title: Controlling adhesion force by means of nanoscale surface roughness.
abstract: Control of adhesion is a crucial aspect in the design of microelectromechanical and nanoelectromechanical devices. To understand the dependence of adhesion on nanometer-scale surface roughness, a roughness gradient has been employed. Monomodal roughness gradients were fabricated by means of silica nanoparticles (diameter ∼12 nm) to produce substrates with varying nanoparticle density. Pull-off force measurements on the gradients were performed using (polyethylene) colloidal-probe microscopy under perfluorodecalin, in order to restrict interactions to van der Waals forces. The influence of normal load on pull-off forces was studied and the measured forces compared with existing Hamaker-approximation-based models. We observe that adhesion force reaches a minimum value at an optimum particle density on the gradient sample, where the mean particle spacing becomes comparable with the diameter of the contact area with the polyethylene sphere. We also observe that the effect on adhesion of increasing the normal load depends on the roughness of the surface.
authors: Laboratory for Surface Science and Technology, Department of Materials, ETH Zurich, Wolfgang-Pauli-Strasse 10, 8093 Zurich, Switzerland.
authors: Shivaprakash N
authors: SN
authors: Ramakrishna
authors: Lucy Y
authors: LY
authors: Clasohm
authors: Akshata
authors: A
authors: Rao
authors: Nicholas D
authors: ND
authors: Spencer