title: (meso-5,5,7,12,12,14-Hexamethyl-1,4,8,11-tetra-aza-cyclo-tetra-deca-ne)copper(II) bis-[O,O'-(o-phenyl-ene)dithio-phosphate].
abstract: In the title compound, [Cu(C(16)H(36)N(4))](C(6)H(4)O(2)PS(2))(2), the Cu(II) cation lies on an inversion center and is chelated by the macrocyclic tetra-amine ligand in a slightly distorted CuN(4) square-planar geometry. The axial positions are occupied by two O,O'-(o-phenyl-ene)dithio-phosphate anions with long Cu⋯S distances of 3.0940 (7) Å. Inter-molecular N-H⋯S and C-H⋯O hydrogen bonding is present between the anions and the cation and helps to stabilize the crystal structure.
authors: College of Chemistry and Pharmaceutical Engineering, Sichuan University of Science and Engineering , 643000 Zigong, Sichuan, People's Republic of China.
authors: Jian-Shen
authors: JS
authors: Feng
authors: Li-Ke
authors: LK
authors: Zou
authors: Bin
authors: B
authors: Xie
authors: Yang-Guang
authors: YG
authors: Xiang
authors: Chuan
authors: C
authors: Lai
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