title: Mechanochromism of Ag(I) complexes with iPrNHC(S)NHP(S)(OiPr)2.
abstract: Reaction of the potassium salt of iPrNHC(S)NHP(S)(OiPr)(2) (HL) with AgPF(6) leads to the hexanuclear [{Ag(3)(iPrNHC(S)NP(S)(OiPr)(2)-S,S')(3)}(2)] ([(Ag(3)L(3))(2)]) complex. The reversible conversion between yellow-emitting ([(Ag(3)L(3))(2)]) and blue-emitting ([Ag(3)L(3)]) materials on grinding and recrystallization was established. [Ag(3)L(3)] was also prepared by a mechanically induced solid-state reaction.
authors.affiliation: Institute of Condensed Matter and Nanosciences, Université Catholique de Louvain, MOST - Inorganic Chemistry, Place L. Pasteur 1, 1348 Louvain-la-Neuve, Belgium. maria.babashkina@ksu.ru
authors.forename: Maria G
authors.initials: MG
authors.lastname: Babashkina
authors.forename: Damir A
authors.initials: DA
authors.lastname: Safin
authors.forename: Michael
authors.initials: M
authors.lastname: Bolte
authors.forename: Yann
authors.initials: Y
authors.lastname: Garcia