title: Facile synthesis of two-dimensional graphene/SnO₂ /Pt ternary hybrid nanomaterials and their catalytic properties.
abstract: In this paper, we reported a simple, aqueous-phase route to the synthesis of two-dimensional graphene/SnO(2) composite nanosheets (GSCN) hybrid nanostructures consisting of 5 nm Pt nanoparticles supported on the both sides of GSCN. Functional two-dimensional GSCN were obtained through the reduction of graphene oxide (GO) using SnCl(2) in the presence of polyelectrolyte poly(diallyldimethylammonium chloride) (PDDA). The main advantages of this preparation are that the reduction of GO, the formation of SnO(2) and the functionalization of GSCN were achieved simultaneously through one-pot reaction. GSCN/Pt ternary hybrid nanomaterials were generated by in situ reduction of negatively charged PtCl(6)(2-) precursors adsorbed on the positively charged surface of GSCN through electrostatic attraction. The as-synthesized GSCN/Pt ternary hybrid nanomaterials exhibited high cycle stabilization during the catalytic reduction of p-nitrophenol into p-aminophenol by NaBH(4). Additionally, our approach is expected to extend to other hybrid nanomaterials. We believe that the obtained GSCN/Pt ternary hybrid nanomaterials have great potential for applications in other field, such as electrochemical energy storage, sensors, and so on.
authors: State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China.
authors: Chengzhou
authors: C
authors: Zhu
authors: Ping
authors: P
authors: Wang
authors: Li
authors: L
authors: Wang
authors: Lei
authors: L
authors: Han
authors: Shaojun
authors: S
authors: Dong
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry; D000627:Aminophenols / Q000737:chemistry; D001894:Borohydrides / Q000737:chemistry; D002384:Catalysis; D006108:Graphite / Q000737:chemistry*; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure; D009596:Nitrophenols / Q000737:chemistry; D010084:Oxidation-Reduction; D010984:Platinum / Q000737:chemistry*; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D017971:Tin Compounds / Q000737:chemistry*
chemical_list: D000498:Allyl Compounds; D000627:Aminophenols; D001894:Borohydrides; D009596:Nitrophenols; D000644:Quaternary Ammonium Compounds; D017971:Tin Compounds; D010984:Platinum; D006108:Graphite; C025364:sodium borohydride; C508190:diallyldimethylammonium chloride; C045358:stannic oxide; C026729:4-aminophenol; C024836:4-nitrophenol