title: An optical sensor based on H-acid/layered double hydroxide composite film for the selective detection of mercury ion.
abstract: A novel optical chemosensor was fabricated based on 1-amino-8-naphthol-3,6-disulfonic acid sodium (H-acid) intercalated layered double hydroxide (LDH) film via the electrophoretic deposition (EPD) method. The film of H-acid/LDH with the thickness of 1 μm possesses a well c-orientation of the LDH microcrystals confirmed by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The fluorescence detection for Hg(II) in aqueous solution was performed by using the H-acid/LDH film sensor at pH 7.0, with a linear response range in 1.0 × 10(-7) to 1.0 × 10(-5) mol L(-1) and a detection limit of 6.3 × 10(-8) mol L(-1). Furthermore, it exhibits excellent selectivity for Hg(II) over a large number of competitive cations including alkali, alkaline earth, heavy metal and transitional metals. The specific fluorescence response of the optical sensor is attributed to the coordination between Hg(II) and sulfonic group in the H-acid immobilized in the LDH matrix, which was verified by NMR spectroscopy and UV-vis spectra. In addition, density functional theory (DFT) calculation further confirms that the coordination occurs between one Hg(2+) and two O atoms in the sulfonic group, which is responsible for the significant fluorescence quenching of the H-acid/LDH film. The results indicate that the H-acid/LDH composite film can be potentially used as a chemosensor for the detection of Hg(2+) in the environmental and biomedical field.
authors.affiliation: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China.
authors.forename: Zhiyong
authors.initials: Z
authors.lastname: Sun
authors.forename: Lan
authors.initials: L
authors.lastname: Jin
authors.forename: Shitong
authors.initials: S
authors.lastname: Zhang
authors.forename: Wenying
authors.initials: W
authors.lastname: Shi
authors.forename: Min
authors.initials: M
authors.lastname: Pu
authors.forename: Min
authors.initials: M
authors.lastname: Wei
authors.forename: David G
authors.initials: DG
authors.lastname: Evans
authors.forename: Xue
authors.initials: X
authors.lastname: Duan