title: Effect of plasma etching on destructive adsorption properties of polypropylene fibers containing magnesium oxide nanoparticles.
abstract: Dermal absorption of pesticides poses a danger for agricultural workers. Use of personal protection equipment (PPE) is required to provide protection; some of the current PPE involves impermeable barriers. In these barrier materials, the same mechanism that prevents the penetration of toxic chemicals also blocks the passage of water vapor and air from flowing through the material, making the garments uncomfortable. Fibers that degrade organophosphate pesticides, such as methyl parathion, were developed by incorporating metal oxides. These modified fibers can be incorporated into conventional fabric structures that allow water vapor to pass through, thereby maintaining comfort. Fibers with self-decontamination functionality were developed by incorporating magnesium oxide (MgO) nanoparticles into a polypropylene (PP) melt-extruded fiber. These fibers were then treated with plasma etching to expose increased surface area of the MgO nanoparticles. Three steps were involved in this research project: (1) determining the reactivity of MgO and methyl parathion, (2) making melt-spun MgO/PP fibers, and (3) testing the reactivity of MgO/PP composite fibers and methyl parathion. It was confirmed that MgO stoichiometrically degrades methyl parathion by way of destructive adsorption. The etching of the PP fibers containing MgO nanoparticles increased the chemical accessibility of MgO reactive sites, therefore making them more effective in degrading methyl parathion. These fibers can enhance the protection provided by PPE to agricultural and horticultural workers and military personnel.
authors.affiliation: Fiber Science, Cornell University, Ithaca, NY 14853, USA. lel72@cornell.edu
authors.forename: Laura E
authors.initials: LE
authors.lastname: Lange
authors.forename: S Kay
authors.initials: SK
authors.lastname: Obendorf
mesh_terms: D000327:Adsorption; D002851:Chromatography, High Pressure Liquid; D008277:Magnesium Oxide / Q000737:chemistry*; D013058:Mass Spectrometry; D008743:Methyl Parathion / Q000378:metabolism; D053758:Nanoparticles / Q000737:chemistry*; D011126:Polypropylenes / Q000378:metabolism*; D011481:Protective Clothing
chemical_list: D011126:Polypropylenes; D008277:Magnesium Oxide; D008743:Methyl Parathion