title: Controlled growth of CNT in mesoporous AAO through optimized conditions for membrane preparation and CVD operation.
abstract: Anodic aluminium oxide (RAAO) membranes with a mesoporous structure were prepared under strictly controlling experimental process conditions, and physically and chemically characterized by a wide range of experimental techniques. Commercial anodic aluminium oxide (CAAO) membranes were also investigated for comparison. We demonstrated that RAAO membranes have lower content of both water and phosphorus and showed better porosity shape than CAAO. The RAAO membranes were used for template growth of carbon nanotubes (CNT) inside its pores by ethylene chemical vapour deposition (CVD) in the absence of a catalyst. A composite material, containing one nanotube for each channel, having the same length as the membrane thickness and an external diameter close to the diameter of the membrane holes, was obtained. Yield, selectivity and quality of CNTs in terms of diameter, length and arrangement (i.e. number of tubes for each channel) were optimized by investigating the effect of changing the experimental conditions for the CVD process. We showed that upon thermal treatment RAAO membranes were made up of crystallized allotropic alumina phases, which govern the subsequent CNT growth, because of their catalytic activity, likely due to their Lewis acidity. The strict control of experimental conditions for membrane preparation and CNT growth allowed us to enhance the carbon structural order, which is a critical requisite for CNT application as a substitute for copper in novel nano-interconnects.
authors.affiliation: Department of Chemical and Food Engineering, University of Salerno, Fisciano (SA), Italy.
authors.forename: P
authors.initials: P
authors.lastname: Ciambelli
authors.forename: L
authors.initials: L
authors.lastname: Arurault
authors.forename: M
authors.initials: M
authors.lastname: Sarno
authors.forename: S
authors.initials: S
authors.lastname: Fontorbes
authors.forename: C
authors.initials: C
authors.lastname: Leone
authors.forename: L
authors.initials: L
authors.lastname: Datas
authors.forename: D
authors.initials: D
authors.lastname: Sannino
authors.forename: P
authors.initials: P
authors.lastname: Lenormand
authors.forename: S Le Blond
authors.initials: Sle B
authors.lastname: Du Plouy
mesh_terms: D000537:Aluminum Oxide / Q000737:chemistry*; D003460:Crystallization; D003890:Desiccation; D004566:Electrodes; D004602:Elements; D008567:Membranes, Artificial; D036103:Nanotechnology / Q000379:methods*; D037742:Nanotubes, Carbon / Q000737:chemistry* / Q000648:ultrastructure; D016062:Porosity; D013059:Spectrum Analysis, Raman; D013696:Temperature; D013818:Thermogravimetry; D014961:X-Ray Diffraction
chemical_list: D004602:Elements; D008567:Membranes, Artificial; D037742:Nanotubes, Carbon; D000537:Aluminum Oxide