title: Silver-mediated trifluoromethoxylation of aryl stannanes and arylboronic acids.
abstract: A silver-mediated cross-coupling of trifluoromethoxide with aryl stannanes and arylboronic acids to give aryl trifluoromethyl ethers is reported. This is the first report of a transition-metal-mediated C(aryl)-OCF(3) bond formation.
authors.affiliation: Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138, United States.
authors.forename: Chenghong
authors.initials: C
authors.lastname: Huang
authors.forename: Theresa
authors.initials: T
authors.lastname: Liang
authors.forename: Shinji
authors.initials: S
authors.lastname: Harada
authors.forename: Eunsung
authors.initials: E
authors.lastname: Lee
authors.forename: Tobias
authors.initials: T
authors.lastname: Ritter
mesh_terms: D001897:Boronic Acids / Q000737:chemistry*; D004987:Ethers / Q000737:chemistry; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D017971:Tin Compounds / Q000737:chemistry*
chemical_list: D001897:Boronic Acids; D004987:Ethers; D006845:Hydrocarbons, Fluorinated; D017971:Tin Compounds; C031525:stannane; D012834:Silver