title: Homo- and heteronuclear alkali metal trimers formed on helium nanodroplets. Part I. Vibronic spectra simulations based on ab initio calculations.
abstract: We compare the 3(4)A(1) and 4(4)B(2) states of homonuclear and heteronuclear alkali trimers formed of potassium and rubidium. The Multireference Rayleigh Schrödinger Perturbation Theory of second order is applied to obtain the corresponding adiabatic potential energy surfaces. In the case of homonuclear trimers these pairs of states correspond to the two branches of the E⊗e Jahn-Teller distorted 2(4)E' state. For heteronuclear trimers, the vibrational modes Q(x) and Q(y) are no longer degenerate, but the two electronic states still show a conical intersection at obtuse (KRb(2)) or acute (K(2)Rb) isosceles geometries. Spectroscopic consequences of this situation are discussed, vibronic spectra are predicted and compared to laser-induced fluorescence spectra obtained in helium droplet isolation spectroscopy experiments of our group.
authors.affiliation: Centre for Theoretical Chemistry and Physics, The New Zealand Institute for Advanced Study, Massey University, 0745 Auckland, New Zealand. andreas.w.hauser@gmail.com
authors.forename: Andreas W
authors.initials: AW
authors.lastname: Hauser
authors.forename: Wolfgang E
authors.initials: WE
authors.lastname: Ernst