title: 2,2'-Dithio-dianiline: a redetermination at 100 K.
abstract: STRUCTURAL STUDIES OF THE TITLE COMPOUND [SYSTEMATIC NAME: 2,2'-(disulfanedi-yl)dianiline], C(12)H(12)N(2)S(2), were previously performed at room temperature [Gomes de Mesquita (1967 ▶). Acta Cryst.23, 671; Lee & Bryant (1970 ▶). Acta Cryst. B26, 1729; Ribar et al. (1975 ▶). Bull. Yugoslav. Crystallogr. Centre, A10, 68]. The results of the current redetermination allow a clarification of the nature of the intra- and inter-molecular N-H⋯S hydrogen bonding described in the literature for this compound. On cooling to 100 K, the unit cell contracts most in the c axis, and it changes rather less in the directions involving the strongly hydrogen-bonded chains, which are the a and b axes. In the crystal structure, N-H⋯N hydrogen bonds link neighbouring mol-ecules into two-dimensional frameworks parallel to the ab plane. An additional inter-molecular N-H⋯S hydrogen bond has also been established, based on freely refined H-atom positions. Inter-molecular C-H⋯π inter-actions further stabilize the crystal structure.
authors.forename: Jia Hao
authors.initials: JH
authors.lastname: Goh
authors.forename: Hoong-Kun
authors.initials: HK
authors.lastname: Fun
authors.forename: M
authors.initials: M
authors.lastname: Babu
authors.forename: B
authors.initials: B
authors.lastname: Kalluraya