title: Bis(2-amino-1,3-benzothia-zol-3-ium) tetra-chloridozincate(II).
abstract: The asymmetric unit of the title compound, (C(7)H(7)N(2)S)(2)[ZnCl(4)], contains a network of 2-amino-benzothia-zolium cations and tetra-hedral [ZnCl(4)](2-) anions. The crystal packing is influenced by cation-to-anion N-H⋯Cl and C-H⋯Cl hydrogen bonds. The [ZnCl(4)](2-) anions have a distorded tetra-hedral geometry. Inter-molecular π-π stacking inter-actions are present between neighboring benzene rings, thia-zole and benzene rings and neighboring thia-zole rings [centroid-centroid distances = 3.711 (2), 3.554 (1), 3.536 (2) and 3.572 (1) Å].
authors.forename: Riadh
authors.initials: R
authors.lastname: Kefi
authors.forename: Erwann
authors.initials: E
authors.lastname: Jeanneau
authors.forename: Frédéric
authors.initials: F
authors.lastname: Lefebvre
authors.forename: Cherif
authors.initials: C
authors.lastname: Ben Nasr