title: Dynamical heterogeneity in a highly supercooled liquid: consistent calculations of correlation length, intensity, and lifetime.
abstract: We have investigated dynamical heterogeneity in a highly supercooled liquid using molecular-dynamics simulations in three dimensions. Dynamical heterogeneity can be characterized by three quantities: correlation length ξ(4), intensity χ(4), and lifetime τ(hetero). We evaluated all three quantities consistently from a single order parameter. In a previous study [H. Mizuno and R. Yamamoto, Phys. Rev. E 82, 030501(R) (2010)], we examined the lifetime τ(hetero)(t) in two time intervals t = τ(α) and τ(ngp), where τ(α) is the α-relaxation time and τ(ngp) is the time at which the non-Gaussian parameter of the Van Hove self-correlation function is maximized. In the present study, in addition to the lifetime τ(hetero)(t), we evaluated the correlation length ξ(4)(t) and the intensity χ({4)(t) from the same order parameter used for the lifetime τ(hetero)(t). We found that as the temperature decreases, the lifetime τ(hetero)(t) grows dramatically, whereas the correlation length ξ(4)(t) and the intensity χ(4)(t) increase slowly compared to τ(hetero)(t) or plateaus. Furthermore, we investigated the lifetime τ(hetero)(t) in more detail. We examined the time-interval dependence of the lifetime τ(hetero)(t) and found that as the time interval t increases, τ(hetero)(t) monotonically becomes longer and plateaus at the relaxation time of the two-point density correlation function. At the large time intervals for which τ(hetero)(t) plateaus, the heterogeneous dynamics migrate in space with a diffusion mechanism, such as the particle density.
authors.affiliation: Department of Chemical Engineering, Kyoto University, Kyoto 615-8510, Japan. h-mizuno@cheme.kyoto-u.ac.jp
authors.forename: Hideyuki
authors.initials: H
authors.lastname: Mizuno
authors.forename: Ryoichi
authors.initials: R
authors.lastname: Yamamoto