title: [2,3,7,8,13,14,17,18-Octa-kis(ethyl-sulfan-yl)-5,10,15,20-porphyrazinato]zinc(II).
abstract: In the title compound, [Zn(C(32)H(40)N(8)S(8))], the Zn(II) ion is coordinated by four N atoms in a slightly distorted square-planar environment. In addition, there is a Zn⋯S contact involving a symmetry-related S atom which, when considered, forms a pseudo-square-pyramidal coordination with respect to the Zn(II) ion. Three of the ethyl groups are disordered over two sites with occupancy ratios of 0.841 (10):0.159 (10), 0.802 (10):0.198 (10) and 0.457 (13):0.543 (13). Weak intra-molecular C-H⋯N and C-H⋯S inter-actions contribute to the stability of the mol-ecular conformation. Inter-molecular C-H⋯S contacts, weak C-H⋯π inter-actions and π-π stacking inter-actions [centroid-centriod distances = 3.832 (4) and 3.850 (5) Å] contribute to the stabilization of the crystal structure.
authors: Mehmet
authors: M
authors: Akkurt
authors: Naciye Yılmaz
authors: NY
authors: Coşkun
authors: Fatma Aytan
authors: FA
authors: Kılıçaslan
authors: Sabiha Manav
authors: SM
authors: Yalçın
authors: Orhan
authors: O
authors: Büyükgüngör
authors: Ahmet
authors: A
authors: Gül
references: Inorg Chem. 2000 Apr 3;39(7):1618-20
references: 12526477
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677