title: 4-Methoxy-benzene-carbothio-amide.
abstract: The asymmetric unit of the title compound, C(8)H(9)NOS, contains two independent mol-ecules with the meth-oxy groups oriented in opposite conformations. The mean planes of the carbothio-amide groups are tilted by 7.88 (15) and 11.16 (9)° from the mean planes of the benzene rings. In the crystal, the mol-ecules form dimers via intermolecular N-H⋯S inter-molecular hydrogen bonds, resulting in eight-membered rings of R(2) (2)(8) graph-set motif. The dimers are further linked by C-H⋯O hydrogen bonds into chains along the c axis. Adjacent chains inter-act through inter-molecular N-H⋯S hydrogen bonds, generating eight-membered rings of R(4) (2)(8) graph-set motif.
authors.forename: Saqib
authors.initials: S
authors.lastname: Ali
authors.forename: Shahid
authors.initials: S
authors.lastname: Hameed
authors.forename: Ahmad
authors.initials: A
authors.lastname: Luqman
authors.forename: Tashfeen
authors.initials: T
authors.lastname: Akhtar
authors.forename: Masood
authors.initials: M
authors.lastname: Parvez