title: Intrinsic impurity-band Stoner ferromagnetism in C60Hn.
abstract: We identify Stoner ferromagnetism in fcc C60H(n) (n=odd) by using a local density approximation in the framework of the density functional theory. Hydrogen chemisorption on fullerenes creates quasilocalized π electrons on the fullerene surface, overlapping of their wave functions giving rise to a narrow half filled impurity band in the fcc C60H(n). The Stoner-type ferromagnetic exchange between the itinerant electrons leads to spin-split impurity bands. The magnetic moment per C60H(n) molecule is 1  μ(B) (for n=odd) or 0 (for n=even, including zero), only one of the hydrogens contributing to the spin-split states. Direct overlapping of the quasilocalized π-electron orbitals is essential for the ferromagnetism.
authors: Department of Physics and Institute for Nano Science, Korea University, Seoul, Korea.
authors: Kyu Won
authors: KW
authors: Lee
authors: Cheol Eui
authors: CE
authors: Lee