title: Competitive adsorption of Cu(II) and Cd(II) ions by chitosan crosslinked with epichlorohydrin-triphosphate.
abstract: In this study, chitosan (CTS) was crosslinked with both epichlorohydrin (ECH) and triphosphate (TPP), by covalent and ionic crosslinking reactions, respectively. The resulting adsorbent (CTS-ECH-TPP) was characterized by SEM, CHN, EDS, FT-IR and TGA analyses, and tested for metal adsorption. The adsorbent was used in batch experiments to evaluate the adsorption of Cu(II) and Cd(II) ions in single and binary metal solutions. In single metal solutions the maximum adsorption capacities for Cu(II) and Cd(II) ions, obtained by Langmuir model, were 130.72 and 83.75 mg g⁻¹, respectively. Adsorption isotherms for binary solutions showed that the presence of Cu(II) decreased Cd(II) adsorption due to a significant competition effect, that is, the adsorbent was selective towards Cu(II) rather than Cd(II).
authors.affiliation: Departamento de Química, Universidade Federal de Santa Catarina, 88040-900 Florianópolis, SC, Brazil.
authors.forename: Rogério
authors.initials: R
authors.lastname: Laus
authors.forename: Valfredo Tadeu
authors.initials: VT
authors.lastname: de Fávere
mesh_terms: D000327:Adsorption; D002104:Cadmium / Q000737:chemistry*; D048271:Chitosan / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D004811:Epichlorohydrin / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D008956:Models, Chemical; D011122:Polyphosphates / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D018508:Water Purification / Q000379:methods*
chemical_list: D011122:Polyphosphates; D014874:Water Pollutants, Chemical; D002104:Cadmium; D004811:Epichlorohydrin; D003300:Copper; D048271:Chitosan; C005692:triphosphoric acid