title: Recoupling in solid state NMR using γ prepared states and phase matching.
abstract: The paper describes two-dimensional solid state NMR experiments that use powdered dephased antiphase coherence (γ preparation) to encode chemical shifts in the indirect dimension. Both components of this chemical shift encoded gamma-prepared states can be refocused into inphase coherence by a recoupling element. This helps to achieve sensitivity enhancement in 2D NMR experiments by quadrature detection. The powder dependence of the gamma-prepared states allows for manipulating them by suitable insertion of delays in the recoupling periods. This helps to design experiments that suppress diagonal peaks in 2D spectra, leading to improved resolution. We describe some new phase modulated heteronuclear and homonuclear recoupling pulse sequences that simplify the implementation of the described experiments based on γ prepared states. Recoupling in the heteronuclear spin system is achieved by matching the difference in the amplitude of the sine/cosine modulated phase on the two rf-channels to the spinning frequency while maintaining the same power on the two rf-channels.
authors: School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, USA.
authors: James
authors: J
authors: Lin
authors: R G
authors: RG
authors: Griffin
authors: Navin
authors: N
authors: Khaneja
mesh_terms: D000465:Algorithms; D004574:Electromagnetic Fields; D005720:Gamma Rays; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*