title: (Methanol-κO)(perchlorato-κO)bis-(triphenyl-phosphine-κP)silver(I).
abstract: In the title complex, [Ag(ClO(4))(CH(3)OH)(C(18)H(15)P)(2)], the angles around the central Ag(+) ion indicate that it is in a distorted tetrahedral coordination. The coordination sphere of silver is formed by two P atoms of two triphenyl-phosphine ligands, one O atom of a perchlorate anion and one O atom of a methanol mol-ecule. The crystal structure is stablized by a bifurcated inter-molecular O-H⋯O hydrogen bond, involving the O-H donor from methanol and two acceptor O atoms from the perchlorate anion, so forming a zigzag chain propagating in [010].
authors: Li-Na
authors: LN
authors: Cui
authors: Qiong-Hua
authors: QH
authors: Jin
authors: Ke-Yi
authors: KY
authors: Hu
authors: Cun-Lin
authors: CL
authors: Zhang
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 03;66(Pt 8):m871
references: 21588119
references: Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 19;65(Pt 9):m1096-7
references: 21577447
references: Inorg Chem. 2005 Oct 31;44(22):7833-45
references: 16241133
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Inorg Chem. 2002 Dec 16;41(25):6633-45
references: 12470058