title: Synthesis and structure of all-syn-1,2,3,4-tetrafluorocyclohexane.
abstract: Preparation of the all-syn isomer of 1,2,3,4-tetrafluorocyclohexane is reported; X-ray structural studies shows a conformation with two of the C-F bonds oriented 1,3-diaxial to each other and (19)F-NMR reveals a through space diaxial (4)J(FF) coupling constant of 29 Hz.
authors.affiliation: University of St Andrews, School of Chemistry and Centre for Biomolecular Sciences, North Haugh, St Andrews, Fife, KY16 9ST, UK.
authors.forename: Alastair J
authors.initials: AJ
authors.lastname: Durie
authors.forename: Alexandra M Z
authors.initials: AM
authors.lastname: Slawin
authors.forename: Tomas
authors.initials: T
authors.lastname: Lebl
authors.forename: Peer
authors.initials: P
authors.lastname: Kirsch
authors.forename: David
authors.initials: D
authors.lastname: O'Hagan
mesh_terms: D018360:Crystallography, X-Ray; D003510:Cyclohexanes / Q000138:chemical synthesis* / Q000737:chemistry*; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis* / Q000737:chemistry; D008968:Molecular Conformation; D013237:Stereoisomerism
chemical_list: C562015:1,2,3,4-tetrafluorocyclohexane; D003510:Cyclohexanes; D006845:Hydrocarbons, Fluorinated; C506365:Cyclohexane