title: Magnetic properties of a manganese(III) Chain with monoatomic bridges: catena-MnF(salen).
abstract: In the solid state, MnF(salen) forms chains wherein fairly linear fluoride bridges between high-spin Mn(III) centers are observed. We interpret the magnetic properties of these chains by use of the classical Fisher model and by use of the high-temperature expansion approach, as well as by exact matrix diagonalization of the spin Hamiltonian, of model rings. In solution, electron paramagnetic resonance shows the chains to be symmetrically cleaved to monomeric MnF(salen).
authors: Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 Copenhagen, Denmark.
authors: Torben
authors: T
authors: Birk
authors: Kasper S
authors: KS
authors: Pedersen
authors: Stergios
authors: S
authors: Piligkos
authors: Christian Aa
authors: CA
authors: Thuesen
authors: Högni
authors: H
authors: Weihe
authors: Jesper
authors: J
authors: Bendix