title: Bis(N,N-dimethyl-formamide-κO)bis-(1-methyl-imidazole-2-carbaldehyde oximato-κN,O)manganese(III) perchlorate.
abstract: In the title compound, [Mn(C(5)H(6)N(3)O)(2)(C(3)H(7)NO)]ClO(4), the Mn(III) atom lies on the inversion centre of the centrosymmetric complex cation and has a distorted octa-hedral coordination geometry, formed by two N atoms and two O atoms from two 1-methyl-imidazole-2-carbaldehyde oximate ligands and two O atoms from two dimethyl-formamide ligands. Perchlorate acts as a counterion to balance the charge. The crystal structure of the title compound is stabilized by C-H⋯O hydrogen-bonding inter-actions.
authors.forename: Feng
authors.initials: F
authors.lastname: Wang
authors.forename: Jianming
authors.initials: J
authors.lastname: Zhang
authors.forename: Qirong
authors.initials: Q
authors.lastname: Wang
authors.forename: Shiying
authors.initials: S
authors.lastname: Huang