title: (6-Hydroxy-2-{[2-(N-methyl-carbamo-thiol-yl)hydrazin-1-yl-idene-κN,S]meth-yl}-phenolato-κO)(triphenyl-phosphane-κP)nickel(II) chloride.
abstract: The deprotonated Schiff base ligand in the title salt, [Ni(C(9)H(10)N(3)O(2)S)(C(18)H(15)P)]Cl, functions as an N,O,S-chelating anion to the phosphine-coordinated nickel(II) atom, which exists in a distorted square-planar geometry. The hy-droxy group forms an intra-molecular O-H⋯O hydrogen bond. The two amino groups of the cation are hydrogen-bond donors to the chloride anion; the hydrogen bonds generate a chain structure running along the b axis.
authors: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
authors: Hana Bashir
authors: HB
authors: Shawish
authors: M Jamil
authors: MJ
authors: Maah
authors: Seik Weng
authors: SW
authors: Ng
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 11;66(Pt 9):m1074
references: 21588494