title: (Z)-4-(2,5-Di-tert-butyl-anilino)pent-3-en-2-one.
abstract: In the crystal structure of the title ketoamine, C(19)H(29)NO, the bond lengths from the N atom through the alkene group to the ketone O atom show the presence of an extensively delocalized π-system. The dihedral angle between the plane of the phenyl ring and that of the alkene component is 63.45 (7)° due to steric hindrance exerted by the tert-butyl groups. The mol-ecule has a Z-configured alkene function, which is facilitated by an intra-molecular N-H⋯O hydrogen bond between the amine and ketone groups. The mol-ecules are linked into extended chains, which run parallel to the [010] direction, by a very weak C-H⋯O inter-action between the methyl substituent of the alkene group and the ketone O atom of a neighbouring mol-ecule.
authors.forename: Jesús
authors.initials: J
authors.lastname: Pastrán
authors.forename: Andrea
authors.initials: A
authors.lastname: Ramírez
authors.forename: Giuseppe
authors.initials: G
authors.lastname: Agrifoglio
authors.forename: Anthony
authors.initials: A
authors.lastname: Linden
authors.forename: Romano
authors.initials: R
authors.lastname: Dorta