title: The combined removal of methyl mercaptan and hydrogen sulfide via an electro-reactor process using a low concentration of continuously regenerable Ag(II) active catalyst.
abstract: In this study, an electrocatalytic wet scrubbing process was developed for the simultaneous removal of synthetic odorous gases namely, methyl mercaptan (CH(3)SH) and hydrogen sulfide (H(2)S). The initial process consists of the absorption of CH(3)SH and H(2)S gases by an absorbing solution, followed by their mediated electrochemical oxidation using a low concentration of active Ag(II) in 6M HNO(3). Experiments were conducted under different reaction conditions, such as CH(3)SH and H(2)S loadings, active Ag(II) concentrations and molar flow rates. The cyclic voltammetry for the oxidation of CH(3)SH corroborated the electro-reactor results, in that the silver in the 6M HNO(3) reaction solution significantly influences the oxidation of CH(3)SH. At a low active Ag(II) concentration of 0.0012 M, the CH(3)SH removal experiments demonstrated that the CH(3)SH degradation was steady, with 100% removal at a CH(3)SH loading of 5 gm(-3) h(-1). The electro-reactor and cyclic voltammetry results indicated that the removal of H(2)S (100%) follows a mediated electrocatalytic oxidation reaction. The simultaneous removal of 100% of the CH(3)SH and H(2)S was achieved, even with a very low active Ag(II) concentration (0.0012 M), as a result of the high efficiency of the Ag(II). The parallel cyclic voltammetry results demonstrated that a process of simultaneous destruction of both CH(3)SH and H(2)S follows an H(2)S influenced mediated electrocatalytic oxidation. The use of a very low concentration of the Ag(II) mediator during the electro-reactor process is promising for the complete removal of CH(3)SH and H(2)S.
authors.affiliation: Department of Chemical Engineering, Sunchon National University, 315 Maegok Dong, Suncheon 540-742, Chonnam, Republic of Korea.
authors.forename: Govindan
authors.initials: G
authors.lastname: Muthuraman
authors.forename: Sang Joon
authors.initials: SJ
authors.lastname: Chung
authors.forename: Il Shik
authors.initials: IS
authors.lastname: Moon
mesh_terms: D002384:Catalysis; D004563:Electrochemistry; D006862:Hydrogen Sulfide / Q000302:isolation & purification*; D010084:Oxidation-Reduction; D012834:Silver / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000302:isolation & purification*
chemical_list: D013438:Sulfhydryl Compounds; C005231:methylmercaptan; D012834:Silver; D006862:Hydrogen Sulfide