title: Synthesis and characterization of hematite pigment obtained from a steel waste industry.
abstract: Pigments that meet environmental and technology requirements are the focus of the research in the ceramic sector. This study focuses on the synthesis of ceramic pigment by encapsulation of hematite in crystalline and amorphous silica matrix. Iron oxide from a metal sheet rolling process was used as chromophore. A different content of hematite and silica was homogenized by conventional and high energy milling. The powders obtained after calcinations between 1050 and 1200 °C for 2h were characterized by X-ray diffraction and SEM analysis. The pigments were applied to ceramic enamel and porcelain body. The effect of pigment was measured by comparing L*a*b* values of the heated samples. Results showed that the color developed is influenced by variables such as oxide content employed, conditions of milling and processing temperature. The results showed that the use of pigment developed does not interfere in microstructural characteristics of pigmented material. The best hue was obtained from samples with 15 wt% of chromophore, heated at 1200 °C in amorphous silica matrix.
authors.affiliation: Department of Mechanical Engineering, University of the State of Santa Catarina, Santa Catarina, Brazil.
authors.forename: S R
authors.initials: SR
authors.lastname: Prim
authors.forename: M V
authors.initials: MV
authors.lastname: Folgueras
authors.forename: M A
authors.initials: MA
authors.lastname: de Lima
authors.forename: D
authors.initials: D
authors.lastname: Hotza
mesh_terms: D002516:Ceramics / Q000737:chemistry; D003743:Dental Enamel / Q000737:chemistry; D003776:Dental Porcelain / Q000737:chemistry; D004784:Environmental Monitoring / Q000379:methods; D005290:Ferric Compounds / Q000737:chemistry*; D007220:Industrial Waste; D008855:Microscopy, Electron, Scanning / Q000379:methods; D010087:Oxides / Q000737:chemistry; D010858:Pigmentation; D011208:Powders; D013232:Steel / Q000032:analysis*; D013696:Temperature; D013997:Time Factors; D014961:X-Ray Diffraction
chemical_list: D005290:Ferric Compounds; D007220:Industrial Waste; D010087:Oxides; D011208:Powders; D003776:Dental Porcelain; D013232:Steel; C000499:ferric oxide