title: Phenyl 2,3,4-tri-O-benzyl-1-thio-α-d-mannopyran-oside monohydrate.
abstract: In the title compound, C(33)H(34)O(5)S·H(2)O, the mannopyran-oside ring adopts a chair conformation with the 2-α-thio-phenyl group occupying an axial position. One of the pendant benzyl groups is disordered over two sets of sites in a 0.5:0.5 ratio. In the crystal, the water mol-ecule makes two O-H⋯O hydrogen bonds to an adjacent sugar mol-ecule with the O atoms of the primary alcohol and ether groups acting as acceptors. At the same time, the OH group of the sugar makes a hydrogen bond to a water mol-ecule.
authors.affiliation: Department of Chemistry, University of Namur, 61 Rue de Bruxelles, B-5000 Namur, Belgium.
authors.forename: Maxime
authors.initials: M
authors.lastname: Durka
authors.forename: Bernadette
authors.initials: B
authors.lastname: Norberg
authors.forename: Yvain
authors.initials: Y
authors.lastname: Roué
authors.forename: Stéphane P
authors.initials: SP
authors.lastname: Vincent
authors.forename: Johan
authors.initials: J
authors.lastname: Wouters