title: Coordination driven axial chirality in a microporous solid assembled from an achiral linker via in situ C-N coupling.
abstract: Metal mediated in situ C-N coupling between 4,4'-azobipyridine and disodium-trans-glutaconate at room temperature has formed a new multifunctional linker Z-dhpe which subsequently self-assembles with Zn(II) or Cd(II) resulting in a chiral or an achiral metal-organic framework, respectively, depending on its different coordination modes.
authors: Chemistry and Physics of Materials Unit, Jawaharlal Nehru Centre for Advanced Scientific Research, Jakkur, Bangalore 560 064, India.
authors: Prakash
authors: P
authors: Kanoo
authors: Ritesh
authors: R
authors: Haldar
authors: Soumya T
authors: ST
authors: Cyriac
authors: Tapas Kumar
authors: TK
authors: Maji