title: The effect of the concentration and oxidation state of Sn on the structural and electrical properties of indium tin oxide nanowires.
abstract: High quality single-crystalline indium tin oxide (ITO) nanowires with controlled Sn contents of up to 32.5 at.% were successfully synthesized via a thermal metal co-evaporation method, based on a vapor-liquid-solid growth mode, at a substrate temperature of as low as 540 °C. The high solubility of Sn in the nanowires was explained with the existence of Sn(2+) ions along with Sn(4+) ions: the coexistence of Sn(2+) and Sn(4+) ions facilitated their high substitutional incorporation into the In(2)O(3) lattice by relaxing structural and electrical disturbances due to the differences in ionic radii and electrical charges between Sn and In(3+) ions. It was revealed that, while the lattice parameter of the ITO nanowires had a minimum value at a Sn content of 6.3 at.%, the electrical resistivity had a minimum value of about 10(-3) Ω cm at a Sn content of 14 at.%. These structural and electrical behaviors were explained by variation in the relative and total amounts of the two species, Sn(2+) and Sn(4+).
authors.affiliation: Nano-Photonics Research Center, Korea Institute of Science and Technology, PO Box 131, Cheongryang, Seoul, 130-650, Korea.
authors.forename: Kyung-Soo
authors.initials: KS
authors.lastname: Park
authors.forename: Young-Jin
authors.initials: YJ
authors.lastname: Choi
authors.forename: Jin-Gu
authors.initials: JG
authors.lastname: Kang
authors.forename: Yun-Mo
authors.initials: YM
authors.lastname: Sung
authors.forename: Jae-Gwan
authors.initials: JG
authors.lastname: Park