title: Construction of Large-Scale Highly Ordered Macroporous Monoliths of π-Conjugated Polymers.
abstract: Large scale of well-ordered macroporous π-conjugated polymer monoliths have been successfully prepared through a new approach using micrometer-sized naphthalene crystals as templates. The macroporous monoliths of poly(p-phenylenevinylene) (PPV) and poly(p-phenyleneethynylene) (PPE) grew along the unidirectional freezing direction inside the template naphthalene crystals which lead to the formation of controlling morphologies and homogeneous diameters. The polymer monoliths show straight and lamella macroporous structures. The diameters of pores and the thickness of pore walls can be controlled by tuning the freezing temperature.
authors.affiliation: CAS Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Sciences (BNLMS), Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, P. R. China; Graduate University of Chinese Academy of Sciences, Beijing 100080, P. R. China.
authors.forename: Zicheng
authors.initials: Z
authors.lastname: Zuo
authors.forename: Yanbing
authors.initials: Y
authors.lastname: Guo
authors.forename: Yuliang
authors.initials: Y
authors.lastname: Li
authors.forename: Jing
authors.initials: J
authors.lastname: Lv
authors.forename: Huibiao
authors.initials: H
authors.lastname: Liu
authors.forename: Jialiang
authors.initials: J
authors.lastname: Xu
authors.forename: Yongjun
authors.initials: Y
authors.lastname: Li