title: Enantioselective conjugate allylation of cyclic enones.
abstract: Enantioselective organocatalytic 1,2-allylation of a cyclic enone followed by anionic oxy-Cope rearrangement delivered the ketone as a mixture of diastereomers. This appears to be a general method for the net enantioselective conjugate allylation of cyclic enones.
authors.affiliation: Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA. taberdf@udel.edu
authors.forename: Douglass F
authors.initials: DF
authors.lastname: Taber
authors.forename: David A
authors.initials: DA
authors.lastname: Gerstenhaber
authors.forename: James F
authors.initials: JF
authors.lastname: Berry
mesh_terms: D002851:Chromatography, High Pressure Liquid; D006844:Hydrocarbons, Cyclic / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet
chemical_list: D006844:Hydrocarbons, Cyclic