title: Gelation of ionic liquid with exfoliated montmorillonite nanoplatelets and its application for quasi-solid-state dye-sensitized solar cells.
abstract: The exfoliated montmorillonite (exMMT) nanoplatelets that carry negative charges are capable of adsorbing 1-methyl-3-propyl-imidazolium cations to form a gel-type ionic liquid-based electrolyte system for dye-sensitized solar cell (DSSC). Interestingly, it also increases the power conversion efficiency of DSSC from 6.58% to 7.77% at full sun. The increased efficiency is attributed to the decreased resistance of gel electrolyte system and enhanced reduction reaction rate at the counter electrode, both of which are related to the two-dimensional electrolyte nature of exMMTs that repel the I(-)/I(3)(-) redox couples toward their major conduction pathway.
authors.affiliation: Department of Materials Science and Engineering, National Taiwan University, Taipei, Taiwan.
authors.forename: Chia-Hsin
authors.initials: CH
authors.lastname: Lee
authors.forename: Ken-Yen
authors.initials: KY
authors.lastname: Liu
authors.forename: Shun-Hsiang
authors.initials: SH
authors.lastname: Chang
authors.forename: Keng-Jen
authors.initials: KJ
authors.lastname: Lin
authors.forename: Jiang-Jen
authors.initials: JJ
authors.lastname: Lin
authors.forename: Kuo-Chuan
authors.initials: KC
authors.lastname: Ho
authors.forename: King-Fu
authors.initials: KF
authors.lastname: Lin