title: Observation of electronic ferroelectric polarization in multiferroic YMn2O5.
abstract: We report the observation of a magnetic polarization of the O 2p states in YMn(2)O(5) through the use of soft x-ray resonant scattering at the oxygen K edge. Remarkably, we find that the temperature dependence of the integrated intensity of this signal closely follows the macroscopic electric polarization, and hence is proportional to the ferroelectric order parameter. This is in contrast with the temperature dependence observed at the Mn L(3) edge, which reflects the Mn magnetic order parameter. First-principles calculations provide a microscopic understanding of these results and show that a spin-dependent hybridization of O 2p and Mn 3d states results in a purely electronic contribution to the ferroelectric polarization, which can exist in the absence of lattice distortions.
authors.affiliation: Leibniz Institute for Solid State and Materials Research IFW Dresden, Helmholtzstrasse 20, 01069 Dresden, Germany.
authors.forename: S
authors.initials: S
authors.lastname: Partzsch
authors.forename: S B
authors.initials: SB
authors.lastname: Wilkins
authors.forename: J P
authors.initials: JP
authors.lastname: Hill
authors.forename: E
authors.initials: E
authors.lastname: Schierle
authors.forename: E
authors.initials: E
authors.lastname: Weschke
authors.forename: D
authors.initials: D
authors.lastname: Souptel
authors.forename: B
authors.initials: B
authors.lastname: Büchner
authors.forename: J
authors.initials: J
authors.lastname: Geck