title: Ammonium 4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ide.
abstract: In the title salt, NH(4) (+)·C(4)H(3)N(2)O(2)S(-), the asymmetric unit comprises two half-occupied ammonium positions and a 4,6-dioxo-2-sulfanylidene-1,3-diazinan-5-ide anion. The anion shows C(2) as well as C(s) symmetry and is present in its diketonic tautomeric form. Intra-cyclic angles span a range from 116.64 (9)-124.67 (9)°. Inter-molecular N-H⋯O hydrogen bonds connect the cations and anions to form a three-dimensional network.
authors.affiliation: Nelson Mandela Metropolitan University, Summerstrand Campus, Department of Chemistry, University Way, Summerstrand, PO Box 77000, Port Elizabeth 6031, South Africa.
authors.forename: Richard
authors.initials: R
authors.lastname: Betz
authors.forename: Thomas
authors.initials: T
authors.lastname: Gerber