title: A guest-induced reversible switching of a self-assembled H-bonded supramolecular framework.
abstract: A new class of organic crystalline 2,2'-biphenol-based H-bonded material displaying 1D-channels encapsulating solvent molecules is described. A reversible guest-induced crystal-to-crystal conversion between the solvated H-bonded phase and a compact H-bonded non-solvated phase was observed. The energy competition between intramolecular H-bonds formation and solvation of organic pores has been characterized using PACHA calculations.
authors.affiliation: Laboratoire de Chimie Moléculaire de l'Etat Solide, UMR 7140, Université de Strasbourg, 67070 Strasbourg, France. mobian@unistra.fr henry@unistra.fr
authors.forename: Pierre
authors.initials: P
authors.lastname: Mobian
authors.forename: Clarisse
authors.initials: C
authors.lastname: Huguenard
authors.forename: Marc
authors.initials: M
authors.lastname: Henry