title: Properties of ionic liquids on Au surfaces: non-conventional anion exchange reactions with carbonate.
abstract: A simple anion metathesis in diluted aqueous carbonate at room temperature affords 1-(12-mercaptododecyl)-3-methyl-imidazolium carbonate (MDMI-HCO(3)) from MDMI salts self-assembled on gold films and nanoparticles. The properties of MDMI-SAM differ from MDMI in solution, for which the anion exchange reaction does not proceed.
authors: Department of Chemistry, Université de Montréal, C.P. 6128 Succ. Centre-Ville, Montréal, QC, Canada.
authors: Mathieu
authors: M
authors: Ratel
authors: Mathieu
authors: M
authors: Branca
authors: Julien
authors: J
authors: Breault-Turcot
authors: Sandy Shuo
authors: SS
authors: Zhao
authors: Pierre
authors: P
authors: Chaurand
authors: Andreea R
authors: AR
authors: Schmitzer
authors: Jean-Francois
authors: JF
authors: Masson
mesh_terms: D000837:Anion Exchange Resins / Q000737:chemistry*; D002254:Carbonates / Q000737:chemistry*; D006046:Gold / Q000737:chemistry*; D007093:Imidazoles / Q000737:chemistry; D052578:Ionic Liquids / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry; D013055:Spectrophotometry, Infrared; D013059:Spectrum Analysis, Raman; D013499:Surface Properties; D013696:Temperature
chemical_list: D000837:Anion Exchange Resins; D002254:Carbonates; D007093:Imidazoles; D052578:Ionic Liquids; D006046:Gold; C029899:imidazole