title: Assembly of a family of mixed metal {Mo:V} polyoxometalates templated by TeO3(2-): {Mo12V12Te3}, {Mo12V12Te2} and {Mo17V8Te}.
abstract: The influence of the pyramidal heteroanion, TeO(3)(2-) in the self-assembly of mixed metal (Mo/V) systems, is demonstrated by the isolation of three novel mixed-metal, mixed-valence architectures, {Mo(12)V(12)Te(3)} (1), {Mo(12)V(12)Te(2)} (2) and {Mo(17)V(8)Te} (3) with the tellurium centres exhibiting the novel μ(8)-TeO(4) and μ(9)-TeO(3) coordination modes while compounds 1 and 2 were discovered utilizing ESI mass spectrometry.
authors: WestCHEM, Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, Scotland, UK.
authors: M Nieves
authors: MN
authors: Corella-Ochoa
authors: Haralampos N
authors: HN
authors: Miras
authors: Alastair
authors: A
authors: Kidd
authors: De-Liang
authors: DL
authors: Long
authors: Leroy
authors: L
authors: Cronin