title: Low-temperature synthesis of Mn(3)O(4) nanoparticles loaded on multi-walled carbon nanotubes and their application in electrochemical capacitors.
abstract: A low-temperature, efficient and one-step deposition method, in which Mn(CH(3)COO)(2)·4H(2)O serves as precursor and O(2) as oxidant, was employed to deposit Mn(3)O(4) nanoparticles on multi-walled carbon nanotubes (MWCNTs) in ethanol solution at 150 and 200 °C. The resulting Mn(3)O(4)/MWCNT composites were characterized by means of different techniques including x-ray diffraction, x-ray photoelectron spectroscopy and transmission electron microscopy. It was indicated that the Mn(3)O(4) nanoparticles were attached uniformly on MWCNTs with sizes less than 10 nm, and the loading amount of Mn(3)O(4) could be tuned by changing the initial weight ratio of Mn(CH(3)COO)(2)·4H(2)O/MWCNT. The electrochemical behavior of the Mn(3)O(4)/MWCNT composites was examined by cyclic voltammetry, and the result indicated the specific capacitance of the composite electrode was 330 F g(-1), nearly 18 times higher than that of the pure MWCNT electrode. The good performance of the as-prepared composites as electrode material may be attributed to the synergistic effects of the Mn(3)O(4) nanoparticles and the MWCNTs.
authors.affiliation: Beijing National Laboratory for Molecular Sciences (BNLMS), Center for Molecular Science, Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080, People's Republic of China.
authors.forename: Guimin
authors.initials: G
authors.lastname: An
authors.forename: Ping
authors.initials: P
authors.lastname: Yu
authors.forename: Meijun
authors.initials: M
authors.lastname: Xiao
authors.forename: Zhimin
authors.initials: Z
authors.lastname: Liu
authors.forename: Zhenjiang
authors.initials: Z
authors.lastname: Miao
authors.forename: Kunlun
authors.initials: K
authors.lastname: Ding
authors.forename: Lanqun
authors.initials: L
authors.lastname: Mao