title: RAFT Polymerization Meets Coordination Chemistry: Synthesis of a Polymer-Based Iridium(III) Emitter.
abstract: A synthetic approach toward the synthesis of well-defined copolymers with attached phosphorescent iridium(III) emitters is presented. A reactive µ-hydroxy-bridged precursor complex has been utilized to coordinate suitable ligand sites of a methacrylate-based copolymer. The starting copolymer has been synthesized via the reversible addition fragmentation chain transfer (RAFT) polymerization technique. Using a reactive complex species, the coordination reaction at the copolymer could be performed under very mild conditions in the absence of any supporting additives.
authors: Dutch Polymer Institute (DPI), P. O. Box 902, 5600 AX Eindhoven, The Netherlands; Laboratory of Macromolecular Chemistry and Nanoscience, Eindhoven University of Technology, P. O. Box 513, 5600 MB Eindhoven, The Netherlands.
authors: Christoph
authors: C
authors: Ulbricht
authors: Caglar Remzi
authors: CR
authors: Becer
authors: Andreas
authors: A
authors: Winter
authors: Ulrich S
authors: US
authors: Schubert