title: Highly effective chiral phosphorus amidite-olefin ligands for palladium-catalyzed asymmetric allylic substitutions.
abstract: This paper describes the development of a type of novel P-olefin hybrid ligand by the incorporation of terminal olefins onto phosphorus amidite ligands for palladium-catalyzed asymmetric allylic alkylations of indoles and substitutions with amines to give the desired products in 70-97% yield with 91-98% ee.
authors.affiliation: Beijing National Laboratory of Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
authors.forename: Zhaoqun
authors.initials: Z
authors.lastname: Liu
authors.forename: Ziping
authors.initials: Z
authors.lastname: Cao
authors.forename: Haifeng
authors.initials: H
authors.lastname: Du