title: [1,5]-H shift of aldehyde hydrogen in dienal compounds to produce ketenes.
abstract: In 3-ethoxycarbonyl-2,4-dienal compounds, a thermal [1,5]-H shift of aldehyde hydrogen easily proceeded to produce the corresponding vinyl ketenes due to the remarkable substituent effect caused by the C3 ester group. The produced ketenes were captured by an alcohol and olefins to afford the corresponding esters and four-membered ring compounds, respectively.
authors.affiliation: School of Science and Technology, Kwansei Gakuin University, Gakuen 2-1, Sanda, Hyogo 669-1337, Japan.
authors.forename: Taku
authors.initials: T
authors.lastname: Sakaguchi
authors.forename: Yudai
authors.initials: Y
authors.lastname: Okuno
authors.forename: Yohei
authors.initials: Y
authors.lastname: Tsutsumi
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Tsuchikawa
authors.forename: Shigeo
authors.initials: S
authors.lastname: Katsumura