title: Benzyl-aminium perchlorate-18-crown-6 (1/1).
abstract: In the title compound, C(7)H(10)N(+)·ClO(4) (-)·C(20)H(24)O(6), the proton-ated benzyl-amine cation forms a rotator-stator complex with the 18-crown-6 (1,4,7,10,13,16-hexa-oxacyclo-octa-deca-ne) mol-ecule via N-H⋯O hydrogen bonds. The cations are associated via weak C-H⋯π inter-actions, forming chains parallel to [011], while the perclorate anions are located between these chains.
authors.affiliation: RiZhao Polytechnic, RiZhao 276826, People's Republic of China.
authors.forename: Wen-Zhe
authors.initials: WZ
authors.lastname: Wang
authors.forename: Xiu-Juan
authors.initials: XJ
authors.lastname: Li
authors.forename: Na
authors.initials: N
authors.lastname: Wang