title: On the reactions of methyl radicals with TiO2 nanoparticles and granular powders immersed in aqueous solutions.
abstract: Methyl radicals react with TiO(2) nanoparticles (NPs) immersed in aqueous solutions to form transients in which the methyls are covalently bound to the particles. The rate constant for this reaction approaches the diffusion-controlled limit and increases somewhat with the number of methyls bound to the particle. The transients decompose to yield ethane. Thus, formally the particles "catalyse" the dimerization of the radicals, a reaction that is diffusion-controlled. Rutile powders behave similarly to the TiO(2) NPs whereas the mechanism for the decomposition of the transients formed in the analogous reaction of the radicals with anatase powders differs. These results are of importance as alkyl radicals are formed near the surface of TiO(2) in a variety of important photocatalytic processes. The results imply that the reactions of alkyl radicals with TiO(2) have to be considered in these processes.
authors: Chemistry Department, Ben-Gurion University of the Negev, Beer-Sheva, Israel.
authors: Olga
authors: O
authors: Golberg-Oster
authors: Ronen
authors: R
authors: Bar-Ziv
authors: Guy
authors: G
authors: Yardeni
authors: Israel
authors: I
authors: Zilbermann
authors: Dan
authors: D
authors: Meyerstein
mesh_terms: D002384:Catalysis; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D053758:Nanoparticles / Q000737:chemistry*; D055668:Photochemical Processes; D011208:Powders / Q000737:chemistry; D012996:Solutions; D014025:Titanium / Q000737:chemistry*; D014867:Water / Q000737:chemistry
chemical_list: D011208:Powders; D012996:Solutions; D014867:Water; C009495:titanium dioxide; C051224:methyl radical; D014025:Titanium; D008697:Methane