title: Diastereoselective radical mediated alkylation of a chiral glycolic acid derivative.
abstract: Radical alkylation of 2-(tert-butyl)-2-methyldioxolan-4-one, a chiral equivalent of glycolic acid, occurs with good to high diastereoselectivity that compares favorably with the corresponding enolate alkylation. The importance of the position of the transition state position, early or late, is highlighted.
authors: Universität Bern, Departement für Chemie und Biochemie, Bern, Switzerland.
authors: Sokol
authors: S
authors: Abazi
authors: Liliana Parra
authors: LP
authors: Rapado
authors: Philippe
authors: P
authors: Renaud