title: Direct Synthesis of Poly(dimethylsiloxane) Copolymers with TPE-Properties via CuAAC (Click Chemistry).
abstract: Poly(dimethylsiloxane) copolymers were synthesized directly from AA/BB monomers employing a CuAAC reaction (click chemistry) in a polyaddition approach. Using organic dialkynes and oligo(siloxane)s end-functionalized with azide moieties it was possible to obtain siloxane-based copolymers with TPE properties by click chemistry for the first time. As seen from DSC experiments, properties were strongly dependent on the incorporated organic comonomer.
authors: Institut für Siliciumchemie, WACKER-Lehrstuhl für Makromolekulare Chemie, Technische Universität München, Lichtenbergstr. 4, 85748 Garching b. München, Germany.
authors: Udo
authors: U
authors: Schmidt
authors: Philip C
authors: PC
authors: Zehetmaier
authors: Bernhard
authors: B
authors: Rieger