title: Bis[N,N-bis-(diphenyl-phosphan-yl)cyclo-hexyl-amine-κP,P']platinum(II) bis-(hexa-fluorido-phosphate) dichloro-methane disolvate.
abstract: In the title compound, [Pt(C(30)H(31)NP(2))(2)](PF(6))(2)·2CH(2)Cl(2), the four-coordinated Pt(II) atom, situated on an inversion centre, exhibits a highly distorted square-planar geometry illustrated by the P-Pt-P bite angle of 70.76 (3)°. The cyclo-hexyl ring and one of the phenyl rings display 0.630 (7):0.37 (7) and 0.60 (2):0.40 (2) positional disorder, respectively. The dichloro-methane solvent mol-ecule displays 0.526 (4):0.474 (4) positional disorder. C-H⋯F hydrogen bonds stabilize the crystal packing.
authors: Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein 9300, South Africa.
authors: Ilana
authors: I
authors: Engelbrecht
authors: Hendrik G
authors: HG
authors: Visser
authors: Andreas
authors: A
authors: Roodt
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