title: Metal-free chlorodeboronation of organotrifluoroborates.
abstract: A mild and metal-free method for the chlorodeboronation of organotrifluoroborates using trichloroisocyanuric acid (TCICA) was developed. Aryl-, heteroaryl-, alkenyl-, alkynyl-, and alkyltrifluoroborates were converted into the corresponding chlorinated products in good yields. This method proved to be tolerant of a broad range of functional groups.
authors.affiliation: Roy and Diana Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, Pennsylvania 19104-6323, USA. gmolandr@sas.upenn.edu
authors.forename: Gary A
authors.initials: GA
authors.lastname: Molander
authors.forename: Livia N
authors.initials: LN
authors.lastname: Cavalcanti
mesh_terms: D001881:Borates / Q000737:chemistry*; D002713:Chlorine / Q000737:chemistry*; D005461:Fluorine / Q000737:chemistry*; D015394:Molecular Structure; D014227:Triazines / Q000737:chemistry
chemical_list: D001881:Borates; D014227:Triazines; C557580:trichloroisocyanuric acid; D005461:Fluorine; D002713:Chlorine