title: Monoclinic form of (cyanato-κN){2,2'-[ethane-1,2-diylbis(nitrilo-methyl-idyne)]diphenolato-κO,N,N',O'}manganese(III).
abstract: The title compound, [Mn(C(16)H(14)N(2)O(2))(NCO)], is a monoclinic polymorph of the previously published ortho-rhom-bic form [Lu et al. (2006 ▶). Inorg. Chem.45, 3538-3548]. The Mn(III) ion is chelated by a tetra-dentate Schiff base ligand and coordinated by the N atom of a cyanate ligand in a distorted square-pyramidal arrangement. In the crystal, there are short inter-molecular Mn⋯O(phenolate) distances of 2.752 (3) Å between pairs of inversion-related mol-ecules.
authors: College of Chemical Engineering, Shandong University of Technology, Zibo 255049, People's Republic of China.
authors: Daopeng
authors: D
authors: Zhang
references: Inorg Chem. 2006 May 1;45(9):3538-48
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