title: (Di-2-pyridyl-amine)-(methanol)sulfato-copper(II).
abstract: The title complex, [Cu(SO(4))(C(10)H(9)N(3))(CH(3)OH)], is a mononuclear species with the Cu(II) ion in a Jahn-Teller-distorted '4 + 1' square-pyramidal geometry. The basal plane is defined by the pyridyl N-atom donors of the bipyridyl-amine (bpa) ligand and two O-atom donors of the sulfate ligand. The coordination geometry is completed by the axial coordination of a methanol O-atom donor. The axial bond length displays the usual elongation: Cu-O(axial) = 2.168 (2), Cu-O(basal) = 2.016 (2) (average) and Cu-N(basal) = 1.951 (3) Å (average). In the crystal structure, the complex mol-ecules are linked through N-H⋯O and O-H⋯O hydrogen bonds into chains along [100].
authors: Department of Chemistry, Syracuse University, Syracuse, New York 13244, USA.
authors: Paul
authors: P
authors: Deburgomaster
authors: Jon
authors: J
authors: Zubieta
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 04;66(Pt 10):m1199-200
references: 21587360
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 04;66(Pt 10):m1197
references: 21587358
references: Angew Chem Int Ed Engl. 1999 Sep;38(18):2638-2684
references: 10508356
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 04;66(Pt 10):m1195-6
references: 21587357
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 04;66(Pt 10):m1198
references: 21587359
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 04;66(Pt 10):m1201-2
references: 21587361