title: Ethyl 2-[(Z)-2-benzyl-hydrazin-1-yl-idene]-2-bromo-acetate.
abstract: In the title compound, C(11)H(13)BrN(2)O(2), the dihedral angle between the phenyl ring and the almost planar (r.m.s. deviation = 0.011 Å) C-C(Br)=N-N(H)- fragment is 74.94 (16)°. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, which generate C(6) chains propagating in [010]. Weak aromatic π-π stacking [centroid-centroid separation = 3.784 (3) Å] may also help to consolidate the packing.
authors: Qian-Jiao
authors: QJ
authors: Yang
authors: Dan
authors: D
authors: Liu
authors: Jian
authors: J
authors: Zuo
authors: Guo-Dong
authors: GD
authors: Hu
authors: Lin-Xiang
authors: LX
authors: Zhao
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Bioorg Med Chem Lett. 2008 Aug 15;18(16):4538-43
references: 18667305