title: Remotion of the antibiotic tetracycline by titania and titania-silica composed materials.
abstract: Removal of the antibiotic tetracycline (TC) by TiO(2) and the mesoporous binary system TiO(2)-SiO(2) have been studied in batch experiments by performing adsorption isotherms/kinetics and photodegradation kinetics under different conditions of pH, supporting electrolyte concentration, temperature, adsorbent amount, and TiO(2)-loading. On the one hand, the adsorption of TC on the studied materials is strongly dependent on pH, increasing as pH decreases. The adsorption mechanism, controlled by diffusion processes, is strongly related to electrostatic attractions and H-bond formations mainly between amide, carbonylic and phenolic groups of the antibiotic and the functional groups of TiO(2). The adsorption capacity at constant pH increases in the order TiO(2)<TiO(2)-SiO(2) mainly due to the highly surface area that the silica offers and to the homogenously dispersion of the TiO(2) nanocrystallites. On the other hand, the photodegradation rate is affected by the presence of the studied materials at several pH, although its photocatalytic activities are more important at pH 7 or lower. The photodegradation mechanisms seem to be related to the formation of OH radicals which are responsible for the decomposition of TC. The composed titania-silica materials might act not only as an excellent adsorbent but also act as an alternative photocatalyst for pollution control.
authors.affiliation: INQUISUR, Departamento de Química, Universidad Nacional del Sur, Av. Alem 1253, 8000 Bahía Blanca, Argentina. brigante@uns.edu.ar
authors.forename: Maximiliano
authors.initials: M
authors.lastname: Brigante
authors.forename: Pablo C
authors.initials: PC
authors.lastname: Schulz
mesh_terms: D000327:Adsorption; D000900:Anti-Bacterial Agents / Q000494:pharmacology*; D003460:Crystallization; D006860:Hydrogen Bonding; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D053758:Nanoparticles; D010777:Photochemistry / Q000379:methods; D010782:Photolysis; D012822:Silicon Dioxide / Q000737:chemistry*; D055672:Static Electricity; D013752:Tetracycline / Q000032:analysis* / Q000494:pharmacology*; D013816:Thermodynamics; D013997:Time Factors; D014025:Titanium / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis; D018508:Water Purification / Q000379:methods
chemical_list: D000900:Anti-Bacterial Agents; D014874:Water Pollutants, Chemical; C009495:titanium dioxide; D012822:Silicon Dioxide; D014025:Titanium; D013752:Tetracycline