title: [1,1'-Bis(diphenyl-phosphino)cobalto-cenium-κP,P']dichloridoplatinum(II) hexa-fluorido-phosphate.
abstract: The title bimetallic compound, [PtCl(2){Co(C(17)H(14)P)(2)}]PF(6), was obtained by reaction of 1,1'-bis-(diphenyl-phosphino)cobalto-cenium hexa-fluorido-phosphate with bis-(acetonitrile)di-chloridoplatinum. The Pt(II) ion is four-coordinated in a slightly distorted square-planar environment by two P atoms of the 1,1'-bis-(diphenyl-phosphino)cobaltocenium moiety and two Cl atoms. In the crystal structure, mol-ecules are linked by weak C-H⋯F and C-H⋯Cl hydrogen bonds.
authors.affiliation: College of Chemical and Environmental Engineering, Wuhan Polytechnic University, Wuhan 430023, People's Republic of China.
authors.forename: Jin-Tao
authors.initials: JT
authors.lastname: Guan
authors.forename: Kai-Cheng
authors.initials: KC
authors.lastname: Zhang
authors.forename: Zhi-Qun
authors.initials: ZQ
authors.lastname: Dai