title: Bis(ethyl-enedithio)tetra-thia-fulvalenium-tetra-chloridocobaltate(II) (3/2).
abstract: The structure of the electrochemically crystallized title compound, (C(10)H(8)S(8))(3)[CoCl(4)](2), consists of two types of bis-(ethyl-enedithio)tetra-thia-fulvalene (BEDT-TTF) radical cation stacks separated by sheets of tetra-hedral [CoCl(4)](2-) anions. One of the BEDT-TTF mol-ecules is generated by inversion. There are short S⋯S contacts between the stacks in the a direction and short C-H⋯Cl contacts between the radical cations and the anions.
authors.affiliation: School of Chemistry and Chemical Engineering, TaiShan Medical University, Tai'an 271016, People's Republic of China.
authors.forename: Fuqi
authors.initials: F
authors.lastname: Zhao
authors.forename: Ping
authors.initials: P
authors.lastname: Li
authors.forename: Xiaohui
authors.initials: X
authors.lastname: Zhu
authors.forename: Lihua
authors.initials: L
authors.lastname: Dong