title: New oxides showing an intense orange color based on Fe3+ in trigonal-bipyramidal coordination.
abstract: Hexagonal YIn(1-x)Fe(x)O(3) phases have been prepared and characterized. The coordination for the In/Fe site in this structure is trigonal-bipyramidal. The colors of the phases change from yellow to orange to dark red with increasing Fe content. Magnetic measurements confirm high-spin Fe(3+) for all phases.
authors.affiliation: Department of Chemistry, Oregon State University, Corvallis, Oregon 97331, USA.
authors.forename: Peng
authors.initials: P
authors.lastname: Jiang
authors.forename: Jun
authors.initials: J
authors.lastname: Li
authors.forename: Arthur W
authors.initials: AW
authors.lastname: Sleight
authors.forename: M A
authors.initials: MA
authors.lastname: Subramanian