title: Redetermination of μ-oxido-bis-[bis-(N,N-diethyl-hydroxyl-aminato)-oxido-vanadium(V)].
abstract: In comparison with the previous determination [Saussine, Mimoun, Mitschler & Fisher (1980 ▶). Nouv. J. Chim.4, 235-237] of the title compound, [V(2)(C(4)H(10)NO)(4)O(3)], the current study reports an improved precision of the derived geometric parameters, along with the deposition of all coordinates and displacement parameters. The two V(V) atoms are each surrounded by two deprotonated N,O-bidentate diethyl-hydroxy-laminate groups, and a terminal and a bridging oxide ligand, in a distorted octa-hedral coordination geometry. The crystal packing is accomplished by van der Waals inter-actions.
authors.affiliation: Department of Chemistry, East China Normal University, Shanghai 200062, People's Republic of China.
authors.forename: Heng-Qiang
authors.initials: HQ
authors.lastname: Zhang
authors.forename: Zhong-Min
authors.initials: ZM
authors.lastname: Jin
authors.forename: Xin
authors.initials: X
authors.lastname: Fan
authors.forename: Qi-Ying
authors.initials: QY
authors.lastname: Zhang