title: The direct synthesis of mesoporous structured MnO(2)/TiO(2) nanocomposite: a novel visible-light active photocatalyst with large pore size.
abstract: A series of visible-light-driven mesoporous structured MnO(2)/TiO(2) nanocrystal photocatalysts have been synthesized through a modified sol-gel method, and the N(2) adsorption-desorption isotherm confirms that the mesoporous materials possess large pore size (up to 9.2 nm) and a narrow pore size distribution. X-ray powder diffraction (XRD) analyses and complementary x-ray photoelectron spectroscopy (XPS) measurements reveal that the doping of the transition metal Mn inhibits the growth of TiO(2) anatase nanocrystals and the Mn species are highly dispersed on the surface of TiO(2). The ultraviolet (UV)-vis spectrum demonstrates the excellent adsorption properties of MnO(2)/TiO(2) over the whole region of visible light, which enables this novel photocatalysis material to possess remarkable activity in the photocatalytic degradation of methylene blue under visible light radiation. Moreover, a 'coating mechanism' based on the nucleation of titania nanocrystals along with the interaction between the dopant precursors and titania clusters has been suggested.
authors.affiliation: Eco-materials and Renewable Energy Research Center (ERERC), Nanjing University, Nanjing 210093, People's Republic of China. School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, People's Republic of China.
authors.forename: Min
authors.initials: M
authors.lastname: Xue
authors.forename: Li
authors.initials: L
authors.lastname: Huang
authors.forename: Jian-Qiang
authors.initials: JQ
authors.lastname: Wang
authors.forename: Ying
authors.initials: Y
authors.lastname: Wang
authors.forename: Ling
authors.initials: L
authors.lastname: Gao
authors.forename: Jian-Hua
authors.initials: JH
authors.lastname: Zhu
authors.forename: Zhi-Gang
authors.initials: ZG
authors.lastname: Zou