title: [N,N,N',N'-Tetra-kis(benzimidazol-2-ylmeth-yl)cyclo-hexane-1,2-trans-diamine]-iron(II) bis-(perchlorate) methanol solvate.
abstract: In the title compound, [Fe(C(38)H(38)N(10))](ClO(4))(2)·CH(3)OH, the Fe(II) atom has a distorted octa-hedral coordination environment with four benzimidazol N atoms and two amino N atoms from an N,N,N',N'-tetra-kis-(benzimidazol-2-ylmeth-yl)cyclo-hexane-1,2-trans-diamine ligand. The uncoordinated solvent methanol mol-ecule is hydrogen bonded to an O atom of a perchlorate anion. One of the perchlorate anions is disordered over two sets of sites with occupancy factors of 0.539 (14) and 0.461 (14). N-H⋯O and C-H⋯O hydrogen bonds, as well as π-π stacking inter-actions between the imidazol rings and between the imidazol and benzene rings [centroid-centroid distances = 3.714 (2) and 3.705 (2) Å] give rise to a three-dimensional network.
authors.affiliation: Key Laboratory of Pesticide & Chemical Biology, Ministry of Education, College of Chemistry, Central China Normal University, Wuhan 430079, People's Republic of China.
authors.forename: Gui-Ling
authors.initials: GL
authors.lastname: Wu
authors.forename: Chun-Ping
authors.initials: CP
authors.lastname: Ou
authors.forename: Feng
authors.initials: F
authors.lastname: Wang
authors.forename: Jian-Ming
authors.initials: JM
authors.lastname: Zhang
authors.forename: She-Min
authors.initials: SM
authors.lastname: Lan