title: Enantioselective hydroformylation of aniline derivatives.
abstract: We have developed a ligand that reversibly binds to aniline substrates, allowing for the control of regioselectivity and enantioselectivity in hydroformylation. In this paper we address how the electronics of the aniline ring affect both the binding of the substrate to the ligand and the enantioselectivity in this reaction.
authors.affiliation: Boston College, 2609 Beacon Street, Chestnut Hill, Massachusetts 02467-3860, USA.
authors.forename: Candice L
authors.initials: CL
authors.lastname: Joe
authors.forename: Kian L
authors.initials: KL
authors.lastname: Tan
mesh_terms: D000814:Aniline Compounds / Q000737:chemistry*; D005561:Formates / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D013237:Stereoisomerism
chemical_list: D000814:Aniline Compounds; D005561:Formates; C030544:formic acid; C023650:aniline