title: A novel low density metal-organic framework with pcu topology by dendritic ligand.
abstract: A novel low density two-fold interpenetrated MOF-5 analogue with pcu topology, JUC-100, was designed and prepared successfully. It can be regarded as MOF-5 in which half of the Zn(4)O(CO(2))(6) units are replaced by organic 1,3,5-triphenylbenzene segments. JUC-100 exhibits H(2) uptake ability comparable to interpenetrated MOF-5, but relatively low initial isosteric heat of adsorption.
authors.affiliation: State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China.
authors.forename: Jiangtao
authors.initials: J
authors.lastname: Jia
authors.forename: Fuxing
authors.initials: F
authors.lastname: Sun
authors.forename: Qianrong
authors.initials: Q
authors.lastname: Fang
authors.forename: Xiaoqiang
authors.initials: X
authors.lastname: Liang
authors.forename: Kun
authors.initials: K
authors.lastname: Cai
authors.forename: Zheng
authors.initials: Z
authors.lastname: Bian
authors.forename: Huijun
authors.initials: H
authors.lastname: Zhao
authors.forename: Lianxun
authors.initials: L
authors.lastname: Gao
authors.forename: Guangshan
authors.initials: G
authors.lastname: Zhu
mesh_terms: D000327:Adsorption; D001555:Benzene Derivatives / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry; D006859:Hydrogen / Q000302:isolation & purification; D008024:Ligands; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D017967:Zinc Compounds / Q000737:chemistry*
chemical_list: D001555:Benzene Derivatives; D002264:Carboxylic Acids; D008024:Ligands; D009942:Organometallic Compounds; D017967:Zinc Compounds; D006859:Hydrogen