title: Bis[μ-2-(2-benzoyl-hydrazinylidenemeth-yl)-6-methoxy-phenolato][2-(2-benzoyl-hydrazinylidenemeth-yl)-6-methoxy-phenolato]dimanganese(II) perchlorate methanol solvate.
abstract: In the title complex, [Mn(2)(C(15)H(13)N(2)O(3))(3)]ClO(4)·CH(3)OH, the two Mn(II) ions are bridged by two phenolate O atoms from two ligands, forming an Mn(2)O(2) quadrangle. Each Mn(II) ion has a distorted octa-hedral coordination geometry. One Mn(II) ion is coordinated by two N atoms and four O atoms from two ligands, and the other is coordinated by one N atom and five O atoms from three ligands. A dimer is formed by inter-molecular N-H⋯O hydrogen bonds. The dimers, perchlorate anions and methanol solvent mol-ecules are further connected into a chain along [01] through N-H⋯O and O-H⋯O hydrogen bonds.
authors.forename: Gui-Miao
authors.initials: GM
authors.lastname: Yu
authors.forename: Yun-Hui
authors.initials: YH
authors.lastname: Li
authors.forename: Li-Fei
authors.initials: LF
authors.lastname: Zou
authors.forename: Jian-Wei
authors.initials: JW
authors.lastname: Zhu
authors.forename: Xiao-Qiu
authors.initials: XQ
authors.lastname: Liu