title: (Dimethyl-formamide-κO)(2-hy-droxy-benzoato-κO,O)[tris-(1-methyl-1H-benzimidazol-2-ylmethyl-κN)amine-κN]manganese(II) perchlorate dimethyl-formamide monosolvate.
abstract: In the title complex, [Mn(C(7)H(5)O(3))(C(27)H(27)N(7))(C(3)H(7)NO)]ClO(4)·C(3)H(7)NO, the Mn(II) ion is coordinated in a slightly distorted monocapped trigonal-prismatic geometry. The tris-(1-methyl-1H-benzimidazol-2-ylmeth-yl)amine (Mentb) ligand coordinates in a tetra-dentate mode and the coordination is completed by a bis-chelating salicylate ligand and a dimethyl-formamide ligand. The hy-droxy group and the ortho H atoms of the salicylate ligand were refined as disordered over two sites with occupancies of 0.581 (8) and 0.419 (8). Both disorder components of the hy-droxy group form intra-molecular O-H⋯O hydrogen bonds.
authors.affiliation: School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People's Republic of China.
authors.forename: Huilu
authors.initials: H
authors.lastname: Wu
authors.forename: Ying
authors.initials: Y
authors.lastname: Bai
authors.forename: Xingcai
authors.initials: X
authors.lastname: Huang
authors.forename: Xuan
authors.initials: X
authors.lastname: Meng
authors.forename: Baoliang
authors.initials: B
authors.lastname: Qi