title: Chiral N-tert-butanesulfinyl α,β-unsaturated ketimine: a simple and highly effective olefin/sulfinimide hybrid ligand for asymmetric 1,4-additions.
abstract: One novel type of chiral olefin/sulfinimide hybrid ligands has been developed through a simple one-step condensation of α,β-unsaturated ketones with tert-butanesulfinamide and utilized successfully for rhodium-catalyzed asymmetric conjugated additions to furnish the desired adducts in high yields with excellent ee's.
authors.affiliation: Beijing National Laboratory of Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China.
authors.forename: Xiangqing
authors.initials: X
authors.lastname: Feng
authors.forename: Beibei
authors.initials: B
authors.lastname: Wei
authors.forename: Jing
authors.initials: J
authors.lastname: Yang
authors.forename: Haifeng
authors.initials: H
authors.lastname: Du