title: catena-Poly[[(2,2'-bipyridine-κN,N')copper(I)]-μ-cyanido-κC:N-[(2,2'-bipyridine-κN,N')copper(I)]-μ-thio-cyanato-κS:N].
abstract: The title compound, [Cu(2)(CN)(SCN)(C(10)H(8)N(2))(2)](n), contains two crystallographically independent Cu(I) atoms, each in a distorted tetra-hedral geometry. Each Cu atom is coordinated by a bidentate chelating 2,2'-bipyridine ligand. A bridging cyanide anion links the two Cu(2,2'-bipyridine) units to form a binuclear unit. Adjacent binuclear units are connected by a thio-cyanate anion into a one-dimensional helical chain along [010]. The cyanide anion is disordered, with each site occupied by both C and N atoms in an occupancy ratio of 0.61 (5):0.39 (5). The S atom of the thio-cyanate anion is also disordered over two sites, with occupancy factors of 0.61 (3) and 0.39 (3). There are π-π inter-actions between the pyridyl rings of neighbouring chains [centroid-centroid distance = 3.82 (1) Å].
authors.affiliation: College of Mechanical and Material Engineering, Functional Materials Research Institue, Three Gorges University, Yichang 443002, People's Republic of China.
authors.forename: Jun
authors.initials: J
authors.lastname: Zhao
authors.forename: Wen-Wen
authors.initials: WW
authors.lastname: Dong
authors.forename: Dong-Sheng
authors.initials: DS
authors.lastname: Li
authors.forename: Qiu-Fen
authors.initials: QF
authors.lastname: He