title: trans-Dichlorido-bis-[tris(4-meth-oxy-phenyl)-phosphane]palladium(II) toluene solvate.
abstract: In the title compound, trans-[PdCl(2){P(4-MeOC(6)H(4))(3)}(2)]·C(7)H(8), the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square planar geometry. The Pd-P and Pd-Cl bond lengths are 2.3409 (4) and 2.2981 (4) Å, respectively. An intra-molecular C-H⋯Cl hydrogen bond occurs. In the crystal, weak C-H⋯O inter-actions are observed between the aromatic rings of adjacent mol-ecules. The toluene solvate molecule is equally disordered over two sets of sites.
authors: Research Centre for Synthesis and Catalysis, Department of Chemistry, University of Johannesburg, PO Box 524 Auckland Park, Johannesburg, 2006, South Africa.
authors: Alfred
authors: A
authors: Muller
authors: Reinout
authors: R
authors: Meijboom
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Acta Crystallogr B. 2010 Feb;66(Pt 1):69-75
references: 20101085