title: Silica SBA-15 template assisted synthesis of ultrasmall and homogeneously sized copper nanoparticles.
abstract: The synthesis of spherical copper nanoparticles with extremely narrow size distribution by electroless copper deposition on mesoporous silica support is described. The materials were characterized by nitrogen sorption, transmission electron microscopy, x-ray diffractometry and Fourier transform infrared spectroscopy. The copper nanoparticles have a cubic crystalline structure and an average particle size of 5.5 +/- 0.8 nm. The copper nanoparticles are stable, without detectable oxidation or further agglomeration under ambient conditions even after months. These results demonstrate that electroless copper reduction can be conducted and constrained within the mesoporous silica framework, which pave the way for engineered mesoreactors.
authors.affiliation: Department of Physics, Chemistry and Biology (IFM), Division of Nanostructured Materials, Linköping University, SE-581 83 Linköping, Sweden.
authors.forename: H T
authors.initials: HT
authors.lastname: Tsai
authors.forename: J M
authors.initials: JM
authors.lastname: Córdoba
authors.forename: E M
authors.initials: EM
authors.lastname: Johansson
authors.forename: M A
authors.initials: MA
authors.lastname: Ballem
authors.forename: M
authors.initials: M
authors.lastname: Odén
mesh_terms: D003300:Copper / Q000737:chemistry*; D003460:Crystallization / Q000379:methods*; D046911:Macromolecular Substances / Q000737:chemistry; D008422:Materials Testing; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D012822:Silicon Dioxide / Q000737:chemistry*; D013499:Surface Properties
chemical_list: D046911:Macromolecular Substances; C509969:SBA-15; D012822:Silicon Dioxide; D003300:Copper