title: Kinetics of core-shell nanoparticle formation by two-dimensional nuclear magnetic resonance.
abstract: We have studied the kinetics of polymeric nanoparticle formation for poly(styrene-block-4-vinylpyridine) [P(S-b-4-VPy)], chains in a non-selective solvent using 1,4-dibromobutane (DBB) as a cross-linker by means of different nuclear magnetic resonance (NMR) spectroscopy techniques. The kinetic process was followed using (1) H, (13) C, and 2-D Heteronuclear Single Quantum Correlation (HSQC) NMR experiments. The kinetic data obtained from 2-D HSQC and (1) H NMR experiments were in good agreement between them, proving the reliability of the 2-D HSQC NMR technique for the in situ study of the kinetics of core-shell nanoparticle formation. A value of 1.5 × 10(-5) s(-1) was determined for the apparent kinetic constant of the P(S-b-4-VPy)-DBB core-shell nanoparticle formation process.
authors.affiliation: New Materials Department, CIDETEC, Paseo Miramón 196, Donostia-San Sebastián E-20009, Spain.
authors.forename: Alaitz Ruiz
authors.initials: AR
authors.lastname: de Luzuriaga
authors.forename: José A
authors.initials: JA
authors.lastname: Pomposo
authors.forename: Hans
authors.initials: H
authors.lastname: Grande
authors.forename: Agustin
authors.initials: A
authors.lastname: Etxeberria