title: Optimisation of the enamelling of an apatite-mullite glass-ceramic coating on Ti6Al4V.
abstract: Apatite-mullite glass-ceramics (AMGCs) are under investigation as a potential alternative to hydroxyapatite (HA) as a coating for cementless fixation of orthopaedic implants. These materials have tailorable mechanical and chemical properties that make them attractive for use as bioactive coatings. Here, AMGC coatings on Ti(6)Al(4)V were investigated to determine an improved heat treatment regime using a systematic examination of the different inputs: composition of glass, nucleation hold and crystallisation hold. An upper limit to the heat treatment temperature was determined by the α + β --> β of Ti(6)Al(4)V at 970°C. The glass composition was modified to produce different crystallisation temperatures and sintering characteristics. A glass was found that is fully crystalline below 970°C and has good sinterability. The effects of different heat treatment time and temperature combinations on the coating and substrate morphologies were examined and the most suitable combination determined. This sample was further investigated and was found to have qualitatively good adhesion and evidence of an interfacial reaction region between the coating and substrate indicating that a chemical reaction had occurred. Oxygen infiltration into the substrate was quantified and the new route was shown to result in a 63% reduction in penetration depth.
authors.affiliation: School of Mechanical and Materials Engineering, University College Dublin, Belfield, Dublin 4, Ireland.
authors.forename: Kevin P
authors.initials: KP
authors.lastname: O'Flynn
authors.forename: Kenneth T
authors.initials: KT
authors.lastname: Stanton
mesh_terms: D000497:Alloys; D001031:Apatites / Q000737:chemistry*; D002152:Calorimetry, Differential Scanning; D002516:Ceramics; D003460:Crystallization; D005898:Glass; D006358:Hot Temperature; D008855:Microscopy, Electron, Scanning; D011208:Powders; D014025:Titanium / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D000497:Alloys; D001031:Apatites; D011208:Powders; C031462:titanium alloy (TiAl6V4); D014025:Titanium