title: Synthesis of Z-alkenyl phosphorus compounds through hydroalumination and carbocupration of alkynyl precursors.
abstract: The stereocontrolled synthesis of Z-alkenylphosphine-borane complexes is easily accomplished via the hydroalumination or carbocupration of alkynyl precursors. Z/E ratios are generally higher than 95/5. These reactions are stereocomplementary to our olefination approach.
authors: Department of Chemistry, Box 298860, Texas Christian University, Fort Worth, Texas 76129, USA.
authors: Stéphanie
authors: S
authors: Ortial
authors: Jean-Luc
authors: JL
authors: Montchamp