title: Poly[[diaqua-(μ(2)-5,5-dioxodibenzo[b,d]thio-phene-3,7-dicarboxyl-ato)(μ(2)-ethyl-ene glycol)manganese(II)] dimethyl-acetamide solvate].
abstract: In the title complex, {[Mn(C(14)H(6)O(6)S)(C(2)H(6)O(2))(H(2)O)(2)]·C(4)H(9)NO}(n), the Mn(II) ion is six-coordinated in a trans-octa-hedral geometry by two carboxyl-ate O atoms from two 5,5-dioxodibenzo[b,d]thio-phene-3,7-dicarboxyl-ate (L) ligands in a monodentate mode, two O atoms from two ethyl-ene glycol (EG) mol-ecules and two aqua O atoms. The metal ions are linked by the EG and L ligands, forming two-dimensional coordination networks, which are associated into the three-dimensional structure through O-H⋯O hydrogen bonds.
authors: Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, People's Republic of China.
authors: Xiu-Chun
authors: XC
authors: Yi
authors: Li
authors: L
authors: Yan
authors: En-Qing
authors: EQ
authors: Gao
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Chemistry. 2009;15(18):4523-7
references: 19301330