title: catena-Poly[[aqua-(5,5'-dimethyl-2,2'-bipyridine-κN,N')copper(II)]-μ-2,2'-oxydibenzoato-κO:O'].
abstract: In the title compound, [Cu(C(14)H(8)O(5))(C(12)H(12)N(2))(H(2)O)](n), the Cu(II) ion is penta-coordinated in a square-pyramidal geometry. Two N atoms of the chelating 5,5'-dimethyl-2,2'-bipyridine (dbp) ligand and two O atoms of two different 2,2'-oxydibenzoic (odb) ligands occupy the basal plane while the water O atom completes the square-pyramidal geometry at the apical site. The non-water N(2)O(2) donor atoms are nearly coplanar, with a mean deviation from the least-squares plane of 0.0518 (11) Å and the Cu atom is displaced by 0.1507 (11) Å from this plane towards the apical water O atom. Further coordination via the 2,2'-oxydibenzoate anions forms a one-dimensional coordination polymer extending parallel to [010]. In the crystal structure, O-H⋯O hydrogen bonds link the mol-ecules into a two-dimensional supra-molecular structure.
authors: Institute of Environmental and Municipal Engineering, North China University of Water Conservancy and Electric Power, Zhengzhou 450011, People's Republic of China.
authors: Chong-Zhen
authors: CZ
authors: Mei
authors: Han-Lin
authors: HL
authors: Xiong
authors: Peng
authors: P
authors: Zhang
references: Acta Crystallogr Sect E Struct Rep Online. 2009 Oct 03;65(Pt 11):m1290
references: 21578058
references: Acta Crystallogr Sect E Struct Rep Online. 2008 Apr 23;64(Pt 5):m712-3
references: 21202241
references: Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 14;65(Pt 12):m1589
references: 21578619
references: Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 30;64(Pt 9):m1211-2
references: 21201646
references: Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 06;64(Pt 1):m17
references: 21200518
references: Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 04;65(Pt 8):m866
references: 21583333
references: Acta Crystallogr Sect E Struct Rep Online. 2008 Sep 06;64(Pt 10):m1233
references: 21200993
references: Acta Crystallogr Sect E Struct Rep Online. 2008 Oct 04;64(Pt 11):m1353-4
references: 21580816
references: Acta Crystallogr Sect E Struct Rep Online. 2008 Aug 06;64(Pt 9):m1106
references: 21201572
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 24;66(Pt 5):m562
references: 21579044
references: Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 06;64(Pt 1):m90
references: 21200657
references: Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 06;64(Pt 1):m21
references: 21200557
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677
references: Acta Crystallogr Sect E Struct Rep Online. 2010 Mar 27;66(Pt 4):m462
references: 21580547