title: (η-Cyclo-penta-dien-yl)[(1,2,3,4,4a,12a-η)-naphtho-[2,3-b][1,4]benzodioxine]iron(II) hexa-fluoridophosphate.
abstract: At 296 (2) K, both complexed rings in the iron(II) complex cation of the title salt, [Fe(C(5)H(5))(C(16)H(10)O(2))]PF(6), are almost parallel [dihedral angle between planes = 2.4 (3)°]. The quaternary C atoms of the complexed arene ring are located at the longest distance from the Fe atom, with Fe-C distances of 2.112 (4) and 2.105 (3) Å, which are slightly longer than the average Fe-C distance for this ring (2.083 Å). The Fe ion is located 1.660 (1) and 1.543 (1) Å, respectively, from the cyclo-penta-dienyl and the complexed arene ring.
authors: Department of Chemistry, Saint Mary's University, Halifax, Nova Scotia, Canada B3H 3C3.
authors: Arthur D
authors: AD
authors: Hendsbee
authors: Jason D
authors: JD
authors: Masuda
authors: Adam
authors: A
authors: Piórko
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 26;66(Pt 7):o1850
references: 21588048