title: Electronic structure of superconducting KC8 and nonsuperconducting LiC6 graphite intercalation compounds: evidence for a graphene-sheet-driven superconducting state.
abstract: We have performed photoemission studies of the electronic structure in LiC(6) and KC(8), a nonsuperconducting and a superconducting graphite intercalation compound, respectively. We have found that the charge transfer from the intercalant layers to graphene layers is larger in KC(8) than in LiC(6), opposite of what might be expected from their chemical composition. We have also measured the strength of the electron-phonon interaction on the graphene-derived Fermi surface to carbon derived phonons in both materials and found that it follows a universal trend where the coupling strength and superconductivity monotonically increase with the filling of graphene π(*) states. This correlation suggests that both graphene-derived electrons and graphene-derived phonons are crucial for superconductivity in graphite intercalation compounds.
authors.affiliation: Condensed Matter Physics and Materials Science Department, Brookhaven National Lab, Upton, New York 11973, USA.
authors.forename: Z-H
authors.initials: ZH
authors.lastname: Pan
authors.forename: J
authors.initials: J
authors.lastname: Camacho
authors.forename: M H
authors.initials: MH
authors.lastname: Upton
authors.forename: A V
authors.initials: AV
authors.lastname: Fedorov
authors.forename: C A
authors.initials: CA
authors.lastname: Howard
authors.forename: M
authors.initials: M
authors.lastname: Ellerby
authors.forename: T
authors.initials: T
authors.lastname: Valla