title: trans-Bromido(pyrimidinyl-κC)bis-(triphenyl-phosphane-κP)palladium(II).
abstract: In the title complex, [PdBr(C(4)H(3)N(2))(C(18)H(15)P)(2)], the geometry around the Pd(II) atom is distorted square-planar with the Pd(II) atom displaced by 0.0150 (5) Å from the least-squares BrP(2)C plane. Two PPh(3) ligands are in trans positions [P-Pd-P = 176.743 (17)°], while the pyrimidinyl ligand and Br atom are trans to one another [C-Pd-Br = 176.56 (5)°]. Structural parameters from NMR, IR and mass spectra are in agreement with the crystal structure of the title compound.
authors: Gene-Hsiang
authors: GH
authors: Lee
authors: Hsiao-Fen
authors: HF
authors: Wang
authors: Kuang-Hway
authors: KH
authors: Yih
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677