title: Graphene oxide based Pt-TiO2 photocatalyst: ultrasound assisted synthesis, characterization and catalytic efficiency.
abstract: An ultrasound-assisted method was used for synthesizing nanosized Pt-graphene oxide (GO)-TiO2 photocatalyst. The Pt-GO-TiO2 nanoparticles were characterized by diffused reflectance spectroscopy, X-ray diffraction, N2 BET adsorption-desorption measurements, atomic force microscopy and transmission electron microscopy. The photocatalytic and sonophotocatalytic degradation of a commonly used anionic surfactant, dodecylbenzenesulfonate (DBS), in aqueous solution was carried out using Pt-GO-TiO2 nanoparticles in order to evaluate the photocatalytic efficiency. For comparison purpose, sonolytic degradation of DBS was carried out. The Pt-GO-TiO2 catalyst degraded DBS at a higher rate than P-25 (TiO2), prepared TiO2 or GO-TiO2 photocatalysts. The mineralization of DBS was enhanced by a factor of 3 using Pt-GO-TiO2 compared to the P-25 (TiO2). In the presence of GO, an enhanced rate of DBS oxidation was observed and, when doped with platinum, mineralization of DBS was further enhanced. The Pt-GO-TiO2 catalyst also showed a considerable amount of degradation of DBS under visible light irradiation. The initial solution pH had an effect on the rate of photocatalytic oxidation of DBS, whereas no such effect of initial pH was observed in the sonochemical or sonophotocatalytic oxidation of DBS. The intermediate products formed during the degradation of DBS were monitored using electrospray mass spectrometry. The ability of GO to serve as a solid support to anchor platinum particles on GO-TiO2 is useful in developing new photocatalysts.
authors.affiliation: The School of Chemistry, University of Melbourne, Parkville, Melbourne, Victoria 3010, Australia.
authors.forename: Bernaurdshaw
authors.initials: B
authors.lastname: Neppolian
authors.forename: Andrea
authors.initials: A
authors.lastname: Bruno
authors.forename: Claudia L
authors.initials: CL
authors.lastname: Bianchi
authors.forename: Muthupandian
authors.initials: M
authors.lastname: Ashokkumar
mesh_terms: D002384:Catalysis; D006108:Graphite / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D008958:Models, Molecular; D053758:Nanoparticles / Q000737:chemistry; D010087:Oxides / Q000737:chemistry*; D010316:Particle Size; D055668:Photochemical Processes; D010984:Platinum / Q000737:chemistry*; D013499:Surface Properties; D014025:Titanium / Q000737:chemistry*; D014465:Ultrasonics
chemical_list: D010087:Oxides; C009495:titanium dioxide; D010984:Platinum; D006108:Graphite; D014025:Titanium