title: Nanoscale phase separation in coated Ag nanoparticles.
abstract: In this paper we report the structural investigation of cysteine and glutathione capped Ag nanoparticles (NPs) by means of transmission electron microscopy (TEM), synchrotron X-ray diffraction (XRD) and pair distribution function (PDF) analysis. The combined use of these probes allowed us to observe the presence of two crystal structures in the coated AgNPs, i.e., the cubic and the hexagonal crystal structures of Ag. In particular, it was possible to demonstrate that the coated AgNPs are a nanoscale phase separated system where the two phases coexist within the single grain. In addition, the relative bulk amount of the fcc and hcp phases has been estimated and a possible correlation with the capping agent proposed.
authors: inLAB, Inorganic Nanochemistry Laboratory, Dipartimento di Chimica, Università di Pavia, Viale Taramelli, 1227100 Pavia, Italy.
authors: Yuri Antonio
authors: YA
authors: Diaz-Fernandez
authors: Piersandro
authors: P
authors: Pallavicini
authors: Luca
authors: L
authors: Pasotti
authors: Chiara
authors: C
authors: Milanese
authors: Eva
authors: E
authors: Pellicer
authors: Maria D
authors: MD
authors: Baró
authors: Yang
authors: Y
authors: Ren
authors: Lorenzo
authors: L
authors: Malavasi
mesh_terms: D003545:Cysteine / Q000737:chemistry; D005978:Glutathione / Q000737:chemistry; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D012834:Silver / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: D012834:Silver; D005978:Glutathione; D003545:Cysteine