title: (2SR,3SR)-Isopropyl 3-{[dimeth-yl(phenyl)-sil-yl]meth-yl}-2-hy-droxy-2-vinyl-pent-4-enoate.
abstract: The relative configuration of the title compound, C(19)H(28)O(3)Si, which was synthesized using a dienolate-[2,3]-Wittig rearrangement, was corroborated by single-crystal X-ray diffraction analysis. The Si-C bond distances are in the range 1.858 (2)-1.880 (2) Å and an intra-molecular O-H⋯O hydrogen bond helps to stabilize the mol-ecular conformation.
authors: Fakultät Chemie, Technische Universität Dortmund, Otto-Hahn-Strasse 6, 44221 Dortmund, Germany.
authors: Bjoern
authors: B
authors: Nelson
authors: Markus
authors: M
authors: Schürmann
authors: Hans
authors: H
authors: Preut
authors: Martin
authors: M
authors: Hiersemann
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55
references: 19171970