title: Chlorido{N,N-dibenzyl-N,N-bis-[(diphenyl-phosphan-yl)meth-yl]pyridine-2,6-diamine}-methyl-platinum(II).
abstract: In the title mononuclear complex, [Pt(CH(3))Cl(C(45)H(41)N(3)P(2))], the pyridine-2,6-diamine ligand can be viewed as a centrosymmetric motif having two pendant N-benzyl-N-[(diphenyl-phosphan-yl)meth-yl] arms, the two P atoms of which chelate to the Pt(II) ion, forming a ten-membered metallocycle. A distorted square-planar coordination geometry around the Pt(II) atom is completed by a methyl ligand and a chloride ion. The packing between the mononuclear units is achieved through C-H⋯π inter-actions, which link the mol-ecules into chains along the c axis.
authors.affiliation: Department of Chemistry, Capital Normal University, Beijing 100048, People's Republic of China.
authors.forename: Zi-Jia
authors.initials: ZJ
authors.lastname: Wang
authors.forename: Xiao-Xi
authors.initials: XX
authors.lastname: Wang
authors.forename: Chong-Qing
authors.initials: CQ
authors.lastname: Wan