiss
authors.forename: Richard D
authors.initials: RD
authors.lastname: Pilkington
authors.forename: Alan D
authors.initials: AD
authors.lastname: Redhouse