title: Pseudorotaxane-type n-hydrocarbon container. Metallacyclodimer of ionic palladium(II) complexes containing 1,3-bis(4-pyridyl)tetramethyldisiloxane.
abstract: An unusual "pseudorotaxaned n-alkane within a metalla-cyclodimer" system, C(n)H(2n+2)@[(Me(4)en)Pd(L)](2)(CF(3)SO(3))(4) (n = 5, 6, 7; Me(4)en = N,N,N',N'-tetramethylethylenediamine; L = 1,3-bis(4-pyridyl)tetramethyldisiloxane), was constructed. This system is the first pseudorotaxane-type petroleum container achieved via the appropriate size effect.
authors.affiliation: Department of Chemistry, Pusan National University, Pusan, 609-735, Republic of Korea.
authors.forename: Jungmin
authors.initials: J
authors.lastname: Ahn
authors.forename: Sung
authors.initials: S
authors.lastname: Min Kim
authors.forename: Tae
authors.initials: T
authors.lastname: Hwan Noh
authors.forename: Ok-Sang
authors.initials: OS
authors.lastname: Jung
mesh_terms: D006838:Hydrocarbons; D010165:Palladium; D010578:Petroleum; D019064:Product Packaging; D043862:Rotaxanes / Q000138:chemical synthesis* / Q000737:chemistry; D012833:Siloxanes
chemical_list: D006838:Hydrocarbons; D010578:Petroleum; D043862:Rotaxanes; D012833:Siloxanes; D010165:Palladium