title: (4-tert-Butyl-pyridine)-chlorido[hydro-tris-(3,5-dimethyl-pyrazol-1-yl)borato]nitro-sylmolybdenum(I) dichloro-methane monosolvate.
abstract: In the title compound, [Mo(C(15)H(22)BN(6))Cl(NO)(C(9)H(13)N)]·CH(2)Cl(2), the Mo(I) atom adopts a distorted MoClN(5) octa-hedral geometry with the hydro-tris-(3,5-dimethyl-pyrazol-yl)borate anion in an N,N',N''-tridentate tripodal (facial) coordination mode. A 4-tert-butyl-pyrine ligand, chloride anion and a nitrosyl cation complement the coodination of the Mo(I) atom and an intra-molecular C-H⋯Cl hydrogen bond helps to stabilize the configuration of the complex mol-ecule. The packing is stabilized by an inter-molecular C-H⋯Cl hydrogen bond involving the complex mol-ecule and the CH(2)Cl(2) solvent mol-ecule.
authors: School of Chemistry, University of Bristol, Cantock Close, BS8 ITS Bristol, England.
authors: Mohammad B
authors: MB
authors: Kassim
authors: Jon A
authors: JA
authors: McCleverty
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