title: The ansa-bridged cyclo-penta-dienyl titanium complex [{η-C(5)Me(4)CH(2)-C(NMe(2))=N}TiCl(2)].
abstract: The title complex, dichlorido[N,N-di-methyl-2-(η(5)-tetra-methyl-cyclo-penta-dien-yl)acetamidinido-κN']titanium(IV), [Ti(C(13)H(20)N(2))Cl(2)], exhibits an unusual ansa-bridged conformation. The cyclo-penta-dienyl ring and the mean plane of the Ti-N=C-C-C fragment form a dihedral angle of 88.08 (11)°.
authors.forename: Donglong
authors.initials: D
authors.lastname: Guo
authors.forename: Hong-Bo
authors.initials: HB
authors.lastname: Tong
authors.forename: Meisu
authors.initials: M
authors.lastname: Zhou