title: [2-(Diphenyl-phosphan-yl)benzene-thiol-ato-κP,S](pyridine-2-thiol-ato-κS)(triphenyl-phosphine-κP)palladium(II).
abstract: In the title compound, [Pd(C(5)H(4)NS)(C(18)H(14)PS)(C(18)H(15)P)], the Pd(II) atom has a slightly distorted square-planar environment. Two coordination sites are occupied by a P,S-chelating 2-(diphenyl-phosphan-yl)benzene-thiol-ate ligand and the other two by a P atom from a triphenyl-phosphine ligand and an S atom from a pyridine-2-thiol-ate ligand, exhibiting a trans arrangement of the two P-donor atoms. In the crystal structure, weak intra- and inter-molecular C-H⋯π and π-π inter-actions are observed. The pyridyl ring is equally disordered over two positions.
authors: Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México 04510, Mexico.
authors: Raúl
authors: R
authors: Ríos-Sanchez
authors: Simón
authors: S
authors: Hernández-Ortega
authors: David
authors: D
authors: Morales-Morales
authors: Alcives
authors: A
authors: Avila-Sorrosa
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