title: (2,2'-Bipyridine-κN,N')chlorido(1,4,7-trithia-cyclo-nonane-κS,S',S'')ruthenium(II) nitrate monohydrate.
abstract: In the title compound, [RuCl(C(10)H(8)N(2))(C(6)H(12)S(3))]NO(3)·H(2)O or [RuCl(bpy)([9]aneS(3))]NO(3)·H(2)O, ([9]aneS(3) is 1,4,7-tri-thia-cyclo-nonane and bpy is 2,2'-bipyridine), the Ru(II) cation has a slightly distorted octa-hedral environment composed of three facially coordinated S atoms from ([9]aneS(3)), two N atoms from bpy and a chloride anion. The nitrate counter-ion and the water mol-ecule of crystallization are engaged in O-H⋯O hydrogen-bonding inter-actions, leading to a supra-molecular chain running parallel to the c axis.
authors: Department of Chemistry, University of Aveiro, CICECO, 3810-193 Aveiro, Portugal.
authors: José A
authors: JA
authors: Fernandes
authors: Filipe A
authors: FA
authors: Almeida Paz
authors: Maria João P
authors: MJ
authors: Mota
authors: Susana S
authors: SS
authors: Braga
authors: Teresa M
authors: TM
authors: Santos
references: Dalton Trans. 2009 Nov 28;(44):9812-9
references: 19885528
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Biometals. 2009 Jun;22(3):541-56
references: 19205901
references: Acta Crystallogr B. 1999 Dec 1;55(Pt 6):1030-1043
references: 10927445
references: J Inorg Biochem. 2008 May-Jun;102(5-6):1120-33
references: 18279961