title: Optical behavior of conjugated Pt-containing polymetallaynes exposed to gamma-ray radiation doses.
abstract: The effect of (60)Co γ irradiation on the absorption and emission spectra of the organometallic polymer [-Pt(PBu(3))(2)-C≡C-C(6)H(4)-C(6)H(4)-C≡C-](n) (Pt-DEBP) in chloroform and toluene solutions for dosimetry applications has been studied. The system Pt-DEBP/chloroform can be used for dosimetric applications in two different ways: (i) monitoring of absorption spectra changes for higher doses (higher than 1 Gy), and (ii) monitoring of emission spectra changes for low doses (below 1 Gy). The response of the polymer solution to γ ray doses has been interpreted with the aid of theoretical studies based on time dependent density functional theory (TD-DFT) calculations on the absorption bands of a model complex and of the possible fragments coming from the degradation of the polymer backbone. It has been proposed that the observed changes are promoted by the attack of radicals, from the radiolysis of the solvent, on the polymer triple bonds.
authors.affiliation: Department of Physics, FC-UNESP, Bauru, Brazil.
authors.forename: Augusto
authors.initials: A
authors.lastname: Batagin-Neto
authors.forename: Erika S
authors.initials: ES
authors.lastname: Bronze-Uhle
authors.forename: David M
authors.initials: DM
authors.lastname: Fernandes
authors.forename: Ilaria
authors.initials: I
authors.lastname: Fratoddi
authors.forename: Iole
authors.initials: I
authors.lastname: Venditti
authors.forename: Franco
authors.initials: F
authors.lastname: Decker
authors.forename: Enrico
authors.initials: E
authors.lastname: Bodo
authors.forename: Maria Vittoria
authors.initials: MV
authors.lastname: Russo
authors.forename: Carlos F O
authors.initials: CF
authors.lastname: Graeff
mesh_terms: D000042:Absorption; D002725:Chloroform / Q000737:chemistry; D005720:Gamma Rays; D008962:Models, Theoretical; D009944:Organoplatinum Compounds / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D014050:Toluene / Q000737:chemistry
chemical_list: D009944:Organoplatinum Compounds; D011108:Polymers; D014050:Toluene; D002725:Chloroform