title: Novel reversible chemosensory material based on conjugated side-chain polymer containing fluorescent pyridyl receptor pendants.
abstract: A novel light-emitting monomer M1 and its side-chain polymer P1 containing three conjugated aromatic pendants, including one pyridyl terminus, were successfully synthesized via Wittig and Pd-catalyzed Heck coupling reactions. The fluorescence of polymer P1 was efficiently quenched upon addition of different metal ions due to the facile energy transfers from the pendent groups of polymer P1 to specific metal ions. Among these metal ions, P1 exhibited extraordinary sensory selectivities for Ni(2+) and Cu(2+) ions over the other metal ions due to the stronger binding capabilities of Ni(2+) and Cu(2+) ions with polymer P1. From the time-resolved fluorescence (TRF) signals in photoluminescence spectra, the emergences of τ(1) decay components in polymer complexes (P1+Ni(2+)) and (P1+Cu(2+)) clearly indicated that their TRF traces consisted of two contributions, one from the complexes (τ(1)) and the other from free polymer P1 (τ(2)). Upon addition of Ni(2+) and Cu(2+) ions, polymer P1 showed faster decay time constants (τ(1)) of metal ion quenching on TRF signals (i.e., better quenching efficiencies on photoluminescence) than its monomer M1. Furthermore, the on-off-on fluorescent switching behavior by adding a tridentate ligand 1,1,4,7,7-pentamethyldiethylenetriamine (PMDTA) to the polymer complex (P1+Cu(2+)) for several successive cycles demonstrated a superior reusable chemosensor of P1 for further applications.
authors.affiliation: Department of Materials Science and Engineering, National Chiao Tung University, Hsinchu, Taiwan.
authors.forename: Hsuan-Chih
authors.initials: HC
authors.lastname: Chu
authors.forename: Yu-Hsien
authors.initials: YH
authors.lastname: Lee
authors.forename: Shou-Jen
authors.initials: SJ
authors.lastname: Hsu
authors.forename: Po-Jen
authors.initials: PJ
authors.lastname: Yang
authors.forename: Atsushi
authors.initials: A
authors.lastname: Yabushita
authors.forename: Hong-Cheu
authors.initials: HC
authors.lastname: Lin
mesh_terms: D003300:Copper / Q000737:chemistry*; D005456:Fluorescent Dyes / Q000737:chemistry*; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry*; D011725:Pyridines / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D005456:Fluorescent Dyes; D011108:Polymers; D011725:Pyridines; D003300:Copper; D009532:Nickel