title: (4-Chloro-benzohydrazidato-κN',O)[2-(4-chloro-benzoyl-hydrazinyl-idene-κN,O)-3-phenyl-propionato(2-)-κO]oxidovanadium(V) methanol monosolvate.
abstract: The V(V) atom in the title compound, [V(C(7)H(6)ClN(2)O)(C(16)H(11)ClN(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoyl-hydrazidate anion and O,N,O'-chelated by the (benzoyl-hydrazinyl-idene)propionate dianion. The distorted octa-hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. The mononuclear and solvent mol-ecules are linked by N-H⋯O and O-H⋯O hydrogen bonds about a center of inversion, generating a dimer.
authors: Department of Chemistry, University of Malaya, 50603 Kuala Lumpur, Malaysia.
authors: Hon Wee
authors: HW
authors: Wong
authors: Kong Mun
authors: KM
authors: Lo
authors: Seik Weng
authors: SW
authors: Ng
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Acta Crystallogr Sect E Struct Rep Online. 2009 Mar 25;65(Pt 4):m422
references: 21582364
references: Acta Crystallogr Sect E Struct Rep Online. 2009 Jun 06;65(Pt 7):m718
references: 21582662