title: Synthesis and electrochemical properties of spin-capable carbon nanotube sheet/MnO(x) composites for high-performance energy storage devices.
abstract: Inspired by the high specific capacitances found using ultrathin films or nanoparticles of manganese oxides (MnO(x)), we have electrodeposited MnO(x) nanoparticles onto sheets of carbon nanotubes (CNT sheets). The resulting composites have high specific capacitances (C(sp) ≤ 1250 F/g), high charge/discharge rate capabilities, and excellent cyclic stability. Both the C(sp) and rate capabilities are controlled by the average size of the MnO(x) nanoparticles on the CNTs. They are independent of the number of layers of CNT sheets used to form an electrode. The high-performance composites result from a synergistic combination of large surface area and good electron-transport capabilities of the MnO(x) nanoparticles with the good conductivity of the CNT sheets. Such composites can be used as electrodes for lithium batteries and supercapacitors.
authors.affiliation: Department of Electrical Engineering, University of Texas at Dallas, 800 West Campbell Road, Richardson, Texas 75080-3021, United States.
authors.forename: Jae-Hak
authors.initials: JH
authors.lastname: Kim
authors.forename: Kyung H
authors.initials: KH
authors.lastname: Lee
authors.forename: Lawrence J
authors.initials: LJ
authors.lastname: Overzet
authors.forename: Gil S
authors.initials: GS
authors.lastname: Lee
mesh_terms: D011211:Electric Power Supplies; D004563:Electrochemistry; D017895:Manganese Compounds / Q000737:chemistry*; D053761:Nanocomposites / Q000737:chemistry*; D036103:Nanotechnology; D037742:Nanotubes, Carbon / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D010316:Particle Size; D013499:Surface Properties
chemical_list: D017895:Manganese Compounds; D037742:Nanotubes, Carbon; D010087:Oxides; C027424:manganese oxide