title: Bis[μ-4-methyl-2-(2-pyridyl-methyl-sulfan-yl)pyrimidine-κN]bis-[(trifluoro-methanesulfonato-κO)silver(I)].
abstract: In the centrosymmetric dinuclear title complex, [Ag(2)(CF(3)SO(3))(2)(C(11)H(11)N(3)S)(2)], the Ag(I) atom is coordinated by two N atoms from two 4-methyl-2-(2-pyridyl-methyl-sulfan-yl)pyrimidine ligands and one O atom from a trifluoro-methane-sulfonate anion in a distorted T-type coordination geometry. The ligand adopts a bidentate bridging coordination mode through one pyridyl N atom and one pyrimidine N atom. In the crystal structure, π-π inter-actions are present between adjacent pyrimidine rings, with a centroid-to-centroid distance of 3.875 (7) Å.
authors: College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, People's Republic of China.
authors: Huan-Huan
authors: HH
authors: Wang
authors: Chao-Yan
authors: CY
authors: Zhang
authors: Yue
authors: Y
authors: Cui
authors: Qian
authors: Q
authors: Gao
authors: Ya-Bo
authors: YB
authors: Xie
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677