title: Effect of water and temperature on absorption of CO2 by amine-functionalized anion-tethered ionic liquids.
abstract: Amine-functionalized anion-tethered ionic liquids (ILs) trihexyl(tetradecyl)phosphonium asparaginate [P(66614)][Asn], glutaminate [P(66614)][Gln], lysinate [P(66614)][Lys], methioninate [P(66614)][Met], prolinate [P(66614)][Pro], taurinate [P(66614)][Tau], and threoninate [P(66614)][Thr] were synthesized and investigated as potential absorbents for CO(2) capture from postcombustion flue gas. Their physical properties, including density, viscosity, glass transition temperature, and thermal decomposition temperature were determined. Furthermore, the CO(2) absorption isotherms of [P(66614)][Lys], [P(66614)][Tau], [P(66614)][Pro], and [P(66614)][Met] were measured using a volumetric method, and the results were modeled with two different Langmuir-type absorption models. The most important result of this study is that the viscosity of [P(66614)][Pro] only increased by a factor of 2 when fully complexed with 1 bar of CO(2) at room temperature. This is in stark contrast to the other chemically reacted ILs investigated here and all other amino acid-based ILs reported in the literature, which dramatically increase in viscosity, typically by 2 orders of magnitude, when complexed with CO(2). The unique behavior of [P(66614)][Pro] is likely due to its ring structure, which limits the number and availability of hydrogen atoms that can participate in a hydrogen bonding network. We found that water can be used to further reduce the viscosity of the CO(2)-complexed IL, while only slightly decreasing the CO(2) capacity. Finally, from temperature-dependent isotherms, we estimate a heat of absorption of -63 kJ/mol of CO(2) for the 1:1 reaction of CO(2) with [P(66614)][Pro], when we use the two-reaction model.
authors.affiliation: Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, Indiana 46556, USA.
authors.forename: Brett F
authors.initials: BF
authors.lastname: Goodrich
authors.forename: Juan C
authors.initials: JC
authors.lastname: de la Fuente
authors.forename: Burcu E
authors.initials: BE
authors.lastname: Gurkan
authors.forename: Zulema K
authors.initials: ZK
authors.lastname: Lopez
authors.forename: Erica A
authors.initials: EA
authors.lastname: Price
authors.forename: Yong
authors.initials: Y
authors.lastname: Huang
authors.forename: Joan F
authors.initials: JF
authors.lastname: Brennecke
mesh_terms: D000042:Absorption; D000588:Amines / Q000737:chemistry*; D000596:Amino Acids / Q000737:chemistry; D002245:Carbon Dioxide / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D010084:Oxidation-Reduction; D044367:Phase Transition; D013696:Temperature; D014783:Viscosity; D014867:Water / Q000737:chemistry*
chemical_list: D000588:Amines; D000596:Amino Acids; D052578:Ionic Liquids; D014867:Water; D002245:Carbon Dioxide