title: Coupling of ortho-substituted aryl chlorides with bulky amides.
abstract: Voluminous amides were coupled with deactivated, sterically hindered aryl chlorides in excellent yields providing products, which have not been efficiently accessible by transition metal catalysis so far. Application of an unsymmetric bisphosphine ligand was critical for the high catalytic activity.
authors: Institute of Organic Chemistry, Karlsruhe Institute of Technology, Fritz-Haber-Weg 6, D-76131 Karlsruhe, Germany.
authors: Florian C
authors: FC
authors: Falk
authors: Roland
authors: R
authors: Fröhlich
authors: Jan
authors: J
authors: Paradies
mesh_terms: D000577:Amides / Q000737:chemistry*; D002384:Catalysis; D002713:Chlorine / Q000737:chemistry*; D006841:Hydrocarbons, Aromatic / Q000737:chemistry*; D007536:Isomerism; D008958:Models, Molecular; D008968:Molecular Conformation
chemical_list: D000577:Amides; D006841:Hydrocarbons, Aromatic; D002713:Chlorine