title: A pillared-bilayer porous coordination polymer with a 1D channel and a 2D interlayer space, showing unique gas and vapor sorption.
abstract: A new 2D pillared-bilayer porous coordination polymer (PCP) has been synthesized and structurally characterized that shows selective adsorption of CO(2) over other gases (N(2), O(2), Ar, H(2), CH(4)) and guest selective single/double-step adsorption of vapor correlated to the successive confinement of adsorbates in a 1D channel and a 2D interlayer space.
authors.affiliation: Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560 064, India.
authors.forename: Prakash
authors.initials: P
authors.lastname: Kanoo
authors.forename: Golam
authors.initials: G
authors.lastname: Mostafa
authors.forename: Ryotaro
authors.initials: R
authors.lastname: Matsuda
authors.forename: Susumu
authors.initials: S
authors.lastname: Kitagawa
authors.forename: Tapas Kumar
authors.initials: TK
authors.lastname: Maji
mesh_terms: D005740:Gases / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D011108:Polymers / Q000737:chemistry*; D016062:Porosity; D011725:Pyridines / Q000737:chemistry; D014835:Volatilization
chemical_list: D005740:Gases; D011108:Polymers; D011725:Pyridines