title: [Bis(diphenyl-phosphan-yl)dimethyl-silane-κP,P']tetra-carbonyl-chromium(0).
abstract: The title compound, [Cr(C(26)H(26)P(2)Si)(CO)(4)], was obtained by the reaction of Ph(2)PSiMe(2)PPh(2) with Cr(CO)(6) in refluxing toluene by ligand exchange. The CrC(4)P(2) coordination geometry at the Cr atom is distorted octa-hedral, with a P-Cr-P bite angle of 80.27 (1)°.
authors: Leibniz-Institut für Katalyse e. V. an der Universität Rostock, Albert-Einstein-Strasse 29a, 18059 Rostock, Germany.
authors: Normen
authors: N
authors: Peulecke
authors: Stephan
authors: S
authors: Peitz
authors: Bernd H
authors: BH
authors: Müller
authors: Anke
authors: A
authors: Spannenberg
authors: Uwe
authors: U
authors: Rosenthal
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677