title: trans-(Pyrimidine-2-thiol-ato-κN,S)[tris-(2-amino-ethyl)amine-κN,N',N'',N''']cobalt(III) chloride hexa-fluoridophosphate.
abstract: In the title compound, [Co(C(4)H(3)N(2)S)(C(6)H(18)N(4))](Cl)PF(6), the Co(III) ion is coordinated by a tripod-like tetra-dentate ligand and a monoanionic N,S-bidentate ligand in an approximately octa-hedral CoN(4)OS geometry. The anionic S atom of the pyrimidine-2-thiol-ate (pymt) ligand is coordinated in the trans position to the primary amine N atom (Nprim) of the tris-(2-amino-ethyl)amine (tren) ligand. The crystal structure exhibits short inter-molecular N-H⋯N hydrogen bonds (N⋯N <3.2 Å), and inter-molecular N-H⋯Cl and C-H⋯F contacts, leading to the formation of an infinite two-dimensional network.
authors.affiliation: Department of Applied Science, Faculty of Science, Kochi University, Akebono-cho, Kochi 780-8520, Japan.
authors.forename: Keisuke
authors.initials: K
authors.lastname: Fujihara
authors.forename: Toshiaki
authors.initials: T
authors.lastname: Yonemura