title: Occurence of an octanuclear motif of uranyl isophthalate with cation-cation interactions through edge-sharing connection mode.
abstract: An uranyl isophthalate has been hydrothermally synthesized at 200 °C for 24 h, from a mixture of uranyl nitrate, isophthalic acid, and hydrazine in water. It was characterized by single-crystal analysis [triclinic, P ̅1, a = 7.3934(3) Å, b = 13.3296(5) Å, c = 15.4432(5) Å, α = 111.865(2)°, β = 90.637(2)°, γ = 104.867(2)°, V = 1355.49(9) Å(3)] and different spectroscopic techniques (Raman, IR-ATR, UV-visible). The 3D structure of the phase (UO(2))(8)O(2)(OH)(4)(H(2)O)(4)(1,3-bdc)(4)·4H(2)O (1,3-bdc = 1,3-benzenedicarboxylate) reveals octanuclear units based on the association of 7-fold coordinated uranyl cations (pentagonal bipyramid) involving a rare case of cation-cation interaction together with edge-sharing polyhedral connection mode. UV-visible absorption spectroscopy confirmed that uranium was only involved in the structure as uranyl forms (excluding the presence of tetravalent or pentavalent uranium). Additionally, μ-Raman and IR-ATR experiments allowed assigning four uranyl contributions to the four types of uranyl entities in the structure, in agreement with the XRD analysis.
authors.affiliation: Unité de Catalyse et Chimie du Solide (UCCS)-UMR CNRS 8181, Université de Lille Nord de France, USTL-ENSCL, Bat C7, BP 90108, 59652 Villeneuve d'Ascq, France.
authors.forename: Ionut
authors.initials: I
authors.lastname: Mihalcea
authors.forename: Natacha
authors.initials: N
authors.lastname: Henry
authors.forename: Nicolas
authors.initials: N
authors.lastname: Clavier
authors.forename: Nicolas
authors.initials: N
authors.lastname: Dacheux
authors.forename: Thierry
authors.initials: T
authors.lastname: Loiseau