title: The intermediate products in the degradation of 4-chlorophenol by pulsed high voltage discharge in water.
abstract: Degradation of 4-chlorophenol by pulsed high voltage discharge is an intricate process involving a series of complex chemical reactions. Hydroxylation of 4-chlorophenol to form hydroquinone, 4-chlororesorcinol and 4-chlorocatechol is the first step, though a very small amount of direct cleavage products of the C(1)-C(2) or C(5)-C(6) bond are observed. The yield of 4-chlorocatechol is about twice as much as that of hydroquinone. Less 4-chloresorcinol is produced. The free chloride ions dropped from the 4-chlorophenol degradation can obtain reactivity again from the discharge, and react with undegraded 4-chlorophenol to form 2,4-dichlorophenol. Some ring-opened products have also been identified and their possible reaction routes are proposed. Several compounds are verified by use of authentic samples. The more stable ring-opened products are low molecular weight (LMW) acids such as formic, acetic, oxalic, malonate, maleic and malic acid. By discharging 4-chlorophenol aqueous solution for 36 min, the amount of carbons obtained from organic acids is more than 50% while that of carbons from aromatic products less than 20% in the carbons of degraded 4-chlorophenol, which is about 94% of initial carbons. After 60 min of discharge, all the 4-chlorophenol and its aromatic intermediates have been removed completely and the organic carbons are mainly presented as organic acid such as acetic and oxalate acid. At the end of the 120 min discharge, the amount of the remaining organic carbons is not more than 14% of the initial carbons.
authors.affiliation: College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China. bwenjuan@suda.edu.cn
authors.forename: Wenjuan
authors.initials: W
authors.lastname: Bian
authors.forename: Xuehong
authors.initials: X
authors.lastname: Song
authors.forename: Deqi
authors.initials: D
authors.lastname: Liu
authors.forename: Jiao
authors.initials: J
authors.lastname: Zhang
authors.forename: Xihua
authors.initials: X
authors.lastname: Chen
mesh_terms: D019342:Acetic Acid / Q000737:chemistry; D002712:Chlorides / Q000737:chemistry; D002733:Chlorophenols / Q000737:chemistry*; D002852:Chromatography, Ion Exchange / Q000379:methods; D004563:Electrochemistry / Q000379:methods*; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods; D006900:Hydroxylation; D007477:Ions; D008970:Molecular Weight; D010070:Oxalates / Q000737:chemistry; D013997:Time Factors; D014874:Water Pollutants, Chemical / Q000032:analysis*; D018508:Water Purification / Q000379:methods*
chemical_list: D002712:Chlorides; D002733:Chlorophenols; D007477:Ions; D010070:Oxalates; D014874:Water Pollutants, Chemical; C029107:4-chlorophenol; D019342:Acetic Acid; C004762:2,4-dichlorophenol