title: An unusual reaction of α-alkoxyphosphonium salts with Grignard reagents under an O2 atmosphere.
abstract: An unusual and novel reaction of α-alkoxyphosphonium salts, generated from O,O-acetals and Ph(3)P, with Grignard reagents under an O(2) atmosphere afforded alcohols in moderate to high yields. It was clarified by isotopic labelling experiments that the reaction proceeded via a novel radical pathway.
authors.affiliation: Graduate School of Pharmaceutical Sciences, Osaka University, Suita, Osaka, Japan. fujioka@phs.osaka-u.ac.jp
authors.forename: Hiromichi
authors.initials: H
authors.lastname: Fujioka
authors.forename: Akihiro
authors.initials: A
authors.lastname: Goto
authors.forename: Kazuki
authors.initials: K
authors.lastname: Otake
authors.forename: Ozora
authors.initials: O
authors.lastname: Kubo
authors.forename: Yoshinari
authors.initials: Y
authors.lastname: Sawama
authors.forename: Tomohiro
authors.initials: T
authors.lastname: Maegawa
mesh_terms: D001272:Atmosphere / Q000737:chemistry*; D007202:Indicators and Reagents / Q000737:chemistry; D009943:Organophosphorus Compounds / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*
chemical_list: D007202:Indicators and Reagents; D009943:Organophosphorus Compounds; D010100:Oxygen