title: Bis(dimethyl sulfoxide)-hydridobis(triphenyl-phosphane)cobalt(I).
abstract: The title compound, [CoH(C(18)H(15)P)(2)(C(2)H(6)OS)(2)], was synthesized by the reaction of chloridotris(triphenyl-phosphane)cobalt(I), [ClCo(PPh(3))(3)], in the presence of one equivalent potassium hydridotris(pyrazol-yl)borate in dimethyl sulfoxide. The structure displays a distorted trigonal-pyramidally coordinated cobalt(I) atom, with two phosphane ligands and one DMSO ligand in the equatorial plane. The coordination is completed by one further DMSO ligand and the anionic hydride in the axial positions.
authors: Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.
authors: Marko
authors: M
authors: Hapke
authors: Nico
authors: N
authors: Weding
authors: Anke
authors: A
authors: Spannenberg
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677