title: 4'-Chloro-biphenyl-3-yl 2,2,2-trichloro-ethyl sulfate.
abstract: The title compound, C(14)H(10)Cl(4)O(4)S, is a 2,2,2-trichloro-ethyl-protected precursor of 4'-chloro-biphenyl-3-yl sulfate, a sulfuric acid ester of 4'-chloro-biphenyl-3-ol. The C(aromatic)-O and O-S bond lengths of the C(aromatic)-O-S unit are comparable to those in structurally analogous biphenyl-4-yl 2,2,2-trichloro-ethyl sulfates with no electro-negative chlorine substituent in the benzene ring with the sulfate ester group. The dihedral angle between the aromatic rings is 27.47 (6)°.
authors: Xueshu
authors: X
authors: Li
authors: Sean
authors: S
authors: Parkin
authors: Michael W
authors: MW
authors: Duffel
authors: Larry W
authors: LW
authors: Robertson
authors: Hans-Joachim
authors: HJ
authors: Lehmler
references: Chem Biol Interact. 2006 Feb 25;159(3):235-46
references: 16413005
references: Environ Health Perspect. 1994 May;102(5):464-9
references: 8593850
references: Chemosphere. 2002 Jan;46(3):485-8
references: 11829405
references: Chem Res Toxicol. 2006 Nov;19(11):1420-5
references: 17112228
references: Environ Int. 2010 Nov;36(8):843-8
references: 19345419
references: Drug Metab Dispos. 2009 May;37(5):1065-72
references: 19196841
references: Environ Sci Technol. 2010 Apr 15;44(8):2876-83
references: 20384379
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Chemosphere. 2008 Feb;70(9):1694-8
references: 17723240
references: Acta Crystallogr Sect E Struct Rep Online. 2008 Nov 29;64(Pt 12):o2464
references: 21581432
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 14;66(Pt 5):o1073
references: 21579128
references: Environ Sci Technol. 2010 May 15;44(10):3732-8
references: 20426459
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Jun 09;66(Pt 7):o1615-6
references: 21587847
references: Aquat Toxicol. 2006 Jun 15;78(2):176-85
references: 16621064