title: Regioselective carbon-carbon bond cleavage in the oxidation of cyclopropenylcarbinols.
abstract: The strained double bond of cyclopropenylcarbinols undergoes a facile oxidation reaction to lead to unsaturated carbonyl derivatives. The distribution of the formed products depends on the relative stability of carbon-centered radical species, and the Sharpless kinetic resolution leads to enantiomerically pure Baylis-Hillman enal adducts.
authors: Mallat Family Laboratory of Organic Chemistry, Schulich Faculty of Chemistry and the Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Technion City, Haifa 32000 Israel.
authors: Ahmad
authors: A
authors: Basheer
authors: Masaaki
authors: M
authors: Mishima
authors: Ilan
authors: I
authors: Marek