title: Palladium-catalyzed hydroacyloxylation of ynamides.
abstract: In the presence of substoichiometric Pd(OAc)(2), carboxylic acids undergo highly regio- and stereoselective additions to ynamides to provide α-acyloxyenamides.
authors.affiliation: EaStCHEM, School of Chemistry, University of Edinburgh, Joseph Black Building, The King's Buildings, West Mains Road, Edinburgh, EH9 3JJ, United Kingdom.
authors.forename: Donna L
authors.initials: DL
authors.lastname: Smith
authors.forename: William R F
authors.initials: WR
authors.lastname: Goundry
authors.forename: Hon Wai
authors.initials: HW
authors.lastname: Lam
mesh_terms: D000085:Acetates / Q000737:chemistry*; D000577:Amides / Q000138:chemical synthesis* / Q000737:chemistry*; D002384:Catalysis; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*
chemical_list: D000085:Acetates; D000577:Amides; D009942:Organometallic Compounds; C516071:palladium(II) acetate; D010165:Palladium