title: Selective oxidative debenzylation of mono- and oligosaccharides in the presence of azides.
abstract: When using benzyl ethers as permanent protecting groups in oligosaccharide synthesis selective oxidative debenzylation with NaBrO(3) + Na(2)S(2)O(4) under biphasic conditions is efficient and compatible with anomeric azides and many other functions.
authors.affiliation: Bioorganische Chemie, Gebäude NWI, Universität Bayreuth, 95440 Bayreuth, Germany.
authors.forename: Mathäus
authors.initials: M
authors.lastname: Niemietz
authors.forename: Lukas
authors.initials: L
authors.lastname: Perkams
authors.forename: Joanna
authors.initials: J
authors.lastname: Hoffman
authors.forename: Steffen
authors.initials: S
authors.lastname: Eller
authors.forename: Carlo
authors.initials: C
authors.lastname: Unverzagt
mesh_terms: D001386:Azides / Q000737:chemistry*; D001554:Benzene / Q000737:chemistry*; D058116:Lewis Acids / Q000737:chemistry; D009005:Monosaccharides / Q000737:chemistry*; D009844:Oligosaccharides / Q000737:chemistry*; D010084:Oxidation-Reduction; D013379:Substrate Specificity
chemical_list: D001386:Azides; D058116:Lewis Acids; D009005:Monosaccharides; D009844:Oligosaccharides; D001554:Benzene