title: Construction of TiO₂ hierarchical nanostructures from nanocrystals and their photocatalytic properties.
abstract: Anatase TiO(2) mesoporous structures with high specific surface areas are of special significance in various applications. In this work, hierarchical anatase TiO(2) materials with flowerlike morphologies have been prepared via a one-step template-free hydrothermal method, by using titanocene dichloride as precursor and EDA as chelating agent in aqueous solution. Particularly, the hierarchical structures are assembled from very thin TiO(2) nanosheets, which are composed of numerous highly crystallized anatase nanocrystals. In addition, the assembled materials own relatively large specific surface areas of 170 m(2)/g, and uniform mesopores of 7 nm. We further demonstrate that the hierarchical TiO(2) materials show very good photocatalytic performance when applied in photodegradation of methylene blue, which should be related to the unique features of hierarchical structures, large specific surface areas and high crystallization degree of the obtained TiO(2) materials. With these features, the hierarchical TiO(2) may find more potential applications in the fields such as dye-sensitized solar cells and lithium ion batteries.
authors.affiliation: Department of Chemistry, Tongji University, Shanghai 200092, People's Republic of China.
authors.forename: Tiejian
authors.initials: T
authors.lastname: Zhu
authors.forename: Jing
authors.initials: J
authors.lastname: Li
authors.forename: Qingsheng
authors.initials: Q
authors.lastname: Wu
mesh_terms: D002384:Catalysis; D003460:Crystallization; D011211:Electric Power Supplies; D005029:Ethylenediamines / Q000737:chemistry; D008094:Lithium / Q000737:chemistry; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D008751:Methylene Blue / Q000737:chemistry; D010782:Photolysis; D016062:Porosity; D012993:Solar Energy; D014025:Titanium / Q000737:chemistry*
chemical_list: D005029:Ethylenediamines; C009495:titanium dioxide; C031234:ethylenediamine; D008094:Lithium; D014025:Titanium; D008751:Methylene Blue