title: Bis(4,6-dimethyl-pyrimidine-2-thiol-ato)dimethyl-tin(IV).
abstract: The asymmetric unit of the title complex, [Sn(CH(3))(2)(C(6)H(7)N(2)S)(2)], contains two independent mol-ecules with similar configurations. In each, the Sn(IV) cation is coordinated by two methyl and two 4,6-dimethyl-pyrimidine-2-thiol-ate anions in a distorted SnS(2)C(2) tetra-hedral geometry. In the two mol-ecules, the S-Sn-S bond angles are 87.70 (5) and 88.93 (4)°, while the C-Sn-C bond angles are 125.7 (3) and 125.9 (2)°. Weak C-H⋯N hydrogen bonding is present in the crystal structure.
authors: College of Chemistry and Chemical Engineering, Liaocheng University, Shandong 252059, People's Republic of China.
authors: Yang
authors: Y
authors: Shi
authors: Ru-Fen
authors: RF
authors: Zhang
authors: Chun-Lin
authors: CL
authors: Ma
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677