title: Optically pure bulky (hetero)arylalkyl carbinols via kinetic resolution.
abstract: Planar chiral nucleophilic catalyst Fc-PIP was employed in the kinetic resolution of bulky (hetero)arylalkyl carbinols delivering unreacted alcohols with extremely high enantiomeric excess (>99.0% ees) in ideal conversions ranging from 50.4-56.7%.
authors: Shanghai Key Laboratory of Functional Materials Chemistry, East China University of Science and Technology, 130 Meilong Road, Shanghai 200237, China.
authors: Bin
authors: B
authors: Hu
authors: Meng
authors: M
authors: Meng
authors: John S
authors: JS
authors: Fossey
authors: Weimin
authors: W
authors: Mo
authors: Xinquan
authors: X
authors: Hu
authors: Wei-Ping
authors: WP
authors: Deng
mesh_terms: D000438:Alcohols / Q000737:chemistry; D002384:Catalysis; D005296:Ferrous Compounds / Q000737:chemistry; D007700:Kinetics; D000075163:Metallocenes; D000432:Methanol / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D000438:Alcohols; D005296:Ferrous Compounds; D000075163:Metallocenes; D011725:Pyridines; C023666:pyridine; C004998:ferrocene; D000432:Methanol