title: Synthesis and anion sensing of water-soluble metallomacrocycles.
abstract: The self-assembly of (TMEDA)Pd(NO(3))(2) or (TMEDA)Pt(NO(3))(2) (where TMEDA = N(1),N(1),N(2),N(2)-tetramethylethane-1,2-diamine) and anthracene- or ferrocene-based diimidazole ligands (L(1-3)) in aqueous solution affords a series of positively charged [M(2)L(2)](4+) dimetallomacrocycles. Their structures were characterized by (1)H NMR and electrospray ionization mass spectrometry and in the cases of {[(TMEDA)Pd](2)L(1)(2)}(NO(3))(4) (1), {[(TMEDA)Pd](2)L(1)(2)}(PF(6))(4) (1a), and {[(TMEDA)Pd](2)L(3)(2)}(NO(3))(4) (4) by single-crystal X-ray diffraction analysis. Interestingly, the NMR spectra of 1 and 1a revealed that the difference of their structures, as confirmed by X-ray diffraction analysis, was that a NO(3)(-) of 1 was encapsulated inside the cavity of the basket-shaped metallomacrocycle by C-H···O hydrogen bonds, while PF(6)(-) of 1a was bound outside by C-H···F hydrogen bonds. The fluorescence titration experiment exhibited the formation of 1:1 host-guest complexation for anthracene-based positively charged [M(2)L(2)](4+)-type metallomacrocycles with NO(3)(-). The interactions between metallomacrocycles and various anions were investigated via fluorescence titration and cyclic voltammetry studies, respectively.
authors.affiliation: Laboratory for Self-Assembly Chemistry, Department of Chemistry, Renmin University of China, Beijing 100872, People's Republic of China.
authors.forename: Liao-Yuan
authors.initials: LY
authors.lastname: Yao
authors.forename: Lin
authors.initials: L
authors.lastname: Qin
authors.forename: Ting-Zheng
authors.initials: TZ
authors.lastname: Xie
authors.forename: Yi-Zhi
authors.initials: YZ
authors.lastname: Li
authors.forename: Shu-Yan
authors.initials: SY
authors.lastname: Yu
mesh_terms: D000838:Anions / Q000737:chemistry; D018360:Crystallography, X-Ray; D047028:Macrocyclic Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*; D012995:Solubility; D013237:Stereoisomerism; D014867:Water / Q000737:chemistry*
chemical_list: D000838:Anions; D047028:Macrocyclic Compounds; D009942:Organometallic Compounds; D014867:Water; D010984:Platinum; D010165:Palladium