title: Regioselective synthesis of fused oxazepinone scaffolds through one-pot Smiles rearrangement tandem reaction.
abstract: The paper describes a convenient and facile methodology for the regioselective synthesis of fused oxazepinone scaffolds. This process is an efficient construction of the oxazepinone scaffold by a one-pot coupling/Smiles rearrangement/cyclization approach. This transition metal-free process has potential applications in the synthesis of biologically and medicinally relevant compounds.
authors.affiliation: School of Chemistry and Chemical Engineering, Shandong University, Jinan, PR China.
authors.forename: Yanli
authors.initials: Y
authors.lastname: Liu
authors.forename: Chunxiao
authors.initials: C
authors.lastname: Chu
authors.forename: Aiping
authors.initials: A
authors.lastname: Huang
authors.forename: Chunjing
authors.initials: C
authors.lastname: Zhan
authors.forename: Ying
authors.initials: Y
authors.lastname: Ma
authors.forename: Chen
authors.initials: C
authors.lastname: Ma
mesh_terms: D001555:Benzene Derivatives / Q000737:chemistry*; D060326:Chemistry Techniques, Synthetic; D018360:Crystallography, X-Ray; D003500:Cyclization; D008958:Models, Molecular; D015394:Molecular Structure; D010077:Oxazepines / Q000138:chemical synthesis* / Q000737:chemistry; D011725:Pyridines / Q000737:chemistry*; D012457:Salicylamides / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D001555:Benzene Derivatives; D010077:Oxazepines; D011725:Pyridines; D012457:Salicylamides