title: Submicrometer intermediates in the citrate synthesis of gold nanoparticles: new insights into the nucleation and crystal growth mechanisms.
abstract: The reduction of tetrachloroaurate by citrate ions in aqueous solutions yielding gold nanoparticles (GNPs) has been studied using in situ tapping mode atomic force microscopy (AFM), UV-vis absorption and dynamic light scattering (DLS) spectroscopies, small-angle X-ray scattering (SAXS) along with ex situ TEM, EDX and XPS. Special attention is given to mesoscale intermediates responsible for the intense coloring of the transient solutions and their role in nucleation and crystal growth. AFM detects liquid droplet-like domains, globules 30-50 nm in diameter arranged in submicrometer aggregates in the gray and blue solutions, and well separated individual particles in the final red sols. DLS shows abrupt appearance of species about 30 nm and larger but not growing Au nanoparticles, while SAXS reveals gradually increasing nanoparticles and no aggregates. The mesoscale structures observed in TEM become looser as the reaction proceeds; they contain signatures of oxidized Au and other solutes. The results are interpreted in terms of decomposition of supersaturated solutions to afford domains ("dense droplets") enriched by gold, and then, after nucleation and coalescence of Au nuclei inside them, rather slow growth of gold nanoparticles within the associated globules; the color changes of the transient solutions are due to increasing interparticle distances.
authors.affiliation: Institute of Chemistry and Chemical Technology of Siberian Branch of Russian Academy of Sciences, K. Marx Street, 42, Krasnoyarsk 660049, Russia. soejima@apch.kindai.ac.jp
authors.forename: Yuri
authors.initials: Y
authors.lastname: Mikhlin
authors.forename: Anton
authors.initials: A
authors.lastname: Karacharov
authors.forename: Maxim
authors.initials: M
authors.lastname: Likhatski
authors.forename: Tatyana
authors.initials: T
authors.lastname: Podlipskaya
authors.forename: Yan
authors.initials: Y
authors.lastname: Zubavichus
authors.forename: Alexey
authors.initials: A
authors.lastname: Veligzhanin
authors.forename: Vladimir
authors.initials: V
authors.lastname: Zaikovski