title: Stereoselective borylative ketone-diene coupling.
abstract: In the presence of catalytic Ni(cod)(2) and P(t-Bu)(3), ketones, dienes, and B(2)(pin)(2) undergo a stereoselective multicomponent coupling reaction. Upon oxidation, the reaction furnishes 1,3-diols as the major reaction product.
authors: Department of Chemisty, Merkert Chemistry Center, 2609 Beacon Street, Boston College, Chestnut Hill, Massachusetts 02467, USA.
authors: Hee Yeon
authors: HY
authors: Cho
authors: Zhiyong
authors: Z
authors: Yu
authors: James P
authors: JP
authors: Morken
mesh_terms: D001895:Boron / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013237:Stereoisomerism
chemical_list: D007659:Ketones; D001895:Boron