title: Bis{2-[3-(dimethyl-ammonio)-propyl-imino-methyl-κN]-6-meth-oxy-phenolato-κO}bis-(thio-cyanato-κN)nickel(II).
abstract: The asymmetric unit of the title complex, [Ni(NCS)(2)(C(13)H(20)N(2)O(2))(2)], consists of two half-mol-ecules, both of which are completed by crystallographic inversion symmetry (Ni(2+) site symmetry = in both cases). Both metal ions are six-coordinated in distorted trans-NiO(2)N(4) geometries arising from two N,O-bidentate Schiff base ligands and two N-bonded thio-cyanate ions. The mol-ecular conformations are reinforced by two intra-molecular N-H⋯O hydrogen bonds.
authors: College of Chemistry and Chemical Engineering, Pingdingshan University, Pingdingshan Henan 467000, People's Republic of China.
authors: Ling-Wei
authors: LW
authors: Xue
authors: Gan-Qing
authors: GQ
authors: Zhao
authors: Yong-Jun
authors: YJ
authors: Han
authors: Li-Hua
authors: LH
authors: Chen
authors: Qin-Long
authors: QL
authors: Peng
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 18;66(Pt 10):m1274
references: 21587418
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 28;66(Pt 9):m1172-3
references: 21588561