title: Activated carbons from sisal waste by chemical activation with K₂CO₃: kinetics of paracetamol and ibuprofen removal from aqueous solution.
abstract: Sisal waste was used as precursor to prepare carbons by chemical activation. The influence of the K(2)CO(3) amount and activation temperature on the materials textural properties were studied through N(2) and CO(2) adsorption assays. As the severity of the treatment increases there is a development of supermicropores, and the micropore size distribution changes from mono to bimodal. A carbon with an apparent surface area of 1,038 m(2)g(-1) and pore volume of 0.49 cm(3)g(-1) was obtained. TPD results showed the incidence in acidic type groups although the pH(PZC) reveals an almost neutral character of the surface. Adsorption kinetic data of ibuprofen and paracetamol show that the processes obey to a pseudo-second order kinetic equation. Regarding the removal efficiency the prepared samples attained values comparable to a commercial carbon (>65%), revealing that chemical activation of sisal wastes with K(2)CO(3) allows obtaining samples suitable for pharmaceutical compounds removal from liquid phase.
authors: Departamento de Química e Bioquímica and CQB, Faculdade de Ciências da Universidade de Lisboa, Ed. C8, Campo Grande, 1749-016 Lisboa, Portugal.
authors: Ana S
authors: AS
authors: Mestre
authors: Ana S
authors: AS
authors: Bexiga
authors: Margarida
authors: M
authors: Proença
authors: Marta
authors: M
authors: Andrade
authors: Moisés L
authors: ML
authors: Pinto
authors: Inês
authors: I
authors: Matos
authors: Isabel M
authors: IM
authors: Fonseca
authors: Ana P
authors: AP
authors: Carvalho
mesh_terms: D000082:Acetaminophen / Q000302:isolation & purification*; D000327:Adsorption; D000893:Anti-Inflammatory Agents / Q000302:isolation & purification*; D002244:Carbon / Q000737:chemistry*; D002254:Carbonates / Q000737:chemistry*; D007052:Ibuprofen / Q000302:isolation & purification*; D011188:Potassium / Q000737:chemistry*
chemical_list: D000893:Anti-Inflammatory Agents; D002254:Carbonates; D000082:Acetaminophen; D002244:Carbon; C037593:potassium carbonate; D011188:Potassium; D007052:Ibuprofen