title: A coupled THC model of the FEBEX in situ test with bentonite swelling and chemical and thermal osmosis.
abstract: The performance assessment of a geological repository for radioactive waste requires quantifying the geochemical evolution of the bentonite engineered barrier. This barrier will be exposed to coupled thermal (T), hydrodynamic (H), mechanical (M) and chemical (C) processes. This paper presents a coupled THC model of the FEBEX (Full-scale Engineered Barrier EXperiment) in situ test which accounts for bentonite swelling and chemical and thermal osmosis. Model results attest the relevance of thermal osmosis and bentonite swelling for the geochemical evolution of the bentonite barrier while chemical osmosis is found to be almost irrelevant. The model has been tested with data collected after the dismantling of heater 1 of the in situ test. The model reproduces reasonably well the measured temperature, relative humidity, water content and inferred geochemical data. However, it fails to mimic the solute concentrations at the heater-bentonite and bentonite-granite interfaces because the model does not account for the volume change of bentonite, the CO(2)(g) degassing and the transport of vapor from the bentonite into the granite. The inferred HCO(3)(-) and pH data cannot be explained solely by solute transport, calcite dissolution and protonation/deprotonation by surface complexation, suggesting that such data may be affected also by other reactions.
authors.affiliation: Lawrence Berkeley National Laboratory, Berkeley, CA 94720, USA. lzheng@lbl.gov
authors.forename: Liange
authors.initials: L
authors.lastname: Zheng
authors.forename: Javier
authors.initials: J
authors.lastname: Samper
authors.forename: Luis
authors.initials: L
authors.lastname: Montenegro
mesh_terms: D000327:Adsorption; D001546:Bentonite / Q000737:chemistry*; D002119:Calcium Carbonate / Q000737:chemistry; D008962:Models, Theoretical; D009995:Osmosis; D011850:Radioactive Waste; D012822:Silicon Dioxide; D013696:Temperature; D018505:Waste Management
chemical_list: D011850:Radioactive Waste; C007886:granite; D001546:Bentonite; D012822:Silicon Dioxide; D002119:Calcium Carbonate