title: In situ observation of cluster formation during nanoparticle solution casting on a colloidal film.
abstract: We present a real-time study of the nanostructuring and cluster formation of gold nanoparticles deposited in aqueous solution on top of a pre-structured polystyrene colloidal thin film. Cluster formation takes place at different length scales, from the agglomerations of the gold nanoparticles to domains of polystyrene colloids. By combining in situ imaging ellipsometry and microbeam grazing incidence small-angle x-ray scattering, we are able to identify different stages of nanocomposite formation, namely diffusion, roughness increase, layer build-up and compaction. The findings can serve as a guideline for nanocomposite tailoring by solution casting.
authors.affiliation: Deutsches Elektronen-Synchrotron (DESY), Notkestrabe, Hamburg, Germany. stephan.roth@desy.de
authors.forename: S V
authors.initials: SV
authors.lastname: Roth
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authors.lastname: Herzog
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authors.lastname: Körstgens
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authors.lastname: Buffet
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authors.lastname: Schwartzkopf
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authors.lastname: Abul Kashem
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authors.lastname: Döhrmann
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authors.lastname: Gehrke
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authors.lastname: Rothkirch
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authors.lastname: Stassig
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authors.lastname: Wurth
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authors.lastname: Benecke
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authors.lastname: Li
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authors.lastname: Fratzl
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authors.lastname: Rawolle
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authors.lastname: Müller-Buschbaum