title: Analysis of a growing dynamic length scale in a glass-forming binary hard-sphere mixture.
abstract: We examine a length scale that characterizes the spatial extent of heterogeneous dynamics in a glass-forming binary hard-sphere mixture up to the mode-coupling volume fraction ϕ(c). First, we characterize the system's dynamics. Then, we utilize a method [Phys. Rev. Lett. 105, 217801 (2010)] to extract and analyze the ensemble-independent dynamic susceptibility χ(4)(t) and the dynamic correlation length ξ(t) for a range of times between the β and α relaxation times. We find that in this time range the dynamic correlation length follows a volume fraction-independent master curve ξ(t)~ln(t). For longer times, ξ(t) departs from this master curve and remains constant up to the largest time at which we can determine the length accurately. In addition to the previously established correlation τ(α)~exp[ξ(τ(α))] between the α relaxation time, τ(α), and the dynamic correlation length at this time, ξ(τ(α)), we also find a similar correlation for the diffusion coefficient D~exp[ξ(τ(α))(θ)] with θ≈0.6. We discuss the relevance of these findings for different theories of the glass transition.
authors: Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.
authors: Elijah
authors: E
authors: Flenner
authors: Min
authors: M
authors: Zhang
authors: Grzegorz
authors: G
authors: Szamel