title: A Calixarene-Based Fluorogenic Reagent for Selective Mercury(II) Recognition.
abstract: The first calixarene-based fluorogenic Hg(II)-selective extractant, 5,11,17,23-tetrakis(1,1-dimethylethyl)-25,27-bis(N-(5-dimethylaminonaphthalene-1-sulfonyl)carbamoylmethoxy)-26,28-dimethoxycalix[4]arene (2), is reported. In solvent extraction from aqueous acidic solutions (HNO(3)), 2 exhibits excellent selectivity for Hg(II) over a wide range of transition, alkali, and alkaline earth metal cations. Quenching of its fluorescence due to Hg(II) coordination is unaffected by the presence of 100-fold excesses of alkali metal cations, alkaline earth metal cations, Ag(I), Tl(I), Cd(II), Co(II), Cu(II), Ni(II), Pb(II), Pd(II), Zn(II), or Fe(III).
authors.affiliation: Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, Texas 79409-1061.
authors.forename: G G
authors.initials: GG
authors.lastname: Talanova
authors.forename: N S
authors.initials: NS
authors.lastname: Elkarim
authors.forename: V S
authors.initials: VS
authors.lastname: Talanov
authors.forename: R A
authors.initials: RA
authors.lastname: Bartsch