title: 2-(Methyl-sulfin-yl)benzamide.
abstract: In the crystal of the title compound, C(8)H(9)NO(2)S, synthesized by the oxidation of 2-(methyl-sulfan-yl)benzamide using NaOCl with 2,2,6,6-tetra-methyl-piperidyl-1-oxy (TEMPO) as the catalyst, mol-ecules are linked via inter-molecular N-H⋯O(amide) hydrogen bonds, forming centrosymmetric amide-amide dimers which are extended into a two-dimensional lamellar framework parallel to (100) through amide-sulfinyl N-H⋯O hydrogen bonds. The benzene ring forms a dihedral angle of 25.6 (2)° with the amide group.
authors: College of Food Science and Biotechnology, Zhejiang Gongshang University, Hangzhou 310035, People's Republic of China.
authors: Zhou
authors: Z
authors: Yan
references: Chem Commun (Camb). 2009 Jun 28;(24):3536-8
references: 19521599
references: Org Lett. 2005 Feb 17;7(4):625-8
references: 15704910
references: Clin Neuropharmacol. 2002 Mar-Apr;25(2):111-4
references: 11981239
references: Chemistry. 2008;14(15):4631-9
references: 18381722
references: J Am Chem Soc. 2003 Mar 12;125(10):3035-45
references: 12617670
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677