title: Highly selective reactions of unbiased alkenyl halides and alkylzinc halides: Negishi-Plus couplings.
abstract: High yielding stereo- and chemoselective Pd-catalyzed cross-couplings in THF at room temperature of alkenyl iodides and bromides with primary and secondary alkyl zinc iodides have been developed with the aid of N-methyimidazole as the key additive.
authors: Department of Chemistry & Biochemistry, University of California, Santa Barbara, California 93106, USA.
authors: Arkady
authors: A
authors: Krasovskiy
authors: Bruce H
authors: BH
authors: Lipshutz
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D006219:Halogens / Q000737:chemistry*; D007093:Imidazoles / Q000737:chemistry; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D000475:Alkenes; D006219:Halogens; D007093:Imidazoles; D010165:Palladium; C029899:imidazole