title: Wrapping graphene sheets around organic wires for making memory devices.
abstract: Hybrids of organic semiconductors and graphene can generate a whole new class of materials with enhanced properties. A simple solution-phase route to synthesize a hybrid material made of organic nanowires and graphene oxide (GO) sheets is demonstrated by sonicating tetracene molecules and GO together in diluted fuming nitric acid. The self-assembled tetracene-derived organic wires become encapsulated by GO sheets during the reaction to produce an interconnected, one-dimensional/two-dimensional lamellar film. Memory devices fabricated using the hybrid film as the sandwiched layer between aluminum electrodes exhibit excellent electrical bistability. The charge retention properties are attributed to charge transfer and a charge-trapping/detrapping mechanism operational at the interfaces and isolated matrices of the GO-tetracene hybrid.
authors.affiliation: Department of Chemistry, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore.
authors.forename: Shuai
authors.initials: S
authors.lastname: Wang
authors.forename: Kiran Kumar
authors.initials: KK
authors.lastname: Manga
authors.forename: Meng
authors.initials: M
authors.lastname: Zhao
authors.forename: Qiaoliang
authors.initials: Q
authors.lastname: Bao
authors.forename: Kian Ping
authors.initials: KP
authors.lastname: Loh