title: cyclo-Tri-μ-oxido-tris-{[(η,η)-1,2-bis-(cyclo-penta-dien-yl)-1,1,2,2-tetra-methyl-disilane]zirconium(IV)}: a trimeric disila-bridged oxidozirconocene.
abstract: The title compound, [Zr(3)(C(14)H(20)Si(2))(3)O(3)], consists of three disila-bridged zirconocene units, which are connected via an oxide ligand, forming a nearly planar six-membered ring with a maximum displacement of 0.0191 (8) Å. The compound was isolated as a by-product from a mixture of [(C(5)H(4)SiMe(2))(2)ZrCl(2)] and Li[AlH(4)] in Et(2)O.
authors.affiliation: Institut für Anorganische Chemie, Universität Würzburg, Am Hubland, D-97074 Würzburg, Germany.
authors.forename: Thomas
authors.initials: T
authors.lastname: Arnold
authors.forename: Holger
authors.initials: H
authors.lastname: Braunschweig
authors.forename: Katrin
authors.initials: K
authors.lastname: Gruss