title: Electocatalytic water oxidation by cobalt(III) hangman β-octafluoro corroles.
abstract: Cobalt hangman corrole, bearing β-octafluoro and meso-pentafluorophenyl substituents, is an active water splitting catalyst. When immobilized in Nafion films, the turnover frequencies for the 4e(-)/4H(+) process at the single cobalt center of the hangman platform approach 1 s(-1). The pH dependence of the water splitting reaction suggests a proton-coupled electron transfer (PCET) catalytic mechanism.
authors: Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139-4307, USA.
authors: Dilek K
authors: DK
authors: Dogutan
authors: Robert
authors: R
authors: McGuire
authors: Daniel G
authors: DG
authors: Nocera