title: Reducing HAuCl(4) by the C(60) dianion: C(60)-directed self-assembly of gold nanoparticles into novel fullerene bound gold nanoassemblies.
abstract: The C(60) dianion is used to reduce tetrachloroauric acid (HAuCl(4)) for the first time; three-dimensional C(60) bound gold (Au-C(60)) nanoclusters are obtained from C(60)-directed self-assembly of gold nanoparticles due to the strong affinities of Au-C(60) and C(60)-C(60). The process was monitored in situ by UV-vis-NIR spectroscopy. The resulting Au-C(60) nanoclusters were characterized using transmission electron microscopy (TEM), selected area electron diffraction (SAED), energy-dispersive spectroscopy (EDS), x-ray powder diffraction (XRD), x-ray photoelectron spectroscopy (XPS), and FT-IR and Raman spectroscopies. TEM demonstrates the formation of 3D nanonetwork aggregates, which are composed of discrete gold nanocores covered with a C(60) monolayer. The SAED and XRD patterns indicate that the gold nanocores inside the capped C(60) molecules belong to the face-centred cubic crystal structure, while the C(60) molecules are amorphous. The EDS and XPS measurements validate that the Au-C(60) nanoclusters contain only Au and C elements and Au(3+) is reduced to Au(0). FT-IR spectroscopy shows the chemiadsorption of C(60) to the gold nanocores, while Raman spectroscopy demonstrates the electron transfer from the gold nanocores to the chemiadsorbed C(60) molecules. Au-C(60) nanoclusters embedded in tetraoctyl-n-ammonium bromide (TOAB) on glassy carbon electrodes (GCEs) have been fabricated and have shown stable and well-defined electrochemical responses in aqueous solution.
authors.affiliation: State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Graduate School of the Chinese Academy of Sciences, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022, People's Republic of China.
authors.forename: Wei
authors.initials: W
authors.lastname: Liu
authors.forename: Xiang
authors.initials: X
authors.lastname: Gao