title: Switching the photoinduced processes in host-guest complexes of β-cyclodextrin-substituted silicon(IV) phthalocyanines and a tetrasulfonated porphyrin.
abstract: Porphyrins and phthalocyanines are two attractive classes of functional dyes for the construction of artificial light harvesting and charge separation molecular systems. The assembly of these components by supramolecular approach is of particular interest as this provides a facile route to build multi-chromophoric arrays with various architectures and tuneable photophysical properties. We report herein a series of host-guest complexes formed between a tetrasulfonated porphyrin and several silicon(IV) phthalocyanines substituted axially with two permethylated β-cyclodextrin units via different spacers. As shown by electronic absorption and fluorescence spectroscopic methods, the two components bind spontaneously in a 1:1 manner in water with large binding constants in the range of 1.1 × 10(7) to 3.5 × 10(8) M(-1). The photophysical properties of the resulting supramolecular complexes have also been studied in detail using steady-state and time-resolved optical spectroscopic methods. It has been found that two major photoinduced processes, namely fluorescence resonance energy transfer and charge transfer are involved which are controlled by the spacer between the β-cyclodextrin units and the silicon centre of phthalocyanine. Despite the fact that charge transfer is a thermodynamically favourable process for all the complexes, only the ones with a tetraethylene glycol or oxo linker exhibit an efficient charge transfer from the excited phthalocyanine to the porphyrin entity. The lifetimes of the corresponding charge-separated states have been determined to be 200 and 70 ps by picosecond pump-probe experiments.
authors: Institut für Physik, Photobiophysik, Humboldt-Universität zu Berlin, Newtonstrasse 15, D-12489 Berlin, Germany. eugeny.ermilov@charite.de
authors: Eugeny A
authors: EA
authors: Ermilov
authors: Roel
authors: R
authors: Menting
authors: Janet T F
authors: JT
authors: Lau
authors: Xuebing
authors: X
authors: Leng
authors: Beate
authors: B
authors: Röder
authors: Dennis K P
authors: DK
authors: Ng
mesh_terms: D004563:Electrochemistry; D007211:Indoles / Q000737:chemistry*; D015394:Molecular Structure; D017646:Organosilicon Compounds / Q000737:chemistry*; D055668:Photochemical Processes; D011166:Porphyrins / Q000737:chemistry*; D013050:Spectrometry, Fluorescence; D013816:Thermodynamics; D047392:beta-Cyclodextrins / Q000737:chemistry*
chemical_list: D007211:Indoles; D017646:Organosilicon Compounds; D011166:Porphyrins; D047392:beta-Cyclodextrins; C082854:silicon phthalocyanine; C031215:betadex