title: Palladium-catalyzed coupling of haloalkynes with allyl acetate: a regio- and stereoselective synthesis of (Z)-β-haloenol acetates.
abstract: A Pd-catalyzed coupling of haloalkynes with allyl acetate has been reported, providing a convenient method for the stereoselective synthesis of (Z)-β-haloenol acetates in good yields. The synthetic utility of this method is demonstrated by the formation of functionalized enol acetates via the Suzuki-Miyaura or Sonogashira coupling of the resulting (Z)-β-haloenol acetate products.
authors.affiliation: Department of Chemistry, Zhejiang Normal University, 688 Yingbin Road, Jinhua 321004, China.
authors.forename: Xiaoyi
authors.initials: X
authors.lastname: Chen
authors.forename: Dongxu
authors.initials: D
authors.lastname: Chen
authors.forename: Zenghui
authors.initials: Z
authors.lastname: Lu
authors.forename: Lichun
authors.initials: L
authors.lastname: Kong
authors.forename: Gangguo
authors.initials: G
authors.lastname: Zhu