title: Poly[bis-[μ-1,4-bis-(1,2,4-triazol-1-ylmeth-yl)benzene-κN:N]dichloridomanganese(II)].
abstract: The Mn(II) atom in the title coordination polymer, [MnCl(2)(C(12)H(12)N(6))(2)](n), lies on a center of inversion in a six-coordinate octa-hedral environment comprising four N-atom donors from four N-heterocyclic ligands and two chloride atoms. Bridging by the ligands results in a layer structure of a 14.79 (5) × 14.79 (5) Å (4,4) rhombic net topology, with the Mn(II) atoms all lying on a plane. The parallel layers stack in an ABCABC… manner through inter-layer C-H⋯N and C-H⋯Cl hydrogen bonds.
authors: Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Tianjin Normal University, Tianjin 300071, People's Republic of China.
authors: Bin
authors: B
authors: Ding
authors: Hong-Ai
authors: HA
authors: Zou
references: Science. 1999 Feb 19;283(5405):1148-50
references: 10024237
references: Chem Commun (Camb). 2005 May 14;(18):2333-5
references: 15877119
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677