title: Improved soil fumigation by Telone C35 using carbonation.
abstract: Soil fumigation to control pests and pathogens is an important part of current agricultural practice. A reduction in fumigant emissions is required to ensure worker safety and environment health. A field trial in Florida was conducted to investigate whether carbonating Telone C35™ ((Z)- and (E)-1,3-dichloropropene with 35 % chloropicrin) would improve the delivery of the fumigant to such an extent that the application rate could be decreased without sacrificing efficacy. All treatments were carried out in three replications in a complete block design. The use of carbon dioxide (CO(2)) to carbonate and pressurize Telone C35 provided quicker and deeper distribution initially compared to application by nitrogen gas (N(2)) pressurization. The deeper distribution of Telone C35 components found with CO(2) application may have lowered the initial concentration of Telone C35, but it did not appreciably alter the disappearance rate of the three chemicals, chloropicrin, (Z)- and (E)-1,3-dichloropropene. The faster vertical distribution within the bedded soil of the Telone C35 by CO(2) did enhance volatilization of the active ingredients into the atmosphere compared to volatilization of similar reduced rate applied by N(2) pressurization. However, the cumulative amount volatilized from the carbonated fumigant beds at 75 % application rate was lower than the cumulative amount emitted by full rate of Telone C35 using N(2). The efficacy of the carbonated Telone C35 at a lower application rate was statistically equivalent to that of non-carbonated fumigant using N(2) pressurized injection at a higher application rate, based on weed enumeration and the root-knot nematode galling index.
authors.affiliation: Soil and Water Science Department, University of Florida, Gainesville, FL 32611, USA. Thomas@UFL.EDU
authors.forename: J E
authors.initials: JE
authors.lastname: Thomas
authors.forename: L T
authors.initials: LT
authors.lastname: Ou
authors.forename: L H
authors.initials: LH
authors.lastname: Allen
authors.forename: J C
authors.initials: JC
authors.lastname: Vu
authors.forename: D W
authors.initials: DW
authors.lastname: Dickson
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry*; D000818:Animals; D002245:Carbon Dioxide / Q000737:chemistry; D002254:Carbonates / Q000737:chemistry; D005651:Fumigation / Q000379:methods*; D006843:Hydrocarbons, Chlorinated; D009348:Nematoda / Q000187:drug effects; D010575:Pesticides / Q000737:chemistry / Q000494:pharmacology*; D012987:Soil / Q000032:analysis* / Q000469:parasitology; D014835:Volatilization
chemical_list: D000498:Allyl Compounds; D002254:Carbonates; D006843:Hydrocarbons, Chlorinated; D010575:Pesticides; D012987:Soil; D002245:Carbon Dioxide; C023891:1,3-dichloro-1-propene