title: Gold nanoparticles generated through "green route" bind Hg2+ with a concomitant blue shift in plasmon absorption peak.
abstract: We discuss here a quick, simple, economic and ecofriendly method through a completely green route for the selective detection of Hg(2+) in aqueous samples. Here we exploited the ability of chitosan to generate gold nanoparticles and subsequently to act as a stabilizer for the formed nanoparticles. When chitosan stabilized gold nanoparticles (CH-Au NPs) are interacted with Hg(2+) a blue shift for its localized surface plasmon resonance absorbance (LSPR) band is observed. The blue shift is reasoned to be due to the formation of a thin layer of mercury over gold. A concentration as low as 0.01 ppm to a maximum of 100 ppm Hg(2+) can be detected based on this blue shift of the CH-Au NPs. While all other reported methods demand complex reaction steps and costly chemicals, the method we reported here is a simple, rapid and selective approach for the detection of Hg(2+). Our results also show that the CH-Au NPs have excellent selectivity to Hg(2+) over common cations namely, Pb(2+), Cd(2+), Mn(2+), Fe(2+), Ag(1+), Ce(4+), Ni(2+), and Cu(2+).
authors.affiliation: Laboratory for Polymer Analysis, Biomedical Technology Wing, Sree Chitra Tirunal Institute for Medical Sciences & Technology, Poojapura, Thiruvananthapuram, 695012, India.
authors.forename: C
authors.initials: C
authors.lastname: Radhakumary
authors.forename: K
authors.initials: K
authors.lastname: Sreenivasan
mesh_terms: D000042:Absorption; D048271:Chitosan / Q000737:chemistry; D005618:Fresh Water / Q000032:analysis; D006046:Gold / Q000737:chemistry*; D007477:Ions / Q000737:chemistry; D008628:Mercury / Q000032:analysis*; D053768:Metal Nanoparticles / Q000737:chemistry*; D019216:Metals, Heavy / Q000737:chemistry; D020349:Surface Plasmon Resonance / Q000379:methods*
chemical_list: D007477:Ions; D019216:Metals, Heavy; D006046:Gold; D048271:Chitosan; D008628:Mercury