title: trans-Chlorido{3-chloro-2-[(1-naphth-yl)imino-meth-yl]phenyl-κC,N}bis-(trimethyl-phosphane)nickel(II).
abstract: The title compound, [Ni(C(17)H(11)ClN)Cl(C(3)H(9)P)(2)], was obtained as a product of the reaction of [Ni(PMe(3))(4)] with a molar equivalent of 2,6-dichloro-N-naphthyl-benzaldehyde-amine in diethyl ether. The τ parameter is 0.3, indicating that the coordination geometry is square-pyramidal. The Ni(II) atom lies in the center of a square pyramidal in which one C, one Cl and two P atoms form the basal plane, with the imine N atom in an apical position. Two P-atom donors are located in trans positions.
authors: Ruixia
authors: R
authors: Cao
authors: Hongjian
authors: H
authors: Sun
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677