title: [Re(CO)3Cl]-chelation-mediated electronic coupling between two amine redox sites through the 5,5'-positions of 2,2'-bipyridine.
abstract: The electronic coupling between two amine redox sites bridged through the 5,5'-positions of the [Re(CO)(3)Cl]-chelated 2,2'-bipyridine was studied by the electrochemical, spectroscopic, and EPR analysis. Interestingly, multiple near-infrared bands were observed in this new organic mixed-valent system. The results are interpreted with the aid of DFT and TDDFT calculations.
authors: Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Bejing 100190, People's Republic of China.
authors: Hai-Jing
authors: HJ
authors: Nie
authors: Chang-Jiang
authors: CJ
authors: Yao
authors: Jiannian
authors: J
authors: Yao
authors: Yu-Wu
authors: YW
authors: Zhong