title: Photoswitching of the antiferromagnetic coupling in an oxamato-based dicopper(II) anthracenophane.
abstract: Thermally reversible photomagnetic (ON/OFF) switching behavior has been observed in a dinuclear oxamatocopper(II) anthracenophane upon UV light irradiation and heating; the two Cu(II) ions (S(Cu) = 1/2) that are antiferromagnetically coupled in the dicopper(II) metallacyclic precursor (ON state) become uncoupled in the corresponding [4+4] photocycloaddition product (OFF state), as substantiated from both experimental and theoretical studies.
authors: Instituto de Ciencia Molecular (ICMol), Universitat de València, 46980 Paterna, València, Spain.
authors: María
authors: M
authors: Castellano
authors: Jesús
authors: J
authors: Ferrando-Soria
authors: Emilio
authors: E
authors: Pardo
authors: Miguel
authors: M
authors: Julve
authors: Francesc
authors: F
authors: Lloret
authors: Corine
authors: C
authors: Mathonière
authors: Jorge
authors: J
authors: Pasán
authors: Catalina
authors: C
authors: Ruiz-Pérez
authors: Laura
authors: L
authors: Cañadillas-Delgado
authors: Rafael
authors: R
authors: Ruiz-García
authors: Joan
authors: J
authors: Cano