title: Stereoselective multimodal transformations of planar chiral 9-membered diallylic amides.
abstract: Intermolecular reactions of planar chiral 9-membered diallylic amides provide a variety of bicyclic compounds with central chiralities in a stereospecific fashion with high group selectivity. Lewis-acid-promoted intramolecular reactions of the obtained bicyclic compounds provide transannular products in a stereospecific fashion. Furthermore, a direct transannular reaction of diallylic amide involving sequential intermolecular-intramolecular reactions has been developed.
authors.affiliation: Institute for Materials Chemistry and Engineering, Kyushu University, Kasuga-shi, Fukuoka 816-8580, Japan. ktomooka@cm.kyushu-u.ac.jp
authors.forename: Katsuhiko
authors.initials: K
authors.lastname: Tomooka
authors.forename: Masaki
authors.initials: M
authors.lastname: Suzuki
authors.forename: Maki
authors.initials: M
authors.lastname: Shimada
authors.forename: Runyan
authors.initials: R
authors.lastname: Ni
authors.forename: Kazuhiro
authors.initials: K
authors.lastname: Uehara
mesh_terms: D000577:Amides / Q000138:chemical synthesis / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D000577:Amides