title: A foldamer-based chiroptical molecular switch that displays complete inversion of the helical sense upon anion binding.
abstract: Chiral indolocarbazole dimers fold into a helical conformation by virtue of intramolecular hydrogen bonds, as demonstrated by (1)H NMR and CD spectra and optical rotations. In particular, the optical properties of the dimers were found to be extremely sensitive to the nature of the solvent, depending on whether they are folded or not. The helical sense of the dimers can be reversibly switched by binding sulfate ion, which gives rise to complete inversion of the CD spectra. The binding mode and absolute stereochemistry of the sulfate complexes was unequivocally determined by single-crystal X-ray structures, which are all consistent with the CD and (1)H NMR spectra in solution.
authors.affiliation: Department of Chemistry, Yonsei University, Seoul, Korea.
authors.forename: Jae-min
authors.initials: JM
authors.lastname: Suk
authors.forename: Veluru Ramesh
authors.initials: VR
authors.lastname: Naidu
authors.forename: Xinfang
authors.initials: X
authors.lastname: Liu
authors.forename: Myoung Soo
authors.initials: MS
authors.lastname: Lah
authors.forename: Kyu-Sung
authors.initials: KS
authors.lastname: Jeong