title: Do all the protic ionic liquids exist as molecular aggregates in the gas phase?
abstract: According to an EI-MS study of 1,1,3,3-tetramethylguanidium-based protic ionic liquids (PILs), it has been concluded that not all PILs exist as molecular aggregates in the gas phase. The detection of both ions of m/z 115.0 and m/z 116.0 for the 1,1,3,3-tetramethylguanidinium trifluoromethylsulfonate (TMGS) protic ionic liquid indicates that both the molecular and ionic aggregates co-exist in the gas phase, which is to say that the TMGS may also evaporate via the ionic aggregates just like aprotic ionic liquids. Furthermore, investigation on triethylamine-based and 1-methylimidazole-based PILs confirmed that the gas phase structure of PILs depends on both the acidity and basicity of the corresponding acid and base.
authors: School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, PR China.
authors: Xiao
authors: X
authors: Zhu
authors: Yong
authors: Y
authors: Wang
authors: Haoran
authors: H
authors: Li
mesh_terms: D005740:Gases / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D015394:Molecular Structure; D021241:Spectrometry, Mass, Electrospray Ionization
chemical_list: D005740:Gases; D052578:Ionic Liquids