title: A regio- and stereoselective synthesis of trisubstituted alkenes via gold(I)-catalyzed hydrophosphoryloxylation of haloalkynes.
abstract: A new stereoselective synthesis of trisubstituted alkenes is developed. Hydrophosphoryloxylation of haloalkynes provides Z-alkenyl halophosphates, which undergo Pd-catalyzed consecutive cross-coupling reactions to afford regio- and stereodefined trisubstituted alkenes.
authors.affiliation: Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 21 Nanyang Link, Singapore 637371, Singapore.
authors.forename: Bathoju Chandra
authors.initials: BC
authors.lastname: Chary
authors.forename: Sunggak
authors.initials: S
authors.lastname: Kim
authors.forename: Doosup
authors.initials: D
authors.lastname: Shin
authors.forename: Phil Ho
authors.initials: PH
authors.lastname: Lee