title: [N-(3-Meth-oxy-2-oxidobenzyl-idene-κO)leucinato-κN,O](1,10-phenanthroline-κN,N')copper(II) monohydrate.
abstract: The asymmetric unit of the title complex, [Cu(C(14)H(17)NO(4))(C(12)H(8)N(2))]·H(2)O, contains two independent Cu(II) complex mol-ecules and two uncoordinated water mol-ecules. In each complex mol-ecule, the Cu atom is O,N,O'-chelated by the tridentate Schiff base ligand and N,N'-chelated by the 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. The Cu-N bond distances in the apical directions are 2.298 (4) and 2.268 (4) Å. In the crystal, inter-molecular O-H⋯O and C-H⋯O hydrogen bonds together with C-H⋯π inter-actions result in a three-dimensional supra-molecular structure.
authors: School of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.
authors: Lei
authors: L
authors: Huang
authors: Jianfang
authors: J
authors: Dong
authors: Buqin
authors: B
authors: Jing
authors: Lianzhi
authors: L
authors: Li
authors: Daqi
authors: D
authors: Wang
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 30;64(Pt 5):m745-6
references: 21202263