title: {4-Bromo-2-[(2-sulfido-phen-yl)imino-meth-yl]phenolato-κS,N,O}(triphenyl-phosphane-κP)nickel(II).
abstract: The Ni(II) atom in the title complex, [Ni(C(13)H(8)BrNOS)(C(18)H(15)P)], is coordinated by the N, O and S atoms of the dianionic tridentate ligand, and its square-planar geometry is completed by a phosphane P atom. The dihedral angle between the aromatic rings in the 4-bromo-2-[(2-sulfido-phen-yl)imino-meth-yl]phenolate ligand is 2.01 (14)°. The most prominent feature of the packing is the presence of supra-molecular chains aligned along the a axis, mediated by C-H⋯S inter-actions.
authors.forename: M Muthu
authors.initials: MM
authors.lastname: Tamizh
authors.forename: R
authors.initials: R
authors.lastname: Karvembu
authors.forename: B
authors.initials: B
authors.lastname: Varghese
authors.forename: Edward R T
authors.initials: ER
authors.lastname: Tiekink