title: Structure analysis of titanate nanorods by automated electron diffraction tomography.
abstract: A hitherto unknown phase of sodium titanate, NaTi(3)O(6)(OH)·2H(2)O, was identified as the intermediate species in the synthesis of TiO(2) nanorods. This new phase, prepared as nanorods, was investigated by electron diffraction, X-ray powder diffraction, thermogravimetric analysis and high-resolution transmission electron microscopy. The structure was determined ab initio using electron diffraction data collected by the recently developed automated diffraction tomography technique. NaTi(3)O(6)(OH)·2H(2)O crystallizes in the monoclinic space group C2/m. Corrugated layers of corner- and edge-sharing distorted TiO(6) octahedra are intercalated with Na(+) and water of crystallization. The nanorods are typically affected by pervasive defects, such as mutual layer shifts, that produce diffraction streaks along c*. In addition, edge dislocations were observed in HRTEM images.
authors.affiliation: Institut für Physikalische Chemie der Johannes Gutenberg-Universität, Mainz, Germany.
authors.forename: Iryna
authors.initials: I
authors.lastname: Andrusenko
authors.forename: Enrico
authors.initials: E
authors.lastname: Mugnaioli
authors.forename: Tatiana E
authors.initials: TE
authors.lastname: Gorelik
authors.forename: Dominik
authors.initials: D
authors.lastname: Koll
authors.forename: Martin
authors.initials: M
authors.lastname: Panthöfer
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Tremel
authors.forename: Ute
authors.initials: U
authors.lastname: Kolb