title: Rapid synthesis of porous honeycomb Cu/Pd through a hydrogen-bubble templating method.
abstract: A rapid electrochemical method based on using a clean hydrogen-bubble template to form a bimetallic porous honeycomb Cu/Pd structure has been investigated. The addition of palladium salt to a copper-plating bath under conditions of vigorous hydrogen evolution was found to influence the pore size and bulk concentration of copper and palladium in the honeycomb bimetallic structure. The surface was characterised by X-ray photoelectron spectroscopy, which revealed that the surface of honeycomb Cu/Pd was found to be rich with a Cu/Pd alloy. The inclusion of palladium in the bimetallic structure not only influenced the pore size, but also modified the dendritic nature of the internal wall structure of the parent copper material into small nanometre-sized crystallites. The chemical composition of the bimetallic structure and substantial morphology changes were found to significantly influence the surface-enhanced Raman spectroscopic response for immobilised rhodamine B and the hydrogen-evolution reaction. The ability to create free-standing films of this honeycomb material may also have many advantages in the areas of gas- and liquid-phase heterogeneous catalysis.
authors.affiliation: School of Applied Sciences, RMIT University, GPO Box 2476V, Melbourne, VIC 3001, Australia.
authors.forename: Ilija
authors.initials: I
authors.lastname: Najdovski
authors.forename: P R
authors.initials: PR
authors.lastname: Selvakannan
authors.forename: Anthony P
authors.initials: AP
authors.lastname: O'Mullane
authors.forename: Suresh K
authors.initials: SK
authors.lastname: Bhargava