title: Ti/Pd-promoted intramolecular Michael-type addition of allylic carboxylates to activated alkenes.
abstract: An interesting protocol for the synthesis of different vinyl substituted carbo- and heterocycles based on a new intramolecular Michael-type reaction using allylic carboxylates as pronucleophiles is reported. The success of the catalytic process is based on the excellent cooperation between the late transition metal (palladium) and the radical reagent (titanium).
authors.affiliation: Departamento de Química Orgánica, Universidad de Granada, Granada, Spain.
authors.forename: Alba
authors.initials: A
authors.lastname: Millán
authors.forename: Ana
authors.initials: A
authors.lastname: Martín-Lasanta
authors.forename: Delia
authors.initials: D
authors.lastname: Miguel
authors.forename: Luis Álvarez
authors.initials: LÁ
authors.lastname: de Cienfuegos
authors.forename: Juan M
authors.initials: JM
authors.lastname: Cuerva