title: Arylation of α-pivaloxyl ketones with arylboronic reagents via Ni-catalyzed sp3 C-O activation.
abstract: A Suzuki-Miyaura coupling of α-pivaloxyl ketones via Ni-catalyzed sp(3) C-O activation to produce α-aryl ketones is developed. This study offers a convenient method to construct α-arylation products from readily available α-hydroxyl carbonyl compounds.
authors.affiliation: Beijing National Laboratory of Molecular Sciences (BNLMS), College of Chemistry and Green Chemistry Center, Peking University, Beijing 100871, China.
authors.forename: Kun
authors.initials: K
authors.lastname: Huang
authors.forename: Gang
authors.initials: G
authors.lastname: Li
authors.forename: Wei-Ping
authors.initials: WP
authors.lastname: Huang
authors.forename: Da-Gang
authors.initials: DG
authors.lastname: Yu
authors.forename: Zhang-Jie
authors.initials: ZJ
authors.lastname: Shi
mesh_terms: D001896:Boron Compounds / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D007202:Indicators and Reagents / Q000737:chemistry; D007659:Ketones / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*
chemical_list: D001896:Boron Compounds; D007202:Indicators and Reagents; D007659:Ketones; D002244:Carbon; D009532:Nickel; D010100:Oxygen