title: Palladium-catalyzed haloallylation of aromatic ynol ethers with allyl chlorides: a highly regio- and stereoselective approach to (1E)-α-chloroenol ethers.
abstract: Described herein is a Pd-catalyzed haloallylation of aromatic ynol ethers and allyl chlorides, allowing facile access to (1E)-α-chloroenol ethers in a highly regio- and stereoselective manner. The synthetic utility of this method is demonstrated well by the synthesis of the stereodefined multisubstituted enol ethers and α-allylated carbonyl compounds.
authors: Department of Chemistry, Zhejiang Normal University, 688 Yingbin Avenue, Jinhua 321004, China.
authors: Haiting
authors: H
authors: Cai
authors: Zheliang
authors: Z
authors: Yuan
authors: Weidong
authors: W
authors: Zhu
authors: Gangguo
authors: G
authors: Zhu