title: Asymmetric addition of pyridine to 1,4-bis(ethynyl)bicyclo[2.2.2]octane: dissymmetrical rotator ligands illustrated in dpppPt(II) and [Re6Se8]2+ complexes and an amphidynamic hydrogen bonded framework solid.
abstract: A polar function like pyridine increases the polarity difference between mono- and disubstituted 1,4-bis(trimethylsilylethynyl)bicyclo[2.2.2]octane cores allowing for their ready separation by chromatography, affording two dissymmetrical ligands illustrated in metal-rotor hybrids like a corner-shaped mononuclear complex, an octahedral hexanuclear metal complex, and a framework solid with a rather slow rotator.
authors.affiliation: Laboratoire MOLTECH-Anjou, CNRS, Université d'Angers, 49045, Angers, France.
authors.forename: C
authors.initials: C
authors.lastname: Lemouchi
authors.forename: A-L
authors.initials: AL
authors.lastname: Barrès
authors.forename: C
authors.initials: C
authors.lastname: Mézière
authors.forename: D
authors.initials: D
authors.lastname: Rondeau
authors.forename: L
authors.initials: L
authors.lastname: Zorina
authors.forename: P
authors.initials: P
authors.lastname: Wzietek
authors.forename: P
authors.initials: P
authors.lastname: Batail