title: Bis[N-(4-chloro-phen-yl)pyridine-3-carboxamide]-silver(I) nitrate.
abstract: In the title compound, [Ag(C(12)H(9)ClN(2)O)(2)]NO(3), two N atoms from two pyridine rings of two N-(4-chloro-phen-yl)pyridine-3-carboxamide ligands coordinate to the Ag(I) atom, forming a nearly linear geometry with an N-Ag-N angle of 173.41 (7)°. The crystal structure is stabilized by N-H⋯O, C-H⋯O and C-H⋯Cl hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance = 3.5469 (16) Å] between the pyridyl and benzene rings. The shortest Ag⋯Ag distance is 3.2574 (5) Å.
authors: Chun-Yue
authors: CY
authors: Shi
authors: Chun-Hua
authors: CH
authors: Ge
authors: Qi-Tao
authors: QT
authors: Liu
references: J Am Chem Soc. 2002 Jun 12;124(23):6613-25
references: 12047182
references: Inorg Chem. 2004 Nov 1;43(22):7075-82
references: 15500345
references: Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22
references: 18156677