title: 1,3-Bis(2,6-diisopropyl-phen-yl)imidazolidinium tetra-phenyl-borate dichloro-methane disolvate.
abstract: The title compound, C(27)H(39)N(2) (+)·C(24)H(20)B(-)·2CH(2)Cl(2), is the first reported imidazolidinium cation with the sterically demanding 2,6-diisopropyl-phenyl groups in the 1,3-positions. The crystal structure is stabilized by weak inter-molecular C-H⋯π(arene) inter-actions. Due to the bulky nature of both the flanking 2,6-diisopropyl-phenyl substituents and the tetra-phenyl-borate counter-ion, anion inter-actions with the imidazolidinium H atom in the 2-position are not observed, also a first for this class of ortho-alkyl-substituted Arduengo-type carbene precursors.
authors: Department of Chemistry, Saint Mary's University, 923 Robie Street, Halifax, NS, Canada B3H 3C3.
authors: Nick A
authors: NA
authors: Giffin
authors: Arthur D
authors: AD
authors: Hendsbee
authors: Jason D
authors: JD
authors: Masuda
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 04;64(Pt 11):m1357
references: 21580818