title: Growth and characteristics of self-assembly defect-free GaN surface islands by molecular beam epitaxy.
abstract: GaN surface nano-islands of high crystal quality, without any dislocations or other extended defects, are grown on a c-plane sapphire substrate by plasma-assisted molecular beam epitaxy. Nano-island growth requires special conditions in terms of V/III ratio and substrate temperature, distinct from either film or nanocolumn growth. The insertion of a nitrided Ga layer can effectively improve the uniformity of the nano-islands in both shape and size. The islands are well faced truncated pyramids with island size ranged from 30 to 110 nm, and height ranged from 30 to 55 nm. On, the other hand, the density and facet of the GaN surface islands would be affected by the growth conditions. An increase of the V/III ratio from 30 to 40 led to an increase in density from 1.4 x 10(9) to 4.3 x 10(9) cm(-2) and an evolution from {1-21-1} facets to {1-21-2} facets. The GaN layers containing the surface islands can moderate the compressive strain due to the lattice and thermal mismatch between GaN and c-sapphire. Conductive atomic force microscopy shows that the off-axis sidewall facets are more electrically active than those at the island center. The formation of the GaN surface islands is strongly induced by the Ehrlich-Schwoebel barrier effect of preexisting islands grown in the early growth stage. GaN surface islands are ideal templates for growing nano-devices.
authors.affiliation: Department of Materials Science and Engineering, National Cheng Kung University, Tainan 70101, Taiwan, Republic of China.
authors.forename: Kuang-Yuan
authors.initials: KY
authors.lastname: Hsu
authors.forename: Cheng-Yu
authors.initials: CY
authors.lastname: Wang
authors.forename: Chuan-Pu
authors.initials: CP
authors.lastname: Liu
mesh_terms: D003460:Crystallization / Q000379:methods*; D005708:Gallium / Q000737:chemistry* / Q000528:radiation effects*; D020450:Heavy Ions; D046911:Macromolecular Substances / Q000737:chemistry / Q000528:radiation effects; D008422:Materials Testing; D008968:Molecular Conformation / Q000528:radiation effects; D049329:Nanostructures / Q000737:chemistry* / Q000528:radiation effects / Q000648:ultrastructure*; D010316:Particle Size; D013499:Surface Properties / Q000528:radiation effects
chemical_list: D046911:Macromolecular Substances; C473348:gallium nitride; D005708:Gallium