title: Catalytic hydrodechlorination of 1,2-dichloroethane using copper nanoparticles under reduction conditions of sodium borohydride.
abstract: 1,2-Dichloroethane (1,2-DCA) is a raw material used for the manufacture of vinyl chloride monomer (VCM) and therefore has very often been detected in the groundwater nearby the VCM manufacturing plant. Zero-valent iron (ZVI) is capable of degrading a wide array of highly chlorinated contaminants; however, the reactivity of ZVI towards 1,2-DCA is very low. In this study, zero-valent copper nanoparticles have been synthesized for effective dechlorination of 1,2-DCA under reduction conditions of sodium borohydride. Copper nanoparticles consisted of mainly metallic copper (Cu(0)) with small amounts of cuprous oxide (Cu(2)O). They have surface areas of about 19.0 m(2) g(-1) and an average diameter of 15 nm. Batch experiments were conducted to test the effectiveness of copper nanoparticles for 1,2-DCA degradation using sodium borohydride as electron donors where the ORP was measured as -1100 mV. More than 80% of 1,2-DCA (30 mg L(-1)) was rapidly degraded within 2 h in the presence of both copper nanoparticles (2.5 g L(-1)) and borohydride (25 mM). No reduction of 1,2-DCA was observed when the system contained either copper nanoparticles alone or borohydride alone. The degradation intermediates included ethane and ethylene accounting for 79% and ∼1.5% of the 1,2-DCA lost, respectively. Potential environmental applications can be achieved by immobilizing copper nanoparticles onto the surface of reducing metals to form a reactive bimetallic structure.
authors.affiliation: Graduate Institute of Environmental Engineering, National Taiwan University, Taipei, 106, Taiwan.
authors.forename: Chang-Chieh
authors.initials: CC
authors.lastname: Huang
authors.forename: Shang-Lien
authors.initials: SL
authors.lastname: Lo
authors.forename: Shin-Mu
authors.initials: SM
authors.lastname: Tsai
authors.forename: Hsing-Lung
authors.initials: HL
authors.lastname: Lien
mesh_terms: D001894:Borohydrides / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D052918:Environmental Restoration and Remediation / Q000379:methods*; D004980:Ethane / Q000737:chemistry; D005025:Ethylene Dichlorides / Q000032:analysis / Q000737:chemistry*; D005030:Ethylenes / Q000737:chemistry; D060587:Groundwater / Q000737:chemistry; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000737:chemistry*
chemical_list: D001894:Borohydrides; D005025:Ethylene Dichlorides; D005030:Ethylenes; D014874:Water Pollutants, Chemical; C024565:ethylene dichloride; D003300:Copper; C025364:sodium borohydride; C036216:ethylene; D004980:Ethane