title: β-cyclodextrin-bonded silica particles as novel sorbent for stir bar sorptive extraction of phenolic compounds.
abstract: A stir bar coated with β-cyclodextrin-bonded-silica (CDS) as novel sorbent has been developed and used to analyze seven phenolic compounds in aqueous samples, followed by thermal desorption and gas chromatography-mass spectrometric detection. Significant parameters affecting sorption process such as the time and temperature of sorption and desorption, ionic strength, pH and stirring rate have been optimized and discussed. The coating has a high thermal stability up to 300°C and long application lifetime (80 times). The porous structure of CDS coating provides high surface area and allows high extraction efficiency. Under the selected conditions, linearity range of 0.1-400 μg/L, limit of quantifications of 0.08-3.3 μg/L and method detection limits of 0.02-1.00 μg/L have been obtained. A satisfactory repeatability (RSD ≤ 6.5, n = 7) with good linearity (0.9975 ≤ r(2) ≤ 0.9996) of results illustrated a good performance of the present method. The recovery of different natural water samples was higher than 81.5%.
authors.affiliation: Department of Chemistry, Varamin Branch, Islamic Azad University, Varamin, Iran. hakimfaraji@yahoo.com
authors.forename: Hakim
authors.initials: H
authors.lastname: Faraji
authors.forename: Syed Waqif
authors.initials: SW
authors.lastname: Husain
authors.forename: Masoumeh
authors.initials: M
authors.lastname: Helalizadeh
mesh_terms: D005591:Chemical Fractionation / Q000379:methods*; D005618:Fresh Water / Q000737:chemistry; D016014:Linear Models; D008900:Mineral Waters; D010636:Phenols / Q000032:analysis / Q000302:isolation & purification*; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D058428:Silica Gel / Q000737:chemistry*; D013696:Temperature; D047392:beta-Cyclodextrins / Q000737:chemistry*
chemical_list: D008900:Mineral Waters; D010636:Phenols; D047392:beta-Cyclodextrins; D058428:Silica Gel