title: Synthesis of zinc tin oxide (ZTO) nanocrystallites at room temperature through association with peptide-containing bolaamphiphile molecules.
abstract: Single crystalline zinc tin oxide (ZTO) nanocrystallites were prepared at room temperature through association with a peptide-containing bolaamphiphile molecule. The bolaamphiphile molecules self-assembled to form spherical structures with creation of ZTO nanocrystallites inside. ZTO nanocrystallite synthesis was achieved only when the bolaamphiphile molecule was present, while a mixture of amorphous Sn and Zn precipitates was formed in the absence of the bolaamphiphile molecule. The bolaamphiphile molecule is thought to stabilize the Zn(2+) and Sn(4+) precursor ions by ligation and to induce subsequent condensation forming crystalline ZTO. The ZTO formation was achieved only at a strong acidic condition that promotes dissociation and ionization of Zn and Sn precursors and represses formation of ZnO and H(2)SnO(3). The prepared ZTO nanocrystallites had almost the same band gap energy as ZTO nanoparticles prepared by the conventional hydrothermal process. The outcomes of this study indicate that the controlled mineralization of metal precursor ions in a peptide-containing bolaamphiphile molecule suspension can be an alternative method to synthesize metal oxides at room temperature, while maintaining their crystalline structure and optoelectrical properties.
authors.affiliation: Department of Chemical and Biomolecular Engineering, 134 Shinchon-dong, Seodaemun-gu, Seoul 120-749, Republic of Korea.
authors.forename: Sungjun
authors.initials: S
authors.lastname: Ahn
authors.forename: Tae-Geun
authors.initials: TG
authors.lastname: Kwon
authors.forename: Sang-Yup
authors.initials: SY
authors.lastname: Lee
mesh_terms: D005663:Furans; D053768:Metal Nanoparticles / Q000737:chemistry*; D010455:Peptides; D011728:Pyridones; D017971:Tin Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D015034:Zinc Oxide / Q000138:chemical synthesis / Q000737:chemistry*
chemical_list: D005663:Furans; D010455:Peptides; D011728:Pyridones; D017971:Tin Compounds; C543575:bolaamphiphile; C045358:stannic oxide; D015034:Zinc Oxide