title: [2-(sec-Butyl-imino-meth-yl)quinoline]-chlorido(η-1-isopropyl-4-methyl-benzene)-ruthenium(II) hexa-fluorido-phosphate.
abstract: In the title compound, [RuCl(C(10)H(14))(C(14)H(16)N(2))]PF(6), the aromatic ring of the isopropyl-methyl-benzene fragment shows an η(6)-arene coordination to the ruthenium atom. Its coordination sphere is completed by a chloride ligand and 2-(sec-butyl-imino-meth-yl)quinoline. The dihedral angle between the η(6)-arene ring and the quinoline Schiff base is 45.64 (9)°. The sec-butyl substituent and the PF(6) (-) anion are disordered over two positions with ratios of 0.595 (11):0.405 (11) and 0.752 (8):0.248 (8), respectively.
authors: Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, México 04510, Mexico.
authors: José Luis
authors: JL
authors: Gárate-Morales
authors: Simón
authors: S
authors: Hernández-Ortega
authors: Juan Manuel
authors: JM
authors: Fernández-G
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677