title: Stereodifferentiation in the compartmentalized photooxidation of a protein-bound anthracene.
abstract: Encapsulation within transport proteins strongly reduces the photooxidation rate of (S)- and (R)-2-(9-anthracenyl)propanoic acid (1) and results in a significant stereodifferentiation. The most remarkable effects are observed within human serum albumin (HSA).
authors.affiliation: Departamento de Química/Instituto de Tecnología Química UPV-CSIC, Universidad Politécnica de Valencia, Camino de Vera s/n, E-46022 Valencia, Spain.
authors.forename: Rafael
authors.initials: R
authors.lastname: Alonso
authors.forename: M Consuelo
authors.initials: MC
authors.lastname: Jiménez
authors.forename: Miguel A
authors.initials: MA
authors.lastname: Miranda
mesh_terms: D000818:Animals; D000873:Anthracenes / Q000737:chemistry*; D006801:Humans; D007700:Kinetics; D015394:Molecular Structure; D010084:Oxidation-Reduction; D055668:Photochemical Processes; D012709:Serum Albumin / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: C568566:2-(9-anthracenyl)propanoic acid; D000873:Anthracenes; D012709:Serum Albumin