title: Synthesis of 1,3,5-alternate azacalix[3]pyridine[3]pyrimidine and its complexation with fullerenes via multiple π/π and CH/π interactions.
abstract: Azacalix[3]pyridine[3]pyrimidine was synthesized efficiently by means of a [3+3] fragment coupling approach. Adopting a preorganized symmetric 1,3,5-alternate conformation, the macrocycle formed complexes with fullerenes through the multiple intramolecular π/π and CH/π interactions.
authors.affiliation: Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China.
authors.forename: Li-Xia
authors.initials: LX
authors.lastname: Wang
authors.forename: Liang
authors.initials: L
authors.lastname: Zhao
authors.forename: De-Xian
authors.initials: DX
authors.lastname: Wang
authors.forename: Mei-Xiang
authors.initials: MX
authors.lastname: Wang
mesh_terms: D047250:Calixarenes / Q000737:chemistry*; D037741:Fullerenes / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D011743:Pyrimidines / Q000138:chemical synthesis* / Q000737:chemistry*
chemical_list: C568308:1,3,5-alternate azacalix(3)pyridine(3)pyrimidine; D037741:Fullerenes; D011743:Pyrimidines; D047250:Calixarenes