title: Benzyl 3-(10-oxo-9,10-dihydrophenanthren-9-ylidene)dithiocarbazate.
abstract: In the title compound, C(22)H(16)N(2)OS(2), the phenanthrene ring is nearly perpendicular to the phenyl ring, making a dihedral angle of 87.2 (2)°. Intra-molecular N-H⋯O inter-actions are present. In the crystal structure, the mol-ecules are linked through inter-molecular C-H⋯O inter-actions. The crystal structure is also stabilized by C-H⋯π inter-actions and weak π-π contacts [centroid-centroid distance = 3.36 (6) Å].
authors.affiliation: School of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan 467000, People's Republic of China.
authors.forename: Qiao-Ru
authors.initials: QR
authors.lastname: Liu
authors.forename: Song-Mao
authors.initials: SM
authors.lastname: Chu
authors.forename: Gan-Qing
authors.initials: GQ
authors.lastname: Zhao
authors.forename: Li-Hua
authors.initials: LH
authors.lastname: Chen
authors.forename: Yong-Jun
authors.initials: YJ
authors.lastname: Han