title: Palladium induced macrocyclic preorganization for stabilization of a tetrathiafulvalene mixed-valence dimer.
abstract: Ditopic metalation of a flexible "Pacman"-like tetrathiafulvalene (TTF) modified Schiff-base-calixpyrrole results in the stabilization upon oxidation of an otherwise difficult-to-access mixed-valence TTF radical dimer. EPR and optical spectroscopies were used to characterize the mixed-valence species.
authors.affiliation: Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, Texas 78712, USA.
authors.forename: Christopher
authors.initials: C
authors.lastname: Bejger
authors.forename: Christina M
authors.initials: CM
authors.lastname: Davis
authors.forename: Jung Su
authors.initials: JS
authors.lastname: Park
authors.forename: Vincent
authors.initials: V
authors.lastname: M Lynch
authors.forename: Jason B
authors.initials: JB
authors.lastname: Love
authors.forename: Jonathan L
authors.initials: JL
authors.lastname: Sessler