title: Dichlorido[(S)-N-(1-phenyl-ethyl-idene)-1-(pyridin-2-yl)ethanamine-κN,N']zinc(II) dichloro-methane solvate.
abstract: In the title compound, [ZnCl(2)(C(15)H(16)N(2))]·CH(2)Cl(2), the Zn(II) atom has a distorted tetra-hedral coordination by two Cl atoms and two N atoms from the organic ligand [the average Zn-N and Zn-Cl bond lengths are 2.060 (4) Å and Zn-Cl = 2.179 (16) Å, respectively]. The dihedral angle between the N-Zn-N and Cl-Zn-Cl planes is 89.9 (1)°. The phenyl ring forms a dihedral angle of 40.6 (5)° with the imine plane.
authors: Department of Chemistry, Kyungpook National University, Taegu, 702-701, Republic of Korea.
authors: Saira
authors: S
authors: Nayab
authors: Seung-Min
authors: SM
authors: Paek
authors: Jong Hwa
authors: JH
authors: Jeong
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Acta Crystallogr Sect E Struct Rep Online. 2008 Feb 06;64(Pt 3):m457
references: 21201852