title: Bis(1,10-phenanthroline-κN,N')bis-(thio-cyanato-κN)cadmium.
abstract: The title compound, [Cd(NCS)(2)(C(12)H(8)N(2))(2)], has been obtained from the decomposition reaction of dithio-oxamide in a dimethyl-formamide solution containing 1,10-phenanthroline (phen) and Cd(NO(3))(2)·4H(2)O. Its crystal structure is formed by monuclear Cd(II) entities in which the metal atom is sited on a twofold rotation axis. The Cd(II) atom is six-coordinated in the form of a distorted octa-hedron by two chelating phenanthroline mol-ecules and two thio-cyanate anions coordinated through their N atoms. In the crystal, C-H⋯N hydrogen bonds are established between the phenanthroline and thio-cyanate ligands of neighbouring complexes.
authors.affiliation: Departamento de Química Inorgánica, Facultad de Ciencia y Tecnología, Universidad del País Vasco, Apdo. 644, E-48080 Bilbao, Spain.
authors.forename: Daniel
authors.initials: D
authors.lastname: Vallejo
authors.forename: Garikoitz
authors.initials: G
authors.lastname: Beobide
authors.forename: Oscar
authors.initials: O
authors.lastname: Castillo
authors.forename: Antonio
authors.initials: A
authors.lastname: Luque