title: [1,1-(Butane-1,4-diyl)-2,3-dicyclohexylguanidinato]dimethylaluminum(III).
abstract: In the crystal structure of the title complex, [Al(CH(3))(2)(C(17)H(30)N(3))], the Al(III) cation is coordinated by two methyl ligands and two N atoms from the guanidinato ligand in a distorted tetra-hedral geometry. The dihedral angle between the CN(2) and AlC(2) planes is 85.37 (2)°. The two N atoms of the guanidinato ligand exhibit an almost uniform affinity to the metal atom.
authors: Department of Chemistry, Taiyuan Normal University, Taiyuan 030031, People's Republic of China.
authors: Haoyang
authors: H
authors: Li
authors: Yonggang
authors: Y
authors: Xiang
authors: Hongfei
authors: H
authors: Han
references: J Am Chem Soc. 2007 Oct 24;129(42):12734-8
references: 17910445
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677