title: Thermal isomerization of η6-arene ferradicarbolllides. Experimental proof for isolobal relation between (η6-arene)Fe and (η5-cyclopentadienyl)Co cluster units.
abstract: The heating of selected [1-(η(6)-arene)-closo-1,2,3-FeC(2)B(9)H(11)] complexes resulted in the thermal rearrangement and isolation of the corresponding 1,2,4-, 1,2,7-, and 1,2,8-cage isomers. Demonstrated here is a similar rearrangement and the NMR behaviour for isostructural [1-(η(5)-cyclopentadienyl)-closo-1,2,3-CoC(2)B(9)H(11)] compounds.
authors: Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, 250 68, Řež, Czech Republic.
authors: Josef
authors: J
authors: Holub
authors: Bohumil
authors: B
authors: Štíbr
authors: Mario
authors: M
authors: Bakardjiev
authors: Aleš
authors: A
authors: Růžička
authors: Zdeňka
authors: Z
authors: Padělková