title: Ionothermal synthesis and structure analysis of an open-framework zirconium phosphate with a high CO2/CH4 adsorption ratio.
abstract: Less is more: an open-framework zirconium phosphate with unusual 7-ring channels was synthesized ionothermally from a deep-eutectic solvent. This small-pore material displays a CO(2)/CH(4) adsorption ratio (17.3 at 1 bar) that is significantly higher than that of typical 8-ring materials, making it highly attractive for CO(2)/CH(4) separations.
authors: Research Institute of Special Chemicals, Taiyuan University of Technology, Shanxi, PR China.
authors: Lei
authors: L
authors: Liu
authors: Jiangfeng
authors: J
authors: Yang
authors: Jinping
authors: J
authors: Li
authors: Jinxiang
authors: J
authors: Dong
authors: Dubravka
authors: D
authors: Sišak
authors: Marisa
authors: M
authors: Luzzatto
authors: Lynne B
authors: LB
authors: McCusker
mesh_terms: D000327:Adsorption; D002245:Carbon Dioxide / Q000737:chemistry*; D008697:Methane / Q000737:chemistry*; D008968:Molecular Conformation; D015040:Zirconium / Q000737:chemistry*
chemical_list: C027006:zirconium phosphate; D002245:Carbon Dioxide; D015040:Zirconium; D008697:Methane