title: Bis(3,5-dimethyl-1H-pyrazole-κN)silver(I) hexa-fluorido-anti-monate.
abstract: The title compound, [Ag(C(5)H(8)N(2))(2)]SbF(6), contains an Ag(+) cation almost linearly bonded to two N atoms of dimethylpyrazole ligands [N-Ag-N = 176.54 (18)°]. The structure exhibits hydrogen bonding between the two dimethyl-pyrazole H atoms and two F atoms of one hexa-fluorido-anti-monate anion. Three relatively short Ag⋯F contacts [2.869 (6), 2.920 (7), and 3.094 (7) Å] exist between the cation and three different SbF(6) (-) anions. The crystal used for data collection was found to be twinned by non-merohedry, with the two components being related by a 180° rotation around the real or reciprocal a axis. Integration resulted in 11.2% of the total peaks being assigned to component 1, 11.2% to component 2, and 77.6% to both components.
authors.affiliation: CB 4160, Department of Chemistry, Illinois State University, Normal, IL 61790, USA.
authors.forename: Devyn
authors.initials: D
authors.lastname: Crawford
authors.forename: Anthony K
authors.initials: AK
authors.lastname: Hofer
authors.forename: Kate L
authors.initials: KL
authors.lastname: Edler
authors.forename: Gregory M
authors.initials: GM
authors.lastname: Ferrence