title: [5-(4-Bromo-phenoxy-meth-yl)-1,3,4-thia-diazole-2-thiol-ato]triphenyl-tin(IV).
abstract: In title compound, [Sn(C(6)H(5))(3)(C(9)H(6)BrN(2)OS(2))], the Sn atom is five-coordinated and the 1,3,4-thia-diazole-2-thiol ligand acts as an S,N-bidentate chelating ligand. The five-coordinate Sn(IV) atom forms four primary bonds, three to the phenyl groups and one to the S atom. Thus, the title complex has a distorted cis-trigonal bipyramidal geometry with the S atom and two C atoms occupying the equatorial plane, whereas the N atom and another C atom are in axial positions. In addition, there is a weak intramolecular Sn⋯N interaction. The crystal structure involves weak intra-molecular C-H⋯N and inter-molecular C-H⋯Br hydrogen bonding.
authors.forename: Zhi-Feng
authors.initials: ZF
authors.lastname: Wang
authors.forename: Gui-Long
authors.initials: GL
authors.lastname: Zhao
authors.forename: Lai-Jin
authors.initials: LJ
authors.lastname: Tian