title: The first solid phase synthesis of pincer palladium complexes.
abstract: Both dimeric μ-chlorine bridged and monomeric bidentate Pd(II) complexes with SCN hybrid pincer-type ligands, bearing thiophosphoryl group and imine moiety of the benzothiazole ring as coordination arms, formed in the reaction with (PhCN)(2)PdCl(2) under kinetic control (20 °C, dichloromethane solution) were readily converted into the corresponding SCN pincer complexes via solid phase synthesis (neat, 200 °C, 15 min). The synthesis of pincer complexes can be performed also by heating (200 °C, 5 min) of a homogeneous mixture of the initial reactants, namely, the ligand and (PhCN)(2)PdCl(2), obtained by manual grinding in a mortar. The efficacy of solid phase approaches is comparable with the analogous synthesis in solutions under severe conditions.
authors.affiliation: A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova Street, Moscow, 119991, Russia.
authors.forename: Vladimir A
authors.initials: VA
authors.lastname: Kozlov
authors.forename: Diana V
authors.initials: DV
authors.lastname: Aleksanyan
authors.forename: Mikhail V
authors.initials: MV
authors.lastname: Korobov
authors.forename: Natalya V
authors.initials: NV
authors.lastname: Avramenko
authors.forename: Rinat R
authors.initials: RR
authors.lastname: Aysin
authors.forename: Olga A
authors.initials: OA
authors.lastname: Maloshitskaya
authors.forename: Alexander S
authors.initials: AS
authors.lastname: Korlyukov
authors.forename: Irina L
authors.initials: IL
authors.lastname: Odinets