title: A Ferrier-type allylic rearrangement of 3'-deoxy-3',4'-didehydronucleosides mediated by DMF dimethyl acetal: direct access to 4'-alkoxy-2',3'-didehydro-2',3'-dideoxynucleosides.
abstract: A straightforward synthesis of epimeric 4'-alkoxy-substituted 2',3'-didehydro-2',3'-dideoxynucleosides via a DMF dimethyl acetal mediated allylic rearrangement of 3'-deoxy-3',4'-didehydronucleosides is described.
authors.affiliation: Institute of Organic Chemistry and Biochemistry, Academy of Sciences of the Czech Republic, v.v.i., Flemingovo nám. 2, 166 10 Praha 6, Czech Republic.
authors.forename: Magdalena
authors.initials: M
authors.lastname: Petrová
authors.forename: Miloš
authors.initials: M
authors.lastname: Buděšínský
authors.forename: Eva
authors.initials: E
authors.lastname: Zborníkovš
authors.forename: Pavel
authors.initials: P
authors.lastname: Fiedler
authors.forename: Ivan
authors.initials: I
authors.lastname: Rosenberg
mesh_terms: D000080:Acetals / Q000737:chemistry*; D000498:Allyl Compounds / Q000737:chemistry*; D015224:Dideoxynucleosides / Q000138:chemical synthesis*; D005557:Formaldehyde / Q000737:chemistry*; D008745:Methylation; D015394:Molecular Structure
chemical_list: D000080:Acetals; D000498:Allyl Compounds; D015224:Dideoxynucleosides; D005557:Formaldehyde