title: Preparation of η2-complexes of fullerenes by reduction. Crystal structure and optical properties of {Ni(dppp)·(η2-C70)}·(C6H4Cl2)0.5.
abstract: The new reduction method for preparation of η(2)-complexes of fullerenes with nickel-1,3-bis(diphenylphosphino)propane has been developed in which Ni(dppp)Cl(2) and C(60)(C(70)) mixtures are reduced with sodium tetraphenylborate. Single crystals of the first η(2)-complex of nickel with fullerene C(70): {Ni(dppp)·(η(2)-C(70))}·(C(6)H(4)Cl(2))(0.5) (1) (C(6)H(4)Cl(2) = o-dichlorobenzene) have been obtained as well as the previously described complex with fullerene C(60): {Ni(dppp)·(η(2)-C(60))}·(Solvent) (2). The crystal structure of 1 has been solved to show the coordination of nickel to the C-C bond of C(70) at the 6-6 ring junction of η(2)-type to form Ni-C(C(70)) bonds of 1.929-1.941(2) Å length, the shortest M-C bonds among those known for η(2)-complexes of fullerenes C(60) and C(70). The length of the C-C bond to which Ni atom is coordinated (1.494(3) Å) is noticeably longer than the average length of these bonds in C(70) (1.381(2) Å). Optical spectra of 1 in the IR- and UV-visible ranges have been analyzed to show the splitting of some C(70) bands due to C(70) symmetry lowering. The complex has a red-brown color in solution and manifests three bands in the visible range at 379, 467 and 680 nm. The solution of 1 is air sensitive since air exposure restores the color and absorption bands of the starting C(70) at 383 and 474 nm.
authors.affiliation: Institute of Problems of Chemical Physics RAS, Chernogolovka, Moscow region, 142432, Russia. konarev@icp.ac.ru
authors.forename: Dmitri V
authors.initials: DV
authors.lastname: Konarev
authors.forename: Sergey V
authors.initials: SV
authors.lastname: Simonov
authors.forename: Salavat S
authors.initials: SS
authors.lastname: Khasanov
authors.forename: Rimma N
authors.initials: RN
authors.lastname: Lyubovskaya