title: Ligand effects on Negishi couplings of alkenyl halides.
abstract: Negishi couplings at olefinic centers do not always occur with the anticipated maintenance of stereochemistry. The source of erosion has been traced to the ligand, and a modified method has been developed that solves the stereochemical issue and significantly improves yields of Negishi couplings in general.
authors: Department of Chemistry & Biochemistry, University of California, Santa Barbara, California 93106, USA.
authors: Arkady
authors: A
authors: Krasovskiy
authors: Bruce H
authors: BH
authors: Lipshutz
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D006219:Halogens / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D000475:Alkenes; D006219:Halogens; D008024:Ligands