title: First substoichiometric version of the catalytic enantioselective addition of an alkyllithium to an aldehyde.
abstract: A substoichiometric enantioselective version of the extremely fast nucleophilic addition of Alk-Li to RCHO is made possible thanks to a thorough analysis of the aggregation phenomena involved in the reaction: calculated quantities of LiCl must be added to the medium at the right time to keep the catalytic cycle running.
authors.affiliation: CNRS UMR 6014 & FR 3038, Université de Rouen and INSA de Rouen, Mont St Aignan, France.
authors.forename: Baptiste
authors.initials: B
authors.lastname: Lecachey
authors.forename: Catherine
authors.initials: C
authors.lastname: Fressigné
authors.forename: Hassan
authors.initials: H
authors.lastname: Oulyadi
authors.forename: Anne
authors.initials: A
authors.lastname: Harrison-Marchand
authors.forename: Jacques
authors.initials: J
authors.lastname: Maddaluno