title: Probabilistic multicompartmental model for interpreting DGT kinetics in sediments.
abstract: Extensive research has been performed on the use of the DIFS (DGT-Induced Fluxes in Soils and Sediments) model to interpret diffusive gradients in thin-film, or DGT, measurements in soils and sediments. The current report identifies some areas where the DIFS model has been shown to yield poor results and proposes a model to address weaknesses. In particular, two major flaws in the current approaches are considered: (i) many studies of accumulation kinetics in DGT exhibit multiple kinetic stages and (ii) several combinations of the two fitted DIFS parameters can yield identical results, leaving the question of how to select the 'best' combination. Previously, problem (i) has been addressed by separating the experimental data sets into distinct time segments. To overcome these problems, a model considering two types of particulate binding sites is proposed, instead of the DIFS model which assumed one single particulate pool. A probabilistic approach is proposed to fit experimental data and to determine the range of possible physical parameters using Probability Distribution Functions (PDFs), as opposed to single values without any indication of their uncertainty. The new probabilistic model, called DGT-PROFS, was tested on three different formulated sediments which mainly differ in the presence or absence of iron oxides. It was shown that a good fit can be obtained for the complete set of data (instead of DIFS-2D) and that a range of uncertainty values for each modeling parameter can be obtained. The interpretation of parameter PDFs allows one to distinguish between a variety of geochemical behaviors, providing useful information on metal dynamics in sediments.
authors.affiliation: EDF, Division Recherche et Développement, Département Laboratoire National d'Hydraulique et Environnement, 78401 Chatou, France. philippe.ciffroy@edf.fr
authors.forename: P
authors.initials: P
authors.lastname: Ciffroy
authors.forename: Y
authors.initials: Y
authors.lastname: Nia
authors.forename: J M
authors.initials: JM
authors.lastname: Garnier
mesh_terms: D004058:Diffusion; D004784:Environmental Monitoring; D019015:Geologic Sediments / Q000032:analysis*; D007700:Kinetics; D008670:Metals / Q000032:analysis*; D015233:Models, Statistical; D012987:Soil / Q000032:analysis*; D012989:Soil Pollutants / Q000032:analysis*
chemical_list: D008670:Metals; D012987:Soil; D012989:Soil Pollutants