title: Effects of preparation method on the performance of Ni/Al(2)O(3) catalysts for hydrogen production by bio-oil steam reforming.
abstract: Steam reforming of bio-oil derived from the fast pyrolysis of biomass is an economic and renewable process for hydrogen production. The main objective of the present work has been to investigate the effects of the preparation method of Ni/Al(2)O(3) catalysts on their performance in hydrogen production by bio-oil steam reforming. The Ni/Al(2)O(3) catalysts were prepared by impregnation, co-precipitation, and sol-gel methods. XRD, XPS, H(2)-TPR, SEM, TEM, TG, and N(2) physisorption measurements were performed to characterize the texture and structure of the catalysts obtained after calcination and after their subsequent use. Ethanol and bio-oil model compound were selected for steam reforming to evaluate the catalyst performance. The catalyst prepared by the co-precipitation method was found to display better performance than the other two. Under the optimized reaction conditions, an ethanol conversion of 99% and a H(2) yield of 88% were obtained.
authors.affiliation: State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, People's Republic of China.
authors.forename: Xinbao
authors.initials: X
authors.lastname: Li
authors.forename: Shurong
authors.initials: S
authors.lastname: Wang
authors.forename: Qinjie
authors.initials: Q
authors.lastname: Cai
authors.forename: Lingjun
authors.initials: L
authors.lastname: Zhu
authors.forename: Qianqian
authors.initials: Q
authors.lastname: Yin
authors.forename: Zhongyang
authors.initials: Z
authors.lastname: Luo
mesh_terms: D000327:Adsorption; D000537:Aluminum Oxide / Q000737:chemistry*; D056804:Biofuels / Q000032:analysis*; D001709:Biotechnology / Q000379:methods*; D002384:Catalysis; D003460:Crystallization; D000431:Ethanol / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D046529:Microscopy, Electron, Transmission; D009532:Nickel / Q000737:chemistry*; D056951:Photoelectron Spectroscopy; D013227:Steam; D013696:Temperature; D013818:Thermogravimetry; D014961:X-Ray Diffraction
chemical_list: D056804:Biofuels; D013227:Steam; D000431:Ethanol; D009532:Nickel; D006859:Hydrogen; D000537:Aluminum Oxide