title: Tetra-aqua-{1-[(1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-1,2,4-triazole}sulfato-zinc(II) dihydrate.
abstract: In the title complex, [Zn(SO(4))(C(9)H(8)N(6))(H(2)O)(4)]·2H(2)O, the Zn(II) ion is six-coordinated by one N atom from a 1-[(1H-1,2,3-benzotriazol-1-yl)meth-yl]-1H-1,2,4-triazole ligand and five O atoms from one monodentate sulfate anion and four water mol-ecules in a distorted octa-hedral geometry. The sulfate tetra-hedron is rotationally disordered over two positions in a 0.618 (19):0.382 (19) ratio. In the crystal, adjacent mol-ecules are linked through O-H⋯O and O-H⋯N hydrogen bonds involving the cation, the anion, and the coordinated and uncoordinated water mol-ecules into a three-dimensional network.
authors: Yan-Zhi
authors: YZ
authors: Wang
authors: Xiao-Kun
authors: XK
authors: Li
authors: Huai-Xia
authors: HX
authors: Yang
authors: Wan
authors: W
authors: Zhou
authors: Xiang-Ru
authors: XR
authors: Meng
references: Inorg Chem. 2005 Oct 3;44(20):6998-7008
references: 16180862
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677