title: cis-Bis(1,10-phenanthroline-κN,N')bis-(thio-cyanato-κN)magnesium(II).
abstract: The title compound, [Mg(NCS)(2)(C(12)H(8)N(2))(2)], has been synthesized from the hydro-thermal reaction of MgCl(2), KSCN, 1,10-phenanthroline and H(2)O. Its structure is isotypic with the Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) analogues. The Mg(II) cation has a slightly distorted octa-hedral geometry containing four N atoms from two 1,10-phenanthroline mol-ecules and two N atoms from two thio-cyanate anions. The asymmetric unit contains one-half mol-ecule, and the complete complex has 2 symmetry.
authors: Department of Physics and Chemistry, Henan Polytechnic University, Jiaozuo, Henan 454000, People's Republic of China.
authors: Dan
authors: D
authors: Zhao
authors: Fei-Fei
authors: FF
authors: Li
authors: Jiao
authors: J
authors: Sha
references: Acta Crystallogr C. 2001 Aug;57(Pt 8):905-8
references: 11498608
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
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