title: N-[3-(2,6-Dimethylanilino)-1-methylbut-2-enylidene]-2,6-dimethylanilinium chloride.
abstract: The title salt, C(21)H(27)N(2) (+)·Cl(-) resulted from the condensation between 2,6-dimethyl-aniline and acetyl-acetone in acidified ethanol. The bulky cation is stabilized in a β-imino-enamine tautomeric form, and presents a W-shaped conformation. The benzene rings are arranged almost parallel, with a dihedral angle of 6.58 (4)° between the mean planes. Both N-H groups in the cation form strong hydrogen bonds with two symmetry-related chloride anions. The resulting supra-molecular structure is a one dimensional polymer running along [001], alternating cations and anions. The π-π inter-action observed in the mol-ecule, characterized by a centroid-centroid separation of 4.298 (4) Å, is thus extended to the chains, with separations of 5.222 (4) Å between benzene rings of neighbouring cations in the crystal.
authors.forename: Víctor M
authors.initials: VM
authors.lastname: Jiménez-Pérez
authors.forename: Sylvain
authors.initials: S
authors.lastname: Bernès
authors.forename: Blanca M
authors.initials: BM
authors.lastname: Munõz
authors.forename: Boris I
authors.initials: BI
authors.lastname: Kharisov
authors.forename: Andrea V
authors.initials: AV
authors.lastname: Vela