title: Modular ion mobility spectrometer for explosives detection using corona ionization.
abstract: Ion mobility spectrometry (IMS) has become the most widely used technology for trace explosives detection. A key task in designing IMS systems is to balance the explosives detection performance with size, weight, cost, and safety of the instrument. Commercial instruments are, by and large, equipped with radioactive (63)Ni ionization sources which pose inherent problems for transportation, safety, and waste disposal regulation. An alternative to a radioactive source is a corona discharge ionization source, which offers the benefits of simplicity, stability, and sensitivity without the regulatory problems. An IMS system was designed and built based on modeling and simulation with the goal to achieve a lightweight modular design that offered high performance for the detection of trace explosives using a corona ionization source. Modeling and simulations were used to investigate design alternatives and optimize parameters. Simulated spectra were obtained for 2,4,6-trinitrotoluene (TNT) and cyclo-1,3,5-trimethylene-2,4,6-trinitramine (RDX) and showed good agreement with experimentally measured spectra using a corona ionization source. The reduced mobilities for TNT and RDX obtained with corona ionization were 1.53 and 1.46 cm(2)/(V s), respectively, and this agreed well with literature values.
authors.affiliation: Department of Chemistry, Washington State University, Pullman, Washington 99164, United States.
authors.forename: Kristyn M
authors.initials: KM
authors.lastname: Roscioli
authors.forename: Eric
authors.initials: E
authors.lastname: Davis
authors.forename: William F
authors.initials: WF
authors.lastname: Siems
authors.forename: Adrian
authors.initials: A
authors.lastname: Mariano
authors.forename: Wansheng
authors.initials: W
authors.lastname: Su
authors.forename: Samar K
authors.initials: SK
authors.lastname: Guharay
authors.forename: Herbert H
authors.initials: HH
authors.lastname: Hill