title: Chiral salen-metal derivatives of polyoxometalates with asymmetric catalytic and photocatalytic activities.
abstract: Immobilization of the chiral salen-metal complex [Mn(III)(salen)(H(2)O)(2)ClO(4)] on the Keggin-type polyoxometalate (POM) skeletons leads to the isolation of POM derivatives functionalized with chiral salen-metal complexes, which represent the first examples of introducing chiral salen-metal complexes into the POM systems.
authors: Institute of Functional Materials, Department of Chemistry, Key Laboratory of Polyoxometalates Science of Ministry of Education, Northeast Normal University, Changchun, 130024, China.
authors: Xing
authors: X
authors: Meng
authors: Chao
authors: C
authors: Qin
authors: Xin-Long
authors: XL
authors: Wang
authors: Zhong-Min
authors: ZM
authors: Su
authors: Bo
authors: B
authors: Li
authors: Qi-Hua
authors: QH
authors: Yang
mesh_terms: D002384:Catalysis; D056831:Coordination Complexes / Q000737:chemistry; D018360:Crystallography, X-Ray; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
chemical_list: D056831:Coordination Complexes; D009942:Organometallic Compounds; D017973:Tungsten Compounds; C542902:Mn-salen; C102296:polyoxometalate I; D000099294:Polyoxometalates