title: Selective oxidation of terminal aryl and aliphatic alkenes to aldehydes catalyzed by iron(III) porphyrins with triflate as a counter anion.
abstract: [Fe(Por)CF(3)SO(3)] (Por = porphyrin dianion) can efficiently catalyze selective oxidation of terminal aryl alkenes and aliphatic alkenes to aldehydes in good to high yields under mild conditions.
authors: Shanghai-Hong Kong Joint Laboratory in Chemical Synthesis, Shanghai Institute of Organic Chemistry, 354 Feng Lin Road, Shanghai, China.
authors: Guo-Qiang
authors: GQ
authors: Chen
authors: Zhen-Jiang
authors: ZJ
authors: Xu
authors: Cong-Ying
authors: CY
authors: Zhou
authors: Chi-Ming
authors: CM
authors: Che
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D007501:Iron / Q000737:chemistry*; D008698:Mesylates / Q000737:chemistry*; D008665:Metalloporphyrins / Q000737:chemistry*; D010084:Oxidation-Reduction; D013379:Substrate Specificity
chemical_list: D000447:Aldehydes; D000475:Alkenes; D008698:Mesylates; D008665:Metalloporphyrins; D007501:Iron