title: Palladium diffusion into bulk copper via the (100) surface.
abstract: Using low-energy electron microscopy, we measure the diffusion of Pd into bulk Cu at the Cu(100) surface. Interdiffusion is tracked by measuring the dissolution of the Cu(100)-c(2 × 2)-Pd surface alloy during annealing (T>240 °C). The activation barrier for Pd diffusion from the surface alloy into the bulk is determined to be (1.8 ± 0.6) eV. During annealing, we observe the growth of a new layer of Cu near step edges. Under this new Cu layer, dilute Pd remaining near the surface develops a layered structure similar to the Cu(3)Pd L 1(2) bulk alloy phase.
authors.affiliation: Sandia National Laboratories, Albuquerque, NM 87185, USA.
authors.forename: E
authors.initials: E
authors.lastname: Bussmann
authors.forename: J
authors.initials: J
authors.lastname: Sun
authors.forename: K
authors.initials: K
authors.lastname: Pohl
authors.forename: G L
authors.initials: GL
authors.lastname: Kellogg