title: Unique Pt5 metallacycle: [Pt(II)Cl(pyrrolidinedithiocarbamate)]5.
abstract: The neutral complex [PtCl(PyDT)](5) (PyDT = (CH(2))(4)NCS(2)(-)) represents the first example of a Pt(5) metallacycle. This unique architecture based on chiral S-bridged Pt(II) monomers was prepared by thermal degradation of the reaction product of PtCl(2) and a pyrrolidinedithioester.
authors: Dipartamento di Science Chimiche, Universita di Padova, 35131, Padova, Italy. diego.montagner@unipd.it
authors: Diego
authors: D
authors: Montagner
authors: Pablo J
authors: PJ
authors: Sanz Miguel
mesh_terms: D056831:Coordination Complexes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008968:Molecular Conformation; D010984:Platinum / Q000737:chemistry*; D011759:Pyrrolidines / Q000737:chemistry*; D013237:Stereoisomerism; D013859:Thiocarbamates / Q000737:chemistry*
chemical_list: D056831:Coordination Complexes; D011759:Pyrrolidines; D013859:Thiocarbamates; C020972:pyrrolidine dithiocarbamic acid; D010984:Platinum