title: Direct laser writing of micro-supercapacitors on hydrated graphite oxide films.
abstract: Microscale supercapacitors provide an important complement to batteries in a variety of applications, including portable electronics. Although they can be manufactured using a number of printing and lithography techniques, continued improvements in cost, scalability and form factor are required to realize their full potential. Here, we demonstrate the scalable fabrication of a new type of all-carbon, monolithic supercapacitor by laser reduction and patterning of graphite oxide films. We pattern both in-plane and conventional electrodes consisting of reduced graphite oxide with micrometre resolution, between which graphite oxide serves as a solid electrolyte. The substantial amounts of trapped water in the graphite oxide makes it simultaneously a good ionic conductor and an electrical insulator, allowing it to serve as both an electrolyte and an electrode separator with ion transport characteristics similar to that observed for Nafion membranes. The resulting micro-supercapacitor devices show good cyclic stability, and energy storage capacities comparable to existing thin-film supercapacitors.
authors.affiliation: Department of Chemistry, Rice University, Houston, Texas 77005, USA.
authors.forename: Wei
authors.initials: W
authors.lastname: Gao
authors.forename: Neelam
authors.initials: N
authors.lastname: Singh
authors.forename: Li
authors.initials: L
authors.lastname: Song
authors.forename: Zheng
authors.initials: Z
authors.lastname: Liu
authors.forename: Arava Leela Mohana
authors.initials: AL
authors.lastname: Reddy
authors.forename: Lijie
authors.initials: L
authors.lastname: Ci
authors.forename: Robert
authors.initials: R
authors.lastname: Vajtai
authors.forename: Qing
authors.initials: Q
authors.lastname: Zhang
authors.forename: Bingqing
authors.initials: B
authors.lastname: Wei
authors.forename: Pulickel M
authors.initials: PM
authors.lastname: Ajayan