title: Phase diagram of the Pluronic L64-H2O micellar system from mechanical spectroscopy.
abstract: The linear viscoelastic properties of aqueous Pluronic L64 solutions have been investigated at high copolymer concentrations (25-62 wt%) using our modified low-frequency mechanical spectroscopy. The concentration-temperature phase diagram of the L64/H(2)O system was constructed by studying the evolution of the loss modulus and loss tangent as temperature is increased at a fixed frequency. A particular attention was focused on the dynamics approaching the beginning and ending points (39% and 60%) of the fusiform gel region in the phase diagram. The dynamics is found to have a similar viscoelastic behavior at the low and high concentrations, where a frequency scaling expected for a static percolated network is exhibited. Moreover, with increasing temperature, the system above the critical gel concentration undergoes a transition from a viscoelastic liquid to a solid gel through a percolated particle network. Therefore, our results suggest that the formation of the gel is dominated by the percolation of the particle clusters.
authors: Key Laboratory of Materials Physics, Institute of Solid State Physics, Chinese Academy of Sciences, P.O. Box 1129, Hefei, Anhui, PR China, 230031.
authors: Xuemao
authors: X
authors: Zhou
authors: Xuebang
authors: X
authors: Wu
authors: Huaguang
authors: H
authors: Wang
authors: Changsong
authors: C
authors: Liu
authors: Zhengang
authors: Z
authors: Zhu