title: Insights into the induced ultrafast electron delocalization in Fe(CO)5 using dark channel fluorescence yield X-ray absorption.
abstract: Well-coordinated: L(2,3) -edge X-ray absorption measurements of Fe(CO)(5), carried out for the first time in solution, are discussed. Using the dark channel fluorescence yield technique, ultrafast delocalization processes on the femtosecond time-scale yield new insights into the electronic structure.
authors.affiliation: Institut für technische Chemie und Polymerchemie, Karlsruhe Institut für Technologie, Germany. matthias.bauer@kit.edu
authors.forename: Matthias
authors.initials: M
authors.lastname: Bauer
authors.forename: Tom
authors.initials: T
authors.lastname: Stalinski
authors.forename: Emad F
authors.initials: EF
authors.lastname: Aziz
mesh_terms: D004583:Electrons; D005453:Fluorescence; D006586:Hexanes / Q000737:chemistry; D058085:Iron Compounds / Q000737:chemistry*; D056928:X-Ray Absorption Spectroscopy
chemical_list: D006586:Hexanes; D058085:Iron Compounds; C026385:n-hexane; C515100:iron pentacarbonyl