title: Zn-containing porphyrin as a biomimetic light-harvesting molecule for biocatalyzed artificial photosynthesis.
abstract: Among the porphyrin molecules with different metal insertion sites and functional ligands, Zn-porphyrin most efficiently regenerates NADH through photo-induced electron transfer in the presence of [Cp*Rh(bpy)H(2)O](2+), a rhodium-based electron mediator. Photochemical regeneration of NADH by Zn-porphyrin is successfully coupled with redox enzymatic synthesis under dark state conditions.
authors: Department of Materials Science and Engineering, Korea Advanced Institute of Science and Technology, Science Road 335, Yuseong-gu, Daejeon 305-701, Republic of Korea.
authors: Jae Hong
authors: JH
authors: Kim
authors: Sahng Ha
authors: SH
authors: Lee
authors: Joon Seok
authors: JS
authors: Lee
authors: Minah
authors: M
authors: Lee
authors: Chan Beum
authors: CB
authors: Park
mesh_terms: D055162:Biocatalysis; D040761:Biomimetic Materials / Q000737:chemistry*; D004579:Electron Transport / Q000528:radiation effects; D008027:Light; D045342:Light-Harvesting Protein Complexes / Q000378:metabolism*; D008665:Metalloporphyrins / Q000737:chemistry*; D009243:NAD / Q000737:chemistry; D055668:Photochemical Processes; D010788:Photosynthesis
chemical_list: D045342:Light-Harvesting Protein Complexes; D008665:Metalloporphyrins; D009243:NAD; C017802:zinc hematoporphyrin