title: Impact of intramolecular twisting and exciton migration on emission efficiency of multifunctional fluorene-benzothiadiazole-carbazole compounds.
abstract: Novel donor-acceptor compounds consisting of singly bonded fluorene (Fl), benzothiadiazole (BT), and carbazole (Cz) functional units in the same molecule were investigated. Analysis of the optical spectra and fluorescence transients of the compounds revealed the domination of intramolecular charge transfer (ICT) states with high fluorescence quantum yield (72%-85%). A similar Cz-Fl-Cz compound exhibiting 100% fluorescence quantum yield and no ICT character was also studied as a reference to reveal the impact of electron-accepting BT groups. Thorough examination of the optical properties of the compounds in different media, i.e., dilute solution and polymer matrix, indicated their twisted conformations due to steric hindrance in the ground state and flattened geometry in the excited state for both reference and ICT compounds. Remarkable fluorescence efficiency losses (amounting to 70%) observed upon casting the molecular solutions into neat films were determined to originate from the low-fluorescent twisted conformers and migration-facilitated exciton quenching. The majority of emission efficiency losses (over 70%) were caused by the twisted conformers, whereas only less than 30% by exciton-migration-induced nonradiative deactivation.
authors.affiliation: Center for Physical Sciences and Technology, A. Goštauto 11, LT-02300 Vilnius, Lithuania.
authors.forename: R
authors.initials: R
authors.lastname: Karpicz
authors.forename: S
authors.initials: S
authors.lastname: Puzinas
authors.forename: S
authors.initials: S
authors.lastname: Krotkus
authors.forename: K
authors.initials: K
authors.lastname: Kazlauskas
authors.forename: S
authors.initials: S
authors.lastname: Jursenas
authors.forename: J V
authors.initials: JV
authors.lastname: Grazulevicius
authors.forename: S
authors.initials: S
authors.lastname: Grigalevicius
authors.forename: V
authors.initials: V
authors.lastname: Gulbinas
mesh_terms: D002227:Carbazoles / Q000737:chemistry*; D005449:Fluorenes / Q000737:chemistry*; D005453:Fluorescence; D015394:Molecular Structure; D011789:Quantum Theory; D013237:Stereoisomerism; D013830:Thiadiazoles / Q000737:chemistry*
chemical_list: D002227:Carbazoles; D005449:Fluorenes; D013830:Thiadiazoles; C041514:carbazole; C015700:benzo-1,2,3-thiadiazole; C041509:fluorene