title: Pressure-induced local structure distortions in Cu(pyz)F2(H2O)2.
abstract: We employed infrared spectroscopy along with complementary lattice dynamics and spin density calculations to investigate pressure-driven local structure distortions in the copper coordination polymer Cu(pyz)F(2)(H(2)O)(2). Here, pyz is pyrazine. Our study reveals rich and fully reversible local lattice distortions that buckle the pyrazine ring, disrupt the bc-plane O-H···F hydrogen-bonding network, and reinforce magnetic property switching. The resiliency of the soft organic ring is a major factor in the stability of this material. Interestingly, the collective character of the lattice vibrations masks direct information on the Cu-N and Cu-O linkages through the series of pressure-induced Jahn-Teller axis switching transitions, although Cu-F bond softening is clearly identified above 3 GPa. These findings illustrate the importance of combined bulk and local probe techniques for microscopic structure determination in complex materials.
authors.affiliation: Department of Chemistry, University of Tennessee, Knoxville, Tennessee 37996, USA. musfeldt@utk.edu
authors.forename: J L
authors.initials: JL
authors.lastname: Musfeldt
authors.forename: Z
authors.initials: Z
authors.lastname: Liu
authors.forename: S
authors.initials: S
authors.lastname: Li
authors.forename: J
authors.initials: J
authors.lastname: Kang
authors.forename: C
authors.initials: C
authors.lastname: Lee
authors.forename: P
authors.initials: P
authors.lastname: Jena
authors.forename: J L
authors.initials: JL
authors.lastname: Manson
authors.forename: J A
authors.initials: JA
authors.lastname: Schlueter
authors.forename: G L
authors.initials: GL
authors.lastname: Carr
authors.forename: M-H
authors.initials: MH
authors.lastname: Whangbo