title: The trigonal polymorph of strontium tetra-borate, β-SrB(4)O(7).
abstract: The asymmetric unit of the title compound, β-SrB(4)O(7), contains five Sr atoms (three located on a threefold rotation axis), twelve B and 21 O atoms. The structure is made up from BO(3) triangles and BO(4) tetra-hedra in a 1:1 ratio. Pairs of BO(3) triangles are linked to BO(4) tetra-hedra via common corners, forming chains. These chains are further linked to adjacent chains through corner-sharing, leading to a three-dimensional framework with channels running parallel to [001]. The Sr(2+) ions reside in the channels and exhibit strongly distorted polyhedra The density of the β-polymorph is considerably lower than that of α-SrB(4)O(7), which is constructed solely from BO(4) tetra-hedra.
authors.affiliation: Institute of Physics SB RAS, Krasnoyarsk 660036, Russian Federation and Siberian Federal University, Svobodnyi st. 79, Krasnoyarsk 660041, Russian Federation.
authors.forename: Alexander D
authors.initials: AD
authors.lastname: Vasiliev
authors.forename: Alexander V
authors.initials: AV
authors.lastname: Cherepakhin
authors.forename: Alexander I
authors.initials: AI
authors.lastname: Zaitsev