title: trans-K(3)[TcO(2)(CN)(4)].
abstract: The structure of the title compound, tripotassium trans-tetra-cyanidodioxidotechnetate(V), is isotypic with its Re analogue. The [TcO(2)(CN)(4)](3-)trans-tetra-cyanido-dioxido-technetate anion has a slightly distorted octa-hedral configuration. The Tc atom is located on a center of inversion and is bound to two O atoms in axial and to four cyanide ligands in equatorial positions. The Tc-O distance is consistent with a double-bond character. The two potassium cations, one located on a center of inversion and one in a general position, reside in octa-hedral or tetra-hedral environments, respectively. K⋯O and K⋯N inter-actions occur in the 2.7877 (19)-2.8598 (15) Å range.
authors: Sayandev
authors: S
authors: Chatterjee
authors: Andrew S
authors: AS
authors: Del Negro
authors: Matthew K
authors: MK
authors: Edwards
authors: Brendan
authors: B
authors: Twamley
authors: Jeanette A
authors: JA
authors: Krause
authors: Samuel A
authors: SA
authors: Bryan
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