title: Silver-catalyzed intramolecular aminofluorination of activated allenes.
abstract: A nice combination: the intramolecular oxidative aminofluorination of allenes using silver catalysis and FN(SO(2)Ph)(2) as the fluorinating reagent has been developed. This reaction represents an efficient method for the synthesis of various 4-fluoro-2,5-dihydropyrrole compounds. Further transformation provided the corresponding fluorinated pyrrole derivatives in good yields.
authors.affiliation: State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, China.
authors.forename: Tao
authors.initials: T
authors.lastname: Xu
authors.forename: Xin
authors.initials: X
authors.lastname: Mu
authors.forename: Haihui
authors.initials: H
authors.lastname: Peng
authors.forename: Guosheng
authors.initials: G
authors.lastname: Liu
mesh_terms: D000466:Alkadienes / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D005461:Fluorine / Q000737:chemistry; D054879:Halogenation; D010084:Oxidation-Reduction; D011758:Pyrroles / Q000737:chemistry; D012834:Silver / Q000737:chemistry*
chemical_list: D000466:Alkadienes; D011758:Pyrroles; D005461:Fluorine; D012834:Silver; C025947:propadiene