title: Chloro- and phenoxy-phosphines in frustrated Lewis pair additions to alkynes.
abstract: The reaction of tBu(C(6)H(4)O(2))P, with the borane B(C(6)F(5))(3) gives rise to NMR data consistent with the formation of the classical Lewis acid-base adduct tBu(C(6)H(4)O(2))P(B(C(6)F(5))(3)) (1). In contrast, the NMR data for the corresponding reactions of tBu(C(20)H(12)O(2))P and Cl(C(20)H(12)O(2))P with B(C(6)F(5))(3) were consistent with the presence of equilibria between free phosphine and borane and the corresponding adducts. Nonetheless, in each case, the adducts tBu(C(20)H(12)O(2))P(B(C(6)F(5))(3)) (2) and Cl(C(20)H(12)O(2))P(B(C(6)F(5))(3)) (3) were isolable. The species 1 reacts with PhCCH to give the new species tBu(C(6)H(4)O(2))P(Ph)C=CHB(C(6)F(5))(3) (4) in near quantitative yield. In an analogous fashion, the addition of PhCCH to solutions of the phosphines tBu(C(20)H(12)O(2))P, tBuPCl(2) and (C(6)H(3)(2,4-tBu(2))O)(3)P each with an equivalent of B(C(6)F(5))(3) gave rise to L(Ph)C=CHB(C(6)F(5))(3) (L = tBu(C(20)H(12)O(2))P 5, tBuPCl(2)6 and (C(6)H(3)(2,4-tBu(2))O)(3)P 7). X-Ray data for 1, 2, 6 and 7 are presented. The implications of these findings are considered.
authors: Department of Chemistry, 80 St. George St., University of Toronto, Toronto, Ontario, Canada M5S 3H6.
authors: Christopher B
authors: CB
authors: Caputo
authors: Stephen J
authors: SJ
authors: Geier
authors: Eva Y
authors: EY
authors: Ouyang
authors: Christoph
authors: C
authors: Kreitner
authors: Douglas W
authors: DW
authors: Stephan