title: Facile synthesis of NiAl-layered double hydroxide/graphene hybrid with enhanced electrochemical properties for detection of dopamine.
abstract: Layered double hydroxides (LDHs), also known as hydrotalcite-like anionic clays, have been investigated widely as promising electrochemical active materials. Due to the inherently weak conductivity, the electrochemical properties of LDHs were improved typically by utilization of either functional molecules intercalated between LDH interlayer galleries, or proteins confined between exfoliated LDH nanosheets. Here, we report a facile protocol to prepare NiAl-LDH/graphene (NiAl-LDH/G) nanocomposites using a conventional coprecipitation process under low-temperature conditions and subsequent reduction of the supporting graphene oxide. Electrochemical tests showed that the NiAl-LDH/G modified electrode exhibited highly enhanced electrochemical performance of dopamine electrooxidation in comparison with the pristine NiAl-LDH modified electrode. Results of high-resolution transmission electron microscopy and Raman spectra provide convincing information on the nanostructure and composition underlying the enhancement. Our results of the NiAl-LDH/G modified electrodes with the enhanced electrochemical performance may allow designing a variety of promising hybrid sensors via a simple and feasible approach.
authors.affiliation: State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China.
authors.forename: Meixia
authors.initials: M
authors.lastname: Li
authors.forename: Jun E
authors.initials: JE
authors.lastname: Zhu
authors.forename: Lili
authors.initials: L
authors.lastname: Zhang
authors.forename: Xu
authors.initials: X
authors.lastname: Chen
authors.forename: Huimin
authors.initials: H
authors.lastname: Zhang
authors.forename: Fazhi
authors.initials: F
authors.lastname: Zhang
authors.forename: Sailong
authors.initials: S
authors.lastname: Xu
authors.forename: David G
authors.initials: DG
authors.lastname: Evans
mesh_terms: D000535:Aluminum / Q000737:chemistry*; D004298:Dopamine / Q000032:analysis*; D055664:Electrochemical Techniques / Q000379:methods*; D004566:Electrodes; D006108:Graphite / Q000737:chemistry*; D006878:Hydroxides / Q000737:chemistry*; D053761:Nanocomposites / Q000737:chemistry; D009532:Nickel / Q000737:chemistry*; D010084:Oxidation-Reduction
chemical_list: D006878:Hydroxides; D006108:Graphite; D009532:Nickel; D000535:Aluminum; D004298:Dopamine