title: Metallization of Kevlar fibers with gold.
abstract: Electrochemical gold plating processes were examined for the metallization of Kevlar yarn. Conventional Sn(2+)/Pd(2+) surface activation coupled with electroless Ni deposition rendered the fibers conductive enough to serve as cathodes for electrochemical plating. The resulting coatings were quantified gravimetrically and characterized via adhesion tests together with XRD, SEM, TEM; the coatings effect on fiber strength was also probed. XRD data showed that metallic Pd formed during surface activation whereas amorphous phases and trace amounts of pure Ni metal were plated via the electroless process. Electrodeposition in a thiosulfate bath was the most efficient Au coating process as compared with the analogous electroless procedure, and with electroplating using a commercial cyanide method. Strongly adhering coatings resulted upon metallization with three consecutive electrodepositions, which produced conductive fibers able to sustain power outputs in the range of 1 W. On the other hand, metallization affected the tensile strength of the fiber and defects present in the metal deposits make questionable the effectiveness of the coatings as protective barriers.
authors.affiliation: Department of Chemistry and Biochemistry, Auburn University, Alabama 36849, USA.
authors.forename: Brian K
authors.initials: BK
authors.lastname: Little
authors.forename: Yunfeng
authors.initials: Y
authors.lastname: Li
authors.forename: V
authors.initials: V
authors.lastname: Cammarata
authors.forename: R
authors.initials: R
authors.lastname: Broughton
authors.forename: G
authors.initials: G
authors.lastname: Mills
mesh_terms: D055664:Electrochemical Techniques / Q000379:methods*; D004595:Electroplating / Q000379:methods*; D006046:Gold / Q000737:chemistry*; D013499:Surface Properties
chemical_list: D006046:Gold