title: Poly[μ-(5,5'-diazenediylditetra-zolido)-dicaesium].
abstract: The asymmetric unit of the title compound, [Cs(2)(C(2)N(10))](n), comprises a Cs(+) cation, and one-half of a 5,5'-diazenediylditetra-zolide anion. The Cs(+) cation is six-coordinated by N atoms from six 5,5'-diazenediylditetra-zolide ligands. Each 5,5'-diazenediylditetra-zolide ligand is surrounded by 12 Cs(+) cations, coordinating through ten N atoms. The Cs(+) cations are arranged in a chain along the a-axis direction with a Cs⋯Cs separation of 4.4393 (10) Å. Such coordination leads to the formation of the three-dimensional framework.
authors.affiliation: School of Environmental Engineering, Chang'an University, South Second Cycle Road 368#, Xi'an 710064, Shaanxi, People's Republic of China.
authors.forename: Yan
authors.initials: Y
authors.lastname: Meng