title: Achieving chemo-, regio-, and stereoselectivity in palladium-catalyzed reaction of γ-borylated allylic acetates.
abstract: Three-carbon highly functionalized γ-borylated allylic acetates underwent a regio- and stereocontrolled Tsuji-Trost reaction in the presence of palladium complexes. An ipso substitution of the acetate with complete stereoretention of the chiral center was achieved, leading to vinylic boronates with enantiomeric excesses above 99%.
authors: Chimie et Photonique Moléculaires, UMR CNRS 6510, Université Rennes 1, Campus de Beaulieu, 263 Avenue du Général Leclerc, F-35042 Rennes Cedex, France.
authors: Krishna Kishore
authors: KK
authors: Kukkadapu
authors: Aziz
authors: A
authors: Ouach
authors: Pedro
authors: P
authors: Lozano
authors: Michel
authors: M
authors: Vaultier
authors: Mathieu
authors: M
authors: Pucheault
mesh_terms: D000085:Acetates / Q000737:chemistry*; D000498:Allyl Compounds / Q000737:chemistry*; D001888:Boric Acids / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000085:Acetates; D000498:Allyl Compounds; D001888:Boric Acids; D010165:Palladium; C498551:allyl acetate; C032688:boric acid