title: Self-consistent density functional calculation of the image potential at a metal surface.
abstract: It is well known that the exchange-correlation (XC) potential at a metal surface has an image-like asymptotic behaviour given by -1/4(z-z(0)), where z is the coordinate perpendicular to the surface. Using a suitable fully non-local functional prescription, we evaluate self-consistently the XC potential with the correct image behaviour for simple jellium surfaces in the range of metallic densities. This allows a proper comparison between the corresponding image-plane position, z(0), and other related quantities such as the centroid of an induced charge by an external perturbation. As a by-product, we assess the routinely used local density approximation when evaluating electron density profiles, work functions, and surface energies by focusing on the XC effects included in the fully non-local description.
authors.affiliation: Departamento de Física Fundamental, Universidad Nacional de Educación a Distancia, Apartado 60141, 28080 Madrid, Spain.
authors.forename: J
authors.initials: J
authors.lastname: Jung
authors.forename: J E
authors.initials: JE
authors.lastname: Alvarellos
authors.forename: E
authors.initials: E
authors.lastname: Chacón
authors.forename: P
authors.initials: P
authors.lastname: García-González