title: 4,4'-, 5,5'-, and 6,6'-dimethyl-2,2'-bipyridyls: the structures, phase transitions, vibrations, and methyl group tunneling of their complexes with chloranilic acid.
abstract: The crystal and molecular structures of 4,4(')- and 6,6(')-dimethyl-2,2(')-bipyridyl complexes with 2,5-dichloro-3,6-dihydroxy-p-benzoquinone (chloranilic acid, CLA) have been determined and compared with those of the complex with the 5,5(')-derivative, which is known to possess interesting antiferroelectric properties. In the crystalline state, all three compounds form hydrogen bonded chains with N(+)-H···O(-) and O-H···N bridges on both sides of the bipyridyl constituent. The comparison of three derivatives indicates that the N(+)-H···O(-) hydrogen bonds are shortest for the 5,5(')-dimethyl complex. The 4,4(')- and 6,6(')-derivatives do not show any ferroelectric feature. The 6,6(')-one is, however, characterized by a continuous phase transition, revealed in the differential scanning calorimetry, dilatometric, and dielectric characteristics. The tunneling splitting measured by neutron backscattering in the energy range ±30 μeV for the neat dimethyl bipyridyls and their complexes with CLA indicates that the different splittings are primarily due to the crystal packing effect and that charge transfer between interacting compounds plays only a minor role.
authors.affiliation: Faculty of Chemistry, University of Wrocław, Joliot-Curie 14, 50-383 Wrocław, Poland. gb@wchuwr.pl
authors.forename: G
authors.initials: G
authors.lastname: Bator
authors.forename: W
authors.initials: W
authors.lastname: Sawka-Dobrowolska
authors.forename: L
authors.initials: L
authors.lastname: Sobczyk
authors.forename: E
authors.initials: E
authors.lastname: Grech
authors.forename: J
authors.initials: J
authors.lastname: Nowicka-Scheibe
authors.forename: A
authors.initials: A
authors.lastname: Pawlukojć
authors.forename: J
authors.initials: J
authors.lastname: Wuttke
authors.forename: J
authors.initials: J
authors.lastname: Baran
authors.forename: M
authors.initials: M
authors.lastname: Owczarek