title: Electrochemical investigation of chromium oxide-coated Ti-6Al-4V and Co-Cr-Mo alloy substrates.
abstract: Hard coatings for articulating surfaces of total joint replacements may improve the overall wear resistance. However, any coating approach must take account of changes in corrosion behavior. This preliminary assessment analyzes the corrosion kinetics, impedance and mechanical-electrochemical stability of 100 μm thick plasma sprayed chromium oxide (Cr₂O₃) coatings on bearing surfaces in comparison to the native alloy oxide films on Co-Cr-Mo and Ti-6Al-6V. Cyclic potentiodynamic polarization, electrochemical impedance spectroscopy, and mechanical abrasion under potentiostatic conditions were performed on coated and substrate surfaces in physiological saline. SEM analysis characterized the coating morphology. The results showed that the corrosion current density values of chromium oxide coatings (0.4-1.2 μA/cm²) were of the same order of magnitude as Ti-6Al-4V alloy. Mechanical abrasion did not increase corrosion rates of chromium oxide coatings but did for uncoated Co-Cr-Mo and Ti-6Al-4V. The impedance response of chromium oxide coatings was very different than Co-Cr-Mo and Ti-6Al-4V native oxides characterized by a defected coating model. More of a frequency-independent purely resistive response was seen in mid-frequency range for the coatings (CPE(coat) : 40-280 nF/cm² (rad/s)(1-α) , α: 0.67-0.83) whereas a more capacitive character is seen for Co-Cr-Mo and Ti-6Al-4V (CPE(ox) around 20 μF/cm² (rad/s)(1-α) , α around 0.9). Pores, interparticle gaps and incomplete fusion typical for thermal spray coatings were present in these oxides which could have influenced corrosion resistance. The coating microstructure could have allowed some fluid penetration. Overall, these coatings appear to have suitable corrosion properties for wear surfaces.
authors.affiliation: Department of Biomedical and Chemical Engineering, Syracuse Biomaterials Institute, Syracuse University, Syracuse, New York.
authors.forename: Viswanathan
authors.initials: V
authors.lastname: Swaminathan
authors.forename: Haitong
authors.initials: H
authors.lastname: Zeng
authors.forename: Daniel
authors.initials: D
authors.lastname: Lawrynowicz
authors.forename: Zongtao
authors.initials: Z
authors.lastname: Zhang
authors.forename: Jeremy L
authors.initials: JL
authors.lastname: Gilbert
mesh_terms: D000497:Alloys / Q000737:chemistry*; D017608:Chromium Compounds; D020099:Coated Materials, Biocompatible / Q000737:chemistry*; D003035:Cobalt; D003343:Corrosion; D055664:Electrochemical Techniques; D008422:Materials Testing / Q000379:methods; D010087:Oxides / Q000737:chemistry*; D014025:Titanium
chemical_list: D000497:Alloys; D017608:Chromium Compounds; D020099:Coated Materials, Biocompatible; D010087:Oxides; D003035:Cobalt; D014025:Titanium; C023600:chromic oxide