title: Effects of high-pressure process on kinetics of leaching oil from soybean powder using hexane in batch systems.
abstract: Mass transfer models of leaching oil from soybean (Glycine max) flour with hexane after high-pressure process (HPP) treatment were developed. High pressure (450 MPa) was applied to the soybean flour (mean diameter of flour particle: 365 μm) for 30 min before leaching the oil components in the solvent. The ratio of solvent (volume, mL) to soybean flour (mass, g), such as 1:10 and 1:20, was employed to characterize the effect of solvent ratio on the leaching rate in the batch type of extraction process. Ultraviolet absorbance at 300 nm was used to monitor the extraction rate. Saturation solubility (C(AS)) was determined to be 21.73 kg/m³. The mass transfer coefficients (k) were determined based on the 1st- and 2nd-order kinetic models. The 2nd kinetic model showed better fit. The HPP treatment showed a higher extraction rate and yield compared to the control, while the amount of solvent did not affect the extraction rate and yield. The scanning electron microscope showed that HPP-treated soybean particles included more pores than the untreated. The pores observed in the HPP-treated soybean flours might help increase the mass transfer rate of solvent and solute in the solid matrix.
  
  
  CONCLUSIONS
  High-pressure processing can help increase the extraction rate of oil from the soybean flour operated in batch systems. The conventional solid to solvent ratio (1:20) used to extract oil composition from the plant seed did not help increase the amount of oil extracted from the soybean flour.
authors: Dept. of Food Science and Biotechnology, School of Biotechnology and Bioengineering, Kangwon Natl. Univ. Chuncheon, Kangwondo 200-701, South Korea.
authors: Joo Tae
authors: JT
authors: Uhm
authors: Won Byong
authors: WB
authors: Yoon
mesh_terms: D005511:Food Handling; D006586:Hexanes / Q000737:chemistry*; D006874:Hydrostatic Pressure; D007700:Kinetics; D008855:Microscopy, Electron, Scanning; D008956:Models, Chemical; D010316:Particle Size; D056910:Republic of Korea; D012639:Seeds / Q000737:chemistry* / Q000648:ultrastructure; D012995:Solubility; D012997:Solvents / Q000737:chemistry*; D045730:Soy Foods / Q000032:analysis; D013024:Soybean Oil / Q000737:chemistry / Q000302:isolation & purification*; D013025:Glycine max / Q000737:chemistry* / Q000648:ultrastructure; D013056:Spectrophotometry, Ultraviolet; D013499:Surface Properties
chemical_list: D006586:Hexanes; D012997:Solvents; C026385:n-hexane; D013024:Soybean Oil