title: Spin crossover in the cyanide-bridged Mo(V)Mn(III) single-chain magnet containing Fe(II) cations.
abstract: A 1D Mo(V)Mn(III) chain compound balanced by {Fe[HC(3,5-Me(2)pz)(3)](2)}(2+) dications was prepared. This complex displays a typical single-chain magnet character associated with the Mo(V)Mn(III) chain and a spin crossover phenomenon arising from cationic Fe(II) subunits. The spin crossover behavior tends to slightly affect single-chain magnetic properties at low temperature.
authors.affiliation: Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-7, 13, Korea.
authors.forename: Jung Hee
authors.initials: JH
authors.lastname: Yoon
authors.forename: Dae Won
authors.initials: DW
authors.lastname: Ryu
authors.forename: Sang Yup
authors.initials: SY
authors.lastname: Choi
authors.forename: Hyoung Chan
authors.initials: HC
authors.lastname: Kim
authors.forename: Eui Kwan
authors.initials: EK
authors.lastname: Koh
authors.forename: Jun
authors.initials: J
authors.lastname: Tao
authors.forename: Chang Seop
authors.initials: CS
authors.lastname: Hong
mesh_terms: D007501:Iron / Q000737:chemistry*; D059346:Magnets / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D008982:Molybdenum / Q000737:chemistry*; D009570:Nitriles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D013696:Temperature
chemical_list: D009570:Nitriles; D009942:Organometallic Compounds; D008345:Manganese; D008982:Molybdenum; D007501:Iron