title: mer-[3-Phenyl-5-(2-pyridyl-κN)-1,2,4-triazol-1-ido-κN]bis-(2-quinolylphenyl-κC,N)iridium(III) deuterochloro-form disolvate.
abstract: In the title compound, [Ir(C(13)H(9)N(4))(C(15)H(10)N)(2)]·2CDCl(3), the coordination at iridium is octa-hedral, but with narrow ligand bite angles ranging from 74.85 (8) to 83.99 (8)°. The bond lengths at iridium show the expected trans influence, with Ir-N trans to C being appreciably longer than trans to N. The chelate rings are mutually perpendicular to a reasonable approximation [interplanar angles ranging from 77.79 (6) to 83.93 (7)°]. All ligands are approximately planar; the maximum inter-planar angles within ligands are ca 12°. One CDCl(3) solvent molecule is severly disordered and was excluded from the refinement.
authors: Peter G
authors: PG
authors: Jones
authors: Andreas
authors: A
authors: Freund
authors: Marc
authors: M
authors: Debeaux
authors: Wolfgang
authors: W
authors: Kowalsky
authors: Hans-Hermann
authors: HH
authors: Johannes
references: Inorg Chem. 2008 Nov 17;47(22):10509-21
references: 18939823
references: Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 16;66(Pt 1):m66-7
references: 21579961
references: Acta Crystallogr D Biol Crystallogr. 2009 Feb;65(Pt 2):148-55
references: 19171970
references: J Am Chem Soc. 2005 Sep 14;127(36):12438-9
references: 16144361
references: Chem Commun (Camb). 2004 Aug 7;(15):1774-5
references: 15278180
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Inorg Chem. 2001 Mar 26;40(7):1704-11
references: 11261983
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Aug 11;66(Pt 9):m1088-9
references: 21588505