title: Differences of crystal structure and dynamics between a soft porous nanocrystal and a bulk crystal.
abstract: We have demonstrated downsizing effects of the soft porous crystal, [Zn(isophthalate)(4,4'-bipyridyl)](n) (CID-1), on the adsorption behavior between CID-1 and CID-1 nanocrystal (NCID-1). The difference results from the packing crystal structures and the dynamics of the frameworks.
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
authors.forename: Yuh
authors.initials: Y
authors.lastname: Hijikata
authors.forename: Satoshi
authors.initials: S
authors.lastname: Horike
authors.forename: Daisuke
authors.initials: D
authors.lastname: Tanaka
authors.forename: Juergen
authors.initials: J
authors.lastname: Groll
authors.forename: Motohiro
authors.initials: M
authors.lastname: Mizuno
authors.forename: Jungeun
authors.initials: J
authors.lastname: Kim
authors.forename: Masaki
authors.initials: M
authors.lastname: Takata
authors.forename: Susumu
authors.initials: S
authors.lastname: Kitagawa
mesh_terms: D000327:Adsorption; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D053758:Nanoparticles / Q000737:chemistry / Q000648:ultrastructure*; D010795:Phthalic Acids / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D016062:Porosity; D011725:Pyridines / Q000737:chemistry*; D017967:Zinc Compounds / Q000737:chemistry*
chemical_list: D010795:Phthalic Acids; D011108:Polymers; D011725:Pyridines; D017967:Zinc Compounds; C059768:isophthalate; C034306:4,4'-bipyridyl