title: catena-Poly[[{2-[(2-hy-droxy-eth-yl)imino-meth-yl]-6-meth-oxy-phenolato}copper(II)]-μ-thio-cyanato].
abstract: In the title thio-cyanate-bridged polynuclear copper(II) complex, [Cu(C(10)H(12)NO(3))(NCS)](n), the Cu atom is five-coordinated in a square-pyramidal geometry, with one phenolato O, one imino N and one hy-droxy O atom of a Schiff base ligand and one thio-cyanato N atom defining the basal plane, and with one thio-cyanato S atom occupying the apical position. In the crystal structure, pairs of adjacent complex mol-ecules are linked through inter-molecular O-H⋯O hydrogen bonds into dimers. The dimers are further linked via Cu⋯S inter-actions, forming two-dimensional layers parallel to the bc plane.
authors: College of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan, Henan 467000, People's Republic of China.
authors: Ling-Wei
authors: LW
authors: Xue
authors: Gan-Qing
authors: GQ
authors: Zhao
authors: Yong-Jun
authors: YJ
authors: Han
authors: Yun-Xiao
authors: YX
authors: Feng
references: Eur J Med Chem. 2008 Jan;43(1):160-5
references: 17532543
references: Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 28;65(Pt 12):m1692-3
references: 21578697
references: Acta Crystallogr Sect E Struct Rep Online. 2009 May 07;65(Pt 6):m617
references: 21582987
references: Acta Crystallogr Sect E Struct Rep Online. 2010 May 26;66(Pt 6):m711-2
references: 21579344
references: Bioorg Med Chem. 2006 Jun 1;14(11):3758-65
references: 16480879
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Eur J Med Chem. 2006 Jan;41(1):147-53
references: 16271421
references: Bioorg Med Chem. 2008 Feb 15;16(4):1822-31
references: 18248993
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Jan 09;66(Pt 2):m136
references: 21579618