title: (Ethanolato)[2,3,7,8,12,13,17,18-octa-ethylporphyrinato(2-)]iron(III).
abstract: The title compound, [Fe(C(2)H(5)O)(C(36)H(44)N(4))], contains a five-coordinate iron-porphyrin complex with an axial eth-oxy ligand. The iron(III) atom is displaced by 0.504 (2) Å towards the eth-oxy ligand from the 24-atom mean plane of the porphyrin. The average Fe-N(p) distance is 2.078 (2) Å and the Fe-O distance is 1.8232 (18) Å. The eth-oxy C atoms are disordered in a 0.581 (12):0.419 (12) ratio. The bond angles of the Fe-O-C linkage are 128.6 (3) and 130.4 (3)°, respectively, for the major and minor occupancy C atoms.
authors: Department of Chemistry and Biochemistry, University of Oklahoma, 101 Stephenson Parkway, Norman, OK 73019-5251 USA.
authors: Lin
authors: L
authors: Cheng
authors: Nan
authors: N
authors: Xu
authors: Douglas R
authors: DR
authors: Powell
authors: George B
authors: GB
authors: Richter-Addo
references: Cell Mol Life Sci. 2004 Jan;61(2):192-208
references: 14745498
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677