title: Dihydroxy(4-thiomorpholinomethyl)benzoic acid: from molecular asymmetry to diode characteristics.
abstract: One of the challenges in molecular electronics is to design molecules which can be used as functional units in electronic devices. The subject of our investigations is an asymmetrical molecule, dihydroxy(4-thiomorpholinomethyl)benzoic acid (TMBA), whose structural and electronic properties are characterized. The self-assembly behavior of TMBA on Au(111) surfaces resulting in highly ordered monolayers is obtained using scanning tunneling microscopy (STM). Furthermore, investigations on the electronic properties of the combined metal/molecule system reveal an orbital mediated tunneling process and tunneling decay constants for the carboxylic and thiomorpholino group. Thus, a diode-like character of TMBA is shown to be caused by intrinsic electronic properties of different molecular moieties.
authors: Peter Grünberg Institut (PGI-7) and JARA-FIT, Forschungszentrum Jülich GmbH, 52425 Jülich, Germany.
authors: M Christina
authors: MC
authors: Lennartz
authors: Miriam
authors: M
authors: Baumert
authors: Silvia
authors: S
authors: Karthäuser
authors: Markus
authors: M
authors: Albrecht
authors: Rainer
authors: R
authors: Waser