title: Diporphyrinylamines: synthesis and electrochemistry.
abstract: The synthesis of three possible diporphyrinylamines is described. All compounds were obtained by using the Buchwald-Hartwig aromatic amination reaction. The electronic spectra of the three porphyrin dimers showed characteristic features found in highly delocalized systems. The first oxidation of these compounds took place on the connecting amine function.
authors.affiliation: Department of Chemistry and QOPNA, University of Aveiro, 3810-193 Aveiro, Portugal.
authors.forename: Ana M V M
authors.initials: AM
authors.lastname: Pereira
authors.forename: Maria G P M S
authors.initials: MG
authors.lastname: Neves
authors.forename: José A S
authors.initials: JA
authors.lastname: Cavaleiro
authors.forename: Christophe
authors.initials: C
authors.lastname: Jeandon
authors.forename: Jean-Paul
authors.initials: JP
authors.lastname: Gisselbrecht
authors.forename: Sylvie
authors.initials: S
authors.lastname: Choua
authors.forename: Romain
authors.initials: R
authors.lastname: Ruppert
mesh_terms: D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry*; D004563:Electrochemistry; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D000588:Amines